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Pilot Production and Properties of ALUHAB Aluminium Foams

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Procedia Materials Science 4 (2014) 121 – 126 Available online at www.sciencedirect.com 2211-8128 © 2014 Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/). Peer-review under responsibility of Scientific Committee of North Carolina State University doi:10.1016/j.mspro.2014.07.549 ScienceDirect 8th International Conference on Porous Metals and Metallic Foams, Metfoam 2013 Pilot production and properties of ALUHAB aluminium foams Norbert Babcsan a, *, Sandor Beke a , Peter Makk a , Gyorgy Szamel a , Csilla Kadar b a Aluinvent Zrt, Szeles u. 2, Felsozsolca, H-3561 Hungary b Department of Materials Physics, Lorand Eotvos University, POB. 32., Budapest, H-1518, Hungary Abstract ALUHAB is a new type of aluminium foams with controlled, homogeneous cell sizes which has a wide range of alloy compositions, and attractive mechanical properties. The technology results in extremely stable metal foams which can be cast into complex forms and re-melted without loss of foam integrity. ALUHAB aluminium foams are manufactured from aluminium alloy containing ultrafine particles (typically below 3μm). Special high temperature admixing technology is used in order to homogeneously disperse the particles and thus create a stable, foamable aluminium melt. Our unique loud-nozzle technology permits the injection of bubbles with optimal size which can vary between 0.5mm and 5mm. CT imaging, different analytical techniques and mechanical tests were used to characterize the influence of the alloy composition and the cell structure on the compression properties. Our recent pilot plant technology is capable to produce 100kg/day aluminium foam block of maximum 200mm width and the thickness can be varied from 20mm to 50mm. Keywords: Aluminium foam; production; characterization; properties; applications; 1. Introduction Cellular metals such as foamed metals are attractive material for light weight design. Several types of metallic foams have been produced (Banhart et al. (2002), Gergely et al. (2000)) since the first invented “foam-like mass of metal” in 1948 (US Patent (1948)). A number of metals and alloys can be foamed (Banhart et al. (2000), Degischer et al. (2002)), but among these the aluminium foams are the most studied and have the highest application and market potential (Gibson et al. (1997), Ashby et al. (2000)). Despite the developments of different production routes * Corresponding author. Tel.: +36-30-415-0001; fax: +36-46-325-317. E-mail address: [email protected] © 2014 Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/). Peer-review under responsibility of Scientific Committee of North Carolina State University
Transcript
Page 1: Pilot Production and Properties of ALUHAB Aluminium Foams

Procedia Materials Science 4 ( 2014 ) 121 – 126

Available online at www.sciencedirect.com

2211-8128 © 2014 Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/).Peer-review under responsibility of Scientifi c Committee of North Carolina State Universitydoi: 10.1016/j.mspro.2014.07.549

ScienceDirect

8th International Conference on Porous Metals and Metallic Foams, Metfoam 2013

Pilot production and properties of ALUHAB aluminium foams Norbert Babcsana,*, Sandor Bekea, Peter Makka, Gyorgy Szamela, Csilla Kadarb

aAluinvent Zrt, Szeles u. 2, Felsozsolca, H-3561 Hungary bDepartment of Materials Physics, Lorand Eotvos University, POB. 32., Budapest, H-1518, Hungary

Abstract

ALUHAB is a new type of aluminium foams with controlled, homogeneous cell sizes which has a wide range of alloy compositions, and attractive mechanical properties. The technology results in extremely stable metal foams which can be cast into complex forms and re-melted without loss of foam integrity. ALUHAB aluminium foams are manufactured from aluminium alloy containing ultrafine particles (typically below 3µm). Special high temperature admixing technology is used in order to homogeneously disperse the particles and thus create a stable, foamable aluminium melt. Our unique loud-nozzle technology permits the injection of bubbles with optimal size which can vary between 0.5mm and 5mm. CT imaging, different analytical techniques and mechanical tests were used to characterize the influence of the alloy composition and the cell structure on the compression properties. Our recent pilot plant technology is capable to produce 100kg/day aluminium foam block of maximum 200mm width and the thickness can be varied from 20mm to 50mm. © 2014 The Authors. Published by Elsevier Ltd. Peer-review under responsibility of Scientific Committee of North Carolina State University.

Keywords: Aluminium foam; production; characterization; properties; applications;

1. Introduction

Cellular metals such as foamed metals are attractive material for light weight design. Several types of metallic foams have been produced (Banhart et al. (2002), Gergely et al. (2000)) since the first invented “foam-like mass of metal” in 1948 (US Patent (1948)). A number of metals and alloys can be foamed (Banhart et al. (2000), Degischer et al. (2002)), but among these the aluminium foams are the most studied and have the highest application and market potential (Gibson et al. (1997), Ashby et al. (2000)). Despite the developments of different production routes

* Corresponding author. Tel.: +36-30-415-0001; fax: +36-46-325-317.

E-mail address: [email protected]

© 2014 Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/).Peer-review under responsibility of Scientifi c Committee of North Carolina State University

Page 2: Pilot Production and Properties of ALUHAB Aluminium Foams

122 Norbert Babcsan et al. / Procedia Materials Science 4 ( 2014 ) 121 – 126

for a range of prototypes and of small scale plants for semi-finished foam products (US Patent (1987), Wood (1998), US Patent (1992), Leitlmeier et al. (2002)), there is still a lack in commercialization of aluminium foams. We developed a novel metal foaming technology (Babcsan et al.) which resulted in a new type of aluminium foam called ALUHAB.

This foam can be produced with controlled cell size and mechanical properties. It is a new material which combines the light-weight structure of polymers and the strength and resistance of metals. By controlling the cell size of the metal foam a broad range of density and mechanical strength combination can be achieved. It also exhibits excellent sound and energy absorbance, which are essential in the field of safety. This new process is cost efficient and since the resulting foam is stable it can be cast in different shapes and can also be used as a core material to fabricate composite structures.

2. Experimental Approach

2.1. Production of foamable composites

The matrix alloy of ALUHAB is a special foamable composite containing ultrafine particles (80nm-20µm). The composite is made by a special high temperature compounding technology which ensures the homogeneous distribution of the foam stabilizing particles. Thus, it is possible to produce foamable alloys from any composition from casting to wrought alloy.

2.2. Foaming of aluminium

In contrast to previous technologies the size of bubbles (and hence the density of the foam) is adjustable and can be changed during the foaming with the same injector. Thus, foams with mixed cell size can be produced as well. Due to loud-nozzle technology the cell size of ALUHAB can be adjusted precisely. The minimum size of bubble can be as small as the diameter of the nozzle, thus, sub-millimeter bubbles can be produced. The recent cell size of ALUHAB is in the range of 0.5-5.0mm.

Foam density is 0.6g/cm3, average cell size is 1.0mm.

3. Results and Discussion

ALUHAB foam has high strength: the compressive and the tensile strength of foam of 1g/cm3 density can vary from 40MPa to 80MPa, while the flexural strength is 140MPa. The high strength of ALUHAB is due to the unique homogeneity of foam cells and the ultrafine stabilizing additive, which has a further strengthening effect. To ensure reliability of the measurement of material parameters such as mechanical strength, the effect of the sample size on the reproducibility of compression strength was investigated. As Fig. 1. shows for the proper determination of the compression strength at least 30 cells large test samples are required.

The effect of the density and the homogeneity of the foam structure on the compression strength were also investigated. The curves of Fig. 2. illustrate the changes in compression properties with increasing foam density.

Regarding the specific strength values, the ALUHAB competes with plastics, aluminium and magnesium alloys. Its heat conductivity is around 32W/mK (of a 1g/cm3 density foam). The structure homogeneity of ALUHAB foam is shown on Fig. 3.

Table I. describes the main technical parameters of ALUHAB foams with different densities. All of these parameters can be designed according to the requirements.

By the application of casting technologies (low pressure casting, die-casting, cast rolling) ALUHAB can be easily shaped upon user demands.

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123 Norbert Babcsan et al. / Procedia Materials Science 4 ( 2014 ) 121 – 126

Fig. 1. Effect of the sample size on the reproducibility of the compressive strength (AlSi10/8vol%SiCp(2μm)).

Fig. 2. The effect of the density, homogeneity and structural defects on the compressive properties of ALUHAB aluminium foams.

(AlSi10/5vol%SiCp(2μm)). The thickness of the black marker is 1.0mm).

Optical image Radioscopic slices Optical image Radioscopic slices

(a) (b) Fig. 3. Optical image (above) and radioscopic slices (below) of 0.4g/cm3 density (a) and 1.0g/cm3 density (b)

ALUHAB aluminium foams.

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124 Norbert Babcsan et al. / Procedia Materials Science 4 ( 2014 ) 121 – 126

ALUHAB is the first remeltable and castable metal foam (Fig. 4.) with several useful properties. It can be cast into complex shapes (and the casting does not change the properties of the metal foam).

The ALUHAB aluminium foam can be laminated by aluminium sheets during cast rolling, or it can be applied as a core material of other types of sandwich structures (Fig. 5.). Furthermore, any type of surface treatment methods (like painting, anodic oxidation, sanding) can be applied in its solid state (Fig. 6.).

Fig 4. Optical (left) and X-ray (right) image of a cast ALUHAB aluminium foam part. Sample diameter is 50mm, foam density is 1.2g/cm3, average cell size is 0.9mm (AlSi10/8vol%Al2O3p(2μm)).

Fig. 5. Image of a sandwich structure having ALUHAB foam core and wood plate reinforcement. Core thickness is 5mm. Foam density is

0.6g/cm3, average cell size is 1.0mm (AlSi10/5vol%SiCp(2μm)).

Fig. 6. The optical image of the surface of a sand-blasted ALUHAB foam panel. Foam density is 0.6g/cm3, average cell size is 1.0mm

(AlSi10/5vol%SiCp(2μm)).

Fig. 7. Photograph of machined ALUHAB blocks: AA6061/8vol%Al2O3p(2μm) density: 1g/cm3, cell size: 2mm, panel thickness: 55mm (left),

AA6061/5vol%Al2O3p(2μm) density:0.5g/cm3, cell size:0.8mm, panel thickness: 45mm (right).

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125 Norbert Babcsan et al. / Procedia Materials Science 4 ( 2014 ) 121 – 126

The foam can also be cut in any direction. Since ALUHAB does not disintegrate during machining, it meets the fundamental conditions and suitable for parts production such as turning, milling, slicing and cogging (Fig. 7-8.). This foam is easily drillable, it steadily keeps the screw, and the wood-screw can be drove into it without threading, so different ALUHAB parts can be screwed together easily.

Applying the conventional aluminium welding techniques ALUHAB foams can be easily welded together with bulk aluminium of different shapes or its own material, also at high working rates (Fig. 9.). The main advantage of its weldability is that it ensures a high degree of material homogeneity between the load bearing framework and other structural elements. It distributes the load evenly.

ALUHAB can be produced on customer demand. In contrast with competitor products ALUHAB is able to completely meet the requirements of secondary processing (precision casting, die-casting, extrusion, roll casting, etc.). The mass produced aluminium foam can be easily transported to the place of use, and inexpensively and effectively integrated into the given technological process (for example in foundries). It means that in a conventional aluminium processing plant it is not necessary to install a foaming production line, only a melting unit should be adapted for the metal foam processing.

Table 1. Main characteristics of low and high density ALUHAB aluminium foams

Shape Foam density (g/cm3)

Yield Strength (MPa)

Yield Strength (Ashby model) (MPa)

Composition A359/5vol% SiCp(2μm)

A359/20vol% SiCp(10μm)

Density 400 1000 kg/m3

Average cell size 1.15 0.65 mm

Cell size half width 0.21 0.05 mm

Compressive strength 6 40 MPa

Compressive modulus 500 7000 MPa

Densification strain 40 25 %

Specific energy absorption

20% strain 3.2 8 kJ/kg

50% strain 8.3 26.3 kJ/kg

Volumetric energy absorption

20% strain 1.2 8 MJ/m3

50% strain 3.1 26.3 MJ/m3

Heat conductivity 12 32 W/mK

Fig. 8. Photograph of a machined low density (0.3g/cm3) ALUHAB block. Block size: 180mm x 100mm x 30mm. Cell size: 0.6mm

(AlSi10/8vol%Al2O3p(2μm))

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126 Norbert Babcsan et al. / Procedia Materials Science 4 ( 2014 ) 121 – 126

Fig. 9. Image of a welded ALUHAB foam block. The foam density is 1.2g/cm3, cell size is 1.0mm. (AA6061/5vol% Al2O3p(2μm))

4. Conclusions

We aimed to implement an innovative manufacturing process which involves a cost effective production technology of aluminium foam. Our foamable composite production process, as part of the aluminium foaming technology, provided prerequisites for manufacturing a recyclable engineered material with enhanced mechanical properties, which is price competitive with modern light weight structural materials as magnesium or engineering plastics. The effects of foam density and structural characteristics on typical mechanical properties were investigated.

We are going to assess the technical and market potential and corresponding effects of our innovation through lifecycle analysis, prototype making, standardization of both the process and the testing, recyclability procedures and collaboration with strong end-users for specific application fields..

References

Ashby, M.F., A.G. Evans, J.W. Hutchinson, N.A. Fleck, Metal Foams: a Design Guide, Butterworth-Heinemann, USA, 2000. Banhart, J. 2000. “Manufacturing routes for metallic foams”, JOM, 52: 22-27 Banhart, J., D. Weaire. “On the Road Again: Metal Foams Find Favor”, Physics Today, Jul 2002, pp.37-42. Degischer, H.P., B. Kriszt, Handbook of cellular metals, Production, Processing and Applications, Wiley-VCH/Verlag GmbH, Germany, 2002. Gergely, V., H.P. Degischer, and T.W. Clyne. 2000. “Recycling of MMCs and production of metallic foams”, Comprehensive Composite

Materials, 3: 797-820 Gibson, L.J., M.F. Ashby, Cellular Solids, Structure and Properties, 2nd ed., Cambridge, U.K, 1997. Leitlmeier, D., H.P. Degischer, H.J. Flankl. 2002. “Development of a foaming process for particulate reinforced aluminum melts”, Advanced

Engineering Materials, 10: 735-740. N. Babcsan, S. Beke, P. Makk, Method for producing a metal foam by oscillations and thus obtained metal foam product, Patent

WO2010_064059 A2. US Patent 2,434,775 (1948) US Patent 4,713,277 (1987) US Patent 5,151,246 (1992) Wood, J.T., “Production and Application of Continuously Cast, Foamed Aluminum”, in Metal Foams, eds. J. Banhart and H. Eifert, MIT/Verlag,

Germany, 1998., pp. 31-35.


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