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Proesa® by Versalis: Enabling 2G sugars for Cellulosic Ethanol and Green Chemistry Dario Giordano Licensing Green Chemistry Manager 2nd EU India Conference on advanced biofuels, New Delhi 11-13 March 2019
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Proesa® by Versalis: Enabling 2G sugars for Cellulosic Ethanol and Green Chemistry

Dario Giordano Licensing Green Chemistry Manager 2nd EU India Conference on advanced biofuels, New Delhi 11-13 March 2019

Versalis roots in the chemical history

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Since 1950s …

A worldwide presence

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Versalis Pacific India (Mumbai)

Versalis International

(Bruxelles)

Versalis Americas (Houston)

Versalis Pacific Trading (Shanghai

and Qingdao)

Versalis Deutschland (Oberhausen)

Dunastyr (Budapest, Százhalombatta)

Versalis France (Dunkerque)

Versalis Kimya (Istanbul)

Versalis Congo and Versalis Ghana

Commercial network

Production plants

Versalis Singapore

Lotte Versalis Elastomers (South Korea) – in JV with Lotte Chemical

Versalis UK (Grangemouth)

Versalis S.p.A. Headquarter and 8 Italian production plants

5,100 employees 4.9 billion € turnover 5 research centres >310 patents

Tailored strategic guidelines for each Business

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Business Unit Intermediates

Business Unit Polyethylene

Business Unit Styrenics

Business Unit Elastomers

Business Unit Biotech

Oilfield chemicals

Greater efficiency and integration

Rationalization of production capacity

Selective growth in insulation

Upgrade of product portfolio

Market-driven business development

Market-driven business development

Opportunities for downstream integration

Optimization of production mix

New production technologies

International development

Technological leadership (R&D and partnerships)

Know-how enlargement

versalis

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Versalis is an established licensor in the traditional chemical business

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Phenol & Derivatives DMC & Derivatives

Polyethylene

Styrenics

Elastomers

Proprietary Catalysts

Cumene PBE-1TM Zeolite catalyst based*

Phenol & Acetone*

DMC & Derivatives via CO & MEOH*

DPC*

LDPE

EVA

Ethylbenzene PBE-1/2TM Zeolite catalyst based

Styrene

GPPS

HIPS

EPS suspension

ABS in continuous mass

SAN

e-SBR

s-SBR

high cis BR

low cis BR

NBR

TPR

EP(D)M

HSL

XSBR

Titanium Silicalite

PBE-1TM Zeolite

PBE-2TM Zeolite

Acetone to IPA*

Acetone to Cumene via IPA**

High selectivity Cyclohexanone e KA-oil

Ammoxymation with TS1TM Cyclohexanone and H2O2

* Licensed through Lummus Technology (a McDermott Company) ** Close to commercialization

Versalis licensed over 5 M ton of capacity

M&G bio activities acquisition

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R&D Rivalta Engineering and

Commercialization of PROESA® Technology Tortona

IBP (Italian BioProduct) - IBP Energia - Production plant of 2G sugars and bioethanol from biomasses Crescentino

November 1st, 2018

Tailored strategic guidelines for each Business

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Business Unit Intermediates

Business Unit Polyethylene

Business Unit Styrenics

Business Unit Elastomers

Business Unit Biotech

Oilfield chemicals

Greater efficiency and integration

Rationalization of production capacity

Selective growth in insulation

Upgrade of product portfolio

Market-driven business development

Market-driven business development

Opportunities for downstream integration

Optimization of production mix

New production technologies

International development

Technological leadership (R&D and partnerships)

Know-how enlargement

versalis

Business Unit Biotech

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Business Unit Biotech

Market-driven business development

Technological leadership (R&D and partnerships)

Matrìca JV with Novamont

Bio –butadiene from sugars JV with Genomatica

Metathesis & Hydrogenation partnership with Elevance

Bridgestone Guayule development

New– bio assets Mossi Ghisolfi

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Versalis has an integrated platform for chemical from renewables

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Business Unit Biotech

Market-driven business development

Technological leadership (R&D and partnerships)

Biomasses Products

Lignocellulosic residues

Oil seeds

Guayule

Food industry waste by products

Bio – fuels Bio-chemicals Bio- herbicides

Cosmetic products Intermediates for

bio- plastic and bio-fibers Natural rubber

versalis

PROESA® technology: a perfect solution for bio-refineries

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PROESATM Technology is the enabler of biomass based biorefineries Other bio -fuel

Chemicals and materials

Ethanol Non-food Biomass

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2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018

PROESA® technology development to date ...

LAB PILOT

Industrial demo plant CRESCENTINO

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Biomasses: versatility of technology in the use of biomasses (hardwood, energy crops, agricultural residues) Steam explosion: no use of chemicals in biomass pretreatment (i.e simple metallurgy) Partners: involvement of leader partners in the enzymes and yeasts fields IP : totally in-house

PROESA®: the only technology proven at industrial scale

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CRESCENTINO SITE

Industrial unit located in Italy, based on PROESA®

technology

Includes ethanol section, power generation, biogas generation integrated with WWT

Several biomasses used as plant feedstock

Ethanol production proven at industrial scale

Power plant operated at 13 MWe

Green energy excess sold to the grid

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Perfect fit for the Indian market

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New Indian policy on biofuels 2018 Biomass availability Ethanol deficit

Proesa® Technology is the solution:

Flexible – in terms of feedstock and therefore siting

Proven – at commercial scale

Competitive – combination of low capex and opex

Guaranteed – backed by performance guarantees on critical parameters

Sustainable – Versalis is committed to continuous improvement in order to remain industry leader and deliver further value to its customers

The committed licensor for your next 2G ethanol industrial project

The industry leader committed to reinforce its competitive position with regards to chemistry from renewables

A reliable licensor ready to operate long term in the demanding Indian market

Versalis is:

versalis

year Sugar cane production [MMT]

Ethanol availability [Bill lit]

Fuel ethanol deficit case 5% [Bill lit]

Fuel ethanol deficit case 10% [Bill lit]

Fuel ethanol deficit case 20% [Bill lit]

2016 -17 397 3.22 -0.7 -2.1 -4.9

2021 -22 483 3.91 -1.5 -3.4 -7.4

…commitment to technology development

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Biomasses Technological platform for the sugars production from biomass PROESA®

Bio-ethanol 2G Bio-chemicals Bio-oil

Feedstock for Green Refinery

Existing platform Planned developments

Co-generation energy

Residual biomass from Versalis/Bridgestone technological platform from guayule

Integrated platform of chemistry from renewables synergistic with Versalis projects as Guayule, Bio Butadiene and High Oleic Bio Oil for Matrica and PHA

«Advanced» biofuels for diesel & kero

Lignin byproduct can be used as component of several materials

Today: energy Tomorrow: marine coatings, plastic composites, bricks, bitumens, etc.

versalis

Is a well established player with a long tradition in the chemical history Is a well established licensor in the traditional chemistry Is committed to circular economy and green chemistry 2G cellulosic sugar is a perfect fit in the strategic development towards green chemistry launched

sever years ago Proesa® Technology is a great addition to our portfolio

…VERSALIS IS READY FOR THE INDIAN MARKET!

PROESA® FOR 2G ETHANOL AND BEYOND

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Summary

VERSALIS:

versalis


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