Product Guide - household-care.evonik.com · Tomamine Alkali Surfactant 5.0 Tetrapotassium...

Tomamine® Ether Amines Product Guide

2

About UsEvonik Corporation is the world’s largest producer of ether amines and ether amine derivatives with an expertise in cationic and amphoteric surfactants. This market leading position starts from a strong commitment to invest in technology, research and people…and is further developed through our strong relationships with customers.

At the core of these strong relationships is our deeper understanding of our customer’s needs and challenges. Our experienced technical team works hand-to-hand with customers to develop effective solutions. Whether it’s an environmental benefit, improving the performance of an existing product, or making a production process more cost effective, customers are always looking for assistance and ways to do things better than others in their market. We have been providing that edge for over 40 years.

Select product applications:

• Hard surface cleaning • Laundry • Emulsifiers • Warewashing • Foaming agents • Solubilizers • Metalworking • Agricultural additives

Formulating can be a complex process. This product guide offers a good starting point providing an overview of our ethoxylated alcohols and alkoxylated nonionic surfactants. For free samples or technical assistance please email us at [email protected].

32

EThoxylATEd EThEr AminEs

ProPoxylATEd EThEr AminEs

EThEr diAminEs

EThEr AminE sAlTs

EThEr AminE AmPhoTErics

EThEr AminE QuATs

EThEr AminE oxidEs

EThEr niTrilEs

EThEr AminEs

Alcohols: linEAr And BrAnchEd

c3 To c20

The Chemistry

4

General Product Overview

Tomamine® Ether AminesTomamine aliphatic ether amines are a unique class of industrial chemicals with broad range properties. Tomamine PA- and DA- series synthetic ether amines are produced by the reaction of an aliphatic alcohol with acrylonitrile. These unique primary ether amines can be used as additives or building blocks for many other surfactants with broad applications.

Ether Amines (PA-series)Tomamine PA-10l Hexyloxypropyl amineTomamine PA-12Eh 2-Ethylhexyloxypropyl amineTomamine PA-1214 Octyl/decyloxypropyl amineTomamine PA-14 Isodecyloxypropyl amineTomamine PA-1618 Dodecyl/tetradecyloxypropyl amineTomamine PA-17 Isotridecyloxypropyl amineTomamine PA-1816 Tetradecyl/dodecyloxypropyl amineTomamine PA-19 Linear alkyloxypropyl amine

Ether diamines (dA-series)Tomamine dA-1214 Octyl/decyloxypropyl-1,3-diaminopropaneTomamine dA-14 Isodecyloxypropyl-1,3-diaminopropaneTomamine dA-1618 Dodecyl/tetradecyloxypropyl-1, 3-diaminopropaneTomamine dA-17 Isotridecyloxypropyl-1,3-diaminopropane

Ethoxylated Amines (E-series)Tomamine E-14-2 bis-(2-hydroxyethyl) isodecyloxypropylamineTomamine E-14-5 poly (5) oxyethylene isodecyloxypropylamineTomamine E-17-2 bis-(2-hydroxyethyl) isotridecyloxypropylamineTomamine E-17-5 poly (5) oxyethylene isotridecyloxypropylamineTomamine E-T-2 bis-(2-hydroxyethyl) tallow amine (and 5 & 15-mole adducts)Tomamine E-dT-3 N-tallow-poly (3) oxyethylene-1,3-diaminopropane

Quaternary AminesTomamine Q-14-2 75% active isodecyloxypropyl bis-(2-hydroxyethyl) methyl ammonium chloride (Available in propylene glycol)Tomamine Q-17-2 75% active isotridecyloxypropyl bis-(2-hydroxyethyl) methyl ammonium chloride (Available in propylene glycol)Tomamine Q-s-70hG 70% active mono soya methyl ammonium chlorideTomamine Q-dT-hG 50% active tallow diamine diquaternary Tomamine Q-c-15 100% active coco poly (15) oxyethylene methyl ammonium chlorideTomamine Emulsifier Four 75% active dialkyl quaternary designed for emulsification of non-polar hydrophobes, particularly mineral seal oil.Tomamine Emulsifier Four hF A modified high-flash version of Emulsifier Four. The flash point is above 200°FTomadry™ n-4 drying Agent 100% active super-concentrated mineral seal oil-containing drying agent. Made with Emulsifier Four.

54

Tomadry n-3 drying Agent 100% active non oil-containing super-concentrated drying agent. Contains ethylene glycol monobutyl ether.Tomadry n-5c drying Agent 100% active non oil-containing drying agent. Designed for quick water break and water beading.Tomadry n-7 drying Agent 100% active non oil-containing super-concentrated drying agent. Does not contain ethylene glycol monobutyl ether. Tomadry n-8 drying Agent A high-flash version of Tomadry N-4. Made with Emulsifier Four HF.Tomamine Emulsion c-340 A 18% active cationic emulsion of carnauba wax. Used for “hot carnauba” drying agents.Tomadry dAB drying Additive A 100% active wax additive designed for formulation into a wide variety of transportation cleaning applications.Tomamine Emulsifier 300 A balanced emulsifier for Mineral Seal Oil (MSO) and other hydrophobes in water used to optimize drying efficiency for vehicle care products.Tomamine Emulsifier 300hF A high-flash version of Tomamine Emulsifier 300.

Amine oxides (Ao-series)Tomamine Ao-14-2 50% active bis-(2-hydroxyethyl) isodecyloxypropylamine oxideTomamine Ao-728 50% active linear alkyloxypropylamine oxideTomamine Ao-405 50% active low-foam alkyloxypropylamine oxideTomamine Ao-455 50% active low-foam alkyloxypropylamine oxide

Amphoteric surfactants Tomamine Amphoteric l 37% active; high foaming hydrotropeTomamine Amphoteric sc 35% active; high foaming hydrotropeTomamine Amphoteric 16 33% active biodegradable; high foaming, hydrotroping surfactantTomamine Amphoteric lh 30% active; moderate foaming hydrotropeTomamine Alkali surfactant 35% active; moderate foaming hydrotropeTomamine Amphoteric 400 50% active; low foaming hydrotropeTomamine Amphoteric 12 35% active biodegradable; low foaming, hydrotroping surfactant

Acid Additives & inhibitorsTomamine Acid Foamer 100% active foaming additive for organic and inorganic acids.Tomamine Acid Thickener 100% active thickener for organic and inorganic acids.Tomamine inhibitor 60s Acid inhibitor for hydrochloric acid and other acids.Tomamine inhibitor 60Q Acid inhibitor for many mineral acids.

Asphalt & coal Tar sealant AdditivesTomamine PA-14 Acetate A patented 100% active cationic surfactant designed to wet various clays, fillers, and fibers resulting in a stable and desirable end-use viscosity for asphalt coatings and sealants.

Tomadyne surfactantsTomadyne 100 surfactant 83% active; moderate-foaming degreaserTomadyne 102 surfactant 83% active; moderate-foaming, non-corrosive as classified by the DOT

6

PA-Series Ether AminesThe Tomamine PA-series synthetic ether amines are produced by the reaction of an aliphatic alcohol with acrylonitrile. These unique primary ether amines can be used as additives or building blocks for many other surfactants with broad applications. Ether amines have excellent low temperature liquidity. Some of the more popular uses for the Tomamine PA-series products include: corrosion inhibitors, lubrication additives, fuel additives, and mineral flotation collectors.

r-o-ch2ch2ch2nh2

Product r Equals description

Tomamine PA-10l C6H13 Hexyloxypropyl amine

Tomamine PA-12Eh Branched C8H17 2-Ethylhexyloxypropyl amine

Tomamine PA-1214 C8H17/C10H21 Octyl/decyloxypropyl amine

Tomamine PA-14 Branched C10H21 Isodecyloxypropyl amine

Tomamine PA-1618 C12H25/C14H29 Dodecy/tetradecyloxypropyl amine

Tomamine PA-17 Branched C13H27 Isotridecyloxypropyl amine

Tomamine PA-1816 C14H29/C12H25 Tetradecyl/dodecyloxypropyl amine

Tomamine PA-19 C12H25/C15H31 Linear alkyloxypropyl amine

TyPicAl ProPErTiEs

TomAminE PA-SEriES EThEr AminES

PA-10l PA-12Eh PA-1214 PA-14 PA-1618 PA-17 PA-1816 PA-19

Molecular Wt. 165 200 207 225 260 265 265 272

Min. amine value 315 280 260 243 200 200 200 195

Min. mole% primary amine 96 96 96 96 96 96 96 96

Water content, %max 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5

Flash point, °F 183 >200 >200 >200 >200 >200 >200 >200

SpG 25°C 0.84 0.85 0.85 0.85 0.85 0.85 0.85 0.85

Gardner color, max 5 5 5 5 5 5 5 5

Pour point, °F -30 -30 20 -50 50 -30 50 50

Physical form @ 25°C Liquid Liquid Liquid Liquid Liquid Liquid Paste Paste

76

DA-Series Ether AminesThe Tomamine DA-series synthetic ether diamines are produced by the reaction of an aliphatic alcohol with two moles of acrylonitrile. Like the Tomamine PA-series, these unique ether diamines can be used as additives or building blocks for many other surfactants with broad applications use. The Tomamine DA-series ether diamines have excellent low temperature liquidity.

hr-o-ch2ch2ch2n

ch2ch2ch2nh2


Tomamine dA-1214 C8H17/C10H21 Octyl/decyloxypropyl-1,3-diaminopropane

Tomamine dA-14 Branched C10H21 Isodecyloxypropyl-1,3-diaminopropane

Tomamine dA-1618 C12H25/C14H29 Dodecyl/tetradecyloxypropyl-1, 3-diaminopropane

Tomamine dA-17 Branched C13H27 Isotridecyloxypropyl-1,3-diaminopropane

TyPicAl ProPErTiEs

TomAminE DA-SEriES EThEr AminES

dA-1214 dA-14 dA-1618 dA-17

Molecular Wt. 290 295 340 330

Min. amine value 385 375 330 325

Min. mole% primary amine 49 49 49 49

Water content, %max 0.5 0.5 0.5 0.5

Flash point, °F >200 >200 >200 >200

SpG 25°C 0.87 0.87 0.87 0.87

Gardner color, max 5 5 5 5

Pour point, °F 20 -50 60 -30

Physical form @ 25°C Liquid Liquid Paste Liquid

8

Ethoxylated AminesEvonik produces a wide range of ethoxylated ether amines and ethoxylated fatty amines. These amines have been reacted with various amounts of ethylene oxide to modify emulsification, surface tension, solubility and cationic strength. Some of the more popular uses of the Tomamine E-Series products include: acid thickening, microemulsification, detergent boosting, and textile processing aids. The Tomamine E-Series ether amines are represented by the formula above, where r is the alkyl radical and n is the total number of moles of ethylene oxide.


Tomamine E-14-2 Branched C10H21 bis-(2-hydroxyethyl) isodecyloxypropylamine

Tomamine E-14-5 Branched C10H21 poly (5) oxyethylene isodecyloxypropylamine

Tomamine E-17-2 Branched C13H27 bis-(2-hydroxyethyl) isotridecyloxypropylamine

Tomamine E-17-5 Branched C13H27 poly (5) oxyethylene isotridecyloxypropylamine

Tomamine E-T-2 Stearic/Oleic bis-(2-hydroxyethyl) tallow amine

TyPicAl ProPErTiEs

TomAminE EThoxyLATED AminES

E-14-2 E-14-5 E-17-2 E-17-5 E-T-2

Molecular Wt. 310 445 345 485 360

Min. amine value 175 123 155 112 156

% tertiary amine 97 100 97 100 97

Flash point, °F >200 >200 >200 >200 >200

SpG 25°C 0.94 0.99 0.94 0.99 0.91

Gardner color, max 9 11 9 11 16

Pour point, °F 20 20 20 20 50

Physical form @ 25°C Liquid Liquid Liquid Liquid Paste

Physical form @ 25°C Liquid Liquid Liquid Paste Paste

(ch2ch2o)xh

r-o-ch2ch2ch2n

(ch2ch2o)n-xh

98

Tomamine E-series Ethoxylated Amines

The Tomamine E-Series amines have a broad range of applications. Some of the suggested uses include:

• Degreasers• Anti-static agents• Textile processing aids • Cationic emulsification• Detergent boosters • Intermediates for the manufacture of quaternaries and amine oxides

Premium laundry detergent

componentWeight

%

Water 79.0

Tomamine E-14-2 Surfactant 3.0

Tomadol® 91-8 Surfactant 7.0

Tomamine Alkali Surfactant 5.0

Tetrapotassium pyrophosphate 4.0

Sodium metasilicate pentahydrate 2.0

Total 100.0

Ternary General Purpose cleaner/detergent

componentWeight

%


Tomamine Q-17-2 PG Surfactant 25.0

Tomadol 91-6 Surfactant 50.0

Total 100.0

Dilute 1 part of this blend with 99 parts of water. Lab studies have shown that the ternary blend is extremely effective without builders at high dilutions for degreasing hydrophobic paraffin-containing non-polar soils.

Terpene microemulsion degreaser

componentWeight

%

Dipentene 122 5.0



Tomamine Alkali Surfactant 0.8

Water 87.0

Total 100.0

10

Quarternary AminesEvonik quaternary amines are based on the reaction of aliphatic tertiary amines with methyl chloride using isopropanol as a diluent. The Tomamine Q-Series ether amine-based quats are represented by the formula, on page 11, where r is the alkyl radical and n is the total number of moles of ethylene oxide.

Tomamine Q-14-2 75% active isodecyloxypropyl bis-(2-hydroxy-ethyl) methyl ammonium chloride (Available in propylene glycol as Q-14-2 PG)

Tomamine Q-17-2 75% active isotridecyloxypropyl bis-(2-hydroxyethyl) methyl ammonium chloride (Available in propylene glycol as Q-17-2 PG)

Tomamine Q-s-70hG 70% active mono soya methyl ammonium chloride in hexylene glycol

Tomamine Q-dT-hG 70% active tallow diamine diquaternary in hexylene glycol

Tomamine Q-c-15 100% active coco poly (15) oxyethylene methyl ammonium chloride

Tomamine Emulsifier Four 75% active dialkyl quaternary designed for emulsification of non-polar hydrophobes, particularly mineral seal oil.

Tomamine Emulsifier Four hF 75% active high flash version of Emulsifier Four. The flash point is above 200°F.

Tomamine Emulsifier 300 Balanced emulsifier for MSO and other hydrophobes in water used to optimize drying efficiency for vehicle care products.

Tomamine Emulsifier 300hF A high-flash version of Tomamine Emulsifier 300.

TyPicAl ProPErTiEs

TomAminE QuArTErnAry AminES

Q-14-2 Q-17-2 Q-s-70hG Q-dT-hG Q-c-15

pH, 5% solution 6-9 6-9 6-9 6-8 6-9

Molecular Wt. 370 410 410 525 915

Flash Point, °F 75 75 >200 >200 >200

SpG 25°C 0.97 0.97 0.97 0.98 1.06

Gardner color, max 8 8 12 14 11

Pour point, °F 0 0 40 20 20

Physical form @ 25°C Liquid Liquid Liquid Liquid Liquid

(ch2ch2o)xh

r-o-ch2ch2ch2nB (ch2ch2o)n-xh clv

ch3

TyPicAl ProPErTiEsTomAminE EmuSifiEr

E-4 E-4hF 300 300hF

lb/gal 8.0 8.3 – –

Active, % 75 75 – –

Diluent Ethylene Glycol Isopropanol Hexylene Glycol – –

Color Amber Amber – –

Physical Form Liquid Liquid – –

1110

Tomamine Q-series Quarternary Amines

The Tomamine Q-Series amines have broad range application. Some of the suggested uses include:

• Corrosion inhibitors• Anti-static agents• Surfactants in non-butyl cleaning systems• Cationic emulsification• Detergent boosters

hard surface cleaning PerformanceNon-Butyl/Low VOC Formula

vs. Other General Purpose Cleaners 1.0% active, 150 ppm hardness @ 22°C

component sxs

Formulations Evaluated: Tomamine Q-14-2/Tomamine Ao-14-2

10% Butyl

Water 83.05% 88.00% 78.75%

Tomamine Q-14-2 Amine – 1.00 –

Tomamine AO-14-2 Amine – 1.00 –

Tomadol 91-6 Surfactant 3.25 2.00 3.25

Sodium carbonate 2.00 2.00 2.00

Sodium metasilicate (5H2O)

4.00 4.00 4.00

EDTA Tetrasodium salt (39%)

1.00 1.00 1.00

Tetrapotassium pyrophosphate 1.00 1.00 1.00

Sodium xylene sulfonate, 40% 5.70 – –

Ethylene glycol butyl ether – – 10.00

Total 100.00% 100.00% 100.00%

Tomamine E-14-2/Q-17-2/Tomadol 900

(1:1:2 ratio, 0.1%)

d-Limonene, 0.1%(microemulsion)

d-Limonene, 1.0%(microemulsion)

d-Limonene,100% (solvent)

% transmittance0 20 40 60 10080

10% Butyl blend

Tomamine Q-14-2/AO-14-2 blend

SXS blend

Water

% Soil Removal0 20 40 60 80

Gardner scrub cleaning Performance

initial Foam height vs. Foam height after 5 minutes 0.1% actives; 0 ppm hardness @ 25°C pH 7.0

ross-miles foam height

immersion cleaning PerformanceTernary General Purpose Cleaner/Detergent vs. d-Limonene

0.1% active, 150 ppm hardness @ 12°C Soil = lithium grease in motor oil

Foam Height (cm)0 5 10 15

Q-C-15

Q-DT-HG

Q-S-70HG

Q-17-2

Q-14-2Initial5 Min.

12

Amphoteric SurfactantsEvonik amphoteric surfactants are designed for use in alkaline and acid cleaners. They offer exceptional cou-pling stability and wetting in a wide range of formulations that may contain other anionic, nonionic, and cationic sur-factants. Scrub tests indicate improved detergency in for-mulations containing Tomamine Amphoteric surfactants compared to formulations containing generic hydrotropes such as sodium xylene sulfonate.

TyPicAl ProPErTiEs

TomAminE AmPhoTEric SurfAcTAnTS

12 400Alkali

surfactant lh 16 400 sc l

SpG 25°C 1.11 1.09 1.05 1.05 1.04 1.09 1.05 1.04

Active, % 35 50 35 30 33 50 35 37

Gardner color, max 7 5 7 6 7 5 7 6

Flash point, °F >212 >212 >212 >212 >212 >212 >212 >212

Pour point, °F 26 30 30 30 30 30 30 30

pH, 5.0% solution 6-9 6-9 6-9 6-9 6-9 6-9 5-9 5-8

CMC,% (critical micelle conc.) 0.02 2.0 0.3 0.014 0.3 2.0 0.013 0.01

Surface tension @ 0.1% (dynes/cm) in 2% NaOH 26 62 37 30 38 62 30 33

o

ch2ch2c — ovnaB

r-o-ch2ch2ch2n

ch2ch2c — oh

o

Tomamine Amphoteric 12 35% active biodegradable; low foaming, hydrotroping surfactant

Tomamine Amphoteric 400 50% active; low foaming hydrotrope

Tomamine Alkali surfactant 35% active; moderate foaming hydrotrope

Tomamine Amphoteric lh 30% active; moderate foaming hydrotrope

Tomamine Amphoteric 16 33% active biodegradable; high foaming, hydrotroping surfactant

Tomamine Amphoteric sc 35% active; high foaming hydrotrope

Tomamine Amphoteric l 37% active; high foaming hydrotrope

% hydrotrope required to couple an Alkaline Formulation

component Weight %

NP-9 2.0

KOH, 45% 20.0

Na Silicate 3.22/1 20.0

Na Gluconate 2.0

Hydrotrope q.s.

Water balance

1312

Tomamine Amphoteric Surfactants

Some of the suggested uses include:

• High & low foam alkaline cleaners• Foamers for acid cleaners• Hand & laundry soaps• Mechanical foaming systems• Shampoos & personal care products

% Soil Removed0 10 20 30 60 7040 50

TomamineAmphoteric 16

TomamineAmphoteric-LH

CocoimidazolineDicarboxylate

TomamineAlkali Surfactant

ImmidzolineCarboxylate

Cocoampho-dipropionate

Phosphate Ester

SXS


TomamineAmphoteric-SC

hard surface cleaning Performance2% Hydrotrope, 2% Soda Ash, 1.5% Na2SiO3 • 5H2O,

1% Baypure CX-100

Foam Height (cm)0 2 4 6 8 10 12 14 16 18 20





TomamineAmphoteric-L

NP-9

TomamineAlkali Surf

TomamineAmphoteric-400

Initial5 Min.

initial Foam height vs. Foam height After 5 minutes0.1% actives; 150 ppm hardness @ 25°C


% Hydrotrope Required0 2 4 6 148 10 12







SXS

% NaOH0 5 10 15 30 3520 25

TomamineAmphoteric-L







Tomamine Amphoterics caustic solubility

1.0% active, 0 ppm hardness @ 25°C

14

Ether Amine OxidesEvonik ether amine oxides are excellent detergents, foam boosters and foam stabilizers. They are used in detergent formulations to provide grease emulsification and soil suspension. Amine oxides tend to act non-ionically in neutral and alkaline ph. Tomamine Ether amine oxides are represented by the formula where r is the alkyl radical and n is the total number of moles of alkylene oxide.

(ch2ch2o)xh

r-o-ch2ch2ch2n o

(ch2ch2o)n-xh

TyPicAl ProPErTiEs

TomAminE EThEr AminE oxiDES

Ao-14-2 Ao-728 Ao-405 Ao-455

SpG @ 20°C 0.95 0.95 1.01 1.03

Active, % 50 50 50 50

Gardner Color, max. 3 3 5 5

Flash point, °F 78 78 >212 >212

Pour Point, °F 30 30 32 32

Physical form Liquid Liquid Liquid Liquid

Surface Tension @ 0.1% (dynes/cm) 28 30 31 34

Tomamine Ao-14-2 50% active bis-(2-hydroxyethyl) isodecyl-oxypropylamine oxide

Tomamine Ao-728 50% active linear alkyloxypropylamine oxide

Tomamine Ao-405 50% active low-foam alkyloxypropylamine oxide

Tomamine Ao-455 50% active low-foam alkyloxypropylamine oxide

1514

Tomamine Ether Amine oxides

The Tomamine AO-Series has a broad range of applications. Some of the suggested uses include:

• Hard surface cleaning• Foam stabilization• Surfactants in non-butyl cleaning systems• Grease emulsification• Detergent Boosters

suGGEsTEd FormulATionspray And Wipe hard surface cleaner

component Weight %

Water 96.5

Sodium Tripolyphosphate 1.0

Tomadol 900 1.0

Tomamine AO-14-2 1.5

TomamineAO-728

TomamineAO-14-2

TomamineAO-455

TomamineAO-405

Foam Height (cm)0 2 4 6 8 10 12

Initial5 Min.

initial Foam height vs. Foam height After 5 minutes0.06% actives; 150 ppm hardness @ 22°C, pH 7.0


Gardner scrub cleaning Performance

hard surface cleaning PerformanceNon-Butyl/Low VOC Formula

vs. Other General Purpose Cleaners 1.0% active, 150 ppm hardness @ 22°C

component sxs

Formulations Evaluated: Tomamine Q-14-2/Tomamine Ao-14-2

10% Butyl

Water 83.05% 88.00% 78.75%

Tomamine Q-14-2 Surfactant

– 1.00 –

Tomamine AO-14-2 Surfactant – 1.00 –

Tomadol 91-6 Surfactant 3.25 2.00 3.25

Sodium carbonate 2.00 2.00 2.00

Sodium metasilicate (5H2O)

4.00 4.00 4.00

EDTA Tetrasodium salt (39%)

1.00 1.00 1.00

Tetrapotassium pyrophosphate 1.00 1.00 1.00

Sodium xylene sulfonate, 40% 5.70 – –

Ethylene glycol butyl ether – – 10.00

Total 100.00% 100.00% 100.00%

10% Butyl blend

Tomamine Q-14-2/AO-14-2 blend

SXS blend

Water

% Soil Removal0 20 40 60 80

16

Tomadry n-4 drying Agent 100% active super-concentrated mineral seal oil-containing drying agent. Made with Emulsifier Four.

Tomadry n-3 drying Agent 100% active non-oil containing super-concentrated drying agent. Contains ethylene glycol monobutyl ether. More biodegradable than mineral seal oil spraywax.

Tomadry n-5c drying Agent 100% active non-oil containing drying agent. Designed for quick water break and water beading. Fast-acting and biodegradable.

Tomadry n-7 drying Agent 100% active non-oil containing super-concentrated drying agent. Does not contain ethylene glycol monobutyl ether. More biodegradable than mineral seal oil spraywax.

Tomadry n-8 drying Agent 100% active non-flammable drying agent. Made with Emulsifier Four HF.

Tomamine Emulsion c-340 18% active cationic emulsion of carnauba wax.

Tomadry dAB drying Additive 100% active wax additive designed for formulation into a wide variety of transportation cleaning applications to improve shine and protection.

TyPicAl ProPErTiEs

TomADry Dry AgEnTTomAminE EmuLSion

n-4 n-3 n-5c n-7 n-8 dAB c-340

lb/gal 8.0 7.8 7.2 7.8 8.3 – 8.6

Active, % None None None None None – Water

Diluent Ethylene Glycol Amber Amber Amber Amber Amber – Black

Color Liquid Liquid Liquid Liquid Liquid – Liquid

Physical Form Liquid Paste Liquid Liquid Liquid Liquid Liquid

Tomadry Drying Agents

The Tomadry N-series are fully formulated super concentrates. Simply dilute 39 parts of concentrate with 61 parts of water. The resulting “39% active” spraywax microemulsion is usually diluted 5 gallons to 50 gallons with water prior to use. Apply 4-6 ounces of the dilute spray wax per vehicle via a spray arch, wand or other delivery system.

The Tomamine Emulsifier Four, and Emulsifier Four HF, are dialkyl quaternary amine emulsifiers designed for formulating microemulsion concentrates.

Charge the mineral seal oil, Tomamine Emulsifier, and ethylene glycol monobutyl ether and mix until clear. Add the water slowly while mixing. When the water has been added, mix about 5 more minutes. Add dye & fragrance if desired. The carwash operator would use 1/3 to 1/2 oz. per car.

Charge the Emulsifier 300, mineral seal oil, ethylene glycol monobutyl ether and Tomadry DAB and mix until clear. Add the water slowly while mixing. When the water has been added, mix about 5 more minutes. Add dye & fragrance if desired. The carwash operator would use 3/4 to 1 oz. per car.

suGGEsTEd FormulATiondrying Agent concentrate

component Weight %

Mineral Seal Oil 12.1

Tomamine Emulsifier 300 15.5

Ethylene glycol monobutyl ether 2.4

Water (cold, tap) 70.0

Total 100.0

suGGEsTEd FormulATionon-line Total Body Protectant

component Weight %

Tomamine Emulsifier 300 11.9

Mineral Seal Oil 9.3

Ethylene glycol monobutyl ether 1.8

Tomadry DAB 5.0

Water (cold, tap) 72.0

Total 100.0

1716

suGGEsTEd FormulATion

Tomamine Acid Foamer

component hF Acid nh4 Bifluoride

Water 70.0% 64.0%

Tomamine Acid Foamer 3.0 3.0

95% Sulfuric Acid 10.0 20.0

70% Hydrofluoric Acid 17.0 –

Ammonium Bifluoride – 13.0

Total 100.0% 100.0%

suGGEsTEd FormulATion

Acid Thickener

component Formulation #1 Formulation #2

Water 67.9% 77.7%

75% Phosphoric Acid 3.0 12.7

Tomamine Acid Thickener 4.0 4.0

Tomadol 91-8 Surfactant 0.5 0.5

Salt (NaCl) – 5.0

37% Hydrochloric Acid 24.5 –

Perfume 0.1 0.10

Total 100.0% 100.0%

Formulation #1 Viscosity @ 25°C: 1750 cPs Formulation #2 Viscosity @ 25°C: 1800 cPs

Acid Additives and InhibitorsEvonik Acid foamer and Acid Thickener are designed to foam and thicken most inorganic and organic acids. in addition to the acid additives, Evonik offers Tomamine inhibitors 60Q and 60S for corrosion protection of mild steel and stainless steel when exposed to inorganic and organic acids.

Tomamine Acid Foamer A cationic surfactant designed to provide dense, stable foam in strong acids such as hydrochloric, hydrofluoric and sulfuric acids. Acid Foamer provides 99% inhibition of HCl or H2SO4 on stainless steel.

Tomamine Acid Thickener A cationic surfactant designed to thicken a variety of acids.

Tomamine inhibitor 60Q A versatile and effective corrosion inhibitor for use in cleaning applications. It is designed to not darken in most acid solutions allowing for a lighter-colored acid-based product.

Tomamine inhibitor 60s A effective, less expensive version of Inhibitor 60Q. It can be used in acid cleaning applications where the acid color is not critical.

TyPicAl ProPErTiEs

TomAminE AciD ADDiTivES AnD inhibiTorS

Acid Foamer

Acid Thickener

inhibitor 60Q

inhibitor 60s

SpG @ 25°C 1.06 0.91 1.02 1.04

Active, % 100 100 90 90

Gardner color, max 13 13 15 17

Flash Point, °F >212 >212 78 78

Physical Form @ 25°C Liquid Paste Liquid Liquid

Acid Thickener with 9.0% hcl; 2.0% Phosphoric Acid

use Level vs. viscosity

1000

0

2000

3000

4000

5000

6000

Acid Thickener (Wt%)

Visc

oity

(cps

)

0 1 2 43

18

Tomadyne™ Heavy-Duty DegreasersTomadyne surfactants are designed for use in hard surface and industrial cleaning formulations including transportation cleaners for cars, trucks, buses, aircraft, as well as metal cleaning detergents for soak tanks and high-pressure spray systems.

TyPicAl ProPErTiEsTomadyne 100

surfactantTomadyne 102

surfactant

Color, Gardner 3 3

Active, % 83 83

pH, 5% in Water 5.5 6.0

Pour Point, °F 25 21

Cloud Point @ 1%,°C 65 60

SpG 25°C 0.99 1.00

Flash Point, °F >200 >200

Tomadyne 100 Surfactant

Designed to be affordable and efficient additives for use in water-based degreasing and hard surface cleaning applications. Both products are moderate-foaming surfactants. Tomadyne 100 Surfactant is classified as corrosive by the DOT while Tomadyne 102 Surfactant is classified as non-corrosive.

Tomadyne 102 Surfactant

Tomakleen TFr ii Surfactant Designed to be affordable and efficient.

Reformulating aid for removing oxygenated solvents.

Tomakleen G12

heavy-duty degreasers and hard surface cleaners

inGrEdiEnTmild

FormulaAlkaline Formula

Acid Formula

Tomadyne 100 or 102 Surfactant 9.0% 9.0% 9.0%

Tetrapotassium Pyrophosphate 8.0 0.0 0.0

50% Sodium Hydroxide 0.0 10.0 0.075% Phosphoric Acid 0.0 0.0 20.0Tomamine Alkali Surfactant 0.2 5.5 0.0Sodium Metasilicate Pentahydrate 0.0 4.0 0.0

Water 82.8 71.5 71.0

FormulATion ProPErTiEs

pH 9.8 14.0 1.3SpG 25°C 1.07 1.08 1.10

1918

Global Regulatory Listings

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Tomadry dAB drying Additive + + +Tomadry n-3 drying Agent + + + + +Tomadry n-4 drying Agent + + + + +Tomadry n-5c drying Agent + + + + + +Tomadry n-7 drying Agent + + +Tomadry n-8 drying Agent + + + + + + +Tomadyne 100 + + + +Tomadyne 102 + + + + + + +Tomadyne 104 + + + + + +Tomamine Acid Foamer + + + + + + +Tomamine Acid Thickener + + + + + + + + + + +Tomamine Alkali surfactant + + + + + + +Tomamine Amphoteric 12 + + + +Tomamine Amphoteric 16 + + +Tomamine Amphoteric 400 + + + + + + +Tomamine Amphoteric l + + + + + + +Tomamine Amphoteric lh +Tomamine Amphoteric sc + + + +Tomamine Anticake 17 + + + + + + + +Tomamine Ao-14-2 + + + + + + + + + +Tomamine Ao-405 + +Tomamine Ao-455 + + + +Tomamine Ao-728 + + +Tomamine dA-1214 + +Tomamine dA-14 + + +Tomamine dA-1618 + + +Tomamine dA-17 + + + + + + + + +Tomamine E-14-2 + + + + +Tomamine E-14-5 + + + + +Tomamine E-17-2 + +Tomamine E-17-5 + +Tomamine E-19-2 + + + + Tomamine E-c-2 + + + + + + + + + +Tomamine E-c-15 + + + + + + + + + +Tomamine E-dT-3 + + + + + + + +Tomamine Emulsifier 300 + + + + + + +Tomamine Emulsifier 300hF + + + + + + +Tomamine Emulsifier Four + + + + +Tomamine Emulsifier Four hF + + + +Tomamine Emulsion c340 + + + +Tomamine E-T-2 + + + + + + + +Tomamine inhibitor 60Q + + + + + + +Tomamine inhibitor 60s + + + + + + + +Tomamine PA-10l** + +Tomamine PA-1214 + + +Tomamine PA-12Eh + + + + + +Tomamine PA-14 Acetate + + + + + + + + + +Tomamine PA-1618 + + + +Tomamine PA-17 + + + + + + + + +Tomamine PA-1816 + +Tomamine PA-19 + + + +Tomamine Q-14-2 + + + + + +Tomamine Q-17-2 + + + + +Tomamine Q-c-15 + + + + + + + + + +Tomamine Q-dT-hG + + + + + + +Tomamine Q-s-70hG + + + +Tomamine Q-sT-50 + + + + + + + + + + +

*Biodegradable according to Annex III of Regulation (EC) No. 648/2004 **Not sold in the USA

©Evonik Corporation, 2017 120-06-067-US-AUG17 E

Evonik corPorATion 7201 Hamilton Blvd.Allentown, PA 181951 800 345-3148Outside U.S. and Canada 1 610 481-6799 For Technical information and support:Americas: [email protected]: [email protected] For samples:Americas: [email protected]: [email protected]: [email protected] For customer service:US / [email protected] [email protected] [email protected] AsiaPMD-Asia Customer Service: [email protected] PMGP (Korea): [email protected] EMEA:[email protected]

The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto.

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Product Guide - household-care.evonik.com · Tomamine Alkali Surfactant 5.0 Tetrapotassium...

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