Program studiów MAKRO

Silesian University of Technology - Faculty of Chemistry

Gliwice, Poland

Curriculum and Subject Syllabi

INDUSTRIAL & ENGINEERING CHEMISTRY

• Technology and engineering of fine chemicals

and specialty materials

• Process engineering in green chemical technologies.

5 – year full-time MSc studiesin English

www.polsl.pl

Silesian University of Technology - Faculty of Chemistryoffers 5-year full-time MSc studies in English

Macrofaculty Course of Industrial and Engineering Chemistry

In response to the mounting requests and the growing demand for professionals

prepared to operate in a global environment, on October 1st, 2002 the Faculty of Chemistry of

Silesian University of Technology launched a new Macrofaculty Course of Studies - -

Industrial and Engineering Chemistry lectured in English.

In concept this course aims to form chemical engineers of a novel type, with integrated, solid

knowledge of fundamentals of the two principal lines of studies, i.e. Chemical and Process

Engineering and Chemical Technology, and hence capable to tackle diverse practical problems

of modern chemical technologies and process engineering, well familiar with computers and

informatics and open to new developments and innovations.

To meet this objective the curricula of the two principal lines of studies were carefully

scrutinized to create the one that includes courses of organic, inorganic, analytical and

physical chemistry, fluid mechanics, process kinetics, unit operations, reaction and reactors

engineering, industrial catalysis, bioprocess engineering and industrial equipment design.

Extensive courses of economics and management are also envisaged as well as classes of

English or other modern languages to improve communication skills.

By the end of the third year the students will choose one of the specjalizations:

• Technology and engineering of fine chemicals and specialty materials

• Process engineering in green chemical technologies.

In both specjalizations the compulsory core courses are supplemented with a number of

optional courses selected according to individual interests.

Alumnus of both specializations acquire skills needed to solve practical problems from the

realms of chemical technology, process engineering and chemistry of materials and are well

prepared to work in industrial, research and marketing environments.

Alumnus of Macrofaculty is very well prepared to join the work market in large and small

enterprises thanks to the high professional qualifications, creativity, openness to new ideas

and skills in team work.

Study Schedule

Faculty of Chemistry

Program for MacrocourseL- Lecture

Ex- Exercise

Lab.- Laboratory

Sem.- Seminary

P- Project

E-Exam

Industrial and Engineering Chemistry I year

Term Course description hours / week

1 No. Subject’s namehours

totalL Ex Lab. Sem. P

ECTS

pts.

1. Applied mathematics I 90 3E 3 8

2. Physics 60 2 2 6

3.General & inorganic

chemistry90 2E 2 2 8

4. Technical drawing 45 3 3

5. Computer science 60 1 3 5

Total 345 23 30

2

1. Applied mathematics I 90 3E 3 8

2. Physics 90 2E 2 2 8

3.General & inorganic

chemistry45 2 1 4

4. Fluid mechanics 45 2E 1 4

5. Technical mechanics 45 3 4

6. English 30 2 2

7. Sport 30 2

Total 375 25 30

Industrial and Engineering Chemistry II year


No. Subject’s namehours


ECTS

pts.

1. Applied mathematics II 60 2E 2 6

2. Physical chemistry 45 2 1 5

3 3.General & inorganic

chemistry90 2E 1 3 7

4. Analytical chemistry 60 1 3 4

5. Organic chemistry 60 3 1 6

6. English 30 2 2

7. Sport 30 2

Total 375 25 30

4

1. Physical chemistry 90 2E 1 3 10

2. Analytical chemistry 45 1E 2 5

3. Organic chemistry 105 2E 5 10

4. Transport phenomena 45 2 1 3

5. English 30 2 2

6. Sport 30 2

Total 345 23 30

Industrial and Engineering Chemistry III year




ECTS

pts.

1. Industrial equipment 75 3E 2 7

2. Chemical technology 30 2 2

5 3. Transport phenomna 45 2E 1 5

4. Unit operations 75 3 2 4

5.Process

thermodynamics45 2E 1 6

6 Industrial catalysis 45 2 1 4

7. English 30 2E 2

Total 345 23 30

6

1. Chemical technology 75 3E 2 6

2. Unit operations 75 2E 2 1 7

3.Thermal processes

engineering30 2 3

4 Biotechnology 30 2 3

5.Process dynamics &

control45 2 1 3

6.Electrical engineering

& electronics30 2 2

7. Bioprocess engineering 60 2E 2 6

Total 345 23 30

Industrial and Engineering Chemistry IV yearSpecialization: Specialty Materials and Fine Chemicals


No. Subject’s name hours L Ex Lab. Sem. P

ECTS

pts.

1.Reactors & reaction

engineering45 2 1 4


control30 2 2

3. Economics 60 4 4

7 4. Optional 60 4 4

5. Separation processes 75 3E 2 7

6.Characterization of

chemical structures75 2E 3 7

7.Membrane

technologies30 2 2

Total 375 25 30

8


engineering45 2E 1 6

2. General & technical II 60 4 6

3. Optional 60 4 4

4.Membrane

technologies30 2E 2

5.Principles of polymer

chemistry90 3E 3 5

6. Sol-gel materials 60 1E 2 1 5

7.Process safety and

wastes management30 2 2

Total 375 25 30

Industrial and Engineering Chemistry V yearSpecialization: Specialty Materials and Fine Chemicals


Lp. Subject’s namehours


ECTS

pts.

1. Humanites 30 2 2

2. Economics 30 2 2

9 3.

Manufacturing

processing and

application of

polymers

105 3E 4 8

4. Fine chemicals 120 1 5 2 10


wastes management30 1E 1 3

6. Transfer thesis 45 3 5

Total 360 2430

10

1. M.Sc.Thesis (200) 25

2 M.Sc.thesis 45 3 5

Total 245 3 30

Industrial and Engineering Chemistry IV year

Specialization: Process Engineering for Green Chemical Technologies




ECTS

pts.


engineering45 2 1 4


control30 2 2

3. Economics 60 4 4

7 4. Optional 60 4 4

5. Separation processes 75 3E 2 7

6.Gas cleaning and water

treatment45 2E 1 4

7.Membrane

technologies30 2 2

8.Environmental

protection30 2 3

Total 375 25 30

8


engineering45 2E 1 6

2. General & technical II 60 4 6

3. Optional 60 4 4

4.Process system

engineering105 3E 1 3 7

5.Process equipment

design45 2 1 3

6.Membrane

technologies

technologies

30 2E 2


wastes management30 2 2

Total 375 25 30

Industrial and Engineering Chemistry V year Specialization: Process Engineering for Green Chemical Technologies

Term Course description hours / weekECTS

pts.

9


totalL Ex Lab.

Sem

.P

1. Humanities 30 2 2

2. Economics 30 2 2

3.

Process simulation,

optimization and

design

105 3 1 3 9

4.Process systems

engineering30 2 2

5.Process equipment

design30 2E 3

6.

Bioprocesses for

environment

protection

30 2E 2


wastes management30 1E 1 3

8. Mass crystallization 30 2 2

9. Transfer thesis 45 3 5

Total 360 24 30

10

1. M.Sc.thesis (200) 25

2 M.Sc. seminar 45 3 5

Total 245 3 30

Applied mathematics I

Objectives of the course

The goal of the course is to discuss the main topics of Calculus and selected topics of

Algebra. The applications in physics and chemistry are also included.

Course description

The course consists of lectures and classes.

The topics discussed during lectures are

1) functions in one and many variables,

2) all the main concepts of Calculus – limits, derivatives, integrals, differential equations and

series,

3) the selected concepts of Algebra – like complex numbers, vectors, linear geometry in R2

and R3, matrices, determinants and systems of linear equations.

The outline of applications in psychics and chemistry is also given.

The aim of the classes is to understand and apply the notions introduced on the lectures by

solving different types of exercises - basic and also more complicated.

References

1. M.D. Weir, J. Hass, F.R. Giordano “Thomas’ Calculus. International Edition”, Addison-

Wesley, 2005.

2. H. Anton, Ch. Rorres “Elementary Linear Algebra. Applications version”, John Wiley &

Sons, New York, 1994.

3. E. Łobos, B. Sikora “Calculus and Differential Equations in Exercises”, Wydawnictwo

Politechniki Śląskiej, Gliwice 2004

Physics


The two semester course provides the knowledge and understanding of basic laws of physics

and shows how physics can help in studying chemistry and chemical engineering. It tries to

proceed along the famous statement by Ostwald “there is no good chemistry without excellent

physics”.

Course description

The first semester of the course starts by repetition of the basic mathematical tools, like vector

algebra and differential calculus. Then the students are taught about mechanics: kinematics,

dynamics and rigid body dynamics. Next, the mechanics and basic facts in fluid dynamics are

introduced. To complete the mechanical topics, harmonic oscillator theory is presented. After

this a short introduction to optics and diffusion starts. This completes the first semester.

In second semester, field theory and electromagnetism is introduced. After that, a set of

lectures on quantum mechanics and atomic physics starts. At the end of semester, some

flavour of special and general relativity theory is provided. The course ends with chosen

problems on cosmology and elementary particles.

References

1. H.D. Young, R. A. Freedman, University Physics, Adison-Wesley, 2000.

2. D.C. Giancoli, Physics for Sciencists and Engineers with Modern Physics, Prentice-Hall,

1999.

3. D.A. McQuarrie, Quantum Chemistry, University Science Books, 1983.

General and inorganic chemistry


The primary objective for the programme is to provide solid foundation knowledge in

chemistry, including substantial laboratory training, particularly those needed in future

courses.

Course description

Laws of chemistry; periodic table and chemical periodicity; stoichiometry, nomenclature,

modern atomic theory and bonding; ionic and molecular compounds; molecular geometry;

oxidation-reduction reactions; solutions and heterogeneous mixtures; gaseous state; states of

matter and intermolecular forces; thermochemistry; physical properties of solutions in

aqueous solution, chemical kinetics, chemical equilibrium, chemical thermodynamics and

electrochemistry.

Introduction to symmetry, chemistry of the main group elements, coordination chemistry of

the transition elements, ligand field theory, organometallic chemistry, solid state chemistry,

bioinorganic chemistry, chemistry of the lanthanide and actinide elements.

Laboratory includes some basic chemical reactions, qualitative methods in chemical analysis,

as well as selected experiments in general chemistry.

References

1. R.H. Petrucci, W.S. Harwood, F.G. Herring, General Chemistry: Principles and Modern

Applications, Prentice Hall, New Jersey, 8th Ed, 2002.

2. G.E. Rodgers, Descriptive Inorganic, Coordination, and Solid State Chemistry,

Brooks/Cole, 2nd Ed, 2002.

3. D.F. Shriver, P.W. Atkins, Inorganic Chemistry, Oxford University Press, 3rd Ed, 1999.

Technical drawing

Objective of the course

The purpose of the course is to present of basic engineering graphics, geometry of apparatus

envelopes and applications of Computer-Aided Design (CAD), to enable students to read and

to realize both construction drawing and technical documentation.

Course description

The students will have the opportunity to realize the drawing works of selected chemical

apparatus elements (projection, elements of tanks, intersections of process apparatus,

technological diagrams), taking advantage of the traditional method as well as the modern

computer software like A-CAD, CHEM-CAD and acquire the skills of using ploter, digitizer

and scaner.

The main intention will to teach the preparation of artworks, connected with engineering

studies, ilustrations and technical drawings.

Reference

1. Thomas E. French, Charles J. Vierck, The fundamentals of engineering drawing

& graphic technology, 4-th. ed., McGraw – Hill Company 1978.

2. A.R.Eide, R.D. Jenison, L.H.Mashaw, Engineering Graphics Problem Books,

McGraw – Hill Company 1985.

3. Pikoń, J.Hehlmann, R.Janowicz, B.Sąsiadek, Atlas konstrukcji aparatury chemiocznej,

wyd. II zmienione i rozszerzone, PWN, Warszawa 1987

Computer science


The course provides a basic knowledge of computer hardware and software, introduce the

functions to which computers are applied, and examine the ways in which they are integrated

into human life. The course will also provide sufficient training in using typical software as

word editor, spreadsheet and presentation graphics in chemistry.

Course description

The course comprises of 15 hr of lectures and 45 hr of practical training (laboratory).

Lectures focus on general knowledge on computers basics from a short history of their

development, their taxonomy with the impact on modern PC, hardware, operating systems,

software applications. Typical software applications as text editors, spreadsheets, databases,

computer graphics are reviewed. The basic ideas lying behind computer networking and

telecommunication are presented. Exploring the Internet as a source of different kinds of

information, including chemical. Finally problems concerning computer security and risks as

well as legal problems concerning use of computers are discussed.

During practical training in computer laboratory students can improve their skills in using

typical office applications as Internet browser, text editor, spreadsheet and presentation

graphics. The special attention is paid to solving different mathematical problems applicable

to chemical technology and engineering with the use of Excel and accompanying tools.

References

1. G. Beekman, E. Rathswohl, Computer Confluence IT Edition, 5 ed, Prentice Hall, New

Jersey 2003.

2. L. Long, N. Long, Computers, 10 ed. Prentice Hall, New Jersey 2002.

3 N. Bandyo-padhyay, Computing for Non-Specialists, Addison-Wesley, Harlow 2000.

Fluid mechanics


An objective of the course is to acquaint first-year students with the fundamental principles

governing the gas and liquid behaviour. Solving of simple practical problems should broaden

the theoretical knowledge.

Course description

The course is divided into two parts: fluid statics and fluid dynamics. The first one comprises

properties of fluid such as density, viscosity, surface tension and capillarity. Then pressure

measurements by the use of a barometer, piezometer, U-tube, differential micrometer and

Burdon gauge are discussed. The equilibrium equation for fluids at rest is derived and its

selected applications including Pascal’s law are shown. Liquid action on immersed surfaces

and bodies are presented under Archimedes’ principle and hydrostatic thrust on a plain or

curved surface. The second part deals with laminar and turbulent flow of liquid. The letter is

described starting from the famous Reynolds experiment and then introducing concepts of

deterministic chaos and the Kolmogorov microscale of turbulence. A beauty and precision of

fluid dynamics is shown in the form of continuity and momentum equations (Euler, Cauchy-

Lagrange and Navier-Stokes). More practical aspects of liquid flow are given by pressure

losses calculations in smooth and rough pipes and the integral form of Bernoulli equation.

Also some typical local pressure losses in elbows, diffusers, confusors and valves are

considered. Transportation of liquids by pumps is shortly discussed together with flow and

pump system characteristic for impeller pumps. Main dependencies for steady-state and

unsteady-state discharge of liquid from a tank are derived. At the end, main devices used in

fluid flow rate measurements, such as the Prandtl tube, Venturi meter, orifice meter,

anemometer and rotameter are presented.

References

1. Y. A. Çengel, J. M. Cimbala, Fluid mechanics. Fundamentals and Applications, McGraw

Hill Co., New York 2006.

2. R. L. Daugherty, J.B. Franzini, Fluid Mechanics with Engineering Applications, McGraw-

Hill Book Co., New York 1977.

3. D. B. Marghitu (Ed.), Mechanical Engineer's Handbook, Academic Press, London 2001.

Technical mechanics


An objective of the course is to acquaint first-year students with the fundamental principles

describing the effects of forces on a rigid solid body, behaviour of an elastic body under the

action of various loads and to recognise different machine elements. The theory is illustrated

by easy computational problems.

Course description

The course is divided into three parts: statics of material systems, strength of materials and

basic machine elements. The first one comprises: the model of rigid body, external,

supporting and internal forces, couples, moments, axioms of statics, reduction of the system

of forces, equilibrium and non-equilibrium systems of forces and friction phenomenon. In the

letter, Coulomb’s experiment, slide, rolling and belt friction are presented. The second one

considers: a concept of the elastic body, stress and deformation, principle of solidification and

Hooke’s law. Then main mechanical properties of materials and their measurements including

tension, compression, hardness and impact strength tests and also creep and fatigue

phenomena are discussed. A basic part of the strength of materials comprises simple cases of

stresses such as axial tension, simple bending, torsion and shearing in straight bars. All cases

are treated as hyperstatic problems and are solved employing a set of equilibrium equations,

geometrical relations and physical relations. The permissive stress method and its usage are

also described. Additionally, main methods showing how to deal with compound cases

together with a concept of reduced stress and basic strength hypothesis are presented. In the

third part of the course various types of fastenings, couplings, clutches, slide bearings, rolling

bearings, brakes and power transfer systems (gears) are presented. The working principles of

machine elements are considered and shown in simple sketches.

References

1. J. L. Meriam, Engineering Mechanics, vol.1 – Statics, John Wiley & Sons, New York

1987.

2. N. M. Belyaev, Strength of Materials, MIR Publishers, Moscow 1979.

3. J. A. Collins, Mechanical Design of Machine Elements, John Wiley & Sons, New York

2003.

Applied mathematics II


The lecture is concerned with development, analysis, and practical application of various

mathematical methods and numerical techniques that can be adapted successfully for the

solution of problems in modern engineering. The lecture should give enough background for

the students to enable specialized journals to be consulted fruitfully.

Course description

Ordinary differential equations (ODE). Classification of ODE. Dimensions. Examples. Steady

state. General form of ODE. General integral. Particular solution. First order ODE. The

method of separation of variables. Linear ODE of first order. The homogeneous and

nonhomogeneous equation. Bernoulli’s equation. Riccati’s equation. Coupled simultaneous

ODE. Second order ODE. The general solution. Two point boundary conditions. Danckwerts

conditions. Bolzman low of radiation.

Solution methods; method of undetermined coefficients, method of variation of parameters,

method of inverse operators. Developed slit flow. Heat exchanger parallel flow and counter

flow. Series solution methods and special Functions. Properties of infinite series. Legedre’s

equation. Bessel’s equation. Expansion of the continuous function using orthogonal functions.

Numerical solution methods. Numerical integration (Trapezoid rule, Simpson’s rule). Error

control and extrapolation. Numerical solution of ODE ( Finite difference. Stability. Stiffness.

Explicit and implicit integration methods. Predictor-Corrector and Runge-Kutta methods.

Step size control). Numerical solution of ODE two point boundary value problem. Thomas

algorithm. Solution methods for nonlinear algebraic equations (Bisection method, Successive

substitution method, Newton-Raphson method). Partial differential equations (PDE). General

form of second order linear PDE in two independent variables. Types of PDE (parabolic,

hyperbolic and elliptic). Examples. Classical analytical methods of solving PDE (separation

of variables).

Numerical solution methods. Linear parabolic PDE (Forward difference equation, Backward

difference equation, Crank-Nicolson equation). Stability analysis. Linear hyperbolic PDE

(Lax method, Wendroff method, Split boundary value problems). Dynamic behaviour of heat

exchangers. Method of characteristics. Elliptic and parabolic equations in two and three space

dimensions (Alternating-direction-implicit method ADI). Diffusion and dispersion. Nonlinear

parabolic equations (Iterating using old value, Forward projection of coefficient of half level

in time, Backward and centered series projection).

References

1. R.G. Rice and D.D. Do, Applied Mathematics and Modeling for Chemical Engineers,

Wiley, 1995.

2. M.K. Jain, Numerical Solution of Differential Equations, Wiley, 1984.

Physical chemistry


Description of the chemical systems that include reactants and products together with their

structure, state of the matter in their different stages of the reaction course is generally an

objective of the physical chemistry. This description covers phenomena and laws, which using

appropriate equations allow interpreting and predicting behaviour of the chemical system at

variety of physical conditions.

Course description

Equilibrium. The properties of gases, perfect and real gas, the gas laws. The First Law of

thermodynamics, thermochemistry, state functions. The Second Law, the direction of

spontaneous change, the efficiencies of thermal processes, the Helmholtz and Gibbs

functions, the chemical potential. The change of state, phase diagrams, phase stability and

phase transitions. The thermodynamic description of mixtures, real solutions. The

electrochemical properties of ions in solution, electrochemical cells. Change. The kinetic

theory of gases, the pressure of gas, collisions, transport properties, diffusion, thermal

conductivity, viscosity, ion transport. The rate of chemical reactions, empirical chemical

kinetics, accounting for the rate laws. The kinetics of complex reactions, chain reactions,

polymerization kinetics, catalysis and oscillation. Reactive encounters, activated complex

theory. Processes at solid interfaces, the extend of adsorption, catalytic activity at surfaces.

Dynamic electrochemistry, the rate of charge transfer. Calculations in physical chemistry.

Thermodynamics, state of equilibrium, reactions kinetics, electrochemical cells. Experimental

physical chemistry. Partial molar entalphy of dissolution, heat of combustion, kinetics of

catalytic decomposition of hydrogen peroxide, simulation of kinetics of complex reactions,

half-live of radioactive isotopes, measurements of dissociation constant and pH of solution,

EMF of galvanic cells and thermodynamic functions, isotherm of adsorption.

References

1. P. W. Atkins, J. de Paula, Atkins’ Physical Chemistry, Oxford University Press, seventh

edition, 2002.

2. R. A. Alberty, R.J. Silbey, Physical Chemistry, John Willey & Sons, Inc., 1992.

Analytical chemistry


The objective of this course is to present an integrated approach of Analytical chemistry,

which incorporates the developments in basic chemistry, instrumentation and also considers

all aspects of data collecting and processing as well as the side effects of chemical

measurements.

Course description

This course will be divided into two parts. The first part will be devoted to the general aspects

of qualitative and quantitative analytical chemistry, definitions, sample preparations, stages of

analytical process, separation, concentration, measurements, statistical evaluation of results,

errors, standards, reference materials and classical analytical techniques.

The second part will embrace instrumental methods of chemical analysis. The following

issues will be discussed: optical methods, atomic absorption, liquid and TLC chromatography,

electrochemical methods, X-Ray, NMR, MS and hyphenated methods.

The essential application of instrumental methods in environmental protection, industrial and

pharmaceutical analysis will be presented.

References

1. G.D. Christian, Analytical Chemistry, New York, John Wiley & Sons,1994.

2. K.A. Rubinson, J.F. Rubinson, Contemporary Instrumental Analysis, Upper Saddle River:

Prentice Hall, 2000.

3. M. Valcarcel, Principles of analytical chemistry, Berlin, Springer 2000.

4. G.W. Ewing, Instrumental analysis, McGraw Hill Book Company, New York 1985.

Organic chemistry


The goal of this lecture is to give to students a background of organic chemistry. A student

who has completed this course should be able to approach the literature directly with

knowledge of modern basic organic chemistry.

Course description

The lecture is divided into three fundamental aspects of organic chemistry.

The first part is devoted to general organic chemistry: chemical bonding (localised and

delocalised), reactive species (carbocations, carboanions, free radicals etc.), acidicity and

basicity or organic compounds, stereochemistry, effects of structure on reactivity. In the

second part organic reactions are discussed: aliphatic nucleophilic and electrophilic

substitution, aromatic electrophilic and nucleophilic substitution, free radical substitution,

addition to carbon-carbon and carbon-hetero multiple bond, elimination and rearrangements.

The third part considers introduction to bioorganic chemistry. The chemistry of selected types

of biomolecules is presented, e.g. monosaccharides, nucleosides, and proteins. An application

of organic compounds in medicine will be also mentioned, particularly antitumor and antiviral

therapy.

References:

1. F.A. Carey, Organic Chemistry, 4th Ed., McGraw-Hill Higher Education, 2001.

2. Marche’s Advanced Organic Chemistry, 5th Ed., John Wiley & Sons Inc., 2001.

3. J. McMurry, Organic Chemistry, Brooks Cole/Thomson Learning, London 2000.

Transport phenomena

Objectives of the Course

Main objectives of the course are: (i) to provide students with the knowledge of heat and mass

transfer, (ii) to acquaint them with modelling and calculation of such processes, (iii) to teach

them how to design shell and tube heat exchanger and packed column absorbers.

Course description

After introduction of the concepts of heat and mass transfer the following topics are

discussed: The Heat Diffusion Equation, Solutions Of The Heat Diffusion Equation, Overall

Heat Transfer Coefficient, Fouling Resistance, Heat Exchanger Design, Extended Use Of The

LMTD, Analysis Of Heat Conduction, The Well-Posed Problem, Dimensional Analysis, The

Buckingham Pi-Theorem, Transient And Multidimensional Heat Conduction, Convective

Heat Transfer, Laminar and Turbulent Boundary Layers, Momentum Integral Method, Forced

Convection, Natural Convection & Film Condensation, Heat Transfer In Boiling, Dropwise

Condensation, Rate Laws and Transfer Coefficients, Types Of Diffusion, The Two Film

Theory, Overall Driving Forces and Mass Transfer Coefficients, The Mass Balances,

Diffusion Coefficients, Transient Diffusion and Diffusion With Reaction, A Survey Of Mass

Transfer Coefficients, Phase Equilibria, Staged Operations, The Equilibrium Stage,

Continuous - Contact Operations, Simultaneous Heat and Mass Transfer, Design of Mass

Transfer Equipment.

References

1. T. Hobler, Ruch ciepła i wymienniki, WNT, Warszawa.

2. T. Hobler, Ruch masy i absorbery,WNT, Warszawa.

3. T. Hobler, Mass Transfer and Absorbers, Pergamon Press 1966.

4. J. H. Lienhard IV, J. H. Lienhard V, A Heat Transfer Textbook, Phlogiston Press, 2003.

5. Diran Basmadjian, Mass Transfer, CRC Press, 2004.

6. R. B. Bird, W. E. Stewart, E. N. Lightfoot, Transport Phenomena, John Wiley & Sons,

Inc., 2002.

7. J. R. Welty, C. E. Wicks, R. E. Wilson, Fundamentals of Momentum, Heat and Mass

Transfer, John Wiley & Sons, Inc.

8. Coulson and Richardson, Chemical Engineering, Pergamon Press.

Industrial equipment


The course is focused on designing bases and selection of apparatuses and devices applied in

chemical and related industries. Special attention is put onto exact relationship among kinetics

of given process and functions fulfilled by designed apparatus.

Course description

The course brings near the practical principles of industrial designing. For this propose the

chosen mechanical and thermal operations like: solid materials transportation, liquids

pumping, gases transmission, vacuum making, liquid drops separation and liquids evaporation

in the industry scale are talked over, respectively. The mentioned issues are illustrated by

numerous practical examples. In the light of a one thermal process the principles of material

as well as energy balance have been detailed presented. The differences of theoretical and real

balance as well as practical results presentation has been also shown. As a pendent in the

range of “thermal” topic, the possibilities of heat energy savings are discussed and illustrated

by definitely industrial examples.

Chemical technology (organic)


The course consists of lectures as well as seminars. It is especially focused on the learning as

well as solving problems connected with the sources and application of raw materials as well

as unit operations used in organic chemical industry.

Course description

Teaching is especially focused on organic primary building blocks, intermediates, products

(bulk and fine chemicals) as well as industrial processes. Examples:

- processing of crude oil and natural gas;

- basic petrochemical products as fuels, raw materials and additives to polymers,

surfactants, drugs, pesticides and dyes;

- oxidation, hydrogenation, dehydrogenation, alkylation, halogenation, sulphonation,

nitration, esterification processes;

- catalytic and non-catalytic processes in organic technology.

The thermodynamic, kinetic, economic, ecological and safety aspects of technologies are

stressed.

References

1. „Industrial Organic Chemistry”, K. Weissermel, H.-J. Arpe, Fourth Ed., Wiley-VCH

GmbH&Co. KgaA, Weinheim, 2003

2. “Petrochemical Processes; Technical and economic characteristics”, A.Chauvel,

G. Lefebvre, Institut Français du Pétrole Publications, TECHNIP, Paris, 1989

3. Ullmann’s Encyclopedia of Industrial Chemistry, Fifth Ed., Wiley-VCH GmbH,

Weinheim, 1995

Chemical technology (inorganic)


The course consists of 3 parts: general, inorganic and organic. In general part the main stress

is laid on material and energy balances, in inorganic part the most important processes are

presented, the organic part is especially focused on the sources and application of raw

materials as well as unit operations used in organic chemical industry.

Course description

The course consists of lectures as well as seminars.

The idea of flowcharts is used for creating material and energy balances for selected systems

with and without chemical reactions.

The best available technologies (BAT) for most important inorganic chemicals such as

ammonia, nitric acid, sulfuric acid and phosphoric acid, chlorine and caustic soda are

analysed with stress on ecological impact of each technology.

In organic part teaching is especially focused on organic primary building blocks,

intermediates, products (bulk and fine chemicals) as well as industrial processes. Examples:

- processing of crude oil and natural gas;

- basic petrochemical products as fuels, raw materials and additives to polymers,

surfactants, drugs, pesticides and dyes;

- oxidation, hydrogenation, dehydrogenation, alkylation, halogenation, sulphonation,

nitration, esterification processes;

- catalytic and non-catalytic processes in organic technology.

The thermodynamic, kinetic, economic, ecological and safety aspects of technologies are

stressed.

References

1. K. Weissermel, H.-J. Arpe, „Industrial Organic Chemistry”, Fourth Ed., Wiley-VCH

GmbH&Co. KgaA, Weinheim, 2003


Weinheim, 1995

3. R.M. Felder, R.W. Rousseau, Elementary Principles of Chemical Processes, Third Ed.

John Wiley & Sons, New York 2000

4. R. Turton, R.C. Bailie, W.B.Whiting, J.A.Shaeiwitz, Analysis, Synthesis, and Design of

Chemical Processes, Prentice Hall, New Jersey 1998.

Unit operations


The two–semester course is divided into two parts: (1) – hydraulics of packed columns,

sedimentation, fluidization, dedusting, filtration and mixing, (2) – liquid extraction and

leaching. Fundamental principles of the operations, their similarities (analogies) and

distinctions, practical applicability, design methods, examples of individual constructions and

integrated technological systems are presented.

Course description

Hydraulics of packed columns, sedimentation, fluidization, dedusting, filtration, mixing –

process characteristics, main principles and their connection with actual environmental

problems, examples – practical application (e.g. thickeners, cyclones, filters, mixers). Liquid

extraction – process characteristics, liquid equilibria, equipment and flowsheets (single-stage

extraction, multistage crosscurrent extraction, continuous countercurrent multistage

extraction, fractional extraction, economic balances, stage efficiency), constructions (agitated

vessels, mixer–settler cascades, spray and packed towers, mechanically agitated

countercurrent extractors). Leaching – process characteristics, initial preparation of the solid,

methods of operation and equipment (in situ leaching, percolation tanks, countercurrent

multiple contact – the Shanks system, filter–press leaching, agitated vessels, leaching during

grinding, continuous countercurrent decantation, leaching of vegetable seeds), stage

efficiency – practical equilibrium, single–stage leaching, multistage crosscurrent leaching,

multistage countercurrent leaching, rate of leaching.

References

1. Kirk–Othmer Encyclopedia of Chemical Technology, 4th Ed., Wiley – Interscience, New

York (1991).

2. McKetta, J.J., Ed., Chemical Processing Handbook, Marcel Dekker, New York (1993).

3. McKetta, J.J., Ed., Unit Operations Handbook, Marcel Dekker, New York (1993).

4. Smith, J.C., Ed., Unit Operations of Chemical Engineering, McGraw-Hill Education –

Europe (2000).

5. Perry, R.H., Green, D.W., Ed., J. Perry’s Chemical Engineering Handbook, McGraw-Hill,

7th Ed. (1997).

Process thermodynamics


The course provides a modern approach to applied thermodynamics. After the course students

should possess a general understanding of the laws of thermodynamics and their

consequences for typical chemical systems. Gaseous systems, phase and chemical equilibria

in ideal and not-ideal systems are quantitatively treated with a number of worked examples.

Course description

The course comprises of 30 hr of lectures and 15 hr of classes.

The main topics which are covered are:

1. Process thermodynamics – basic concepts and definitions.

2. Volumetric and thermodynamic properties of pure fluids: equations of state.

3. The first law of thermodynamics: internal energy, enthalpy, energy balances.

4. The second law of thermodynamics: entropy, Helmholtz energy, Gibbs energy, general

conditions of equilibrium.

5. Open systems, the Gibbs-Duhem equation, chemical potential, fugacity and activity.

6. Phase equilibria: the phase rule, the general equilibrium condition.

7. Vapour-liquid equilibria.

8. Solutions: partial molal properties, mixing and excess functions.

9. Chemical equilibria: the equilibrium constant, equilibrium composition.

10. Thermodynamic properties of electrochemical systems.

References

1. P. Infelta, Introductory Thermodynamics, Brown Walker Press, Boca Raton, Florida 2004.

2. S. I. Sandler, Chemical and Engineering Thermodynamics, 3rd ed. John Wiley & Sons,

New York 1999.

3. V. V. Nashchokin, Engineering Thermodynamics and Heat Transfer, Mir, Moscow 1979.

4. W. R. Salzman, Chemical Thermodynamics, Dept. of Chemistry, University of Arizona,

Tucson, Arizona 85721, available at http://www.chem.arizona.edu/~salzmanr

http://www.chem.arizona.edu/~salzmanr

Industrial catalysis


Physicochemical background of catalysis, basic and most common catalytic transformations,

many applications of catalysis in heavy industry and in fine chemical production with

development and research in catalysis.

Course description

The course consists of a lecture with a complementary seminar. The lecture encompasses

presentation of physicochemical basics of catalysis with both thermodynamic and kinetic

description. The basics are explained on homogeneous and heterogeneous catalytic examples,

i.e. hydrogenation of olefins. Further industrial catalytic processes are discussed:

esterification, Alkylation, Acylation, hydroformylation, carbonylation, Wacker process,

synthesis of sulphuric and nitric acids, synthesis of ammonia, methanol, Fisher-Tropsch

process, oxidation of hydrocarbons leading to phenol, propylene oxide, synthesis of styrene,

electrocatalytic processes (fuel cells, etc.), phase transfer catalysis, catalytic petrochemical

processes (hydrotreating, reforming, MTBE synthesis, etc.) with some examples of enzymatic

processes as biocatalysis. On the seminars students present chosen topics from catalysis with

the most up-to-data news from technology and the development of catalysis together with

crucial research in this field.

References

1. P. Atkins, J. de Paula, Atkins' Physical Chemistry, Oxford University Press, Oxford 2002.

2. G.W. Parshall, S.D. Ittel, Homogeneous Catalysis, Wiley Interscience, New York, 1992.

3. N. Dorit, N. Herman, Encyclopedic Dictionary of Chemical Technology, VCH Publ., New

York, 1993.

Thermal process engineering


The course aims to acquaint students with the selected unit operations of thermal separation

methods, e.g. distillation, rectification and drying and also other issues of thermal engineering

of practical importance i.e. fuels and their combustion, fuel cells, heat recovery systems.

Course description

The selected unit operations of thermal separation: distillation, rectification, drying are

presented. The theoretical background and designing bases are explained. Regarding

distillation and rectification elaborated are the topics of physical bases of the process,

equilibrium state and diagrams for binary systems, continuous and batch systems. The drying

issues are focused on problems like: physical bases, definitions of wet gases state,

psychrometric chart and its practical application, drying curves, mass and energy balances.

The relationships between process kinetics, operation parameters, energy consumption as well

as the algorithm of designing procedure and apparatus selection are also discussed. Discussed

are also the properties of liquid, gaseous and solid fuels, basis of combustion processes and

to-date combustions techniques: fluidised bed combustion and suspension fireing, methods of

NOx emission control. Topics also include introduction to fuel cells - basis of operation,

types/classification and properties, and heat recovery – operation principles and systems.

References

1. M.J. Lockett, Distillation tray fundamentals, Cambridge University Press 1986

2. H.Z. Kister “Distillation Design” McGraw-Hill, Inc. 1992

3. G. Nonhebel, A.A.H. Moss, Drying of solids in the chemical industry, Butterworths 1971

4. H.J. Perry, D.W. Green, Perry’s Chemical Engineers’ Handbook, 7-th ed. McGraw-Hill,

Inc. 1997

Biotechnology


The students will obtain the basic information from biology, biochemistry and technology,

which are parts of biotechnology. It should help them understand the selected problems of

contemporary biotechnology.

Course description

The course contains a few parts. First of all the cell biology is presented including its

construction and mechanisms of cellular information transduction. Genome management and

tools for genetic engineering and cloning are presented. The major metabolic pathways of

basic cell nutrients: saccharides and nitrogen are also discussed. The second important topic is

enzymes, their classification, kinetics of enzymatic reactions and manners of their

immobilization. Third part is devoted for engineering principles for bioprocesses including

cells grow and stoichiometry of microbial growth, and bioreactors. The basic technological

operations and control of bioreactors are presented. In the last part the practical applications

of bioprocesses for the production of amino acids, carboxylic acids, antibiotics and others are

presented.

References

1. Biochemistry, G. Zubay, Wm. C. Brown Publishers, London 1998.

2. The organic chemistry of enzyme-catalysed reactions, R. B. Silverman,

3. Academic Press, Londyn, 2000.

4. Basic \biotechnology, C. Ratledge, B. Kristiansen, Cambridge University Press, 2002.

5. Bioprocess Engineering, Basic Concepts, M. L. Shuler, F. Kargi, Prentice Hall PTR, New

York, 2002.

Process dynamics & controlSpecialities “Fine Chemicals and Speciality Materials” and Speciality “Process Engineering

for Green Chemical Technologies"


The goal is to learn about: basic concepts in dynamics and dynamic modelling, basic concepts

in automatic control. Another goal is to become familiar with equipment needed for

implementation of control.

Course description

This course explains basic principles of process operation and importance of dynamic

modelling. The subject area of the course is divided into three sections:

o Dynamics and dynamic modelling

o Concepts in automatic control and types of control

o Instrumentation for control implementation.

The first section covers the topics of dynamic model creation, standard form of the model,

linearization of the model, Laplace transform and transfer function form of the model. This

section also presents dynamics analyze path and its importance for control. In second section

students become familiar with basic concepts in automatic control, different types of control

and properties of closed loop control. The last section covers the topics of control

implementation (sensors & transmitters, actuators, distributed control systems and smart

instrumentation).

The lecture notes for this course and other information could be found at:

http://terminator.ia.polsl.gliwice.pl/dydaktyka/pdc/

References

1. W.L. Luyben, Process Modelling, Simulation And Control For Chemical Engineers,

McGraw-Hill Publishing Company, 1996, (2nd ed.).

2. DOE Fundamentals Handbook - Instrumentation And Control (2 volumes), U.S.

Department of Energy, Washington 1992.

3. D.R. Coughanowr, Process Systems Analysisand Control, McGraw-Hill Publishing

Company, 1991, (2nd ed.).

4. C.A. Smith, A.B. Corripio, Principles and Practice of Automatic Process Control, John

Wiley & Sons, Inc., 1997 (2nd ed.).

Electrical engineering & electronics


The main goal of the course is to provide students with general knowledge concerning

principles of construction, operation and application of electrical and electronic devices.

Course description

Basic concepts, electrostatic field, potential, magnetic field, electromagnetic field. Elements

of a circuit, resistor, inductor, capacitor, resistance, conductance, inductance, capacitance.

Voltage, current, Ohm’s law, ideal sources, real sources, controlled sources, power,

Kirchhoff’s laws. Introduction to AC circuits, phasor method and its application, impedance

and admittance, resonance. Basic electronic devices, diodes, transistors, operational

amplifiers, integrated circuits.

Circuits with magnetic coupling, coupled inductors, principle of transformer operation.

Electrical machines. Classification and basic information about electrical motors. Application

of electrical machines in chemistry.

Power system. Electrical power delivery to chemical plants. Safety rules. Three phase systems

and their classifications.

Meters and measurements of electrical and non-electrical quantities, noise in measurement

systems, measuring equipment in chemical industry. Industrial communication networks.

Supervision systems.

Principles of digital signal processing, sampling and reconstruction. Fourier series and

transform, frequency spectrum. DFT and FFT. Filtering, analog and digital filters.

References

1. D.J. Shanefield, Industrial Electronics for Engineers, Chemists and Technicians, Noyes

Publication, Norwich 2001.

2. J.H. McClellan, R.W. Schafer, M.A. Yoder, Signal Processing First, Prentice-Hall, Upper

Saddle River 2003.

3. N. Morris, Electrical and Electronics Engineering Principles, Longman Scientific and

Technical, Harlow 1994.

Bioprocess engineering fundamentals


The course aims to introduce students to the topics of bioprocess engineering and engineering

aspects of using biological materials in the process industries.

Description of the course

Balances: elemental material balances for growth, product formation stoichiometry, heat-

balance equations. Constraints for the growth of biomass. Kinetics of enzyme-catalyzed

reactions: simple kinetics with one and two substrates, activation, deactivation, inhibition,

effects of pH and temperature. Kinetics of substrate utilization by microorganisms, product

formation and biomass production. Identification of kinetic parameters. Nutrient media.

Macrokinetics in heterogeneous systems. Bioreactors, types, properties, specific applications

and mathematical modelling. Upstream and downstream processing. Product recovery

operations. Biological wastewater treatment: activated sludge process and anaerobic

technologies, properties, operation principles. Computations and simulations of selected

situations.

References

1. J Nielsen, J. Villadsen, Bioreaction Engineering Principles, Plenum Press, New York

1994.

2. J.E. Bailey, D.F. Ollis, Biochemical Engineering Fundamentals, 2 ed., McGraw-Hill Inc,

New York 1986.

3. K. Schuegerl, Bioreaction Engineering, Vol.2. Characteristic Features of Bioreactors, J.

Wiley, New York 1991.

Reactors and reaction engineeringSpecializations “Fine Chemicals and Specialty Materials” and “Process Engineering for

Green Chemical Technologies"


The lecture is concerned with the fundamentals of chemical reaction engineering and reactor

design. It is intended primarily for instruction at basic level with the emphasis on reactor

design. However substantial portion of the material deals with advanced problems and could

be a background for further study.

Course description

Introduction; Chemical treatment steps, Stoichiometry (independence of reactions,

concentration changes with a single reaction and with several reactions, rate of reaction); The

reaction order; Elementary reactions and molecularity. Thermochemistry; Heat of reaction and

its variation; Rate of generation of heat by reaction: Chemical equilibrium; The calculation of

homogeneous equilibrium compositions. Kinetics of homogeneous reactions; Concentration

and temperature dependent terms of a rate equation; Searching for a mechanism.

Mass balances of different reactor types; Batch operation; Continuous stirred tank reactor

CSTR: Tubular plug flow reactor; Cascade of CSTR’s.

Homogeneous reactor design; Design for a single reaction; Design for multiple reactions

(parallel and series reactions). Comparison and choice of reactors for a single homogeneous

reaction. Nonideal Flow; Residence time distribution, Models for nonideal flow; Dispersion

model. Catalyst and characterization; definitions and catalyst properties. Kinetics of catalytic

reactions; Surface reactions; Mechanisms and Kinetic Models; Synthesizing a rate law.

Design of reactors for gas-solid reactions. Heterogeneous data analysis for reactor design;

Catalyst deactivation. External diffusion effects in heterogeneous reactions. Diffusion and

reaction in porous catalysts; Spherical catalyst pellets; Internal and external transport

processes; Internal effectiveness factor; overall effectiveness factor. Heat and Mass transfer

and reaction in a packed bed; Conservation equations and simplifications; Autothermic

reactors.

References

1. R. Aris, Elementary Chemical Reactor Analysis, Dover Publications 1989.

2. O. Levenspiel, Chemical Reaction Engineering, John Wiley, 1962.

3. H.S. Fogler, Elements of Chemical Reaction Engineering, Prentice-Hall, 1986.

Separation processesSpecializations “Fine Chemicals and Specialty Materials” and “Process Engineering for



Main objectives of the course are: (i) to provide students with the knowledge of solvent

extraction, leaching and supercritical extraction techniques, (ii) to acquaint them with

modelling and calculation of such processes, (iii) to practice design of selected systems:

absorbers and continuous tray fractionation columns.

Course description

After introduction of the concepts of solvent extraction, leaching and supercritical extraction

the following topics are discussed: liquid equilibria, prediction of the distribution, selection of

solvent and solvent recovery, methods of calculation of stagewise contact ternary systems

with one solvent, continuous contercurrent contact, laboratory equipment, pilot plant

acquisition data. Apparatus, equipment for stagewise contact, equipment for differential -

continuous contact, issues of extractor economics, liquid extraction processes; petroleum

refining; fat, oil and similar processes; coke-oven processes; pharmaceuticals; inorganic

processes; leaching, supercritical extraction.

Problems of mass diffusion and transfer are only noted outlined to consolidate the knowledge

and understanding of the processes and design.

References

1. Diran Basmadjian, Mass Transfer, CRC Press, 2004.

2. R. E. Treybal, Liquid extraction, Mc Graw-Hill, 1963.

3. T. C. Lo, M. H. I. Bird, C. Hanson, Handbook of Solvent Extraction, John Willey, 1983.

4. R. D. Noble, P. A. Terry, Principles of Chemical Separations with Environmental

Applications, Cambridge U. P., 2004.

5. E. L. Cussler, Diffusion, Mass Transfer In Fluid Systems, Cambridge U. P., 2003.

Gas cleaning and water treatmentSpecialization “Process Engineering for Green Chemical Technologies"


Presentation of any waste treatment systems and basic understanding of the fundamental

methods for gas cleaning and wastewater treatment.

Course description

The course is divided into two parts: gas cleaning and wastewater treatment. Water and air are

essential for life. If they become polluted its loses theirs values and can become a threat to

health. Some kinds of pollution can occur through natural process, however it is mostly

a result of human activity. Therefore, as an introduction the laws and the regulations of the

country are discussed. In the first part chemical engineering unit operation, commonly used

for the control of gases emission, are presented. The science and technology of settling

chambers, cyclones, inertial dust collectors, wet scrubbers, fluidized-bed, dust collectors,

cloth filters and electrostatic precipitators are studied. It covers topics a type, performance,

sizing procedure, practical considerations, scientific principles and mechanisms. Additional,

three unit operations becoming more and more popular in the recent years: biofiltration,

membrane filtration and selective combustion methods are presented. The aim of the second

part is to provide the initial perspective of treatment, disposal and reuse of wastewater, brief

review of the historical background, current status and expected new trends of wastewater

engineering. Also the subject of source control, collection transmission and the units

operations: primary, secondary and advanced (tertiary) treatment of a typical wastewater plant

are presented. In the primary treatment (physical removal of floatable and settleable solids)

physical operations such as screening, sedimentation and flotation are studied. During

secondary treatment (the biological removal of dissolved solids) biological and chemical

process include activated sludge, tricking filters and lagoons are described. Nowadays, an

increasing number of wastewater facilities employ tertiary treatment. Therefore this process is

also discussed during this course. Tertiary treatment may include processes to remove

nutrients such as nitrogen and phosphorus, and carbon adsorption to remove chemicals. These

processes can be physical, biological, or chemical.

References

1. K. Wark, C. F. Warner, W. T. Davis, Air Pollution, Its Origin and Control, Addison

Wesley Longman 1998.

2. G. Tchobanoglous, F. L. Burton, Wastewater Engineering, Treatment Disposal and Reuse,

McGraw-Hill Inc. 1991.

3. E. D. Schroeder, Water and wastewater treatment, McGraw-Hill 1977.

Membrane technologiesSpecializations “Fine Chemicals and Specialty Materials” and “Process Engineering for



This course will enable students to understand and solve membrane-based separation/reaction

problems by acquiring in-depth knowledge in the area of membrane separation mechanisms,

transport models, membrane permeability, membrane types and modules, and membrane

reactors.

Course description

Classification of membranes and membrane processes. Pressure driven membrane processes,

electro membrane processes. Driving forces and mass transfer mechanisms. Polarization

phenomena and membrane fouling. Aspects of the design of membranes, membrane modules

and membrane systems. Operating principles of major membrane processes. Microfiltration

and ultrafiltration. Vapor permeation. Reverse osmosis and nanofiltration. Pervaporation.

Electrodialysis and related processes. Liquid membranes. Membrane bioseparations.

Membrane contactors. Membrane permeators for gas separation. Catalytic membrane

reactors. Selected applications and economic aspects of membrane technology in the fields of

biotechnology, controlled release, chemical and food processing, electrical power generation,

water and wastewater treatment, desalination. Hybrid and integrated processes. Future

progresses in membrane engineering.

References

1. R. W. Baker, Membrane Technology and Applications, John Wiley and Sons,

2004.

2. M. Mulder, Basic Principles of Membrane Technology, Kluwer Academic Publishers,

1996.

Environmental protectionSpecialization “Process Engineering for Green Chemical Technologies"


The main goals of this class are better understanding of the cost-benefit ratio of various

alternative energy sources. The main problems (acidic rain, ozone hole and greenhouse effect)

which have a great impact on environment is discussed.


Alternative energy refers to energy sources which are not based on the burning of fossil fuels

or the splitting of atoms. The renewed interest in this field of study comes from the

undesirable effects of pollution (as witnessed today) both from burning fossil fuels and from

nuclear waste byproducts. Fortunately, there are many means of harnessing energy which

have less damaging impacts on our environment. This course deals with the issues of

alternative energy sources and sustainable energy sources. The intent is to perform an

objective cost-benefit analysis on each form of alternative energy in order to determine what

is practical on a large scale, as well as on the scale of the individual homeowner. Particular

attention is paid to the efficiency of each alternative energy source as well as what limitations

exist in terms of extracting useable energy. The course starts out with solar energy but then

moves to other alternative energy sources such as, wind, tides, hydroelectric, ocean currents,

geothermal and biomass. During this course students also receive information about actual

global problems such as acid rain effect, greenhouse effect and ozone hole. Causes, effects,

and possible solutions are discussed. At the end, solid waste management (generation,

storage, collection, transportation and disposal) is presented.

References

1. M. L. McKinney, R. M. Schoch, Environmental Science, Jones & Bartlett Publishers

2003.

2. J. R Fanchi, Energy in the 21st Century, World Scientific, 2005.

3. Maureen Christie, The Ozone Layer, Publisher Cambridge University Press, 2001.

Characterization of chemicals & materials structure & propertiesSpecialization “Fine Chemicals and Specialty Materials”


The course aims to acquaint students with modern spectroscopic and other instrumental

techniques employed in characterization of chemical compounds and manufactured out of

related materials, e.g. plastics, ceramics, composites and other specialty materials.

Course description

The course consists of lectures and labs. The content of the course, especially the labs

programme, is limited to the techniques which are available at the Faculty of Chemistry of the

Silesian University of Technology. Theretofore, some important modern techniques will be

temporarily omitted due to their inaccessibility on the site. However, those included into the

course, compose themselves a representative set of the most important and widely used

nowadays instrumentation aimed as above.

The course comprises: mass spectrometry (MS), UV, VIS and IR spectrophotometry, NMR

spectroscopy, gas and liquid chromatography (GC and HPLC), X-ray difractometry,

differential scanning calorimetry (DSC) and atomic force microscopy (AFM). The lecturers

are selected from among staff members having a long-term experience in using of given

techniques and capable of teaching both a good theoretical background and a practical use of

particular instrumentation.

References

1. E. Derome, Modern NMR Techniques for Chemistry Research, Pergamon Press, Oxford

1987.

2. R. M. Silverstein, F. X. Webster, Spectrometric Identification of Organic Compounds, 6-th

ed., J Wiley & Sons, New York, 1998.

3. Uwe D. Neue, HPLC Columns. Theory, Technology and Practice, John Wiley & Sons,

New York 1997.

4. D. E. Sands, Introduction to Crystallography, Dover Publ. Inc., New York, 1993.

5. S. N. Magonov, M.-H. Whangbo, Surface Analysis with STM and AFM, VCH Weinheim ,

New York Basel, 1996.

6. T. Hatakeyama, F. X. Quinn, Thermal analysis. Fundamentals and Applications to

Polymer Science, John Wiley and Sons, West Sussex 2000.

Basic bioorganic chemistryOptional course


The course is addressed to students interested in knowledge of chemical reactions occur at

molecular level. The actual trends of investigation in molecular biology and biochemistry are

presented.

Course description

The course consists of lectures and seminars. The particular topics for lectures covered

receptor theories, drug – receptor interactions, the structure of cell membranes and forms of

trans membrane transport. The special attention is paid for selected problems in chemistry of

nucleosides, nucleotides and nucleic acids, including methods for synthetic nucleic acids

preparation. Chemistry and form of action of selected types of bioactive compounds including

antiviral, antibacterial and antineoplastic drugs are also discussed. The aspects of biogenetic

processes, prebiothic synthesis including key substrates and biomimetics are also mentioned.

Lecturer suggests the subjects for seminar but students can propose they individual topics.

The students prepare their own presentation using available sources: scientific papers, books

and information available by Internet.

References

1. R. B. Silverman, The Organic Chemistry of Drug Designe and Drug Action, Academic

Press 1992.

2. J. H. Block, J. M. Beale, Organic medicinal and pharmaceutical chemistry, Lippincott

Williams & Wilkins 2004.

3. G. Zubay, Wm. C, Biochemistry, Brown Publishers, London 1998.

4. R. B. Silverman, The organic chemistry of enzyme-catalysed reactions, Academic Press,

Londyn, 2000.

General chemical technology IISpecializations: “Fine Chemicals and Specialty Materials” and “Process Engineering for



The laboratory course is especially focused on the learning as well as solving problems

connected with the main unit operations used in organic and inorganic chemical industry.

Course description

Part of the course, connected with organic industrial chemistry, allows students to recognize

and perform processes widely applied in industry (alkylation, oxidation, esterification, etc.).

The integration of some processes e.g. alkylation, oxidation, acid decomposition helps to

learn how to choose proper raw materials, catalysts, reaction system and reaction conditions

(temperature, concentration, residence time and mixing) to obtain desired product with

a highest selectivity or yield. The second part of the course acquaints students with inorganic

– heterogeneous (gas-liquid-solid) and catalytic processes (e.g. carbonisation of ammoniacal

brine and contact oxidation of sulphur dioxide).

Discussion about advantages and disadvantages of each system is also involved.

Thermodynamic, kinetic, economic, ecological and safety aspects are stressed.

References

1. K. Weissermel, H.J. Arpe, Industrial Organic Chemistry, Fourth Ed., Wiley-VCH

GmbH&Co. KgaA, Weinheim, 2003.

2. A. Chauvel, G. Lefebvre, Petrochemical Processes; Technical and economic

characteristics, Institut Français du Pétrole Publications, TECHNIP, Paris, 1989.


Weinheim, 1995.

Principles in polymer chemistrySpecialization “Fine Chemicals and Specialty Materials”


The course aims to introduce undergraduate students to the field of polymer chemistry,

acquaint students with techniques of molecular weight determination and modern

spectroscopic techniques applied in the characterization of macromolecules.

Course description

The course consists of lectures and labs. The content of the course includes the general

considerations of addition and step-growth polymerizations. The polyreactions will be

defined in the terms relating to reactions involving, organic compounds with C=C or C=O

bond, heterocyclic compounds, the nature of the initiation, characteristics depending on which

of three initiation steps in polymerisation (mechanism of propagation – radical, cationic

anionic), and the termination of growing chains, and copolymerisation.. Another route for the

preparation of polymers starts with the polycondensation (step-growth polymerisation). The

lecture also consists characterization of linear polycondensation, definitions of extent of

reaction p, number average degree of polymerisation as a function of conversion, non-

stoichiometric equivalence of bifunctional monomers, molecular weight distributions,

cyclization versus linear polycondensation.

The course comprise: osmometric, ebuliometric and cryoscopic methods, viscosity

measurement, end-group assay, size exclusion chromatography, light scattering method and

ESI-MS , MALDI-ToF – methods for molecular weight determination.

The labs programme, is limited to the experiments of radical polymerisation and

copolymerisation, linear and crosslinked structure polymers, cationic polymerisation of

oxiranes and determination of kinetics of polycondensation.

.

Reference

1. G. Odian, Principles of Polymerization, 3-th ed., J Wiley & Sons, New York, 1991.

The sol-gel and nanostructured materialsSpecialization “Fine Chemicals and Specialty Materials”


The course aims to introduce undergraduate students to the field of colloids applied to obtain

nanostructured materials, known as the sol-gel processing, and also the use of liquid crystal

templates as the structure directing agents.

Course description

The course is divided into three parts: lectures, labs and seminars, to provide students with a

sound knowledge of both fundamental and practical issues of the sol-gel processing.

Lectures provide an outline of the principal sol-gel processing issues, i.e. chemistry of

precursor solutions, colloidal particles and sols, gelation, ageing, gels. Classification and

properties of wet gels, drying, properties of dry gels. Characterisation of sol-gel materials.

Metal-oxide gels and hybrid organic-inorganic materials. Ordered mesoporous materials made

with surfactant templates. Sintering of sol-gel ceramics. The seminars focus on the application

of sol-gel processing to obtain advanced materials: coatings and thin films, microfibers, micro

- and nanoparticles, monoliths.

Lab works aim to consolidate the knowledge of the method by carrying out practical synthesis

and characterisation of selected materials.

References

1. A.C. Pierre, Introduction to sol-gel processing, Kluver, Dodrecht 1998.

2. J.D. Wright, N.A.J.M. Sommerdijk, Sol-gel materials. Chemistry and application, Gordon

& Breach, Amsterdam 2001.

Process safety & wastes managementSpecializations: “Fine Chemicals and Specialty Materials” and “Process Engineering for



The objectives of the course are: (i) to give students the knowledge about Process Safety and

Waste Management, (ii) to form thinking in terms of safety and environmental protection, (iii)

to practice the above by analysis of the major case history studies.

Course description

After an introduction to the problems of Process Safety and Waste Management, the

following topics will be considered: legislation of EU, USA, and Poland; hazard incident and

loss. Major hazard control, economics and insurance, management and management systems,

reliability engineering, hazard identification, reactive chemicals, hazard assessment, plant

sitting & layout, process design, pressure system design, control system design, human factor

& human error, fire & explosions, toxic release, plant commissioning and inspection, plant

operation, accident research, waste management.

References

1. C. Ray Asfahl, Industrial Safety and Health Management, Prientice Hall, 2003.

2. J. P. Seiler, Good laboratory Practice, Springer, 2001.

3. R. E. Sanders, Chemical Process Safety, Learning from Case histories, B.H., 1999.

4. V. Marshall, S. Ruhemann, Fundamentals of Process Safety, IChemE, 2002.

5. S. Mannan, Lee's Loss Prevention in the Process Industries, Elsevier, 2005.

Process system engineeringSpecialization “Process Engineering for Green Chemical Technologies"


Fundamental introduction to the design of chemical processes. The basic procedures are

presented and explained in detail. Practical problems are solved to illustrate the usefulness of

provided rules. Selected modern CAD programs are presented to demonstrate their functions

and possibilities.

Course description

The design process – its objectives, basic steps in designing and retrofitting the chemical

processes, creation of the new process concept, development of base case, detailed process

synthesis using algorithmic methods, detailed design, equipment sizing, cost estimation,

profitability analysis, optimization. Plantwide controllability assessment. Environmental

protection – environmental factors in process design. Safety considerations, design

approaches toward safe chemical plants.

Application of computers – basic spreadsheets, mathematical packages, process simulators

(ASPEN PLUS, HYSYS, PREO/II, CHEMCAD, computational guidelines. Principles of

flowsheet simulation.

Detailed process creation – database preparation, thermophysical property data, role of

experiments, preliminary process synthesis – continuous/batch processing, chemical state of

the substance, synthesis steps – unit operations, synthesis tree, heuristics for process

synthesis.

Detailed process flowsheet, process integration, process simulation and pilot plant testing.

Interaction of process design and automatic process control. Profitability analysis.

References

1. J.M., Douglas, Conceptual Design of Chemical Processes, McGraw–Hill, New York

(1988).

2. A.L. Myers, and W.D. Seider, Introduction to Chemical Engineering and Computer

Calculations, Prentice–Hall, Englewood Cliffs, NJ (1976).

3. G.D. Ulrich, A Guide to Chemical Engineering Process Design and Economics, Wiley,

New York (1984).

Process equipment designSpecialization “Process Engineering for Green Chemical Technologies"


In the course the selected issues of process design like: (i) common presentation of mass end

energy balances (ii) optimum parameters of selected operations, (iii) block and flow-sheets

drawing, (iv) scale up, are discussed, respectively. The classes are focused on practical

designing of each operation.

Course description

The issues have been applied to the chemical and related industries and their specific

requirements. The selected topics of process equipment design like: (i) common presentation

of mass and energy balance results in the form of figures and tables, (ii) optimum parameters

of selected operations, (iii) block and flow-sheets preparation for processes in chemical

industry, (iv) scaling up problems, are presented, respectively. The practical backgrounds of

designing bases are mainly emphasised, as the concrete examples of engineering in the

domain of chemical industry are prepared for discussion. The proper apparatus selection is

also taken into consideration as well as the relationship among operation parameters, energy

consumption, and production economy.

References

1. H.J. Perry, Chemical Engineers’ Handbook, 5-th ed. McGraw-Hill, Inc. 1973.

2. W.L. McCabe, J.C. Smith, Unit Operations of Chemical Engineering, McGraw-Hill, Inc.

1976.

Process simulation optimization and designSpecialization “Process Engineering for Green Chemical Technologies"


The main objective of the course is the introduction to up-to-date routines, procedures and

then computational systems (software), enabling simulation and optimisation of major

processes within the field of chemical engineering, followed by more detailed practical course

on selected engineering cases. A general knowledge, gained by the theoretical part of the

course, will be successively enhanced by the detailed discussion and practice of selected

engineering cases/processes by means of both, universal and highly specialised software

solutions.

Course description

Current state of art within the field of process simulators significantly enhance the process

design which leads to the work yield increase, hence more and more interest is found within

this specific field of technical solutions. As such this sub-discipline is found among the

important ones for modern chemical and process engineer. Therefore the course will be

focused on both, theoretical background and the practical use of selected tools commonly

used in practice. A general introduction to principles and types of computational simulation,

optimisation and design of basic process within the field of chemical engineering will be

carried out. Selected unit operations and their more complex assemblies will be discussed in

view of the potential use of either universal software, like MathCAD, and more complex

solutions such as very advanced process simulators, namely ChemCAD.

Theoretical part of the course will comprise of the following, key issues:

- brief introduction to selected major process,

- standard routines of process simulation, optimisation and design (general overview),

- general introduction to process automation,

- theoretical background of modern solutions;

o implementation of simple tools e.g. Excel worksheets and their capabilities,

o more advanced computational systems e.g. MathCAD,

o high-end solutions like ASPEN, HYSYS and ChemCAD.

Successive practical part of the course will include:

- examples of design routines enhancement by means of simple tools like own-developed

worksheets,

- practicalities relevant to MathCAD system, enabling user friendly implementation of more

advanced mathematical engines within the engineering design procedure,

- the practical use of ChemCAD system for simulation, optimisation and design of selected

unit operations and more complex systems.

Economical aspects of process optimisation will be also addressed to during both parts of the

course. Each part of the theoretical course will be reflected by the relevant practice scope.

References

1. R.H. Perry, D.W. Green, Perry's Chemical Engineers' Handbook, (7th Edition), McGraw-

Hill, (1997).

2. A.L. Myers, W.D. Seider, Introduction to Chemical Engineering and Computer

Calculations, Prentice-Hall, Englewood Cliffs, NJ (1976).

3. G.D. Ulrich, A guide to Chemical Engineering Process Design and Economics, Wiley,

New York (1984).

4. ChemCAD 5 Manual, ChemCAD 5 Example Book, ChemCAD 5 Training Book. (available

from lecturers).

Manufacturing, processing and application of polymersSpecialization “Fine Chemicals and Specialty Materials”


The course aims to introduce undergraduate students to basics of industrial methods of

manufacturing of polymers, their basic use properties and processing as well as the scope of

their conventional and uncommon applications related to the properties of selected specialty

polymers.

Course description

The course consists of lectures and labs. The lectures introduce the students into industrially

important methods of manufacturing of polymers and resins illustrated by technology of

selected commodity polymers, such as PE, PS, PVC, PET, PC, and EP. Basic properties of

plastics and relation with their application are discussed. Methods of tailoring their properties

by chemical or physical modification are presented as well. Main methods of processing of

plastics, both thermoplastic and thermoset ones are presented too. Introduction in basic

practical problems of manufacturing, processing and application of the polymers is followed

with presentation of the polymers and polymeric materials displaying special properties and

purposed for special applications, such as resins for coatings, high performance polymers

including LC ones, stimuli sensitive polymers, shape memory polymers etc.

Students will verify their theoretical background concerning polymers and resins during

laboratory exercises based on preparation, characterization and processing of epoxy resins.

References

1. C.D.Craver, C.E.Carraher, Jr., Applied Polymer Science. 21st Century, Elsevier,

Amsterdam 2000.

2. C.A.Harper, E.M.Petrie, Plastics Materials and Processes: a Concise Encyclopedia,

Wiley, 2003.

3. D.Rosato, Plastics Processing Data Handbook, Chapman & Hall, London 1997.

4. D.Stoy (Ed.), Paints, Coatings and Solvents, VCH, Weinheim 1993.

5. T.Brock, M.Grotelklaes, P.Mischke, European Coatings Handbook, C.R.Vincentz Verlag,

Hanover 2000.

Fine chemicals – synthesis and applicationSpecialization “Fine Chemicals and Specialty Materials”


The goal of the course is to introduce some theoretical and practical problems connected with

fine chemicals. It concerns synthesis of different groups of fine chemicals, process

development, environmental factor and registration.

Course description

The course consists of lectures, seminars and labs. Lectures provide the information

concerning production of fine chemicals, product life cycle, registration problems and

environmental factor as well as principles of development of processes. Examples of

production of the particular groups of fine chemicals will also be given. The laboratory course

focuses on the practical application of knowledge about synthesis of fine chemicals using

different methods, catalysts and systems e.g. phase transfer catalysis as well as ionic liquids.

Syntheses of plasticizers, dyes, intermediates, cosmetics ingredients and others as well as their

application are also part of the lab course. Seminars introduce discussion about other groups

of fine and specialty chemicals like plant protection products, biocides, pharmaceuticals,

vitamins, etc.

References

1. N. G. Anderson, “Practical Process Research and Development”, Academic Press, New

York, 2000.

2. D.F. Williams, W.H. Schmitt, "Chemistry and Technology of the Cosmetics and Toiletries

Industry", Blackie Academic & Proffessional, New York 1996.

3. Sheldon R.A., van Bekkum H., Fine Chemicals through Heterogeneous Catalysis, Wiley-

VCH, Weinheim, 2001.

4. Peter Wasserscheid, Tom Welton (Eds.) „Ionic Liquids in Synthesis”, WILEY-VCH 2003.

5. Ullmann's Encyclopedia of Industrial Chemistry, Vol. A20, 193, VCH Verlagsgesellschaft,

Weinheim 1994.

Bioprocesses for environmental protectionSpecialization “Process Engineering for Green Chemical Technologies"


The course aims to acquaint students with the applications of bioprocesses to tackle major

issues of environmental protection, i.e. wastewater, air, land and waste treatment.

Course description

Regulations and monitoring parameters. Wastewater treatment – general background, primary

and secondary pollutants. Review of the methods - aerobic and anaerobic processes - typical

parameters, selection of the method. Activated sludge process – balances, kinetics of

digestion. Nitrogen and phosphorous removal. Nitrification and denitrification. Contact

stabilisation. Modelling and scale up. Selection of aerators. Anaerobic treatment – process

fundamentals, kinetics of digestion, production of biogas, modelling and scale up. Removal of

VOC on biofilters. Composting of solid wastes. Typical set ups and plant configurations.

References

1. H.-J. Rehm, G. Reed, eds., Biotechnology, vol. 11a. J. Winter , ed, Environmental

Processes I, VCH-Wiley, Weinheim 1999.

2. K. Schruegerl, Bioreaction Engineering, J.Wiley, Chichester 1991.

Mass crystallizationSpecialization “Process Engineering for Green Chemical Technologies"


Fundamental introduction to the mass crystallization problems. Process design and

overcoming the possible operation problems. Crystallization kinetics and its interaction with

side–phenomena. Mathematical models of the process. Practical applicability of mass

crystallization operation.

Course description

Fundamentals of mass crystallization from solution. Mass crystallization as a unit operation.

Definition of crystal size and shape. Solubility and supersaturation. Nucleation phenomena –

their mechanisms and possible sources of nuclei in industrial crystallizers. Primary nucleation

– homogeneous and heterogeneous. Origin of secondary nuclei. Crystal growth – mass

transport through the film, surface integration processes and their kinetics. Size dependent

crystal growth. Growth rate dispersion. Crystal growth rate expressions. Mathematical

modeling of the crystallizing systems. Population balance concept. General population

equation. Moments of the distribution. Average sizes. Coefficient of variation – CV. An

MSMPR crystallizer model – an idealized configuration concept. Population balance for

MSMPR configuration. Population density distribution function – for size independent and

size dependent growth kinetics. Selected more complex population functions – deviations

from MSMPR crystallizer configuration, internal classification of solids, external

classification, attrition, agglomeration. Derivation of pure crystallization kinetics. Derivation

of crystallization kinetics from distributions affected by population functions. Physical

transport phenomena in mass crystallization – influence of hydrodynamics on the system’s

performance and crystal product’s quality. Sampling and analyzing the crystallizing systems.

Crystallizer design (batch and continuous). Reaction–crystallization (precipitation) systems –

their design and practical application.

References

1. S.J. Jančić, P.A.M. Grootscholten, Industrial Crystallization, Delft University Press,

D. Reidel Publishing Company (1984).

2. J. Nývlt, Industrial crystallization – the present state of the art, Verlag Chemie,

Weinheim – New York (1978).

3. J. Nývlt, O. Söhnel, M. Matuchová, M. Broul, The kinetics of industrial

crystallization, Elsevier, Amsterdam–Oxford–New York–Tokyo (1985).

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