PROGRESS REPORT ON THE GEOKINETICS HORIZONTAL
IN SITU RETORTING PROCESS
M. A. Lekas
Geokinetics Inc.
280 Buchanan Field Road
Concord, CA 94520
Geokinetics Inc., in cooperation with
the U. S. Department of Energy, is engaged
in developing an in situ process for the
extraction of shale oil. The process is
designed specifically for areas where the
oil shale beds are relatively thin and
close to the surface. We call this
technique the LOFRECO process. Geokinetics
is a very small company, and does not have
the resources for massive capital expendi
tures ahead of production. Therefore, we
set out to develop a process with low
front end costs. The result was the
LOFRECO process - LOFRECO being an acronym
for Low Front End Cost.
LOFRECO truly lives up to its name.
Front end costs are minimal, as most of the
expenditures are in the form of operating
costs. In the process, a pattern of
blastholes is drilled from the surface,
through the overburden, and into the oil
shale bed. The holes are loaded with
explosives and fired, using a carefully
planned blast system. The blast results
in a well fragmented mass of oil shale,
with a high permeability. The void space
in the fragmented zone comes from lifting
the overburden, and producing a small
uplift of the surface.
The fragmented zone constitutes an
in situ retort. (Figure 3) The bottom
of the retort is sloped to provide drain
age for the oil to a sump where it is
lifted by a number of oil production wells.
Air injection holes are drilled at one
end of the retort, and off gas holes are
drilled at the other end.
The oil shale is ignited at the air
injection wells, and air is injected to
establish and maintain a burning front
that occupies the full thickness of the
fragmented zone . The front is moved in a
horizontal direction through the fractured
shale towards the off gas wells at the far
end of the retort. The burning front
heats the oil shale ahead of the front,
driving out the shale oil, which drains to
the bottom of the retort,where it flows
along the sloping bottom to the oil pro
duction wells. As the burn front moves
from the air-in to the air-out wells, it
burns the residual coke in the retorted
shale as fuel. The combustion gases are
recovered at the air-out wells. This gas
is combustible, and could be used for
power generation. Progress of the burn
front is monitored by thermocouples set
in thermocouple wells.
Although the process was designed to
retort relatively thin oil shale beds
under shallow overburden, the basic
horizontal burn that is being developed
can be applied to a number of other
situations, such as a modified in situ
process in thinner oil shale beds, or as
a secondary recovery process to follow
after a room and pillar mining operation
to recover oil from the mine pillars and
from oil shales above and below the mined
zone.
Laboratory and pilot work was carried
out at the Geokinetics facilities at
Concord, California, during 1974 and early
1975, to demonstrate the technical
feasibility of establishing and maintaining
a horizontally moving burning front
through a random sized mass of rubblized
oil shale.
In March of 1975, leases on oil
shale lands suitable for the LOFRECO
process were acquired in the Book Cliffs
area, south of Vernal, Utah, on lands
228
owned by the State of Utah. The oil shale
bed is approximately 30 feet thick, and has
an average grade of about 23 gallons per
ton. The beds strike in an east-west
direction and dip to the north at about
120 feet per mile. Overburden over the
shale ranges from zero to 150 feet.
(Figure 1)
The leases are located in a very
remote area, 70 miles from the nearest
settlement. Communication is by a poorly
maintained, unpaved road. There are no
power lines or telephone lines in the area.
Immediately upon acquiring the property,
field operations began. Because of the
remote location and poor communications, it
was necessary to establish a fully equipped,
self-contained living and operating
facility at the test site. In order to
move the project ahead with the minimum
delay, the experimental work began concur
rently with the construction of the camp
facilities, and the camp has grown as the
project progressed and increased in size.
The initial camp was established in April
of 1975, and was promptly christened
"KampKerogen."
Kamp Kerogen consisted
initially of three tents and outdoor cooking
and eating facilities. The field work
progressed rapidly. Two small retorts
were blasted in July of 1975, and the first
small retort was ignited on March of 1976.
Work has proceeded seven days a week, and
continued throughout the winters despite
heavy snowfall and difficult living
conditions .
Our field program has made steady
progress since its inception in the spring
of 1975. After four years of field work,
we have blasted 18 retorts, and burned
11 retorts. In the course of carrying out
our experimental work, we have produced
over 5,000 barrels of shale oil. Kamp
Kerogen has grown from three tents in the
sagebrush to a small village, with a
permanent population of 30 persons,includ
ing wives and children.
It has been demonstrated that:
1) It is possible to drill a pattern
of blastholes from the surface into the
oil shale, and fracture the shale in a
manner to establish a zone of high perme
ability in the shale, with a relatively
impermeable zone between the fragmented
shale and the surface.
2) It is possible to drill through
the rubblized material, and construct the
various wells necessary for the operation,
including air-in holes, off gas holes,
oil recovery wells and instrument wells.
3) A point ignition can be made in
the rubblized shale and expanded into a
burn front that covers the cross section
of the retort.
4) The burn front can be moved down
the length of the retort as a cohesive
temperature front, with satisfactory sweep
efficiency.
5) Produced oil can be recovered
from a well drilled to the bottom of the
rubblized zone.
We feel that the technical feasibility
of the LOFRECO process is established. We
are now engaged in optimizing the process
to make it economically feasible. This
involves :
1) Reducing the cost of rock frag
mentation. This is the single most
significant cost item in the process.
2) Improving the recovery of in-place
oil. This involves improved blasting
techniques to prepare the shale bed for
retorting, optimized burning techniques
to minimize burn-up and coking of oil in
the retort, and better oil lifting
techniques . Our target is a recovery of
50% or more of the in-place oil. Out of
11 retorts burned to date we have achieved
50% recovery on two retorts, including
the #16, which is our latest and largest.
3) Making effective use of the
combustible retort off gas to generate
electrical power.
4) Meeting all of the environmental
requirements .
229
5) Establishing a market for crude
shale oil at the refineries in Salt Lake
City; Roosevelt, Utah; or at Fruita,
Colorado. In order to make our shale oil
acceptable to these refineries, we are
investigating the feasibility of controlled
blending of shale oil with the normal
refinery feedstock, and upgrading our shale
oil by a hydrotreating process.
Our primary objectives for 1979 are
to:
1) test a number of retorting pro
cedures to optimize oil recovery,
2) burn a retort with full thickness
of the oil shale bed (30 feet) , and
3) blast a full-sized retort (200
feet wide by 200 feet long by 30 feet
thick) .
In 1980, we plan to blast a cluster
of three full-sized retorts. During 1981,we will burn this cluster, and blast a
second three-retort cluster. This second
cluster will be burned during 1981 and the
first half of 1982.
By mid-1982, we expect to have
achieved our overall program objective of
developing and testing the Geokinetics
Horizontal In Situ Retorting Process. Bythis date we should have sufficient data
on hand to evaluate the technical,
environmental, and economic feasibility of
the process. If the results are favorable,we will be in a position to construct a
full scale operating unit producing a
minimum of 2,000 barrels of shale oil
each day.
230
\
\\
\
s'y
an/.////
<r-
Z
UJDO
2<Z-J
o
cr
>
/////
//
//
Q Q
UJ ID
HOH-
w U </)
<z <
CD O CD
CD
H H
CC Q CC
O Z O
l-< V-
Ul UJ
or q:
A
z:
o
<
O
o_1
CD
o
X
(/)
I
<r-
3
UJ
CD
O
CC
UJ
*
CL
<
CO
>-< 5}
tCO (J
UJ
h-Q
CO
UJH
CC
ouj-
LULi- CC
Q
tUJ ^
*-
o
UJ u_
to O
o
o -
UJ
CO
"o _l UJ
m|< cr
wrf to
too"
u_
231
Lan: view
A\C. IMTEcTlOSJ
VajCU-S
0*L PCofc u cTom
WELUS
CoMBUST-|dM
GAS
weu_s
A 'A. !N
^
SEC^
'OS
CoMBUSTloM
v?a^- 'i'-Asr soixfacit^ "Surface, o putft
>W=-
OV/EC^ClV^evj
ou
/
'
i. 0 &
~^=\(>>
7 \' ^^^^^sr- \
? <?
^3>^
^iSo^E 3 ^'-ASJ ASJO SSCT-ovJ 0F A TV?'CA_ Mo2-\Z.ONTAl_ IM <3 lT<j^TOfcT"
232
Retort
Number
Date
Blasted
Thickness
of Shale
Blasted
Overburden
Thickness Width Length
Cross -
Sectional
Area ft2
Tons of
Broken
Shale
Date
Ignited
Barrels
of Oil
Recovered
1 7/75 10 ft. 0 ft. 10 ft. 50 ft. 100 330 9/76 56
2 7/75 3 10 10 30 30 60 3/76 28
3 1/76 10 17 20 40 200 530 7/76 82
4 2/76 10 16 20 40 200 530 2/77 146
S 2/76 11 19 20 81 220 1200 5/77 354
6 Drilled - Not Blasted
7 11/76 10 15 20 50 200 670 -
8 11/76 23 22 20 83 460 2600 - -
9 12/76 22 22 40 83 880 4900 9/77 1007
10 12/76 11 14 20 50 220 730 - -
11 3/77 12 14 20 45 240 720 4/77 272
12 3/7/ 11 31 30 50 330 1100 - -
13 6/77 11 31 30 50 330 1100 - -
14 6/77 12 29 40 70 480 2200 2/78 384
15 7/77 20 31 50 75 1000 5000 5/78 1003
16 8/77 20 41 62 87 1200 7200 8/78 2067
17 5/78 17 26 72 156 1200 13000 - -
18 7/78 17 27 108 156 1800 19000 - -
19 12/78 30 50 126 182 3800 46000 - -
FIGURE 4. SUMMARY OF DATA ON re:"ORTS 1 THROUGH 19 (to 12/31/78)
Days API
Gravity
Pour Nitro-
Point gen
oF%
Sulfur
7.
Engler Distillation D-86
IBP 57. 107. 207. 307. 407. 507. 607. 707. 807.
Residue
907. 7.
1-6 24.4 55 1.88
7-10 25.0 60 1.83
11-15 25.6 66 1.67
16-20 25.8 65 1.55
21-25 26.2 64 1.66
26-30 25.8 69 1.46
31-35 26.4 60'
1.45
36-40 26.7 63 1.42
41-45 26.7 65 1.19
46-51 26.5 64 1.28
0.91 210
0.92 j 302
0.84 212
0.81 I 230
0.78
0.77
0.83
0.80
0.77
0.91
232
223
205
214
238
223
398 436 501 548 594 630 670
384 431 496 552 605 644 689
382 438 490 550 599 640 672
416 452 501 548 589 630 680
407 444 498 546 589 634 685
416 449 502 547 592 641 672
408 444 503 555 598 643 692
406 441 493 543 588 627 670
383 436 486 529 571 616 657
439 466 510 548 589 627 670
732
734
710
705
712
709
728
709
700
709
736
753
743
729
738
741
739
734
737
734
752
750
753
755
755
755
754
748
6
14
13
9
3
6
5
6
6
6
Avg. 25.9 63 1.54 0.83 229 404 444 498 547 591 633 676 715 738 754
FIGURE 5. ANALYSIS OF OIL PRODUCED FROM RETORT #14, SHOWING CHANGE IN CHARACTERISTICS
OF THE OIL DURING RETORTING.
FIVE DAY COMPOSITE SAMPLES
233
at
cat 0)
01
eu c at 01
at
cid
o.
at
c01
r-l
>a.
o
at
g9pa
i
o
01
c
u
9oa
at
catjj
9pa
9pai
CM
1
c<d
at
u
9oai
<M
1
tn
H
a
<d
u
9pa
CO
Isu
aat
ft.i
o
01
u
C01
ft.
at
catAJ
eat
ft-
01
c01
rH
>fi
01 i
grfi
Days N2 2 co2 CO CH4 H2u
Oa
u
Pa
M
M
t
z
i U
HM
O l-l H z i-i w w
1-10 71.1 6.3 15.5 2.2 1.1 2.5 .109 .119 .009 .029 .046 .007 .005 .009..017
.104 .077 .24 .21
11-20 67.4 4.8 18.2 3.5 1.5 3.6 .078 .069 .019 .030 .034 .009 .003 .003 .005.013 .006 .27 .31
21-30 67.9 4.3 17.7 3.6 1.3 4.2 .082 .061 .012 .030 .030 .006 .003 .003 .006 .016 .006 .30 .35
31-40 67.2 3.7 18.1 4.6 1.2 4.3 .068 .048 .012 .032 .028 .006 .004 .002 .013 .019 .008 .30 .38
41-50 67.7 3.7 17.6 4.3 1.1 4.3 .092 .062 .013 .037 .030 .007 .003 .001 .008 .024 .008 .28 .46
51-60 65.2 2.0 18.6 4.9 1.8 5.9 .113 .074 .017 .051 .034 .010 .006 .003 .013 .207 .206 .24 .44
61-70 - - - - - - - - - - - - - - - - - - -
71-80 60.3 4.1 13.3 9.9 1.3 10.5 .084 .071 .017 .054 .042 .010 .005
-.006 .031 .008 .03 .19
81-90 59.1 2.3 17.6 8.5 0.8 10.7 .140 .139 .030 .072 .052 .012 .006 .005 .015 .052 .015 .12 .31
91-100 62.5 1.9 19.3 5.0 1.1 9.2 .250 .189 .033 .084 .065 .015 .010 .003 .017 .067 .020 .05 .24
101-110 62.0 1.5 22.0 3.9 1.3 8.1 .238 .184 .046 .070 .058 .027 .011 .017 .015 .058 .085 .13 .28
111-120 54.5 2.8 24.9 3.8 2.3 10.2 .283 .167 .041 .096 .073 .017 .017 .025 .020 .059 .146 .13 .52
Avg. 64.5 3.4 18.8 4.6 1.3 6.4 .144 .112 .024 .053 .045 .012 .007 .009 .013 .054 .050 .21 .33
FIGURE 6. ANALYSIS OF RETORT #16 OFF GAS, SHOWING CHANGE IN CHARACTERISTICS DURING RETORTING
TEN DAY COMPOSITE SAMPLES
2.0
'
i1
-
^.^
^i* \f
! i
;rogen'
;
i :
1
1.0
j
K! i
N
i ;
Su Lfur |I
!
A*^
0
1i
!1
0-6 7-10 11-15 16-20 21-25 26-30 31-35 36-40 41-45 46-51
ELAPSED DAYS
'FIGURE 7. RETORT #14, SHOWING CHANGE IN NITROGEN AND SULFUR IN OIL DURING RETORTING
234
oH
H
s
u HCO
QW 5W PQ
feco e>
z
X M
gX Q
OV
w
r=
Or-l
fe
oH
a
rJ
M
o
w
g
goH
fe
ozM
HCO
3pa
o
H
PES
oM
fe
goH
zo
CO
HW
aH
O
HOXfe
fe
235
w
oHCO
l->
H
O
O
sfeoH
feWCO
fe
aPoM
fe
fer-l
w
ozH
kJ
Qz
CO
3fefe
o
236
PRODUCT YIELDS
R. N. Heistand
Development Engineering, Inc.
Box A, Anvil Points
Rifle, Colorado 81650
ABSTRACT
The Fischer Assay (FA) , termed "the
standard for the oil shale industry", is
designed to assay the oil potential of geo
logical deposits. It is not designed for
process control nor process evaluation. Yet
traditionally, the calculation "oil yield,
volume percent FischerAssay"
is used.
The product split between oil and gas
in the Fischer Assay does not relate to any
known oil shale retorting process. The
Fischer Assay is a laboratory test; heat is
transferred through the reactor wall; it is
a batch process in which the energy products
are separated by cooling to 0C.
Sincf? both the crude shale oil and
product gas are valuable energy products, a
calculated Product Yield presents a truer
picture of retort production. This Product
Yield compares the retort products (oil and
gas) with the Fischer Assay products (oil
and gas) .
The Product Yield is based on the
products produced from the retorting opera
tions before any allowance for energy
consumed. No credit is given for any
process heat supplied from the raw shale
feed. When this energy (expressed as
MBtu/T) is included, Retort Yield can be
calculated using products plus any heat
supplied by the carbon residue on the shale.
For the Paraho Direct Mode process, the
Retort Yields are generally 110% of assay.
Increases in this number are anticipated as
more of the carbon residue is utilized.
OIL YIELD
The classical approach toward assessing
a given retorting process is to calculate
the oil yield as based on Fischer Assay.
The oil yield, as a volume percent of
Fischer Assay, is simply the oil produced
by the retort divided by the oil produced
by the assay, as shown by the following
equation :
R(1) Oil Yield, % Assay
= 100% x
Where 0 = Oil Produced
R = Retort
A = Assay
This simple expression has several draw
backs. The first is the Fischer Assay
itself (Heistand, 1976) . It is meant to
assay geological deposits, not assess
retorting processes. The American
Society for Testing and Materials (ASTM)
cautions the user that:
"The method neither yields quantities
that necessarily duplicate yields
in experimental or commercial oil
shale processes nor does it yield
products that necessarily duplicate
in physical or chemical nature the
products that may be obtained in
such experimental or commerical
processes."
(ASTM, 1978)
Also, the oil, determined by Fischer
Assay, is obtained by cooling the off
gas to 0C. This cooling cannot be
achieved economically nor practically in
a commercial process. The most important
drawback of the simple expression is that
only the liquid oil is considered. In
the Green River oil shale, oil comprises
only two-thirds of the total organics,
or kerogen, in the raw shale. For many
other shales, this oil fraction is less
yet since they yield larger assaygas-to-
oil ratios.
237
PRODUCT YIELD
A better approach would be to expand
Equation (1) to consider both the oil and
gas yields as shown in the following
equation:
(2) Product Yield, % Assay = 100% x fc + )Oa
gA'
Where g=
energy value of the gas produced.
This expression, Equation (2), has the
advantage that both commercial products of
oil shale retorting, oil and gas, are taken
into consideration. However, this complex
expression has several drawbacks. First,
this expression results in a mixed number -
percent oil plus percent gas, as determined
by Fischer Assay-
since oil produced is
measured in liter/tonne and the gas produced
in kcal/tonne. Secondly, the energy value
of the Fischer Assay gas, kcal/tonne, is not
normally determined.
The energy value of the gas produced
from the retorting process, kcal/tonne, can
be calculated from the gross heating value,
3 3kcal/m , and the quantity, m /tonne. This
can be converted to equivalent oil using
the following equation:
(3) 1.0 Liter of Oil = 9500 kcal.
Although the heating value of the gas
produced by Fischer Assay is normally not
determined in the standard Fischer Assay
procedure, the value can be determined using
the Material Balance Assay. (Goodfellow and
Atwood, 1974)
The heating value of the assay gas has
been determined for Green River shales
having different assay oil contents. (USBM,
1951) The relationship between assay oil,
liter/tonne and gas, kcal/tonne, can be
expressed by a straight line formula using
least squares (see Figure 1) . Combining
this straight line relationship between
assay oil and gas with Equation (3), it is
possible to calculate the assay gas, equiva
lent oil (EO) , from the measured assay oil.
This produces the following expression:
(4) Gas (EO) Liter/Tonne = 0.11 x 0A,Liter/Tonne - 3.3
The good agreement between the calculated
and measured gas data, as indicated by
the r2 term = 0.982, tends to validate
the straight line equation. Thus, with
this straight line equation, one can cal
culate the equivalent oil of the assay
gas from the measured assay oil yield.
.300
GAS
4
-200 kcal/Tonne
-100
OIL
Liter/Tonne
'100 200
i
300
Assay Oil vs. Gas (USBM RI4825)
Figure 1
Using the relationships developed
in Equations (3) and (4) , the product
(oil plus gas) for both the retort and
the Fischer Assay can be expressed as
liquid volumes per unit weight of raw
shale (liter/tonne). Thus, the Product
Yield, expressed in Equation (2) , can be
simplified as follows:
R Gr(5) Product Yield, % Assay = 100% x ^ + ^
9a gA
Where G = equivalent oil of gas produced
(liter/tonne) .
RETORT YIELD
The Product Yield, as shown in Equa
tion (5), compares the retort and Fischer
Assay products. The numerator is the sum
of products out of the retort and the
denominator is the sum of products
measured in the raw shale feed using
Fischer Assay. This concept still does
not give the complete picture of
238
retorting. It needs to be expanded to
include the thermal energy supplied from the
raw shale feed for retorting. When thermal
energy is included, the expression becomes
Retort Yield. The thermal energy (E) is
added to the retort products when it origi
nates from the kerogen in the raw shale in
the same manner as the product gas and oil.
It is subtracted from the retort products
when it is obtained from burning part of the
oil or gas produced in the retort. Thus,
the Retort Yield becomes:
(6) Retort Yield, % of Assay=
100* x0r +
g;+ Er
A + A
Where E = thermal energy to fuel process.
CONCLUSIONS
For the Paraho Direct Mode, a typical
Retort Net Yield is 114 Vol% assay (see
Table 1) . This reflects the 14 liter/tonne
TABLE 1
YIELDS
Indirect Direct
Liter/Tonne Liter/Tonne
Raw Shale Feed
Assay Oil + Gas (EO) 115 123
Paraho Retort
Oil + Gas (EO) 115 126
Thermal Energy (EO)- 14 + 14
Total 101 140
Yields, Volume % Assay
Product 100 102
Retort 88 114
B0 is the equivalent oil, in liter/tonne.
(equivalent oil) of thermal energy supplied
as heat by the raw shale feed to operate the
retorting process. For the Paraho Indirect
Mode, a typical Retort Yield is 88 Vol%
assay (see Table 1) . This reflects the heat
supplied by the external combustion of
product oil or gas. Product yields for both
Direct Mode and Indirect Mode are 100-102
Vol% assay.
Further expansion of the Retort Yield
equation would provide the means for
including other terms such as resource
recovery, materials handling, and energy
conversion. This expanded equation could
then compare in-situ to above-ground
retorting, take into account the convey
ing or transport of shale, include the
energy consumption of other operations
such as mining and crushing, and the
losses caused by energy conversion and
environmental controls. However, for
many processes, these detailed energy
requirements for commercial operations
are not available at this time.
There are both disadvantages and
advantages in using the concepts of
Retort Yield and the more expanded equa
tions. Some additional work is needed.
Some of the disadvantages are:
1) Fischer Assay remains the
benchmark .
2) Additional laboratory work is
needed to quantify the assay
gas.
3) Energy premiums for oil and
gas products are not the same.
However, the advantages far outweigh the
disadvantages. Some of the advantages
are:
1) Both products (oil and gas)
are considered.
2) A numerical assessment of a
particular oil shale retorting
process is possible.
3) The technique can be expanded
to various energy (or economic)
parameters.
4) Results are based on a common
point- the Fischer Assay of
the raw shale feed.
Some additional work which should
be done to assure that the concepts of
Retort Yield are used in valid fashion
include:
1) The equation relating assay
gas quantity to the assay oil
yield should be confirmed.
239
2) The heating value of crude shale
oil should be measured for each
retort tested.
3) The heat and power required for
retorting should be confirmed.
4) The energy requirements for
various aspects of oil shale
operations should be determined.
What has been presented is a basis for
more fully evaluating oil shale retorting
processes. At this time, the concept of
Retort Yield, which takes into account both
products of oil shale retorting (oil plus
gas) , and the energy required to fuel the
retort, best describes the retorting
process.
ACKNOWLEDGEMENT
This work was carried out at the
Department of Energy's Anvil Points Oil
Shale Research Facility located on the
Naval Oil Shale Reserves near Rifle,
Colorado.
REFERENCES
American Society for Testing and
Materials, "Oil and Water from Oil
Shale (Resource Evaluation by the
USBM Fischer Assay Procedure)",D 78T, ASTM, Phila, PA, 1978.
Bureau of Mines, Report of Investiga
tion 4825, III-4b(2), (3), 1951.
Goodfellow, L and M. T. Atwood,
"Fischer Assay of the Oil Shale
Procedures of The Oil Shale Corpor
ation", 7th Oil Shale Symposium,
Colorado School of Mines, Golden,
CO, 1974.
Heistand, R.N. , "The Fischer Assay: A
Standard Method?", Div. of Fuel
Chemistry (ACS) Preprints, 21~(6) ,
40-43 (1976).
240