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Background
Alternative
Residual Management
Conclusion
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Are
a (m
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Month
Montreal Protocol
01000200030004000500060007000800090001000011000
HFC-134a
HFC-32
HCFC-124
HCFC-22
HCFC-142b
Methyl Chloroform
HCFC-141b
Methyl Bromide
CFC-115
CFC-113
CFC-11
CFC-114
CFC-12
Carbon Tetrachloride
Halon-1211
Halon-1301
Global Worming Potential (20 Year, CO2 = 1)(Source: Scientific Assessment of Ozone Depletion)
0.022
0.055
0.065
0.1
0.11
0.6
0.6
0.8
1
1
1
1.1
3
10
0 1 2 3 4 5 6 7 8 9 10 11
Ozone Depletion Potential (CFC-11 = 1)(Source: The Montreal Protocol)
0
0
Summary of Montreal Protocol control measuresOzone depleting substances Developed countries Developing countries
Chlorofluorocarbons (CFCs) Phased out end of 1995a Total phase out by 2010
Halons Phased out end of 1993 Total phase out by 2010
Carbon tetrachloride Phased out end of 1995a Total phase out by 2010
Methyl chloroform Phased out end of 1995a Total phase out by 2015
Hydrochlorofluorocarbons (HCFCs) Freeze from beginning of 1996b
35% reduction by 200475% reduction by 201090% reduction by 2015Total phase out by 2020c
Freeze in 2013 at a base level calculated asthe average of 2009 and 2010 consumption levels10% reduction by 201535% reduction by 202067.5% reduction by 2025Total phase out by 2030d
Hydrobromofluorocarbons (HBFCs) Phased out end of 1995 Phased out end of 1995
Methyl bromide(horticultural uses)
Freeze in 1995 at 1991 base levele
25% reduction by 199950% reduction by 200170% reduction by 2003Total phase out by 2005
Freeze in 2002 at average 1995-1998 base levele
20% reduction by 2005Total phase out by 2015
Bromochloromethane (BCM) Phase out by 2002 Phase out by 2002
“without significant subsequent action, the world environment would surely have been in
grave jeopardy”
REGULATION NO CONTENTPeraturan Presiden Nomor 33 Tahun 2005 Pengesahan Beijing Amendment To The
Montreal Protocol On Substances That Deplete
The Ozone Layer (Amendemen Beijing Atas
Protokol Montreal Tentang Bahan-Bahan Yang
Merusak Lapisan Ozon)
Peraturan Presiden No 46 Tahun 2005 Pengesahan Montreal Amendment To The
Montreal Protocol On Substances That Deplete
The Ozone Layer (Amendemen Montreal Atas
Protokol Montreal Tentang Bahan-Bahan Yang
Merusak Lapisan Ozon)
Peraturan Menteri Perdagangan No 24/M-
dag/Per/6/2006
Ketentuan Impor Bahan Perusak Lapisan Ozon
Peraturan Menteri Perindustrian No 33/M-
ind/Per/4/2007
Larangan Memproduksi Bahan Perusak Lapisan
Ozon Serta Memproduksi Barang Yang
Menggunakan Bahan Perusak Lapisan Ozon
Peraturan Menteri Perdagangan No 51/M-
dag/Per/12/2007
Ketentuan Impor Metil Bromida Untuk
Keperluan Karantina dan Pra Pengapalan
Back
• ODP
• GWPEnvironmental
• Flammability
• ToxicitySafety
• Operating Pressure
• Oil Transport PropertiesTechnical
• New material price
• Conversion cost
• Down timeEconomic
COMMERCIAL REFRIGERATION
Alternative and Presenter Advantages Disadvantages
R-422D retrofit of HCFC-22 supermarket systems
(Epta)
• Retrofits done quickly without business interruption
or additional investment
• Energy advantages
• Lower discharge temperature (for longer compressor
and components lifespan)
• Direct GWP climate impact
• No other disadvantages specifically addressed in
presentation
R-417A retrofit of HCFC-22 medium temp. ref. and
stationary AC
R-422A retrofit of HCFC-22 and R-502 medium/low
temp. ref.
R-422D retrofit of HCFC-22 ref. and stationary AC
R-437A retrofit of CFC-12 medium temp. ref. and
mobile AC (DuPont)
• Safety classification of A1
• Typically no-oil-change retrofit
• Comparable energy efficiency compared to HCFC-
22 for R-417A, R-422A, and R-422D, and compared
to CFC-12 or HFC-134a for R-437A
• Comparable capacity compared to HCFC-22 or R-
417A, R-422A, and R-422D, and compared to CFC-12
or HFC-134a for R-437A
• Direct GWP climate impact
• No other disadvantages specifically addressed in
presentation
R-744 (CO2) new transcritical and cascade
supermarket refrigeration systems (Green Cooling
Council)
• No climate impact
• Low toxicity and no flammability
• Potential for low power consumption in
cool/moderate climates
• Theoretical higher efficiency than HFC-134a up to
30°C
• Low cost and widely available refrigerant
• Lack of systems knowledge/familiarity
• Potential for high power consumption in hot
climates
• Remote location servicing challenge
• Installation costs currently 20% higher than
conventional system
R-290 (propane)
commercial refrigeration equipment, including
bottle coolers, glass door merchandisers, ice
cream/chest freezers, commercial refrigerators
and freezers (Danfoss)
Low cost and widely available refrigerant
In running production
Good thermodynamic performance compared
to HCFC-22, especially in low countries
Low climate impact (GWP of 3)
Comparable pressure, capacity loss, and COP
performance compared to HCFC-22
Improved pressure ratio LBP, discharge
temperature, and volumetric capacity compared
to HCFC-22
Safety concerns (flammability); may mean
slightly increased cost depending on base design
Costs for factory investments in leak test,
charging, and safety installments
Change of system parts for larger appliances
Ammonia commercial/industrial applications
(Jaeggi/Guntner)
No climate impact
Favorable in large systems
No simple replacement in new systems; all
refrigerants need adjustments (e.g., different
refrigerant-carrying tubes)
Hydrocarbons retrofit of large chillers (Energy
Resources Group)
Energy savings
Low climate impact
Technician training to understand hydrocarbon
characteristics Some projects, sites, and chillers
are not suitable for hydrocarbons because of
location, serviceability, ventilation
Back
R-22 Residu
Recycle Disposal
Available in Indonesia : PT Holcim Indonesia Tbk
• Cement Kiln is a destruction technology in which CFC gas decomposes completely in a few seconds at high temperatures, thus generating hydrochloric and hydrofluoric acids which we are then reacted with alkaline calcium and fixed to form non-toxic and harmless clinker material
• CFC thermal Destruction in cement kiln:– (1) CF2Cl2 + 2H2O 2HCl + 2HF + CO2
– (2) CaCO3 CaO + CO2
– (3) CaO + 2HCl CaCl2 + H2O
– (4) CaO + 2HF CaF2 + H2O
Back
• HCFC is phasing out both in developed and developing countries
• Several alternatives have been available in the market
• No one substance is fit for all application
• ODS destruction facility is already available in Indonesia
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