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Presentation: 2006-09-25 to 27 Status of Lithium Batteries ... · V. Evan House, Ph.D. ... L ead A...

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1 innovation at work With the exception of historical information, matters discussed in this presentation regarding product development, target markets, revenue and income projections, are forward looking statements that involve a number of risks and uncertainties as defined under the Private Securities Reform Act of 1995. Status of Lithium Batteries Using Lithium Titanate Based Anode (Safety, Rapid Charge, Cycle Life) V. Evan House, Ph.D. Director Advanced Materials & Power Systems
Transcript

1

innovation at work

With the exception of historical information, matters discussed in this presentation

regarding product development, target markets, revenue and income projections,

are forward looking statements that involve a number of risks and uncertainties

as defined under the Private Securities Reform Act of 1995.

Status of Lithium Batteries UsingLithium Titanate Based Anode(Safety, Rapid Charge, Cycle Life)

V. Evan House, Ph.D.DirectorAdvanced Materials & Power Systems

2

innovation at workAltairnano

• Public company (NASDAQ: ALTI)

• An innovator in ceramic nano-materials

• With titanium dioxide and metal oxides

– Having performance never achieved before

• Revolutionize electric and hybrid vehicles

• And, that’s just part of the story

3

innovation at workOffices, Labs & Semi-Works

• 100,000+ sq ft facilities

• Reno, NV and Anderson, IN

• 77 employees

• Rapid prototyping

• NIOSH partnership

Win-Win, Rapid Product Development

4

innovation at workCurrent Li Ion Batteries

• Surface area impacts Li ion diffusion rate

– Limits charge and discharge rates

• Crystal fracture and electrode poisoning

– Limits cycle and calendar life

• Hazardous combination of chemicals

– Products are not safe.

Performance Limited / Safety Compromised

Only Suitable for Low Rates / Ambient Environments

5

innovation at workAltairnano’s Solution

• Nano-structured electrodes

– Increase electrode surface area

• Small particle size

• High surface area

– Use stable 3 dimensional host materials

– Replaces graphite eliminating most hazards

• The performance impact?

– Battery performance dramatically improved

– Products are intrinsically safe

………Superior Performance Characteristics

Replacing Graphite Leads to…………..

6

innovation at workn-LTO (Li4Ti5O12) Based Anode

• n-LTO is a stable 3-D crystal structure (spinel)– Lithium can insert from any angle – fast kinetics

• Retains fast 3-D kinetics at low temperatures• Stable crystalline morphology

– Near zero deformation from charge / discharge

• Stable to 700°C• High capacity - 160 mAh/g• Voltage vs. Lithium

– Eliminates lithium metal formation– Eliminates SEI formation– Allows aluminum current collector– Reduces electrolyte side reactions

Nano Lithium Titanate Possesses Unique Properties

Enables a New Class of Batteries

7

innovation at workData

• Characteristic Voltage Curve

• Recharge Rate Performance

• Cycle Life

• Power Performance

• Cold Temperature Recharge

• High Temperature Recharge

• Safety

The Evidence Speaks for Itself

Nano Lithium Titanate IS a Disruptive Technology

8

innovation at workNanoSafe Rapid Charge

EV Cell Capacity vs. Charge Rate

1.5

1.7

1.9

2.1

2.3

2.5

2.7

2.9

0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100%

Capacity retention, %

Cel

l vol

tage

, V

1C (10A) charge & 1C discharge

5C (50A) charge & 1C discharge

10C (100A) charge & 1C discharge

Over 90% Charge Capacity in 6 Minutes

Pack Rated to 90% in < 10 Minutes

9

innovation at workNanoSafe Cycle Life

Altair = Over 15 Times the Cycle Life at 20 Times the Rate!

Common Li-Ion Capable of ~750 Cycles at C/2 Rate

1 0 C C h a r g e / 1 0 C D is c h a r g e C y c l in g

5 0 %

6 0 %

7 0 %

8 0 %

9 0 %

1 0 0 %

0 2 0 0 0 4 0 0 0 6 0 0 0 8 0 0 0 1 0 0 0 0 1 2 0 0 0C y c le

Cap

acity

ret

entio

n, %

10

innovation at workAltairnano Battery Performance

Lithium Batteries with POWER

Nano-Structured Electrodes Provide Advantages

10

100

1000

1 10 100 1000 10000

Specific Power (W / kg)

Sep

cific

Ene

rgy

(Wh

/ kg)

Altairnano TechnologyConventional Li-IonLead AcidNiMHNiCd

Altairnano'sDisruptive

Technology

TDT = 100 HourC/100 Rate

TDT = 10 HourC/10 Rate

TDT = 1 HourC Rate

TDT = 6 Min10C Rate

TDT = 36 Sec100C Rate

TDT = Total Discharge Time

11

innovation at workSpecific Impedance

H P P C : 1 0 s e c P u ls e Im p e d a n c e o f n a n o -L i 4 T i 5 O 1 2 C e l l

0

5

1 0

1 5

2 0

2 5

0 2 0 4 0 6 0 8 0 1 0 0S O D , %

Spe

cific

impe

danc

e, o

hms.

cm2

D is c h a rg eR e g e n

t = 3 0 o C

Nano-Structured Electrodes Provide Advantages

12

innovation at workSpecific Power / Specific Energy

H P P C : 1 0 s e c . S p e c if ic P o w e r o f n a n o -L i4 T i5 O 1 2

0 .0

1 .0

2 .0

3 .0

4 .0

5 .0

6 .0

0 2 0 4 0 6 0 8 0 1 0 0

S O D , %

Cel

l spe

cific

pow

er,

kW/k

g

0 .0

1 .5

3 .0

4 .5

6 .0

7 .5

9 .0

Cel

l pow

er d

ensi

ty,

kW/l

D is c h a r g eR e g e n

t = 3 0 o C

High Power Across Wide State of Charge

13

innovation at workPulse Power

H P P C : 1 0 s e c . S p e c i f ic P o w e r o f n a n o -L i 4 T i 5 O 1 2

0

2 0

4 0

6 0

8 0

1 0 0

1 2 0

1 4 0

0 2 0 4 0 6 0 8 0 1 0 0S O D , %

Spe

cific

pow

er,

mW

/cm

2

D is c h a r g eR e g e n

t = 3 0 o C

Wide Power Range Means Smaller Batteries

Long Cycle Life Means Smaller Batteries

14

innovation at workCold Temperature Performance

• Nano-structured Li4Ti5O12 spinel materials

– Allows high cold temp charge / discharge rates

• Nano particles compensate for lower kinetics

• 10 to 20 times higher charge rates at -30°C

– No SEI Layer

• No Li deposition at high rate or cold temps

Nearly Full Battery Utilization at Very Low Temperatures

Enables Applications Unattainable With Other Batteries

15

innovation at workCharge Rate Comparison

0 %

1 0 %

2 0 %

3 0 %

4 0 %

5 0 %

6 0 %

7 0 %

8 0 %

9 0 %

1 0 0 %

1 3 5 7 9C h a rg e R a te

Per

cent

age

of R

T C

apac

ity A lta i r N a n o T i ta n a te S p in e l 1 5 1 0 m A h

A lta i r N a n o T i ta n a te S p in e l 1 5 2 0 m A h

P a n a s o n ic C G R 1 8 6 5 0 H G L i- Io n 1 5 8 4 m A h

P a n a s o n ic C G R 1 8 6 5 0 H G L i- Io n 1 5 7 1 m A h

E n e rS y s (1 ) L e a d A c id 1 5 8 6 M a h

E n e rS y s (2 ) L e a d A c id 1 6 0 0 m A h

N u o n (1 ) N iM h 3 1 6 2 m A h

N u o n (2 ) N iM h 3 3 7 5 m A h

-3 0 °Cx C C h a rg e - - 1 C D is c h a rg e

90% of Room Temperature Capacity in ½ Hour @ -30°C

Other Batteries Can’t Perform

16

innovation at workVoltage Comparison

0

0 .5

1

1 .5

2

2 .5

3

3 .5

0 0 .2 0 .4 0 .6 0 .8 1 1 .2 1 .4 1 .6 1 .8

C a p a c i ty (A h )

Vol

tage

R o o m T e m p

-3 0 °C

-4 0 °C

1 C D is c h a r g e a t In d ic a te d T e m p e ra tu reF o l lo w in g 1 C C h a r g e a t S a m e T e m p e r a tu re

Voltage Stays High at Temperatures of 25, -30 & -40°C

Power is Not Lost at Environmental Extremes

17

innovation at workNanoSafe - 65°C Charge

0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

1 0 0

1 2 3 4 5 6 7 8 9

6 5 °C C h a rg e R a te (C )

% 1

C C

apac

ity C e l l 9 9 0 5C e l l 9 9 0 6

n C C h a rg e - - 1 C D is c h a rg e

Outstanding Performance at Elevated Temperatures

~90 % of Fresh Capacity in Under 7 Minutes – SAFELY!!

18

innovation at workBattery Performance

Tesla 18650 Performance Scaled Altair nLTO Performance

Unmatched Performance at T <0°C or Rates >2C !!!

18650 vs Altairnano NanoSafe BatteriesSpecific Energy vs Discharge Rate vs Temp

19

innovation at workNanoSafe Safety Performance

• Short Circuit – Passed

• Forced Discharge – Passed

• Over Charge – Passed

• Over Discharge – Passed

• Nail Puncture – Passed

• Crush – Passed

• Over Temperature (240°C) Passed

• Drop – Passed

Inherently Safe Batteries

20

innovation at workGraphite Based Li-Ion Batteries

-0.5

0

0.5

1

1.5

2

2.5

3

3.5

4

4.5

0 10 20 30 40 50 60 70

Time (minutes)

Cel

l Vol

tage

0

50

100

150

200

250

300

Cel

l Tem

pera

ture

Cell VoltageCell Temperature

18650 Li-Ion Cell

18650 Li-Ion Cell

Hotbox Test -- Laptop Type Battery Cell

Routinely Explodes - High Temperatures / Other Stresses

21

innovation at workAltairnano n-LTO - Hotbox Test

-0.5

0

0.5

1

1.5

2

2.5

3

0 50 100 150 200

Time (minutes

Cel

l Vol

tage

0

50

100

150

200

250

Cel

l Tem

pera

ture

Cell VoltageCell Temperature

Nano Lithium Titanate Batteries at EXTREME Temperature

NO Smoke – NO Fire – NO Explosion

22

innovation at workCell Phone Battery

Typical Overcharge Result From ANY Graphite Battery

Altair nLTO Based = NO Smoke – NO Fire – NO Explosion

23

innovation at workAltairnano’s NanoSafe Battery

Full Size 12 Volt Battery Module ~ 1,250Wh

Module Contains Internal Controller, Connection to Master

24

innovation at workAltairnano’s Demo EV

SUV Long Range EV

>150 Mile Range, ~10 Minute Recharge Capable

25

innovation at workAltairnano’s Demo EV

12 Volt Modules Base Unit of the Battery Pack

The Pack Resides Under the Car

26

innovation at workAltairnano’s Demo EV

Underbody Battery Pack

Typical Arrangement for Commercial Batteries

27

innovation at workAltairnano’s Demo EV

Under-hood Demo Pack

Experience the Altairnano Difference

28

innovation at workPhoenix Motorcar EV

• ’07 Model – Exclusive to US Market• Employs 33 Modules (35kWh @ 386V)• 136 Mile Range• 10 Minute Recharge• 10 Packs Deliverable by end Q4 ’06

Focus on Fast Charge Infrastructure

ZEV Class 3 Compliant

29

innovation at workSummary

• Disruptive technologies– Nano-structured electrode materials…

• Rapid battery recharge -- in a few minutes

• POWER for numerous applications

• Four (4) times longer battery life (est. 12+ years)

• Inherently safe battery designs

• Green battery design

• Establishing Large nLTO Materials Supply

• Rapid development capabilities

• Looking for early adoption partnerships

Imagine the Possibilities!

Altairnano has…

30

innovation at workContact Info

Dr. Evan House, PhDDirector, Advanced Materials & Power

Systems Business

[email protected]

www.altairnano.com

Realize the Possibilities!


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