Product Name: ABC Dry Chemical Fire Extinguishant · Page 2 of 8 Pages ABC Silicone oil NR*** NR NR...

$Page 1: Product Name: ABC Dry Chemical Fire Extinguishant · Page 2 of 8 Pages ABC Silicone oil NR*** NR NR Calcium carbonate PNOC Total dust, 15 mg/m3 Respirable fraction, 5 mg/m3 PNOC Total$
Page 1 of 8 Pages ABC

MATERIAL SAFETY DATA SHEET

Section 1. Chemical product and company identification

Product Name: ABC Dry Chemical Fire Extinguishant Synonym: Multi-purpose Dry Chemical (CH550, F15, F18) Manufacturer: AMEREX CORPORATION Internet Address: www.amerex-fire.com Address: 7595 Gadsden Highway P.O. Box 81 Trussville, AL 35173-0081 Telephone: (205) 655-3271 Emergency Contacts: Chemtrec 1(800) 424-9300 or (703) 527–3887 Revised: January, 2015

Section 2. Hazard identification and emergency overview

Emergency overview: Light yellow, fine solid powder, odorless. Adverse health effects and symptoms: Irritating to the respiratory system, eyes and skin. Symptoms may include coughing, shortness of breath, and irritation of the lungs, eyes, and skin. Ingestion, although unlikely, may cause cramps, nausea and diarrhea. Exposure guidelines:

Ingredients OSHA PEL**** ACGIH TLV DFG MAK * Mono-ammonium phosphate PNOC**

Total dust, 15 mg/m3

Respirable fraction, 5 mg/m3

PNOC Total dust, 10 mg/m

3



3

Respirable fraction, 1.5 mg/m

3

Ammonium sulphate PNOC Total dust, 15 mg/m

3



3



3


3

Mica 6 mg/m3 3 mg/m3 NR

Fullers Earth PNOC Total dust, 15 mg/m

3



3



3


3

http://www.amerex-fire.com/


Silicone oil

NR*** NR NR

Calcium carbonate PNOC Total dust, 15 mg/m

3



3


-------

Amorphous silica

143 mg/m3

80 mg/m3

or % SiO2 10 mg/m

3 4 mg/m

3

Yellow 14 pigment NR NR NR

*German regulatory limits **PNOC = Particulates not otherwise classified (ACGIH) also known as Particulates not otherwise regulated (OSHA) *** NR = Not Regulated. All values are 8 hour time weighted average concentrations. **** Total dust PEL for Washington state= 10mg/ m

3 for PNOC

Hazard symbols: WHMIS (Canadian workplace hazardous materials identification system D2B Product may irritate eyes, skin, or mucous membranes

Section 3. Composition/information on ingredients

Name/Compound Weight % CAS # Mono-ammonium phosphate and Ammonium sulphate

>94

7722-76-1 7783-20-2

Fullers Earth magnesium aluminum silicate-

<3

8031-18-3

Mica potassium aluminum silicate

1-2

12001-26-2

Silicone oil methyl hydrogen polysiloxane

<1

63148-57-2

Calcium carbonate

<1

1317-65-3

Amorphous silica precipitated synthetic zeolite

<1

112926-00-8

Yellow 14 pigment – di-azo dye

<1

5468-75-7

Section 4. First Aid Measures

Eye Exposure: Irrigate eyes with water and repeat until pain free. Seek medical attention if irritation develops or if vision changes occur.


Skin Exposure: In case of contact, wash with plenty of soap and water. Seek medical attention if irritation develops. Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if irritation persists. Ingestion: If victim is conscious and alert, give 2-3 glasses of water to drink and do not induce vomiting. Seek immediate medical attention. Do not leave victim unattended. To prevent aspiration of swallowed product, lay victim on side with head lower than waist. If vomiting occurs and the victim is conscious, give water to further dilute the chemical. Medical conditions possibly aggravated by exposure: Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema, or bronchitis. Skin contact may aggravate existing skin disease. Chronic overexposure may cause pneumoconiosis (“dusty lung” disease).

Section 5. Fire fighting measures

Extinguishing media: non combustible and non flammable – product is an extinguishing agent. Unusual fire/explosion hazards: in a fire this material may decompose, releasing oxides of sulfur and carbon (see Section 10). Insensitive to mechanical impact or static discharge. HMIS Hazard Ranking: health = 1, flammability = 0, reactivity = 0, personal protective equipment: ½ mask APR w/HEPA cartridges (see Section 8).

Section 6. Accidental release measures

Clean up released material using vacuum or wet sweep and shovel to minimize generation of dust. Wear appropriate respiratory protection. Bag and drum for disposal. If product is used and/or contaminated, use PPE and containment appropriate to the nature of the mixture. Prevent material from entering waterways.


Section 7. Handling and storage

Avoid skin, eye, or respiratory exposure. Use appropriate PPE when handling or maintaining equipment, and wash thoroughly after handling (see Section 8). Keep product in original container or extinguisher. Contents may be under pressure – inspect for extinguisher rust periodically to insure container integrity. Do not mix with other extinguishing agents.

Section 8. Exposure controls/ personal protection

During the application of this product against fires, exhaust gases and the products of incomplete combustion (PICs) are the principal respiratory hazards. In the manufacture of extinguishers, automated systems and point source ventilation controls sufficiently minimize respiratory exposure. Employers and employees must use their collective judgment in determining occupational settings where the use of a dust mask or air purifying respirator is prudent. The need for respiratory protection is not likely for short-term use in well ventilated areas.

Respiratory protection: use N95 dust mask or air-purifying respirator (APR) with high efficiency particulate air (HEPA) filters. Eye protection: wear chemical goggles. Skin protection: use nitrile, latex, or similar gloves and coveralls. Good personal hygiene practices essential, such as avoiding food, tobacco products, or other hand-to-mouth contact when handling. Wash thoroughly after handling.

Section 9. Physical and chemical properties

Appearance: yellow powder, finely divided odorless solid. Specific gravity: ~ .88 in aerated condition Solubility: product is coated-not immediately soluble in water Non –flammable Flash point: none Vapor pressure: < 1 mm Hg pH: approximately 4-5 Boiling point: not applicable No explosive or oxidizing properties


Section 10. Stability and reactivity

Stability: stable Incompatibles: strong alkalis (bases), magnesium, strong oxidizers such as calcium hypochlorite (pool chlorine) and isocyanuric acids. Decomposition products: heat of fire may release carbon monoxide, carbon dioxide, and sulfur dioxide. Oxides of phosphorous and ammonia reported. Possibility of hazardous reactions: Slight. See incompatibilities above.

Section 11. Toxicological information

Acute toxicity: Mono ammonium phosphate LD50 (rat): > 1000mg/kg body weight Ammonium sulfate LD50 (rat): 2840 mg/kg body weight

Target organs in man: respiratory system, eyes, skin. This product is an irritant to epithelial tissue, and may aggravate dermatitis. No information was found indicating the product causes sensitization.

Chronic toxicity: Pneumoconiosis, or “dusty lung” disease, may result from chronic

exposure to any dust. Reproductive toxicity: This product’s ingredients are not known to have reproductive or

teratogenic effects.

Section 12. Ecological information

Ecotoxicity: negative effects unknown. Provides nutrient nitrogen and

phosphorus to plant life. Persistence/ Degradability: degrades rapidly in humid/wet environment. Bioaccummulation: extent unknown. Mobility in soil: slow evaporation rate; water soluble, may leach to groundwater.


Section 13. Disposal considerations

This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of according to state or local laws, which may be more restrictive than federal laws or regulations. Used product may be altered or contaminated, creating different disposal considerations.

Section 14. Transportation information

This product is not a hazardous material under U.S. Department of Transportation (DOT) 49 CFR 172, and is not regulated by the DOT or Transport Canada “Transportation of Dangerous Goods” regulations. When shipped in a stored pressure type fire extinguisher, and pressurized with a non-flammable, non-toxic inert expellant gas, the fire extinguisher is considered a hazardous material by the US Department of Transportation and Transport Canada. The proper shipping name shall be FIRE EXTINGUISHER and the UN designation is UN 1044. The DOT hazard class is Limited Quantity when pressurized to less than 241 psig and when shipped via highway or rail. Use a Non-Flammable Gas label (class 2.2) when shipping via air.

Section 15. Regulatory information

International Inventory Status:

All ingredients are on the following inventories

Country(ies) Agency Status

United States of America TSCA Yes

Canada DSL Yes

Europe EINECS/ELINCS Yes

Australia AICS Yes

Japan MITI Yes

South Korea KECL Yes


European Risk and Safety phrases: EU Classification: Harmful. R Phrases: 22 Harmful if swallowed. 36/37/38 Irritating to eyes, respiratory system, and skin. S Phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

36 Wear suitable protective clothing. Components: Mono ammonium phosphate: EU Classification: Harmful. R Phrases: 22 Harmful if swallowed. 36/37/38 Irritating to eyes, respiratory system, and skin. S Phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

36 Wear suitable protective clothing. Ammonium sulfate: EU Classification: Irritant R Phrases: 22 Harmful if swallowed. 36/37/38 Irritating to eyes, respiratory system, and skin. S Phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

36 Wear suitable protective clothing. U.S. federal regulatory information:

None of the chemicals in this product are under SARA reporting requirements or have SARA threshold planning quantities (TPQs) or CERCLA reportable quantities (RQs), or are regulated under TSCA 8(d). State regulatory information: Chemicals in this product are covered under specific State regulations, as denoted below: Alaska - Designated Toxic and Hazardous Substances: NoneCalifornia – Permissible Exposure Limits for Chemical Contaminants: None Florida – Substance List: Mica Dust, Ammonium Sulfate Illinois – Toxic Substance List: None


Kansas – Section 302/303 List: None Massachusetts – Substance List: Mica Dust, Ammonium Sulfate Minnesota – List of Hazardous Substances: None Missouri – Employer Information/Toxic Substance List: None New Jersey – Right to Know Hazardous Substance List: None North Dakota – List of Hazardous Chemicals, Reportable Quantities: None Pennsylvania – Hazardous Substance List: None Rhode Island – Hazardous Substance List: Mica Dust, Ammonium Sulfate Texas – Hazardous Substance List: No West Virginia – Hazardous Substance List: None Wisconsin – Toxic and Hazardous Substances: None

California Proposition 65: No component is listed on the California Proposition 65 list. _____________________________________________________________________

Section 16

Section 17. Other information

This MSDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or standards, and conforms to the proposed 2003 ANSI Z400.1 format.

The information herein is given in good faith but no warranty, expressed or implied, is made. Updated by Lindsay R. Hill, CIH.

When shipped in a stored pressure type fire extinguisher, and pressurized with a non-flammable, non-toxic inert expellant gas, the fire extinguisher is considered a hazardous material by the US Department of Transportation and Transport Canada. The proper shipping name shall be FIRE EXTINGUISHER and the UN designation is UN 1044. The DOT hazard class/ division is 2.2 Non-Flammable Gas. Packing Group—N/A

Page 1 of 8 Pages PURPLE – K


Section 1. Chemical product and company identification Product Name: Purple K Dry Chemical Fire Extinguishant Synonym: Potassium Bicarbonate, KDC, PK Manufacturer: AMEREX CORPORATION Internet Address: www.amerex-fire.com Address: 7595 Gadsden Highway P.O. Box 81 Trussville, AL 35173-0081 Telephone: (205) 655-3271 Emergency Contacts: Chemtrec 1(800) 424-9300 or (703) 527–3887 Revised: January, 2015

Section 2. Hazard identification and emergency overview

Emergency overview: Light purple, fine solid powder, odorless. Adverse health effects and symptoms: Moderate irritant to the respiratory system and eyes; mild irritant to the skin. Symptoms may include coughing, shortness of breath, and irritation of the lungs, eyes, and skin. Ingestion, although unlikely, may cause gastric distress. Exposure guidelines:

Ingredients OSHA PEL ACGIH TLV DFG MAK * Potassium bicarbonate

PNOC** Total dust, 15 mg/m

3



3



3


3

Mica 6 mg/m3 3 mg/m3 -------

Fullers Earth


3



3



3


3

Silicone oil

NR*** NR NR

Violet 23 pigment NR NR NR

http://www.amerex-fire.com/


*German regulatory limits **PNOC = Particulates not otherwise classified (ACGIH) also known as Particulates not otherwise regulated (OSHA) *** NR = Not Regulated. All values are 8 hour time weighted average concentrations.

Hazard symbols: WHMIS (Canadian workplace hazardous materials identification system) D2B may irritate eyes, mucous membranes, or skin

Section 3. Composition/information on ingredients

Name/Compound Weight % CAS # Potassium bicarbonate (potassium hydrogen carbonate)- may contain minor calcium carbonate

>93

298-14-6

Fullers earth magnesium aluminum silicate-

>4

8031-18-3

Mica potassium aluminum silicate

>2

12001-26-2

Silicone oil methyl hydrogen polysiloxane

< 0.5

63148-57-2

Violet 23 pigment oxazine dye

< 0.2

6358-30-1

Section 4. First Aid Measures

Eye Exposure: Irrigate eyes with water and repeat until pain free. Seek medical attention if irritation develops, or if vision changes occur. Skin Exposure: In case of contact, wash with plenty of soap and water. Seek medical attention if irritation develops.


Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if irritation persists. Ingestion: If victim is conscious and alert, give 2-3 glasses of water to drink. If conscious, induce vomiting. Seek immediate medical attention. Do not leave victim unattended. To prevent aspiration of swallowed product, lay victim on side with head lower than waist. Medical conditions possibly aggravated by exposure: Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema, or bronchitis. Skin contact may aggravate existing skin disease. Chronic overexposure may cause pneumoconiosis (“dusty lung” disease).

Section 5. Fire fighting measures

Extinguishing media: non combustible and non flammable – product is an extinguishing agent Unusual fire/explosion hazards: in a fire this material may decompose, releasing oxides of carbon, potassium and nitrogen (see Section 10). Insensitive to mechanical impact or static discharge. HMIS Hazard Ranking: health = 1, flammability = 0, reactivity = 0, personal protective equipment: use N-95 dust mask (see Section 8)

Section 6. Accidental release measures

Clean up released material using vacuum or wet sweep and shovel to minimize generation of dust. Wear appropriate respiratory protection. Bag and drum for disposal. If product is used and/or contaminated, use PPE and containment appropriate to the nature of the mixture. Prevent material from entering waterways.

Section 7. Handling and storage

Avoid skin, eye, or respiratory exposure. Use appropriate PPE when handling or maintaining equipment, and wash thoroughly after handling (see Section 8).


Keep product in original container or extinguisher. Contents may be under pressure – inspect for extinguisher rust periodically to insure container integrity. Do not mix with other extinguishing agents, particularly ammonium phosphate. Do not store in high humidity.

Section 8. Exposure controls/ personal protection

During the application of this product against fires, exhaust gases and the products of incomplete combustion (PICs) are the principal respiratory hazards. In the manufacture of extinguishers, automated systems and point source ventilation controls sufficiently minimize respiratory exposure. Employers and employees must use their collective judgment in determining occupational settings where the use of a dust mask or air purifying respirator is prudent. The need for respiratory protection is not likely for short-term use in well ventilated areas.

Respiratory protection: use N95 dust mask for limited exposure, use air-purifying respirator (APR) with high efficiency particulate air (HEPA) filters for prolonged exposure. Eye protection: wear chemical goggles or full-face APR. Skin protection: use nitrile, latex, or similar gloves and coveralls. Good personal hygiene practices essential, such as avoiding food, tobacco products, or other hand-to-mouth contact when handling. Wash thoroughly after handling.

Section 9. Physical and chemical properties

Appearance: light purple powder, finely divided odorless solid. Specific gravity: Approximately .88 in aerated condition Solubility: product is coated, not immediately soluble in water Non –flammable Flash point: none Vapor pressure: < 1 mm Hg pH: approximately 9 – 10 for a 10% solution Boiling point: not applicable No explosive or oxidizing properties


Section 10. Stability and reactivity

Stability: stable Incompatibles: strong acids, ammonium phosphate, lithium. Decomposition products: heat of fire may release carbon monoxide, carbon dioxide, and oxides of potassium and nitrogen. Possibility of hazardous reactions: none

Section 11. Toxicological information

Acute toxicity: Potassium bicarbonate LD50 (rat): unknown, testing has not been

conducted. Relatively non-toxic. Target organs in man: respiratory system. This product is a mild irritant to epithelial tissue, (eyes, mucous membranes, skin) and may aggravate dermatitis. No information was found indicating the product causes sensitization.

Chronic toxicity: Pneumoconiosis, or “dusty lung” disease, may result from chronic

exposure to any dust. Reproductive toxicity: This product’s ingredients are not known to have reproductive or

teratogenic effects.

Section 12. Ecological Information (potassium bicarbonate)

Environmental and biodegradation. Ready biodegradability prediction: yes

Solubility - 0.756 @ 25oC

Probability of rapid biodegradation:

0.718 (linear model) 0.894 (non-linear model)

Anaerobic biodegradation probability: 0.836 (linear model)


Bioaccumulation est. - biotransformation half-life: 0.012 days

Ecotoxic effects - Product is relatively non-toxic.

Rainbow Trout: LC50 - 1300 mg/L (96 hr)

Fathead Minnow: minimum dose, mortality - 260 mg/L

Water flea (Daphnia magna): LC50 - 670 mg/L (24 hr), minimum dose, mortality

- 94 mg/L

Algae: no active toxicity with aquatic plants

Behavior in environmental compartments.

Biota: log Kow -4.01, does not accumulate in fat tissue

Soil: soil adsorption coefficient, Koc 0.009, log Koc -2.06

Water: volatilization rates - river: 4.9710 days, lake: 5.4211 days

Air: particle/gas partition coefficient, Kp 0.0974 (Mackay Model)

Fraction sorbed to airborne particulates: 0.886

Atmospheric oxidation half-life: 20.6 days

Level lII fugacity model: 62% soil, 37% water, <0.1% sediment, air

Section 13. Disposal considerations

This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of according to state or local laws, which may be more restrictive than federal laws or regulations. Used product may be altered or contaminated, creating different disposal considerations.


Section 14. Transportation information

This product is not defined as a hazardous material under U.S. Department of Transportation (DOT) 49 CFR 172, or by Transport Canada “Transportation of Dangerous Goods” regulations. When shipped in a stored pressure type fire extinguisher, and pressurized with a non-flammable, non-toxic inert expellant gas, the fire extinguisher is considered a hazardous material by the US Department of Transportation and Transport Canada. The proper shipping name shall be FIRE EXTINGUISHER and the UN designation is UN 1044. The DOT hazard class is Limited Quantity when pressurized to less than 241 psig and when shipped via highway or rail. Use a Non-Flammable Gas label (class 2.2) when shipping via air.

Section 15. Regulatory information

International Inventory Status:

All ingredients are on the following inventories

Country(ies) Agency Status

United States of America TSCA Yes

Canada DSL Yes

Europe EINECS/ELINCS Yes

Australia AICS Yes

Japan MITI Yes

South Korea KECL Yes

European Risk and Safety phrases: EU Classification: Irritant R Phrases: 20 Harmful by inhalation. 36/37 Irritating to eyes, respiratory system. S Phrases: 22 Do not breathe dust. 24/25 Avoid contact with skin and eyes

26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

36 Wear suitable protective clothing.


U.S. federal regulatory information:

None of the chemicals in this product are under SARA reporting requirements or have SARA threshold planning quantities (TPQs) or CERCLA reportable quantities (RQs), or are regulated under TSCA 8(d). State regulatory information: Chemicals in this product are covered under specific State regulations, as denoted below: Alaska - Designated Toxic and Hazardous Substances: NoneCalifornia – Permissible Exposure Limits for Chemical Contaminants: None Florida – Substance List: Mica Dust Illinois – Toxic Substance List: None Kansas – Section 302/303 List: None Massachusetts – Substance List: Mica Dust Minnesota – List of Hazardous Substances: None Missouri – Employer Information/Toxic Substance List: None New Jersey – Right to Know Hazardous Substance List: None North Dakota – List of Hazardous Chemicals, Reportable Quantities: None Pennsylvania – Hazardous Substance List: None Rhode Island – Hazardous Substance List: Mica Dust T exas – Hazardous Substance List: No West Virginia – Hazardous Substance List: None Wisconsin – Toxic and Hazardous Substances: None

California Proposition 65: No component is listed on the California Proposition 65 list. _____________________________________________________________________

Section 16. Other information This MSDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or standards, and conforms to the proposed 2003 ANSI Z400.1 format. The information herein is given in good faith but no warranty, expressed or implied, is made. Updated by Lindsay R. Hill, CIH

1

ARCTIC™ 3% AFFF

FOAM CONCENTRATE


Section 1: Chemical product and company identification

Product Name: ARCTIC™ 3% Aqueous Film Forming Foam Synonym: ARCTIC 3% AFFF, 3% AFFF Chemical Name: N/A This product is a mixture C.A.S No.: N/A This product is a mixture Chemical Formula: N/A This product is a mixture EINECS Number: N/A This product is a mixture

Use of this product: The intended use of this product is as a fire extinguishing agent.

Company / Undertaking Identification:

Americas Europe/Middle East/Africa Asia-Pacific

The Solberg Company 1520 Brookfield Avenue Green Bay, WI 54313 United States Tel: +1 920 593 9445

Solberg Scandinavian AS Radøyvegen 721 - Olsvollstranda N-5938 Sæbøvågen Norway Tel: +47 56 34 97 00

Solberg Asia Pacific Pty Ltd 3 Charles Street St. Marys NSW 2760 Australia Tel: +61 2 9673 5300

Telephone: (920) 593-9445 Emergency Contacts: Chemtrec: (800) 424-9300 or (703) 527-3887 Revised: November 2014

Section 2: Hazard identification and emergency overview HMIS: Health 1, Flammability 0, Reactivity 0, PPE B NFPA: Health 1, Flammability 0, Reactivity 0 WHMIS: D2B – may irritate eyes, skin, mucous membranes

Human Exposure:

Product:

EU Classification: Xi Irritant R Phrases: 36 Irritating to eyes S Phrases: 2 Keep out of reach of children 24 Avoid contact with skin

26 In case of contact with eyes, rinse immediately with copious amounts of water and seek medical advice.

Components: Diethylene Glycol Monobutyl Ether:

EU Classification Xi Irritant R Phrases 36 Irritating to eyes

2

S Phrases 2 Keep out of reach of children 24 Avoid skin contact

26 In case of contact with eyes, rinse immediately with copious amounts of water and seek medical advice

Limit Values for Exposure: Diethylene Glycol Monobutyl Ether: OSHA PEL (General Industry) 8 hour TWA: None established MAK (DE) Limit Value: 100 mg/m

3

Short term exposure limit value (8 times, 5 minutes): 200mg/m

3

Neither this product nor any of the ingredients contained in it have been listed as carcinogenic by the National Toxicology Program IARC, or OSHA. As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to chemical substances and ensure prompt removal from skin, eyes, and clothing Signs and Symptoms:

Acute Exposure: Eye Contact: May cause mild to moderate transient irritation Skin Contact: May cause mild transient irritation and/or dermatitis Inhalation: Not a normal route of entry Ingestion: Irritating to mucous membranes Chronic Overexposure: Possible systemic and motor disorders, diethethylene glycol monobutyl ether did not interfere with reproduction; however, body weights of newborn animals were decreased. Medical conditions generally aggravated by exposure: Diseases of the kidney and liver. For Environment: As much as possible, keep from being washed into surface water.

Section 3: Composition/information on ingredients Ingredient Name: Proprietary mixture consisting of fluorosurfactants, hydrocarbon surfactants,

inorganic salts and water Chemical Formula: N/A - This is a mixture C.A.S. No.: N/A - This is a mixture EINECS Number: N/A - This is a mixture Concentration, Wt. %: >85% Hazard Classification: See section 2 Ingredient Name: Diethylene Glycol Monobutyl Ether (a) Chemical Formula: C4H9O(CH2CH2O)2H C.A.S. No.: 112-35-5 EINECS Number: 230-961-6 Concentration, Wt.%: 12% Hazard Classification: See section 2

(a) This chemical is subject to reporting requirements of SARA Title III Section 313 and 40CFR Section 372

3

Section 4: First aid measures

Eye Exposure: Irrigate eyes at eye wash station and repeat until pain free. Seek medical

attention immediately. Skin Exposure: In case of contact, wash with plenty of soap and water. If irritation persists

seek medical attention. Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Provide

oxygen if breathing is difficult. Seek medical attention if irritation develops or persists.

Ingestion: Do not induce vomiting. If victim is alert, give liquids such as milk or water.

Seek immediate medical attention. Do not leave victim unattended. To prevent aspiration of swallowed product, lay victim on side with head lower than waist.

Medical conditions possibly aggravated by exposure: Inhalation of product may aggravate existing chronic respiratory conditions.

Section 5: Firefighting measures This product is an extinguishing media. No special protective equipment is required for fire fighters. Insensitive to mechanical impact or static discharge. HMIS (hazardous materials identification system) rankings (as liquid): health = 1, flammability = 0, reactivity = 0, personal protective equipment: eye and skin protection (see Section 8).

Section 6: Accidental release measures

For personal protection: Prevent skin and eye contact, see Heading 8 Clean up: Use an absorbent material, to include but not be limited to, diatomaceous earth, kitty litter, or saw dust, and sweep up. See Heading 12

Section 7: Handling and storage

Avoid eye, respiratory, and skin exposure. Use appropriate PPE (personal protective equipment) when handling, and wash thoroughly after handling (Section 8). Keep product in original container until packaging for use as extinguisher. Clean used equipment before storage. Use this product only in well ventilated areas. Do not mix with other extinguishing agents.

Section 8: Exposure controls/ personal protection Respiratory protection: None expected to be needed, mechanical ventilation is recommended

4

Hand Protection:

Use chemical resistant gloves when handling the product Eye protection: Chemical goggles are recommended Skin protection:

Standard fire-fighting equipment should provide all necessary protection

____________________________________________________________________________ Section 9: Physical and chemical properties

Appearance: Clear liquid slight straw color; mild sweet odor Solubility: Completely soluble in water Flammability: Non -flammable Flash point: Does not flash Vapor density (Air = 1): Not determined, but <1 Explosive properties: Not explosive Oxidizing properties: Not an oxidizer Relative density: About 1 (Water = 1) pH: 7.0 to 8.5 Boiling point: ~ 220° F

Section 10: Stability and reactivity Stability: stable Incompatibles: Reactive metals, electrically energized equipment, any material reactive with water and strong oxidizers Conditions to avoid: There are no known conditions which may cause a dangerous reaction.

Section 11: Toxicological Information Product: The toxicity of the product mixture has not been determined Components: Diethylene Glycol Monobutyl Ether Toxicity Data: Oral (rat) LD50 5,660 mg/kg Oral (rat) LD50 9,626 mg/kg (EINECS ESIS) Dermal (rabbit) LD50 4,000 mg/kg Dermal (rabbit) LD50 2,764 mg/kg (EINECS ESIS) Irritation Data: Eye (rabbit) 20 mg/day Moderate (EINECS ESIS) Eye (rabbit) Highly irritating (EINECS ESIS) Skin (rabbit) 1000 mg/kg/day Moderate with edema,

fissuring, leathery appearance (EINECS ESIS)

Target organs: Kidney, blood, liver, lungs, gastrointestinal, spleen

5

Section 12: Ecological information Ecotoxicity: Components: Diethylene Glycol Monobutyl Ether Fish Lepomis marcrochinus: LC50 (96 hrs.) 1,300 mg/L Carassius auratus: LC50 (24 hrs.) 2,700 mg/L Daphnids, Daphnia magna: EC50 24 hrs.) 3,184 mg/L Algae, Scenedesmus subspicatus: EC50 (96 hrs.) >100 mg/L Mobility Diethylene Glycol Monobutyl Ether

Should not partition from a water column to organic matter contained in sediments and suspended solids.

Persistence/ Degradability:

Diethylene glycol monobutyl ether: Indirect photodegradation is about 50% in 3.5 hours Aerobic degradation with adapted activated sludge is 60% after 28 days COD = 2080 mg/g of substance BOD5 = 250 mg O2/g substance

Theoretical oxygen demand = 2.17 mg/mg Bioaccumulation: Diethylene glycol monobutyl ether:

Should not bioaccumulate.

Section 13: Disposal considerations

As much as possible, keep from being washed into surface water, see Heading 12. Dispose of in compliance with national, regional, and local provisions that may be in force.

Section 14: Transportation information

This product is not a hazardous material under U.S. Department of Transportation (DOT) 49 CFR 172, and is not regulated by the DOT, IMO, lATA, RID/ADR, or Canada's TDG

Section 15: Regulatory information Product:

EU Classification: Xi Irritant R Phrases: 36 Irritating to eyes S Phrases: 2 Keep out of reach of children 24 Avoid contact with skin

26 In case of contact with eyes, rinse immediately with copious amounts of water and seek medical advice.

6

Limit Values for Exposure: Diethylene Glycol Monobutyl Ether: OSHA PEL (General Industry) 8 hour TWA: None established MAK (DE) Limit Value: 100 mg/m

3

Short term exposure limit value (8 times, 5 minutes): 200mg/m

3

State regulatory information: Chemicals in this product under specific State regulations, as denoted below: California - Permissible Exposure Limits for Chemical Contaminants: Florida – Substance List: None Massachusetts - Substance List: None Minnesota - List of Hazardous Substances: None New Jersey - Right to Know Hazardous Substance List: None Pennsylvania: Hazardous Substance List: None California Proposition 65: No component is listed on the California Proposition 65 list or the No Significant Risk Level List.

Section 16. Other information This MSDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or standards, and conforms to the 2003 ANSI Z400.1 format. The information herein is given in good faith to be correct but does not claim to be all inclusive and shall be used only as a guide. Solberg or Amerex Corporation shall not be held liable for any damage resulting from handling or from contact with the above product.

Date Prepared: 03 November, 2014 Supersedes: Feb, 2012


ABC Fire ExtinguisherIssue Date: 04-13-2011

1. Product and Company Identification

Material name ABC Fire Extinguisher

Version # 02

Revision date 04-13-2011

CAS # Mixture

Product use Fire Extinguisher

CHEMTREC 800-424-9300 or 703-527-3887

http://www.ansul.com

Marinette, WI 54143-2542

One Stanton Street

Tyco Fire Protection Products

Emergency Phone Number

Internet

Phone

Address

Name

Supplier

Manufacturer / Importer /

715-735-7411

2. Hazards Identification

Emergency overview WARNING

Irritating to eyes and skin.

OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).

Potential health effects

Routes of exposure Eye contact. Skin contact. Inhalation. Ingestion.

Eyes Avoid contact with eyes. Contact with eyes may cause irritation.

Skin Avoid contact with the skin. May cause skin irritation.

Inhalation Inhalation of dusts may cause respiratory irritation.

Ingestion Not a likely route of entry.

Target organs Eyes. Respiratory system. Skin.

Signs and symptoms Irritation of eyes and mucous membranes.

Hazardous components CAS # Percent

3. Composition / Information on Ingredients

471-34-1 1 - 2.5CALCIUM CARBONATE

Non-hazardous components CAS # Percent

7783-20-2 10 - 20Ammonium Sulfate

7722-76-1 60 - 80Ammonium Phosphate

2.5 - 10Other components below reportable levels

4. First Aid Measures

First aid procedures

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation persists after washing.

Skin contact Wash off with warm water and soap. Get medical attention if irritation develops and persists.

Inhalation Move to fresh air. Get medical attention, if needed.

Ingestion Rinse mouth. Do not induce vomiting without advice from poison control center. If vomitingoccurs, keep head low so that stomach content doesn't get into the lungs.

Notes to physician Symptoms may be delayed.

Material name: ABC Fire Extinguisher

1667 Version #: 02 Revision date: 04-13-2011

MSDS US

1 / 5

General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medicalpersonnel are aware of the material(s) involved, and take precautions to protect themselves.Show this safety data sheet to the doctor in attendance.

5. Fire Fighting Measures

Flammable properties No unusual fire or explosion hazards noted.

Extinguishing media

Suitable extinguishing

media

This product is not flammable. Use extinguishing agent suitable for type of surrounding fire.

Protection of firefighters

Specific hazards arising

from the chemical

None known.

Hazardous combustion

products

Carbon monoxide and carbon dioxide.

6. Accidental Release Measures

Personal precautions Local authorities should be advised if significant spillages cannot be contained. Avoid inhalation ofdust from the spilled material. Wear a dust mask if dust is generated above exposure limits.

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.

Methods for containment If sweeping of a contaminated area is necessary use a dust suppressant agent which does notreact with the product. Prevent entry into waterways, sewer, basements or confined areas.

Methods for cleaning up Should not be released into the environment. Sweep up or vacuum up spillage and collect insuitable container for disposal. Collect dust using a vacuum cleaner equipped with HEPA filter.Avoid dust formation. Following product recovery, flush area with water.

Other information Clean up in accordance with all applicable regulations.

7. Handling and Storage

Handling Keep formation of airborne dusts to a minimum. Do not breathe dust. Avoid contact with eyes. Donot use in areas without adequate ventilation. Wear personal protective equipment. Washthoroughly after handling.

Storage Keep container tightly closed. Guard against dust accumulation of this material. Use care inhandling/storage.

U.S. - OSHA

8. Exposure Controls / Personal Protection

Occupational exposure limits

Components Type Value Form

CALCIUM CARBONATE (471-34-1) 5.0000 mg/m3 Respirable fraction.PEL

15.0000 mg/m3 Total dust.

5.0000 mg/m3 Respirable fraction.TWA


Engineering controls Ensure adequate ventilation, especially in confined areas.

Personal protective equipment

Eye / face protection Do not get in eyes. Chemical goggles are recommended.

Skin protection No special protective equipment required.

Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriatecertified respirators.

General hygiene

considerations

Do not get in eyes.

9. Physical & Chemical Properties

Appearance

Form Powder.

Color Yellow.

Odor Odorless.

Physical state Solid.



MSDS US

2 / 5

pH Not available.

Melting point Not available.

Freezing point Not available.

Boiling point Not available.

Flash point Not available.

Evaporation rate Not available.

Flammability limits in air, upper,

% by volume

Not available.

Flammability limits in air, lower,

% by volume

Not available.

Vapor pressure Not available.

Vapor density Not available.

Specific gravity Not available.

Relative density Not available.

Solubility (water) Not available.

Partition coefficient

(n-octanol/water)

Not available

Auto-ignition temperature Not available.

Decomposition temperature Not available.

VOC Not available.

10. Chemical Stability & Reactivity Information

Chemical stability Material is stable under normal conditions.

Incompatible materials Strong acids.

Hazardous decomposition

products

Carbon oxides.

11. Toxicological Information

Toxicological information The toxicity of this product has not been tested.

Toxicological data

Components Test Results

Acute Oral LD50 Rat: 6450 mg/kgCALCIUM CARBONATE (471-34-1)

Local effects Components of the product may be absorbed into the body through the skin. Contact may irritateor burn eyes.

Chronic effects Hazardous by OSHA criteria. Prolonged inhalation may be harmful.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

Ecotoxicological data

12. Ecological Information


LC50 Western mosquitofish (Gambusia affinis): > 56000 mg/l96.00 Hours

CALCIUM CARBONATE (471-34-1)

EC50 Water flea (Ceriodaphnia dubia): 52 - 67 mg/l 48.00hours

Ammonium Sulfate (7783-20-2)

LC50 Pink salmon (Oncorhynchus gorbuscha): 0.068 mg/l96.00 hours

Ecotoxicity This material is not expected to be harmful to aquatic life.

Environmental effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

Persistence and degradability Not available.



MSDS US

3 / 5

13. Disposal Considerations

Disposal instructions This product, in its present state, when discarded or disposed of, is not a hazardous wasteaccording to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility ofthe user of the product to determine, at the time of disposal, whether the product meets RCRAcriteria for hazardous waste. Dispose of waste material according to Local, State, Federal, andProvincial Environmental Regulations.

Waste from residues / unused

products

Dispose of in accordance with local regulations.

14. Transport Information

DOT

Basic shipping requirements:

UN1044UN number

Fire extinguishersProper shipping name

2.2Hazard class

Additional information:

18, 110Special provisions

309Packaging exceptions

309Packaging non bulk

NonePackaging bulk

126ERG number

DOT

15. Regulatory Information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

CERCLA/SARA Hazardous Substances - Not applicable.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration

Ammonium Phosphate (CAS 7722-76-1) 1.0 %

Ammonium Sulfate (CAS 7783-20-2) 1.0 %

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance

Ammonium Phosphate (CAS 7722-76-1) Listed.

Ammonium Sulfate (CAS 7783-20-2) Listed.

CERCLA (Superfund) reportable quantity

None

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Acute Health - YesChronic Health - YesFire Hazard - NoPressure Hazard - YesReactivity Hazard - No

Section 302 extremely

hazardous substance

No

Section 311 hazardous

chemical

No



MSDS US

4 / 5

Inventory status

Country(s) or region Inventory name On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)

YesEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

NoJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

YesNew Zealand New Zealand Inventory

YesPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

State regulations This product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive harm.

US - Pennsylvania RTK - Hazardous Substances: Listed substance


CALCIUM CARBONATE (CAS 471-34-1) Listed.

16. Other Information

Further information HMIS® is a registered trade and service mark of the NPCA.

HMIS® ratings Health: 1*Flammability: 0Physical hazard: 0

NFPA ratings Health: 1Flammability: 0Instability: 0

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to thespecific material designated and may not be valid for such material used in combination with anyother materials or in any process, unless specified in the text.

Issue date 04-13-2011



MSDS US

5 / 5


ANSULEX Low pH Liquid Fire Suppressant

Product Code: 1070-2-000 ANa Issue Date: 07-31-2010


Material name ANSULEX Low pH Liquid Fire Suppressant

Version # 01


Product Code 1070-2-000 ANa

Product use Fire exintinguishing agent

CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street

Tyco Fire Suppression and Building Products


Internet

Phone

Address

Name

Supplier


715-735-7411


Emergency overview Health injuries are not known or expected under normal use.

OSHA regulatory status This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication).



Eyes May cause minor irritation on eye contact.

Skin Non-irritating to the skin.

Inhalation None known.



The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.



Eye contact Rinse with water. Get medical attention if irritation develops and persists.

Skin contact Rinse skin with water/shower. Get medical attention if irritation develops and persists.

Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.Call a physician if symptoms develop or persist.

Ingestion Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately.

General advice If you feel unwell, seek medical advice (show the label where possible).



Extinguishing media


media


Specific methods None known.


products

May include oxides of nitrogen.

Material name: ANSULEX Low pH Liquid Fire Suppressant

1390 Version #: 01 Revision date: 07-31-2010 F-9763

MSDS US

1 / 4


Personal precautions Keep unnecessary personnel away. Local authorities should be advised if significant spillagescannot be contained.


Methods for containment Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.Use water spray to reduce vapors or divert vapor cloud drift.

Methods for cleaning up Should not be released into the environment.

Large Spills: Dike far ahead of spill for later disposal. Use a non-combustible material likevermiculite, sand or earth to soak up the product and place into a container for later disposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).

Never return spills in original containers for re-use. Following product recovery, flush area withwater. Clean surface thoroughly to remove residual contamination.


Handling Avoid release to the environment. Handle and open container with care.

Storage Use care in handling/storage.



Eye / face protection Not normally needed.


Respiratory protection No personal respiratory protective equipment normally required.

General hygiene

considerations

Handle in accordance with good industrial hygiene and safety practice.


Appearance

Form Liquid.

Color Yellow green

Odor Mild.

Physical state Liquid.

pH 7.7 - 8.7







% by volume

Not available.


% by volume

Not available.



Specific gravity 1.33




(n-octanol/water)

Not available



VOC Not available.



MSDS US

2 / 4



Incompatible materials None known.


products

Toxic gas. Nitrogen oxides (NOx).



Chronic effects Not available.


Skin corrosion/irritation Not available.

Epidemiology Not available.

Neurological effects Not available.


Ecotoxicity Not expected to be harmful to aquatic organisms.




Disposal instructions This product, in its present state, when discarded or disposed of, is not a hazardous wasteaccording to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility ofthe user of the product to determine, at the time of disposal, whether the product meets RCRAcriteria for hazardous waste. Dispose in accordance with all applicable regulations.


products

Not applicable.


DOT

Not regulated as dangerous goods.


US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA HazardCommunication Standard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.



Hazard categories Acute Health - NoChronic Health - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


hazardous substance

No


chemical

No

Inventory status


NoAustralia Australian Inventory of Chemical Substances (AICS)

NoCanada Domestic Substances List (DSL)


NoChina Inventory of Existing Chemical Substances in China (IECSC)





MSDS US

3 / 4



NoKorea Existing Chemicals List (ECL)

NoNew Zealand New Zealand Inventory

NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)






HMIS® ratings Health: 0Flammability: 0Physical hazard: 0






MSDS US

4 / 4


ANSULITE 3% AFFF (AFC-3-A)



Material name ANSULITE 3% AFFF (AFC-3-A)

Version # 02


CAS # Mixture


Product use Fire extinguishing agent

CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411


Emergency overview WARNING! Causes skin and eye irritation.




Eyes Do not get this material in contact with eyes.

Skin Avoid contact with the skin. Frequent or prolonged contact may defat and dry the skin, leading todiscomfort and dermatitis.

Inhalation Do not breathe vapor. May be irritating.

Ingestion Not a likely route of entry. Do not ingest.

Target organs Eyes. RESPIRATORY SYSTEM. Skin. Central nervous system.

Chronic effects Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Defatting of the skin.Rash. Skin irritation.

Components CAS # Percent


112-34-5 2.5 - 10Butyl Carbitol

> 90Other components below reportable levels





Inhalation Move to fresh air. For breathing difficulties, oxygen may be necessary. Get medical attention, ifneeded.

Ingestion Rinse mouth. Do not induce vomiting without advice from poison control center. IF SWALLOWED:Immediately call a POISON CENTER or doctor/physician. If vomiting occurs, keep head low sothat stomach content doesn't get into the lungs.


Material name: ANSULITE 3% AFFF (AFC-3-A)


MSDS US

1 / 5




Extinguishing media


media




from the chemical

None known.



products



Personal precautions Local authorities should be advised if significant spillages cannot be contained. Surfaces maybecome slippery after spillage.

Environmental precautions Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses oronto the ground.

Methods for containment Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.Prevent entry into waterways, sewer, basements or confined areas.






Handling Do not get this material in contact with eyes. Avoid contact with skin. Avoid prolonged exposure.Handle and open container with care.

Storage Store in cool place. Store in a well-ventilated place. Keep container tightly closed. Keep out of thereach of children. Use care in handling/storage.



Eye / face protection Do not get in eyes. Wear approved chemical safety glasses or goggles where eye exposure isreasonably probable.

Skin protection Wear appropriate chemical resistant clothing. Chemical resistant gloves.


General hygiene

considerations

Handle in accordance with good industrial hygiene and safety practice. When using, do not eat,drink or smoke. Avoid contact with skin.


Appearance

Form Liquid.

Color Light yellow. Clear.

Odor Mild. Sweet.


pH 6.5 - 8.5



Boiling point 206.6 °F (97 °C)



MSDS US

2 / 5

Flash point > 212 °F (> 100 °C)



% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.



Conditions to avoid None known.

Incompatible materials Alkaline metals. Strong acids, alkalies and oxidizing agents.


products

Nitrogen oxides (NOx). Sulfur oxides. Carbon oxides.



Toxicological data


Acute Dermal LD50 Rabbit: 2700 mg/kgButyl Carbitol (112-34-5)

Acute Oral LD50 Guinea pig: 2000 mg/kg

Acute Oral LD50 Rabbit: 2200 mg/kg

Acute Oral LD50 Rat: 6560 mg/kg

Acute Other LD50 Mouse: 850 mg/kg

Acute Other LD50 Rat: 500 mg/kg






EC50 Algae: > 100 mg/l 96.00 HoursButyl Carbitol (112-34-5)

EC50 Water flea (Daphnia magna): 3184 mg/l 24.00 hours

LC50 Bluegill (Lepomis macrochirus): 1300 mg/l 96.00 hours






MSDS US

3 / 5




products



DOT





Butyl Carbitol (CAS 112-34-5) 1.0 % N230


Butyl Carbitol (CAS 112-34-5) Listed. N230


None


Hazard categories Acute Health - YesChronic Health - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


hazardous substance

No


chemical

No

Inventory status















US - New Jersey Community RTK (EHS Survey): Reportable threshold

Butyl Carbitol (CAS 112-34-5) 500 LBS


Butyl Carbitol (CAS 112-34-5) Listed.



MSDS US

4 / 5







This data sheet contains

changes from the previous

version in section(s):

Product and Company Identification: Product and Company Identification



MSDS US

5 / 5


ANSULITE 3% AFFF (FORMULA DC-3)



Material name ANSULITE 3% AFFF (FORMULA DC-3)

Version # 01


CAS # Mixture



CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411


Emergency overview WARNING! Causes skin and eye irritation.




Eyes Do not get this material in contact with eyes.


Inhalation Do not breathe vapor. May be irritating.


Target organs Eyes. RESPIRATORY SYSTEM. Skin. Central nervous system.


Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Defatting of the skin.Rash. Skin irritation.



57-55-6 1 - 2.5propylene glycol

112-34-5 10 - 20Butyl Carbitol

80 - 90Other components below reportable levels





Inhalation Move to fresh air. For breathing difficulties, oxygen may be necessary. Get medical attention, ifneeded.

Ingestion Rinse mouth. Do not induce vomiting without advice from poison control center. IF SWALLOWED:Immediately call a POISON CENTER or doctor/physician. If vomiting occurs, keep head low sothat stomach content doesn't get into the lungs.

Material name: ANSULITE 3% AFFF (FORMULA DC-3)


MSDS US

1 / 5





Extinguishing media


media




from the chemical

None known.

Specific methods In the event of fire, cool tanks with water spray.


products



Personal precautions Local authorities should be advised if significant spillages cannot be contained. Surfaces maybecome slippery after spillage.


Methods for containment Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.Prevent entry into waterways, sewer, basements or confined areas.






Handling Do not get this material in contact with eyes. Avoid contact with skin. Avoid prolonged exposure.Handle and open container with care.

Storage Store in cool place. Store in a well-ventilated place. Keep container tightly closed. Keep out of thereach of children. Use care in handling/storage.



Eye / face protection Do not get in eyes. Wear approved chemical safety glasses or goggles where eye exposure isreasonably probable.

Skin protection Wear appropriate chemical resistant clothing. Chemical resistant gloves.


General hygiene

considerations

When using do not smoke. Avoid contact with skin. Keep away from food and drink. Handle inaccordance with good industrial hygiene and safety practice.


Appearance

Form Liquid.

Color Not available.

Odor Not available.


pH 7 - 8.5





MSDS US

2 / 5

Boiling point 210.2 °F (99 °C)




% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.




Incompatible materials Alkaline metals. Strong acids, alkalies and oxidizing agents.


products


Toxicological data









Acute Oral LD50 Dog: 19000 mg/kgpropylene glycol (57-55-6)

Acute Oral LD50 Guinea pig: 18400 - 99999 mg/kg

Acute Oral LD50 Mouse: 23900 - 31800 mg/kg




Acute Other LD50 Mouse: 17.3 g/kg


Acute Other LD50 Rat: 14 g/kg






EC50 Algae: > 100 mg/l 96.00 HoursButyl Carbitol (112-34-5)



MSDS US

3 / 5


EC50 Water flea (Daphnia magna): 3184 mg/l 24.00 hoursButyl Carbitol (112-34-5)


EC50 Water flea (Daphnia magna): > 10000 mg/l 48.00 hourspropylene glycol (57-55-6)

LC50 Fathead minnow (Pimephales promelas): 710 mg/l 96.00hours

Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment.






products



DOT









None


Hazard categories Acute Health - YesChronic Health - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


hazardous substance

No


chemical

No

Inventory status











MSDS US

4 / 5












propylene glycol (CAS 57-55-6) Listed.









MSDS US

5 / 5


ANSULITE Low Viscosity 3x3 ARC



Material name ANSULITE Low Viscosity 3x3 ARC

Version # 05


CAS # Mixture



CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411


Emergency overview Causes skin and eye irritation.

OSHA regulatory status NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.


Routes of exposure Eye contact. Skin contact.


Inhalation May be irritating.


Target organs Eyes. Skin.


Signs and symptoms Defatting of the skin. Skin irritation.



112-34-5 2.5 - 10Butyl Carbitol

> 90Other components below reportable levels



Eye contact Rinse with water.

Skin contact Get medical attention if irritation develops and persists.


Ingestion Rinse mouth.


General advice If you feel unwell, seek medical advice (show the label where possible). Show this safety datasheet to the doctor in attendance.


Flammable properties This product is not flammable.

Material name: ANSULITE Low Viscosity 3x3 ARC


MSDS US

1 / 4

Extinguishing media


media




from the chemical

None known.



products



Personal precautions Surfaces may become slippery after spillage.


Methods for containment Dike the spilled material, where this is possible.

Methods for cleaning up Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the productand place into a container for later disposal.


Never return spills in original containers for re-use.


Handling Avoid contact with skin.

Storage Keep container tightly closed.


Engineering controls None known.


Respiratory protection Not normally needed.

General hygiene

considerations

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin.


Appearance

Form Liquid.

Color Light yellow. Clear.

Odor Mild. Sweet.


pH 6.5 - 8.5



Boiling point >= 212 °F (>= 100 °C)




% by volume

Not available.


% by volume

Not available.



Specific gravity 1





MSDS US

2 / 4


(n-octanol/water)

Not available



VOC Not available.


Chemical stability This is a stable material.


Incompatible materials Alkaline metals.


products




Toxicological data








Local effects Irritating to eyes. Mild skin irritation





LC50 Bluegill (Lepomis macrochirus): 1300 mg/l 96.00 hoursButyl Carbitol (112-34-5)



Aquatic toxicity Not known.




products



DOT



US federal regulations Not regulated.All components are on the U.S. EPA TSCA Inventory List.






None



MSDS US

3 / 4




hazardous substance

No


chemical

No

Inventory status



























MSDS US

4 / 4


CARBON DIOXIDEIssue Date: 03-18-2011


Material name CARBON DIOXIDE

Version # 02


CAS # 124-38-9


CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411


Emergency overview DANGER

Contents under pressure. Heat may cause the containers to explode.



Routes of exposure Inhalation.

Eyes None known.

Skin None known.

Inhalation Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygenbelow safe breathing levels.


Potential environmental effects Ecological injuries are not known or expected under normal use.



124-38-9 90 - 100CARBON DIOXIDE



Eye contact Flush thoroughly with water for at least 15 minutes. Get medical assistance.

Skin contact Rinse with water.

Inhalation Remove to fresh air.

Ingestion Not likely, due to the form of the product.



Flammable properties The product is not flammable. No unusual fire or explosion hazards noted.

Extinguishing media


media

This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.

Material name: CARBON DIOXIDE


MSDS US

1 / 5



from the chemical

Contents under pressure. Pressurized container may explode when exposed to heat or flame.



Personal precautions None known.

Environmental precautions No special environmental precautions required.

Methods for containment Move the cylinder to a safe and open area if the leak is irreparable.

Methods for cleaning up Not applicable.



Handling Handle and open container with care.

Storage Contents under pressure. Use care in handling/storage.

ACGIH



Material Type Value

CARBON DIOXIDE (124-38-9) 30000.0000 ppmSTEL

5000.0000 ppmTWA

U.S. - OSHA

Material Type Value

CARBON DIOXIDE (124-38-9) 5000.0000 ppmPEL

9000.0000mg/m3

54000.0000mg/m3

STEL

30000.0000 ppm

10000.0000 ppmTWA

18000.0000mg/m3





General hygiene

considerations



Appearance

Color Not available.

Odor Not available.

Physical state Gas.

pH 3.2 - 3.7 The pH of saturated CO2 solutions varies from 3.7 at 101 kPa (1 atm) to 3.2 at 2370kPa (23.4 atm)



Boiling point -110.2 °F (-78.5 °C)





MSDS US

2 / 5


% by volume

Not available.


% by volume

Not available.

Vapor pressure 6439.45 kPa

Vapor density 1.522 at 21°C



Solubility (water) 2 g/l


(n-octanol/water)

Not available



VOC Not available.

Molecular weight 44.01 g/mol

Molecular formula C-O2



Conditions to avoid Excessive heat.


products

No hazardous decomposition products are known.


Chronic effects Prolonged inhalation may be harmful.



Ecotoxicity This product has no known eco-toxicological effects.





products

Not applicable.

Contaminated packaging Not applicable.


DOT


UN1013UN number

Carbon dioxideProper shipping name

2.2Hazard class

2.2Subsidiary hazard class


302, 304Packaging non bulk

302, 314, 315Packaging bulk

120ERG number



MSDS US

3 / 5

DOT





None




hazardous substance

No


chemical

No

Inventory status








YesJapan Inventory of Existing and New Chemical Substances (ENCS)








CARBON DIOXIDE (CAS 124-38-9) Listed.







MSDS US

4 / 5



This data sheet contains

changes from the previous

version in section(s):

Product and Company Identification: Product and Company Identification



MSDS US

5 / 5


FE-36Issue Date: 03-17-2011


Material name FE-36

Version # 01


CAS # 690-39-1


CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411






Eyes Contact with liquefied gas might cause frostbites, in some cases with tissue damage.

Skin Contact with liquefied gas might cause frostbites, in some cases with tissue damage.

Inhalation Severe overexposure may cause cardiac sensitization and result in irregular rhythm. Intentionalmisuse by concentrating and inhaling the product can be harmful or fatal.





690-39-1 90 - 1001,1,1,3,3,3-HEXAFLUOROPROPANE (HFC-236FA)




Skin contact Wash frost-bitten areas with plenty of water. Do not remove clothing. Get medical attention ifirritation persists after washing.

Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.Call a physician if symptoms develop or persist.





Extinguishing media


media


Material name: FE-36


MSDS US

1 / 4



from the chemical










Handling When using do not smoke. All equipment used when handling the product must be grounded. DONOT handle, store or open near an open flame, sources of heat or sources of ignition. Protectmaterial from direct sunlight.

Storage Contents under pressure. Keep away from heat and sources of ignition. Keep at temperature notexceeding 49 °C. This material can accumulate static charge which may cause spark and becomean ignition source. Prevent electrostatic charge build-up by using common bonding and groundingtechniques. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Keep out ofthe reach of children.


Engineering controls General ventilation normally adequate.


Eye / face protection Wear approved chemical safety glasses or goggles where eye exposure is reasonably probable.

General hygiene

considerations



Appearance

Form Liquefied gas.

Color Colorless.

Odor Odorless.

Physical state Gas.

pH Not available.

Melting point -144.4 °F (-98 °C)

Freezing point -153.4 °F (-103 °C)

Boiling point 30.2 °F (-1.4 °C)




% by volume

Not available.


% by volume

Not available.

Vapor pressure 272.4 kPa






(n-octanol/water)

Not available



VOC Not available.



MSDS US

2 / 4

Molecular formula C3H2F6


Incompatible materials This product may react with strong reducing agents. and Alkaline metals.







products

Not applicable.


DOT


UN3163UN number

Liquefied gas, n.o.s. (1,1,1,3,3,3-Hexafluoropropane)Proper shipping name

2.2Hazard class

Additional information:

126ERG number

DOT



None




hazardous substance

No


chemical

No

Inventory status




YesCanada Non-Domestic Substances List (NDSL)




MSDS US

3 / 4


NoEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS)

YesEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)













MSDS US

4 / 4

I. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

1.1. Identification of the preparationProduct Name: "R-102 Flushing Concentrate" Chemical Name: N/A – This is a mixture/preparation.CAS No.: N/A – This is a mixture/preparation.Chemical Formula: N/A – This is a mixture/preparation.EINECS Number: N/A – This is a mixture/preparation.

1.2. Use of the preparationThe intended or recommended use of this preparation is as a FIRE EXTINGUISHING AGENT.

1.3. Company identificationManufacturer/Supplier: ANSUL INCORPORATEDAddress: One Stanton Street, Marinette, WI 54143-2542Prepared by: Safety and Health DepartmentPhone: 715-735-7411Internet/Home Page: http://www.ansul.comDate of Issue: September, 2009

1.4. Emergency telephoneCHEMTREC 800-424-9300 or 703-527-3887

2. Composition/Information on Ingredients

2.1. Ingredient Name: Potassium Carbonate (Potash).Chemical Formula: K2CO3.CAS No.: 584-08-7.EINECS Number: 209-529-3.Concentration, Wt%: 40-42%.Hazard Identification: See Heading 3.

Ingredient Name: Water.Chemical Formula: H2O.CAS No.: 7732-18-5.EINECS Number: 231-791-2.Concentration, Wt%: 58-60%.Hazard Identification: See Heading 3.

R-102 FLUSHING CONCENTRATE MATERIALSAFETY DATA SHEET CONFORMS TO DIRECTIVE 2001/58/EC

ANSULANSUL INCORPORATEDMARINETTE, WI 54143-2542


FOR HUMANS:Product:

EU Classification: Irritant.R 36/37/38 Irritating to eyes, respiratory system, and skin.S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S 36 Wear suitable protective clothing.

Components:Potassium Carbonate:

EU Classification: Harmful.R 20/21/22 Harmful by inhalation, in contact with skin, and if swallowed.S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S 36 Wear suitable protective clothing.

Water:EU Classification: Not classified as dangerous.

Limit Values for Exposure: None established.

Neither this preparation nor the substances contained in it have been listed as carcinogenic by National ToxicologyProgram, I.A.R.C., or OSHA.

SIGNS AND SYMPTOMS:Acute Exposure:

Eye Contact: Irritant. Prolonged contact can cause chemical burns.Skin Contact: Irritant. Prolonged contact can cause chemical burns.Inhalation: Can be irritating to mucous membranes.Ingestion: Irritating to mucous membranes.

Chronic Overexposure: No data available.

Medical Conditions Generally Aggravated by Exposure: None known.

FOR ENVIRONMENT:No data available.


Eye Contact: Wash with water for a minimum of 15 minutes. If irritation persists seek medical attention.Skin Contact: Wash affected area with soap and water. If irritation persists seek medical attention.Inhalation: Remove from exposure. If irritation persists seek medical attention.Ingestion: Dilute by drinking large quantities of water.

5. Fire-Fighting Measures

This preparation is an extinguishing media.There are NO extinguishing media which must not be used for safety reasons.NO special protective equipment is needed for fire-fighters. Wear protective equipment appropriate for the fire conditions.


Turn off or disconnect electrical sources in the immediate area.For personal protection: Prevent skin and eye contact, see Heading 8.Clean up: Use an absorbent material such as diatomaceous earth, sawdust, etc., and sweep up, see Heading 13.NO harm to the environment is expected from an accidental release of this preparation.

Page 2R-102 FLUSHING CONCENTRATE (Continued)


7.1. HandlingKeep separate from acids. See incompatibility information in Heading 10.

7.2. StorageNO special conditions are needed for safe storage. See Heading 10 for incompatibilities.Store in original container. Keep tightly closed until used.There is minimal danger to the environment from a storage release.

7.3. Specific useThe intended or recommended use of this preparation is as a FIRE EXTINGUISHING AGENT.

8. Exposure Controls/Personal Protection

8.1. Exposure limit valuesThere are NO currently occupational exposure limit values for this preparation or any components.

8.2. Exposure controls8.2.1. Occupational exposure controls

8.2.1.1. Respiratory protectionNot expected to be needed. Vapors will be water.

8.2.1.2. Hand protectionUse rubber gloves when handling the preparation.

8.2.1.3. Eye protectionUse safety glasses with side shields or safety goggles.

8.2.1.4. Skin protectionNo special equipment is needed.

8.2.2. Environmental exposure controlsNo special equipment is needed.

9. Physical and Chemical Properties

9.1. General informationAppearance: Clear colorless liquid.Odor: None.

9.2. Important health, safety, and environmental informationpH: 11 to 13 (at 25 °C).Boiling point/boiling range: About 110 °C (About 230 °F).Flash point: None to boiling.Flammability (solid/gas): Not flammable.Explosive properties: Not explosive.Oxidizing properties: Not an oxidizer.Vapor Pressure: About 12 mm Hg.Relative Density (Water = 1): About 1.4.Solubility:

– Water solubility: Completely soluble.– Fat solubility: Not soluble.

Partition coefficient, n-octanol/water: Not determined.Viscosity: Not determined.Vapor density: Not determined.Evaporation rate (Butyl acetate = 1): N/A.

9.3. Other informationAuto-ignition temperature: Does not ignite.


10. Stability and Reactivity

10.1. Conditions to avoidThere are no known conditions such as temperature, pressure, light, shock, etc., which may cause a dangerous reaction.

10.2. Materials to avoidAmmonium compounds, acids, corrodible metals (copper, aluminum).Reactive metals may react with the water in this preparation.Energized electrical equipment may cause a shock hazard when this fire extinguishing agent is used.

10.3. Hazardous decomposition productsNormally stable.Hazardous polymerization will not occur.Combustion or decomposition products include CO2, CO.


Toxicity data has not been determined for this product.Potassium Carbonate: Oral LD50 (rat) = 1870 mg/kg.


12.1. EcotoxicityNot determined.

12.2. MobilityNot determined.

12.3. Persistence and degradabilityNot determined.

12.4. Bioaccumulative potentialNot determined.

12.5. Other adverse effectsOzone depletion potential: None.Photochemical ozone creation potential: None.Global warming potential: Release of carbon dioxide by thermal decomposition or chemical reaction could

contribute to global warming.


No harm to the environment is expected from this preparation.Dispose of in compliance with national, regional, and local provisions that may be in force.


Hazard Class or Division: Not hazardous.There are no special precautions known.No harm to the environment is expected from this preparation.


EU Classification: Irritant.Exposure Limit Values: None.EINECS Status: All components are included in EINECS inventory or are exempt from listing.EPA TSCA Status: All components are included in TSCA inventory or are exempt from listing.Canadian DSL (Domestic Substances List): All components are included in the DSL or are exempt from listing.Environmental restrictions: None are known.Restrictions on Marketing and Use: None are known.Refer to any other national measures that may be relevant.



EU Classification: Irritant.R 36/37/38 Irritating to eyes, respiratory system, and skin.S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S 36 Wear suitable protective clothing.The EU Classification has been changed in accordance with Directive 1999/45/EC and information in the EINICS ESISfiles (Existing Substances Information System).Toxicological information added from the EINICS ESIS (Existing Substances Information System).A rating under WHMIS has been added, following the Canadian guidelines.

Format is from directive 2001/58/EC.EINECS data is from http://exb.jrc.it/existing-chemicals/Data used to compile the data sheet is from ANSUL Material Safety Data Sheet, February, 2002.

17. Disclaimer

THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT, BUT DOES NOT PURPORT TO BE ALL INCLUSIVE ANDSHALL BE USED ONLY AS A GUIDE. ANSUL SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROMHANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT.

N/A = Not Applicable NDA = No Data Available

(WHMIS) CANADIAN WORKPLACE HAZARDOUS MATERIALIDENTIFICATION SYSTEM RATINGS:This product is rated: D2B – Product may irritate skin, eyes, or mucousmembrane.

(HMIS) HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS:HEALTH: 2 4. Severe Hazard___FLAMMABILITY: 0 3. Serious Hazard___REACTIVITY: 0 2. Moderate Hazard___

1. Slight Hazard0. Minimal Hazard


TYCO FIRE SUPPRESSION & BUILDING PRODUCTS, MARINETTE, WI 54143-2542 715-735-7411 Form No. F-9762-5 Copyright ©2009 Tyco International Ltd.

MSDS available at http://www.ansul.com

ANSUL is a trademark of Tyco International Ltd. or its affiliates.


FORAY



Material name FORAY

Version # 01


CAS # Mixture



CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411















471-34-1 1 - 2.5CALCIUM CARBONATE


5468-75-7 0 - 0.1Pigment Yellow 14

63148-57-2 0.1 - 1Silicone fluid

8031-18-3 2.5 - 10FULLERS EARTH

7783-20-2 10 - 20Ammonium Sulfate

7722-76-1 60 - 80Ammonium Phosphate




Material name: FORAY


MSDS US

1 / 5








Extinguishing media


media




from the chemical

None known.


products











U.S. - OSHA




CALCIUM CARBONATE (471-34-1) 5.0000 mg/m3 Respirable fraction.PEL


5.0000 mg/m3 Respirable fraction.TWA







General hygiene

considerations

Do not get in eyes.



MSDS US

2 / 5


Appearance

Form Powder.

Color Yellow.

Odor Odorless.


pH Not available.







% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.





products

Carbon oxides.



Toxicological data


Acute Oral LD50 Rat: 6450 mg/kgCALCIUM CARBONATE (471-34-1)







LC50 Western mosquitofish (Gambusia affinis): > 56000 mg/l96.00 Hours

CALCIUM CARBONATE (471-34-1)

EC50 Water flea (Ceriodaphnia dubia): 52 - 67 mg/l 48.00hours

Ammonium Sulfate (7783-20-2)

LC50 Pink salmon (Oncorhynchus gorbuscha): 0.068 mg/l96.00 hours



MSDS US

3 / 5







products



DOT






Ammonium Phosphate (CAS 7722-76-1) 1.0 %

Ammonium Sulfate (CAS 7783-20-2) 1.0 %


Ammonium Phosphate (CAS 7722-76-1) Listed.



None


Hazard categories Acute Health - YesChronic Health - YesFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


hazardous substance

No


chemical

No

Inventory status
















MSDS US

4 / 5




CALCIUM CARBONATE (CAS 471-34-1) Listed.









MSDS US

5 / 5


MET-L-X



Material name MET-L-X

Version # 01


CAS # Mixture



CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411


Emergency overview CAUTION

Exposure to powder or dusts may be irritating to eyes, nose and throat.




Eyes Avoid contact with eyes. May cause temporary eye irritation.

Skin Avoid contact with the skin.





557-04-0 1 - 2.5Magnesium distearate

7647-14-5 80 - 90SODIUM CHLORIDE










Material name: MET-L-X


MSDS US

1 / 4



Extinguishing media


media




from the chemical

None known.


products



Personal precautions Avoid inhalation of dust from the spilled material. Wear a dust mask if dust is generated aboveexposure limits.



Methods for cleaning up Sweep up or vacuum up spillage and collect in suitable container for disposal. Collect dust usinga vacuum cleaner equipped with HEPA filter. Avoid dust formation. Following product recovery,flush area with water.




Storage Store in a well-ventilated place. Keep container tightly closed. Guard against dust accumulation ofthis material. Use care in handling/storage.

ACGIH



Components Type Value

Magnesium distearate (557-04-0) 10.0000 mg/m3TWA


Eye / face protection Use tight fitting goggles if dust is generated.


Respiratory protection Wear respirator with dust filter.

General hygiene

considerations

Do not breathe dust. Avoid contact with eyes. Handle in accordance with good industrial hygieneand safety practice.


Appearance

Form Powder.

Color Tan.

Odor Odorless.


pH Not available.








MSDS US

2 / 4


% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.





products

Carbon oxides.



Toxicological data


Acute Oral LD50 Mouse: 4000 mg/kgSODIUM CHLORIDE (7647-14-5 )



Local effects Inhalation of dusts may cause respiratory irritation.


ACGIH Carcinogens

Magnesium distearate (CAS 557-04-0) A4 Not classifiable as a human carcinogen.

Further information This product has no known adverse effect on human health.




EC50 Water flea (Daphnia magna): 340.7 - 469.2 mg/l 48.00hours

SODIUM CHLORIDE (7647-14-5 )

LC50 American eel (Anguilla rostrata): 1e-006 - 27260 mg/l96.00 hours

Ecotoxicity The product is not expected to be toxic to aquatic organisms.






products




MSDS US

3 / 4


DOT






None




hazardous substance

No


chemical

No

Inventory status























MSDS US

4 / 4


NITROGENIssue Date: 08-02-2010


Material name NITROGEN

Version # 01


CAS # 7727-37-9


CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411






Eyes None known.

Skin None known.

Inhalation Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygenbelow safe breathing levels.





7727-37-9 90 - 100NITROGEN




Skin contact Rinse with water.

Inhalation Remove to fresh air.





Extinguishing media


media


Material name: NITROGEN


MSDS US

1 / 4



from the chemical










Handling Handle and open container with care.

Storage Contents under pressure. Use care in handling/storage.






General hygiene

considerations



Appearance

Form Compressed gas.

Color Colorless.

Odor Odorless.

Physical state Gas.

pH Not available.



Boiling point -320.8 °F (-195.79 °C)




% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

0.67



VOC Not available.

Molecular weight 28.01 g/mol

Molecular formula N2



MSDS US

2 / 4



Conditions to avoid Excessive heat.


products

No hazardous decomposition products are known.










products

Not applicable.

Contaminated packaging Not applicable.


DOT


UN1066UN number

Nitrogen, compressedProper shipping name

2.2Hazard class

2.2Subsidiary hazard class


302Packaging non bulk

314, 315Packaging bulk

121ERG number

DOT





None



MSDS US

3 / 4




hazardous substance

No


chemical

No

Inventory status
















NITROGEN (CAS 7727-37-9) Listed.









MSDS US

4 / 4


PLUS-FIFTY C



Material name PLUS-FIFTY C

Version # 01


CAS # Mixture


Product use Fire extiguishing agent

CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411















14807-96-6 2.5 - 10talc (Mg3H2(SiO3)4)


147-14-8 0 - 0.1COPPER PHTHALOCYANINE PIGMENT


8031-18-3 2.5 - 10FULLERS EARTH

144-55-8 90 - 100SODIUM BICARBONATE






Material name: PLUS-FIFTY C


MSDS US

1 / 5






Extinguishing media


media




from the chemical

None known.


products











ACGIH




talc (Mg3H2(SiO3)4) (14807-96-6) 2.0000 mg/m3 Respirable fraction.TWA

U.S. - OSHA


talc (Mg3H2(SiO3)4) (14807-96-6) 2.0000 mg/m3 Respirable dust.TWA

0.1000 mg/m3 Respirable.

2.4000 mppcf Respirable.


20.0000 mppcf








MSDS US

2 / 5

General hygiene

considerations

Do not get in eyes.


Appearance

Form Powder.

Color Blue.

Odor Odorless.


pH Not available.







% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.





products

Carbon oxides.



Local effects Contact may irritate or burn eyes.



ACGIH Carcinogens

talc (Mg3H2(SiO3)4) (CAS 14807-96-6) A4 Not classifiable as a human carcinogen.

IARC Monographs. Overall Evaluation of Carcinogenicity

talc (Mg3H2(SiO3)4) (CAS 14807-96-6) 2B Possibly carcinogenic to humans.

3 Not classifiable as to carcinogenicity to humans.




LC50 Western mosquitofish (Gambusia affinis): 7550 mg/l96.00 hours

SODIUM BICARBONATE (144-55-8)




MSDS US

3 / 5






products



DOT






None




hazardous substance

No


chemical

No

Inventory status
















talc (Mg3H2(SiO3)4) (CAS 14807-96-6) Listed.





MSDS US

4 / 5







MSDS US

5 / 5


PURPLE-K



Material name PURPLE-K

Version # 01


CAS # Mixture



CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411















12001-26-2 2.5 - 10MICA



68647-14-3 1 - 2.5Purple Pigment

8031-18-3 2.5 - 10FULLERS EARTH

298-14-6 90 - 100POTASSIUM BICARBONATE






Material name: PURPLE-K


MSDS US

1 / 4






Extinguishing media


media




from the chemical

None known.


products











ACGIH




MICA (12001-26-2) 3.0000 mg/m3 Respirable fraction.TWA

U.S. - OSHA


MICA (12001-26-2) 3.0000 mg/m3 Respirable dust.TWA

20.0000 mppcf






General hygiene

considerations

Do not get in eyes.



MSDS US

2 / 4


Appearance

Form Powder.

Color Violet.

Odor Odorless.


pH Not available.







% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.





products

Carbon oxides.











products



DOT




MSDS US

3 / 4





None




hazardous substance

No


chemical

No

Inventory status




YesCanada Non-Domestic Substances List (NDSL)












MICA (CAS 12001-26-2) Listed.









MSDS US

4 / 4


SPILL-X-S



Material name SPILL-X-S

Version # 01


CAS # Mixture


Product use Spill control agent

CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411



Flammable/Combustible Material. May be ignited by heat, sparks or flames. Health injuries arenot known or expected under normal use.




Eyes Avoid contact with eyes. Dust or powder may irritate eye tissue.


Inhalation Do not breathe dust. Inhalation of dusts may cause respiratory irritation.


Target organs Eyes. Skin. Respiratory system.

Signs and symptoms Irritation of eyes and mucous membranes. Upper respiratory tract irritation.



7440-44-0 90 - 100CARBON, ACTIVATED









Material name: SPILL-X-S

1483 Version #: 01 Revision date: 07-30-2010 SC-8668

MSDS US

1 / 4



Extinguishing media


media

Use extinguishing agent suitable for type of surrounding fire.



from the chemical

None known.


products





Methods for containment None necessary.

Methods for cleaning up Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dustformation. Clean up in accordance with all applicable regulations.





ACGIH




CARBON, ACTIVATED (7440-44-0) 2.0000 mg/m3 Respirable fraction.TWA

U.S. - OSHA


CARBON, ACTIVATED (7440-44-0) 15.0000 mg/m3 Total dust.PEL

5.0000 mg/m3 Respirable fraction.

15.0000 mppcfTWA



Eye / face protection Avoid contact with eyes. Use tight fitting goggles if dust is generated.

Skin protection Wear appropriate chemical resistant clothing. Chemical resistant gloves. Wear protective gloves.


General hygiene

considerations

Do not breathe dust. Avoid contact with eyes. Avoid contact with skin. Keep away from food anddrink. Handle in accordance with good industrial hygiene and safety practice.


Appearance

Form Granular.

Color Black.

Odor Odorless.


pH Not available.



MSDS US

2 / 4







% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.



Incompatible materials Strong oxidizing agents.


products

Carbon oxides.



Toxicological data


Acute Oral LD50 Rat: > 10000 mg/kgCARBON, ACTIVATED (7440-44-0)










products



DOT




MSDS US

3 / 4





None


Hazard categories Acute Health - NoChronic Health - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No


hazardous substance

No


chemical

No

Inventory status























MSDS US

4 / 4

SAFETY DATA SHEET Nitrogen (Expellant)

Revision Date: April 10, 2015 Page 1 of 7

1. IDENTIFICATION

Product Name Nitrogen (Expellant)

Other Names N2

Recommended use of the chemical and

restrictions on use

Identified uses Fire Extinguishing Expellant

Restrictions on use Consult applicable fire protection codes

Company Identification Badger Fire Protection

944 Glenwood Station Lane, Suite 303 Charlottesville, VA 22901 USA

Customer Information Number (434)-964-3200 Emergency Telephone Number

CHEMTREC Number (800) 424-9300

(703) 527-3887 (International)

Issue Date April 10, 2015

Supersedes Date February 9, 2015

Safety Data Sheet prepared in accordance with OSHA’s Hazard Communication Standard (29 CFR 1910.1200) and the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2. HAZARD IDENTIFICATION

Hazard Classification

Gas under pressure – compressed gas

Simple Asphyxiant

Label Elements Hazard Symbols

Signal Word: Warning

Hazard Statements

Contents under pressure; may explode if heated.

May displace oxygen and cause rapid suffocation.

Precautionary Statements

Prevention

Do not enter confined space unless adequately ventilated.

In case of inadequate ventilation wear respiratory protection.



2. HAZARD IDENTIFICATION

Response

None

Storage Keep container tightly closed. Protect from sunlight and store in well-ventilated place.

Disposal None

Other Hazards

Avoid direct inhalation of undiluted gas. Can cause suffocation by reducing oxygen available for breathing. Breathing very high concentrations can cause dizziness, shortness of breath, unconsciousness or asphyxiation.

Specific Concentration Limits

The values listed below represent the percentages of ingredients of unknown toxicity.

Acute oral toxicity 0%

Acute dermal toxicity 0%

Acute inhalation toxicity 0%

Acute aquatic toxicity 100%

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms: N2 This product is a substance.

Component CAS Number Concentration Nitrogen 7727-37-9 100%

4. FIRST- AID MEASURES

Description of necessary first-aid measures

Eyes No specific measures.

Skin No specific measures.

Ingestion Ingestion is not considered a potential route of exposure.

Inhalation Remove from exposure. If there is difficulty in breathing, give oxygen. Obtain medical attention immediately.

Most important symptoms/effects, acute and delayed Aside from the information found under Description of necessary first aid measures (above) and Indication of immediate medical attention and special treatment needed, no additional symptoms and effects are anticipated.



4. FIRST- AID MEASURES

Indication of immediate medical attention and special treatment needed

Notes to Physicians Treat symptomatically.

5. FIRE - FIGHTING MEASURES

Suitable Extinguishing Media All known extinguishing media can be used. Use extinguishing media appropriate for containers in the area.

Specific hazards arising from the chemical Containers may explode in heat of fire.

Special Protective Actions for Fire-Fighters Wear full protective clothing and self-contained breathing apparatus as appropriate for specific fire conditions.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Remove leaking cylinder to a safe place. Ventilate the area. Leaks inside confined spaces may cause suffocation as oxygen is displaced and should not be entered without a self-contained breathing apparatus.

Environmental Precautions None - Material is a normal atmospheric gas.

Methods and materials for containment and cleaning up None

7. HANDLING AND STORAGE

Precautions for safe handling Containers should be properly stored and secured to prevent falling or being knocked over. Do not drag, slide or roll containers. Do not drop containers or permit them to strike against each other. Never apply flame or localized heat directly to any part of the containers.

Conditions for safe storage Store away from sources of heat or ignition. Storage area should be: - cool - dry - well ventilated - under cover - out of direct sunlight

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters Exposure limits are listed below, if they exist.

Nitrogen None established



8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Appropriate engineering controls Use with adequate ventilation (natural or mechanical), especially in a confined space.

Individual protection measures

Respiratory Protection Not normally required. In oxygen deficient atmospheres, use a self contained breathing apparatus, as an air purifying respirator will not provide protection.

Skin Protection Use leather or sturdy work gloves when handling cylinders.

Eye/Face Protection Chemical goggles or safety glasses with side shields.

Body Protection Normal work wear.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical State Compressed gas

Color Colorless

Odor None

Odor Threshold No data available

pH Not applicable

Gas Density 0.075 lb/ft3 @70oF as vapor

Boiling Range/Point (°C/F) -196oC/-321 oF

Melting Point (°C/F) -210oC/-346 oF

Flash Point (PMCC) (°C/F) Not flammable

Vapor Pressure No data available

Evaporation Rate (BuAc=1) Not applicable

Solubility in Water 0.2 g/l

Vapor Density (Air = 1) 0.97

VOC (%) Not applicable

Partition coefficient (n-

octanol/water)

No data available

Viscosity Not applicable

Auto-ignition Temperature No data available

Decomposition Temperature No data available

Upper explosive limit Not explosive

Lower explosive limit Not explosive

Flammability (solid, gas) Not flammable



10. STABILITY AND REACTIVITY

Reactivity Containers may rupture or explode if exposed to heat.

Chemical Stability Stable under normal conditions.

Possibility of hazardous reactions Hazardous polymerization will not occur.

Conditions to Avoid Extremely high temperatures

Incompatible Materials None known

Hazardous Decomposition Products None

11. TOXICOLOGICAL INFORMATION

Acute Toxicity Simple asphyxiant.

Specific Target Organ Toxicity (STOT) – single exposure Exposure to nitrogen gas at high concentrations can cause suffocation by reducing oxygen available for breathing. Breathing very high concentrations can cause dizziness, shortness of breath, unconsciousness or asphyxiation.

Specific Target Organ Toxicity (STOT) – repeat exposure No data available.

Serious Eye damage/Irritation No data available.

Skin Corrosion/Irritation No data available.

Respiratory or Skin Sensitization No data available.

Carcinogenicity Not considered carcinogenic by NTP, IARC, and OSHA.

Germ Cell Mutagenicity No data available.

Reproductive Toxicity No data available.



11. TOXICOLOGICAL INFORMATION

Aspiration Hazard Not an aspiration hazard.

12. ECOLOGICAL INFORMATION

Ecotoxicity No data available

Mobility in soil Nitrogen occurs naturally in the atmosphere.

Persistence/Degradability Nitrogen occurs naturally in the atmosphere.

Bioaccumulative Potential Nitrogen occurs naturally in the atmosphere.

Other adverse effects No relevant studies identified.

13. DISPOSAL CONSIDERATIONS

Disposal Methods Dispose of container in accordance with all applicable local and national regulations. Do not cut puncture or weld on or near to the container. If spilled, contents will vaporize to the atmosphere.

14. TRANSPORT INFORMATION

Safety Data Sheet information is intended to address a specific material and not various forms or states of containment. Specific volumes, pressures or hardware configurations containing such materials can dictate various different hazard classifications for transportation and labelling requirements. Under Federal Regulations only trained and qualified individuals are permitted to label and ship products following the applicable Department of Transportation (DOT), Federal Aviation Administration (FAA), Transport Canada (TC), International Maritime Dangerous Goods (IMDG) or International Air

Transport Association (IATA) requirements.

15. REGULATORY INFORMATION

United States TSCA Inventory All components of this product are in compliance with the inventory listing requirements of the US Toxic Substance Control Act (TSCA) Chemical Substance Inventory.

Canada DSL Inventory All ingredients in this product have been verified for inclusion on the Domestic Substance List (DSL).

SARA Title III Sect. 311/312 Categorization Pressure Hazard



15. REGULATORY INFORMATION

SARA Title III Sect. 313 This product does not contain a chemical which is listed in Section 313 at or above de minimis concentrations.

16. OTHER INFORMATION

NFPA Ratings NFPA Code for Health - 0 NFPA Code for Flammability - 0 NFPA Code for Reactivity - 0 NFPA Code for Special Hazards – None

HMIS Ratings HMIS Code for Health - 0 HMIS Code for Flammability - 0 HMIS Code for Physical Hazard - 0 HMIS Code for Personal Protection - See Section 8 *Chronic

Legend ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstracts Service IARC: International Agency for Research on Cancer LCLo: Lethal concentration low N/A: Denotes no applicable information found or available NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit SDS: Safety Data Sheet STEL: Short Term Exposure Limit TLV: Threshold Limit Value

Revision Date: April 10, 2015 Replaces: February 9, 2015 Changes made: Updated to GHS Classification. Information Source and References This SDS is prepared by Hazard Communication Specialists based on information provided by internal

company references. Prepared By: EnviroNet LLC.

The information and recommendations presented in this SDS are based on sources believed to be accurate. Badger Fire Protection assumes no liability for the accuracy or completeness of this information. It is the user's responsibility to determine the suitability of the material for their particular purposes. In particular, we make NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, with respect to such information, and we assume no liability resulting from its use. Users should ensure that any use or disposal of the material is in accordance with applicable Federal, State, and local laws and regulations.


LITH-X



Material name LITH-X

Version # 01


CAS # Mixture


Product use Fire extinguising agent

CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411



Flammable/Combustible Material. May be ignited by heat, sparks or flames. Health injuries arenot known or expected under normal use.








Target organs Eyes. Skin. Respiratory system.

Signs and symptoms Irritation of eyes and mucous membranes. Upper respiratory tract irritation.



557-04-0 1 - 2.5Magnesium distearate

7782-42-5 90 - 100GRAPHITE

2.5 - 10Other components below reportable levels








Material name: LITH-X


MSDS US

1 / 5




Extinguishing media


media

Use extinguishing agent suitable for type of surrounding fire.



from the chemical

None known.


products











ACGIH




GRAPHITE (7782-42-5) 2.0000 mg/m3 Respirable fraction.TWA

Magnesium distearate (557-04-0) 10.0000 mg/m3TWA

U.S. - OSHA


GRAPHITE (7782-42-5) 5.0000 mg/m3 Respirable fraction.PEL


15.0000 mppcfTWA


5.0000 mg/m3 Respirable fraction.






General hygiene

considerations




MSDS US

2 / 5


Appearance

Form Powder.

Color Black

Odor Odorless.


pH Not available.







% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.



Incompatible materials Strong oxidizing agents.


products

Carbon oxides.



Toxicological data


Acute Oral LD50 Rat: > 10000 mg/kgGRAPHITE (7782-42-5)



ACGIH Carcinogens

Magnesium distearate (CAS 557-04-0) A4 Not classifiable as a human carcinogen.







MSDS US

3 / 5




products



DOT






None


Hazard categories Acute Health - NoChronic Health - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No


hazardous substance

No


chemical

No

Inventory status





















MSDS US

4 / 5





MSDS US

5 / 5


SPILL-X-A



Material name SPILL-X-A

Version # 01


CAS # Mixture



CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411



Irritating to eyes. Prolonged exposure may cause chronic effects. Exposure to powder or dustsmay be irritating to eyes, nose and throat.








Target organs Eyes. RESPIRATORY SYSTEM. Skin.


Signs and symptoms Irritation of eyes and mucous membranes. Upper respiratory tract irritation. Skin irritation.



497-19-8 2.5 - 10sodium carbonate

1309-48-4 60 - 80MAGNESIUM OXIDE









Material name: SPILL-X-A


MSDS US

1 / 5




Extinguishing media


media




from the chemical

None known.


products











ACGIH




MAGNESIUM OXIDE (1309-48-4) 10.0000 mg/m3 Inhalable fraction.TWA

U.S. - OSHA


MAGNESIUM OXIDE (1309-48-4) 15.0000 mg/m3 Total particulate.PEL

10.0000 mg/m3 Total particulate.TWA






General hygiene

considerations



Appearance

Form Powder.

Color Red.



MSDS US

2 / 5

Odor Odorless.


pH Not available.







% by volume

Not available.


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.





products

Carbon oxides.



Toxicological data


Acute Inhalation LC50 Guinea pig: 0.8 mg/l 2.00 Hourssodium carbonate (497-19-8)

Acute Inhalation LC50 Mouse: 1.2 mg/l 2.00 Hours

Acute Inhalation LC50 Rat: 2.3 mg/l 2.00 Hours


Acute Other LD50 Mouse: 116.6 mg/kg 30.00 Days

Local effects Contact may irritate or burn eyes. Inhalation of dusts may cause respiratory irritation.



ACGIH Carcinogens

MAGNESIUM OXIDE (CAS 1309-48-4) A4 Not classifiable as a human carcinogen.




EC50 Water flea (Ceriodaphnia dubia): 156.6 - 298.9 mg/l48.00 hours

sodium carbonate (497-19-8)






MSDS US

3 / 5





products



DOT





None




hazardous substance

No


chemical

No

Inventory status
















MAGNESIUM OXIDE (CAS 1309-48-4) Listed.






MSDS US

4 / 5






MSDS US

5 / 5


SPILL-X-C



Material name SPILL-X-C

Version # 01


CAS # Mixture



CHEMTREC 800-424-9300 or 703-527-3887



One Stanton Street



Internet

Phone

Address

Name

Supplier


715-735-7411



Irritating to eyes. Prolonged exposure may cause chronic effects. Exposure to powder or dustsmay be irritating to eyes, nose and throat.








Target organs Eyes. RESPIRATORY SYSTEM. Skin.


Signs and symptoms Irritation of eyes and mucous membranes. Upper respiratory tract irritation. Skin irritation.



110-17-8 10 - 20FUMARIC ACID









Material name: SPILL-X-C


MSDS US

1 / 4




Extinguishing media


media




from the chemical

None known.


products

















General hygiene

considerations



Appearance

Form Powder.

Color Tan.

Odor Odorless.


pH Not available.







% by volume

Not available.



MSDS US

2 / 4


% by volume

Not available.







(n-octanol/water)

Not available



VOC Not available.





products

Carbon oxides.



Toxicological data


Acute Oral LD50 Rat: 10700 mg/kgFUMARIC ACID (110-17-8)

Acute Oral LDL0 Rabbit: 5000 mg/kg


Acute Other LDL0 Rat: 587 mg/kg

Local effects Inhalation of dusts may cause respiratory irritation.






EC50 Water flea (Daphnia magna): 204 - 220 mg/l 48.00hours

FUMARIC ACID (110-17-8)






products



DOT




MSDS US

3 / 4




FUMARIC ACID: 5000.0000




hazardous substance

No


chemical

No

Inventory status
















FUMARIC ACID (CAS 110-17-8) Listed.









MSDS US

4 / 4

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