Preliminary Results...0.078-0.100 mg/kg 0.100-0.500 mg/kg > 0.500 mg/kg EUPT-FV16 Preliminary...

EUPT-FV16 Preliminary Results

11th September 2014

Preliminary Results

EUPT-FV16 Preliminary Results 11th September 2014

DG SANCO

Mrs. Almut Bitterhof

ORGANISING GROUP

Dr. Amadeo R. Fernández-Alba

Dr. Milagros MezcuaMr. Octavio Malato

Mrs. Carmen Ferrer

QUALITY CONTROL GROUP

Dr. Antonio Valverde

Mr. Stewart Reynolds

STATISTICAL GROUP

Dr. Carmelo Rodríguez

ADVISORY GROUP

Dr. Michelangelo Anastassiades

Mr. Richard Fussell

Dr. Miguel Gamón

Dr. Magnus Jezussek

Dr. André de Kok

Mr. Ralf Lippold

Dr. Sonja MasselterDr. Tuija Pihlström Dr. Mette Erecius Poulsen

Dr. Darinka Stajnbaher

EUPT-Panel

Mrs. Veerle Vanheusden


11th September 2014

Participation


Total No. of Labs = 183

EU/EFTA Labs = 169

Other countries Labs = 14

Participation

(28 EU + 3 EFTA + 3 Candidate countries + 9 other countries)

Total No. of Countries = 43

EU/EFTA countries = 31

Other countries = 12


11th September 2014

Country No. of Labs Country No. of Labs Country No. of Labs

Austria 2 Hungary 4 Serbia 1

Belgium 3 Iceland 1 Singapore 1

Brazil 2 Ireland 1 Slovakia 2

Bulgaria 2 Israel 1 Slovenia 3

China 2 Italy 23 Spain 32

Croatia 7 Kenya 1 Sweden 2

Cyprus 1 Latvia 1 Switzerland 3

Czech Republic 3 Lithuania 1 Thailand 1

Denmark 2 Luxembourg 1 The Netherlands 4

Egypt 1 Norway 1 Turkey 1

Estonia 2 Peru 1 United Kingdom 4

Finland 2 Poland 10 Uruguay 1

France 8 Portugal 2 Total No. of Labs = 183

Total No. of Non-EU countries Labs = 14

Total No. of Countries = 43

EU countries, EFTA countries, 3rd countries

Germany 28 Romania 4

Greece 10 Saudi Arabia 1


11th September 2014

3-hydroxy-carbofuran

Acephate

Acetamiprid

Acrinathrin

Aldicarb

Aldicarb Sulfone

Aldicarb Sulfoxide

Amitraz

Azinphos-methyl

Azoxystrobin

Benfuracarb

Bifenthrin

Bitertanol

Boscalid

Bromopropylate

Bromuconazole

Bupirimate

Buprofezin

Cadusafos*

Captan

Carbaryl

Carbendazim

Carbofuran

Carbosulfan

Chlorfenapyr

Chlorfenvinphos

Chlorobenzilate*

Chlorothalonil

Chlorpropham

Chlorpyrifos

Chlorpyrifos-methyl

Clofentezine

Clothianidin

Cyfluthrin

Cypermethrin

Cyproconazole

Cyprodinil

Deltamethrin

Demeton-S-methylsulfone

Desmethyl-pirimicarb

Diazinon

Dichlofluanid

Dichlorvos

Dicloran

Dicofol

Difenoconazole

Diflubenzuron

Dimethoate

Dimethomorph

DMST

Diphenylamine

DMF

DMPF

Endosulfan alpha

Endosulfan beta

Endosulfan sulfate

EPN

Epoxiconazole

Ethion

Ethoprophos

Etofenprox

Fenamiphos

Fenamiphos sulfone

Fenamiphos sulfoxide

Fenarimol

Fenazaquin

Fenbuconazole

Fenhexamid

Fenitrothion

Fenoxycarb

Fenpropathrin

Fenpropimorph

Fenthion

Fenthion oxon

Fenthion oxon sulfone

Fenthion oxon sulfoxide

Fenthion sulfone

Fenthion sulfoxide

Fipronil

Fludioxonil

Flufenoxuron

Fluopicolide*

Fluquinconazole

Flusilazole

Flutolanil*

Flutriafol

Folpet

Fosthiazate

Hexaconazole

Hexythiazox

Imazalil

Imidacloprid

Indoxacarb

Iprodione

Iprovalicarb

Isofenphos-methyl

Kresoxim-methyl

Lambda-Cyhalothrin

Linuron

Lufenuron

Malaoxon

Malathion

Mepanipyrim

Metaflumizone*

Metalaxyl and metalaxyl-M

Metconazole

Methamidophos

Methidathion

Methiocarb

Methiocarb sulfone

Methiocarb sulfoxide

Methomyl

Methoxyfenozide

Monocrotophos

Myclobutanil

Omethoate

Orthophenylphenol

Oxadixyl

Oxamyl

Oxydemeton-methyl

Paclobutrazole

Paraoxon-methyl

Parathion-ethyl

Parathion-methyl

Penconazole

Pencycuron

Pendimethalin

Phenthoate

Phosalone

Phosmet

Phosmet oxon

Phoxim

Pirimicarb

Pirimiphos-methyl

Prochloraz

Procymidone

Profenofos

Propargite

Propiconazole

Propyzamide

Prothioconazole

Prothiofos

Pyraclostrobin

Pyridaben

Pyrimethanil

Pyriproxyfen

QuinoxyfenSpinosad

Spirodiclofen

Spiroxamine

Tau-Fluvalinate

Tebuconazole

Tebufenozide

Tebufenpyrad

Teflubenzuron

Tefluthrin

Tetraconazole

Tetradifon

Thiabendazole

Thiacloprid

Thiamethoxam

Thiodicarb

Tolclofos-methyl

Tolylfluanid

Triadimefon

Triadimenol

Triazophos

Trichlorfon

Trifloxystrobin

Triflumuron

Trifluralin

Triticonazole

Vinclozolin

Zoxamide

Thiophanate-me

175 pesticides

*Not in the coordinated

multiannual control programme

Pesticides Target List


11th September 2014

Pesticides used for thetreatment

Acetamiprid Endosulfan beta

Acrinathrin Fenamiphos

Buprofezin Fenhexamid

Captan Fludioxonil

Chlorothalonil Lambda-Cyhalothrin

Chlorpyrifos Methoxyfenozide

Cypermethrin Pirimicarb

Cyprodinil Pyridaben

Diazinon Spinosad

Difenoconazole Tetraconazole

Endosulfan alpha Total: 21

ALL INCLUDED IN MACP

COMMISSION IMPLEMENTING REGULATION (EU)

No 788/2012 of 31 August 2012

concerning a coordinated multiannual control

programme of the Union for 2013, 2014 and 2015 to

ensure compliance with maximum residue levels of

pesticides and to assess the consumer exposure

to pesticide residues in and on food of plant and

animal origin .


CALENDAR

ACTIVITY DATE

- Publishing the Target Pesticide List, Calendar and Matrix on the Web page.

15th November 2013

- Receiving Application Form from invited laboratories. 23rd Dec 2013 – 31st Jan 2014

- Specific Protocol published on the Web site. 3rd Feb 2014 at the latest

- Deadline for receiving Laboratory scope: Form 0 3rd-14th February 2014

- Sample distribution. 24th February 2014

- Deadline for receiving sample acceptance: Form 1 28th February 2014

- Deadline for receiving results: Forms 2, 3 and 4 17th March 2014

- Filling in Form 5 24th-28th March 2014

- Preliminary Report: only results, no statistical treatment. End of April 2014

- Final Report distributed to the Laboratories. November 2014


Pepper


Organic peppers were grown in the EURL-FV greenhouse in

Almería, Spain.



Before harvest, the peppers were

treated with commercial formulations


Pesticide Type Commercial Product

Acetamiprid Commercial Formulation Epik 20SG (20%)

Acrinathrin Commercial Formulation Jokari (7.5%)

Buprofezin Commercial Formulation Geiser (25%)

Captan Commercial Formulation Merpan 50 (50%)

Chlorothalonil Commercial Formulation Daconil 50 SC (50%)

Chlorpyrifos Commercial Formulation Clorifos 48 EC (48%)

Cypermethrin Commercial Formulation Citron (10%)

Cyprodinil + Fludioxonil Commercial Formulation Switch (37.5%+25%)

Diazinon Commercial Formulation Fegazinogole (60%)

Difenoconazole Commercial Formulation Core (25%)

Endosulfan α y ß Commercial Formulation Sulfanex 35 EC (35%)

Fenamiphos Commercial Formulation Nemacur 40LE (40%)

Fenhexamid Commercial Formulation Teldor (50%)

Lambda Cyhalothrin Commercial Formulation Karate Zeon (1.5%)

Methoxyfenozide Commercial Formulation Runner (24%)

Pirimicarb Commercial Formulation Aphox (50%)

Pyridaben Commercial Formulation Sanmmite 20% (20%)

Spinosad Commercial Formulation Spintor 480 SC (48%)

Tetraconazole Commercial Formulation Eminent (10%)

Commercial products used to treat the sample


Preparation of the test item


- The homogeneity in the treated sample was studied using

the 2006 Harmonised Protocol.

-The sampling standard deviation of all the pesticides must be

lower than the critical value.

Ssample2 < c

Homogeneity

20 extracts

All the pesticides passed the homogeneity test


Stability

1st Analysis - prior to the sample shipment

2nd Analysis - after the deadline for reporting results

All the pesticides passed the stability test


Stability

Additionally:

3rd Analysis - reproducing the delivery conditions that the samples experienced during 48 hours


11th September 2014

Preliminary Results


Acetamiprid Endosulfan beta Acrinathrin Fenamiphos

Buprofezin Fenhexamid Captan Fludioxonil

Chlorothalonil Lambda-Cyhalothrin Chlorpyrifos

Methoxyfenozide Cypermethrin Pirimicarb Cyprodinil

Pyridaben Diazinon Spinosad Difenoconazole

Tetraconazole Endosulfan alpha

• Tebuconazole

• Pirimicarb-desmethyl

• Endosulfan sulfate

• Fenamiphos sulfone and Fenamiphos sulfoxide

• Propiconazole

http://articles.clarkedesign.co.uk/wp-content/uploads/2011/04/Search-Magnifying-Glass.jpg

http://articles.clarkedesign.co.uk/wp-content/uploads/2011/04/Search-Magnifying-Glass.jpg

http://www.google.es/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&uact=8&docid=BwZNUjGzGTdj0M&tbnid=AwarXTkCtuomsM:&ved=0CAUQjRw&url=http://www.jphotostyle.com/html/gallery01/green-pepper02.html&ei=ywJHU4z_H8i90QWP3YG4Ag&bvm=bv.64507335,d.d2k&psig=AFQjCNFrcB9Fn0dN2EQgnuLzMDND_iFvaA&ust=1397249024549128













Pesticides Robust mean (mg/kg)

Lambda-Cyhalothrin 0,078

Diazinon 0,084

Spinosad 0,098

Tetraconazole 0,105

Fenamiphos sulfone 0,109

Captan 0,132

Pyridaben 0,149

Methoxyfenozide 0,170

Fludioxonil 0,245

Acrinathrin 0,263

Buprofezin 0,469

Cypermethrin 0,528

Cyprodinil 0,588

Acetamiprid 0,636

Pirimicarb 0,730

Fenhexamid 0,855

Difenoconazole 0,945

Endosulfan beta 0,964

Endosulfan alpha 1,149

Chlorothalonil 2,179

Chlorpyrifos 3,667

Fenamiphos sulfoxide 6,625

Fenamiphos 7,297


Endosulfan sulfate 0,011

Propiconazole 0,011

Tebuconazole 0,020

Desmethyl-pirimicarb 0,027



Endosulfan sulfate 0,011

Propiconazole 0,011

Tebuconazole 0,020

Desmethyl-pirimicarb 0,027

0.011-0.027 mg/kg




Diazinon 0,084

Spinosad 0,098

Tetraconazole 0,105


Captan 0,132

Pyridaben 0,149


Fludioxonil 0,245

Acrinathrin 0,263

Buprofezin 0,469

Cypermethrin 0,528

Cyprodinil 0,588

Acetamiprid 0,636

Pirimicarb 0,730

Fenhexamid 0,855





Chlorpyrifos 3,667


Fenamiphos 7,297

0.078-0.100 mg/kg




Diazinon 0,084

Spinosad 0,098

Tetraconazole 0,105


Captan 0,132

Pyridaben 0,149


Fludioxonil 0,245

Acrinathrin 0,263

Buprofezin 0,469

Cypermethrin 0,528

Cyprodinil 0,588

Acetamiprid 0,636

Pirimicarb 0,730

Fenhexamid 0,855





Chlorpyrifos 3,667


Fenamiphos 7,297

0.078-0.100 mg/kg

0.100-0.500 mg/kg




Diazinon 0,084

Spinosad 0,098

Tetraconazole 0,105


Captan 0,132

Pyridaben 0,149


Fludioxonil 0,245

Acrinathrin 0,263

Buprofezin 0,469

Cypermethrin 0,528

Cyprodinil 0,588

Acetamiprid 0,636

Pirimicarb 0,730

Fenhexamid 0,855





Chlorpyrifos 3,667


Fenamiphos 7,297

0.078-0.100 mg/kg

0.100-0.500 mg/kg

> 0.500 mg/kg


Acetamiprid

mg/kg

Fre

qu

en

cy

0 0,2 0,4 0,6 0,8 1

0

10

20

30

40

Acrinathrin

mg/kg

Fre

qu

en

cy

0 0,2 0,4 0,6 0,8

0

10

20

30

40

Buprofezin

mg/kg

Fre

qu

en

cy

0 0,2 0,4 0,6 0,8 1

0

10

20

30

40

50

Chlorothalonil

mg/kg

Fre

qu

en

cy

-1 1 3 5 7 9 11

0

10

20

30

40

50

Mean: 0.636 mg/kg Mean: 0.263 mg/kg


Distribution of data-Histograms


Cypermethrin

mg/kg

Fre

qu

en

cy

0 0,5 1 1,5 2 2,5 3

0

20

40

60

80

Diazinon

mg/kg

Fre

qu

en

cy

0 0,1 0,2 0,3 0,4

0

20

40

60

80

Chlorpyrifos

mg/kg

Fre

qu

en

cy

0 2 4 6 8

0

10

20

30

40

Cyprodinil

mg/kg

Fre

qu

en

cy

0 0,2 0,4 0,6 0,8 1

0

10

20

30

40





Difenoconazole

mg/kg

Fre

qu

en

cy

0 0,4 0,8 1,2 1,6

0

5

10

15

20

25

30

Endosulfan alpha

mg/kg

Fre

qu

en

cy

-0,1 0,9 1,9 2,9 3,9

0

10

20

30

40

50

60

Endosulfan beta

mg/kg

Fre

qu

en

cy

-0,1 0,9 1,9 2,9 3,9

0

20

40

60

80

Fenamiphos

mg/kg

Fre

qu

en

cy

-1 3 7 11 15 19 23

0

10

20

30

40

50





Fenamiphos sulfone

mg/kg

Fre

qu

en

cy

0 0,1 0,2 0,3 0,4

0

10

20

30

40

50


mg/kg

Fre

qu

en

cy

-1 2 5 8 11 14 17

0

5

10

15

20

25

30

Fenhexamid

mg/kg

Fre

qu

en

cy

0 0,3 0,6 0,9 1,2 1,5

0

4

8

12

16

20

24

Fludioxinil

mg/kg

Fre

qu

en

cy

0 0,1 0,2 0,3 0,4 0,5

0

10

20

30

40





Lambda-cyhalothrin

mg/kg

Fre

qu

en

cy

0 0,04 0,08 0,12 0,16 0,2 0,24

0

10

20

30

40

50

Methoxyfenozide

mg/kg

Fre

qu

en

cy

0 0,1 0,2 0,3 0,4

0

4

8

12

16

20

Pirimicarb

mg/kg

Fre

qu

en

cy

0 0,3 0,6 0,9 1,2 1,5

0

10

20

30

40

Pyridaben

mg/kg

Fre

qu

en

cy

0,06 0,09 0,12 0,15 0,18 0,21 0,24

0

4

8

12

16

20





Spinosad (sum of spinosyn A and spinosyn D, expr. as spinosad)

mg/kg

Fre

qu

en

cy

0 0,1 0,2 0,3 0,4

0

10

20

30

40

50

Tetraconazol

mg/kg

Fre

qu

en

cy

0 0,1 0,2 0,3 0,4

0

10

20

30

40

50

60




Tebuconazole

mg/kg

Fre

qu

en

cy

0 0,01 0,02 0,03 0,04 0,05

0

10

20

30

40

Desmethyl-pirimicarb

mg/kg

Fre

qu

en

cy

0 0,03 0,06 0,09 0,12 0,15

0

10

20

30

40

50

Endosulfan sulfate

mg/kg

Fre

qu

en

cy

0 0,01 0,02 0,03 0,04

0

10

20

30

40

Propiconazole

mg/kg

Fre

qu

en

cy

0,008 0,01 0,012 0,014 0,016 0,018 0,02

0

5

10

15

20

25

30

Mean: 0.027 mg/kg


Distribution of data-Histograms (special cases)

Mean: 0.020 mg/kg


Distribution of data-Histograms (special cases)

Captan

mg/kg

Fre

qu

en

cy

-0,02 0,18 0,38 0,58 0,78

0

4

8

12

16

20

Mean: 0.132 mg/kg


129 laboratories analysed captan

Captan

54 detected captan 75 did not detect captan

40% GC-ECD

60% GC-MS or GC-MS/MS

30 % GC-ECD

70 % GC-MS or GC-MS/MS

?Captan + THPI expressed as captan

Captan expressed as captan

THPI expressed as captan


Pesticides MRRL (mg/kg) Robust mean (mg/kg) CV (%)

Acetamiprid 0.01 0,636 15,89

Acrinathrin 0.01 0,263 18,62

Buprofezin 0.01 0,469 13,61

Captan 0.01 0,132 120,09

Chlorothalonil 0.01 2,179 34,39

Chlorpyrifos 0.01 3,667 20,40

Cypermethrin 0.01 0,528 16,45

Cyprodinil 0.01 0,588 14,63

Desmethyl-pirimicarb 0.01 0,027 20,02

Diazinon 0.01 0,084 16,92

Difenoconazole 0.01 0,945 18,71

Endosulfan alpha 0.01 1,149 17,30

Endosulfan beta 0.01 0,964 18,42

Endosulfan sulfate 0.01 0,011 20,71

Fenamiphos 0.01 7,297 21,03

Fenamiphos sulfone 0.01 0,109 19,33

Fenamiphos sulfoxide 0.01 6,625 23,57

Fenhexamid 0.01 0,855 19,84

Fludioxonil 0.01 0,245 18,96

Lambda-Cyhalothrin 0.01 0,078 19,72

Methoxyfenozide 0.01 0,170 21,15

Pirimicarb 0.01 0,730 14,57

Propiconazole 0.01 0,011 14,27

Pyridaben 0.01 0,149 18,17

Spinosad 0.01 0,098 25,18

Tebuconazole 0.01 0,020 17,50

Tetraconazole 0.01 0,105 16,02


Dispersion of Results


Pesticides

No. of Reported

Results

No. of False Negative

Results

No. of Not Analysed

Results

Percentage of Reported Results

(out of 169)

Acetamiprid 129 1 39 76

Acrinathrin 136 5 28 80

Buprofezin 145 3 21 86

Chlorothalonil 139 8 22 82

Chlorpyrifos 167 0 2 99

Cypermethrin 154 1 14 91

Cyprodinil 152 1 16 90

Diazinon 164 1 4 97

Difenoconazole 142 0 27 84

Endosulfan alpha 160 2 7 95

Endosulfan beta 159 2 8 94

Fenamiphos 131 3 35 78

Fenamiphos sulfone 102 7 60 60

Fenamiphos sulfoxide 102 7 60 60

Fenhexamid 143 1 25 85

Fludioxonil 138 5 26 82

Lambda-Cyhalothrin 147 6 16 87

Methoxyfenozide 119 2 48 70

Pirimicarb 154 0 15 91

Pyridaben 138 1 30 82

Spinosad 115 1 53 68

Tetraconazole 139 1 29 82


11th September 2014

z-Scores


Acceptable Questionable Unacceptable

z-Scores classification

%


PesticidesRobust Mean

(mg/kg)% Acceptable

z-scores% Questionable

z-scores% Unacceptable

z-scores

Acetamiprid 0,636 98,5 0,8 0,8

Acrinathrin 0,263 89,4 5,0 5,7

Buprofezin 0,469 95,3 1,4 3,4

Chlorothalonil 2,179 83,0 7,5 9,5

Chlorpyrifos 3,667 91,6 6,6 1,8

Cypermethrin 0,528 96,1 2,6 1,3

Cyprodinil 0,588 98,0 1,3 0,7

Diazinon 0,084 96,4 1,2 2,4

Difenoconazole 0,945 96,5 3,5 0,0

Endosulfan alpha 1,149 90,7 3,7 5,6

Endosulfan beta 0,964 90,7 4,3 5,0

Fenamiphos 7,297 88,1 6,0 6,0

Fenamiphos sulfone 0,109 85,3 3,7 11,0

Fenamiphos sulfoxide 6,625 85,3 5,5 9,2

Fenhexamid 0,855 97,2 2,1 0,7

Fludioxonil 0,245 93,0 2,1 4,9

Lambda-Cyhalothrin 0,078 92,2 2,0 5,9

Methoxyfenozide 0,170 95,0 3,3 1,7

Pirimicarb 0,730 98,1 1,9 0,0

Pyridaben 0,149 97,1 2,2 0,7

Spinosad 0,098 86,2 5,2 8,6

Tetraconazole 0,105 95,0 1,4 3,6


Acetamiprid

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab098

Lab149

Lab018

Lab095

Lab006

Lab169

Lab069

Lab038

Lab073

Lab174

Lab020

Lab093

Lab134

Lab102

Lab119

Lab163

Lab116

Lab117

Lab123

Lab159

Lab051

Lab147

Lab042

Lab019

Lab157

Lab054

Lab167

Lab164

Lab012

Lab062

Lab160

Lab104

Lab033

Lab103

Lab133

Lab118

Lab145

Lab084

Lab101

Lab078

Lab008

Lab182

Lab007

Lab027

Lab128

Lab171

Lab002

Lab024

Lab053

Lab155

Lab050

Lab015

Lab082

Lab001

Lab059

Lab138

Lab165

Lab060

Lab146

Lab031

Lab072

Lab016

Lab009

Lab021

Lab066

Lab106

Lab136

Lab081

Lab047

Lab097

Lab121

Lab139

Lab029

Lab151

Lab056

Lab055

Lab144

Lab130

Lab076

Lab162

Lab068

Lab153

Lab077

Lab010

Lab011

Lab112

Lab110

Lab126

Lab067

Lab079

Lab065

Lab142

Lab183

Lab004

Lab111

Lab140

Lab173

Lab080

Lab105

Lab061

Lab120

Lab003

Lab114

Lab044

Lab063

Lab075

Lab083

Lab122

Lab141

Lab052

Lab178

Lab166

Lab181

Lab028

Lab057

Lab096

Lab030

Lab032

Lab087

Lab025

Lab046

Lab115

Lab017

Lab040

Lab179

Lab070

Lab049

Lab177

Lab013

Lab137

Lab090

Lab034

Lab100

Lab058

Lab099

Lab127

Lab107

Lab091

Lab085

Lab131

Lab041

Lab172

Lab089

Acetamiprid

0,636 mg/kg98,5 % Acceptable

0,8 % Questionable

0,8 % Unnacceptable

1 False negative


Acrinathrin

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab126

Lab139

Lab111

Lab030

Lab169

Lab102

Lab041

Lab065

Lab142

Lab143

Lab146

Lab148

Lab138

Lab154

Lab025

Lab125

Lab002

Lab117

Lab183

Lab105

Lab158

Lab058

Lab020

Lab073

Lab028

Lab178

Lab046

Lab128

Lab096

Lab103

Lab172

Lab042

Lab078

Lab054

Lab060

Lab053

Lab012

Lab051

Lab068

Lab168

Lab066

Lab110

Lab080

Lab122

Lab033

Lab153

Lab179

Lab130

Lab174

Lab015

Lab062

Lab031

Lab134

Lab057

Lab165

Lab136

Lab090

Lab100

Lab127

Lab115

Lab181

Lab044

Lab017

Lab149

Lab108

Lab010

Lab035

Lab162

Lab082

Lab077

Lab011

Lab081

Lab045

Lab069

Lab119

Lab056

Lab101

Lab113

Lab171

Lab018

Lab151

Lab095

Lab167

Lab072

Lab121

Lab097

Lab055

Lab120

Lab086

Lab089

Lab032

Lab123

Lab016

Lab098

Lab063

Lab067

Lab049

Lab129

Lab131

Lab006

Lab163

Lab052

Lab157

Lab161

Lab099

Lab013

Lab093

Lab064

Lab092

Lab008

Lab177

Lab145

Lab133

Lab061

Lab112

Lab084

Lab182

Lab050

Lab059

Lab075

Lab027

Lab009

Lab173

Lab034

Lab074

Lab114

Lab147

Lab085

Lab083

Lab040

Lab107

Lab003

Lab021

Lab106

Lab038

Lab166

Lab118

Lab164

Lab091

Lab140

Lab036

Lab076

Lab150

Lab019

Lab141

Lab160

Lab079

Lab007

Lab070

Lab104

Acrinathrin


5,0 % Questionable

5,7 % Unnacceptable

5 False negatives


Buprofezin

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab059

Lab083

Lab092

Lab170

Lab018

Lab157

Lab024

Lab062

Lab023

Lab102

Lab025

Lab174

Lab009

Lab066

Lab130

Lab131

Lab140

Lab164

Lab016

Lab006

Lab139

Lab169

Lab167

Lab064

Lab093

Lab168

Lab002

Lab104

Lab078

Lab116

Lab134

Lab146

Lab123

Lab014

Lab165

Lab048

Lab155

Lab076

Lab182

Lab128

Lab098

Lab141

Lab142

Lab008

Lab033

Lab081

Lab021

Lab084

Lab158

Lab166

Lab172

Lab072

Lab143

Lab178

Lab077

Lab090

Lab122

Lab163

Lab118

Lab151

Lab007

Lab038

Lab065

Lab111

Lab054

Lab015

Lab050

Lab161

Lab120

Lab138

Lab045

Lab105

Lab028

Lab159

Lab160

Lab171

Lab181

Lab073

Lab031

Lab129

Lab019

Lab097

Lab013

Lab088

Lab027

Lab040

Lab082

Lab060

Lab152

Lab029

Lab133

Lab055

Lab099

Lab101

Lab117

Lab119

Lab149

Lab177

Lab061

Lab095

Lab091

Lab049

Lab063

Lab173

Lab179

Lab126

Lab020

Lab068

Lab085

Lab043

Lab089

Lab107

Lab056

Lab086

Lab162

Lab001

Lab137

Lab053

Lab057

Lab147

Lab136

Lab079

Lab080

Lab042

Lab011

Lab034

Lab114

Lab047

Lab036

Lab110

Lab183

Lab145

Lab103

Lab003

Lab153

Lab017

Lab127

Lab069

Lab044

Lab112

Lab046

Lab109

Lab012

Lab032

Lab070

Lab115

Lab030

Lab100

Lab052

Lab051

Lab106

Lab121

Lab010

Lab075

Lab096

Lab150

Lab058

Lab041

Lab035

Lab148

Lab067

Buprofezin


1,4 % Questionable

3,4% Unnacceptable

3 False negatives


Chlorothalonil

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab028

Lab041

Lab073

Lab095

Lab121

Lab135

Lab146

Lab180

Lab157

Lab037

Lab159

Lab158

Lab098

Lab003

Lab102

Lab184

Lab007

Lab165

Lab124

Lab024

Lab174

Lab106

Lab166

Lab168

Lab138

Lab176

Lab042

Lab151

Lab066

Lab120

Lab114

Lab164

Lab080

Lab100

Lab055

Lab069

Lab019

Lab030

Lab078

Lab136

Lab005

Lab062

Lab011

Lab063

Lab051

Lab143

Lab039

Lab072

Lab162

Lab153

Lab017

Lab097

Lab059

Lab126

Lab009

Lab109

Lab054

Lab025

Lab082

Lab130

Lab161

Lab131

Lab155

Lab101

Lab088

Lab081

Lab090

Lab050

Lab092

Lab077

Lab089

Lab179

Lab021

Lab056

Lab075

Lab160

Lab043

Lab139

Lab110

Lab058

Lab099

Lab140

Lab154

Lab049

Lab085

Lab107

Lab149

Lab014

Lab096

Lab152

Lab046

Lab065

Lab145

Lab076

Lab026

Lab112

Lab104

Lab182

Lab119

Lab178

Lab060

Lab016

Lab108

Lab074

Lab177

Lab032

Lab091

Lab079

Lab094

Lab013

Lab053

Lab010

Lab147

Lab002

Lab064

Lab115

Lab125

Lab171

Lab036

Lab052

Lab070

Lab015

Lab061

Lab133

Lab084

Lab103

Lab111

Lab006

Lab001

Lab068

Lab137

Lab033

Lab128

Lab172

Lab113

Lab018

Lab083

Lab087

Lab181

Lab040

Lab163

Lab123

Lab170

Lab167

Lab012

Lab117

Lab173

Lab048

Lab038

Lab031

Lab044

Lab057

Lab035

Lab122

Lab118

Lab020

Lab105

Lab127

Chlorothalonil


7,5 % Questionable

9,5 % Unnacceptable

8 False negatives


Chlorpyrifos

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab124

Lab073

Lab170

Lab037

Lab158

Lab010

Lab146

Lab135

Lab005

Lab149

Lab157

Lab167

Lab048

Lab174

Lab025

Lab030

Lab081

Lab116

Lab066

Lab078

Lab062

Lab168

Lab159

Lab139

Lab006

Lab022

Lab064

Lab111

Lab123

Lab140

Lab136

Lab102

Lab097

Lab101

Lab151

Lab130

Lab015

Lab058

Lab077

Lab016

Lab134

Lab075

Lab092

Lab023

Lab076

Lab131

Lab082

Lab166

Lab109

Lab169

Lab184

Lab067

Lab088

Lab104

Lab072

Lab094

Lab145

Lab051

Lab065

Lab162

Lab129

Lab056

Lab161

Lab143

Lab142

Lab008

Lab011

Lab032

Lab021

Lab019

Lab002

Lab132

Lab043

Lab059

Lab106

Lab117

Lab150

Lab175

Lab036

Lab177

Lab137

Lab009

Lab040

Lab093

Lab122

Lab049

Lab182

Lab050

Lab080

Lab017

Lab138

Lab120

Lab128

Lab163

Lab165

Lab012

Lab024

Lab038

Lab063

Lab084

Lab061

Lab126

Lab053

Lab090

Lab087

Lab085

Lab003

Lab013

Lab153

Lab141

Lab014

Lab099

Lab172

Lab001

Lab147

Lab183

Lab068

Lab113

Lab042

Lab107

Lab031

Lab091

Lab108

Lab054

Lab154

Lab171

Lab020

Lab033

Lab027

Lab105

Lab086

Lab029

Lab083

Lab118

Lab178

Lab055

Lab103

Lab079

Lab100

Lab044

Lab119

Lab152

Lab089

Lab133

Lab114

Lab070

Lab057

Lab115

Lab155

Lab179

Lab181

Lab028

Lab018

Lab110

Lab047

Lab060

Lab112

Lab045

Lab173

Lab160

Lab098

Lab125

Lab004

Lab095

Lab074

Lab007

Lab096

Lab046

Lab039

Lab052

Lab127

Lab041

Lab180

Lab035

Lab176

Lab148

Lab069

Lab026

Lab034

Lab121

Lab164

Chlorpyrifos


6,6 % Questionable

1,8 % Unnacceptable

0 False negatives


Cypermethrin (cypermethrin incl. other mixtures of constituent isomers (sum of isomers))

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab003

Lab184

Lab124

Lab146

Lab023

Lab081

Lab024

Lab121

Lab167

Lab028

Lab064

Lab066

Lab157

Lab009

Lab093

Lab118

Lab090

Lab177

Lab102

Lab006

Lab162

Lab123

Lab049

Lab005

Lab065

Lab161

Lab140

Lab082

Lab178

Lab016

Lab143

Lab091

Lab164

Lab138

Lab017

Lab030

Lab151

Lab031

Lab078

Lab139

Lab158

Lab073

Lab166

Lab018

Lab183

Lab088

Lab145

Lab128

Lab134

Lab008

Lab068

Lab076

Lab169

Lab015

Lab083

Lab098

Lab120

Lab150

Lab062

Lab133

Lab002

Lab019

Lab021

Lab059

Lab077

Lab087

Lab108

Lab117

Lab104

Lab036

Lab053

Lab105

Lab131

Lab051

Lab122

Lab153

Lab045

Lab032

Lab048

Lab103

Lab149

Lab060

Lab014

Lab097

Lab092

Lab086

Lab165

Lab056

Lab043

Lab155

Lab159

Lab172

Lab072

Lab033

Lab085

Lab001

Lab027

Lab055

Lab058

Lab142

Lab154

Lab174

Lab013

Lab050

Lab079

Lab095

Lab067

Lab011

Lab063

Lab099

Lab100

Lab126

Lab182

Lab069

Lab089

Lab010

Lab054

Lab112

Lab115

Lab175

Lab107

Lab101

Lab171

Lab181

Lab070

Lab025

Lab119

Lab144

Lab034

Lab113

Lab125

Lab044

Lab074

Lab075

Lab012

Lab020

Lab057

Lab111

Lab173

Lab179

Lab136

Lab137

Lab041

Lab052

Lab046

Lab038

Lab096

Lab163

Lab040

Lab106

Lab035

Lab084

Lab141

Lab116

Lab129

Lab110

Lab039

Lab061

Lab152

Lab026

Lab147

Lab042

Lab007

Lab114

Lab037

Lab168

Lab160

Lab109

Lab148

Cypermethrin


2,6 % Questionable

1,3 % Unnacceptable

1 False negative


Cyprodinil

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab170

Lab124

Lab157

Lab160

Lab048

Lab006

Lab159

Lab025

Lab123

Lab165

Lab168

Lab062

Lab102

Lab078

Lab167

Lab082

Lab183

Lab016

Lab023

Lab120

Lab066

Lab174

Lab097

Lab019

Lab011

Lab090

Lab136

Lab155

Lab146

Lab169

Lab002

Lab007

Lab021

Lab140

Lab141

Lab130

Lab009

Lab058

Lab084

Lab158

Lab086

Lab149

Lab081

Lab064

Lab101

Lab108

Lab161

Lab162

Lab077

Lab015

Lab133

Lab131

Lab099

Lab104

Lab151

Lab059

Lab029

Lab008

Lab038

Lab076

Lab030

Lab065

Lab098

Lab103

Lab106

Lab105

Lab001

Lab178

Lab118

Lab112

Lab172

Lab179

Lab121

Lab126

Lab119

Lab056

Lab122

Lab005

Lab166

Lab027

Lab028

Lab111

Lab049

Lab152

Lab153

Lab036

Lab012

Lab091

Lab129

Lab087

Lab116

Lab128

Lab137

Lab139

Lab181

Lab085

Lab031

Lab044

Lab164

Lab057

Lab018

Lab033

Lab050

Lab150

Lab173

Lab060

Lab072

Lab095

Lab068

Lab177

Lab055

Lab083

Lab109

Lab054

Lab020

Lab079

Lab110

Lab003

Lab061

Lab080

Lab047

Lab073

Lab063

Lab093

Lab138

Lab163

Lab046

Lab014

Lab182

Lab145

Lab017

Lab040

Lab089

Lab117

Lab070

Lab107

Lab053

Lab069

Lab092

Lab004

Lab127

Lab114

Lab100

Lab051

Lab039

Lab115

Lab171

Lab013

Lab032

Lab096

Lab052

Lab147

Lab042

Lab088

Lab045

Lab075

Lab043

Lab041

Lab067

Lab148

Lab026

Lab035

Lab034

Lab010

Cyprodinil

0,588 mg/kg

98,0 % Acceptable

1,3 % Questionable

0,7 % Unnacceptable

1 False negative


Diazinon

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab170

Lab124

Lab146

Lab048

Lab139

Lab184

Lab081

Lab165

Lab051

Lab132

Lab140

Lab158

Lab174

Lab088

Lab178

Lab058

Lab097

Lab133

Lab121

Lab134

Lab002

Lab019

Lab102

Lab078

Lab184

Lab023

Lab030

Lab169

Lab009

Lab047

Lab131

Lab066

Lab077

Lab084

Lab092

Lab098

Lab105

Lab123

Lab142

Lab130

Lab060

Lab003

Lab033

Lab076

Lab094

Lab090

Lab104

Lab073

Lab096

Lab151

Lab054

Lab057

Lab062

Lab164

Lab065

Lab021

Lab063

Lab072

Lab001

Lab036

Lab083

Lab111

Lab116

Lab128

Lab154

Lab168

Lab175

Lab167

Lab037

Lab050

Lab086

Lab099

Lab138

Lab162

Lab014

Lab027

Lab034

Lab053

Lab089

Lab106

Lab163

Lab061

Lab087

Lab103

Lab122

Lab143

Lab180

Lab008

Lab044

Lab064

Lab101

Lab109

Lab148

Lab149

Lab183

Lab011

Lab046

Lab059

Lab160

Lab006

Lab016

Lab049

Lab056

Lab137

Lab159

Lab025

Lab068

Lab145

Lab166

Lab126

Lab017

Lab069

Lab075

Lab129

Lab012

Lab013

Lab020

Lab079

Lab005

Lab024

Lab026

Lab038

Lab041

Lab110

Lab150

Lab157

Lab172

Lab173

Lab181

Lab022

Lab085

Lab114

Lab125

Lab177

Lab052

Lab074

Lab147

Lab153

Lab042

Lab182

Lab107

Lab082

Lab141

Lab152

Lab070

Lab136

Lab119

Lab040

Lab004

Lab031

Lab100

Lab118

Lab007

Lab093

Lab029

Lab045

Lab018

Lab028

Lab032

Lab035

Lab055

Lab091

Lab108

Lab115

Lab155

Lab039

Lab043

Lab067

Lab080

Lab120

Lab179

Lab010

Lab112

Lab117

Lab015

Lab095

Lab171

Lab176

Lab135

Lab161

Diazinon0,084 mg/kg

96,4 % Acceptable

1,2 % Questionable

2,4 % Unnacceptable

1 False negative


Difenoconazole

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab124

Lab098

Lab174

Lab006

Lab160

Lab017

Lab157

Lab149

Lab081

Lab023

Lab078

Lab102

Lab151

Lab019

Lab169

Lab018

Lab002

Lab123

Lab062

Lab111

Lab042

Lab066

Lab076

Lab164

Lab016

Lab136

Lab146

Lab140

Lab155

Lab077

Lab009

Lab024

Lab083

Lab008

Lab007

Lab101

Lab030

Lab165

Lab167

Lab097

Lab047

Lab104

Lab021

Lab049

Lab133

Lab181

Lab001

Lab131

Lab072

Lab073

Lab087

Lab128

Lab139

Lab172

Lab046

Lab120

Lab069

Lab138

Lab065

Lab050

Lab118

Lab025

Lab130

Lab162

Lab028

Lab079

Lab114

Lab179

Lab061

Lab031

Lab064

Lab112

Lab182

Lab082

Lab183

Lab036

Lab052

Lab027

Lab051

Lab013

Lab053

Lab137

Lab095

Lab153

Lab055

Lab080

Lab119

Lab063

Lab084

Lab099

Lab107

Lab091

Lab033

Lab093

Lab126

Lab075

Lab057

Lab161

Lab015

Lab040

Lab054

Lab056

Lab122

Lab085

Lab012

Lab059

Lab103

Lab116

Lab068

Lab058

Lab004

Lab142

Lab163

Lab110

Lab177

Lab145

Lab159

Lab020

Lab060

Lab089

Lab141

Lab152

Lab129

Lab070

Lab178

Lab173

Lab038

Lab044

Lab115

Lab117

Lab125

Lab150

Lab171

Lab180

Lab003

Lab029

Lab096

Lab100

Lab121

Lab166

Lab045

Lab011

Lab041

Lab105

Lab147

Lab088

Lab074

Lab048

Lab106

Lab034

Lab067

Lab090

Lab032

Lab148

Lab108

Difenoconazole0,945 mg/kg

96,5 % Acceptable

3,5 % Questionable

0,0 % Unnacceptable

0 False negatives


Endosulfan alpha

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab003

Lab041

Lab073

Lab156

Lab170

Lab025

Lab157

Lab062

Lab176

Lab124

Lab135

Lab145

Lab184

Lab023

Lab048

Lab081

Lab006

Lab174

Lab076

Lab090

Lab159

Lab162

Lab031

Lab030

Lab168

Lab049

Lab064

Lab019

Lab002

Lab169

Lab082

Lab038

Lab133

Lab009

Lab102

Lab146

Lab111

Lab180

Lab078

Lab120

Lab150

Lab158

Lab015

Lab149

Lab130

Lab131

Lab026

Lab166

Lab136

Lab016

Lab021

Lab151

Lab001

Lab140

Lab123

Lab128

Lab114

Lab086

Lab033

Lab037

Lab129

Lab032

Lab043

Lab083

Lab084

Lab117

Lab134

Lab080

Lab013

Lab101

Lab104

Lab165

Lab152

Lab058

Lab155

Lab010

Lab060

Lab098

Lab077

Lab097

Lab139

Lab178

Lab177

Lab036

Lab072

Lab028

Lab034

Lab164

Lab163

Lab005

Lab088

Lab017

Lab137

Lab182

Lab094

Lab138

Lab093

Lab126

Lab110

Lab079

Lab122

Lab018

Lab119

Lab035

Lab063

Lab085

Lab112

Lab116

Lab161

Lab171

Lab175

Lab181

Lab167

Lab044

Lab055

Lab056

Lab075

Lab113

Lab068

Lab109

Lab091

Lab095

Lab051

Lab054

Lab053

Lab027

Lab153

Lab050

Lab061

Lab147

Lab057

Lab107

Lab144

Lab173

Lab089

Lab179

Lab022

Lab040

Lab099

Lab103

Lab106

Lab125

Lab142

Lab154

Lab141

Lab143

Lab008

Lab046

Lab020

Lab105

Lab096

Lab012

Lab042

Lab065

Lab011

Lab067

Lab087

Lab100

Lab070

Lab160

Lab074

Lab115

Lab121

Lab045

Lab069

Lab052

Lab148

Lab007

Lab118

Lab172

Lab014

Lab066

Lab108

Lab059

Endosulfan alpha1,149 mg/kg

90,7 % Acceptable

3,7 % Questionable

5,6 % Unnacceptable

2 False negatives


Endosulfan beta

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab003

Lab041

Lab073

Lab176

Lab156

Lab170

Lab124

Lab135

Lab157

Lab059

Lab145

Lab184

Lab155

Lab030

Lab025

Lab023

Lab081

Lab174

Lab014

Lab064

Lab066

Lab017

Lab062

Lab006

Lab102

Lab162

Lab172

Lab002

Lab048

Lab076

Lab078

Lab123

Lab139

Lab121

Lab111

Lab058

Lab098

Lab158

Lab151

Lab150

Lab120

Lab082

Lab090

Lab033

Lab057

Lab131

Lab130

Lab072

Lab122

Lab149

Lab136

Lab021

Lab179

Lab038

Lab134

Lab146

Lab001

Lab015

Lab019

Lab056

Lab140

Lab181

Lab129

Lab133

Lab105

Lab104

Lab143

Lab177

Lab138

Lab005

Lab109

Lab028

Lab084

Lab166

Lab083

Lab142

Lab144

Lab077

Lab049

Lab009

Lab088

Lab168

Lab079

Lab097

Lab128

Lab036

Lab152

Lab164

Lab091

Lab027

Lab032

Lab034

Lab114

Lab060

Lab137

Lab022

Lab113

Lab171

Lab094

Lab085

Lab035

Lab063

Lab099

Lab112

Lab141

Lab054

Lab075

Lab126

Lab119

Lab165

Lab016

Lab107

Lab178

Lab013

Lab044

Lab154

Lab159

Lab050

Lab067

Lab093

Lab161

Lab182

Lab042

Lab043

Lab061

Lab080

Lab101

Lab031

Lab055

Lab173

Lab086

Lab068

Lab089

Lab020

Lab070

Lab117

Lab065

Lab026

Lab040

Lab087

Lab103

Lab106

Lab147

Lab153

Lab018

Lab118

Lab095

Lab074

Lab160

Lab096

Lab051

Lab110

Lab012

Lab046

Lab116

Lab011

Lab125

Lab175

Lab008

Lab053

Lab037

Lab167

Lab052

Lab100

Lab169

Lab045

Lab180

Lab007

Lab115

Lab010

Lab069

Lab148

Lab108

Endosulfan Beta0,964 mg/kg

90,7 % Acceptable

4,3 % Questionable

5,0 % Unnacceptable

2 False negatives


Fenamiphos

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab041

Lab083

Lab146

Lab073

Lab069

Lab120

Lab116

Lab149

Lab010

Lab124

Lab184

Lab151

Lab081

Lab025

Lab170

Lab157

Lab021

Lab003

Lab019

Lab165

Lab179

Lab020

Lab014

Lab137

Lab006

Lab002

Lab007

Lab153

Lab166

Lab173

Lab018

Lab118

Lab082

Lab078

Lab030

Lab051

Lab182

Lab155

Lab169

Lab095

Lab101

Lab174

Lab167

Lab072

Lab140

Lab104

Lab145

Lab108

Lab123

Lab062

Lab066

Lab064

Lab084

Lab111

Lab177

Lab131

Lab139

Lab159

Lab054

Lab097

Lab033

Lab122

Lab161

Lab089

Lab009

Lab164

Lab004

Lab012

Lab126

Lab138

Lab117

Lab147

Lab058

Lab061

Lab049

Lab076

Lab085

Lab011

Lab107

Lab016

Lab052

Lab106

Lab091

Lab032

Lab105

Lab063

Lab065

Lab056

Lab077

Lab178

Lab119

Lab053

Lab088

Lab013

Lab099

Lab047

Lab110

Lab050

Lab008

Lab114

Lab093

Lab171

Lab079

Lab059

Lab128

Lab068

Lab057

Lab080

Lab112

Lab133

Lab162

Lab027

Lab115

Lab046

Lab121

Lab023

Lab103

Lab075

Lab045

Lab141

Lab070

Lab040

Lab067

Lab055

Lab028

Lab042

Lab017

Lab136

Lab031

Lab060

Lab029

Lab098

Lab096

Lab127

Lab100

Lab001

Lab183

Lab035

Lab015

Lab160

Lab090

Lab158

Lab039

Lab026

Lab172

Lab034

Fenamiphos7,297 mg/kg

88,1 % Acceptable

6,0 % Questionable

6,0 % Unnacceptable

3 False negatives


Fenamiphos sulfone

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab004

Lab012

Lab041

Lab059

Lab083

Lab095

Lab146

Lab097

Lab029

Lab166

Lab051

Lab006

Lab073

Lab020

Lab007

Lab061

Lab107

Lab008

Lab131

Lab089

Lab155

Lab047

Lab042

Lab121

Lab028

Lab157

Lab062

Lab096

Lab002

Lab103

Lab123

Lab077

Lab032

Lab128

Lab145

Lab104

Lab084

Lab027

Lab066

Lab085

Lab101

Lab173

Lab076

Lab122

Lab050

Lab080

Lab133

Lab119

Lab015

Lab018

Lab078

Lab060

Lab079

Lab054

Lab056

Lab138

Lab139

Lab001

Lab009

Lab033

Lab063

Lab093

Lab106

Lab115

Lab140

Lab171

Lab172

Lab081

Lab082

Lab100

Lab049

Lab126

Lab151

Lab091

Lab136

Lab016

Lab178

Lab068

Lab110

Lab052

Lab053

Lab057

Lab065

Lab075

Lab153

Lab118

Lab182

Lab167

Lab031

Lab072

Lab023

Lab046

Lab160

Lab019

Lab105

Lab090

Lab070

Lab011

Lab058

Lab112

Lab147

Lab013

Lab017

Lab040

Lab055

Lab067

Lab174

Lab162

Lab021

Lab141

Lab025

Lab069

Lab034

Lab164

Fenamiphos sulfone0,109 mg/kg

85,3 % Acceptable

3,7 % Questionable

11,0 % Unnacceptable

7 False negatives



-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab004

Lab041

Lab059

Lab069

Lab083

Lab146

Lab147

Lab162

Lab073

Lab151

Lab170

Lab025

Lab174

Lab061

Lab153

Lab116

Lab021

Lab131

Lab119

Lab095

Lab085

Lab006

Lab020

Lab123

Lab051

Lab107

Lab128

Lab121

Lab078

Lab171

Lab008

Lab106

Lab066

Lab002

Lab053

Lab042

Lab072

Lab082

Lab062

Lab015

Lab034

Lab032

Lab103

Lab079

Lab101

Lab145

Lab133

Lab049

Lab084

Lab028

Lab104

Lab033

Lab122

Lab046

Lab077

Lab050

Lab080

Lab136

Lab167

Lab019

Lab091

Lab011

Lab076

Lab155

Lab110

Lab058

Lab138

Lab070

Lab089

Lab060

Lab029

Lab027

Lab016

Lab141

Lab017

Lab126

Lab166

Lab173

Lab013

Lab182

Lab055

Lab115

Lab057

Lab096

Lab075

Lab040

Lab023

Lab178

Lab097

Lab018

Lab093

Lab054

Lab007

Lab063

Lab112

Lab047

Lab056

Lab001

Lab100

Lab105

Lab052

Lab009

Lab090

Lab157

Lab067

Lab068

Lab139

Lab172

Lab118

Lab065

Lab160

Lab081

Lab140

Lab031

Lab164

Fenamiphos sulfoxide6,625 mg/kg

85,3 % Acceptable

5,5 % Questionable

9,2% Unnacceptable

7 False negatives


Fenhexamid

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab041

Lab024

Lab157

Lab141

Lab007

Lab030

Lab149

Lab048

Lab009

Lab093

Lab077

Lab006

Lab159

Lab032

Lab146

Lab014

Lab180

Lab069

Lab086

Lab123

Lab167

Lab066

Lab169

Lab164

Lab174

Lab073

Lab078

Lab023

Lab182

Lab091

Lab042

Lab002

Lab129

Lab155

Lab105

Lab081

Lab160

Lab062

Lab092

Lab076

Lab016

Lab043

Lab130

Lab015

Lab153

Lab047

Lab099

Lab102

Lab171

Lab036

Lab133

Lab104

Lab051

Lab101

Lab072

Lab165

Lab126

Lab038

Lab065

Lab137

Lab140

Lab005

Lab114

Lab122

Lab004

Lab019

Lab117

Lab136

Lab049

Lab162

Lab025

Lab131

Lab020

Lab111

Lab138

Lab001

Lab027

Lab161

Lab121

Lab166

Lab053

Lab080

Lab178

Lab060

Lab021

Lab116

Lab061

Lab090

Lab008

Lab034

Lab181

Lab118

Lab050

Lab108

Lab127

Lab179

Lab063

Lab067

Lab056

Lab085

Lab013

Lab147

Lab075

Lab031

Lab163

Lab017

Lab119

Lab074

Lab112

Lab152

Lab079

Lab089

Lab068

Lab145

Lab057

Lab103

Lab125

Lab128

Lab100

Lab173

Lab110

Lab012

Lab011

Lab040

Lab058

Lab044

Lab082

Lab059

Lab087

Lab172

Lab107

Lab046

Lab120

Lab095

Lab033

Lab106

Lab183

Lab018

Lab052

Lab097

Lab029

Lab070

Lab084

Lab096

Lab055

Lab064

Lab115

Lab139

Lab177

Lab028

Lab150

Lab088

Lab054

Lab148

Lab151

Lab083

Fenhexamid


2,1 % Questionable

0,7 % Unnacceptable

1 False negative


Fludioxonil

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab004

Lab034

Lab041

Lab069

Lab164

Lab124

Lab018

Lab134

Lab129

Lab067

Lab088

Lab118

Lab064

Lab174

Lab024

Lab032

Lab048

Lab066

Lab149

Lab062

Lab025

Lab030

Lab006

Lab023

Lab002

Lab146

Lab169

Lab081

Lab077

Lab153

Lab078

Lab007

Lab021

Lab108

Lab140

Lab165

Lab097

Lab054

Lab152

Lab178

Lab095

Lab091

Lab131

Lab027

Lab033

Lab087

Lab123

Lab141

Lab157

Lab120

Lab138

Lab105

Lab073

Lab122

Lab145

Lab076

Lab167

Lab063

Lab082

Lab084

Lab101

Lab102

Lab050

Lab130

Lab151

Lab017

Lab046

Lab045

Lab001

Lab072

Lab104

Lab009

Lab011

Lab053

Lab083

Lab086

Lab111

Lab112

Lab161

Lab121

Lab085

Lab160

Lab061

Lab136

Lab126

Lab068

Lab019

Lab040

Lab055

Lab147

Lab031

Lab060

Lab014

Lab044

Lab075

Lab139

Lab128

Lab012

Lab058

Lab093

Lab158

Lab173

Lab181

Lab057

Lab166

Lab090

Lab182

Lab020

Lab042

Lab089

Lab107

Lab051

Lab110

Lab079

Lab115

Lab163

Lab177

Lab133

Lab056

Lab059

Lab099

Lab103

Lab005

Lab003

Lab114

Lab080

Lab070

Lab100

Lab013

Lab038

Lab098

Lab155

Lab183

Lab039

Lab036

Lab008

Lab010

Lab015

Lab172

Lab179

Lab049

Lab119

Lab052

Lab162

Lab096

Lab035

Lab171

Lab065

Lab016

Lab028

Lab150

Lab026

Lab106

Fludioxonil


2,1 % Questionable

4,9 % Unnacceptable

5 False negatives


Lambda-Cyhalothrin

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab003

Lab124

Lab014

Lab034

Lab103

Lab146

Lab148

Lab024

Lab098

Lab139

Lab023

Lab076

Lab049

Lab184

Lab006

Lab178

Lab078

Lab093

Lab151

Lab025

Lab165

Lab058

Lab174

Lab074

Lab138

Lab066

Lab140

Lab145

Lab157

Lab081

Lab163

Lab134

Lab002

Lab062

Lab128

Lab012

Lab016

Lab027

Lab099

Lab136

Lab171

Lab181

Lab060

Lab065

Lab112

Lab121

Lab137

Lab169

Lab001

Lab088

Lab130

Lab133

Lab045

Lab046

Lab079

Lab102

Lab009

Lab031

Lab032

Lab087

Lab123

Lab131

Lab142

Lab158

Lab017

Lab068

Lab057

Lab101

Lab118

Lab183

Lab019

Lab077

Lab149

Lab161

Lab177

Lab053

Lab059

Lab104

Lab172

Lab082

Lab111

Lab166

Lab011

Lab063

Lab064

Lab070

Lab072

Lab110

Lab008

Lab141

Lab144

Lab100

Lab179

Lab021

Lab085

Lab125

Lab107

Lab075

Lab038

Lab044

Lab048

Lab096

Lab147

Lab154

Lab173

Lab119

Lab164

Lab091

Lab126

Lab005

Lab030

Lab061

Lab020

Lab105

Lab106

Lab143

Lab097

Lab113

Lab167

Lab036

Lab040

Lab152

Lab018

Lab050

Lab069

Lab051

Lab067

Lab095

Lab182

Lab084

Lab115

Lab010

Lab028

Lab035

Lab150

Lab033

Lab052

Lab026

Lab086

Lab092

Lab117

Lab120

Lab122

Lab089

Lab015

Lab056

Lab041

Lab055

Lab108

Lab153

Lab162

Lab039

Lab073

Lab054

Lab013

Lab043

Lab083

Lab116

Lab155

Lab168

Lab129

Lab007

Lab042

Lab114

Lab127

Lab160

Lab090

Lambda-Cyhalothrin


2,0 % Questionable

5,9 % Unnacceptable

6 False negatives


Methoxyfenozide

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab083

Lab164

Lab114

Lab157

Lab006

Lab160

Lab019

Lab089

Lab002

Lab020

Lab093

Lab134

Lab081

Lab062

Lab042

Lab100

Lab104

Lab139

Lab078

Lab172

Lab169

Lab097

Lab001

Lab077

Lab131

Lab178

Lab174

Lab007

Lab033

Lab066

Lab106

Lab123

Lab142

Lab031

Lab151

Lab138

Lab050

Lab167

Lab027

Lab111

Lab180

Lab095

Lab165

Lab051

Lab145

Lab073

Lab076

Lab133

Lab054

Lab146

Lab065

Lab120

Lab136

Lab017

Lab025

Lab072

Lab130

Lab016

Lab166

Lab008

Lab009

Lab021

Lab063

Lab082

Lab101

Lab116

Lab122

Lab128

Lab147

Lab162

Lab080

Lab137

Lab011

Lab118

Lab140

Lab029

Lab126

Lab182

Lab061

Lab068

Lab090

Lab044

Lab047

Lab075

Lab032

Lab053

Lab059

Lab117

Lab079

Lab110

Lab121

Lab046

Lab052

Lab067

Lab049

Lab013

Lab070

Lab091

Lab056

Lab058

Lab099

Lab112

Lab060

Lab003

Lab119

Lab183

Lab105

Lab084

Lab030

Lab085

Lab107

Lab177

Lab096

Lab057

Lab127

Lab171

Lab173

Lab179

Lab159

Lab012

Lab024

Lab040

Lab087

Lab103

Lab115

Lab055

Lab041

Lab155

Lab153

Lab149

Lab163

Lab034

Lab141

Lab015

Methoxyfenozide


3,3 % Questionable

1,7 % Unnacceptable

2 False negatives


Pirimicarb

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab124

Lab149

Lab018

Lab014

Lab048

Lab026

Lab168

Lab006

Lab025

Lab085

Lab174

Lab044

Lab065

Lab102

Lab084

Lab116

Lab119

Lab012

Lab034

Lab120

Lab123

Lab097

Lab093

Lab163

Lab002

Lab143

Lab160

Lab101

Lab131

Lab078

Lab136

Lab036

Lab107

Lab047

Lab099

Lab035

Lab008

Lab167

Lab164

Lab122

Lab023

Lab118

Lab171

Lab121

Lab128

Lab061

Lab007

Lab016

Lab083

Lab103

Lab062

Lab169

Lab022

Lab140

Lab086

Lab003

Lab051

Lab038

Lab066

Lab108

Lab130

Lab088

Lab114

Lab166

Lab027

Lab053

Lab059

Lab153

Lab076

Lab049

Lab137

Lab009

Lab134

Lab141

Lab155

Lab157

Lab180

Lab109

Lab133

Lab033

Lab072

Lab112

Lab104

Lab126

Lab058

Lab150

Lab138

Lab082

Lab067

Lab146

Lab050

Lab081

Lab079

Lab005

Lab021

Lab161

Lab179

Lab031

Lab054

Lab045

Lab030

Lab077

Lab110

Lab089

Lab177

Lab100

Lab046

Lab019

Lab087

Lab098

Lab117

Lab182

Lab178

Lab015

Lab162

Lab004

Lab013

Lab057

Lab145

Lab183

Lab080

Lab017

Lab011

Lab028

Lab032

Lab055

Lab068

Lab070

Lab029

Lab064

Lab096

Lab056

Lab073

Lab148

Lab001

Lab040

Lab095

Lab111

Lab175

Lab165

Lab158

Lab060

Lab043

Lab075

Lab106

Lab105

Lab173

Lab090

Lab159

Lab181

Lab139

Lab020

Lab039

Lab151

Lab147

Lab074

Lab042

Lab069

Lab010

Lab063

Lab115

Lab041

Lab091

Lab052

Lab172

Pirimicarb


1,9 % Questionable

0,0 % Unnacceptable

0 False negatives


Pyridaben

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab108

Lab027

Lab102

Lab174

Lab064

Lab081

Lab023

Lab062

Lab140

Lab077

Lab139

Lab172

Lab149

Lab143

Lab065

Lab123

Lab006

Lab078

Lab019

Lab136

Lab076

Lab007

Lab021

Lab066

Lab093

Lab101

Lab111

Lab128

Lab088

Lab051

Lab016

Lab046

Lab178

Lab165

Lab002

Lab033

Lab038

Lab106

Lab025

Lab085

Lab015

Lab045

Lab138

Lab091

Lab145

Lab167

Lab054

Lab121

Lab131

Lab146

Lab001

Lab009

Lab130

Lab147

Lab158

Lab164

Lab182

Lab050

Lab018

Lab073

Lab031

Lab169

Lab036

Lab042

Lab049

Lab096

Lab129

Lab029

Lab060

Lab072

Lab095

Lab012

Lab032

Lab059

Lab097

Lab013

Lab020

Lab090

Lab126

Lab008

Lab133

Lab017

Lab067

Lab079

Lab105

Lab151

Lab152

Lab057

Lab089

Lab137

Lab068

Lab010

Lab011

Lab053

Lab055

Lab058

Lab083

Lab112

Lab141

Lab153

Lab161

Lab180

Lab084

Lab104

Lab122

Lab056

Lab179

Lab075

Lab107

Lab163

Lab162

Lab119

Lab082

Lab086

Lab040

Lab044

Lab063

Lab087

Lab103

Lab116

Lab173

Lab110

Lab166

Lab069

Lab100

Lab030

Lab003

Lab177

Lab070

Lab061

Lab099

Lab115

Lab155

Lab047

Lab183

Lab109

Lab028

Lab171

Lab117

Lab118

Lab157

Lab014

Lab052

Lab080

Lab034

Lab160

Lab114

Lab159

Lab035

Lab041

Pyridaben


2,2 % Questionable

0,7 % Unnacceptable

1 False negative


Spinosad (sum of spinosyn A and spinosyn D, expr. as spinosad)

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab179

Lab114

Lab134

Lab019

Lab002

Lab047

Lab137

Lab078

Lab095

Lab020

Lab155

Lab030

Lab077

Lab131

Lab010

Lab157

Lab174

Lab169

Lab149

Lab122

Lab165

Lab076

Lab100

Lab119

Lab104

Lab055

Lab058

Lab072

Lab112

Lab138

Lab166

Lab059

Lab061

Lab139

Lab099

Lab015

Lab027

Lab123

Lab130

Lab006

Lab021

Lab046

Lab062

Lab003

Lab110

Lab120

Lab028

Lab042

Lab066

Lab140

Lab167

Lab060

Lab073

Lab118

Lab162

Lab178

Lab107

Lab057

Lab183

Lab133

Lab182

Lab017

Lab025

Lab063

Lab103

Lab126

Lab081

Lab008

Lab029

Lab033

Lab044

Lab082

Lab117

Lab016

Lab031

Lab070

Lab075

Lab106

Lab159

Lab011

Lab053

Lab084

Lab101

Lab177

Lab001

Lab013

Lab090

Lab128

Lab067

Lab079

Lab121

Lab024

Lab034

Lab068

Lab111

Lab115

Lab172

Lab136

Lab056

Lab051

Lab007

Lab093

Lab151

Lab040

Lab096

Lab171

Lab089

Lab050

Lab160

Lab102

Lab054

Lab127

Lab097

Lab145

Lab146

Lab141

Lab173

Lab065

Lab049

Lab105

Lab083

Lab163

Lab012

Lab052

Lab041

Lab032

Lab164

Spinosad

(sum of spinosyn A and spinosyn D, expr. as spinosad)


5,2 % Questionable

8,6 % Unnacceptable

1 False negative


Tetraconazole

-5,0

-4,0

-3,0

-2,0

-1,0

0,0

1,0

2,0

3,0

4,0

5,0

Lab035

Lab140

Lab177

Lab139

Lab108

Lab174

Lab146

Lab102

Lab040

Lab048

Lab066

Lab099

Lab179

Lab131

Lab025

Lab027

Lab077

Lab002

Lab018

Lab127

Lab006

Lab033

Lab076

Lab130

Lab009

Lab104

Lab150

Lab123

Lab169

Lab045

Lab073

Lab181

Lab084

Lab167

Lab151

Lab165

Lab078

Lab097

Lab149

Lab152

Lab178

Lab019

Lab136

Lab016

Lab030

Lab129

Lab133

Lab036

Lab070

Lab072

Lab021

Lab081

Lab137

Lab038

Lab041

Lab058

Lab062

Lab087

Lab101

Lab105

Lab111

Lab118

Lab161

Lab164

Lab120

Lab160

Lab003

Lab122

Lab001

Lab050

Lab056

Lab060

Lab138

Lab166

Lab057

Lab089

Lab128

Lab162

Lab054

Lab068

Lab020

Lab015

Lab017

Lab047

Lab031

Lab065

Lab008

Lab028

Lab063

Lab064

Lab069

Lab083

Lab090

Lab093

Lab103

Lab115

Lab145

Lab172

Lab014

Lab088

Lab126

Lab046

Lab061

Lab095

Lab119

Lab080

Lab085

Lab049

Lab051

Lab086

Lab096

Lab079

Lab121

Lab044

Lab034

Lab053

Lab059

Lab110

Lab112

Lab116

Lab125

Lab142

Lab173

Lab082

Lab075

Lab029

Lab159

Lab067

Lab182

Lab055

Lab107

Lab114

Lab052

Lab004

Lab007

Lab011

Lab091

Lab147

Lab155

Lab042

Lab013

Lab163

Lab153

Lab024

Lab012

Lab010

Lab171

Lab183

Lab032

Lab141

Lab100

Lab148

Lab157

Tetraconazole


1,4 % Questionable

3,6 % Unnacceptable

1 False negative


False Positives

4 different laboratories from EU/EFTA

countries reported 4 pesticides as false

positives


Laboratory

Code PesticideConcentration

(mg/kg)

Determination

Technique

RL

(mg/Kg)

MRRL

(mg/Kg)

Lab059 Fenpropathrin 0,980 LC-MS/MS (ESI+) 0.01 0,01

Lab160 Folpet 0,240 GC-MS/MS (EI) 0.02 0.01

Lab024 Metalaxyl and metalaxyl-M 0,010 LC-MS/MS (ESI+) 0.01 0.01

Lab003 Tefluthrin 0,012 GC-ECD 0.01 0.01

False Positives


Laboratory


(mg/kg)

Determination

Technique

RL

(mg/Kg)

MRRL

(mg/Kg)





False Positives


Laboratory


(mg/kg)

Determination

Technique

RL

(mg/Kg)

MRRL

(mg/Kg)





False Positives


Combined z-Scores


Average of Squared z-Scores

AZ2

AZ2 2 Good

3 Satisfactory

3 Unsatisfactory

<2

>AZ2

n

ZZn

1i

ii==

n

ZZ2

n

1i

ii==AZ


NRLs OfLs AZ2 Representation

92 % Good 5 % Satisfactory 3 % Unsatisfactory

Category A: 59,2 % of the EU/EFTA Laboratories

(100 Laboratories out of 169)

EU/EFTA Laboratories

EUPT-FV15: 92 % Good 7 % Satisfactory 1 % Unsatisfactory

EUPT-FV15: 54%


11th September 2014

Date post:	14-Nov-2020
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Preliminary Results...0.078-0.100 mg/kg 0.100-0.500 mg/kg > 0.500 mg/kg EUPT-FV16 Preliminary...

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