Prof Baoguo Zhao
Professor Baoguo Zhao received his BSc in chemistry from Wuhan
University in 1996 and his MSc in organic chemistry under the
supervision of Professor Jianhua Xu from Nanjing University in 2002 He
obtained his PhD in organic chemistry under the supervision of Professor
Kuiling Ding at Shanghai Institute of Organic Chemistry Chinese
Academy of Science in 2006 He did postdoctoral research with Professor
Yian Shi at Colorado State University from 2006 to 2011 Since
September 2011 he has been appointed as a professor at the Chemistry Department of Shanghai
Normal University
Address 100 guiling Road Room 8-217 Shanghai 200234 China
Email zhaobg2006shnueducn
Research Interests
A Vitamin B6 based biomimetic asymmetric catalysis
Vitamin B6 family ie pyridoxal 5rsquo-phospate (PLP) and pyridoxamine 5prime-phosphate are one
of the most important coenzymes for many crucial biological transformations such as
transamination racemization of chiral amino acids deamination aldol condensation (threonine
synthesis) retro claisen cleavage β-substitution (tryptophane synthesis) etc Although the vitamin
B6 has displayed versatile catalytic power in biological systems its catalytic potential has not been
fully recognized in organic chemistry and awaits to be explored Based on the unique structure of
vitamin B6 we design and synthesize chiral pyridoxals and pyridoxamines and imitate biological
processes for development of new biomimetic synthesis methodologies (Scheme 1) So far we
have developed chiral pyridoxalpyridoxamine catalyzed biomimetic asymmetric transamination
(Scheme 2) as well as biomimetic asymmetric carbonyl catalysis process (Schemes 3 and 4)
Scheme 1 Vitamin B6 based biomimetic catalysis
(a) Biomimetic asymmetric transamination
Transaminases are capable to catalyze the transformation of carbonyl compounds such as
-keto acids and unactivated ketones and aldehydes to the corresponding chiral amines By using
chiral pyridoxals or pyridoxamines as the catalyst we have developed biomimetic asymmetric
transamination of -keto acids -ketoamides and trifluromethyl ketones respectively to chiral
-amino acids polypeptides and trifluromethyl amines with excellent enantioselectivity and
stereoselectivity under very mild conditions Our continuing studies include further development of
more efficient catalytic processes and expanding substrate scope
Scheme 2 Biomimetic asymmetric transamination
(b) Biomimetic carbonyl catalysis
Enamine catalysis is a strategy to use chiral amines as catalysts to activate carbonyl groups for
α-functionalization (Scheme 3) As sharing the same imine intermediate carbonyl catalysis is a
reverse strategy for activation of primary amines with carbonyl compounds as catalysts (Scheme 3)
By using N-quaternized pyridoxals as carbonyl catalysts we have developed biomimetic carbonyl
catalysis process for -functionalization of primary amines without additional NH2 protecting
manipulations (Scheme 4) Our continuing studies will focus on exploring and expanding more
applications of carbonyl catalysis in organic synthesis
Scheme 3 Carbonyl catalysis vs enamine catalysis
Scheme 4 Biomimetic carbonyl catalysis for asymmetric -functionalization of amines
B Biomimetic Total Synthesis
We are interested in biomimetic total synthesis of natural products and related compounds
with high bioactivities Bioactive properties will also be studied
Publications
(43) Jianfeng Chen12dagger Xing Gong1dagger Jianyu Li1 Yingkun Li1 Jiguo Ma1 Chengkang Hou1
Guoqing Zhao1 Weicheng Yuan2 Baoguo Zhao1 ldquoCarbonyl Catalysis Enables a
Biomimetic Asymmetric Mannich Reactionrdquo Science 2018 in press
(42) Tao Ding1 Yazhen Duan2 Hui Li2 Baoguo Zhao1 Jun Yang2 ldquoAn Efficient HCl Promoted
Petasis Reaction of 2-Pyridinecarbaldehydes Amines and 12-Oxborol-2(5H)-olsrdquo
Tetrahedron Lett 2018 59 2502
(41) Chengkang Hou Guoqing Zhao Dongfang Xu Baoguo Zhao ldquoEnantioselective
Biomimetic Transamination of -Keto Acids Catalyzed by H4-Naphthalene-Derived Axially
Chiral Biaryl Pyridoxaminesrdquo Tetrahedron Lett 2018 59 1028
(40) Dongfang Xu Baoguo Zhao ldquoHighly Regioselective Hydroformylation of Olefins with
Formic Acid Instead of Toxic and Flammable COH2rdquo Sci China Chem 2017 60 839
(39) Feng Liu Jiaxin Tian Yong Liu Chuangan Tao Hao Zhu Aina Zhang Dongfang Xu and
Baoguo Zhao ldquoDecarboxylative Umpolung of Conjugated Enal to β-Carbanion for
Intramolecular Nucleophilic Addition to Aldehyderdquo Org Chem Front 2017 4 1586
(38) Yong Ethan Liu Zhaole Lu Bo Li Jiaxin Tian Feng Liu Junyu Zhao Chengkang Hou
Yingkun Li Lili Niu Baoguo Zhao ldquoEnzyme-Inspired Axially Chiral Pyridoxamines Armed
with a Cooperative Lateral Amine Chain for Enantioselective Biomimetic Transaminationrdquo J
Am Chem Soc 2016 138 10730
(37) Xiaoyu Lan Chuangan Tao Xuliang Liu Aina Zhang Baoguo Zhao ldquoAsymmetric
Transamination of α-Keto Acids Catalyzed by Chiral Pyridoxaminesrdquo Org Lett 2016 18
3658
(36) Jianfeng Chen Junyu Zhao Xing Gong Dongfang Xu Baoguo Zhao ldquoA new type of
chiral-pyridoxamines for catalytic asymmetric transamination of -keto acidsrdquo Tetrahedron
Lett 2016 57 4612
(35) Limin Shi Chuangan Tao Qin Yang Yong Ethan Liu Jing Chen Jianfeng Chen Jiaxin Tian
Feng Liu Bo Li Yongling Du Baoguo Zhao ldquoChiral Pyridoxal-Catalyzed Asymmetric
Biomimetic Transamination of α-Keto Acidsrdquo Org Lett 2015 17 5784
(34) Bin Rong Qin Yang Hong Xu Yifan Hu Xuejing Cheng Yong Liu Baoguo Zhao
ldquoPd-catalyzed Asymmetric α-Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2015 56
595
(33) Juan Xu Jing Chen Lei Ding Xuliang Liu Dongfang Xu Baoguo Zhao ldquoSynthesis of
α-Methylene-γ-amino acid Esters from Aldehydes via Aminative Umpolung Strategyrdquo Adv
Synth Catal 2014 356 3219
(32) Xuliang Liu Ang Gao Lei Ding Juan Xu Dongfang Xu Baoguo Zhao ldquoAminative
Umpolung Synthesis of Vicinal Amines from Aromatic Aldehydesrdquo Org Lett 2014 16
2118
(31) Lei Ding Jing Chen Yifan Hu Juan Xu Xing Gong Dongfang Xu Baoguo Zhao Hexing
Li ldquoAminative Umpolung of Aldehydes to α-Amimo Anion Equivalents for Pd-catalyzed
Allyation An Efficient Synthesis of Homoallylic Aminesrdquo Org Lett 2014 16 720
(30) Bing Rong Lei Ding Hailei Yu Qing Yang Xuliang Liu Dongfang Xu Baoguo Zhao
ldquoPd-Catalyzed Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2013 54 6501
(29) Baoguo Zhao Zhaobin Han Kuiling Ding ldquoN-H Functions in Organometallic Catalysisrdquo
Angew Chem Int Ed 2013 52 4744
(28) Hailei Yu Xuliang Liu Lei Ding Qin Yang Bin Rong Ang Gao Baoguo Zhao Haifeng
Yang ldquoPd-Catalyzed α-Arylation of Thioamidesrdquo Tetrahedron Lett 2013 54 3060
(27) Richard G Cornwall Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Synthesis of Cyclic
Sulfamides from Conjugated Dienesrdquo Org Lett 2013 15 796
(26) Yingguang Zhu Baoguo Zhao Yian Shi ldquoHighly Efficient Cu(I)-Catalyzed Oxidation of
Alcohols to Ketones and Aldehydes with Diaziridinonerdquo Org Lett 2013 15 992
(25) Thomas A Ramirez Baoguo Zhao and Yian Shi ldquoRecent advances in transition
metal-catalyzed sp3 CndashH amination adjacent to double bonds and carbonyl groupsrdquo Chem
Soc Rev 2012 41 931-942
(24) Baoguo Zhao Xingao Peng Yingguang Zhu Thamos A Ramirez Richard G Cornwall
Yian Shi ldquoCu(I)-Catalyzed Diamination of Conjugated Dienes Complementary
Regioselectivity from Two Distinct Mechanistic Pathwaysrdquo J Am Chem Soc 2011 133
20890-20900
(23) Xingao Peng Yingguang Zhu Thomas A Ramirez Baoguo Zhao Yian Shi ldquoNew
Reactivity of Oxaziridine Pd(II)-Catalyzed Aromatic C-H Ethoxycarbonylation via C-C
Bond Cleavagerdquo Org Lett 2011 13 5244-5247
(22) Richard G Cornwall Baoguo Zhao Yian Shi ldquoComplementary Regioselectivity in the
Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamidesrdquo Org Lett
2011 13 434-437
(21) Baoguo Zhao Xingao Peng Sunliang Cui Yian Shi ldquoCu(I)-catalyzed Regioselective
Diamination of Conjugated Dienes via Dual Mechanistic Pathwaysrdquo J Am Chem Soc 2010
132 11009-11011
(20) Baoguo Zhao Haifeng Du Sunliang Cui Yian Shi ldquoSynthetic and Mechanistic Studies of
Pd(0)-Catalyzed Diamination of Conjugated Dienesrdquo J Am Chem Soc 2010 132
3523-3532
(19) Baoguo Zhao Haifeng Du Renzhong Fu Yian Shi ldquoPd(0)-Catalyzed Asymmetric Allylic
and Homoallylic Diamination of 4-Phenyl-1-butene with Di-tert-butyldiaziridinonerdquo Org
Synth 2010 87 263
(18) Thamos A Ramirez Baoguo Zhao Yian Shi ldquoAn effective C-C Double bond formation via
Cu(I)-Catalyzed dehydrogenationrdquo Tetrahedron Lett 2010 51 1822-1825
(17) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-catalyzed Diamination of Conjugated Olefins
with Tunable Counteranions A Possible Approach to Asymmetric Diaminationrdquo J Org
Chem 2009 74 8392-8395
(16) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed C-H α-Amination of Aryl Ketones
Direct Synthesis of Imidazolinonesrdquo J Org Chem 2009 74 4411-4413
(15) Yuehong Wen Baoguo Zhao Yian Shi ldquoCu(I)-Catalyzed Diamination of Disubstituted
Terminal Olefins An Approach to Potent NK1 Antagonistrdquo Org Lett 2009 11 2365-2368
(14) Rengzhong Fu Baoguo Zhao Yian Shi ldquoSynthesis of (+)-CP-99994 via Pd(0)-Catalyzed
Asymmetric Allylic and Homoallylic C-H Diamination of Terminal Olefinrdquo J Org Chem
2009 74 7577-7580
(13) Haifeng Du Baoguo Zhao Yian Shi Pd(0)-Catalyzed Diamination of
trans-1-Phenyl-13-butadiene with Di-tert-butyldiaziridinone as Nitrogen Sourcerdquo Org Synth
2009 86 315
(12) Baoguo Zhao Haifeng Du Yian Shi ldquoA Cu(I)-Catalyzed C-H α-Amination of Esters Direct
Synthesis of Hydantoinsrdquo J Am Chem Soc 2008 130 7220-7221
(11) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Cycloguanidination of Olefinsrdquo Org
Lett 2008 10 1087-1090
(10) Haifeng Du Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Allylic and Homoallylic
Diamination of Terminal Olefins via Formal C-H Activationrdquo J Am Chem Soc 2008 130
8590-8591
(9) Haifeng Du Baoguo Zhao Weicheng Yuan Yian Shi ldquoCu(I)-Catalyzed Asymmetric
Diamination of Conjugated Dienesrdquo Org Lett 2008 10 4231-4234
(8) Baoguo Zhao Xingao Peng Zheng wang Chungu Xia Kuiling Ding ldquoModular Chiral
Bidentate Phosphonites Design Synthesis and Application in Catalytic Asymmetric
Hydroformylation Reactionsrdquo Chem Eur J 2008 14 7847-7857
(7) Baoguo Zhao Weicheng Yuan Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Intermolecular
Diamination of Activated Terminal Olefinsrdquo Org Lett 2007 9 4943-4945
(6) Haifeng Du Baoguo Zhao Yian Shi ldquoA Facile Pd(0)-Catalyzed Regio- and Stereoselective
Diamination of Conjugated Dienes and Trienesrdquo J Am Chem Soc 2007 129 762-763
(5) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoA Pd(0)-Catalyzed Diamination of
Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under
Solvent-Free Conditionsrdquo J Am Soc Chem 2007 129 7496-7497
(4) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Diamination
of Conjugated Dienes and Trienerdquo J Am Soc Chem 2007 129 11688-11689
(3) Weicheng Yuan Haifeng Du Baoguo Zhao Yian Shi ldquoA Mild Cu(I)-Catalyzed
Regioselective Diamination of Conjugated Dienesrdquo Org Lett 2007 9 2589-2591
(2) Baoguo Zhao Zheng Wang Kuiling Ding ldquoPractical by Ligand Design A New Generation
of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective
Hydrogenationsrdquo Adv Synth Catal 2006 348 1049-1057
(1) Min Zhang Huiying An Baoguo Zhao Jianhua Xu ldquoAromatic annulation strategy for
naphthalenes fused at 12- and 34-positions with two heterocyclesrdquo Org Biomol
Chem 2006 4 33-35
Patents
(6) 赵宝国刘勇卢兆乐李波ldquo一种手性联芳骨架吡哆胺类催化剂及其合成方
法与应用rdquo 申请号201610444057X
(5) 赵宝国陈剑锋赵濬宇龚幸ldquo一种新型手性开链吡哆胺催化剂及其合成方法与应
用rdquo 专利号2016104441125
(4) 赵宝国兰晓宇 陶创安 刘旭亮ldquo一种手性吡哆胺催化剂及其合成方法和应用rdquo
专利号2016104431284
(3) 赵宝国陈静石力敏刘勇杨琴陈剑锋田家昕陶创安李波许东芳ldquo一
种新型吡哆素衍生物及其制备方法rdquo专利号2015104139003
(2) 赵宝国陈静杨琴陈剑锋石力敏刘勇(Yong Ethan Liu)龚幸兰晓宇
卢兆乐刘勇 (Yong Liu)陶创安田家昕许东芳ldquo一种吡哆醛催化剂及其合成
方法与应用rdquo专利号2015104150464
(1) 赵宝国陶创安石力敏刘勇陈静ldquo一种手性吡哆醛催化剂及其合成方法与应
用rdquo专利号2015104271774
Awards
(1) 入选上海市东方学者特聘教授2010 年
(2) 入选教育部ldquo新世纪优秀人才计划rdquo2012 年
(3) 入选上海市ldquo浦江人才计划rdquo2012 年
stereoselectivity under very mild conditions Our continuing studies include further development of
more efficient catalytic processes and expanding substrate scope
Scheme 2 Biomimetic asymmetric transamination
(b) Biomimetic carbonyl catalysis
Enamine catalysis is a strategy to use chiral amines as catalysts to activate carbonyl groups for
α-functionalization (Scheme 3) As sharing the same imine intermediate carbonyl catalysis is a
reverse strategy for activation of primary amines with carbonyl compounds as catalysts (Scheme 3)
By using N-quaternized pyridoxals as carbonyl catalysts we have developed biomimetic carbonyl
catalysis process for -functionalization of primary amines without additional NH2 protecting
manipulations (Scheme 4) Our continuing studies will focus on exploring and expanding more
applications of carbonyl catalysis in organic synthesis
Scheme 3 Carbonyl catalysis vs enamine catalysis
Scheme 4 Biomimetic carbonyl catalysis for asymmetric -functionalization of amines
B Biomimetic Total Synthesis
We are interested in biomimetic total synthesis of natural products and related compounds
with high bioactivities Bioactive properties will also be studied
Publications
(43) Jianfeng Chen12dagger Xing Gong1dagger Jianyu Li1 Yingkun Li1 Jiguo Ma1 Chengkang Hou1
Guoqing Zhao1 Weicheng Yuan2 Baoguo Zhao1 ldquoCarbonyl Catalysis Enables a
Biomimetic Asymmetric Mannich Reactionrdquo Science 2018 in press
(42) Tao Ding1 Yazhen Duan2 Hui Li2 Baoguo Zhao1 Jun Yang2 ldquoAn Efficient HCl Promoted
Petasis Reaction of 2-Pyridinecarbaldehydes Amines and 12-Oxborol-2(5H)-olsrdquo
Tetrahedron Lett 2018 59 2502
(41) Chengkang Hou Guoqing Zhao Dongfang Xu Baoguo Zhao ldquoEnantioselective
Biomimetic Transamination of -Keto Acids Catalyzed by H4-Naphthalene-Derived Axially
Chiral Biaryl Pyridoxaminesrdquo Tetrahedron Lett 2018 59 1028
(40) Dongfang Xu Baoguo Zhao ldquoHighly Regioselective Hydroformylation of Olefins with
Formic Acid Instead of Toxic and Flammable COH2rdquo Sci China Chem 2017 60 839
(39) Feng Liu Jiaxin Tian Yong Liu Chuangan Tao Hao Zhu Aina Zhang Dongfang Xu and
Baoguo Zhao ldquoDecarboxylative Umpolung of Conjugated Enal to β-Carbanion for
Intramolecular Nucleophilic Addition to Aldehyderdquo Org Chem Front 2017 4 1586
(38) Yong Ethan Liu Zhaole Lu Bo Li Jiaxin Tian Feng Liu Junyu Zhao Chengkang Hou
Yingkun Li Lili Niu Baoguo Zhao ldquoEnzyme-Inspired Axially Chiral Pyridoxamines Armed
with a Cooperative Lateral Amine Chain for Enantioselective Biomimetic Transaminationrdquo J
Am Chem Soc 2016 138 10730
(37) Xiaoyu Lan Chuangan Tao Xuliang Liu Aina Zhang Baoguo Zhao ldquoAsymmetric
Transamination of α-Keto Acids Catalyzed by Chiral Pyridoxaminesrdquo Org Lett 2016 18
3658
(36) Jianfeng Chen Junyu Zhao Xing Gong Dongfang Xu Baoguo Zhao ldquoA new type of
chiral-pyridoxamines for catalytic asymmetric transamination of -keto acidsrdquo Tetrahedron
Lett 2016 57 4612
(35) Limin Shi Chuangan Tao Qin Yang Yong Ethan Liu Jing Chen Jianfeng Chen Jiaxin Tian
Feng Liu Bo Li Yongling Du Baoguo Zhao ldquoChiral Pyridoxal-Catalyzed Asymmetric
Biomimetic Transamination of α-Keto Acidsrdquo Org Lett 2015 17 5784
(34) Bin Rong Qin Yang Hong Xu Yifan Hu Xuejing Cheng Yong Liu Baoguo Zhao
ldquoPd-catalyzed Asymmetric α-Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2015 56
595
(33) Juan Xu Jing Chen Lei Ding Xuliang Liu Dongfang Xu Baoguo Zhao ldquoSynthesis of
α-Methylene-γ-amino acid Esters from Aldehydes via Aminative Umpolung Strategyrdquo Adv
Synth Catal 2014 356 3219
(32) Xuliang Liu Ang Gao Lei Ding Juan Xu Dongfang Xu Baoguo Zhao ldquoAminative
Umpolung Synthesis of Vicinal Amines from Aromatic Aldehydesrdquo Org Lett 2014 16
2118
(31) Lei Ding Jing Chen Yifan Hu Juan Xu Xing Gong Dongfang Xu Baoguo Zhao Hexing
Li ldquoAminative Umpolung of Aldehydes to α-Amimo Anion Equivalents for Pd-catalyzed
Allyation An Efficient Synthesis of Homoallylic Aminesrdquo Org Lett 2014 16 720
(30) Bing Rong Lei Ding Hailei Yu Qing Yang Xuliang Liu Dongfang Xu Baoguo Zhao
ldquoPd-Catalyzed Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2013 54 6501
(29) Baoguo Zhao Zhaobin Han Kuiling Ding ldquoN-H Functions in Organometallic Catalysisrdquo
Angew Chem Int Ed 2013 52 4744
(28) Hailei Yu Xuliang Liu Lei Ding Qin Yang Bin Rong Ang Gao Baoguo Zhao Haifeng
Yang ldquoPd-Catalyzed α-Arylation of Thioamidesrdquo Tetrahedron Lett 2013 54 3060
(27) Richard G Cornwall Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Synthesis of Cyclic
Sulfamides from Conjugated Dienesrdquo Org Lett 2013 15 796
(26) Yingguang Zhu Baoguo Zhao Yian Shi ldquoHighly Efficient Cu(I)-Catalyzed Oxidation of
Alcohols to Ketones and Aldehydes with Diaziridinonerdquo Org Lett 2013 15 992
(25) Thomas A Ramirez Baoguo Zhao and Yian Shi ldquoRecent advances in transition
metal-catalyzed sp3 CndashH amination adjacent to double bonds and carbonyl groupsrdquo Chem
Soc Rev 2012 41 931-942
(24) Baoguo Zhao Xingao Peng Yingguang Zhu Thamos A Ramirez Richard G Cornwall
Yian Shi ldquoCu(I)-Catalyzed Diamination of Conjugated Dienes Complementary
Regioselectivity from Two Distinct Mechanistic Pathwaysrdquo J Am Chem Soc 2011 133
20890-20900
(23) Xingao Peng Yingguang Zhu Thomas A Ramirez Baoguo Zhao Yian Shi ldquoNew
Reactivity of Oxaziridine Pd(II)-Catalyzed Aromatic C-H Ethoxycarbonylation via C-C
Bond Cleavagerdquo Org Lett 2011 13 5244-5247
(22) Richard G Cornwall Baoguo Zhao Yian Shi ldquoComplementary Regioselectivity in the
Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamidesrdquo Org Lett
2011 13 434-437
(21) Baoguo Zhao Xingao Peng Sunliang Cui Yian Shi ldquoCu(I)-catalyzed Regioselective
Diamination of Conjugated Dienes via Dual Mechanistic Pathwaysrdquo J Am Chem Soc 2010
132 11009-11011
(20) Baoguo Zhao Haifeng Du Sunliang Cui Yian Shi ldquoSynthetic and Mechanistic Studies of
Pd(0)-Catalyzed Diamination of Conjugated Dienesrdquo J Am Chem Soc 2010 132
3523-3532
(19) Baoguo Zhao Haifeng Du Renzhong Fu Yian Shi ldquoPd(0)-Catalyzed Asymmetric Allylic
and Homoallylic Diamination of 4-Phenyl-1-butene with Di-tert-butyldiaziridinonerdquo Org
Synth 2010 87 263
(18) Thamos A Ramirez Baoguo Zhao Yian Shi ldquoAn effective C-C Double bond formation via
Cu(I)-Catalyzed dehydrogenationrdquo Tetrahedron Lett 2010 51 1822-1825
(17) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-catalyzed Diamination of Conjugated Olefins
with Tunable Counteranions A Possible Approach to Asymmetric Diaminationrdquo J Org
Chem 2009 74 8392-8395
(16) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed C-H α-Amination of Aryl Ketones
Direct Synthesis of Imidazolinonesrdquo J Org Chem 2009 74 4411-4413
(15) Yuehong Wen Baoguo Zhao Yian Shi ldquoCu(I)-Catalyzed Diamination of Disubstituted
Terminal Olefins An Approach to Potent NK1 Antagonistrdquo Org Lett 2009 11 2365-2368
(14) Rengzhong Fu Baoguo Zhao Yian Shi ldquoSynthesis of (+)-CP-99994 via Pd(0)-Catalyzed
Asymmetric Allylic and Homoallylic C-H Diamination of Terminal Olefinrdquo J Org Chem
2009 74 7577-7580
(13) Haifeng Du Baoguo Zhao Yian Shi Pd(0)-Catalyzed Diamination of
trans-1-Phenyl-13-butadiene with Di-tert-butyldiaziridinone as Nitrogen Sourcerdquo Org Synth
2009 86 315
(12) Baoguo Zhao Haifeng Du Yian Shi ldquoA Cu(I)-Catalyzed C-H α-Amination of Esters Direct
Synthesis of Hydantoinsrdquo J Am Chem Soc 2008 130 7220-7221
(11) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Cycloguanidination of Olefinsrdquo Org
Lett 2008 10 1087-1090
(10) Haifeng Du Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Allylic and Homoallylic
Diamination of Terminal Olefins via Formal C-H Activationrdquo J Am Chem Soc 2008 130
8590-8591
(9) Haifeng Du Baoguo Zhao Weicheng Yuan Yian Shi ldquoCu(I)-Catalyzed Asymmetric
Diamination of Conjugated Dienesrdquo Org Lett 2008 10 4231-4234
(8) Baoguo Zhao Xingao Peng Zheng wang Chungu Xia Kuiling Ding ldquoModular Chiral
Bidentate Phosphonites Design Synthesis and Application in Catalytic Asymmetric
Hydroformylation Reactionsrdquo Chem Eur J 2008 14 7847-7857
(7) Baoguo Zhao Weicheng Yuan Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Intermolecular
Diamination of Activated Terminal Olefinsrdquo Org Lett 2007 9 4943-4945
(6) Haifeng Du Baoguo Zhao Yian Shi ldquoA Facile Pd(0)-Catalyzed Regio- and Stereoselective
Diamination of Conjugated Dienes and Trienesrdquo J Am Chem Soc 2007 129 762-763
(5) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoA Pd(0)-Catalyzed Diamination of
Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under
Solvent-Free Conditionsrdquo J Am Soc Chem 2007 129 7496-7497
(4) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Diamination
of Conjugated Dienes and Trienerdquo J Am Soc Chem 2007 129 11688-11689
(3) Weicheng Yuan Haifeng Du Baoguo Zhao Yian Shi ldquoA Mild Cu(I)-Catalyzed
Regioselective Diamination of Conjugated Dienesrdquo Org Lett 2007 9 2589-2591
(2) Baoguo Zhao Zheng Wang Kuiling Ding ldquoPractical by Ligand Design A New Generation
of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective
Hydrogenationsrdquo Adv Synth Catal 2006 348 1049-1057
(1) Min Zhang Huiying An Baoguo Zhao Jianhua Xu ldquoAromatic annulation strategy for
naphthalenes fused at 12- and 34-positions with two heterocyclesrdquo Org Biomol
Chem 2006 4 33-35
Patents
(6) 赵宝国刘勇卢兆乐李波ldquo一种手性联芳骨架吡哆胺类催化剂及其合成方
法与应用rdquo 申请号201610444057X
(5) 赵宝国陈剑锋赵濬宇龚幸ldquo一种新型手性开链吡哆胺催化剂及其合成方法与应
用rdquo 专利号2016104441125
(4) 赵宝国兰晓宇 陶创安 刘旭亮ldquo一种手性吡哆胺催化剂及其合成方法和应用rdquo
专利号2016104431284
(3) 赵宝国陈静石力敏刘勇杨琴陈剑锋田家昕陶创安李波许东芳ldquo一
种新型吡哆素衍生物及其制备方法rdquo专利号2015104139003
(2) 赵宝国陈静杨琴陈剑锋石力敏刘勇(Yong Ethan Liu)龚幸兰晓宇
卢兆乐刘勇 (Yong Liu)陶创安田家昕许东芳ldquo一种吡哆醛催化剂及其合成
方法与应用rdquo专利号2015104150464
(1) 赵宝国陶创安石力敏刘勇陈静ldquo一种手性吡哆醛催化剂及其合成方法与应
用rdquo专利号2015104271774
Awards
(1) 入选上海市东方学者特聘教授2010 年
(2) 入选教育部ldquo新世纪优秀人才计划rdquo2012 年
(3) 入选上海市ldquo浦江人才计划rdquo2012 年
B Biomimetic Total Synthesis
We are interested in biomimetic total synthesis of natural products and related compounds
with high bioactivities Bioactive properties will also be studied
Publications
(43) Jianfeng Chen12dagger Xing Gong1dagger Jianyu Li1 Yingkun Li1 Jiguo Ma1 Chengkang Hou1
Guoqing Zhao1 Weicheng Yuan2 Baoguo Zhao1 ldquoCarbonyl Catalysis Enables a
Biomimetic Asymmetric Mannich Reactionrdquo Science 2018 in press
(42) Tao Ding1 Yazhen Duan2 Hui Li2 Baoguo Zhao1 Jun Yang2 ldquoAn Efficient HCl Promoted
Petasis Reaction of 2-Pyridinecarbaldehydes Amines and 12-Oxborol-2(5H)-olsrdquo
Tetrahedron Lett 2018 59 2502
(41) Chengkang Hou Guoqing Zhao Dongfang Xu Baoguo Zhao ldquoEnantioselective
Biomimetic Transamination of -Keto Acids Catalyzed by H4-Naphthalene-Derived Axially
Chiral Biaryl Pyridoxaminesrdquo Tetrahedron Lett 2018 59 1028
(40) Dongfang Xu Baoguo Zhao ldquoHighly Regioselective Hydroformylation of Olefins with
Formic Acid Instead of Toxic and Flammable COH2rdquo Sci China Chem 2017 60 839
(39) Feng Liu Jiaxin Tian Yong Liu Chuangan Tao Hao Zhu Aina Zhang Dongfang Xu and
Baoguo Zhao ldquoDecarboxylative Umpolung of Conjugated Enal to β-Carbanion for
Intramolecular Nucleophilic Addition to Aldehyderdquo Org Chem Front 2017 4 1586
(38) Yong Ethan Liu Zhaole Lu Bo Li Jiaxin Tian Feng Liu Junyu Zhao Chengkang Hou
Yingkun Li Lili Niu Baoguo Zhao ldquoEnzyme-Inspired Axially Chiral Pyridoxamines Armed
with a Cooperative Lateral Amine Chain for Enantioselective Biomimetic Transaminationrdquo J
Am Chem Soc 2016 138 10730
(37) Xiaoyu Lan Chuangan Tao Xuliang Liu Aina Zhang Baoguo Zhao ldquoAsymmetric
Transamination of α-Keto Acids Catalyzed by Chiral Pyridoxaminesrdquo Org Lett 2016 18
3658
(36) Jianfeng Chen Junyu Zhao Xing Gong Dongfang Xu Baoguo Zhao ldquoA new type of
chiral-pyridoxamines for catalytic asymmetric transamination of -keto acidsrdquo Tetrahedron
Lett 2016 57 4612
(35) Limin Shi Chuangan Tao Qin Yang Yong Ethan Liu Jing Chen Jianfeng Chen Jiaxin Tian
Feng Liu Bo Li Yongling Du Baoguo Zhao ldquoChiral Pyridoxal-Catalyzed Asymmetric
Biomimetic Transamination of α-Keto Acidsrdquo Org Lett 2015 17 5784
(34) Bin Rong Qin Yang Hong Xu Yifan Hu Xuejing Cheng Yong Liu Baoguo Zhao
ldquoPd-catalyzed Asymmetric α-Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2015 56
595
(33) Juan Xu Jing Chen Lei Ding Xuliang Liu Dongfang Xu Baoguo Zhao ldquoSynthesis of
α-Methylene-γ-amino acid Esters from Aldehydes via Aminative Umpolung Strategyrdquo Adv
Synth Catal 2014 356 3219
(32) Xuliang Liu Ang Gao Lei Ding Juan Xu Dongfang Xu Baoguo Zhao ldquoAminative
Umpolung Synthesis of Vicinal Amines from Aromatic Aldehydesrdquo Org Lett 2014 16
2118
(31) Lei Ding Jing Chen Yifan Hu Juan Xu Xing Gong Dongfang Xu Baoguo Zhao Hexing
Li ldquoAminative Umpolung of Aldehydes to α-Amimo Anion Equivalents for Pd-catalyzed
Allyation An Efficient Synthesis of Homoallylic Aminesrdquo Org Lett 2014 16 720
(30) Bing Rong Lei Ding Hailei Yu Qing Yang Xuliang Liu Dongfang Xu Baoguo Zhao
ldquoPd-Catalyzed Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2013 54 6501
(29) Baoguo Zhao Zhaobin Han Kuiling Ding ldquoN-H Functions in Organometallic Catalysisrdquo
Angew Chem Int Ed 2013 52 4744
(28) Hailei Yu Xuliang Liu Lei Ding Qin Yang Bin Rong Ang Gao Baoguo Zhao Haifeng
Yang ldquoPd-Catalyzed α-Arylation of Thioamidesrdquo Tetrahedron Lett 2013 54 3060
(27) Richard G Cornwall Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Synthesis of Cyclic
Sulfamides from Conjugated Dienesrdquo Org Lett 2013 15 796
(26) Yingguang Zhu Baoguo Zhao Yian Shi ldquoHighly Efficient Cu(I)-Catalyzed Oxidation of
Alcohols to Ketones and Aldehydes with Diaziridinonerdquo Org Lett 2013 15 992
(25) Thomas A Ramirez Baoguo Zhao and Yian Shi ldquoRecent advances in transition
metal-catalyzed sp3 CndashH amination adjacent to double bonds and carbonyl groupsrdquo Chem
Soc Rev 2012 41 931-942
(24) Baoguo Zhao Xingao Peng Yingguang Zhu Thamos A Ramirez Richard G Cornwall
Yian Shi ldquoCu(I)-Catalyzed Diamination of Conjugated Dienes Complementary
Regioselectivity from Two Distinct Mechanistic Pathwaysrdquo J Am Chem Soc 2011 133
20890-20900
(23) Xingao Peng Yingguang Zhu Thomas A Ramirez Baoguo Zhao Yian Shi ldquoNew
Reactivity of Oxaziridine Pd(II)-Catalyzed Aromatic C-H Ethoxycarbonylation via C-C
Bond Cleavagerdquo Org Lett 2011 13 5244-5247
(22) Richard G Cornwall Baoguo Zhao Yian Shi ldquoComplementary Regioselectivity in the
Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamidesrdquo Org Lett
2011 13 434-437
(21) Baoguo Zhao Xingao Peng Sunliang Cui Yian Shi ldquoCu(I)-catalyzed Regioselective
Diamination of Conjugated Dienes via Dual Mechanistic Pathwaysrdquo J Am Chem Soc 2010
132 11009-11011
(20) Baoguo Zhao Haifeng Du Sunliang Cui Yian Shi ldquoSynthetic and Mechanistic Studies of
Pd(0)-Catalyzed Diamination of Conjugated Dienesrdquo J Am Chem Soc 2010 132
3523-3532
(19) Baoguo Zhao Haifeng Du Renzhong Fu Yian Shi ldquoPd(0)-Catalyzed Asymmetric Allylic
and Homoallylic Diamination of 4-Phenyl-1-butene with Di-tert-butyldiaziridinonerdquo Org
Synth 2010 87 263
(18) Thamos A Ramirez Baoguo Zhao Yian Shi ldquoAn effective C-C Double bond formation via
Cu(I)-Catalyzed dehydrogenationrdquo Tetrahedron Lett 2010 51 1822-1825
(17) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-catalyzed Diamination of Conjugated Olefins
with Tunable Counteranions A Possible Approach to Asymmetric Diaminationrdquo J Org
Chem 2009 74 8392-8395
(16) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed C-H α-Amination of Aryl Ketones
Direct Synthesis of Imidazolinonesrdquo J Org Chem 2009 74 4411-4413
(15) Yuehong Wen Baoguo Zhao Yian Shi ldquoCu(I)-Catalyzed Diamination of Disubstituted
Terminal Olefins An Approach to Potent NK1 Antagonistrdquo Org Lett 2009 11 2365-2368
(14) Rengzhong Fu Baoguo Zhao Yian Shi ldquoSynthesis of (+)-CP-99994 via Pd(0)-Catalyzed
Asymmetric Allylic and Homoallylic C-H Diamination of Terminal Olefinrdquo J Org Chem
2009 74 7577-7580
(13) Haifeng Du Baoguo Zhao Yian Shi Pd(0)-Catalyzed Diamination of
trans-1-Phenyl-13-butadiene with Di-tert-butyldiaziridinone as Nitrogen Sourcerdquo Org Synth
2009 86 315
(12) Baoguo Zhao Haifeng Du Yian Shi ldquoA Cu(I)-Catalyzed C-H α-Amination of Esters Direct
Synthesis of Hydantoinsrdquo J Am Chem Soc 2008 130 7220-7221
(11) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Cycloguanidination of Olefinsrdquo Org
Lett 2008 10 1087-1090
(10) Haifeng Du Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Allylic and Homoallylic
Diamination of Terminal Olefins via Formal C-H Activationrdquo J Am Chem Soc 2008 130
8590-8591
(9) Haifeng Du Baoguo Zhao Weicheng Yuan Yian Shi ldquoCu(I)-Catalyzed Asymmetric
Diamination of Conjugated Dienesrdquo Org Lett 2008 10 4231-4234
(8) Baoguo Zhao Xingao Peng Zheng wang Chungu Xia Kuiling Ding ldquoModular Chiral
Bidentate Phosphonites Design Synthesis and Application in Catalytic Asymmetric
Hydroformylation Reactionsrdquo Chem Eur J 2008 14 7847-7857
(7) Baoguo Zhao Weicheng Yuan Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Intermolecular
Diamination of Activated Terminal Olefinsrdquo Org Lett 2007 9 4943-4945
(6) Haifeng Du Baoguo Zhao Yian Shi ldquoA Facile Pd(0)-Catalyzed Regio- and Stereoselective
Diamination of Conjugated Dienes and Trienesrdquo J Am Chem Soc 2007 129 762-763
(5) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoA Pd(0)-Catalyzed Diamination of
Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under
Solvent-Free Conditionsrdquo J Am Soc Chem 2007 129 7496-7497
(4) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Diamination
of Conjugated Dienes and Trienerdquo J Am Soc Chem 2007 129 11688-11689
(3) Weicheng Yuan Haifeng Du Baoguo Zhao Yian Shi ldquoA Mild Cu(I)-Catalyzed
Regioselective Diamination of Conjugated Dienesrdquo Org Lett 2007 9 2589-2591
(2) Baoguo Zhao Zheng Wang Kuiling Ding ldquoPractical by Ligand Design A New Generation
of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective
Hydrogenationsrdquo Adv Synth Catal 2006 348 1049-1057
(1) Min Zhang Huiying An Baoguo Zhao Jianhua Xu ldquoAromatic annulation strategy for
naphthalenes fused at 12- and 34-positions with two heterocyclesrdquo Org Biomol
Chem 2006 4 33-35
Patents
(6) 赵宝国刘勇卢兆乐李波ldquo一种手性联芳骨架吡哆胺类催化剂及其合成方
法与应用rdquo 申请号201610444057X
(5) 赵宝国陈剑锋赵濬宇龚幸ldquo一种新型手性开链吡哆胺催化剂及其合成方法与应
用rdquo 专利号2016104441125
(4) 赵宝国兰晓宇 陶创安 刘旭亮ldquo一种手性吡哆胺催化剂及其合成方法和应用rdquo
专利号2016104431284
(3) 赵宝国陈静石力敏刘勇杨琴陈剑锋田家昕陶创安李波许东芳ldquo一
种新型吡哆素衍生物及其制备方法rdquo专利号2015104139003
(2) 赵宝国陈静杨琴陈剑锋石力敏刘勇(Yong Ethan Liu)龚幸兰晓宇
卢兆乐刘勇 (Yong Liu)陶创安田家昕许东芳ldquo一种吡哆醛催化剂及其合成
方法与应用rdquo专利号2015104150464
(1) 赵宝国陶创安石力敏刘勇陈静ldquo一种手性吡哆醛催化剂及其合成方法与应
用rdquo专利号2015104271774
Awards
(1) 入选上海市东方学者特聘教授2010 年
(2) 入选教育部ldquo新世纪优秀人才计划rdquo2012 年
(3) 入选上海市ldquo浦江人才计划rdquo2012 年
(38) Yong Ethan Liu Zhaole Lu Bo Li Jiaxin Tian Feng Liu Junyu Zhao Chengkang Hou
Yingkun Li Lili Niu Baoguo Zhao ldquoEnzyme-Inspired Axially Chiral Pyridoxamines Armed
with a Cooperative Lateral Amine Chain for Enantioselective Biomimetic Transaminationrdquo J
Am Chem Soc 2016 138 10730
(37) Xiaoyu Lan Chuangan Tao Xuliang Liu Aina Zhang Baoguo Zhao ldquoAsymmetric
Transamination of α-Keto Acids Catalyzed by Chiral Pyridoxaminesrdquo Org Lett 2016 18
3658
(36) Jianfeng Chen Junyu Zhao Xing Gong Dongfang Xu Baoguo Zhao ldquoA new type of
chiral-pyridoxamines for catalytic asymmetric transamination of -keto acidsrdquo Tetrahedron
Lett 2016 57 4612
(35) Limin Shi Chuangan Tao Qin Yang Yong Ethan Liu Jing Chen Jianfeng Chen Jiaxin Tian
Feng Liu Bo Li Yongling Du Baoguo Zhao ldquoChiral Pyridoxal-Catalyzed Asymmetric
Biomimetic Transamination of α-Keto Acidsrdquo Org Lett 2015 17 5784
(34) Bin Rong Qin Yang Hong Xu Yifan Hu Xuejing Cheng Yong Liu Baoguo Zhao
ldquoPd-catalyzed Asymmetric α-Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2015 56
595
(33) Juan Xu Jing Chen Lei Ding Xuliang Liu Dongfang Xu Baoguo Zhao ldquoSynthesis of
α-Methylene-γ-amino acid Esters from Aldehydes via Aminative Umpolung Strategyrdquo Adv
Synth Catal 2014 356 3219
(32) Xuliang Liu Ang Gao Lei Ding Juan Xu Dongfang Xu Baoguo Zhao ldquoAminative
Umpolung Synthesis of Vicinal Amines from Aromatic Aldehydesrdquo Org Lett 2014 16
2118
(31) Lei Ding Jing Chen Yifan Hu Juan Xu Xing Gong Dongfang Xu Baoguo Zhao Hexing
Li ldquoAminative Umpolung of Aldehydes to α-Amimo Anion Equivalents for Pd-catalyzed
Allyation An Efficient Synthesis of Homoallylic Aminesrdquo Org Lett 2014 16 720
(30) Bing Rong Lei Ding Hailei Yu Qing Yang Xuliang Liu Dongfang Xu Baoguo Zhao
ldquoPd-Catalyzed Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2013 54 6501
(29) Baoguo Zhao Zhaobin Han Kuiling Ding ldquoN-H Functions in Organometallic Catalysisrdquo
Angew Chem Int Ed 2013 52 4744
(28) Hailei Yu Xuliang Liu Lei Ding Qin Yang Bin Rong Ang Gao Baoguo Zhao Haifeng
Yang ldquoPd-Catalyzed α-Arylation of Thioamidesrdquo Tetrahedron Lett 2013 54 3060
(27) Richard G Cornwall Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Synthesis of Cyclic
Sulfamides from Conjugated Dienesrdquo Org Lett 2013 15 796
(26) Yingguang Zhu Baoguo Zhao Yian Shi ldquoHighly Efficient Cu(I)-Catalyzed Oxidation of
Alcohols to Ketones and Aldehydes with Diaziridinonerdquo Org Lett 2013 15 992
(25) Thomas A Ramirez Baoguo Zhao and Yian Shi ldquoRecent advances in transition
metal-catalyzed sp3 CndashH amination adjacent to double bonds and carbonyl groupsrdquo Chem
Soc Rev 2012 41 931-942
(24) Baoguo Zhao Xingao Peng Yingguang Zhu Thamos A Ramirez Richard G Cornwall
Yian Shi ldquoCu(I)-Catalyzed Diamination of Conjugated Dienes Complementary
Regioselectivity from Two Distinct Mechanistic Pathwaysrdquo J Am Chem Soc 2011 133
20890-20900
(23) Xingao Peng Yingguang Zhu Thomas A Ramirez Baoguo Zhao Yian Shi ldquoNew
Reactivity of Oxaziridine Pd(II)-Catalyzed Aromatic C-H Ethoxycarbonylation via C-C
Bond Cleavagerdquo Org Lett 2011 13 5244-5247
(22) Richard G Cornwall Baoguo Zhao Yian Shi ldquoComplementary Regioselectivity in the
Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamidesrdquo Org Lett
2011 13 434-437
(21) Baoguo Zhao Xingao Peng Sunliang Cui Yian Shi ldquoCu(I)-catalyzed Regioselective
Diamination of Conjugated Dienes via Dual Mechanistic Pathwaysrdquo J Am Chem Soc 2010
132 11009-11011
(20) Baoguo Zhao Haifeng Du Sunliang Cui Yian Shi ldquoSynthetic and Mechanistic Studies of
Pd(0)-Catalyzed Diamination of Conjugated Dienesrdquo J Am Chem Soc 2010 132
3523-3532
(19) Baoguo Zhao Haifeng Du Renzhong Fu Yian Shi ldquoPd(0)-Catalyzed Asymmetric Allylic
and Homoallylic Diamination of 4-Phenyl-1-butene with Di-tert-butyldiaziridinonerdquo Org
Synth 2010 87 263
(18) Thamos A Ramirez Baoguo Zhao Yian Shi ldquoAn effective C-C Double bond formation via
Cu(I)-Catalyzed dehydrogenationrdquo Tetrahedron Lett 2010 51 1822-1825
(17) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-catalyzed Diamination of Conjugated Olefins
with Tunable Counteranions A Possible Approach to Asymmetric Diaminationrdquo J Org
Chem 2009 74 8392-8395
(16) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed C-H α-Amination of Aryl Ketones
Direct Synthesis of Imidazolinonesrdquo J Org Chem 2009 74 4411-4413
(15) Yuehong Wen Baoguo Zhao Yian Shi ldquoCu(I)-Catalyzed Diamination of Disubstituted
Terminal Olefins An Approach to Potent NK1 Antagonistrdquo Org Lett 2009 11 2365-2368
(14) Rengzhong Fu Baoguo Zhao Yian Shi ldquoSynthesis of (+)-CP-99994 via Pd(0)-Catalyzed
Asymmetric Allylic and Homoallylic C-H Diamination of Terminal Olefinrdquo J Org Chem
2009 74 7577-7580
(13) Haifeng Du Baoguo Zhao Yian Shi Pd(0)-Catalyzed Diamination of
trans-1-Phenyl-13-butadiene with Di-tert-butyldiaziridinone as Nitrogen Sourcerdquo Org Synth
2009 86 315
(12) Baoguo Zhao Haifeng Du Yian Shi ldquoA Cu(I)-Catalyzed C-H α-Amination of Esters Direct
Synthesis of Hydantoinsrdquo J Am Chem Soc 2008 130 7220-7221
(11) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Cycloguanidination of Olefinsrdquo Org
Lett 2008 10 1087-1090
(10) Haifeng Du Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Allylic and Homoallylic
Diamination of Terminal Olefins via Formal C-H Activationrdquo J Am Chem Soc 2008 130
8590-8591
(9) Haifeng Du Baoguo Zhao Weicheng Yuan Yian Shi ldquoCu(I)-Catalyzed Asymmetric
Diamination of Conjugated Dienesrdquo Org Lett 2008 10 4231-4234
(8) Baoguo Zhao Xingao Peng Zheng wang Chungu Xia Kuiling Ding ldquoModular Chiral
Bidentate Phosphonites Design Synthesis and Application in Catalytic Asymmetric
Hydroformylation Reactionsrdquo Chem Eur J 2008 14 7847-7857
(7) Baoguo Zhao Weicheng Yuan Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Intermolecular
Diamination of Activated Terminal Olefinsrdquo Org Lett 2007 9 4943-4945
(6) Haifeng Du Baoguo Zhao Yian Shi ldquoA Facile Pd(0)-Catalyzed Regio- and Stereoselective
Diamination of Conjugated Dienes and Trienesrdquo J Am Chem Soc 2007 129 762-763
(5) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoA Pd(0)-Catalyzed Diamination of
Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under
Solvent-Free Conditionsrdquo J Am Soc Chem 2007 129 7496-7497
(4) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Diamination
of Conjugated Dienes and Trienerdquo J Am Soc Chem 2007 129 11688-11689
(3) Weicheng Yuan Haifeng Du Baoguo Zhao Yian Shi ldquoA Mild Cu(I)-Catalyzed
Regioselective Diamination of Conjugated Dienesrdquo Org Lett 2007 9 2589-2591
(2) Baoguo Zhao Zheng Wang Kuiling Ding ldquoPractical by Ligand Design A New Generation
of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective
Hydrogenationsrdquo Adv Synth Catal 2006 348 1049-1057
(1) Min Zhang Huiying An Baoguo Zhao Jianhua Xu ldquoAromatic annulation strategy for
naphthalenes fused at 12- and 34-positions with two heterocyclesrdquo Org Biomol
Chem 2006 4 33-35
Patents
(6) 赵宝国刘勇卢兆乐李波ldquo一种手性联芳骨架吡哆胺类催化剂及其合成方
法与应用rdquo 申请号201610444057X
(5) 赵宝国陈剑锋赵濬宇龚幸ldquo一种新型手性开链吡哆胺催化剂及其合成方法与应
用rdquo 专利号2016104441125
(4) 赵宝国兰晓宇 陶创安 刘旭亮ldquo一种手性吡哆胺催化剂及其合成方法和应用rdquo
专利号2016104431284
(3) 赵宝国陈静石力敏刘勇杨琴陈剑锋田家昕陶创安李波许东芳ldquo一
种新型吡哆素衍生物及其制备方法rdquo专利号2015104139003
(2) 赵宝国陈静杨琴陈剑锋石力敏刘勇(Yong Ethan Liu)龚幸兰晓宇
卢兆乐刘勇 (Yong Liu)陶创安田家昕许东芳ldquo一种吡哆醛催化剂及其合成
方法与应用rdquo专利号2015104150464
(1) 赵宝国陶创安石力敏刘勇陈静ldquo一种手性吡哆醛催化剂及其合成方法与应
用rdquo专利号2015104271774
Awards
(1) 入选上海市东方学者特聘教授2010 年
(2) 入选教育部ldquo新世纪优秀人才计划rdquo2012 年
(3) 入选上海市ldquo浦江人才计划rdquo2012 年
(33) Juan Xu Jing Chen Lei Ding Xuliang Liu Dongfang Xu Baoguo Zhao ldquoSynthesis of
α-Methylene-γ-amino acid Esters from Aldehydes via Aminative Umpolung Strategyrdquo Adv
Synth Catal 2014 356 3219
(32) Xuliang Liu Ang Gao Lei Ding Juan Xu Dongfang Xu Baoguo Zhao ldquoAminative
Umpolung Synthesis of Vicinal Amines from Aromatic Aldehydesrdquo Org Lett 2014 16
2118
(31) Lei Ding Jing Chen Yifan Hu Juan Xu Xing Gong Dongfang Xu Baoguo Zhao Hexing
Li ldquoAminative Umpolung of Aldehydes to α-Amimo Anion Equivalents for Pd-catalyzed
Allyation An Efficient Synthesis of Homoallylic Aminesrdquo Org Lett 2014 16 720
(30) Bing Rong Lei Ding Hailei Yu Qing Yang Xuliang Liu Dongfang Xu Baoguo Zhao
ldquoPd-Catalyzed Allylic Alkylation of Thioamidesrdquo Tetrahedron Lett 2013 54 6501
(29) Baoguo Zhao Zhaobin Han Kuiling Ding ldquoN-H Functions in Organometallic Catalysisrdquo
Angew Chem Int Ed 2013 52 4744
(28) Hailei Yu Xuliang Liu Lei Ding Qin Yang Bin Rong Ang Gao Baoguo Zhao Haifeng
Yang ldquoPd-Catalyzed α-Arylation of Thioamidesrdquo Tetrahedron Lett 2013 54 3060
(27) Richard G Cornwall Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Synthesis of Cyclic
Sulfamides from Conjugated Dienesrdquo Org Lett 2013 15 796
(26) Yingguang Zhu Baoguo Zhao Yian Shi ldquoHighly Efficient Cu(I)-Catalyzed Oxidation of
Alcohols to Ketones and Aldehydes with Diaziridinonerdquo Org Lett 2013 15 992
(25) Thomas A Ramirez Baoguo Zhao and Yian Shi ldquoRecent advances in transition
metal-catalyzed sp3 CndashH amination adjacent to double bonds and carbonyl groupsrdquo Chem
Soc Rev 2012 41 931-942
(24) Baoguo Zhao Xingao Peng Yingguang Zhu Thamos A Ramirez Richard G Cornwall
Yian Shi ldquoCu(I)-Catalyzed Diamination of Conjugated Dienes Complementary
Regioselectivity from Two Distinct Mechanistic Pathwaysrdquo J Am Chem Soc 2011 133
20890-20900
(23) Xingao Peng Yingguang Zhu Thomas A Ramirez Baoguo Zhao Yian Shi ldquoNew
Reactivity of Oxaziridine Pd(II)-Catalyzed Aromatic C-H Ethoxycarbonylation via C-C
Bond Cleavagerdquo Org Lett 2011 13 5244-5247
(22) Richard G Cornwall Baoguo Zhao Yian Shi ldquoComplementary Regioselectivity in the
Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamidesrdquo Org Lett
2011 13 434-437
(21) Baoguo Zhao Xingao Peng Sunliang Cui Yian Shi ldquoCu(I)-catalyzed Regioselective
Diamination of Conjugated Dienes via Dual Mechanistic Pathwaysrdquo J Am Chem Soc 2010
132 11009-11011
(20) Baoguo Zhao Haifeng Du Sunliang Cui Yian Shi ldquoSynthetic and Mechanistic Studies of
Pd(0)-Catalyzed Diamination of Conjugated Dienesrdquo J Am Chem Soc 2010 132
3523-3532
(19) Baoguo Zhao Haifeng Du Renzhong Fu Yian Shi ldquoPd(0)-Catalyzed Asymmetric Allylic
and Homoallylic Diamination of 4-Phenyl-1-butene with Di-tert-butyldiaziridinonerdquo Org
Synth 2010 87 263
(18) Thamos A Ramirez Baoguo Zhao Yian Shi ldquoAn effective C-C Double bond formation via
Cu(I)-Catalyzed dehydrogenationrdquo Tetrahedron Lett 2010 51 1822-1825
(17) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-catalyzed Diamination of Conjugated Olefins
with Tunable Counteranions A Possible Approach to Asymmetric Diaminationrdquo J Org
Chem 2009 74 8392-8395
(16) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed C-H α-Amination of Aryl Ketones
Direct Synthesis of Imidazolinonesrdquo J Org Chem 2009 74 4411-4413
(15) Yuehong Wen Baoguo Zhao Yian Shi ldquoCu(I)-Catalyzed Diamination of Disubstituted
Terminal Olefins An Approach to Potent NK1 Antagonistrdquo Org Lett 2009 11 2365-2368
(14) Rengzhong Fu Baoguo Zhao Yian Shi ldquoSynthesis of (+)-CP-99994 via Pd(0)-Catalyzed
Asymmetric Allylic and Homoallylic C-H Diamination of Terminal Olefinrdquo J Org Chem
2009 74 7577-7580
(13) Haifeng Du Baoguo Zhao Yian Shi Pd(0)-Catalyzed Diamination of
trans-1-Phenyl-13-butadiene with Di-tert-butyldiaziridinone as Nitrogen Sourcerdquo Org Synth
2009 86 315
(12) Baoguo Zhao Haifeng Du Yian Shi ldquoA Cu(I)-Catalyzed C-H α-Amination of Esters Direct
Synthesis of Hydantoinsrdquo J Am Chem Soc 2008 130 7220-7221
(11) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Cycloguanidination of Olefinsrdquo Org
Lett 2008 10 1087-1090
(10) Haifeng Du Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Allylic and Homoallylic
Diamination of Terminal Olefins via Formal C-H Activationrdquo J Am Chem Soc 2008 130
8590-8591
(9) Haifeng Du Baoguo Zhao Weicheng Yuan Yian Shi ldquoCu(I)-Catalyzed Asymmetric
Diamination of Conjugated Dienesrdquo Org Lett 2008 10 4231-4234
(8) Baoguo Zhao Xingao Peng Zheng wang Chungu Xia Kuiling Ding ldquoModular Chiral
Bidentate Phosphonites Design Synthesis and Application in Catalytic Asymmetric
Hydroformylation Reactionsrdquo Chem Eur J 2008 14 7847-7857
(7) Baoguo Zhao Weicheng Yuan Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Intermolecular
Diamination of Activated Terminal Olefinsrdquo Org Lett 2007 9 4943-4945
(6) Haifeng Du Baoguo Zhao Yian Shi ldquoA Facile Pd(0)-Catalyzed Regio- and Stereoselective
Diamination of Conjugated Dienes and Trienesrdquo J Am Chem Soc 2007 129 762-763
(5) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoA Pd(0)-Catalyzed Diamination of
Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under
Solvent-Free Conditionsrdquo J Am Soc Chem 2007 129 7496-7497
(4) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Diamination
of Conjugated Dienes and Trienerdquo J Am Soc Chem 2007 129 11688-11689
(3) Weicheng Yuan Haifeng Du Baoguo Zhao Yian Shi ldquoA Mild Cu(I)-Catalyzed
Regioselective Diamination of Conjugated Dienesrdquo Org Lett 2007 9 2589-2591
(2) Baoguo Zhao Zheng Wang Kuiling Ding ldquoPractical by Ligand Design A New Generation
of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective
Hydrogenationsrdquo Adv Synth Catal 2006 348 1049-1057
(1) Min Zhang Huiying An Baoguo Zhao Jianhua Xu ldquoAromatic annulation strategy for
naphthalenes fused at 12- and 34-positions with two heterocyclesrdquo Org Biomol
Chem 2006 4 33-35
Patents
(6) 赵宝国刘勇卢兆乐李波ldquo一种手性联芳骨架吡哆胺类催化剂及其合成方
法与应用rdquo 申请号201610444057X
(5) 赵宝国陈剑锋赵濬宇龚幸ldquo一种新型手性开链吡哆胺催化剂及其合成方法与应
用rdquo 专利号2016104441125
(4) 赵宝国兰晓宇 陶创安 刘旭亮ldquo一种手性吡哆胺催化剂及其合成方法和应用rdquo
专利号2016104431284
(3) 赵宝国陈静石力敏刘勇杨琴陈剑锋田家昕陶创安李波许东芳ldquo一
种新型吡哆素衍生物及其制备方法rdquo专利号2015104139003
(2) 赵宝国陈静杨琴陈剑锋石力敏刘勇(Yong Ethan Liu)龚幸兰晓宇
卢兆乐刘勇 (Yong Liu)陶创安田家昕许东芳ldquo一种吡哆醛催化剂及其合成
方法与应用rdquo专利号2015104150464
(1) 赵宝国陶创安石力敏刘勇陈静ldquo一种手性吡哆醛催化剂及其合成方法与应
用rdquo专利号2015104271774
Awards
(1) 入选上海市东方学者特聘教授2010 年
(2) 入选教育部ldquo新世纪优秀人才计划rdquo2012 年
(3) 入选上海市ldquo浦江人才计划rdquo2012 年
(28) Hailei Yu Xuliang Liu Lei Ding Qin Yang Bin Rong Ang Gao Baoguo Zhao Haifeng
Yang ldquoPd-Catalyzed α-Arylation of Thioamidesrdquo Tetrahedron Lett 2013 54 3060
(27) Richard G Cornwall Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Synthesis of Cyclic
Sulfamides from Conjugated Dienesrdquo Org Lett 2013 15 796
(26) Yingguang Zhu Baoguo Zhao Yian Shi ldquoHighly Efficient Cu(I)-Catalyzed Oxidation of
Alcohols to Ketones and Aldehydes with Diaziridinonerdquo Org Lett 2013 15 992
(25) Thomas A Ramirez Baoguo Zhao and Yian Shi ldquoRecent advances in transition
metal-catalyzed sp3 CndashH amination adjacent to double bonds and carbonyl groupsrdquo Chem
Soc Rev 2012 41 931-942
(24) Baoguo Zhao Xingao Peng Yingguang Zhu Thamos A Ramirez Richard G Cornwall
Yian Shi ldquoCu(I)-Catalyzed Diamination of Conjugated Dienes Complementary
Regioselectivity from Two Distinct Mechanistic Pathwaysrdquo J Am Chem Soc 2011 133
20890-20900
(23) Xingao Peng Yingguang Zhu Thomas A Ramirez Baoguo Zhao Yian Shi ldquoNew
Reactivity of Oxaziridine Pd(II)-Catalyzed Aromatic C-H Ethoxycarbonylation via C-C
Bond Cleavagerdquo Org Lett 2011 13 5244-5247
(22) Richard G Cornwall Baoguo Zhao Yian Shi ldquoComplementary Regioselectivity in the
Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamidesrdquo Org Lett
2011 13 434-437
(21) Baoguo Zhao Xingao Peng Sunliang Cui Yian Shi ldquoCu(I)-catalyzed Regioselective
Diamination of Conjugated Dienes via Dual Mechanistic Pathwaysrdquo J Am Chem Soc 2010
132 11009-11011
(20) Baoguo Zhao Haifeng Du Sunliang Cui Yian Shi ldquoSynthetic and Mechanistic Studies of
Pd(0)-Catalyzed Diamination of Conjugated Dienesrdquo J Am Chem Soc 2010 132
3523-3532
(19) Baoguo Zhao Haifeng Du Renzhong Fu Yian Shi ldquoPd(0)-Catalyzed Asymmetric Allylic
and Homoallylic Diamination of 4-Phenyl-1-butene with Di-tert-butyldiaziridinonerdquo Org
Synth 2010 87 263
(18) Thamos A Ramirez Baoguo Zhao Yian Shi ldquoAn effective C-C Double bond formation via
Cu(I)-Catalyzed dehydrogenationrdquo Tetrahedron Lett 2010 51 1822-1825
(17) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-catalyzed Diamination of Conjugated Olefins
with Tunable Counteranions A Possible Approach to Asymmetric Diaminationrdquo J Org
Chem 2009 74 8392-8395
(16) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed C-H α-Amination of Aryl Ketones
Direct Synthesis of Imidazolinonesrdquo J Org Chem 2009 74 4411-4413
(15) Yuehong Wen Baoguo Zhao Yian Shi ldquoCu(I)-Catalyzed Diamination of Disubstituted
Terminal Olefins An Approach to Potent NK1 Antagonistrdquo Org Lett 2009 11 2365-2368
(14) Rengzhong Fu Baoguo Zhao Yian Shi ldquoSynthesis of (+)-CP-99994 via Pd(0)-Catalyzed
Asymmetric Allylic and Homoallylic C-H Diamination of Terminal Olefinrdquo J Org Chem
2009 74 7577-7580
(13) Haifeng Du Baoguo Zhao Yian Shi Pd(0)-Catalyzed Diamination of
trans-1-Phenyl-13-butadiene with Di-tert-butyldiaziridinone as Nitrogen Sourcerdquo Org Synth
2009 86 315
(12) Baoguo Zhao Haifeng Du Yian Shi ldquoA Cu(I)-Catalyzed C-H α-Amination of Esters Direct
Synthesis of Hydantoinsrdquo J Am Chem Soc 2008 130 7220-7221
(11) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Cycloguanidination of Olefinsrdquo Org
Lett 2008 10 1087-1090
(10) Haifeng Du Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Allylic and Homoallylic
Diamination of Terminal Olefins via Formal C-H Activationrdquo J Am Chem Soc 2008 130
8590-8591
(9) Haifeng Du Baoguo Zhao Weicheng Yuan Yian Shi ldquoCu(I)-Catalyzed Asymmetric
Diamination of Conjugated Dienesrdquo Org Lett 2008 10 4231-4234
(8) Baoguo Zhao Xingao Peng Zheng wang Chungu Xia Kuiling Ding ldquoModular Chiral
Bidentate Phosphonites Design Synthesis and Application in Catalytic Asymmetric
Hydroformylation Reactionsrdquo Chem Eur J 2008 14 7847-7857
(7) Baoguo Zhao Weicheng Yuan Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Intermolecular
Diamination of Activated Terminal Olefinsrdquo Org Lett 2007 9 4943-4945
(6) Haifeng Du Baoguo Zhao Yian Shi ldquoA Facile Pd(0)-Catalyzed Regio- and Stereoselective
Diamination of Conjugated Dienes and Trienesrdquo J Am Chem Soc 2007 129 762-763
(5) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoA Pd(0)-Catalyzed Diamination of
Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under
Solvent-Free Conditionsrdquo J Am Soc Chem 2007 129 7496-7497
(4) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Diamination
of Conjugated Dienes and Trienerdquo J Am Soc Chem 2007 129 11688-11689
(3) Weicheng Yuan Haifeng Du Baoguo Zhao Yian Shi ldquoA Mild Cu(I)-Catalyzed
Regioselective Diamination of Conjugated Dienesrdquo Org Lett 2007 9 2589-2591
(2) Baoguo Zhao Zheng Wang Kuiling Ding ldquoPractical by Ligand Design A New Generation
of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective
Hydrogenationsrdquo Adv Synth Catal 2006 348 1049-1057
(1) Min Zhang Huiying An Baoguo Zhao Jianhua Xu ldquoAromatic annulation strategy for
naphthalenes fused at 12- and 34-positions with two heterocyclesrdquo Org Biomol
Chem 2006 4 33-35
Patents
(6) 赵宝国刘勇卢兆乐李波ldquo一种手性联芳骨架吡哆胺类催化剂及其合成方
法与应用rdquo 申请号201610444057X
(5) 赵宝国陈剑锋赵濬宇龚幸ldquo一种新型手性开链吡哆胺催化剂及其合成方法与应
用rdquo 专利号2016104441125
(4) 赵宝国兰晓宇 陶创安 刘旭亮ldquo一种手性吡哆胺催化剂及其合成方法和应用rdquo
专利号2016104431284
(3) 赵宝国陈静石力敏刘勇杨琴陈剑锋田家昕陶创安李波许东芳ldquo一
种新型吡哆素衍生物及其制备方法rdquo专利号2015104139003
(2) 赵宝国陈静杨琴陈剑锋石力敏刘勇(Yong Ethan Liu)龚幸兰晓宇
卢兆乐刘勇 (Yong Liu)陶创安田家昕许东芳ldquo一种吡哆醛催化剂及其合成
方法与应用rdquo专利号2015104150464
(1) 赵宝国陶创安石力敏刘勇陈静ldquo一种手性吡哆醛催化剂及其合成方法与应
用rdquo专利号2015104271774
Awards
(1) 入选上海市东方学者特聘教授2010 年
(2) 入选教育部ldquo新世纪优秀人才计划rdquo2012 年
(3) 入选上海市ldquo浦江人才计划rdquo2012 年
Chem 2009 74 8392-8395
(16) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed C-H α-Amination of Aryl Ketones
Direct Synthesis of Imidazolinonesrdquo J Org Chem 2009 74 4411-4413
(15) Yuehong Wen Baoguo Zhao Yian Shi ldquoCu(I)-Catalyzed Diamination of Disubstituted
Terminal Olefins An Approach to Potent NK1 Antagonistrdquo Org Lett 2009 11 2365-2368
(14) Rengzhong Fu Baoguo Zhao Yian Shi ldquoSynthesis of (+)-CP-99994 via Pd(0)-Catalyzed
Asymmetric Allylic and Homoallylic C-H Diamination of Terminal Olefinrdquo J Org Chem
2009 74 7577-7580
(13) Haifeng Du Baoguo Zhao Yian Shi Pd(0)-Catalyzed Diamination of
trans-1-Phenyl-13-butadiene with Di-tert-butyldiaziridinone as Nitrogen Sourcerdquo Org Synth
2009 86 315
(12) Baoguo Zhao Haifeng Du Yian Shi ldquoA Cu(I)-Catalyzed C-H α-Amination of Esters Direct
Synthesis of Hydantoinsrdquo J Am Chem Soc 2008 130 7220-7221
(11) Baoguo Zhao Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Cycloguanidination of Olefinsrdquo Org
Lett 2008 10 1087-1090
(10) Haifeng Du Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Allylic and Homoallylic
Diamination of Terminal Olefins via Formal C-H Activationrdquo J Am Chem Soc 2008 130
8590-8591
(9) Haifeng Du Baoguo Zhao Weicheng Yuan Yian Shi ldquoCu(I)-Catalyzed Asymmetric
Diamination of Conjugated Dienesrdquo Org Lett 2008 10 4231-4234
(8) Baoguo Zhao Xingao Peng Zheng wang Chungu Xia Kuiling Ding ldquoModular Chiral
Bidentate Phosphonites Design Synthesis and Application in Catalytic Asymmetric
Hydroformylation Reactionsrdquo Chem Eur J 2008 14 7847-7857
(7) Baoguo Zhao Weicheng Yuan Haifeng Du Yian Shi ldquoCu(I)-Catalyzed Intermolecular
Diamination of Activated Terminal Olefinsrdquo Org Lett 2007 9 4943-4945
(6) Haifeng Du Baoguo Zhao Yian Shi ldquoA Facile Pd(0)-Catalyzed Regio- and Stereoselective
Diamination of Conjugated Dienes and Trienesrdquo J Am Chem Soc 2007 129 762-763
(5) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoA Pd(0)-Catalyzed Diamination of
Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under
Solvent-Free Conditionsrdquo J Am Soc Chem 2007 129 7496-7497
(4) Haifeng Du Weicheng Yuan Baoguo Zhao Yian Shi ldquoCatalytic Asymmetric Diamination
of Conjugated Dienes and Trienerdquo J Am Soc Chem 2007 129 11688-11689
(3) Weicheng Yuan Haifeng Du Baoguo Zhao Yian Shi ldquoA Mild Cu(I)-Catalyzed
Regioselective Diamination of Conjugated Dienesrdquo Org Lett 2007 9 2589-2591
(2) Baoguo Zhao Zheng Wang Kuiling Ding ldquoPractical by Ligand Design A New Generation
of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective
Hydrogenationsrdquo Adv Synth Catal 2006 348 1049-1057
(1) Min Zhang Huiying An Baoguo Zhao Jianhua Xu ldquoAromatic annulation strategy for
naphthalenes fused at 12- and 34-positions with two heterocyclesrdquo Org Biomol
Chem 2006 4 33-35
Patents
(6) 赵宝国刘勇卢兆乐李波ldquo一种手性联芳骨架吡哆胺类催化剂及其合成方
法与应用rdquo 申请号201610444057X
(5) 赵宝国陈剑锋赵濬宇龚幸ldquo一种新型手性开链吡哆胺催化剂及其合成方法与应
用rdquo 专利号2016104441125
(4) 赵宝国兰晓宇 陶创安 刘旭亮ldquo一种手性吡哆胺催化剂及其合成方法和应用rdquo
专利号2016104431284
(3) 赵宝国陈静石力敏刘勇杨琴陈剑锋田家昕陶创安李波许东芳ldquo一
种新型吡哆素衍生物及其制备方法rdquo专利号2015104139003
(2) 赵宝国陈静杨琴陈剑锋石力敏刘勇(Yong Ethan Liu)龚幸兰晓宇
卢兆乐刘勇 (Yong Liu)陶创安田家昕许东芳ldquo一种吡哆醛催化剂及其合成
方法与应用rdquo专利号2015104150464
(1) 赵宝国陶创安石力敏刘勇陈静ldquo一种手性吡哆醛催化剂及其合成方法与应
用rdquo专利号2015104271774
Awards
(1) 入选上海市东方学者特聘教授2010 年
(2) 入选教育部ldquo新世纪优秀人才计划rdquo2012 年
(3) 入选上海市ldquo浦江人才计划rdquo2012 年
(2) Baoguo Zhao Zheng Wang Kuiling Ding ldquoPractical by Ligand Design A New Generation
of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective
Hydrogenationsrdquo Adv Synth Catal 2006 348 1049-1057
(1) Min Zhang Huiying An Baoguo Zhao Jianhua Xu ldquoAromatic annulation strategy for
naphthalenes fused at 12- and 34-positions with two heterocyclesrdquo Org Biomol
Chem 2006 4 33-35
Patents
(6) 赵宝国刘勇卢兆乐李波ldquo一种手性联芳骨架吡哆胺类催化剂及其合成方
法与应用rdquo 申请号201610444057X
(5) 赵宝国陈剑锋赵濬宇龚幸ldquo一种新型手性开链吡哆胺催化剂及其合成方法与应
用rdquo 专利号2016104441125
(4) 赵宝国兰晓宇 陶创安 刘旭亮ldquo一种手性吡哆胺催化剂及其合成方法和应用rdquo
专利号2016104431284
(3) 赵宝国陈静石力敏刘勇杨琴陈剑锋田家昕陶创安李波许东芳ldquo一
种新型吡哆素衍生物及其制备方法rdquo专利号2015104139003
(2) 赵宝国陈静杨琴陈剑锋石力敏刘勇(Yong Ethan Liu)龚幸兰晓宇
卢兆乐刘勇 (Yong Liu)陶创安田家昕许东芳ldquo一种吡哆醛催化剂及其合成
方法与应用rdquo专利号2015104150464
(1) 赵宝国陶创安石力敏刘勇陈静ldquo一种手性吡哆醛催化剂及其合成方法与应
用rdquo专利号2015104271774
Awards
(1) 入选上海市东方学者特聘教授2010 年
(2) 入选教育部ldquo新世纪优秀人才计划rdquo2012 年
(3) 入选上海市ldquo浦江人才计划rdquo2012 年