PROPOSED EXPANSION OF DEVELOPER AND AZOCOLORANTS...

1

FORM-I

For

PROPOSED EXPANSION OF DEVELOPER AND

AZOCOLORANTS DYESIN EXISTING UNIT

of

M/s. BASF INDIA LIMITED (UNIT-II)

PLOT NO. 8001&8001A, PHASE-VI, G.I.D.C.,

ANKLESHWAR, DIST: BHARUCH-393002, GUJARAT

2

APPENDIX I

FORM 1 (I) Basic Information

Sr.

No.

Item Details

1. Name of the Project/s M/s.BASF India Ltd. (Unit-II)

2. S.No. in the Schedule 5 (f)

3. Proposed

capacity/area/length/tonnage to be

handled/command area/lease

area/number of wells to be drilled

Proposed Capacity = 1820 MT/Month

4. New/Expansion/Modernization Expansion

5. Existing capacity/area etc. Existing Capacity (on 100% Basis) = 140

MT/Month

6. Category of project i.e. ‘A’ or ‘B’ ‘A’

7. Does it attract the general condition?

If yes, please specify.

Yes.Located in critically polluted area

(Ankleshwar).

8. Does it attract the specific condition?

If yes, please specify.

N.A.

9. Location Plot No. 8001 & 8001A, Phase-VI, GIDC,

Ankleshwar,Dist:Bharuch-393002, Gujarat

Plot/Survey/Khasra No. Plot. No. 8001& 8001A,

Village GIDC Estate,Ankleshwar

Tehsil Ankleshwar

District Bharuch

State Gujarat

10. Nearest railway station/airport along

with distance in kms.

Nearest Railway Station : Ankleshwar:4kms

Nearest Airport:Surat: 60 kms

11. Nearest Town, city, District

Headquarters along with distance in

kms.

Nearest town:Ankleshwar: 4.5kms, Nearest

District Head quarter:Bharuch: 10 kms

12. Village Panchayats, zillaparishad,

Municipal corporation, Local body

(Complete postal addresses with

telephone nos. to be given)

Notifies Area Authority, Ankleshwar

13. Name of the applicant M/s.BASF India Ltd. (Unit-II)

14. Registered address Plot No. 8001& 8001A, Phase-VI, GIDC

Ankleshwar, Dist: Bharuch, Gujarat

15. Address for correspondence:

Name Mr. P.J.Chandak

Designation (Owner/Partner/CEO) Site Director

Address Plot No. 8001& 8001A, Phase-VI, GIDC Estate,

Ankleshwar, Dist: Bharuch-393002, Gujarat

Pin Code 393002

3

E-Mail [email protected]

Telephone No. 02646 - 617322/ +918980023652

Fax No. 02646 - 238039

16. Details of Alternative Sites examined,

if any location of these sites should be

shown on a topo sheet.

No

17. Interlinked Projects No

18. Whether separate application of

interlinked project has been

submitted?

Not applicable

19. If Yes, date of submission Not applicable

20. If no., reason Not applicable

21. Whether the proposal involves

approval/clearance under: If yes,

details of the same and their status to

be given.

(a) The Forest (Conservation) Act,

1980?

(b) The Wildlife (Protection) Act,

1972?

(c) The C.R.Z Notification, 1991?

Not applicable, as the project is located in

notified industrial estate.

22. Whether there is any Government

order/policy relevant/relating to the

site?

No

23. Forest land involved (hectares) No

24. Whether there is any litigation

pending against the project and/or

land in which the project is propose to

be set up?

(a) Name of the Court

(b) Case No.

(c) Orders/directions of the Court,

if any and its relevance with the

proposed project.

No

4

(II) Activity

1. Construction, operation or decommissioning of the Project involving actions, which

will cause physical changes in the locality (topography, land use, changes in water

bodies, etc.)

Sr.

No.

Information/Checklist confirmation Yes

/No?

Details thereof (with approximate

quantities / rates, wherever possible)

with source of information data

1.1 Permanent or temporary change in land

use, land cover or topography including

increase in intensity of land use (with

respect to local land use plan)

No As the project site is in GIDC notified

area of Ankleshwar and is designated

for industrial purpose.

1.2 Clearance of existing land, vegetation

and buildings?

No --

1.3 Creation of new land uses? No --

1.4 Pre-construction investigations e.g. bore

houses, soil testing?

No --

1.5 Construction works? Yes Approved plan for construction is

attached as Annexure: 1.

1.6 Demolition works? No --

1.7

Temporary sites used for construction

workers or housing of construction

workers?

No --

1.8 Above ground buildings, structures or

Earthworks including linear structures,

cut and fill or excavations

Yes Approved plan for construction is

attached as Annexure: 1.

1.9

Underground works including mining or

tunneling?

No --

1.10 Reclamation works? No --

1.11 Dredging? No --

1.12 Offshore structures? No --

1.13 Production and manufacturing Yes List of Products is attached Annexure: 2

and manufacturing process is attached

as Annexure: 3.

1.14 Facilities for storage of goods or

materials?

Yes Dedicated storage area for storage of

Raw Materials and finished products,

solvents, etc. provided.

1.15

Facilities for treatment or disposal of

solid waste or liquid effluents?

Yes Effluent will be treated in our modified

ETP and the treated effluent will be

discharged to FETP of M/s NCTthrough

GIDC under-ground drainage for further

treatment & final disposal to deep sea

through common effluent disposal

pipeline of M/s. NCT, Ankleshwar.

See Annexure 5 for ETP drawing and

Effluent treatment scheme.

Hazardous/non-hazardous solid waste is

5

referred as Annexure -6.

1.16

Facilities for long term housing of

operational workers?

No --

1.17 New road, rail or sea traffic during

construction or operation?

No --

1.18 New road, rail, air waterborne or other

airports etc?

No --

1.19 Closure or diversion of existing

transport routes or infrastructure

leading to changes in traffic

movements?

No --

1.20 New or diverted transmission lines or

pipelines?

No --

1.21

Impoundment, damming, converting,

realignment or other changes to the

hydrology of watercourses or aquifers?

No --

1.22 Stream crossings? No --

1.23

Abstraction or transfers or the water

form ground or surface waters?

Yes No ground water shall be used. The

requirement of raw water shall be met

through GIDC Water Supply.

1.24

Changes in water bodies or the land

surface affecting drainage or run-off?

No --

1.25

Transport of personnel or materials for

construction, operation or

decommissioning?

Yes Through hired Services

1.26 Long-term dismantling or

decommissioning or restoration works?

No There is no dismantling of any sort. Not

applicable.

1.27 Ongoing activity during

decommissioning which could have an

impact on the environment?

No No Impact on the Environment

1.28

Influx of people to an area in either

temporarily or permanently?

Yes This is a well-developed Industrial Area

and company will give employment to

local people.

1.29 Introduction of alien species? No --

1.30 Loss of native species of genetic

diversity?

No --

1.31 Any other actions? No --

2. Use of Natural resources for construction or operation of the Project (such as land, water,

materials or energy, especially any resources which are non-renewable or in short supply):

Sr.

No

Information/checklist confirmation Yes/

No?

Details there of (with approximate

quantities/rates, wherever possible) with

source of information data

2.1 Land especially undeveloped or

agriculture land (ha)

No --

2.2 Water (expected source & competing Yes Water requirement will meet through the

6

users) unit: KLD GIDC Water Supply. For detail water

balance is refer as Annexure – 4.

2.3 Minerals (MT) No Not applicable

2.4

Construction material -stone,

aggregates, sand / soil (expected

source MT)

Yes Company shall use Sand, stone, Cement

and Structural Steel for Construction as

required.

2.5 Forests and timber (source - MT) No No wood shall be used as construction

material or as a fuel.

2.6

Energy including electricity and fuels

source, competing users Unit: fuel

(MT), energy (MW)

Yes Please refer Annexure -7.

2.7 Any other natural resources (use

appropriates standard units)

No --

3. Use, storage, transport, handling or production of substances or materials, which could be

harmful to human health or the environment or raise concerns about actual or perceived

risks to human health.

Sr.

No.

Information / Checklist confirmation Yes/

No?


quantities / rates wherever possible)


3.1 Use of substances or materials, which

are hazardous (as per MSIHC rules) to

human health or the environment

(flora, fauna, and water supplies)

Yes

Please refer Annexure : 7.

3.2 Changes in occurrence of disease or

affect disease vectors (e.g. insect or

water borne diseases)

No Not applicable as site is located in

Ankleshwar Industrial Area.

3.3 Affect the welfare of people e.g. by

changing living conditions?



3.4

Vulnerable groups of people who could

be affected by the project e.g. hospital

patients, children, the elderly etc.,



3.5 Any other causes No --

4. Production of solid wastes during construction or operation or decommissioning

MT/month)

Sr.

No.

Information/Checklist confirmation Yes/

No?




4.1 Spoil, overburden or mine wastes No --

4.2

Municipal waste (domestic and or

commercial wastes) No --

4.3

Hazardous wastes (as per Hazardous

Waste Management Rules)

Yes Please refer Annexure: 6

4.4 Other industrial process wastes Yes Please refer Annexure: 6

7

4.5 Surplus product No --

4.6

Sewage sludge or other sludge from

effluenttreatment

Yes Please refer Annexure: 6

4.7 Construction or demolition wastes No --

4.8 Redundant machinery or equipment No --

4.9 Contaminated soils or other materials No --

4.10 Agricultural wastes No --

4.11 Other solid wastes Yes Please refer Annexure: 6

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)

Sr.

No.


No?


quantities/rates, wherever possible)


5.1 Emissions from combustion of fossil

fuels From stationary or mobile sources

Yes Details of flue & process gas emission

are attached as Annexure: 7

5.2 Emissions from production processes Yes Reactors shall be connected to

common scrubber system.

Details of Air Pollution Control

measures are attached as Annexure: 7

5.3 Emissions from materials handling

including storage or transport

Yes All liquid raw materials shall be

procured in bulk tankers and shall be

transferred through a closed circuit

pipe lines by pumps.

Solid raw material shall be handled in

closed charging rooms with proper

ventilation and charged through close

pipeline into reactors.

5.4 Emissions from construction activities

including plant and equipment

No Utmost care will be taken during

construction activity and water

sprinklers shall be utilized whenever

necessary.

5.5

Dust or odours from handling of

materials including construction

materials, sewage and waste

No --

5.6 Emissions from incineration of waste No --

5.7 Emissions from burning of waste in

open air (e.g. slash materials,

construction debris)

No --

5.8 Emissions from any other sources Yes Please refer Annexure-7.

8

6. Generation of Noise and Vibration, and Emissions of Light and Heat:

Sr.

No.


No?

Details there of (with approximate

Quantities /rates, wherever possible) With

source of source of information data

6.1

From operation of equipment e.g.

engines, ventilation plant, crushers

Yes Acoustic enclosures provided for DG set.

6.2 From industrial or similar processes Yes All machinery / equipment shall be well

maintained, shall be proper foundation with

anti-vibrating pads wherever applicable and

noise levels within permissible limits.

Acoustic enclosures provided for DG set.

6.3 From construction or demolition No --

6.4 From blasting or piling No --

6.5 From construction or operational traffic No --

6.6 From lighting or cooling systems No --

6.7 From any other sources Yes Acoustic enclosures provided for DG set.

7. Risks of contamination of land or water from releases of pollutants into the ground

or into sewers, surface waters, groundwater, coastal waters or the sea:

Sr.

No


No?


quantities / rates, wherever possible) with


7.1

From handling, storage, use or spillage

of hazardous materials

Yes All the raw material stored separately in

designated storage area and safely. Bund

walls provided around raw materials storage

tanks for containing any liquid spillage.

Other materials stored in bags / drums on

pallets with concrete flooring and no spillage

is likely to occur. Please refer Annexure : 8.

7.2

From discharge of sewage or other

effluents to water or the land

(expected mode and place of

discharge)

Yes Sewage effluent shall be treated in Septic

Tank&Soak Pit and treated along with

industrial effluent and discharge to FETP of

M/s NCT.

7.3

By deposition of pollutants emitted to

air into the land or into water

No The factory is located in Ankleshwar

Industrial Area. The emissions shall conform

to the GPCB / CPCB / NCT norms of

discharge. The treated effluent sent to FETP

of M/s NCT through GIDC drainage system

for further treatment and final disposal into

deep sea through NCT pipe line.

7.4 From any other sources No Not applicable

7.5 Is there a risk of long term build up of

pollution in the environment from

these sources?

No

Full- fledged Environmental Management

System (EMS) is in place. i.e. ETP, Air

Pollution Control systems, Solid Hazardous

Waste Handling and Management as per

9

norms, etc. which eliminates the possibility

of building up of pollution.

8. Risks of accident during construction or operation of the Project, which could affect

human health or the environment:

Sr.

No

Information/Checklist confirmation

Yes/

No?


quantities / rates, wherever possible) with


8.1 From explosions, spillages, fires etc

from storage, handling, use or

production of hazardous substances

Yes The risk assessment will be carried out and

all mitigative measures shall be taken to

avoid accidents.

8.2 From any other causes No Not applicable

8.3 Could the project be affected by natural

disasters causing environmental

damage (e.g. floods, earthquakes,

landslides, cloudburst etc)?

No --

9. Factors which should be considered (such as consequential development) which could

lead to environmental effects or the potential for cumulative impacts with other existing

or planned activities in the locality

Sr.

No.


No?




9.1 Lead to development of supporting

facilities, ancillary development or

development stimulated by the project

which could have impact on the

environment e.g.:

* Supporting infrastructure (roads,

power supply, waste or waste water

treatment, etc.)

• housing development

• extractive industries

• supply industries

• other

Yes Site is located in Ankleshwar Industrial

Area, Ankleshwar, having the entire

required infrastructure.

This industrial zone is having existing road

infrastructure, power supply are to be

utilized.

Local people will be employed and no

housing is required.

Please refer Annexure – 9.

9.2

Lead to after-use of the site, which

could have an impact on the

environment

No

--

9.3 Set a precedent for later developments No Not applicable

9.4 Have cumulative effects due to

proximity to Other existing or planned

projects with similar effects

Yes The ETP of the company designed such

that the treated effluent conforms to the

statutory requirement.

The treated effluent sent to FETP of M/s

NCT through GIDC drainage system for

further treatment and final disposal into

10

deep sea through NCT pipe line.

(III)Environmental Sensitivity

Sr.

No

Information/Checklist confirmation Name /

Identity

Aerial distance (within 25 km).

Proposed Project Location Boundary.

1 Areas protected under international

conventions national or local

legislation for their ecological,

landscape, cultural or other related

value


area of Ankleshwar and expansion is

within existing premises.

2 Areas which are important or sensitive

for Ecological reasons - Wetlands,

watercourses or other water bodies,

coastal zone, biospheres, mountains,

forests




3 Areas used by protected, important or

sensitive species of flora or fauna for

breeding, nesting, foraging, resting,

over wintering, migration




4 Inland, coastal, marine or underground

waters

Yes Amla Khadi =4Kms

River Narmada = 8Kms

5 State, National boundaries No --

6 Routes or facilities used by the public

for to recreation or other tourist,

pilgrim areas.

No Not applicable

7 Defense installations No NIL

8 Densely populated or built-up area Yes Ankleshwar=3 lakh population

9 Areas occupied by sensitive man-made

land community facilities)

No --

10 Areas containing important, high

quality or scarce resources (ground

water resources, surface resources,

forestry, agriculture, fisheries, tourism,

tourism, minerals)

No --

11 Areas already subjected to pollution or

environmental damage. (those where

existing legal environmental standards

are exceeded)

No --

12 Are as susceptible to natural hazard which

could cause the project to present

environmental problems (earthquake s,

subsidence ,landslides, flooding erosion, or

extreme or adverse climatic conditions)

- N.A.

11

IV). Proposed Terms of Reference for EIA studies: For detail please refer Annexure – 10.

I hereby given undertaking that, the data and information given in the application and

enclosures are true to the best of my knowledge and belief and I am aware that if any

part of the data and information submitted is found to be false or misleading at any

stage the project will be rejected and clearance given, if any to the project will be

revoked at our risk and cost.

Date: 18.5.2017 For BASF India Ltd. (Unit-II)

Place: Ankleshwar

P. J. Chandak

(Site Director)

NOTE:

1. The projects involving clearance under Coastal Regulation Zone Notification, 1991 shall be

submitted with the application a C.R.Z. map duly demarcated by one of the authorized

agencies, showing the project activities, w.r.t. C.R.Z. (at the stage of TOR) and the

recommendations of the State Coastal Zone Management Authority (at the stage of EC).

Simultaneous action shall also be taken to obtain the requisite clearance under the

provisions of the C.R.Z. Notification, 1991 for the activities to be located in the CRZ.

2. The projects to be located within 60 km of the National Parks, Sanctuaries, Biosphere

Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit the

map duly authenticated by Chief Wildlife Warden showing these features vis-à-vis the

project location and the recommendations or comments of the Chief Wildlife Warden

thereon (at the stage of EC).

3. All correspondence with the Ministry of Environment & Forests including submission of

application for TOR/Environmental Clearance, subsequent clarifications, as may be

required from time to time, participation in the EAC Meeting on behalf of the project

proponent shall be made by the authorized signatory only. The authorized signatory

should also submit a document in support of his claim of being an authorized signatory

for the specific project.

12

ANNEXURES

1 PLANT LAYOUT

2 LIST OF PRODUCTS WITH PRODUCTION CAPACITY AND RAW MATERIALS

3 BRIEF MANUFACTRING PROCESS, CHEMICAL REACTION AND MASS

BALANCE WITH FLOW DIAGRAM

4 WATER CONSUMPTION AND EFFLUENT GENERATION WITH SEGREGATION

OF EFFLUENT STREAMS

5 DETAILS OF PROPOSED EFFLUENT TREATMENT PLANT

6 DETAILS OF HAZARDOUS SOLID WASTE MANAGEMENT AND DISPOSAL

7 DETAILS OF AIR POLLUTION CONTROL MEASURES

8 DETAILS OF HAZARDOUS CHEMICAL STORAGE FACILITY

9 SOCIO - ECONOMIC IMPACTS

10 PROPOSED TERMS OF REFERENCES

11 GIDC WATER SUPPLY LETTER

12 TREATED EFFLUENT DISCHARGE – NCT MEMBER CERTIFICATE

13 BEIL MEMBERSHIP CERTIFICATE

14 GIDC PLOT ALLOTMENT LETTER

15 COPY OF CONSENT TO OPERATE

13

ANNEXURE: 1

PLANT LAYOUT

14

ANNEXURE: 2

LIST OF PRODUCTS WITH PRODUCTION CAPACITY

Sr.

No.

NAME OF PRODUCTS CAS No. EXISTING

Quantity

(MT/Month)

ADDITIONAL

Quantity

(MT/Month)

TOTAL

AFTER

PROPOSED

EXPANSION

Quantity

(MT/Month)

1. Developer 232938-43-1

140

1678

1818

a. Pergafast 201

b. Pergafast 201 (Dispersion)

2. Azocolorants (Pergasol) paper

dyes

--

a. Pergasol Yellow 3GN-Z Liq 35342-16-6

b. Pergasol Yellow 6VHC-Z Liq 72705-24-9

c. Pergasol Yellow 6VHC

(Direct Yellow 157 Powder) 72705-26-1

d. Pergasol Yellow GA-Z Liq 55067-15-7

e. Pergasol Yellow GA

(Direct Yellow 137 Powder) 55067-12-4

f. Pergasol Yellow G-Z Liq

114565-65-

0

g. Pergasol Yellow RN-Z Liq.

130201-55-

7

h. Pergasol Red 2B-Z Liq 6300-50-1

i. Pergasol Red 2G-Z Liq 28706-25-4

j. Pergasol Red 2GE Crude Liq. 28706-25-4

k. Pergasol Red 2G-E

(Direct Red 239 Powder) 28706-25-4

l. Pergasol Red 3B-Z Liq. 68201-95-6

m. Pergasol Orange 6R-Z Liq 65072-27-7

n. Pergasol Blue 2R-Z Liq 75173-68-1

o. Pergasol Blue R Liq

124605-82-

9

p. Pergasol Yellow S-Z OR

Direct Yellow 11 1325-37-7

q. Pergasol Brown T Liq Mixing &

Blending of

Below CAS

No.

1325-37-7

28706-25-4

124605-82-9

And

65072-27-7

--

r. Pergasol Brown KP Liq --

s. Pergasol Brown BP Liq --

t. Pergasol Brown BZB Liq --

u. Pergasol Brown RT Liq --

v. Pergasol Brown ZB Liq --

w. Pergasol Brown RB --

x. Pergasol Brown RBP Liq. --

3. Microencapsulation Products -- --

a. Lupasol PA 140 35641-59-9

4 Paper Dyes --

15

a Irgalite Violet SCM-L ap 1310-73-2

--

b Irgalite Violet HCR-L ap --

5. R & D Products on Pilot Plant

Scale --

-- 2 2

TOTAL 140 1680 1820

16

LIST OF RAW MATERIALS

Sr. No. Name of Raw material Quantity (MT/Month)

Existing Additional Total

Pergafast 201

1 Toluene 88.02 156.98 245.00

2 N,N-Dimethylacetamide 2.09 3.91 6.00

3 3-Amino Phenol 23.48 42.52 66.00

4 Para-Toluene Sulfonyl Isocyanate 45.13 82.87 128.00

5 Sodium Hydroxide 70.96 126.14 197.10

6 Para-Toluene Sulfo Chloride 45.60 82.40 128.00

7 Formic Acid 19.57 35.43 55.00

8 Methanol 279.13 496.87 776.00

Pergafast 201 Dispersion

1 Gohseran 1.80 0.00 1.80

2 Xenthan Gum 0.18 0.00 0.18

3 Thor MBS 0.54 0.00 0.54

4 Water 12.03 0.00 12.03

PERGASOL YELLOW 3GN-Z LIQ

1 2(4AmPHENYL)-6MetBenzThiazol 6.28 2.61 8.89


3 Hydrochloric Acid 43.21 17.95 61.16

4 Sodium Nitrite 3.87 1.61 5.48

5 Sulfamic Acid 0.28 0.12 0.40

6 Barbituric acid 2.48 1.03 3.51

7 Acticid MBS /PreventolBm 5 0.12 0.05 0.18

8 Lithium Hydroxide 0.99 0.41 1.40

9 Triethanol Amine 2.84 1.18 4.01

10 Hyflow Supercel 0.15 0.06 0.21

PERGASOL YELLOW 6VHC-Z LIQ






6 3-(Acetoacetamide)-4-methoxytoluol-

6sulphonic acid, ammonium salt

3.03 0.63 3.65

7 Ammonia 1.21 0.25 1.46

8 Hydrogen Peroxide 3.49 0.72 4.22

9 Ferrous Sulfate 7H2O 2.10 0.43 2.53


11 Phenoxy propanol 0.30 0.06 0.37

12 E-Caprolactum 2.74 0.57 3.30

PERGASOL YELLOW GA-Z LIQUID



17





7 2-Cynimino Barbituric acid 0.89 0.31 1.20

8 Triethanol Amine 1.48 0.52 1.99


PERGASOL YELLOW GA LIQUID (Direct Yellow 137

Powder)

1 Pergasol Yellow GA Crude Solution 105.0 105.0 210.0

2 Dedusting Oil 0.173 0.173 0.346

3 Sodium Sulphate 2.77 2.77 5.54

PERGASOL YELLOW G-Z LIQ.






6 2,4,6-Triamino-pyrimidin 0.72 0.23 0.95

7 Diethanolamine 0.26 0.08 0.35

8 3-Eethylamino Propylamine 0.80 0.26 1.06

9 N-Methyl ethanolamine 1.40 0.45 1.85


PERGASOL YELLOW RN-Z LIQ.

1 Aniline -3-sulfosaeure (Metanilic Acid) 1.80 0.63 2.43




5 3-Acetamidoanilinium chloride 2.13 0.75 2.88


7 Sodium bi-carbonate 0.33 0.12 0.45

8 Sodium Chloride 7.52 2.63 10.15

9 Surfynol 104 PG-50 0.00 0.00 0.01

10 Cyanuric Chloride 0.73 0.25 0.98

11 Morpholine Bulk 0.53 0.19 0.72




15 E-Caprolactum 1.82 0.64 2.45


PERGASOL RED 2B-Z LIQUID

1 4-Amino Azobenzol-4-sulfonic acid 1.54 0.54 2.09




5 Surfynol 104 PG-50 0.00 0.00 0.00

18


7 2-Amino-5- Naphthol-7- Sulfonic Acid 1.43 0.50 1.92





PERGASOL RED 2G-Z LIQ.

1 2-Naphthalamine-6-Sulfonic Acid 5.52 1.43 6.95



4 Surfynol 104 PG-50 0.01 0.00 0.01


6 J-Acid-Urea Disodium Salt 6.90 1.79 8.69







13 Glutaraldehyde 0.14 0.04 0.17

PERGASOL RED 2 GE CRUDE LIQUID

1 2-Naphthalamine-6-Sulf. Acid 5.517 1.43 6.95



4 Surfynol 104E 0.006 0.00 0.01

5 Sulfamic Acid 0.431 0.11 0.54

6 J- Acid Urea 6.897 1.79 8.69



9 Sodium Bicarbonate 1.034 0.27 1.30

PERGASOL RED 3B-Z LIQ. NEW

1 4-Aminoazobenzol-4-Sulfonic Acid 0.95 0.52 1.47




5 Surfynol 104 PG-50 0.02 0.01 0.03


7 2-Amino-5- Naphthol-7- Sulfonic Acid 1.00 0.55 1.55

8 Sodium Chloride 6.58 3.59 10.17

9 Cyanuric Chloride 0.65 0.36 1.01

10 Mono Ethanolamine 0.52 0.29 0.81




14 Benzyl alcohol 0.29 0.16 0.45


19

PERGASOL ORANGE 6R-Z LIQUID

1 2-Aminotoluol-5-sulphonic acid 1.25 0.21 1.46

2 4-Amino benzoic acid 0.88 0.15 1.03




6 J-Acid-Urea Disodium Salt 3.91 0.67 4.58







13 Glutaraldehyde 0.06 0.01 0.07

14 Am Phenyl-Me-B-7-Acid 0.11 0.02 0.13

PERGASOL BLUE 2R-Z LIQ.

1 2-amino -5nitroanisole 2.28 0.60 2.88





6 1 - Naphthol - 3,6 Disulfonic Acid 7.63 2.00 9.63

7 Glucose 1 Aq Ph 1.82 0.48 2.30

8 Surfynol 104 PG-50 0.03 0.01 0.04

9 Ammonia 3.96 1.04 5.00

10 Copper Sulphate 2.77 0.73 3.50




14 CAD 17 Sodium AlumiatePolysulphate 2.38 0.62 3.00

15 Acticid MBS /Preventol 5 0.09 0.02 0.11

PERGASOL BLUE R LIQ.

1 4,4-Diamino-2-Methyl Azobenzol 0.40 0.30 0.69

2 Surfynol 104E 0.01 0.01 0.02




6 1- amino, 8-naphthol, 3,6-disulfonic acid 1.29 0.97 2.26

7 Lithium Hydroxide 0.47 0.35 0.81





12 T.G. Urea 0.66 0.50 1.16

PERGASOL YELLOW S-Z LIQUID

1 2-Methyl-5-nitrobenzenesulfonic acid 0.000 5.232 5.232

20



4 Sodium Nitrite 0.000 3.076 3.076

5 Sulfamic Acid 0.000 0.226 0.226

6 o-Toluenesulfnic acid 0.000 2.963 2.963

7 Triethanolamine 0.000 4.902 4.902

8 Acticide MBS/ Preventol BM 5 0.000 0.143 0.143

9 2-Methyl-5-nitrobenzenesulfonic acid 0.000 5.232 5.232

PERGASOL BROWN T LIQUID

1 Yellow S-Z or Yellow Direct 11 0.000 59.119 59.119

2 Pergasol Red 2G-Z 0.000 16.891 16.891

3 Pergasol Blue R-Z 0.000 6.756 6.756

4 Pergasol Orange 6R-Z 0.000 1.689 1.689

5 DM Water 0.000 0.422 0.422


PERGASOL BROWN KP LIQUID


2 Pergasol Red 2G-Z 0.000 14.357 14.357

3 Pergasol Blue R-Z 0.000 1.689 1.689


5 DM Water 0.000 0.422 0.422


PERGASOL BROWN BP LIQUID


2 Pergasol Red 2G-Z 0.000 21.114 21.114

3 Pergasol Blue R-Z 0.000 6.756 6.756


5 DM Water 0.000 0.422 0.422


PERGASOL BROWN BZB LIQUID


2 Pergasol Red 2G-Z 0.000 25.337 25.337

3 Pergasol Blue R-Z 0.000 6.756 6.756


5 DM Water 0.000 0.422 0.422


PERGASOL BROWN RT LIQUID


2 Pergasol Red 2G-Z 0.000 21.114 21.114

3 Pergasol Blue R-Z 0.000 4.223 4.223


5 DM Water 0.000 0.422 0.422


PERGASOL BROWN ZB LIQUID


2 Pergasol Red 2G-Z 0.000 25.337 25.337

21

3 Pergasol Blue R-Z 0.000 3.378 3.378


5 DM Water 0.000 0.422 0.422


PERGASOL BROWN RB LIQUID


2 Pergasol Red 2G-Z 0.000 23.647 23.647

3 Pergasol Blue R-Z 0.000 0.845 0.845


5 DM Water 0.000 0.422 0.422


PERGASOL BROWN RBP LIQUID


2 Pergasol Red 2G-Z 0.000 23.647 23.647

3 Pergasol Blue R-Z 0.000 12.668 12.668


5 DM Water 0.000 0.422 0.422


Microencapsulation Product (Lupasol)

1 AMPS 0.000 5.38 5.38

2 MEHQ 0.000 0.01 0.01


4 Brueggolite L 40 0.000 0.05 0.05

5 sodium-persulfate solution 0.000 0.17 0.17

Paper Dyes (Irgalite SCM / HCR)

1 Pigment Violet 3 Dispersion 0.000 42.64 42.64

2 Acticid MBS 0.000 0.06 0.06

Irgalite HCR-L ap

1 Pigment Violet 44 Dispersion 0.000 13.95 13.95

2 Acticide MV 0.000 0.02 0.02

Other Chemicals

1 Optisul HIS LQ 1 1 2.00

2 Citric Acid 1 1 2.00

3 P-3Ultracil 1 1 2.00

22

ANNEXURE: 3

BRIEF MANUFACTRING PROCESS, CHEMICAL REACTION AND MASS BALANCE WITH FLOW

DIAGRAM

DESCRIPTION OF MANUFACTURING PROCESS (EXISTING)

1) DEVELOPER PERGAFAST 201

A solution of aminophenol in a mixture of toluene and dimethylacetamide is reacted with para

tolueneisocyanate at 40o-50

oC to form the intermediate. The intermediate is then isolated into an

aqueous phase as the sodium salt and the toluene layer is removed. The intermediate is then

reacted with para tolunesulphonylchloride in the presence of aqueous sodium hydroxide. After

completion of reaction, distillation is carried out to remove any traces of residual solvent. The

product is then acidified.

The product is washed with Methanol and dried. This product is Pergafast – 201 packed in bag.

Chemical Reaction:

NaOH + + +

3-Amino Phenol p-Toluenesulphonylisocynate p-Toluenesulphonylchloride

Pergafast 201

23

MATERIAL BALANCE FOR PERGAFAST-201

24

2) PERGAFAST 201 (Dispersion)

A solution of aminophenol in a mixture of toluene and dimethylacetamide is reacted with p-

tolueneisocyanate at 40o-50

oC to form the intermediate. The intermediate is then isolated into an

aqueous phase as the sodium salt and the toluene layer is removed. The intermediate is then

reacted with p-toluenesulphonylchloride in the presence of aqueous sodium hydroxide. After

completion of reaction, distillation is carried out to remove any traces of residual solvent. The

product is acidified with formic acid for isolating the product. The isolated mass is wash with solvent

mixture of acetone and methanol.

Chemical Reaction:

• FORMULATION OF PERGAFAST 201 DISPERSION.

The product (crude Pergafast 201) is dispersed with additives and wet milled for final packing

MATERIAL BALANCE FOR PERGAFAST 201 DISPERSION

NaOH + + +

3-Amino Phenol p-Toluenesulphonylisocynate p-Toluenesulphonylchloride

Pergafast 201

DESCRIPTION OF MANUFACTURING PROCESS

3) Azocolorants (Pergasol Paper Dyes)

Pergasol Red 2G-Z

The processes is aqueous base reaction principle. The Amin solution is gets prepared in water and

then diazotization this solution takes place with sodium nitrite at lower temperature. Temperature

controlled via direct ICE charging to the reactor. Then in the diazotization mass Coupler compound

solution charged for coupling reaction. The desired pH is measured online and adju

sodium hydroxide or hydrochloric acid. Once there is diazotization reaction completes, it gets

transfer for conditioning after heating where work up done and then the whole mass taken to Nano

filtration for desalting, concentration, washing

formulated and packed via filling station.

Chemical Reaction:

DESCRIPTION OF MANUFACTURING PROCESS

Azocolorants (Pergasol Paper Dyes)


solution takes place with sodium nitrite at lower temperature. Temperature


solution charged for coupling reaction. The desired pH is measured online and adju



filtration for desalting, concentration, washing and impurity removal. The final liquid product is then


25


solution takes place with sodium nitrite at lower temperature. Temperature


solution charged for coupling reaction. The desired pH is measured online and adjusted by either



and impurity removal. The final liquid product is then

26

Material Balance for Pergasol Red 2G-Z

Description Qty. in MT Description Qty. in MT

DM water 4.920 Stage 1

2-Naphthalamine-6-Sulfonic Acid 0.960 Amine Slurry

Hydrochloric Acid 0.660 Stage 2

Sodium Nitrite 0.813

Ice 2.160 Diazotization

Surfynol 104 PG-50 0.001

Sulfamic Acid 0.075

DM water 4.080


J-Acid-Urea Disodium Salt 1.200 Coupling Slurry

Ice 1.800 Stage 4

Sodium Hydroxide 0.866

DM water 0.120 Coupling reaction & Clarrification

Hyflow Supercel 0.015 Hyflo waste 0.019

Sodium bi-carbonate 0.180

Process water 5.000

DM Water washing 44.000 Stage 5

Hydrogen Peroxide 1.250 Waste Water 59.400

Ferrous Sulfate 7H2O 0.750 Nano-filtration

Acticid MBS/ Preventol Bm 5 0.035 Stage 6

DM water 1.790

Glutaraldehyde 0.024 Formulation & Packing

Pergasol Red 2G-Z LIQ 17.400

Total input in MT 76.819 Total Output in MT 76.819

InputReaction / Operation / Equipment

Output

4) Pergasol Red 2B-Z

The process is aqueous base reaction principle. The Amin solution is gets prepared in water and then

diazotization this solution takes place with sodium nitrite at lower temperature. Temperature

controlled via direct ICE charging to the reactor. Then in the diazotizatio



transfer for conditioning after heating



Chemical Reaction:

aqueous base reaction principle. The Amin solution is gets prepared in water and then








27

aqueous base reaction principle. The Amin solution is gets prepared in water and then


n mass Coupler compound



where work up done and then the whole mass taken to Nano


28

Material Balance for Pergasol Red 2B-Z



4-Amino Azobenzol-4-sulfonic acid 0.780 Amine Slurry






Sulfamic Acid 0.023

DM water 0.480

Stage 3

DM water 5.880 Coupling Slurry

2-Amino-5- Naphthol-7- Sulfonic Acid 0.720

Ice 4.500 Stage 4


DM water 0.140

Hyflow Supercel 0.018 Coupling reaction & Clarrification

Hydrochloric Acid 0.042 Hyflo waste 0.024

Process water 5.000


Hydrogen Peroxide 2.050 Waste Water 63.400



DM water 0.900 Formulation & Packing

Pergasol Red 2B-Z LIQ 10.100



Output

29

5)Pergasol Orange 6R-Z









Chemical Reaction: CH

3

NH2

HO3S

NH2

COOH

+

N N

O

OH OH

HO3S

H H

NN N N

CH3

HO3S

OH

O

SO3H

N N

O

OH OH

SO3HHO

3S

H H

+

N,N'-Bis-(I-Säure)-Harnstoff

1.) HCl2.) NaNO2

C35

H26

N6S

3O

14

C35

H22

N6Na

4S

3O

14

NaOH, H2O

Pergasol Orange 6R

M= 850,8 g.mol -1, freie Säure

M= 938,7 g.mol -1, Na-Salt

pH= 7,0-7,5

4-Amino-benzoesäure

2-Aminotoluol-5-sulfosäure

T<15°C

30

Material Balance for Pergasol Orange 6R-Z



2-Aminotoluol-5-sulphonic acid 0.384 Amine Slurry

4-Amino benzoic acid 0.270




Sulfamic Acid 0.071

DM water 0.480


J-Acid-Urea Disodium Salt 1.200 Coupling Slurry

Ice 3.000 Stage 4

Hydrochloric Acid 0.060



Hyflow Supercel 0.025

Sodium bi-carbonate 0.360 Hyflo waste 0.026

Process water 5.000


Hydrogen Peroxide 1.290 Nano-filtration Waste Water 57.500

Ferrous Sulfate 7H2O 0.774


DM water 1.180

Glutaraldehyde 0.018 Formulation & Packing

Am Phenyl-Me0B-7-Acid 0.033

Pergasol Orange 6R-Z LIQ 10.750



Output

31

6) Pergasol Blue 2R-Z




solution charged for coupling reaction. The desired pH is measured online and adjusted by sodium

hydroxide. The coupling reaction mass is precipitated out with hydrochloric acid & ultra-filtered and

processed further to produce by doing Copperization reaction with copper sulfate and Ammonia.

After Copperization, whole solution is clarified for Nano filtration to concentrate the solution &

reduce the salt content & finally Pergasol Blue 2R-Z is formulated & packed.

Chemical Reaction:

NH2

O

N+O

O OH

SO3HHO

3S

ClH

NaNO2

NN

OH

SO3H

HO3S

N+

O

O

O

NN

OH

SO3H

HO3S

O

NN O

NN

OH

HO3S SO

3H

NN

O

SO3H

HO3S

O

NN O

NN

O

HO3S SO

3H

Cu

NH3

CuSO4. OH

2

Cu

2-amino-5.nitroanisol

1-naphtol-3,6-disulfosäure

NaOHGlucose

(UF)

5

PERGASOL BLAU 2R Roh Flüssig

32

Material Balance for Pergasol Blue 2R-Z


DM Water 4.485 Stage 1

2-amino -5nitroanisole 0.575 Amine Slurry





Sulfamic Acid 0.060

DM Water 0.230


1 - Naphthol - 3,6 Disulfonic Acid 1.926 Coupling Slurry

Sodium Hydroxide 0.690 Stage 4

DM water 1.265

Glucose 1 Aq Ph 0.460

Sodium Hydroxide 1.696 Coupling reaction, Reduction


Process water 10.000


Ultra-filtration Waste Water 57.600


Ammonia 1.000

Copper Sulphate 0.700

Hydrochloric Acid 0.667 Copperization



Hydrogen Peroxide 1.272


CAD 17 Sodium Alumiate Polysulphate 0.600 Waste Water 47.900


Acticid MBS/ Preventol Bm 5 0.022 Formulation & Packing

Pergasol Blue 2R-Z LIQ 10.600



Output

33

7) Pergasol Blue R




solution charged for coupling reaction. The desired pH is measured online and adjusted by Lithium

Hydroxide. Once the reaction completes, it gets transfer for conditioning after heating where work

up done and then the whole mass taken to Nano filtration for desalting, concentration, washing and

impurity removal. The final liquid product is then formulated and packed via filling station.

Chemical Reaction:

N

N

NH2

NH2

ClH

NaNO2

N

N

N2

N2

NH2

OH

HO3S SO

3H

N

N

N

N

N

N

OH

NH2

OH

NH2

HO3S

SO3H

SO3H

HO3S

C33

H26

S4O

14N

8

LiOH

DAMAB= 4,4'-Diamino-2-methyl-azobenzol

0°C-3°C

+

+

Freie säure M= 886,85g.mol-1

34

Material Balance for Pergasol Blue R



4,4-Diamino-2-Methyl Azobenzol 0.396 Amine Slurry





Sulfamic Acid 0.027

DM water 0.480


1- amino, 8-naphthol, 3,6-disulfonic acid 1.290 Coupling Slurry

Ice 6.750 Stage 4

Surfynol 0.007

Lithium Hydroxide 0.120

Lithium Hydroxide 2.760 Coupling reaction & Clarrification

Hyflow Supercel 0.023

DM water 0.120 Hyflo waste 0.037

Ice 6.000

Process water 5.000





DM water 1.050

T.G. Urea 0.660 Formulation & Packing

Pergasol Blue R LIQ 12.000



Output

35

8) Pergasol Yellow 3GN-Z



controlled via direct ICE charging to the reactor. The Coupler solution is gets prepared in water and

then Coupler compound solution charged in the diazotization mass for coupling reaction. The

desired pH is measured online and adjusted by Sodium Hydroxide. Once the reaction completes, the

solution is crystalized in the form of slurry by acidification with Hydrochloric Acid at higher

temperature and then the whole mass taken to Ultra filtration for desalting, concentration, washing

and impurity removal The concentrate slurry is dissolved in liquid form with dissolving process. This

liquid solution clarified. The final liquid product is then formulated and packed via filling station.

Chemical Reaction:

S

N

H3C

S O3

H

N H2

S

N

H3

C

S O3

H

N+

N

N

N

O

O

O

H

H

S

N

H3

C

N N

S O3

N a

N

N

OH

O H

OH

S

N

H3

C

N N

N

N

OH

O H

OHS O

3H

S

N

H3C

N N

N

N

OH

O H

OHS O

3NH C H

2

CH

2C H2

C H2

O HH

C H2

O H

C H2

O H

N a N O 2

H C l

1 5 -2 0 °C

L ö s e n p H 7 ,5 - 86 0 °C5 0 °C ,

p H 3 ,3 , 3 0 °C

8 5 °C , H C l, p H 0 ,5

B ild u n g S ä u re fo rm

L iO H

T r ie th a n o la m in

C l

L i+ /+-

-

p H 8

(b z w .K e to fo rm )

36

Material Balance for Pergasol Yellow 3GN-Z



2(4AmPHENYL)-6MetBenzThiazol 1.063 Amine Slurry





Sulfamic Acid 0.048

DM Water 0.460


Barbituric acid 0.420 Coupling Slurry



Ice 2.500

Hydrochloric Acid 5.768 Coupling reaction & Crystallization

DM Water 0.500

Process water 5.000


Hydrochloric Acid 0.520 Ultra-filtration Waste Water 117.500

Lithium Hydroxide 0.936 Stage 6

Triethanol Amine 0.480

2(4AmPHENYL)-6MetBenzThiazol 0.030 Dissolving Dye & Clarrification




Pergasol Yellow 3GN-Z LIQ 11.000



Output

37

9) Pergasol Yellow GA-Z







temperature and then the whole mass taken to Ultra filtration for desalting, concentration, washing

and impurity removal The concentrate slurry is dissolved in liquid form with dissolving process. This

liquid solution clarified. The final liquid product is then formulated and packed via filling station.

Chemical Reaction:

S

N

H3

C

S O3

H

N H2

S

N

H3

C

S O3

H

N+

N

S

N

H3

C

S O3

N a

N N

N

N

N H C N

OH

OH

N

N

N H C N

OH

OH

S

N

H3

C

S O3

H

N N

N

N

N H C N

OH

OH

S

N

H3

C

S O3

-

N N

N

N

N H C N

OH

OH

N

O H

O H

OH

NH

+

O H

O H

OH

N a N O 2

H C l2 5 - 3 0 ° C

8 5 ° C , 1 0 % H C lU m w a n d lu n g - - > U F

F o r m u l ie r u n g

38

Material Balance for Pergasol Yellow GA-Z








Sulfamic Acid 0.046

DM Water 0.460


2-Cynimino Barbituric acid 0.602 Coupling Slurry



DM water 0.115


Process water 5.000




Triethanol Amine 0.996

Hyflow Supercel 0.025 Dissolving Dye & Clarrification Hyflo waste 0.025



Pergasol Yellow GA-Z LIQ 13.500



Output

10) Pergasol Yellow G-Z



controlled via direct ICE charging to the reactor. The Coup


desired pH is measured online and adjusted by Sodium Hydroxide. Once the reaction completes,


temperature and and then the whole mass taken to Ultra filtration for desalting, concentration,

washing and impurity removal The concentrate slurry is dissolved in liquid form with di

process. This liquid solution clarified

filling station.

Chemical Reaction:





desired pH is measured online and adjusted by Sodium Hydroxide. Once the reaction completes,

in the form of slurry by acidification with Hydrochloric Acid at higher

and then the whole mass taken to Ultra filtration for desalting, concentration,

The concentrate slurry is dissolved in liquid form with di

process. This liquid solution clarified. The final liquid product is then formulated and packed via

39



ler solution is gets prepared in water and



in the form of slurry by acidification with Hydrochloric Acid at higher

and then the whole mass taken to Ultra filtration for desalting, concentration,

The concentrate slurry is dissolved in liquid form with dissolving

. The final liquid product is then formulated and packed via

40

Material Balance for Pergasol Yellow G-Z








Sulfamic Acid 0.050

DM Water 0.480


2,4,6-Triamino-pyrimidin 0.360 Coupling Slurry



DM water 0.120


Process water 5.000




Diethanolamine 0.131

3- Ethylamino Propylamine 0.400 Dissolving Dye & Clarrification

N-Methylethanolamine 0.700



Formulation & Packing

Pergasol Yellow G-Z LIQ 12.500



Output

41

11) Pergasol Yellow 6VHC-Z





desired pH is measured online and adjusted by Ammonia liquid solution. Once the reaction

completes, the solution is clarified and then the whole mass taken to Nano filtration for desalting,

concentration, washing and impurity removal. The final liquid product is then formulated and

packed via filling station.

Chemical Reaction:

S

N

H3C

SO3H

NH2

S

N

H3C

SO3H

N+

N

S

N

H3C

SO3-

N N

CH3

O

NH

O

O

CH3

SO3-

CH3

O

CH3

NH

O

OCH3

SOO

O

H3C

NH4+

NaNO2

HClT<25 °C

NH3 25%

pH 5,0-5,525-30°C

als NH4+ / Na+-Mischsalz vorliegend

42

Material Balance for Pergasol Yellow 6VHC-Z








Sulfamic Acid 0.058

DM water 0.480


3-(Acetoacetamide)-4-methoxytoluol-

6sulphonic acid, ammonium salt 1.200 Coupling Slurry

Ice 2.400 Stage 4

Ammonia 0.480


Process water 5.000





DM water 1.520

Phenoxypropanol 0.120

E-Caprolactum 1.085 Formulation & Packing

Pergasol Yellow 6VHC-Z LIQ 11.500



Output

43

12) Pergasol Yellow RN-Z





desired pH is measured online and adjusted by Sodium Hydroxide. The reaction mass is precipitated

with Sodium Chloride. This precipitated slurry is filtered and it forms wet cake. The wet cake is

charged in water to prepare solution. Then the solution is charged to suspension Cyanuric Chloride

for first second condensation reaction at low temperature maintaining pH with Sodium Hydroxide

and third condensation reaction is done with Morpholine at high temperature and finally reaction

mass is cooled to lower temperature. The mass is clarified and then the whole mass taken to Nano



Chemical Reaction:

NN

N C l

C l

C l

NH

O

N a O H p H = 5 ,0 -6 ,0T = 0 -5 ° CN a C l, T = 6 0 ° C , p H = 6 ,0 -6 ,2

C3 5

H3 4

N1 2

O9

S2

N

N

NH

N H2

H O3S

O

N

N NH

NH

C l

NNN

N HO

NN

N HO

S O3H S O

3H

N

N NH

NH

N

NNN

N HO

NN

N HO

OS O

3HS O

3H

C3 5

H3 2

N1 2

N a2

O9

S2

T = 8 7 ° C , p H = 8 ,5 -8 ,6

M = 8 3 0 ,8 5 g .m o l- 1 ( F re ie S ä u re )

M = 8 7 4 ,8 2 g .m o l- 1 (N a - S a lz )

44

Material Balance for Pergasol Yellow RN-Z



Aniline -3-sulfosaeure (Metanilic Acid) 0.743 Amine Slurry




Sulfamic Acid 0.550

DM water 0.220


3-Acetamidoanilinium chloride 0.880 Coupling Slurry


DM water 0.410

Sodium bi-carbonate 0.138

Ice 2.750 Coupling reaction, Precipitation, Filtration

Pure Salt 3.100 Waste Water 34.900

DM water 15.000

Process water 5.000


Surfynol 104 PG-50 0.001 Slurry Preparation


Ice 7.000


Cyanuric Chloride 0.300


Morpholine Bulk 0.220 Condensation & Clarrification




Hydrogen Peroxide 0.889 Nano-filtration

Ferrous Sulfate 7H2O 0.534 Waste Water 64.800


E-Caprolactum 0.750


Pergasol Yellow RN-Z LIQ 8.250



Output

45

13) Pergasol Red 3B-Z





desired pH is measured online and adjusted by Sodium Hydroxide. The reaction mass is precipitated

with Sodium Chloride. This precipitated slurry is filtered and it forms wet cake. The wet cake is

charged in water to prepare solution. Then the solution is charged to suspension Cyanuric Chloride

for first second condensation reaction at low temperature maintaining pH with Sodium Hydroxide

and third condensation reaction is done with Mono Ethanolamine at high temperature and finally

reaction mass is cooled to lower temperature. The mass is clarified and then the whole mass taken

to Nano filtration for desalting, concentration, washing and impurity removal. The final liquid

product is then formulated and packed via filling station.

Chemical Reaction:

46

Material Balance for Pergasol Red 3B-Z



4-Aminoazobenzol-4-Sulfonic Acid 0.522 Amine Slurry






Sulfamic Acid 0.010

DM water 0.321


2-Amino-5- Naphthol-7- Sulfonic Acid 0.552 Coupling Slurry

Ice 3.600 Stage 4


DM water 0.240

Sodium Chloride 3.618 Coupling reaction, Precipitation, Filtration

Hydrochloric Acid 0.024 Waste Water 23.761

Process water 10.000

Surfynol 104 PG-50 0.001 Stage 5

Sodium Hydroxide 0.040 Slurry Preparation

DM water 9.049


Ice 10.200


Pure Salt 0.360


Mono Ethanolamine 0.288 Condensation & Clarrification




Hydrogen Peroxide 0.889 Nano-filtration

Ferrous Sulfate 7H2O 0.534 Waste Water 68.900


Benzyl alcohol 0.159


Pergasol Red 3B-Z LIQ 6.050



Output

47

14) Process Description of Lupasol

[1-Propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propenyl) amino]-, monosodium salt,homopolymer]

2-Acrylamido-2-methylpropane sulfonic acid (AMPS) is charged in to the reactor with water. The

mass is stirred and then other raw material like Caustic soda. Heat the mass and add Sodium

Persulphate. The product is then cooled after addition of water. The product is stored in

intermediate tank from where it is packed.

Chemical Reaction

AMPS �PolyAMPS

Redox initiator

�

Material Balance for Lupasol


AMPS 1.793 Stage 1

MEHQ 0.004 Polymerization


Brueggolite L 40 0.015 Process Reactor Losses - VOC's 0.008

DM Water 6.798

sodium-persulfate solution 0.058

Intermediate Storage Storage

Storage Tank

Packing Material Packing Lupasol 10.000



Output

48

15) Pergasol Red 2G-E Crude Sol






transfer for conditioning after heating where work up done and then the whole mass clarified. The

final liquid product is packed via filling station.

Chemical Reaction:

49

Material Balance for Pergasol Red 2G-E Crude Sol



2-Naphthalamine-6-Sulf. Acid 0.960 Amine Slurry





Sulfamic Acid 0.075

DM water 4.080


J- Acid Urea 1.200 Coupling Slurry

Ice 1.800 Stage 4




Sodium Bicarbonate 0.180

Process water 1.050

Pergasol Red 2G-E Crude Sol 25.000



Output

50

17) Process Description of Irgalite SCM-L ap

The manufacturing process involves batch wise mixing of dispersed pigment Violet 3 Dispersion and

ingredients like DM water / Distilled water, Acticide MBS in different proportion as per the batch

requirement.

After proper mixing, batch quality to be check & After QA approval, finish product is packed via filling

station.

Material Balance for Irgalite SCM-L ap

18) Process Description of Irgalite HCR-L ap

The manufacturing process involves batch wise mixing of dispersed pigment Violet 44 Dispersion and

ingredients like DM water / Distilled water, Acticide MV in different proportion as per the batch

requirement.

After proper mixing, batch quality to be check & After QA approval, finish product is packed via filling

station.

Material Balance for Irgalite HCR-L ap



Pigment Violet 3 Dispersion 30.100 Mixing & Clarrification

Acticid MBS 0.042

Packing & Storage Irgalite SCM-L ap 35.002



Output



Pigment Violet 44 Dispersion 13.950 Mixing & Clarrification

Acticide MV 0.020

Packing & Storage Irgalite HCR-L ap 15.000



Output

51

ANNEXURE: 4

WATER CONSUMPTION AND EFFLUENT GENERATION

WATER CONSUMPTION

Water consumption

QUANTITY (KL/DAY)

EXISTING ADDITIONAL TOTAL

Domestic 30 20 50

Gardening -- 4 4

Industrial Process 180 92 272

Boiler 60 39 99

Cooling& Chilling 30 20 50

Washing --- 25 25

Total (Industrial) 270 177 450

Total Water Consumption KL/day 300 201 500

WASTEWATER GENERATION

Wastewater Generation

QUANTITY (KL/DAY)


Domestic 20 15 35

Industrial Process 215 145 360

Boiler 10 10 20

Cooling 5 5 10

Washing - 25 25

Total (Industrial) 230 185 415

Total Wastewater Generation KL/day 250 200 450

Note:

1) Domestic effluent shall be disposed off through septic tank&soak pit system or

shall be treated along with industrial effluent and discharged into GIDC

underground drainage system and conveyed to FETP (NCT)

2) The industrial effluent is discharged into GIDC underground drainage pipeline &

conveyed to final pumping station, Ankleshwar and then FETP (NCT) for further

treatment. ultimately discharged into deep sea through NCT pipeline.

52

WATER BALANCE DIAGRAM:

450 KL/Day: After treatment sent to FCETP of M/s

NCT through GIDC Pipe line for final treatment

&disposal in to Deep Sea.

Raw Water: 500 KL/Day from GIDC

Domestic:

50 KL/Day

Process:

272 KL/Day Boiler:

99 KL/Day

Washing:

25 KL/Day Gardening:

4 KL/Day

Septic tank

&Soak Pit:

35 KL/Day

360 KL/Day 20 KL/Day 10 KL/Day

ETP: 450 KL/Day

Cooling

Tower:

50 KL/Day

25 KL/Day

53

ANNEXURE: 5

Details of Effluent Treatment Scheme

Primary Treatment:

Advance Oxidation Process (Fenton Reaction):

The wastewater from Nano filtration stream transferred to AOP unit. In AOP, Hydrogen

Peroxide and Ferrous Sulphate are online dosed through static mixture in the required ratio

for individual Nano-filtration stream.

This treated wastewater is collected in 6m3 tank and as the level of the tank reaches to high

level then the discharge pump of this tank is automatically started and transferred the

treated wastewater to NF buffer tank in WWTP (Waste Water Treatment Plant).

During transferring, sample is also automatically collected in sample bean at the interval of

the 500 lit transfers. Collected samples are sent for the analysis of the wastewater if

required.

Once the low level of the tank is reached then pump automatically stops.

This operation of AOP contuse till Nano-filtration of particular batch is completed.

After AOP process, waste water from plant is collected in 10 KL sumps. It’s then being

pumped through overhead pipeline to main effluent treatment buffer storage tanks.

From buffer storage tanks effluent transfer 10 KL reactor where pH of the wastewater is

adjusted by Acid / Caustic and then polyelectrolyte solution to improve the flocculation.

The precipitated & flocculated waste water is passed though filter press to remove

flocculated mass and the filtered waste water coming out from the filter press is sent to ETP

feed tank for biological process.

Secondary treatment:

Biological Treatment Facility:

After advance oxidation process and primary treatment, waste water treated through

biological treatment (as per flow chart) which is having its own automation concept. This

unit allows COD removal as well as nitrification and de-nitrification of N- compounds for

Ammonical Nitrogen Reduction. For optimal operation, necessary nutrition is added like

Phosphate. In the D-N-C Tanks, the Ammonical nitrogen gets converted into organic

Ammonical nitrogen which is then converted into NO2 & then NO3 & when it gets back to D

tank, it releases the Nitrogen.

After Biological treatment, effluent goes to final treated holding tanks through clarifier &

then treated effluent send to common final effluent treatment plant (M/s NCT) for further

treatment disposal into deep sea.

Multiple Effect Evaporator:

MEE plant operated only for high TDS effluent stream and the product campaign is based on

market demand.

High TDS waste water from plant is collected in 10 KL sumps. It’s then being pumped

through overhead pipeline to MEE buffer storage tanks. The buffer storage tank is fitted

with agitator to keep mass in homogenized condition. As and when collection tank is filled

up pH of the effluent is checked and corrected to PH 7.0 to 7.5 by caustic.

After neutralization the waste water is passed through filter press to remove the suspended

solid. The filtrated waste water

tank and solid waste received from filter press is sent to solid waste storage shed for

disposal at TSDF

The waste water from MEE feed tank is sent to Multi Effect Evaporator for further treatment

as per flow chart. The MEE distillate is collected in final effluent storage tank for disposal

and salt received from the MEE Horizontal Belt Filter (HBF) is collected in bags & transfer to

solid waste storage shed for disposal at TSDF.

A. Primary treatment flow diagram:


solid. The filtrated waste water coming out from the filter press is collected in MEE feed



s per flow chart. The MEE distillate is collected in final effluent storage tank for disposal


solid waste storage shed for disposal at TSDF.

flow diagram:

54


coming out from the filter press is collected in MEE feed



s per flow chart. The MEE distillate is collected in final effluent storage tank for disposal


55

B. ETP Flow Diagram for Biological treatment:

C. MEE Treatment Flow Diagram:

C. MEE Treatment Flow Diagram:

56

57

Characteristics of effluent:

Sr. No. Parameters Units Raw

Effluent

After

Primary

Treatment

After

Biological

Treatment

FETP

Norms

1 pH -- 4 to 6 6.5 to 8.5 6.5 to 8.5 6.5 – 8.5

2 COD ppm 7000 5000 350 1000

3 TOC ppm 1500 1100 100 250

4 Ammonical

Nitrogen ppm 250 210 10

50

5 TSS ppm 1000 80 <80 100

Note: After treatment, effluent is sent to NCT (Final Common

Effluenttreatment plant for further treatment & disposal in to deep sea.

58

ANNEXURE: 6

DETAILS OF HAZARDOUS SOLID WASTE MANAGEMENT AND DISPOSAL

Sr.

No.

Name of

Hazardous

Waste

Schedule Cat.

No.

Quantity in MT / Year Facility Mode of Disposal & Remark

Existing Addition

al

Total

after

expansion

1 Spent Solvents I 20.2 4800 00 4800 Collection,

Disposal, Reuse,

Recovery,

Storage,

Transportation

Disposal by sell out to authorized users who

is having authorization with valid CCA and

rule 9 permission to receive this waste or

send for job work to authorized distillation

unit such as M/s. Daxesh Petrochem P. Ltd.,

Ankleshwar

2 Spent Solvents I 20.2 2021 00 2021 Collection,

Incineration,

Disposal, Storage,

Transportation

Disposal by incineration in common

incinerator of BEIL, Ankleshwar / SEPPL,

Ankleshwar or sent for co-processing in

cement industries/RSPL.

3 Process Waste

Sludge/Residues

Containing Acid,

Toxic Metals,

Organic

Compounds

I 26.1 22 13 35 Collection,

Incineration,

Disposal, Storage,

Transportation

Process waste residue / Hyflow waste

disposal by incineration in common



cement industries / RSPL.

4 Off Specification

Products

I 28.4 150 00 150 Collection,

Incineration,

Disposal, Storage,

Transportation

Off specification materials disposal by

incineration in commonincinerator of BEIL,

Ankleshwar / SEPPL,Ankleshwar or sent for

co-processing in cement industries / RSPL.

5 Non-recyclable

Plastic Waste,

insulation material,

Used PPE, Filter

I 33.1 21.4 28.6 50 Collection,

Disposal, Reuse,

Storage ,

Transportation

Disposal to TSDF of M/s. BEIL,Ankleshwar /

SEPPL.

59

Cloth, Filter

Cartridge & Broken

Glassware’s

6 Empty barrels

/containers /liners

Contaminated with

hazardous

chemicals

/wastes

I 33.1 170 180 350 Collection,

Disposal, Reuse,

Storage,

Transportation

Disposal by sending to authorized

decontamination facility / recycler or reuse

orsend back to supplier.

7 Chemical sludge

from

waste water

treatment

I 35.3 1400 600 2000 Collection,

Disposal, Storage,

Transportation

ETP Waste & MEE Salt: Disposal by sending

to TSDF of M/s. BEIL, Ankleshwar / SEPPL.

8 Used or Spent Oil I 5.1 2 13 15 Collection,

Disposal, Reuse,

Storage,

Transportation

Disposal by Reuse in plant & machinery as

lubricant or sell it to authorized re-refiners /

recycler.

9 e-Waste 0 20 20 Collection,

Disposal, Reuse,

Storage,

Transportation

Disposal by sell it to authorized recycler or

reuse

10 Spent Carbon I 28.3 0 25 25 Collection,

Incineration,

Disposal, Storage,

Transportation

Disposal by incineration in common



cement industries /RSPL.

11 Spent ion exchange

Resin

I 35.2 0 25 25 Collection,

Disposal, Reuse,

Storage,

Transportation

Spent ion exchange resin from waster

softening/DM plant: Disposal by sending to

TSDF of M/s. BEIL, Ankleshwar /

SEPPLorsend back to supplier.

12 Salts of Per-Acids II B36 125 0 125 Collection,

Disposal, Reuse,

Sodium Acetate Crystal: Reuse or sell out to

authorized users who is having

60

Storage,

Transportation

authorization with valid CCA and rule 9

permission to receive this waste.

13 Salts of Per-Acids II B36 75 0 75 Collection,

Disposal, Reuse,

Storage,

Transportation

Sodium Acetate Solution (on 100% basis):

Reuse or sell out to authorizedusers who is

having authorization with validCCA and rule

9 permission to receive thiswaste.

61

ANNEXURE: 7

DETAILS OF FLUE & PROCESS GAS EMISSION

DETAILS OF AIR POLLUTION CONTROL MEASURES

DETAILS OF FUEL CONSUMPTION

SR.

No.

NAME OF FUEL QUANTITY


1. Natural Gas 17,878 SM3/DAY 10,722 SM

3/DAY 28,600 SM

3/DAY

2. LDO 600 Ltr./HR 00 600 Ltr. /HR

3. Diesel / Furness

Oil (FO)

--- 600 Ltr/HR 600 Ltr./HR

4. Electricity 3383 KW 2117 KW 5500 KW

DETAILS OF FLUE GAS EMISSION THROUGH STACK ATTACHED TO BOILER

(NO CHANGE)

Sr.

No.

PCB

ID

Of

Stack

Stack

Attached

To

Capacity/Remark APCM Stack

Height

(M)

Parameter Permissible

Limit

Unit

1 93428 D.G. Sets D.G. Set -I, CAP:

1010 KVA

-- 14 PM

SO2

NOX

150

100

50

mg/Nm³

ppm

ppm

2 8915 D.G. Sets D.G. Set -II, CAP:

1010 KVA

-- 14 PM

SO2

NOX

150

100

50

mg/Nm³

ppm

ppm

3 8914 Boiler Boiler - I

CAP:3.5 TPH

Boiler – II

CAP:3.5 TPH

-- 32 PM

SO2

NOX

150

100

50

mg/Nm³

ppm

ppm

4 45984 Flue Gas

Emission

Source

VapourAbsorption

Machina

(VAM)

CAP.250 TR

-- 9 PM

SO2

NOX

150

100

50

mg/Nm³

ppm

ppm

62

DETAILS OF PROCESS EMISSION THROUGH VARIOUS STACKS

(NO CHANGE)

Sr.

No.

PCB ID

Of Stack

Stack

Attached To

Name of Process Plant Air Pollution

Control

Measure

(APCM)

Stack

Height in

Meter

(From

G.L.)

Parameter &

Permissible

Limit

1 55785 Reaction

Vessels

Exhaust of process

vessels attached to

alkali scrubber

Alkali

Scrubber

30 HCl<20

mg/Nm³

2 39372 Reaction

Vessels

Exhaust of process

vessels (attached to

alkali scrubber &

Regenerative Thermic

Oxidiser)

Alkali

Scrubber

30 HCl<20

mg/Nm³

3 39398 Reaction

Vessels

Exhaust of process

vessels attached to

acid scrubber

Acidic

Scrubber

30 PM<150

mg/Nm³

SO2<40

mg/Nm³

Ammonia<175

mg/Nm³

4 39400 Process

Emission

Vessel

Stack attached to dust

collector-I

Bag Filter 32 PM<150

mg/Nm³

5 93429 Process

Emission

Vessel


collector-II


mg/Nm³

6 93430 Process

Emission

Vessel


collector-III

Bag Filter

32

PM<150

mg/Nm³

7 93431 Process

Emission

Vessel


collector-IV

Bag Filter 32

PM<150

mg/Nm³

8 39399 Process

Emission

Vessel

Exhaust of storage

tanks attached to alkali

scrubber

Alkali

Scrubber

9 HCl<20

mg/Nm³

9 Proposed Process

Emission

Vessel

Stack attached to

chemical charging

hopper


mg/Nm³

10 Proposed Laboratories

fumehoods&

Lab chemical

Vent attached to

Laboratories fume

hoodscabinets& Lab

-- 12 HCl<20

mg/Nm³

63

storage

cabinets

chemical storage

cabinets

64

ANNEXURE: 8

DETAILS HAZARDOUS CHEMICAL STORAGE FACILITY

Tank

No. Name of Materials

Type of

Hazard Kind of Storage

Max.

Quantity to

be stored in

(M3)

Tank

Dimensions

in (Mtr.)

Dyek

Dimensions in

(Mtr.)

B-1310 Methanol Flammable Above Ground

Tank 50 4.0 x 4.3 6.5 x 6.0 x 1.4

B-1320 Toluene Flammable Above Ground

Tank 50 4.0 x 4.3 6.5 x 6.0 x 1.4

B-1330 Spent Toluene Flammable Above Ground

Tank 35 3.5 x 4.0 6.5 x 6.5 x 1.4

B-1340 Spent Methanol Flammable Above Ground

Tank 35 3.5 x 4.0

6.01 x 5.065 x

1.4

B-1350 Spent Toluene Flammable Above Ground

Tank 35 3.5 x 4.0 6.01 x 6.59 x 1.4


Tank 35 3.5 x 4.0

6.01 x 5.935 x

1.4


Tank 35 4.0 x 4.3 6.5 x 5.935 x 1.4

B-1400 Recovered

Methanol Flammable

Above Ground

Tank 50 4.0 x 4.3 6.5 x 5.935 x 1.4


Tank 50 4.0 x 4.3

6.01 x 5.935 x

1.4

B-1370 Diesel Flammable Above Ground

Tank 35 3.5 x 4.0

6.01 x 5.935 x

1.4

B-1390 Recovered

Methanol Flammable

Above Ground

Tank 50 4.0 x 4.3

6.01 x 5.935 x

1.4

--

Emergency Tank as

a secondary

containment

-- Concrete Tank 213.2 -- 12.64 x 4.82 x

3.5

-- Hydrogen Peroxide

35%

Corrosive &

Oxidizing

Cold storage

room 3 -- 9.77 x 5.77 x 3.5

Acid / Alkali Storage Tank Farm Details (Existing)

B-1120 Hydrochloric acid

32% Corrosive

Above Ground

Tank 16 2.2 x 3.0 6.84 x 6.47 x 1.4

B-1150 Formic Acid Corrosive Above Ground

Tank 10 2.4 x 5.46 6.58 x 4.55 x 1.4

B-1180 Formic Acid Corrosive Above Ground

Tank 10 2.7 x 4.0

5.965 x 6.47 x

1.4

B-1160 Sodium Hydroxide

32% Corrosive

Above Ground

Tank 25 3.0 x 4.0 6.58 x 4.55 x 1.4

B-1110 Sodium Hydroxide

32% Corrosive

Above Ground

Tank 25 3.0 x 4.0 6.58 x 4.55 x 1.4

B-1230 N,N-

Dimethylacetamide Toxic

Above Ground

Tank 25 3.0 x 4.0 6.58 x 4.55 x 1.4

65

B-1220 Sodium Nitrite 46

% Oxidizing

Above Ground

Tank 25 3.0 x 4.0 6.58 x 4.55 x 1.4

B-1140 Pergasol Finshed

Goods Non DG

Above Ground

Tank 50 4.0 x 4.3 6.58 x 6.15 x 1.4


Goods Non DG

Above Ground

Tank 50 3.5 x 5.6 6.58 x 6.15 x 1.4


Goods Non DG

Above Ground

Tank 50 4.0 x 4.3 6.58 x 6.15 x 1.4

Note: Remaining chemicals are stored in warehouse

Control measures provided for Solvent Tank Farm:

1. Construction & Installation of solvent storage facility is provided as per explosive act,

(License & local rules / regulation followed).

2. Flame proof electrical fitting & intrinsically safe instruments are installed.

3. Flame arrestor installed on vent pipe with breather valve & emergency vent valve provided.

4. Earth fault relay trip installed for solvent tanker unloading system (Solvent pump having interlock

with grounding of the tanker to make 100% grounding.).

5. Grounding (double earthing) & Jumper for flange joint provided for all installation & it is monitored

periodically.

6. Road Tanker grounded before unloading.

7. Convenient metallic SS hose pipes provided for tanker unloading for better connectivity.

8. Deep in let pipe provided inner side of the solvent tanks.

9. Check list is followed for loading & unloading.

10. Level indicator provided on the tank.

11. Adequate dyke wall (noncombustible) is provided.

12. Leakage collection bund with foam system is provided.

13. Combustible Gas Detection system, Fire (Foam / Powder) extinguisher, Foam monitors is provided.

14. F-30 coating provided for solvent storage tanks.

15. Nitrogen blanketing system is provided.

16. Closed handling system is provided.

17. Smoke detector system installed at Hydrogen Peroxide storage room.

18. Cooling system provided for Hydrogen Peroxide storage room.

19. In case of High temperature of Hydrogen Peroxide Storage Room, High temp. indication provided &

connected centralized DCS system.

Control measures provided for Acid / Alkali Tank Farm:

1. Adequate dyke wall (with acid proof coating) provided.

2. Level indicator with high level alarm provided on the tank.

3. Water curtain system installed on southern extreme of site in front of tank farm to avoid gas

dispersing on general road traffic.

4. Scrubber system installed for HCL storage tank & used during road tanker unloading.

5. Adequate flexible SS hose provided for tanker connection for unloading.

66

6. Dedicated pumps are provided and located with its close proximity to the respective tank to avoid

unintentional mistake of mixing of chemicals.

7. Leakage / Spillage handling kit provided.

8. To avoid chemical exposure, closed handling system is provided.

9. Fire hydrant system provided including water curtain system.

Control measures provided for Warehouse:

1. Fixed electrical fitting is provided. Lighting is installed between racks above the gangways & away

from material storage to avoid heating to storage goods.

2. Electrical fitting tested periodically (i.e. electrical load thermo graphic temperature measurement,

mechanical integrity of cables, physical condition of cable & other electrical appliances /

installation.)

3. BT reach truck battery charging station is provided outside of ware house.

4. Appropriate passage, gangways provided.

5. Fire detection system (Beam Detector) provided.

6. Adequate portable fire extinguishers installed at noticeable position & kept easily accessible.

7. Fire hydrant system provided.

8. Auto sprinkler system provided on individual racks compartments at Ware House: this system is

independent system having Separate Pumps with separate piping from Pump House to Ware House,

it consists of automatic operated sprinkler on 59°C.

9. Fire Alarm System: Automatic fire detection & alarm system consists of Fire Detectors, Addressable

Manual Call Points (MCP) & Hooters Beam Detectors (Ware House) are placed at strategic locations

and connected by cable to central control panel at ECC with repeater panel at DCS Control Room.

10. Emergency exit provided.

11. A warehouse is used exclusively for storage activities. Loose chemical handling not allowed.

12. Chemical segregation is done based on reactivity.

13. In case of maintenance work, Ignition sources controlled by hot work permit system.

14. Natural & Eco ventilator is provided.

15. Proper drainage system is provided for used fire water.

67

ANNEXURE 9

SOCIO - ECONOMIC IMPACTS

1) EMPLOYMENT OPPORTUNITIES

The manpower requirement for the proposed project is expected to generate some permanent

jobs and secondary jobs for the operation and maintenance of plant. This will increase direct /

indirect employment opportunities and ancillary business development to some extent for the

local population. This phase is expected to create a beneficial impact on the local socio-economic

environment.

2) INDUSTRIES

Required raw materials and skilled and unskilled labors will be utilized maximum from the local

area. The increasing industrial activity will boost the commercial and economical status of the

locality, to some extent.

3) PUBLIC HEALTH

The company regularly examines, inspects and tests its emission from sources to make sure that

the emission is below the permissible limit. Hence, there will not be any significant change in the

status of sanitation and the community health of the area, as sufficient measures have been

taken and proposed under the EMP.

4) TRANSPORTATION AND COMMUNICATION

Since the existing factory is having proper linkage for the transport and communication, the

development of this project will not cause any additional impact.

In brief, as a result of the proposed project there will be no adverse impact on sanitation,

communication and community health, as sufficient measures have been proposed to be taken

under the EMP. The proposed project is not expected to make any significant change in the

existing status of the socio - economic environment of this region.

68

ANNEXURE – 10

PROPOSED DRAFT TERMS OF REFERENCE:

1. Project Description

• Justification of project.

• Promoters and their back ground

• Project site location along with site map of 5 km area and site details providing various

industries, surface water bodies, forests etc.

• Project cost

• Project location and Plant layout.

• Water source and utilization including proposed water balance.

• Product spectrum (proposed products along with production capacity) and process

• List of hazardous chemicals.

• Mass balance of each product

• Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection

• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5 km

area.

• Existing environmental status Vis a Vis air, water, noise, soil in 5 km area from the project site.

For SPM, RSPM, SO2, NOx.

• Ground water quality at 5 locations within 5 km.

• Complete water balance

3. Socio Economic Data

• Existing socio-economic status, land use pattern and infrastructure facilities available in the study

area were surveyed.

4. Impacts Identification And Mitigatory Measures

• Identification of impacting activities from the proposed project during construction and

operational phase.

• Impact on air and mitigation measures including green belt

• Impact on water environment and mitigation measures

• Soil pollution source and mitigation measures

• Noise generation and control.

• Solid waste quantification and disposal.

5. Environmental Management Plan

• Details of pollution control measures

• Environment management team

• Proposed schedule for environmental monitoring including post project

69

6. Risk Assessment

• Objectives and methodology of risk assessment

• Details on storage facilities

• Process safety, transportation, fire fighting systems, safety features and emergency capabilities to

be adopted.

• Identification of hazards

• Consequence analysis through occurrence & evaluation of incidents

• Disaster Management Plan.

7. Information for Control of Fugitive Emissions

8. Post Project Monitoring Plan for Air, Water, Soil and Noise.

9. Information on Rain Water Harvesting

10. Green Belt Development plan

70

ANNEXURE -11

GIDC WATER SUPPLY LETTER

71

ANNEXURE -12

TREATED EFFLUENT DISCHARGE – NCT MEMBER CERTIFICATE

72

73

ANNEXURE -13

BEIL MEMBERSHIP CERTIFICATE

74

ANNEXURE -14

GIDC PLOT ALLOTMENT LETTER

75

ANNEXURE -15

COPY OF CONSENT TO OPERATE

NOC (2005)

76

77

78

CCA (2017)

79

80

81

82

83

84

85

86

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