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Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There...

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1 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway Pre-normative REsearch for Safe use of Liquid HYdrogen Prenormative REsarch for Safe use of Liquid HYdrogen Thomas Jordan, KIT Joint Workshop on Liquid Hydrogen Safety - Bergen, Norway, 6 March 2019
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Page 1: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

1 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Pre-normative REsearch for Safe use of Liquid HYdrogen

Prenormative REsarch for Safe use of Liquid HYdrogenThomas Jordan, KITJoint Workshop on Liquid Hydrogen Safety - Bergen, Norway, 6 March 2019

Page 2: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

2 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

OutlineMotivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

− Motivation− PRESLHY Overview− WP3 Release− WP4 Ignition− WP5 Combustion− Exploitation− Closure

Page 3: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

3 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Motivationo Scale-up of existing and new applications increase demand.

o Liquid hydrogen (LH2) provides larger densities and gains in efficiency over gaseous transport and storage.

o The hazards and risks associated with LH2 are different from the relatively well-known compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2)

o PRESLHY project addresses the pre-normative research for a safer use of cryogenic and liquid hydrogen as energy carrier.

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 4: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

4 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

PRESLHY Objectiveso Report initial state-of-the-art and knowledge gaps with priorities wrt intended use of LH2

o Execute adjusted experimental program addressing release, ignition and combustion phenomena with highest priorities

o Document and publish detailed, aggregated and interpreted data in a FAIR way

o Develop suitable models and engineering correlations and integrate them in a suitable open risk assessment toolkit

o Provide enhanced recommendations for safe design and operations of LH2 technologies

o Support international SDOs in• updating of existing standards or • developing of new international

performance based and risk informed standardso Document and disseminate the enhanced state-of-the-art

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 5: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

5 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Partners & AdvisorsMotivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Advisor name CompanyInstitution

Nation

Derek Miller Air Products US

Andrei Tchouvelev AVT CANKlaus Schäfer DLR DFranz Grafwallner ET DTrygve Skjold GexCon NKarl Verfondern Jülich DShoji Kamiya KHI JPSalvador Aceves LLNL USLee Philips Shell UKEthan Hecht SNL USChristoph Haberstroh Uni Dresden D

Olav Hansen Loyds NGerd-Michael Würsig DNV GL DPietro Moretto JRC NLVolker Schröder BAM D

Steve Woods NASA US

Page 6: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

6 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

HySafe (+ Hydrogen Safety Panel)

RCS SCGJRC

(HIAD)ISO TC

197IEA

Hydrogen Task 37US DOE

WP1 –Manage-

ment(KIT)

WP2 - Strategy (AL)

WP5 –Combus-

tion(KIT)

WP3 –Release & Mixing(NCSRD)

WP6 – Implementation (UU)

WP4 –Ignition(HSL) PRESLHY

Advisory Board

External Networking / Dissemination

Presentationon 19.10.2018

ISO/PWI 24077: „Safe Use of LH2 in Non-Industrial Settings“ established on 6.12.2018Presentation

planned fornext meeting

SH2IFT; GexCon, IFE

SNL

KHI, Toyota

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 7: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

7 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

WP6 – Technical Implementation

WP1 –Management

WP2 - Technical Strategy & Evaluation

WP5 –Combustion

WP3 –Release &

Mixing

Advisory Board

WP4 –Ignition

General ApproachMotivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 8: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

8 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Visuals for RCS Priority TopicsMotivation - WP2 Results - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 9: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

9 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

RCS- Visuals for LH2 Separation DistancesMotivation - WP2 Results - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 10: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

10 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway10

RCS Status - NFPA2:2016 LH2 Separation Distances

Do these numbers make sense?What are correct criteria / methodology?

Motivation - WP2 Results - WP4 Ignition - WP5 Combustion – Exploitation - Closure

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11 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

RCS Status - EIGA Code of Practice for LH2

Motivation - WP2 Results - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 12: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

12 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

WP6 – Technical Implementation

WP1 –Management

WP2 - Technical Strategy & Evaluation

WP5 –Combustion

WP3 –Release &

Mixing

Advisory Board

WP4 –Ignition

WP3 –Release &

Mixing

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 13: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

13 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Gaps− No experiments for under-expanded release & dispersion from LH2 storage

(saturated or sub-cooled conditions)− No Blowdown− No droplet size measurements− No velocities or fluctuations− Very limited structure of two-phase jets close to the release

Weak points in many past experiments− Release momentum not measured− Uncertainty on the discharge rates− Large variability or limited info about meteorological conditions− Only few concentrations and temperatures

Gaps / Weak points wrt cryogenic H2 release and dispersion

NET-Tools Expert Workshop 19th – 20th March 2018

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

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14 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

HEM / HNEM Two-Phase Choked Flow Modelinge.g. NASA test 1197 (P0=12.9 bar, T0=30.7 K)

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

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15 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

WP3 Experimental Activities KIT / PS

− Design and set-up of tests E3.1, E3.4 HSL

− Design of tests E3.5 INERIS

− Sharing of existing LHe experiments data− Excluded tests

test 0 for no humidity info tests 1,2 for too large wind variation tests 7-9 for no H1, H2, L info

− Tests 3 and 6 selected for validation

L the length of the cloud on the groundH1 the height of the base of the cloudH2 the height at the top of the cloud.

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 16: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

16 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

E3.1 DISCHA-Facility Setup

• Vessel and valve will be cooled from outside by LN2 pool (Tmin = 77K)• Release of cold CGH2 and LN2 from up to 20 MPa

LN2

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

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17 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

camera 1 (different positions)

camera 2 (constant position)

object (jet)

origin

camera coverage areas

1,50 m

4 m

8 m

BOS background, two-sided: „natural“ and special produced

E3.1 DISCHA-FacilityRelease experiments combined withnear- and far-field optical measurements (BOS, laser, shadow,..) of mixing

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

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18 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

− top flange with pipework, controls under construction,

− safety valves replaced, − safety check by TÜV Süd scheduled.

E3.1 CRYO-Vessel LN2-shielded Cryo-vessel:

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

LH2

Flow-Meter

Valve

Nozzle

P

T

T

PosI

PosII

Line as shortas possible

− Pmax: 6 bar Pmax(exp): 5 bar− Volume: 225 l

(can be reduced via Styrofoam rings),− Long, uncooled neck further reduces

available volume,− Previous use for LHe

Page 19: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

19 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

E3.4 Pool-Facility / Planned Experiments• Basin with size 50 x 50 cm

with variation of ground material (e.g. concrete, earth or sand, to be defined!)

• LH2 release on surface in basin,• As long as no LH2-pool is formed no significant increase in weight,• LH2-release until weight increases (or LH2-reservoir is empty),• When pool has formed LH2 supply is stopped,• All frozen gases evaporate loss of weight,• In correlation with ground surface temperature evaporation of different species

(LH2, LN2, LO2) might be distinguished (distillation),• Using loss of weight over time for surface temperatures below 80 K might give

evaporation rate for LH2.

CC

Ground(Concrete, Earth, Sand)

T

Insulation (PU-Foam)

Scales

TT T

TTT

T T T T T T T

CC

C

CC

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 20: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

20 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

WP6 – Technical Implementation

WP1 –Management

WP2 - Technical Strategy & Evaluation

WP5 –Combustion

WP3 –Release &

Mixing

Advisory Board

WP4 –IgnitionWP4 –

Ignition

Page 21: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

21 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

E4.1 MIE Device (INERIS)Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

− Triggered spark− Current and voltage measured in the spark gap− Inductance = 1 mH or zero− Capacitance : variable − From a few microjoules to 1 joule

Page 22: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

22 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

E4.1 Ignition by hot surfaces/power(INERIS)

Valves

Dampingreservoirs

Pressure controls

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 23: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

24 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

E4.2 Electrostatic Ignition in jet (KIT)

T1

Ambiant air

Nozzle

Nozzle

to environment Set-up in test chamberQ160

Flow meter

LN2

P P%H2O

H2H2 He

PP1V1

V2

V3 V4

V5 V6

V7

TA

insulation

Hand valves

PP2T2

T3

T4H2

Field mill

Autogeneration ofelectrostatic field bywater ice particles

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 24: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

25 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Further ignition experiments

− E4.3 Electrostatic Ignition in plume (HSL)− E4.4 Ignition above pool (KIT)− E4.5 Condensed phase ignition (HSL)

Page 25: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

26 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

WP6 – Technical Implementation

WP1 –Management

WP2 - Technical Strategy & Evaluation

WP5 –Combustion

WP3 –Release &

Mixing

Advisory Board

WP4 –Ignition

WP5 –Combustion

Page 26: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

27 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Flammability, pressure and heat flux for ignited cold jet

For the ignited experiments an ignition device will be added to the existing facilities.

Selected experiments of the unignited series will be repeated with ignition,

Parameters to be varied include:• Ignition position,• Ignition time.

E5.1: DISCHA Ignited JetMotivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 27: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

28 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

E5.2: Combustion-Tube-FacilityTube experiments for FA and DDT criteria for T down to 80K

• End-Flange with ports for: − Thermocouple− Pressure-Sensor− Gas-Outlet

• Front-Flange with ports for: − Gas-Inlet− Glow-Plug− Thermocouple

• Along the tube 52 ports for:− Pressure Sensors (2 different types),− Phototransistors

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

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29 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

E5.2: Combustion-Tube-Facility

• 2 different obstacles (BR 30% and BR 60%),• obstacles will be positioned evenly along the complete tube length

(spacing: 1 inner diameter of tube) via three thin threaded rods,• obstacles were manufactured externally (already delivered).

BR 30% BR 60%

• Obstacles

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 29: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

30 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

E5.5: Integral test in congested space

Pool in congestion rig Jet release into congestion rig

Higher flow rate release into rig, larger orifice

Jet opening angle? (24 deg)Blockage ratio?

Variables:• LH2 pool or jet• Congestion level• Confinement level• LH2 jet flow rateIgnition source located just downstream of rig to limit inventory of unburnt gas prior to entry into the congestion rig, this is to limit noise

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 30: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

31 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Long termrepository

Select, edittransfer

Experimentalsub-program

Localrepository

INERIS

Experimentalsub-program

Localrepository

KIT

Experimentalsub-program

Localrepository

HSL

WP1

,2,6

WP3

,4,5

DOI

RADAR Services(alternatively

KITopen)

FAIR Data ManagementMotivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

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32 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

PRESLHYExploitation & Dissemination

Activities

Management(WP1)

Implementation(WP6)

Task 1.3 Website

Data Manage

ment

Engineering tools Handbook Guidelines RCS Recom-

mendationsWhite Paper

Task 6.6 Dissemination

Conference

OutreachMotivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

www.preslhy.eu

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33 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Deliverables on www.preslhy.eu

today

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 33: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

34 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Invitation to www.ichs2019.com

ENDORSEMENTS COLLABORATION HOSTING

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure

Page 34: Prenormative REsarch for Safe use of Liquid HYdrogen · compressed gaseous hydrogen (CGH2). (There are indications for reduced risk potential compared to CGH2) o PRESLHY project addresses

35 SH2IFT-PRESLHY Joint Workshop on LH2 Safety, 6 March 2019, Bergen, Norway

Acknowledgement

The PRESLHY project has received funding from the Fuel Cells and Hydrogen 2 Joint Undertaking under the European Union’s Horizon 2020 research and innovation program under the grant agreement No 779613

Motivation - PRESLHY Overview - WP3 Release - WP4 Ignition - WP5 Combustion – Exploitation - Closure


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