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PRE-RESTORATION ANALYSIS OF DISCHARGE, SEDIMENT TRANSPORT RATES, WATER QUALITY, AND LAND-USE IMPACTS IN THE BAYOU LA BATRE WATERSHED, MOBILE COUNTY, ALABAMA
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Page 1: PRE-RESTORATION ANALYSIS OF DISCHARGE, SEDIMENT … · PRE-RESTORATION ANALYSIS OF DISCHARGE, SEDIMENT TRANSPORT RATES, WATER QUALITY, AND LAND-USE IMPACTS IN THE BAYOU LA BATRE WATERSHED,

PRE-RESTORATION ANALYSIS OF DISCHARGE,

SEDIMENT TRANSPORT RATES, WATER QUALITY,

AND LAND-USE IMPACTS IN

THE BAYOU LA BATRE WATERSHED,

MOBILE COUNTY, ALABAMA

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PRE-RESTORATION ANALYSIS OF DISCHARGE,

SEDIMENT TRANSPORT RATES, WATER QUALITY,

AND LAND-USE IMPACTS IN

THE BAYOU LA BATRE WATERSHED,

MOBILE COUNTY, ALABAMA

By

Marlon R. Cook,

Polyengineering, Inc.

Funding for this project was provided by the

Mobile Bay National Estuary Program

August 2016

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TABLE OF CONTENTS

Introduction .........................................................................................................................1

Acknowledgments ...............................................................................................................1

Project area...........................................................................................................................1

Project monitoring strategy and site conditions ...................................................................3

Land use ...............................................................................................................................3

Stream flow conditions ........................................................................................................6

Specific conductance ...........................................................................................................8

Turbidity ..............................................................................................................................9

Sedimentation ....................................................................................................................12

Sediment loads transported by project streams ............................................................13

Suspended sediment ...............................................................................................13

Bed sediment ..........................................................................................................17

Total sediment loads ..............................................................................................18

Nutrients .............................................................................................................................20

Nitrate ....................................................................................................................20

Phosphorus .............................................................................................................21

Dissolved oxygen ...............................................................................................................23

Conclusions and sources of water-quality impacts ............................................................24

References cited .................................................................................................................29

ILLUSTRATIONS

Figure 1. Bayou La Batre project area ..............................................................................2

Figure 2. Bayou La Batre watershed, streams, and monitored sites .................................4

Figure 3. Land use classifications for the Bayou La Batre area ........................................5

Figure 4. USGS 7.5-minute topographic map of a selected area of the Bayou

La Batre watershed, showing stream gradients and anthropogenic

features ...............................................................................................................7

Figure 5. Conductivity and discharge relationships for samples collected at

sites BLB1 and BLB2 ......................................................................................10

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Figure 6. Turbidity and TSS relationship showing difference between fresh-

and saline-water samples at site BLB1 ............................................................11

Figure 7. Average turbidity and discharge relationships for Bayou La Batre

monitored sites .................................................................................................11

Figure 8. Turbidity and TSS relationship for fresh-water samples from Carls

Creek site BLB3 ...............................................................................................14

Figure 9. Average annual daily discharge and suspended sediment loads for

Bayou La Batre monitored sites .......................................................................16

Figure 10. Comparisons of total sediment geologic erosion rate loads with

estimated total sediment loads for monitored Bayou La Batre

watersheds ........................................................................................................18

Figure 11. Comparison of total sediment loads for streams in Baldwin and

Mobile Counties ...............................................................................................19

Figure 12. Relationships of measured nitrate with measured conductance and

discharge at site BLB3 (Carls Creek man-made channel at Arnette

Street) ...............................................................................................................22

Figure 13. Relationship of nitrate and discharge at site BLB4 (Carls Creek

natural channel at Arnette Street) ....................................................................22

Figure 14. Carls Creek channel bifurcation just south of Padgett Switch Road ................25

Figure 15. Sources of water quality impacts identified by field observations ...................27

Figure 16. Turbid runoff from row-crop fields in unnamed tributary to

Hammar Creek at Tom Waller Road immediately after a rain event ..............28

TABLES

Table 1. Stream-flow characteristics for monitored sites in the

Bayou La Batre watershed .................................................................................8

Table 2. Measured specific conductance values for the Bayou La Batre

monitoring sites ..................................................................................................9

Table 3. Measured discharge, turbidity, and TSS and estimated suspended

sediment loads in monitored streams in Bayou La Batre watershed ...............15

Table 4. Dissolved oxygen measured in monitored streams in the Bayou La

Batre watershed ................................................................................................24

Appendix A—Field and analytical data .............................................................................31

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INTRODUCTION

Commonly, land-use and climate are major contributors to non-point source

contaminants that impact surface-water quality. In parts of Baldwin and Mobile Counties,

population growth and economic development are critical issues leading to land-use

change. When combined with highly erodible soils and Alabama’s coastal climate,

characterized by cyclonic storms that produce high intensity rainfall events, deleterious

water-quality and biological habitat impacts can be severe. Previous investigations of

sediment transport and general water quality have shown dramatic increases in sediment

loading and loss of biological habitat in streams downstream from areas affected by rapid

runoff and resulting erosion from particular types of land uses. Other areas are virtually

unimpacted by land-use change and are characterized by natural landscapes dominated by

forests and wetlands. Results of these investigations are valuable in quantifying impacts

so that limited regulatory and remedial resources may be focused to remediate problem

areas or to preserve relatively pristine watersheds.

The purpose of this investigation is to assess general hydrogeologic and water

quality conditions and to estimate sediment loads for Bayou La Batre and its tributaries.

These data will be used to quantify water quality impacts and to support development of

a watershed management plan, designed to preserve, protect, and restore the Bayou La

Batre watershed.

ACKNOWLEDGMENTS

Ms. Roberta Swann, Director; Ms. Amy Newbold, Deputy Director; and Mr. Tom

Herder, Watershed Protection Coordinator, Mobile Bay National Estuary Program,

provided administrative and coordination assistance for the project; Mr. Bruce Bradley,

President, Polyengineering, Inc., provided administrative and technical assistance; Mr.

Christopher Warn, Senior Project Manager, Dewberry, provided coordination for the

watershed management plan.

PROJECT AREA

The Bayou La Batre watershed covers 19,584 acres (30.6 square miles (mi2) (US

Geological Survey (USGS), 2016) in southern Mobile County (fig. 1). The project area

includes monitoring sites on three tributaries and the main stem of Bayou La Batre.

Bayou La Batre flows southwestward from its headwaters about one and three quarters

miles northeast of the town of Bayou La Batre to its mouth in Portersville Bay in the

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Mississippi Sound (fig 2). Elevations in the project area vary from about 15 feet above

mean sea level (ft MSL) at the headwaters to sea level at the mouth. The three monitored

tributaries include two unnamed streams, and Carls Creek. Carls Creek is the largest

subwatershed, containing 13,248 acres (20.7 mi2) (USGS, 2016) and two tributaries;

Hammar Creek and Bishops Manor Creek with maximum elevations of about 140 ft

MSL.

Figure 1.— Bayou La Batre project area.

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PROJECT MONITORING STRATEGY AND SITE CHARACTERISTICS

The monitoring strategy employed for the Bayou La Batre project was to collect

water samples at each site over a wide range of discharge from base flow to high flow for

analyses of total suspended solids, nitrate, and total phosphorus, and constituent load

estimation. A number of factors, including site accessibility in a rural, wetlands

dominated setting, extensive wetlands and tidal influence that constrains stream flow and

impacts water chemical character, and selection of sites as far downstream as possible,

were considered during selection of monitoring sites.

Site BLB1 is on the main stem of Bayou La Batre at Wintzell Avenue, the most

downstream access point, flowing southwestward, 2.5 mi from the mouth (latitude (lat)

30.40572, longitude (long) -88.24798). The watershed upstream from site BLB1 covers

14,848 acres (23.2 mi2 ) (USGS, 2016) (fig. 2).

Site BLB2 is on an unnamed tributary on the northwest side of the town of Bayou

La Batre at the Little River Road crossing (lat 30.40706, long -88.25691). The watershed

upstream from site BLB2 covers 3,200 acres (5.0 mi2 ) (USGS, 2016) (fig. 2).

Sites BLB3 and BLB4 are on Carls Creek, which is formed by two tributaries,

Hammar Creek and Bishops Manor Creek, that join to form Carls Creek 2.5 miles

upstream from Site BLB3 (fig. 2). One mile downstream from the tributary confluence,

the Carls Creek channel splits (fig. 2). Site BLB3 is on a man-made channel at the

Arnette Street crossing, about 1.5 miles downstream from the split (lat 30.41066, long -

88.24566) (fig. 2). The man-made channel rejoins the natural channel 400 ft downstream

from site BLB3 and flows into Bayou La Batre 2,600 ft downstream from the site (fig.2).

Site BLB4 is on a natural channel at the Arnette Street crossing (lat 30.41060,

long -88.24496), 150 ft east of the BLB3 site and 1.5 mi downstream from the Carls

Creek channel split. The watershed upstream from sites BLB3 and BLB4 contains 13,248

acres (20.7 mi2 ) (USGS, 2016) (fig. 2).

LAND USE

Land use is directly correlated with water quality, hydrologic function, ecosystem

health, biodiversity, and the integrity of streams and wetlands. Land-use classification for

the project area was calculated from the USDA National Agricultural Statistics Service

2013 Alabama Cropland Data Layer (NASS CDL) raster dataset. The CDL is produced

using satellite imagery from the Landsat 5 TM sensor, Landsat 7 ETM+ sensor, the

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Spanish DEIMOS-1 sensor, the British UK-DMC 2 sensor, and the Indian Remote

Sensing RESOURCESAT-1 (IRS-P6) Advanced Wide Field Sensor (AWiFS) collected

during recent growing seasons (USDA, 2013). Figure 3 shows land use, subdivided into

17 classified types defined as developed, forested, grassland, wetlands, barren areas, open

water, and agriculture, subdivided into eight specific crops (fig. 3).

Bayou La Batre watershed

Hammar Creek

Bishop Manor Creek Carls Creek

Bayou La Batre

BLB1 BLB4

BLB3

BLB2

Figure 2.—Bayou La Batre watershed, streams, and monitored sites.

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The dominant land use category in the Bayou La Batre watershed is pasture/hay

and wetlands (fig. 3). Wetlands are important because they provide water quality

improvement and management services such as: flood abatement, storm water

management, water purification, shoreline stabilization, groundwater recharge, and

streamflow maintenance. The next largest land use categories are evergreen and mixed

forest and surprisingly, developed land (fig. 3). Developed land in the northern part of the

watershed (Carls Creek and tributaries) is dominated by residential development,

Figure 3.-Land use classifications for the Bayou La Batre area.

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primarily along roadways (fig. 3). Developed land in the southern part of the watershed is

primarily related to the town of Bayou La Batre (fig. 3). Agriculture is a dominant land

use in the headwaters of Carls Creek tributaries (fig. 3). Crops consist of peanuts,

soybeans, corn, cotton, and pecans. Land uses and their specific impacts are discussed in

detail in the Conclusions and Sources of Water-Quality Impacts section of the report.

STREAM FLOW CONDITIONS

Numerous streams in Baldwin County exhibit flashy discharge due to relatively

high topographic relief and land-use change. Most streams in the Dog River watershed, in

and near the city of Mobile, are also flashy, with relatively high velocities and an average

stream gradient of 48 ft/mi, due to channelization and urbanization. However, the

character of stream flows in the Bayou La Batre watershed are quite different and

influenced by a number of natural and anthropogenic factors. Stream channels in the

northern part of the watershed, consisting of Carls Creek tributaries (Bishop Manor and

Hammar Creeks) are characterized by relatively high elevation (maximum 140 ft MSL,

average 48 ft MSL), with topography that decreases in relief from north (upstream) to

south (downstream). The tributary flood plains are dominated by wetlands, channels that

are in part, anastomosing, and stream gradients that decrease from upstream to

downstream in three zones from 33 to 21 to 10 ft/mi (fig. 4). Prior to 1956, anthropogenic

impacts influencing stream discharge in the downstream part of Carls Creek, include a

relief channel 1.6 miles long along Padgett Switch Road and eight man-made channels

constructed to drain a 300-acre low area between the Carls Creek relief channel and

Padgett Switch Road (fig. 4). After 1985, much of the drained area was filled to construct

Lucille Zirlott Park, a number of businesses, and a medical center along Padgett Switch

Road. However, one of the drainage ditches and the Carls Creek relief channel remain.

Other anthropogenic impacts to stream flow include a 6,800-foot-long constructed

channel in the headwaters of Bayou La Batre, east of the town of Bayou La Batre (fig. 4).

The Carls Creek natural channel, monitored unnamed tributary, and Bayou La Batre are

in the Alabama Coastal Zone, where they flow through the eastern extent of Grand Bay

Swamp, and have an average gradient of 7 ft/mi. The Carls Creek man-made channel has

a gradient of 11 ft/mi. Conductance values for a number of monitoring events indicate

tidal influence on volume and quality of stream flow.

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Figure 4.—USGS 7.5-minute topographic map of a selected area of the Bayou La Batre watershed,

showing stream gradients and anthropogenic features.

Carls Creek channelized drainage

Bayou La Batre channelization

High stream gradients

Moderate stream gradients

Low stream gradients

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A wide range of discharge events are required to adequately evaluate hydrologic

conditions in Bayou La Batre. Table 1 shows that sampling occurred in the Bayou La

Batre watershed during discharge conditions from base flow to flood. For example,

minimum discharge measured for Carls Creek at Arnette Street (site 3) was 10.3 cfs

(January 13, 2016) and the maximum was 444 cfs, measured on January 21, 2016 .

Average daily discharge for each monitored stream is also required to adequately

estimate constituent loading. Discharge data collected at the USGS stream gaging site

02471078, Fowl River at Half Mile Road, near Laurendine, Alabama was used as a basis

for average daily discharge estimation for each monitored stream.

Table 1.—Stream-flow characteristics for monitored sites in the

Bayou La Batre watershed.

Monitored

site

Average

discharge

(cfs)

Maximum

discharge

(cfs)

Minimum

discharge

(cfs)

Average discharge

per unit area

(cfs/mi)

Average

stream flow

velocity

(ft/s)

Stream gradient

(ft/mi)

1 1,131 1,9371 4391 49 0.6 3.2

2 162 2301 110 35 0.5 8.6

3 131 444 10 1.1

4 160 2811 17 0.9

3 and 4 291 725 27 14 1.0 16.3 1TI- tidal influence

SPECIFIC CONDUCTANCE

Surface water in each project watershed is characterized by a unique specific

conductance (SC) (microseimens/centimeter (µS/cm)) profile based on physical and

chemical properties. The variability of SC is influenced by differences in stream

temperature, discharge, total dissolved solids, local geology and soil conditions, and ionic

influxes from nonpoint sources of pollution or from seawater in reaches of streams with

tidal influence. Streams without significant contaminant sources exhibit increased SC

values with decreasing discharge due to increasing volumes of relatively high SC

groundwater inflow and decreased SC with increasing discharge due to increasing volumes

of relatively low SC runoff. The opposite SC character is exhibited for streams with

significant contaminant sources where relatively high conductance runoff causes

increasing SC with increasing discharge. Fluctuations of SC in streams with tidal influence

correspond to tidal cycles with relatively high SC (salt water) at high tide and relatively

low SC (fresh water) at low tide. However, the relationship between runoff, discharge, tidal

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cycles, and conductivity can be extremely complex, as was observed in data collected at

sites BLB1 and BLB2. Table 2 shows SC in monitored streams in the Bayou La Batre

watershed. Figure 5 shows the relationship between discharge and conductivity for samples

collected at sites BLB 1 and 2. BLB1 samples are grouped by relatively high discharge and

low conductivity and relatively low discharge and high conductivity. BLB2 samples are

grouped by relatively high and low conductivity, but discharge does not appear to have an

influence. This is most likely due to the dominance of wetlands and marsh upstream from

site BLB2 that limits surface-water runoff and maximizes groundwater contributions to

flow. However, it is clear that tidal cyclicity is a major influence on the chemical character

of these waters.

Table 2.—Measured specific conductance values for the Bayou La Batre

monitoring sites.

Monitoring

site

Maximum

conductivity

(µS/cm)

Minimum

conductivity

(µS/cm)

Average

conductivity

(µS/cm)

1 22,100 101 11,880

2 21,700 42 9,982

3 630 39 230

4 1,690 37 388

TURBIDITY

Turbidity in water is caused by suspended and colloidal matter such as clay, silt,

finely divided organic and inorganic matter, and plankton and other microscopic

organisms (Eaton, 1995). Turbidity is an expression of the optical property that causes

light to be scattered and absorbed rather than transmitted with no change in direction or

flux level through the stream (Eaton, 1995). Turbidity values measured in nephlametric

turbidity units (NTU) from water samples may be utilized to formulate a rough estimate

of long-term trends of total suspended solids (TSS) and therefore may be used to observe

trends in suspended sediment transport in streams. This relationship is more complex in

estuaries and streams with tidal influence, as is the case for streams in the Bayou La

Batre watershed. Turbidity and TSS in marine settings originate from organic and

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inorganic material. Salinity of the ocean or estuary will cause suspended solids to

aggregate, or combine. As the aggregate weight increases, the solids begin to sink and

will settle on the seafloor or estuary bottom. This effect causes greater water clarity than

is observed in most lakes and rivers. The higher the salinity, the greater the effect. In

estuaries and tidal streams, turbidity values may be consistently high, due to the constant

resuspension of settled solids as tides move in and out (Fondriest Environmental, Inc.,

2014). However, turbidity and TSS in tidally influenced streams in the Bayou La Batre

watershed correlate differently, depending on whether the samples are fresh or saline (fig.

6). Samples from Bayou La Batre streams with elevated conductivity (saline water)

resulting from tidal influence, on average, have 43 percent higher TSS concentrations

than fresh-water samples with the same turbidity values. Figure 6 shows fresh-water and

saline-water turbidity and TSS correlations.

10

100

1,000

10,000

100,000

0 500 1,000 1,500 2,000

Co

nd

uct

ivit

y

Discharge BLB1 BLB2

Figure 5.—Conductivity and discharge relationships for samples collected at

sites BLB1 and BLB2.

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Analyses of turbidity and stream discharge provide insights into hydrologic, land-

use, and general water-quality characteristics of a watershed. Average measured turbidity

and discharge, shown in figure 7, illustrates that generally, site BLB3 (channelized part of

Carls Creek at Arnette Street) has the highest turbidity to discharge ratio (0.4 NTU/cfs),

0

5

10

15

20

25

30

35

0 10 20 30 40 50 60 70

TSS

(mg/

L)

Turbidity

saline water

fresh water

0

200

400

600

800

1000

1200

0 5 10 15 20 25 30 35 40 45 50

Dis

char

ge (

cfs)

Turbidity (NTU) BLB1 BLB2 BLB3 BLB4

Figure 6.—Turbidity and TSS relationship showing difference between

fresh- and saline-water samples at site BLB1.

Figure 7.—Average turbidity and discharge relationships for Bayou La Batre

monitored sites.

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site BLB 4 (natural channel of Carls Creek at Arnette Street) is 0.1 NTU/cfs, site BLB2

(unnamed tributary at Little River Road) is 0.04 NTU/cfs, and site BLB1 (BLB at

Wintzel Avenue) has the lowest (0.02 NTU/cfs).

Commonly, excessive turbidity is closely tied to land uses that cause land

disturbances that lead to erosion or to land uses that cause excessive runoff. Field

observation indicate that a number of row crop fields in the headwaters of Bishop Manor

Creek have intermittent drainage channels with no vegetative buffers. Although a

majority of the monitoring data for Carls Creek (the largest tributary watershed in the

Bayou La Batre system) was collected in the downstream part of the watershed in order

to estimate constituent loading, additional data were collected at upstream sites to

determine tributary and headwaters contributions to downstream water quality. Storm

impacted flows were monitored in early August 2016 in the Bishop Manor and Hammar

Creeks watershed. Turbidity for Bishop Manor Creek, 1.8 mi upstream from the

confluence with Hammar Creek (Bishop Manor Creek at Argyle Road) was 114 NTU

and for Hammar Creek, 1.2 mi upstream from the confluence with Bishop Manor Creek

(Hammar Creek at 3 Mile Road) was 44 NTU. The highest turbidity measured during the

project period was 375 NTU at an unnamed tributary to Hammar Creek at Tom Weller

Road. This is a headwaters tributary, where part of the stream flows through row crop

fields with no vegetative buffer.

SEDIMENTATION

Sedimentation is a process by which eroded particles of rock are transported

primarily by moving water from areas of relatively high elevation to areas of relatively

low elevation, where the particles are deposited. Upland sediment transport is primarily

accomplished by overland flow and rill and gully development. Lowland or flood plain

transport occurs in streams of varying order, where upland sediment joins sediment

eroded from flood plains, stream banks, and stream beds. Erosion rates are accelerated by

human activity related to agriculture, construction, timber harvesting, unimproved

roadways, or any activity where soils or geologic units are exposed or disturbed.

Excessive sedimentation is detrimental to water quality, destroys biological habitat,

reduces storage volume of water impoundments, impedes the usability of aquatic

recreational areas, and causes damage to structures.

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Precipitation, stream gradient, geology and soils, and land use are all important

factors that influence sediment transport characteristics of streams. Sediment transport

conditions in the Bayou La Batre watershed are evaluated and quantified by tributary, in

order to evaluate factors impacting erosion and sediment transport at a localized scale. In

addition to commonly observed factors above, wetlands, vegetation, and tidal effects also

play prominent roles in sediment transport and overall water quality in the Bayou La

Batre watershed. Estimates of sediment loads for this assessment are based on measured

sediment and stream discharge. Therefore, a stream flow dataset composed of values

ranging from base flow to flood is desirable. Observed stream flow conditions are shown

in table 1.

Sediment loads in streams are composed of relatively small particles suspended in

the water column (suspended solids) and larger particles that move on or periodically

near the streambed (bed load). A pre-monitoring assessment of sediment characteristics

indicated that due to low elevation and topographic relief and extensive wetlands,

relatively little bed sediment was present in the streams at selected Fowl River

monitoring sites. Therefore, total sediment loads for all monitored sites were assumed to

be suspended.

SEDIMENT LOADS TRANSPORTED BY PROJECT STREAMS

The rate of transport of sediment is a complex process controlled by a number of

factors primarily related to land use, precipitation runoff, erosion, stream discharge and

flow velocity, stream base level, and physical properties of the transported sediment.

Deterrents to excessive erosion and sediment transport include wetlands, forests,

vegetative cover and field buffers for croplands, limitations on impervious surfaces, and a

number of constructed features to promote infiltration of precipitation and to store and

slow runoff. Currently, the Bayou La Batre watershed maintains a relatively healthy

hydrologic environment, characterized by a relatively rural setting, minimal row crop

agriculture, low topographic relief, abundant wetlands, anastomosing stream channels,

and forested flood plains. However, a number of anthropogenic impacts to stream flow

and water quality were identified in the Bayou La Batre watershed that require evaluation

and possible remediation (see Conclusions and Sources of Water-Quality Impacts section

of the report).

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SUSPENDED SEDIMENT

The basic concept of constituent loads in a river or stream is simple. However, the

mathematics of determining a constituent load may be quite complex. The constituent

load is the mass or weight of a constituent that passes a cross-section of a stream in a

specific amount of time. Loads are expressed in mass units (tons or kilograms) and are

measured for time intervals that are relative to the type of pollutant and the watershed

area for which the loads are calculated. Loads are calculated from concentrations of

constituents obtained from analyses of water samples and stream discharge, which is the

volume of water that passes a cross-section of the river in a specific amount of time.

Suspended sediment is defined as that portion of a water sample that is separated

from the water by filtering. This solid material may be composed of organic and

inorganic particles that include algae, industrial and municipal wastes, urban and

agricultural runoff, and eroded material from geologic formations. These materials are

transported to stream channels by overland flow related to storm-water runoff and cause

varying degrees of turbidity. Figure 8 shows that turbidity and suspended sediment are

closely related in Carls Creek (site BLB3), where water is primarily fresh. Turbidity,

TSS, suspended sediment loads, and discharge values for all monitoring sites are shown

in table 2.

0

50

100

150

200

250

0 50 100 150 200 250 300 350

TSS

(mg/

L)

Turbidity (NTU)

Figure 8.—Turbidity and TSS relationship for fresh-water samples from Carls

Creek site BLB3.

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Annual suspended sediment loads were estimated for Bayou La Batre monitored

streams using the computer regression model Regr_Cntr.xls (Regression with Centering)

(Richards, 1999). The program is an Excel adaptation of the U.S. Geological Survey

(USGS) seven-parameter regression model for load estimation in perennial streams

(Cohn and others, 1992). The regression with centering program requires total suspended

solids (TSS) concentrations and average daily stream discharge to estimate annual loads.

Although average daily discharge for project streams was not available from direct

measurement for the monitored sites, it was estimated by establishing a ratio between

periodic measured discharge in project streams and discharge values for the same times

obtained from USGS stream gaging site (02471078, Fowl River at Half Mile Road, near

Laurendine, Alabama). The USGS gaging site is 7.4 mi northeast of Bayou La Batre and

has similar hydrogeologic and hydrologic characteristics (Cook, 2014).

Concentrations of TSS in mg/L were determined by laboratory analysis of

periodic water grab samples. These results were used to estimate the mass of TSS for the

period of stream flow (July 2015 to July 2016). Site BLB1 (Bayou La Batre at Wintzell

Avenue), had a suspended sediment load of 22,277 tons per year (t/yr) (table 3). Site

BLB2 (unnamed tributary at Little River Road) and the combined load for sites BLB3

and BLB4 (Carls Creek at Arnette Street) had suspended sediment loads of 2,921 and

7,604 t/yr, respectively. Figure 9 shows estimated average annual daily discharge and

suspended sediment loads, which shows that generally, increased discharge results in

increased suspended sediment loads for Bayou La Batre monitored sites.

Table 3.—Measured discharge, turbidity, and TSS and estimated suspended sediment

loads in monitored streams in the Bayou La Batre watershed.

Monitored

site

Average

Discharge

(cfs)

Average

turbidity

(NTU)

Maximum

turbidity

(NTU)

Average

TSS

(mg/L)

Maximum

TSS

(mg/L)

Estimated

suspended

sediment load

(t/yr)

Estimated

normalized

suspended

sediment load

(t/mi2/yr)

1 1,131 26 58 16 31 22,277 960

2 162 20 35 12 17 2,921 622

3 131 47 122 28 100

4 160 21 42 9 26

3&4

combined 291 34 122 37 106 7,604 367

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For comparison with other watersheds in Mobile County, the largest suspended

sediment loads in the Dog River watershed were urban streams, Eslave Creek, Spencer

Branch, and Spring Creek with 10,803, 5,970, and 5,198 tons per year (t/yr), respectively

(Cook, 2012) and Fowl River watershed streams, Dykes Creek and Fowl River with

1,139 and 795 t/yr, respectively (Cook, 2014). Discharge and watershed area are two of

the primary factors that influence sediment transport rates in the Bayou La Batre

watershed.

Normalizing suspended loads to unit watershed area permits comparison of

monitored watersheds and negates the influence of drainage area size and discharge on

sediment loads. Normalized loads in the Bayou La Batre watershed are 960 t/mi2/yr for

Bayou La Batre site BLB1 (Bayou La Batre at Wintzell Avenue), 622 t/mi2/yr for site

BLB2 (unnamed tributary at Little River Road), and 367 t/mi2/yr for combined sites

BLB3 and BLB4 (Carls Creek at Arnette Street). These loads can be compared to the

largest normalized loads in Dog River streams, Spencer Branch, Spring Creek, and

Eslava Creek with 4,332 and 2,985, and 1,662 t/mi2/yr, respectively (Cook, 2012). The

0

100

200

300

400

500

600

700

0

5,000

10,000

15,000

20,000

25,000

BLB1 BLB2 BLB3-4

Dis

char

ge (

cfs)

Susp

end

ed s

edim

ent

(t/y

r)

Monitored site Suspended sediment Discharge

Figure 9.—Average annual daily discharge and suspended sediment loads for

Bayou La Batre monitored sites.

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largest normalized loads in Fowl River streams were, unnamed tributary at Half Mile

Road, Dykes Creek, and unnamed tributary at Bellingrath Road with normalized loads of

303 and 271, and 128 t/mi2/yr, respectively. When the contribution of Carls Creek is

removed, the suspended sediment load upstream from site BLB1 (Bayou La Batre at

Wintzell Avenue) is 14,673 t/yr (5,869 t/mi2/yr). This is a substantial sediment load and

normally indicates significant upstream sources of sediment. However, it is suspected

that a significant part of the suspended sediment is related to the tidal resuspension of

sediment discussed previously.

BED SEDIMENT

Transport of streambed material is controlled by a number of factors including

stream discharge and flow velocity, erosion and sediment supply, stream base level, and

physical properties of the streambed material. Most streambeds are in a state of constant

flux in order to maintain a stable base level elevation. The energy of flowing water in a

stream is constantly changing to supply the required power for erosion or deposition of

bed load to maintain equilibrium with the local water table and regional or global sea

level. Stream base level may be affected by regional or global events including

fluctuations of sea level or tectonic movement. Local factors affecting base level include

fluctuations in the water table elevation, changes in the supply of sediment to the stream

caused by changing precipitation rates, and/or land use practices that promote excessive

erosion in the floodplain or upland areas of the watershed.

Bed load sediment is composed of particles that are too large or too dense to be

carried in suspension by stream flow. These particles roll, tumble, or are periodically

suspended as they move downstream. Traditionally, bed load sediment has been difficult

to quantify due to deficiencies in monitoring methodology or inaccuracies of estimating

volumes of sediment being transported along the streambed. This is particularly true in

streams that flow at high velocity or in streams with excessive sediment loads.

Due to a number of factors including relatively small areas of development or

land disturbance, limited sources of coarse-grained sediment, relatively low stream

gradients and stream flow velocities, and extensive wetlands that slow stream flow

velocities and detain sediment, no bed sediment was observed in Bayou La Batre streams

except the man-made channel upstream from site BLB3, which was too small to measure.

Therefore, all sediment loads are assumed to be suspended.

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TOTAL SEDIMENT LOADS

Without human impact, erosion rates in the watershed, called the geologic erosion

rate, would be 64 t/mi2/yr (Maidment, 1993). Normalized sediment loads for all three

monitored watersheds were at least five times greater than the geologic erosion rate.

Calculated non-normalized geologic erosion rate loads are compared to total estimated

loads in figure 10.

Comparisons of sediment loads from other watersheds are helpful in determining

the severity of erosion problems in a watershed of interest. Estimates of total sediment

loads from Dog River site 2 (Spencer Branch at Cottage Hill Road in the city of Mobile)

(Cook, 2012), D’Olive Creek site 3 (D’Olive Creek at U.S. Highway 90 in Daphne)

(Cook, 2008), Tiawasee Creek site 7 (Tiawasee Creek upstream from Lake Forest)

(Cook, 2008), in Baldwin County, Joes Branch site 10 (at North Main Street in Daphne)

1,485

301

1,325

22,277

2,921

7,604

100

1,000

10,000

100,000

BLB1 BLB2 BLB3-4

Tota

l sed

imen

t lo

ad (

t/yr

)

Monitored site Geologic erosion rate load Estimated load

Figure 10.—Comparisons of total sediment geologic erosion rate loads with

estimated total sediment loads for monitored Bayou La Batre watersheds.

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(Cook, 2008), Magnolia River site 4 (at U.S. Highway 98) (Cook, 2009), and Bon Secour

River site 3 (County Road 12 in Foley) (Cook, 2013) are compared to Bayou La Batre

monitored sites in figure 11. GSA estimated sediment loads for more than 60 streams in

Alabama. Fowl River at Half Mile Road (site FR2), three miles northeast of the Bayou La

Batre watershed, is an excellent reference site for streams in south Mobile County. Fowl

River, upstream from site FR2 is characterized by geology, topography, soils, wetlands,

and land use is similar to other streams in the region. The estimated sediment load at site

FR2 was 53 t/mi2/yr (20 percent lower than the geologic erosion rate).

52

4,332

1,987

692

35,813

112

1,531

960622

367

10

100

1,000

10,000

100,000

Tota

l sedim

ent

(t/m

i2/y

r)

Monitored site name and number

Figure 11.—Comparison of total sediment loads for streams in Baldwin and Mobile

Counties.

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NUTRIENTS

Excessive nutrient enrichment is a major cause of water-quality impairment.

Excessive concentrations of nutrients, primarily nitrogen and phosphorus, in the aquatic

environment can lead to increased biological activity, increased algal growth, decreased

dissolved oxygen concentrations at times, and decreased numbers of species (Mays,

1996). Nutrient-impaired waters are characterized by numerous problems related to

growth of algae, other aquatic vegetation, and associated bacterial strains. Blooms of

algae and associated bacteria can cause taste and odor problems in drinking water and

decrease oxygen concentrations to eutrophic levels. Toxins also can be produced during

blooms of particular algal species. Nutrient-impaired water can dramatically increase

treatment costs required to meet drinking water standards. Nutrients discussed in this

report are nitrate (NO3-N) and phosphorus (P-total).

NITRATE

The U.S. Environmental Protection Agency (USEPA) Maximum Contaminant

Level (MCL) for nitrate in drinking water is 10 mg/L. Typical nitrate (NO3 as N)

concentrations in streams vary from 0.5 to 3.0 mg/L. Concentrations of nitrate in streams

without significant nonpoint sources of pollution vary from 0.1 to 0.5 mg/L. Streams fed

by shallow groundwater draining agricultural areas may approach 10 mg/L (Maidment,

1993). Nitrate concentrations in streams without significant nonpoint sources of pollution

generally do not exceed 0.5 mg/L (Maidment, 1993).

Water samples were collected from January through May 2016 at Bayou La Batre

monitoring sites for discharge events from base flow to bank full. Samples were analyzed

for nitrate. The critical nitrate concentration in surface water for excessive algae growth

is 0.5 mg/L (Maidment, 1993). All samples analyzed for nitrate at site BLB1 (Bayou La

Batre at Wintzell Avenue) were below detection limit of 0.3 mg/L. All samples analyzed

for nitrate from site BLB2 (unnamed tributary to Bayou La Batre at Little River Road)

were below detection limit or below the 0.5 mg/L nitrate criterion. Forty-three percent of

analytical results from samples collected at site BLB3 (man-made channel of Carls Creek

at Arnette Street) were below the detection limit, 43 percent were below the 0.5 mg/L

nitrate criterion, and 14 percent exceeded the 0.5 mg/L criterion. Analytical results for

samples collected at site BLB4 (natural channel of Carls Creek at Arnette Street) indicate

that 57 percent are below the detection limit and 29 percent are below the 0.5 mg/L

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nitrate criterion, and 14 percent exceeded the 0.5 mg/L criterion. Lower concentrations of

nitrate are common in most streams during high flows due to dilution, resulting in

negative regressions when nitrate is plotted with discharge. However, nitrate and

discharge are not well correlated for streams in the Bayou La Batre watershed. Extremely

small nitrate concentrations at sites BLB1 (Bayou La Batre at Wintzell Avenue) and

BLB2 (unnamed tributary to Bayou La Batre at Little River Road) are likely caused by

dilution of runoff from the urban area of Bayou La Batre. Nitrate is poorly correlated

with discharge at site BLB3 but is relatively well correlated with conductivity (fig. 12).

Nitrate/conductivity correlations were the subject of an investigation by Iowa State

University researchers (Gali and others, 2012). The Iowa State University researchers

showed that in fresh water, conductivity and nitrate form positive regression correlations

and in some cases, conductivity could be used as a surrogate for nitrate. Nitrate has a

much better correlation with discharge at site BLB4, forming an expected negative

regression (fig. 13). These relationships indicate that dilution is a primary control of

nitrate concentrations in fresh-water streams.

Although concentrations are relatively small throughout the monitoring period,

elevated concentrations of nitrate in Carls Creek are expected, due to row crop

agriculture, cattle, and residential development in the headwaters of Bishop Manor Creek

and Hammar Creek (tributaries to Carls Creek) (fig. 3).

PHOSPHORUS

Phosphorus in streams originates from the mineralization of phosphates from soil

and rocks or runoff and effluent containing fertilizer or other industrial products. The

principal components of the phosphorus cycle involve organic phosphorus and inorganic

phosphorus in the form of orthophosphate (PO4) (Maidment, 1993). Orthophosphate is

soluble and is the only biologically available form of phosphorus. Since phosphorus

strongly associates with solid particles and is a significant part of organic material,

sediments influence water column concentrations and are an important component of the

phosphorus cycle in streams.

The natural background concentration of total dissolved phosphorus is

approximately 0.025 mg/L. Phosphorus concentrations as low as 0.005 to 0.01 mg/L may

cause algae growth, but the critical level of phosphorus necessary for excessive algae is

around 0.05 mg/L (Maidment, 1993). Although no official water-quality criterion for

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phosphorus has been established in the United States, total phosphorus should not exceed

0.05 mg/L in any stream or 0.025 mg/L within a lake or reservoir in order to prevent the

development of biological nuisances (Maidment, 1993). In many streams phosphorus is

10

100

1000

0 0.1 0.2 0.3 0.4 0.5 0.6

Co

nd

uct

ance

an

d D

isch

arge

Nitrate (mg/L) Conductance Discharge

Figure 12.—Relationships of measured nitrate with measured conductance and

discharge at site BLB3 (Carls Creek man-made channel at Arnette Street).

0.000

0.100

0.200

0.300

0.400

0.500

0.600

0 25 50 75 100 125 150 175 200 225 250 275 300

Nit

rate

(m

g/L)

Discharge (cfs)

Figure 13.—Relationship of nitrate and discharge at site BLB4 (Carls Creek

natural channel at Arnette Street).

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the primary nutrient that influences excessive biological activity. These streams are

termed “phosphorus limited.” All samples analyzed for total phosphorus at site BLB1

(Bayou La Batre at Wintzell Avenue) were below detection limit of 0.05 mg/L. All

samples but one analyzed for total phosphorus from site BLB2 (unnamed tributary to

Bayou La Batre at Little River Road) were below detection limit. One saline water

sample collected in April 2016 had a total phosphorus concentration of 0.063 mg/L. All

samples but one analyzed for total phosphorus from site BLB3 (man-made channel of

Carls Creek at Arnette Street) were below detection limit. The sample collected during

the largest discharge event for the monitoring period had a total phosphorus concentration

of 0.398, which exceeded the 0.05 mg/L criterion. All samples analyzed for total

phosphorus at site BLB4 (natural channel of Carls Creek at Arnette Street) were below

detection limit of 0.05 mg/L.

DISSOLVED OXYGEN

Dissolved oxygen (DO) concentration is an essential constituent that affects the

biological health and the chemical composition of surface waters. Biological processes,

oxidation, and sediment loads all contribute to depletion of DO in surface water. The

ADEM standard for DO in surface water classified as Fish and Wildlife is 5.0 mg/L

except under extreme conditions when it may be as low as 4.0 mg/L. The effects of an

impoundment on DO in the impounded waters and in the downstream release from the

impoundment must be carefully considered in the planning and design stage of a

reservoir project. The equilibrium concentration of DO in water that is in contact with air

is primarily related to water temperature and barometric pressure and secondarily related

to concentrations of other solutes (Hem, 1985). Equilibrium DO in water at 10° C and

25° C is 11.27 mg/L and 8.24 mg/L, respectively. DO concentrations in the project

watersheds are significantly affected by water temperature, stream discharge,

concentrations of organic material in the water, and oxygen-consuming pollutants. These

factors are represented in table 4 where observed DO is compared to the 100 percent

dissolved oxygen saturation for the observed stream temperature for each of the

monitoring periods. Additional DO measurements were made on August 3, 2016 in Carls

Creek tributaries, dominated by wetlands and anastomosing stream channels. Hammar

Creek at 3 Mile Road and Bishop Manor Creek at Argyle Road had DO concentrations of

4.7 and 5.2 mg/L, respectively.

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Table 4.—Dissolved oxygen measured in monitored streams in the

Bayou La Batre watershed.

Site Dissolved oxygen (mg/L) Average DO saturation

(% atmospheric saturation) Maximum Minimum Average

BLB1 8.3 6.9 7.5 84

BLB2 8.2 6.4 7.3 83

BLB3 9.8 6.4 7.4 80

BLB4 8.3 7.1 7.6 84

CONCLUSIONS AND SOURCES OF WATER-QUALITY IMPACTS

Evaluations of sediment loads, water-quality analyses, land-use data, and aerial

imagery led to conclusions of probable sources of water quality and habitat impairments

in the Bayou La Batre watershed. Stream flow conditions are an important factor that

influences erosion, sediment transport, and attenuation of nutrients and other

contaminants that impact water quality in a watershed. Streams in the Bayou La Batre

watershed are characterized by relatively low gradients, anastomosing channels, forested

flood plains, extensive wetlands, and tidal impacts in the downstream part of the

watershed. The topography of the watershed can be divided into two zones; an upland

headwaters zone and a downstream coastal zone. The upland headwaters zone has

elevations of about 140 ft MSL, 80 ft of relief, and three percent slopes. The average

stream gradient in the upland zone is about 20 ft/mi. The downstream coastal zone part of

the watershed is in the Alabama Coastal Zone and is characterized by extensive wetlands

and marsh, maximum elevation of 25 ft MSL, and an average stream gradient of 7 ft/mi.

Carls Creek splits into two channels just south of Padgett Switch Road (fig. 14).

Site BLB3 is on the man-made relief channel of Carls Creek at Arnette Street. This site

had the highest average turbidity (47 NTUs) and the highest turbidity to discharge ratio

(0.4 NTU/cfs).

Site BLB1 (Bayou La Batre at Wintzell Avenue), had a suspended sediment load

of 22,277 tons per year (t/yr). Site BLB2 (unnamed tributary at Little River Road) and the

combined load for sites BLB3 and BLB4 (Carls Creek at Arnette Street) had suspended

sediment loads of 2,921 and 7,604 t/yr, respectively. Sediment loads normalized to unit

drainage area in the Bayou La Batre watershed are 960 t/mi2/yr for Bayou La Batre site

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BLB1, 622 t/mi2/yr for site BLB2, and 367 t/mi2/yr for combined sites BLB3 and BLB4.

When the Carls Creek load is subtracted from the load at Bayou La Batre site

BLB1, the remaining load for Bayou La Batre upstream from site BLB1 is 14,673 t/yr

(5,869 t/mi2/yr). Field reconnaissance and research review led to the conclusion that this

surprisingly large suspended sediment load results from three primary sources. The first,

as discussed previously, are estuary streams with tidal influence that have constantly

elevated turbidity and suspended sediment due to movement of water upstream and

downstream in response to tidal cyclicity that mobilizes fine-grained sediment that settled

out in the low gradient estuary zone. Secondly, part of the town of Bayou La Batre storm

water runoff enters Bayou La Batre immediately upstream from the BLB1 site. The third

Figure 14.—Carls Creek channel bifurcation just south of Padgett Switch Road.

Natural channel

Man-made channel

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source is from three upstream, unnamed tributaries to Bayou La Batre that have relatively

severe bank erosion (fig. 15).

Comparisons of sediment transport rates and water-quality data in watersheds in

Baldwin and Mobile Counties indicate that streams in the Bayou La Batre watershed

have moderate-sized sediment loads and generally good water quality. This is attributed

to the relatively rural setting, extensive wetlands and forests, and use of winter cover

crops on agricultural fields. However, water quality and habitats could be improved and

protected for the future by employing best management practices that prevent destruction

of wetlands, prevent erosion and sediment transport from areas of timber harvesting and

row crop agriculture, and control runoff from urban areas including construction sites and

areas with significant bare and impervious surfaces. Sources of sediment in the Bayou La

Batre watershed include runoff from headwaters row crop agriculture, sand mining

operations, and runoff from urban areas in the town of Bayou La Batre (fig. 15).

Observations recorded during monitoring included at least seven fields used for row crop

agriculture in the headwaters of Bishop Manor and Hammar Creeks have streams or

drainage ditches running through them with no vegetative buffer or sediment detention

(Google Earth, 2016) (fig. 15). One of these streams (unnamed tributary to Hammar

Creek at Tom Waller Road, site BLB8), had the highest turbidity (375 NTU) recorded

during during a storm event in early August 2016 (figs. 15, 16). Other potential sediment

sources are two sand mining operations (fig. 15).

Water samples collected from January through May 2016 at Bayou La Batre

monitoring sites were analyzed for nitrate. The critical nitrate concentration in surface

water for excessive algae growth is 0.5 mg/L. All samples analyzed for nitrate at site

BLB1 (Bayou La Batre at Wintzell Avenue) were below detection limit of 0.3 mg/L. All

samples analyzed for nitrate from site BLB2 (unnamed tributary to Bayou La Batre at

Little River Road) were below detection limit or below the 0.5 mg/L nitrate criterion.

Forty-three percent of analytical results from samples collected at site BLB3 (man-made

channel of Carls Creek at Arnette Street) were below the detection limit, 43 percent were

below the 0.5 mg/L nitrate criterion, and 14 percent exceeded the 0.5 mg/L criterion.

Analytical results for samples collected at site BLB4 (natural channel of Carls Creek at

Arnette Street) indicate that 57 percent are below the detection limit and 29 percent are

below the 0.5 mg/L nitrate criterion, and 14 percent exceeded the 0.5 mg/L criterion.

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Sand mining

Sand mining

Field

drainage

with no

vegetative

buffer

BLB6 BLB5

BLB3 BLB4

BLB2

BLB1

Stream bank erosion

Bayou La Batre

Figure 15.—Sources of water quality impacts identified by field observations.

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Water samples collected at Bayou La Batre monitoring sites were also analyzed

for total phosphorus. All samples collected at site BLB1 (Bayou La Batre at Wintzell

Avenue) were below detection limit of 0.05 mg/L. All samples but one analyzed for total

phosphorus from site BLB2 (unnamed tributary to Bayou La Batre at Little River Road)

were below detection limit. One saline water sample collected in April 2016 had a total

phosphorus concentration of 0.063 mg/L. All samples but one analyzed for total

phosphorus from site BLB3 (man-made channel of Carls Creek at Arnette Street) were

below detection limit. The sample collected during the largest discharge event for the

monitoring period had a total phosphorus concentration of 0.398, which exceeded the

0.05 mg/L criterion. All samples analyzed for total phosphorus at site BLB4 (natural

channel of Carls Creek at Arnette Street) were below detection limit of 0.05 mg/L.

Figure 16.—Turbid runoff from row-crop fields in unnamed tributary to Hammar Creek at Tom

Waller Road immediately after a rain event.

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This assessment indicates that the water quality in the Bayou La Batre watershed

is relatively good, due primarily to the rural character of the watershed and land cover

dominated by forest and wetlands. However, sediment loads are significantly larger than

the geologic erosion rate. Therefore, steps should be taken to correct current impairments

and to protect the watershed from future negative impacts that are common in streams in

Alabama’s coastal region, including urban expansion, timber cutting, poorly maintained

agricultural fields, and conversion of agricultural and forest land to residential

development. One of the primary targets of watershed protection should be preservation

of wetlands and marsh in the Bayou La Batre watershed.

REFERENCES CITED

Cohn, T. A., Caulder D. L., Gilroy E. J., Zynjuk L. D., and Summers, R. M., 1992, The

validity of a simple statistical model for estimating fluvial constituent loads: an

empirical study involving nutrient loads entering Chesapeake Bay: Water

Resources Research, v. 28, p. 2353-2363.

Cook, M. R., and Moss, N. E., 2008, Analysis of water quality, sediment loading,

biological resources, and impacts of land-use change on the D’Olive and

Tiawasee Creek watersheds, Baldwin County, Alabama, 2008: Geological Survey

of Alabama Open-file Report 0811, 140 p.

Cook, M. R., and Moss, N. E., 2012, Analysis of discharge and sediment loading rates in

tributaries of Dog River in the Mobile metropolitan area: Geological Survey of

Alabama Open-file Report 1214, 24 p.

Cook, M. R., Moss, N. E., and Murgulet, Dorina, 2009, Analysis of sediment loading for

the Magnolia River watershed, Baldwin County, Alabama, 2009: Geological

Survey of Alabama Open-file Report 0914, 22 p.

Cook, M. R., and Moss, N. E., Rogers, A. L., Mac McKinney, 2014, Analysis of

sediment loading and water quality for the Bon Secour River watershed, Baldwin

County, Alabama: Geological Survey of Alabama Open-file Report 1409, 34 p.

Eaton, A. D., Clesceri, L. S., and Greenberg, A. E., 1995, Standard methods for the

examination of water and wastewater, 19th edition: Washington, D. C., American

Public Health Association, p. 9-53—9-72.

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Fondriest Environmental, Inc., 2014, “Turbidity, Total Suspended Solids and Water

Clarity.” Fundamentals of Environmental Measurements. 13 Jun. 2014. Web. <

http://www.fondriest.com/environmental-measurements/parameters/water-

quality/turbidity-total-suspended-solids-water-clarity/ >.

Gali, Rohinth K.; Soupir, Michelle L.; and Helmers, Matthew J., "Electrical Conductivity

as a tool to estimate chemical properties of drainage water quality in the Des

Moines Lobe, Iowa" (2012).Agricultural and Biosystems Engineering Conference

Proceedings and Presentations. Paper 209.

http://lib.dr.iastate.edu/abe_eng_conf/209

Google Earth, 2016, Image of Bayou La Batre watershed, Image date, 1/30/15.

Maidment, D. R., ed., 1993, Handbook of hydrology: New York, Mcgraw-Hill Inc., p.

11.37-11.54.

Mays, L. W., ed., 1996, Water resources handbook: New York, McGraw-Hill, p. 8.3-8.49.

Richards, R. P., 1999, Estimation of pollutant loads in rivers and streams: a guidance

document for NPS programs: Heidelberg College.

U.S. Geological Survey, 2016, StreamStats watershed mapping and statistics, south

Mobile County, Alabama, URL http:// http://water.usgs.gov/osw/streamstats/

accessed July 28, 2016.

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APPENDIX A

FIELD AND ANALYTICAL DATA

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Bayou La Batre at North Wintzel Avenue Drainage area=23.2 square miles

Site Date Time Discharge Temp Conductance Turbidity pH DO Salinity TSS Nitrate Total Phosphorus

cfs °C mS/cm NTU mg/L mg/L mg/L mg/L

BLB1 01/13/16 9:05 439 22,100 8 6.4 13.2 10.4 <0.3 <.05

BLB1 01/21/16 22:40 668 16,700 15 6.0 10 22.0 <0.3 <.05

BLB1 02/15/16 20:45 1,031 15.1 20,800 21 7.3 8.3 12.4 12.0 <0.3 <.05

BLB1 03/11/16 14:10 1,937 19.7 2,650 58 6.9 7.1 1.4 31.2 <0.3 <.05

BLB1 03/28/16 11:15 1,362 21.0 101 25 5.9 7.5 0 6.0 <0.3 <.05

BLB1 04/01/16 14:45 1,473 21.2 709 44 6.5 6.9 0.3 13.6 <0.3 <.05

BLB1 05/31/16 18:10 1,008 28.1 20,100 14 6.9 7.8 12.0 14.0 <0.3 <.05

Unnamed Tributary to Bayou La Batre at Little River Road Drainage area=4.7 square miles Site Date Time Discharge Temp Conductance Turbidity pH DO Salinity TSS Nitrate Total

Phosphorus

cfs °C mS/cm NTU mg/L mg/L mg/L mg/L

BLB2 01/13/16 8:45 130 18,300 8 6.0 11 10.0 <.3 <.05

BLB2 01/21/16 22:55 198 11,000 16 6.0 6.6 13.6 0.424 <.05

BLB2 02/15/16 21:00 230 15.1 21,700 35 7.0 8.2 13.0 16.8 <.3 <.05

BLB2 03/11/16 14:25 189 19.2 79 30 5.3 7.4 0.0 11.6 <.3 <.05

BLB2 03/28/16 11:30 110 20.9 42 13 4.6 7.5 0.0 7.0 <.3 <.05

BLB2 04/01/16 14:55 150 20.8 52 22 5.5 6.4 0.0 8.4 <.3 <.05

BLB2 05/31/16 18:30 129 29.1 18,700 16 6.7 7.0 11.1 15.2 <.3 0.063

Carls Creek at Arnette Street (man-made channel) Drainage area=17.8

Site Date Time Discharge Temp Conductance Turbidity pH DO Salinity TSS Nitrate Total Phosphorus

cfs °C mS/cm NTU mg/L mg/L mg/L mg/L

BLB3 01/13/16 8:20 10.3 111 16 5.5 0.07 2 0.399 <.05

BLB3 01/21/16 23:10 444 243 122 6.8 0.1 100.0 0.327 0.398

BLB3 02/15/16 21:15 115 14.9 498 44 6.4 7.4 0.2 18.8 0.559 <.05

BLB3 03/11/16 14:30 180 19.3 39 67 6.4 7.1 0 46.0 <.3 <.05

BLB3 03/28/16 11:40 35 21.0 45 21 6.0 9.8 0 6.0 <.3 <.05

BLB3 04/01/16 15:05 114 20.8 45 48 6.3 6.5 0 18.8 <.3 <.05

BLB3 05/31/16 18:45 17 25.6 630 10 4.3 6.4 0.2 2.0 0.315 <.05

Unnamed Tributary to Bayou La Batre at Arnette Street (natural channel) Drainage area=2.9 square miles Site Date Time Discharge Temp Conductance Turbidity pH DO Salinity TSS Nitrate Total

Phosphorus

cfs °C mS/cm NTU mg/L mg/L mg/L mg/L

BLB4 01/13/16 8:30 17 112 6 5.6 0.07 2 0.356 <.05

BLB4 01/21/16 23:20 281 1,690 10 5.6 1 6.4 <.3 <.05

BLB4 02/15/16 21:20 75 14.7 110 20 6.4 7.5 0.1 5.6 0.558 <.05

BLB4 03/11/16 14:35 270 19.2 37 42 6.1 7.3 0 26.4 <.3 <.05

BLB4 03/28/16 11:50 205 20.9 42 32 6.3 7.6 0 8.4 <.3 <.05

BLB4 04/01/16 15:15 230 20.9 45 35 6.4 7.1 0 10.8 <.3 <.05

BLB4 05/31/16 18:55 39 25.2 680 5 4.6 8.3 0.3 2.0 0.308 <.05

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BLB 5 Hammar Creek at 3 mile road

Site Date Time Discharge Temp Conductance Turbidity pH DO Salinity TSS Nitrate Total Phosphorus

cfs °C mS/cm NTU mg/L mg/L mg/L mg/L

BLB5 8/3/2016 1630 55 25.1 79 44 5.6 4.7 0 24.0 0.509 <.05

Bishop Manor Creek at Argyle Road

Site Date Time Discharge Temp Conductance Turbidity pH DO Salinity TSS Nitrate Total Phosphorus

cfs °C mS/cm NTU mg/L mg/L mg/L mg/L

BLB6 8/3/2016 1650 28 25.2 46 114 6.0 5.2 0 50.0 <.3 0.116

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GEOLOGICAL SURVEY OF ALABAMA 420 Hackberry Lane

P.O. Box 869999 Tuscaloosa, Alabama 35486-6999

205/349-2852

Berry H. (Nick) Tew, Jr., State Geologist

A list of the printed publications by the Geological Survey of Alabama can be obtained from the Publications Office (205/247-3636) or

through our web site at http://www.gsa.state.al.us.

E-mail: [email protected]

The Geological Survey of Alabama (GSA) makes every effort to collect, provide, and maintain accurate and complete information. However, data acquisition and research are ongoing activities of GSA, and interpretations may be revised as new data are acquired. Therefore, all information made available to the public by GSA should be viewed in that context. Neither the GSA nor any employee thereof makes any warranty, expressed or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed in this report. Conclusions drawn or actions taken on the basis of these data and information are the sole responsibility of the user.

As a recipient of Federal financial assistance from the U.S. Department of the Interior, the GSA prohibits discrimination on the basis of race, color, national origin, age, or disability in its programs or activities. Discrimination on the basis of sex is prohibited in federally assisted GSA education programs. If anyone believes that he or she has been discriminated against in any of the GSA’s programs or activities, including its employment practices, the individual may contact the U.S. Geological Survey, U.S. Department of the Interior, Washington, D.C. 20240.

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