&R203I67 - Superfund Records Collections | US ... Ioluene-d8 23.U4 bB3 1UV822 233.// ug/L 4U3 Ch...

91L-3551-1Q Sample Data Package

&R203I67

KtPUK I

Uperator 1U: HRLLJb ' Uuant Kev: 6 Uluant l i m e : V1112/ 18:46Uutput I- ile: ~«3/66::U2 injected at: yill2/ I/:1? 3Data h i l e : >«3/66::i33 D i l u t i o n hactor: ^.UUUUUName: V lL->1?'? 1- 1U ;r-Uac :

1 U h i 1 e : 1 U__UCtt : : U2 \l i t l e : HH UUft Standards for ^ Point Calibration Lurve Kev. tLast Calibration: V 11 113 16:18

j

Compound K. I . Scan* Hrea Lone Units

13 *Bromoch lorome thane 9. U2 221 241/8 bU.CJU ug/L43 Uinyl Chloride 2./U b8 141!? I1?. 41 ug/L143 Irans-l,2-LMchloroethene 1U.61 262 y?91 6 .8/ ug/L163 1 ,2-Uich Ioroethane-d4 11,.81 293 6421?/ 221?.1?! ug/L23) *1,4-Uif luorobenzene 19.36 488 1U2383 'jU.OU ug/L2V3 Benzene ' 16.8U 422 12446 33.V6 ug/L33) *Ch lorobenzene-d1? ! 24.2U 613 88 60 bU.OU ug/L383 loluene , 23.16 b86 2U81? 8.13 ug/L3V3 Ioluene-d8 23.U4 bB3 1UV822 233.// ug/L4U3 Ch lorobenzene 24.32 616 -18U834 Û/./1? ug/L

•) Uromofluorobenzene 2B.43 /22 93693 223.Ul ug/L

* Compound is IblU

AR203I68

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Data I-lie: >(=»3/66::U3 Uluant Output I-lie: /xName: 91L-3^?^1-1UMisc: IML/bML

1 d H i 1 e : 1 U_"JL-tt: : 02l i t l e : HP UUft Standards for 5 Point Calibration Curve Kev. tLast Calibration: 911113 16:1B

Uperator 1U: MttLUbQuant Time: 91112^ IB:46injected at: 91112^ l/:!?3

AR203169

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PFriRi.m cRflnKfinmiNn siiRTRorTFn^3766 91L-35S1 — 10 iflL.-'SfIL ?5 afi 2213605. """ ~* SIIR " "" ~ 9.02 min.

49( 13»-100

37 | 52 . <l *> ^ 116 1 ' \/ 1 1 / if 1 1 \ \ t

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PECTRUtl <UM«LTERED>3766 91L-3551-10 IMLxBttL Scan 2213605. 9.02 win.

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Uata I-i l e : >«3/66t!U3 Uuant Uutput H i l e : "«3/66::U2Name: 91L-3'?17l-lU '.Hisc: IHL/'jHL 'Duant t i m e s 91112? 18:46 Uuant 1U File: IU_UCR::U2Injected at: V1112/ l/:t?3 Last Calibration: 911113 16:18

Compound No: 1- 11STU3Compound Name: Bromoch1oromethanebean Number: 221Ketent ion lime: 9 . U2 mm.Ljuant Ion: 12B.Oftrea: 241/BConcentration: 5U.OU ug/L-'v-a lue: 8U

AR203I70

ri c. r c. K.C. n u e. o ivinyi unioriaa ssxx£7 xuiuu scan eo

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r i i a /G^ÂA at i _-5g«!^_i r\ i MI /gM(_ QC M,"Bok fib 160. *"" ~ "" SUB *"'"' " 2.70 w

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ECTRUM <UNfll_TER£D> - _ - . - _ ____ ___ _?66 "" 91L-3551-10 lt1L>5ML " ~ Scar79. 2.70 H

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Uata l-ils: >«3/66::U3 Uuant Uutput t-ile: 'vft3/66::U2Name: 91L-3b'?l-lU ',riisc: IHL/^HLUuant lime: 91112/ IB:46 Uuant iU File: IU_UC«::U2Injected at: 91112X l/:'?3 Last Calibration: 911113 16: IB

Compound No: 4Compound Name: Umyl Chloridebean Number: 'yti ,detention lime: 2./U mm.Uuant Ion: 62.0«rea: 141^>Concentration! 15.41 ug/Lq-âlue: Bl

AR203I7I

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, , , , , , . , 1 1 .' . |«-0•;>o 1003RMPLE SPECTRUM <yNRl.TERED) __ _ __ ___Fil« ?R3766 " 91L-3551-10 ~ TuL/BML "~Sc»nBpk Rb 1253. 10.61 Min

6196

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Uata hi la: >R3/66:;:U3 Uuant Uutput rile: "ft3/66::L)2Name: 91L-3^"?1-1Uriisc: IHL/^ML ]Uuant lime: 9111VJ7 IB: 46 Quant IL3 File: lU_UCft::U2Injected at: 91112/ l/:t«3 Last Calibration: 911113 16:lB

Compound No: 14Compound Name: I rans-1,2-L3ich loroetheneScan Number: 262He tent ion lime: 1U.61 min.Uuant Ion: 96.0ftrea: 9 91Concentration: 6 7.8/ ug/Lq-valua: 9U

AR203I72

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Uata rile: >«3/66::U3 Uuant Uutput File: "«3/66::U2Name: 91L-31?^ 1-1U '

Uuant Time: 91112/" 1B-.46 Quant 1U File: IU_UCtt::U2Injected at: 91112/ l/:«?3 Last Calibration: 911113 16: IB

i!

Compound No: 16Compound Name: 1 ,2-Uich Ioroethane-d4bean Number: 293Ketent ion I ime : ll.Bl mm.Uuant Ion: 6"? . 0

Concentrations 22"?.1?1 ug/Lq-va lue : B'2

AR2Q3I73

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Scan 48819.36 Min.

114

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Uata t-ile: >«3/66::U3 Uuant Uutput I-lie: /NM3/66::U2Name: 91L-3'?'?1-1UHisc: inL/'-yflLUuant lime: 91112/ 1B:46 Uuant 1U File: IU_UCtt::U2Injected at: 91112/ l/:-73 . Last Calibration: 911113 16: IB

Compound No: 23 11SIU)Compound Name: 1 ?4-L)i F luorobenzenebean Number: 4BBKe tent ion lime: 19.36 mm.Uuant Ion: 114.0Area: 1U23B3Concentration: bU.OU ug/Lq-'v'a lue : 6B

AR203I71*

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<UNRUTERED> ;91L-3551-10 1ML/5ML Sea

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I ' l ' l ' l ' l ' l ' l ' l ' l ' i ' l ' l ' l ' l ' l ' l ' l • 1 '44 48 55 56 60 64 6S 72 (6

Uata rile: >A3/66::U3 Uuant Uu,tput rile: "«3/66::U2Name: 91L-31?'?1~1U jDisc: IHL/briL iUuant Time: 91112/ 1B:46 Quant ID File: lU_YCtt::U2injected at: V1112/ l/:'?3 Last Calibration: 911113 16: IB

Compound No: 29Compound Name: Benzeneb'can Number: 422Retention lime: 16.HU mm.Uuant Ion: 78.U !firea: 12446 . ,Concentration: 33.96 ug/Lq-vaiue: 92

AR203I75

REr'cREN'CE STPN'DnRu SFcCTRun_________________________________________i F"i i« >vXN5P HP VUH Ho 5pi ke Internal Standards and 5u 5c an 660I PI_ >. r»u •• rtn r>t n MP>M ~*f f A .• • .-|i_-w*nt^.i.v*/. ^ 1.1 i» IM t i_ U » O T ftf i. 11 ,

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sflMPLE SPECTRUM <UMBLTEReO>( _ _ _ _ _ _Fil«'>P3766 "91L-355i-10 ""iMLxBHL" " "" " Scan" '613Bpk Rb 6625. 24.20 Min.

117J B« ; t1)r' (-100

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Data t-iie: >R3/66::U3 Uuant Uutput I-lie: /Nft3/66::U2Name: 91L-3^1-1UMisc: inL/^riLUuant Time: 91112x' IB: 46 Uuani: IU File: lU_VCtt::U2Injected at: 91112/ l/:b3 Last Calibration: 911113 16: IB

Compound No: 33 CiblD)Compound Name: Ch lorobenzene-dbbean Number: 613Ketent ion I ime : 24. 2 U mm.Uuant ion: ll/.Uttrea: BB56UConcentration: bU.OU ug/L

99

AR203I76

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100

SQMPI F RPFP.TRIIM < RflrKRRfll INfl SlIRTRflrTFmFila , 93766 • 91L-3551-1C I.IL.'SML : Scan ?86Bck Rb 268. SUB , 23.16 min.

91.">• 92 MOO

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f f • *** 1 — *1 1 . i i 1 1 i40 50 60 70 80 9Q

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SflflPLE SPECTRUM (UNRLTERED)Fil« >R3766 91L-3551-10 1ML/5ML Scan 586Bpk Rb 2338. , 23.16 win.

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Uata rile: >ft3/66:: U3 Uuant Uutput I- lie: ^R3/66::U2Name: 91L-3'?I?1-1U '

Uuant lime: 91112/ IB: 46 Uuant iU File: lD_UCft::U2Injected at: 91112/ l/:'?3 Last Calibration: 911113 16: IB

iiCompound No: 3BCompound Name: loluenebean Number: bB6 jKe tent ion lime: 23.16 mm. ,Uuant Ion: 92.0 'ttrea: 2UB1? '.Concentration: B . 13 ug/Lq-vaiue: B9

AR203I77

r i i •/vXNSf HP VOH Ho Spik« Internal Standards and 5>u Scanr* _ ,. r«fc. t firr t.rtM ^»« ^rtwpn. «L^ J.W . l«,X,t L.W.k.w'

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<UNRLTEREO>91L-3551-1Q 1ML./5ML Scan 583

23.04 Min.

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i

Uata I- ile: >H3/66::U3 Uuant Uutput rile: ' 3/66: :U2Name: 9 1L-31?1?!- 1U

Uuant Time: 91112/ IB: 46 Uuant 1U File: iU_UCft::U2Iniected at: 91112/ l/:\?3 Last Calibration: 911113 16:lB

Compound No: 39Compound Name: loluene-dBScan Number: 5B3Ketention lime: 23. U4 mm.Uuant Ion: 9B.Ottrea: 1U9B22Concentrations 233. 77 ug/Lq-value: 9B

AR203I78

I i - l i e 51605 Benzene, chioro- ' Scan 105507, r.-... Du , «C> CLp ,-,_-. „„* NCM n>CC ,-,.,;,•-,.

i 112

"1 . 77 '

I GI '' ^ 114

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SfiMPLE SPECTRUM CyNRLTEREO) _ _ ,_ __File ">R3766 ~ """ " 91L-3551-10 ~ '""" 1ML/"5ML ~~ ~" "~"""~"s'cin" 6161>k flb 13514.

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Uata I-ile: >«3/66::U3 Uuant Uutput I-i 1 e: "ft3/66::U2Name: 91L-3'?'?1-1U !Hisc: IHL/'-'nL •Uuant lime: 91112/ IB:46 Uuant IU File: IU_YCfl::U2Injected at: 91112/ l/:l?3 Last Calibration: 911113 16: IB

iiCompound No: 4UCompound Name: ChlorobenzeneScan Number: 616 iKetent ion lime: 24.32 mm.Uuant Ion: 112.0 |Rrea: 1BU834Concentration! bO/*./^ ug/Lq-value: 96

AR203I79

SEr t .c.ftoc. 3Tm*uHRG 3F C.^ I HUH

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174 MOol

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SflriPLE SPECTRUMFile >R3766Bpk flb 4793.

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174f\ , on-»

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-100

i£0 140 160 i<50 cOO

Data Hile: >tt3/66::U3 Uuant Uutput l-ile: /XW3/66::U2Name: 91L-3'?I?1-1U

Uuant lime: 91112/ IB: 46 Uuant 1U File: IU_UCft::U2Injected at: 91112/ l/:.>3 Last Calibration: 911113 16:'1B

Compound No: 41?Compound Name: fctromof luorobenzeneScan Number: /22Retention lima: 2B.43 mm.Uuant Ion: 9 <? . 0 .ftrea: 93693 ;Concentration! 223. Ul ug/Lq-value: B9 i

AR203I80

SAMPLE INTEGRATION SUMMARYii

SAMPLE NAME AND AMT: 91L-3551-10 1ML/5MLSAMPLE DATA FILE: >A3766

PEAK NO. RET. TIME SCAN AREA IDENTIFICATION1 9.02 221 199077 IS2 10.61 262 48459 TC3 11.81 293 , 154141 SS

4 16.80 422 32746 TC5 19.36 488 294203 IS6 23.04 583 . 340308 SS7 24.32 616 1067135 TC8 28.43 722 . 594460 SS9 34.90 889 861676 UK

IS = INTERNAL STANDARDSS = SURROGATETC = TARGET COMPOUNDUK = UNKNOWN<10% = UNKNOWN LESS THEN 10% OF INTERNAL STANDARD

AR20318I

File >R3766 35

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3

L91

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-100

-90

-80

-70

':6 0

-50

140

-30

L29

r10

12 ' 16 ' 20 ' 24 ' 28 ' 3SI ' 36 ' 40 ' 44

AR203I82

File >R3766 91L-3551-10 1ML/5ML Scan 889Bpk Rb 4261. SUB

.^ " 50 ,fe - 37 , 61 63 { 84 97 99^^B - s*** \ ^^. -ft** 1 1 / v»_ _jf^r ft- 1 ' l • i i i ' t ' ' i i ' i ' f • 1 4-* •/'"li ''Ht-v •^ • •>•''

40 60 80 100

34.90 min.146/ L

' 120i / 1 1 1.

120 140-0

File >BIGDB Benzene, 1 ,4-dichloro- <9CI> Scan 16705Bpk flb 9999. 0.00 min.

146

•37 50 55 63 75 85 9? 98

40 60 80 100

11/ 120... ./.. 1 ll .

120 ' 140L0

File >BIGDB Benzene, 1 ,£-dichloro- <9CI> Scan 16704Bpk flb 9999. 0.00 min.

146

1 75 1J 37 50 55 63 , 85 97 98air f ...... .rrT" ...r"-" ....I.. .../... .* ....

40 60 80 100

11t 120 :..

120 ' 140t

File >BIGDB Benzene, 1 ,3-dichloro- <9CI> Scan 16706Bpk flb 9999. 0.00 min.

3_j 37 50 55 63 /5 85 97 98

• 40 ' 60 ' 80 - 100

146

11/ 120.•. ./. i it .

120 140-0

o

1. Benzene, 1,4-dichloro- (9CI) 146 C6H4C122. Benzene, 1,2-dichloro- (9CI) 146 C6H4C123. Benzene, 1,3-dichloro- (9CI) 146 C6H4C124. Peroxide, bis(dichlorobenzoyl) (9CI) 378 C14H6C1404

Sample file: >A3766 Spectrum #: 889Search speed: 1 Tilting option: S No. of ion ranges searched: 60

i

Prob. GAS # CON # ROOT K ^DK #FLG TILT % CON C_I R_IV

1. 95* 106467 16705 "BIGDB 100 8 1 2 100 0 72 932. 83* 95501 16704 "BIGDB 68 43 0 0 100 21 47 833. 81* 541731 16706 "BIGDB 60 48 0 0 100 20 45 734. 70 28604902 16707 "BIGDB 97 50 1 0 169 19 32 57

IiCORRECTED TOTAL ION AREA OF UNKNOWN = 861676CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 294203CONCENTRATION OF INTERNAL STD =50 ug/L DILUTION FACTOR =EMI QUANTITATION OF UNKNOWN = 730 ug/L

QUANT REPORT

Aerator ID: LUELLA Quant Rev: 6 Quant Time: 911206 13:23tput File: AD7806::D2 Injected at: 911206 12:37

uata File: >D7806::A1 Dilution Factor: 40.00000Name: 91L3551-10R :Misc: 25ML/1ML EXT:12/04/91 (RS0381) BTL# 1

ID File: ID_BAD::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911122 08:43

Compound R.T. Scan# Area Cone Units q

1) *d4-l,4-Dichlorobenzene 10.07 669 144983 40.00 UG/L 973) 2-Fluorophenol 6.74 349 299683 2664.52 UG/L 915) Phenol-d6 : 9.55 619 415197 2643.74 UG/L 9510) 1,4-Dichlorobenzene 10.13 674 6239 44.05 UG/L 8212) 1,2-Dichlorobenzene 10.67 726 18310 125.28 UG/L 8618) *d8-Naphthalene 13.90 1037 516178 40.00 UG/L 9419) Nitrobenzene-d5 ' 11.87 841 295014 2015.87 UG/L 9533) *dlO-Acenaphthene 19.39 1564 283699 40.00 UG/L 9338) 2-Fluorobiphenyl 17.43 1376 451163 1928.72 UG/L 9254) *dlO-Phenanthrene 23.95 2'002 407125 40.00 UG/L 9958) 2,4,6-Tribromophenol 21.91 1806 76440 2876.30 UG/L 8066) *d!2-Chrysene 32.26 2801 170904 40.00 UG/L 9369) Terphenyl-dl4 I 29.15 2502 345232 2439.64 UG/L 8773) Bis(2-Ethylhexyl)Phthalate 32.94 2866 14036 106.32 UG/L 8675) *d!2-Perylene 36.44 3203 73110 40.00 UG/L 94

*• Compound is ISTD '..

AR203I81+

TOTflL ION CHROHflTOGRflMFile >D

120000&i

1100000:

100000&

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Data File: >D7806::A1 Quant Output File: AD7806::D2Name: 91L3551-10RMisc: 25ML/1ML EXT:12/04/91 (RS0381) BTL# 1

Id File: ID_BAD::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911122 08:43

Operator ID: LUELLAQuant Time: 911206 13:23Injected at: 911206 12:37

&R203I85

REFERENCE STflNDflRD SPECTRUMFile >B7941 d4-l ,4-Dichlorobenzene 910925 09:20 Scan 752Bpk flb 44024.

40800-

- 40

40

SUB 10.89 min.150

~sDo £ . fO Q O i';D*T f t " 9 » ^ j . _ ._

/ S \ I

/•

1 ,1,

-100

-a60 80 100 120 140

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7806 91L3551-10R 25ML/1ML EXT:12/0 Scan 669Bpk flb 97656.

100000-j

•

fr

SUB 10.07 min.150

SP -70 1IL55,2 56 64 7,8 „, 99 108 /

,< ,• V0 ' ' ' '

.,/.../ ...,,.i... ..?:. S.N..L'

i ,i.

hl00••

60 ' 80 ' 100 ' 120 140

SflMPLE SPECTRUM <UNflLTERED>File >D7806 91L3551-10R 25ML/1ML EXT:12/0 Scan 669Bpk flb 97656.

100000-

-

0-

10.07 min.150

40 52 5,6 >4 7 97 99 108 V5

v-, . , , . . . ,40

1 ' ' ill ( ^ \ 1 I

f

, .1.

-100

•

-060 ' 80 ' 100 ' 120 ' 140

Data File: >D7806::A1 Quant Output File: 07806::D2Name: 91L3551-10RMisc: 25ML/1ML EXT:12/04/91 (RS0381) BTL# 1Quant Time: 91120$ 13:23 Quant ID File: ID_BAD::QTInjected at: 911206 12:37 Last Calibration: 911122 08:43Compound No: 1 (ISTD)Compound Name: d4-l,4-DichlorobenzeneScan Number: 669Retention Time: 10.07 min.Quant Ion: 152.0Area: 144983Concentration: 40.00 UG/Lq-value: 97

AR203I86

REFERENCE STflNDflRD SPECTRUMFile >BBpk flb

40000--

0-

7941 2-Fluorophenol 910925 09:20 Sea46568. SUB 7.50

164/

38 Rfl ^** ^ 83 ^^

l l l l | M l l [ l i l l | l l l l | l t i | l 1 - |li^! h l l | i l i l | l l l l | i i n | i l l l | i i i i | I I I I | I M i|l-40 50 60 70 80 90 100 110

nm

12/

-H

426in .

-100

'

-0

SflMPLE SPECTRUM <BflCKGROUNO SUBTRflCTED)File >D7806 91L3551-10RBpk flb 119832.

25ML/1MLSUB

EXT:12/0]

Scan 3496.74 min .

112•I 64 'Man

100000-

: /8 4X540

50 !? ,.r,.,,,!,,,!50 60

/73 83

68 / >*,

70 80, y T /

90 ' 100,,,,•! ! i -0119

SflMPLE SPECTRUM <UNflLTERED>File >DBpk flb

.

100000-

fr

7806 91L3551-10R119832.

38 45 50 / '/ / /. 1 1 1 . .. . . {.. . . 1 1 . i . . 1 1 . .ii40 ' 50 ' 60

25ML/1ML EXT:12/0 Sea6.74

154/

73 83 92 9768 , \ 86 { /

,../.../. . ....I../ .1... /70 80 90 ' 100 ' 110

nn

12f

349in .

-100

-0

Data File: >D7806::A1 Quant Output File: AD7806::D2Name: 91L3551-10RMisc: 25ML/1ML EXT:12/04/91 (RS0381) BTL# 1Quant Time: 911206 13:23 Quant ID File: ID_BAD::QTInjected at: 911206 12:37 Last Calibration: 911122 08:43

Compound No: 3Compound Name: 2-FluorophenolScan Number: 349Retention Time: 6.74 min.Quant Ion: 112.0Area: 299683Concentration: 2664.52 UG/Lq-value: 91

AR203I87

«-* -X.REFERENCE STflNDflRD SPECTRUMFile >B7941Bpk flb 41968.

40000-

40 ,

0 - l l l f l l j40

Phenol-d6SUB

42 „ 71-~ 49 54 58 66 ^/ . / / 's"%-~-

50 60 70

9.L0925

72 81 82/ \ /1 1 1 1 n 1 1 n 1 1 1 1

3 '3

09:29 Scan 69210.26 min.

99f -100

94

1 , '«,i i i i | i i i r | i l l | l u90 100

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >D7806 91L3551-10RBpk flb 141057.

.100000- 42

/ 1fr. . . 1 1 1 1 1 . .40

49 52

50

25ML/1MLSUB

7158 66 ^ yZ

60 70

EXTsl2/0 Scan 6199 .55 min .

99' h!00

1

8\ f ^ ;. . . . " i f /". . • i . .0

819 90 100

SflMPLE SPECTRUM CUNflLTERED)File >07806 91L3551-10RBpk flb 141057.

100000. 4240. -/ |

OL . \ . 1 1 1 1 1 . .. . __ .....

49 52. { . i . i . .50

25ML/1ML

7158 66 > 7 8^. ( . . . rî . . 1 1 1 / . . . . >60 70 88

EXT:12/0 Scan 6199 .55 min .

99' [-100

*

? r :, , , , , , , , , , , • i-, , i ,' i i -090 100

Data File: >D7806::A1 Quant Output File: 07806::D2Name: 91L3551-10RMisc: 25ML/1ML EXT:12/04/91 (RS0381) BTL# 1Quant Time: 911206 13:23 Quant ID File: ID_BAD::QTInjected at: 911206 12:37 Last Calibration: 911122 08:43Compound No: 5Compound Name: Phenol-d6Scan Number: 619Retention Time: 9.55 min.Quant Ion: 99.0Area: 415197Concentration: 2643.74 UG/Lq-value: 95

AR203I88

REFERENCE STflNDflRD SPECTRUMFile >B7941 1,4-Dichlorobenzene 910925 09:20 Scan 756Bpk flb 61248. SUB 10.93 min.

146-

40000-

&•

37

l'1'i i i i'l'40

50 55 72 ?5 _,_108 120/ S ^\_ ^' XL /

^

60 80 100 120 140

-100

-0

SflMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >D7806Bpk flb 2621

.

2000-•.

0-"40

91L3551-10R

55/1

60

25ML/1ML EXT:12/0 Scan 674SUB 10.13 min.

146-""

89 *i i "i

\ /> .1 , . 1

-100

.-0

80 ' 100 ' 120 ' 140

SflMPLE SPECTRUM <UNflLTERED>File >D7806 91L3551-10R 25ML/1ML EXT:12/0 Scan 674Bpk flb 4564. 10.13 min.

•4000-

-•

0-J

150/

40 52 71 78 i"

ll

/ ^ 63 <" f 85 99, ,. I.I.I. ,.>i. > ,lll ( . ^ .I I. ,l J.i 1

L^ CkC.

L040 ' 60 ' 80 ' 100 ' 120 ' 140


Compound No: 10Compound Name: 1,4-DichlorobenzeneScan Number: 674Retention Time: 10.13 min.Quant Ion: 146.0Area: 6239Concentration: 44.05 UG/Lq-value: 82

AR203I89

REFERENCE STflNOflRD SPECTRUMFile >B7941 1Bpk flb 52632.

.

40000-

fr*. • l i . • . i

37.Hi ,. i40

,2-Dichlorobenzene 910925 09:20 Scan 807SUB

75 "50 55 ;« , Q4 91 105

°° y' | / \I., I, ,-,i|.|. ..l|l,,.l. .III. ..f .. . Vil,i' ' ' ' 1 " ' :' ' 1 ' ' ' ' 1 ' ' ' ' 1 i ' ' ' 1 ' ' ' ' 1

60 80 108

11.461467

11120

I'M, M,. M ,,..,« 1 ,129 149

mm .

-100•

•

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >DBpk flb

•.

4000

0

7806 91L3551-10R 25ML/1ML6671. SUB

75 ^37 f f 71 / 84rT ,1, / . N.ll, f,40 60 80 100

EXT:12/0 Sc10.6

1

11/

,1120 140

a74t

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nro6

il

726in .

-100

-0

SflMPLE SPECTRUM <UNflLTERED>File >DBpk flb

•

4000

7806 91L3551-10R 25ML/1ML EXT:12/0 Sc6671. 10.6

1

75 1/1140 J 55 71 f 84

40 ' 60 80 ' 100 ' 120 ' 140

a74(

ntt6

,11

726lin .

[-100

•


Compound No: 12Compound Name: 1,2-DichlorobenzeneScan Number: 726Retention Time: lp.67 min.Quant Ion: 146.0Area: 18310Concentration: 125.28 UG/Lq-value: 86

A-R203I90

REFERENCE STflNDflRD SPECTRUMFile >B7941 d8-NaphthaleneBpk flb 85872.

-

50000 52i 42 v- / \ f40

54 68 7i I • 1 . 1 i

60

910925SUB

106 ..fta82 88 94 v J 08

1 I H ' l - i i (-I . M 1 | 1 1 1 1 i i i80 100

09:20 Scan 112014.72 min.

136^ -100

128i . l . . .'P| I'M -fl129

SflMPLE SPECTRUM <BflCKGROUND SUBTRP.CTED)File >D7806 91L3551-10RBpk flb 190017.

200000-

" 42 52

40

54 66 76

60

25ML/1MLSUB

78 90 106

80 100

EXT:12/0 Scan 103713.90 min.

136r -100

198 130 :rr....,...VM*120

SflMPLE SPECTRUM <UNflLTERED>File >D7806 91L3551-10RBpk flb 190017.

200000-

" 42 52

40

J.4 66 761 . . .....i.i . . . , .

69

25ML/1ML

78 90

/. \ /'80

EXT:12/0 Scan 103713.90 min.

136' -100

106 108 139 ;... .\l. >.,.!, 1. 10

100 120


Compound No: 18 (ISTD)Compound Name: d8-NaphthaleneScan Number: 1037Retention Time: 13.90 min. ,Quant Ion: 136.0Area: 516178Concentration: 40.00 UG/Lq-value: 94

AR203I9I

•.iOREFERENCE STflNDflRD SPECTRUMFile >B7941 Ni trobenzene-d5 910925 09:20 Scan 923Bpk flb 40856. SUB 12.67 min.

8240000-

J42 5*

r-H —— 1 1 ''!'40

54

64 70 ?7\ { /

,., i ; . i . i i . 1 . . . 1 1 1 t .

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93 98 11S\ ' /\ .1. f ,. .t \ i i i i t i f i r 'i i f i i i | i i i i i i i i • i i i i i i i i i i i

60 80 109 129

-100

-0

SflMPLE SPECTRUM <BflCKSROUND SUBTRflCTED)File >DBpk flb

100000-

0-

7806 91L3553105312.

i

42 50

, i-rl.rM.40

.-10R 25MLSUB

S54

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./1ML EXT:12/0 Sea11.87

32

1

..(. T60 80 130 120

nm

2!(

841in .

-100J

SflMPLE SPECTRUM <UNflLTERED>File >0Bpk flb

100000-

0-

7806 91L3553105312.

i

42 50.,>,.. N.I.40

L-10R 25ML

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64 70 ?6

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32/

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nin

2!

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841in .

-1001

-0


Compound No: 19Compound Name: Nitrobenzene-d5Scan Number: 841Retention Time: 11.87 min.Quant Ion: 82.0Area: 295014Concentration: 2015.87 UG/Lq-value: 95

AR203I92

REFERENCE STflNDflRD SPECTRUM__________________________________________ r -^^ '-L- QFile >B7941 d!0-flcenaphthene 910925 09:20 Scan 1651

Bpk flb 44083.

40000--

0J

SUB 20.24 min.164

42 54 66 <=8 ./ 92 10 f8 ±22 132 138 1\

i r n . . i - 1 ' h i . i-i'hi.-iN'l' 1 1 t I'l'l i i 1 M M i i i i 1 i 1 i i i rl'i"!1!1! i i 1 i i i"!'!'-1

x

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-100

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L040 60 80 109 120 140 160

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >DBpk flb

100000-

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7806 91L3551-10R 25ML/1ML . EXT:12/0 Sc<96312. SUB 19. C

1

42 54 66 76 /0 90 100 ^ 122 132 14 156..'. .,(... l, .>l.Ji... ..'.,. ./,.. ./.. . / ../,,. N. i.l,40 ' 60 ' 80 ' 100 ' 120 ' 140 ' i(

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rl00

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SflMPLE SPECTRUM CUNflLTERED)File >D7806 91L3551-19R 25ML/1ML EXT:12/9 Scan 1564Bpk flb 96312. 19.39 min.

164100000-

£•

42 54 66 76 80 90 100 188 lgg 13£ 146 ±56..f. .,/... ., .>!.„! i..../. .../...../.. . / ../,.,. N. .1,

>x

1 1 1.

-100

-a40 60 80 100 120 140 160


Compound No: 33 (ISTD)Compound Name: dlO-AcenaphtheneScan Number: 1564Retention Time: 19.39 min.Quant Ion: 164.0Area: 283699Concentration: 40.00 UG/Lq-value: 93

AR203I93

REFERENCE STflNDflRD SPECTRUM " "'File >B7941Bpk flb 93144

100000-

0- . i , i ,.

39

40

2-Fluorobiphenyl•

51 63' • I ' l l iVl'l'l'il'l''1

60

76 85

'I'l'l I'l'i 'I'l'i30

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94l"i'l I'l'l i100

910925 09:20

120107 v 125

120

133

140

146

I'h-f'l'l

Scan 145918.24 min.

172"

157 -Allt,4

-100

n

169

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >D7806 91L3551-10RBpk flb 174273.

100000 39: / 51&.S.. .. .,{. .. i .... i ...40

63 75 85. .../. .....„'.. ,...u....,....,....,....,

60 30

25ML/1MLSUB

99 120v 107 v 125

100 120

EXT

133

"l49

:12/0 Scan 137617.43 min.

172" -100

^Jf3 :.,. .H\fC..,. ..ill 1. -p

169

SflMPLE SPECTRUM <UNflLTERED)File >D7806 91L3551-10RBpk flb 174273.

100000: 39: y 51 63 75 85

40 60 80

25ML/1ML

99 120N. 107 v 12S

100 120

EXT:12/0 Scan 137617.43 min.

172^ -100

i ™ 151 '

140 ' 160


Compound No: 38Compound Name: 2-FluorobiphenylScan Number: 1376Retention Time: 17.43 min.Quant Ion: 172.0Area: 451163Concentration: 1928.72 UG/Lq-value: 92

AR203I9U

REFERENCE STflNDflRD SPECTRUMFile >BBpk flb

50000-

7941 d!0-Phenanthrene 910925 09:20 Scan74056. SUB 24.82

188

42 ^ 66 88 94^ 100 US 130 132 146 ±^ -

| l i i i | I M i | I'l'l i f i l ' l ' / h I'l'l 1 iifl l l l | M i l | III i |l'Ni'|li li|'l I'l'l'/'iul |iil'/'|'l'M40 60 30 100 120 140 160 180

ctt\091in .

-100

u.

SflMPLE SPECTRUM (BRCKGROUNO SUBTRflCTED)File >D7806 91L3551-10RBpk flb 129056.

100000-

0-42t

40

j>2 66 30

60 80

25ML/1ML EXT.-12/0 Scan 2002SUB

94 118 130 132 146 3 0

.!7l .f., .... . . \ . . .-... . t ..i.i/100 ' 120 ' 140 ' 160

23.95 min.188^

178. {. ....U|t

H00

•-8

180


100000-

0-42 /2 66 80 94

40 60 80

25ML/1ML

-M 118 130 132100 v \ // \ N f i

. i j" i'i i [ I -i i i j i i'i i j'i i f i | i i i100 120 140

EXT:12/0 Scan 200223.95 min.

188^ 1-100

•

/* ?•!« :C, , r »'{•.. . . i rC,-, , j-r'k'1 'j -0

160 180


Compound No: 54 (ISTD)Compound Name: dlO-PhenanthreneScan Number: 2002Retention Time: 23.95 min.Quant Ion: 188.0Area: 407125Concentration: 40.00 UG/Lq-value: 99

AR203195

REFERENCE STflNDflRD SPECTRUMFile >B7941Bpk flb 21200

20000-•- 37

0-''l it1,40

2,4,6-Tribromophenol•

J2 141^ 91 111 fi / { y

80 120

SUB

172 i9J 220.ft d4 |> >

160 200

910925 09:20

222 250

)fcl 't1c!40 280

Scan 189222.75 min.

330

""ll "190

393 ill.• . • M JlUk — fl

320

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)FileBpk

>D7806 91L3551-10Rflb 29872.

62

•

20000-

0-

37

i. J 1L,...40 80

25MLX1MLSUB

91

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197\

220 J. 11,200

EXT:12x0 Scan 180621

•?* £;0 301£40 280

.91 min.332

1-100

•

-f)320

SflMPLE SPECTRUM <UNflLTERED>File >D7806 91L3551-10R 25ML/1ML EXT:12/0 Scan 1806Bpk flb 29872. 21.91 min.

62Z- 332

20000-

^37

rTj 1/3 197 222L.U.I ..!.... i .. N ST" 2r 3/ai ti-180

.

-040 ' 80 ' 120 ' 160 ' 200 ' c!40 ' 280 ' 320

Data File: >D7806::A1 Quant Output File: AD7806::D2Name: 91L3551-10RMisc: 25ML/1ML EXT:12/04/91 (RS0381) BTL# 1Quant Time: 911206 13:23 Quant ID File: ID_BAD::QTInjected at: 911206 12:37 Last Calibration: 911122 08:43Compound No: 58Compound Name: 2,4,6-TribromophenolScan Number: 1806Retention Time: 21.91 min.Quant Ion: 330.0Area: 76440Concentration: 2876.30 UG/Lq-value: 80

AR2Q3I96

REFERENCE STflNDflRD SPECTRUM ___________________ i, 7File >B7941Bpk flb 75899.

50000-

52/

fr-T' I'"-1 i140

d!2-Chrysene

66 90 106 120f ^ "^ ^Tii»|i | i|»i|i .iinflii,,,!,,^! .|lli,||ll| ,,|i

80 120

SUB

126 154 170/ \ \"'•i I • i"M"| VI •

160

910925

182 1/4:/ /HrwSS?

09:20 Scan 289533.18 min.

240"" -100

212 _i41 :.tl/|...|..l.i.|.4<lH-A-0

240

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7806 91L3551-10RBpk flb 44848.

40000-

: 52 66 9 10i1 * *" *" 1 * ' ' I ' ' ' 1 '40 80

25ML/1MLSUB

1/1813215< 168180...Jl.. ' .. V ./ /:.120 160

EXT

194

200

:12/0 Scan 280132.26 min.

240""" -100

208 241 ;

..., ...-r-jjl., , , 10. . 1 . . i 1 . i • -

240

SflMPLE SPECTRUM (UNflLTERED)File >D7806Bpk flb 44348

40000-

529- /40

91L3551-10R.

66 ™ 10t./ .. \u ,J

1 • ' 'eV

25ML/1ML

118 156/ 13£ x 168180-..Jl. . / . . > . .f ?..120 160

EXT

194/ i200

S12/0 Scan 280132.26 min.

240" -100

208 241 ;

/ . .....LI. 10240


Compound No: 66 (ISTD)Compound Name: d!2-ChryseneScan Number: 2801Retention Time: 32.26 min.Quant Ion: 240.0Area: 170904Concentration: 40.00 UG/Lq-value: 93

AB203I97

REFERENCE STflNDflRD SPECTRUMFile >B7941 Terpheny l-d!4Bpk flb 110832.

1000001

SUB910925 09:20 Scan 2591

30.02 min.244"

• 54 _ 106 ..p? 136 .,,- 198 212 nnf\ 66 80 94 . s 122 160 174 ^ v 226

40 80 120 It

-100

|— , — , — r— f— i — r— > — | — r— « — i — pi — i — i""f"-r «»0 208 240

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7806 91L3551-10RBpk flb 107744.

1000001

- 54• v 66

40

88 92

80

25ML/1ML EXT:12/SUB

y6 322 36

120

160 174 1tJ 212

I 60 ' 200

0 Scan 250229 .15 min .

244" -100

226

240


100000-

. V 66 80 92

40 80

25ML/1ML EXT:12/9

106 122 136 160 ±?4 198 £12.rf .....l .,.r .,{.. .. f ..__>_ i...

120 160 200

Scan 258229.15 min.

244^ -100

226/ i | 'ft

240

Data File: >D7806::A1 Quant Output File: AD7806::D2Name: 91L3551-10RMisc: 25ML/1ML EXT:12/04/91 (RS03U1) BTL# 1Quant Time: 911206 13:23 Quant ID File: ID_BAD::QTInjected at: 911206 12:37 Last Calibration: 911122 08:43

Compound No: 69Compound Name: Terphenyl-dl4Scan Number: 2502Retention Time: 29.15 min.Quant Ion: 244.0Area: 345232Concentration: 2439.64 UG/Lq-value: 87

AR203I98

REFERENCE STflNDflRD SPECTRUMFile >B7941 Bis<2-E thy Ihexy DPhthalateBpk flb 66584. SUB

149_

'

40000

•

»v.

57 7< 1 •}*>r 1 o~ 1 1 'a i<3c^ - , / W^ iiw w

167

l ,. I.40 30 120 160

910925 09:20 Scan 295233.77 min.

261 279.N. ~i

-100

•

-ct200 240 288

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7806Bpk flb 4313

4000-• 57- ^ ^

alill.40

91L3551-10R.

. ^ 83 104ll ill , rf . I ,.

80 120

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149^

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-100

.,..,... , ........... ,u200 240 280

SfiMPLE SPECTRUM <UNflLTERED)File >DBpk flb

4000-

0-

7806 91L3551-10R 2E4313.

149,

57 71^ 7/ 83 194

,11. ll ,lt, if . { „

5ML/1ML EXT:12/9 Scan E32.94 n

167*"x

140 ' 80 ' 120 ' 160 ' 200 ' 240 ' 28

866in .

-100

-00


Compound No: 73Compound Name: Bis(2-Ethylhexyl)PhthalateScan Number: 2866Retention Time: 32.94 min.Quant Ion: 149.0Area: 14036Concentration: 106.32 UG/Lq-value: 86

AR203I99

REFERENCE STflNDfiRD SPECTRUMFile >B7941Bpk flb 72040.

80000-

40000-

0-, . , , ,

42

40

d!2-Perylene

9066 v 104'/' i"i -"'i' i n1 i

80

118/

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SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7806Bpk flb 14147

-10000-: 42^x

40" ' '

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9066 v 1041 II II ' !•

80

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132

Jl160

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264" -100

,_ 228 232r\s .!..•„200 240

SflMPLE SPECTRUM <UNP.LTERED>File >D7806Bpk flb 1414'

10000-'. 44

40

91L3551-10R 25ML/1ML? ,

u \ - "'j?880 120 160

EXT:12/0 Scan 320336.44 min.

264^ [-100

r™7 ,.,.L200 240


Compound No: 75 (ISTD)Compound Name: d!2-PeryleneScan Number: 3203Retention Time: 36.44 min.Quant Ion: 264.0Area: 73110Concentration: 40.00 UG/Lq-value: 94

AR203200

• SAMPLE INTEGRATION SUMMARY r "•

SAMPLE NAME AND AMI: 91L3551-10R ; 25ML/1MLSAMPLE DATA FILE: -.-07806 !

PEAK NO. RET. TIME SCAN ! AREA IDENTIFICATION1 5.77 255 I 145751 . UK2 6.74 349 ! 1247043 SS3 9.55 619 : 1408244 SS4 10.09 - 670 ! 942886 IS5 10.67 726 ! 76010 TC6 11.87 841 ' : 943729 SS

13.90 1037 : 1157576 IS

8 17.43 1376 ; 1408512 SS9 17.68 1400 ; 2392170 UK10 18.12 1442 5401051 UK11 19.39 1564 I 1272010 IS

12 21.91 1806 : 1004810 SS13 23.95 2002 1107887 IS

14 29.15 2502 : 1028318 SS15 32.27 2802 558924 IS

16 36.44 3203 . 230177 IS

IS = INTERNAL STANDARD '.SS = SURROGATETC - TARGET COMPOUND '.UK = UNKNOUIN ' •<10X = UNKNOUN LESS THEN 109. OF INTERNAL STANDARD

AR20320I

File >D

1200000:

00000:

1000000-

900000:

800000-

700000

6QOOO<>

500000-

4QQQO<>

300000-

200000-

100000-

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32 36 40 44

AR203202

File >07S06 91L3551-10R 25ML.--1ML EXT : 12''04/91 'BcaBpk flb 18243. SUB , 5.77

! 11, 7 7 ' , , . ' •1 =il ' > 1J 33 4Q }. 56 61 73 \ 35 36

• 40 50 60 70 ' 30

File i-BIGDB Benzene, chloro- (8CI9CIBpk Rb 9999.

1 7733 43 51 56 61 -,-, / ft4 gJ.rT. . -^.>{....rf. .^. •>•..,.. .. "^rt-r

40 ' 50 ' 60 ' 70 ' 80

File >BH3DB Benzovl chloride <DOTX8C!Bpk flb 9999.

1 51 .7j 37 43 / 57 g,2 72 79 S

Q| i ' I " " I ' ' ' ' I ' ' ' ' I " " I ' ' ' ' I ' ' " I ' " ' l ' ' ' ' l " " l "40 50 60 70 80

90 ''' 100 110

•; ! Scan: 0.00

11/i i

5 97 103•-"' : " ~:

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: f6 96 97 111•... >.-*•!. .....A.90 100 110

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10883min .

1 in

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-HÔ

1. Benzene, chloro- (8CI9CI) 112 C6H5C12. Benzoyl chloride (DOT)(8CI9CI) ', 140 C7H5C10

Sample file: >D7806 Spectrum #: 255Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS * CON * ROOT K DK #FLG TILT % CON C_I R_IU

1. 59* 108907 10883 "BIGDB 45 49 0 -1 84 30 24 392. 25 98884 458 "BIGDB 56 39 2 0 80 47 7 19

i

CORRECTED TOTAL ION AREA OF UNKNOWN - 145751CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 942886CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR = 40SEMI QUANT I TAT I ON OF UNKNOWN =* 250UGXL

AR203203

File >07S06 91L3551-10R : 25t1L.'lML EXT :12.-'Q4''91 Scan 1400Bpk flb 228225. I ' 17.63 mm.

154

39 51 63 'fa 37: 89 102 115 128 139 151/ / / ''-| . ^ / l -v. --„ "---

•I'l'i'i i I'l'i'i'i i i'1'l'i i ) i'1'l'l | i i'i'lV' i I'l'l'l1' ' I'l'l'l1' ' I'l'i'l'l'i i i i'1'l i i i i'|40 60 80 • 100 120 140 160

172, ,'7TiL0

File '8IGDB 1,1 '-B ipheny 1 <9CO Scan 17935Bpk flb 9999. , _ 0.00 mm.

51 63 76 78- S9 1Q2 115 i£6 139 151

154

156

60 80 : 100 120 140 160

File >BIGDB Naphthalene, 2-ethenyl- <9C!> Scan 17944Bpk Hb 9999. • 0.00 min.

40 60 80 : 100 120 140 160

Fil« >BISDB flcenaphthene <3CI> Scan 17933Bpk flb 9999. i 0.00 min.

154

39 51 63 '. 37: 9g log 115 126 139 157

40 60 80 ' 100 120 140 160

1. 1,1'-Biphenyl (9CI) 154 C12H102. Naphthalene, 2-ethenyl- (9CI) 154 C12H103. Acenaphthene (SCI) 154 C12H104. 1,4-Ethenonaphthalene, 1,4-dihydro- C8CI9CI) 154C12H105. 2-Quinolinecarbonitrile (9CI) 154C10H6N2

Sample file: >D7806 '• Spectrum #: 1400Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS # CON * ROOT K DK #FLG TILT 96 CON C_I R_IU

1. 94* 92524 17935 "BIGDB 79 26 0 0 76 17 60 942. 86* 827543 17944 "BIGDB 71 30 1 0 76 9 59 71J. 63* 83329 17933 "BIGDB 60 45 1 1 52 34 22 484. 35* 7322476 17956 "BIGDB 36 56 0 1 33 50 11 325. 31* 1436437 17947 "BIGDB 24 38 2 0 69 34 12 14

CORRECTED TOTAL ION AREA OF UNKNOWN - 2392170CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 12720JJ$R 2 0 3 2 0 kCONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR - 40SEMI QUANTI TATION OF UNKNOWN * 3000UG/L

File ,--07806 91L3551-10R 25ML/1ML EXT: 12/04/91 Scan 1442Bpk flb 227585. SUB ; 13.12 min.

I f -

- 39'. I

t - 1^ ' '40

File -.>BI6DBBpk fib 9999

• 39

40

File >BI8DBBpk ftb 9999

1"O-WfTH40

File >BI8DBBpk flb 9999

• 39

40

51 __ 1-fl65 --. 73 94 102 !15 128 139 [ ; 155

-T-r-jlTM I'l'lil'll'i'l'l IV I'l'l ri'i'i > I'l'i'i i \ i'|l|'i | i I'M!', i i77i|l|'i i'i i'1'iM i | i i i |l| ii ,60 30 100 ISO 140 : 160

-0

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170

51 77 . 141/ 65 "-_ 85 94 102 115 1£9 139 --": 154

. .,,.., .....>,„„....,.,,. ./.........'.. ....,''. ..L... ":-.... .ll,. ...«C. i.60 ' 'so ' ' ' ' 'ioo ' ' ' 'iab ' ' '140 : ' i6o

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141--. 168

115 13q i '51 63 74 34 39 iQ2 / 127 -^ i 155n •!<•: .. '' n ,.rT' . .' ,,', f Jill, f ,ii

60 ' 80 ' 100 ' 120 • ' 140 ' ' 160

Cl,l'-Biphefiyl.-£-ol C9CI) , Scan 20293. 0 .00 min .: 170

115 14151 63 71 37 39 102 , 126 139 _-- 155

..{.... ./.. ...f ..... ..-'" ./ ..i, :' .!i.. ' .... / it.60 ' 80 ' 100 ' 120 ' 140 ' ' 160

I

1. Benzene, l,l'-oxybis- (9CI)2. lH,3H-Naphtho[l,8-cd]pyran C8CI9CI)

170 C12H100170 C12H100

3. [1,1'-Biphenyl3-2-ol (9CI) • 170 C12H100

Sample file: >D7806 Spectrum #: 1442Search speed: 1 Tilting option: S :No. of ion ranges searched: 55

Prob. CAS # CON # . ROOT K : DK #FLG TILT % CON C_I R_IU

1. 64* 101848 20296 "BIGDB 58 ' 48 1 1 66 25 28 422. 15* 203849 15988 "BIGDB 39 69 2 0 51 60 3 14J. 11* 90437 20293 "BIGDB 31 ,'60 2 0 38 61 2 15

CORRECTED TOTAL ION AREA OF UNKNOWN = 5401051CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 1272010CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR = 40SEMI QUANT I TAT I ON OF UNKNOWN = 6800UG/L

AR203205

w J

911-3551-11 Sample Data Package

AR203206

UUHNT RhPURT ;

Up e rat or 1U: MALUS Uuant Kev: 6 ! Quant Time: 911119 2U:4/'Output F i l e : "Cl'JUB : : D2 . ; Injected at: 911119 20: U^Data F i l e : >C1508::D1 Dilution Factor: l . U U O U UName: 91L-31?1? 1-11 " !Hisc: "? ML !

ID Fi Is: I U_ULL: : 111 ( ' ' !T i t l e : HP UUA Standards For _> Point Calibration Curve Rev. £Last C a l i b r a t i o n : 911119 13:18 !

Compound R.T. Scahtt Area Cone Units q'

1; *Bromochloromethane 3.50 104 24017 50.OU ug/L 749.1 Acetone 5.«7 70 4223 38.05 ug/L V216; 1,2-Dichloroethane-d4 11.43 142 50151 54.56 ug/L 96•J5; *1 ,4-Di f luorobenzene 19.07 241 105352 •? U. U'G ug/L 6V33J *Ch lorobenzene-d_> 24.09 3136 82358 50.00 ug/L V339 J Toluene-d8 '22. B5 290 120038 49.4.7 ug/l_ V U4bJ Bromof luorobenzene 28.41 362 80178 47.73 ug/L 81?

* Compound ts 1STD

fl«203207

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Data File: >C1508:iDl Quant Output File: "C15Q8::02Name: 91L-3551-11Misc: 5ML :

Id File: ID_vCC::QTT i t l e : HP UOA Standards for 5 Point Calibration Curve Rev. ZLast Calibration: 911119 13:18

Operator ID: MALOS' •. tQuant Time: 911119 20:47Injected at: 911119 20:02

AR203208

r. c. r c. r. c. li L c. bFile '--VXNSri,- P k ^ b ICO

100J

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Data File: >C1508::Dl Quant Output File: 'SC1508::U2Name: 91L-3551-11 •Misc: 5ML [Quant Time: 911119 20:47 Quant ID File: ID_UCC::QTInjected at: 911119 2G:02 Last Calibration: 911119 13:18

Compound No: 1 (ISTDJ iCompound Name: BromochloromethaneScan Number: 104 ;Retention Time: 8.50 mm. ,Quant Ion: 128.0Area: 24017 ,Concentration: 50.00 ug/Lq-value: 74

AR203209

REFERENCE STRNOaRO SFECTRuH>• i i e • H vct r. HCCr> _ i . o i- £ fi •»U1 .' f n u1 * -i O J. *

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SflMPLE SPECTRUM <UNRLTERED>File >C1508Bpk flb 1105.

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Data File: >C1508:':D1 Quant Output File: ~C1508::D2Name: 91L-3551-11 ;Misc: 5MLQuant Time: 911119 20:47 Quant ID File: 1D_UCC::QTInjected at: 911119 20:02 Last Calibration: 911119 13:18

Compound No: 9 \Compound Name: HcetoneBean Number: 70! . .Retention Time: !5.87 mm.Quant Ion: 43.0 :Area: 4223 ;Concentration: 38.05 ug/Lq-value: 92 ;

AR2032IO

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50 i

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69 • « i?a :. .(^ ' \ f.l....ni . i i i . i . | .... | . . . , , . . . . , i , i i , .... | .,..,.... , . ... t .... f .... t .... t ......

4g 50 60 70 80 90 100————— - —— - —— - ————————————————————————————————————————————————————

Data I-lie: >C1508::D1 Quant Output File: /-C1508::D2Name: 91L-3551-11 iMisc: 5ML \Quant Time: 911119 20:47 Quant ID File: ID_UCC::QTInjected at: 91111? 20:02 Last Calibration: 911119 13:18

Compound No: 16Compound Name: 1/2-Dich1oroethane-d4 ;Scan Number: 142Retention Time: 11.43 mm. ,•Quan t Ion: ' 65.0Area: 50151 \Concentration: 54.56 ug/Lq-va1ue: 96 ,

&R2Q32II

N C£ 3 TmS'ui-in C 3FcC TRLmr i i e •VXNSr- HP V-JH No Spike' Internal Standards and Su Scan 5 £5 ir~i _ , i~i L. 1 .-, n '• r. i r, *,,", **' **> •* "' •• • •« 'L.> )_' N n >-> .1. _• *• . ' •_ l_ I It t\ I , t- J. • -' U Ml 1 I , • I

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Uata File: >C1508::D1 Quant Output File: /XC15U8::D2Name: 91L-3551-11Mis c: 5 MLQuant Time: 911119 20:47 Quant ID File: ID_u'CC::QTInjected at: 911119 20:02 Last Calibration: 911119 13:IB

Compound No: 23 USTD)Compound Name: 1 ,4-DifluorobenzeneScan Number: 241Retention Time: 19.07 mm.Quant Ion: 114.0Area: 105352Concentration: 50.00 ug/Lq-value : 69

AR2032I2

.rCrERENC£ oTfiNDflRD SPECTRUMFile ••VXNSP HP VUH No Spike Internal Standards and on Scan 660Spk fib 100. CLP NRK ; SC.C4 ,-.-,in.

i 117

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Data File: >C1508::D1 Quant Output File: 'NC15U8::D2Name: 91L-3551-11 ',Misc: 5ML '..Quant Time: 911119 20:47 Quant; ID File: ID_UCC::QTInjected at: 911119 20:02 Last Calibration: 911119 13:lB

Compound No: 33 (ISTD)Compound Name: ChIorobenzene-d5Scan Number: 306Retention Time: 24.09 mm.Quant Ion: 117.0 ']Area: 82358 ,Concentration: 50.00 ug/Lq-value: 93 '

AR2032I3

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SflMPLE SPECTRUM <UNflLTERED>File >CBpk flb

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1508 91L-3551-11 5f1L Sc'an3977. 22.85 w

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4<i 44 K~, 1,4 62 ,-. 70 76 78 8£x^ / 52 °^ , 66 , . . 99 94

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Data File: >C15uS::Dl Quant Output File: ~C1508::D2Name: 91L-3551-11Misc: 5MLQuant Time: 911119 20:47 Quant ID File: ID_UCC::QTInjected at: 911119 20:02 Last Calibration: 911119 13:18

Compound No: 39Compound Name: Toluene-d8Scan Number: 290 iRetention Time: 22.85 mm.Quant Ion: 98.0Area: 120038Concentration: 49.47 ug/Lq-value: 90

AR2032U

r* -. ~« - u

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80 100 120 140 160 . 1.30 200

Rpriimo SIIRTROCTEO> i91L-3551-11 5ML i Scan 362

Slip . ; 28.41 min.95 i{ \ 1-1 00

87\ - - - ,

174 ).118 141 143 f, 207 [

1'Jb / \ / • lfe3 \ t,.,.,. i. ,,lli . :' . :' " ;' '. Id, I.Ln80 100 120 140 160 180 200

SflMPLE SPECTRUM CUNflLTERED) . . jFile >C1508Bpk fib 4226.

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Data File: >C1508::D1 Quant Output File: /SC1508::D2Name: 91L-3551-11 'Misc: 5ML sQuant Time: 911119 20:47 Quant ID File: ID_UCC::QTInjected at: 911119 20:02 Last Calibration: 911119 13:18

i

Compound No: 45 ]Compound Name: Bromof1uorobenzeneScan Number: 362 . •Retention Time: 28.41 mm. 'Quant Ion: 95 ; 0Area: 80178Concentration: 47.73 ug'/Lq-value: 85

AR2032I5

SAMPLE INTEGRATION SUMMARY

SAMPLE NAME AND AMT: 91L-3551-11 5MLSAMPLE DATA FILE: >C1508

PEAK NO. RET. TIME SCAN AREA IDENTIFICATION1 5.87 70 6853 TC2 8.57 105 207268 IS3 11.43 142 150319 SS

4 16.68 210 5946 <10%5 19.07 241 285709 IS

6 22.85 290 337897 SS7 24.09 306 308138 IS8 26.79 341 4746 <10%9 28.41 362 372390 SS

IS = INTERNAL STANDARDSS = SURROGATETC = TARGET COMPOUNDUK = UNKNOWN<10% = UNKNOWN LESS THEN 10% OF INTERNAL STANDARD

AR2032I6

File >C1508 35.0-260.0 amu. 91L-3551-11 5MLSMT TIC

£2000-

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AR2032I7

GC/MS Tune and Mass Calibration Summary

AR2032I8

GC/MS PERFORMANCE STANDARD

Bromofluorobenzene (BFB)% Relative Abundance

Ion Abundance Base Appropriatem/z Criteria ., Peak Peak Status

_ ——. ___ ——— ——. »________,___________..--....-.--..___«______._.____________.._,___«___..___._________ ——. --1 ._.«._- M. _» ™ _.. ™ ——— —————— ——— ——,._,•——•._.•. ——.-». «.———.-, ___ «

50 15-40% of mass 95 21.33 21.33 Ok75 30-60% of mass 95 49.23 49.23 Ok95 Base peak, 100% relative abundance 100.00 100.00 Ok96 5-9% of mass 95 7.11 7.11 Ok173 Less than 2% of mass 174 0.00 0.00 Ok174 Greater than 50% of mass 95 65.62 65.62 Ok175 5-9% of mass 174 5.85 8.92 Ok176 95-101% of mass 174 62.74 95.61 Ok177 5-9% of mass 176 3.87 6.17 Ok

Injection Date: 11/19/91Injection Time: 13:20

Data File: >C1500Scan: 93

>C1500 BFB SONG93 NRM

File: >C1500 Scan #: 93 Retn. time: 7.64

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.. 7.00 6.661 48.90 3.510 70.10 2.160 80.10 1.620 96.00 7.11138.10 6.031 50.10 21.332 74.10 19.802 80.90 5.581 128.00 1.35040.00 62.286 51.10 6.391 75.10 49.235 86.00 1.440141.00 1.17041.00 1.710 55.20 2.880 75.70 3.420 87.00 6.931 174.00 65.61743.10 6.301 57.10 7.111 76.00 3.780 88.00 10.441 174.90 5.85144.10 31.683 62.00 4.680 77.30 1.530 93.00 3.690 176.00 62.73645.10 8.371 68.00 9.721 78.80 3.780 94.00 12.331 177.00 3.87047.10 1.620 69.10 10.711 79.00 3.780 95.00 100.000

AR203219

File >C1500 35.0-260.0 anm.TIC

6000-

4000-/ \

•49; \2900-

1-20

-199

-80

6.0 7.9 3.9 9.9 10.0

File >C1509 BFB 50NS Scan 93Bpk flb 100. NRI1 7.64 min.

1 95100- •"" -199

80- 40 174 -88X' '60- 75 -60

40- -48

29- 57 9 98 12{J -28

^ . l l . . I .( l ll. uiJ .ll ill .............../ .../............... ''..i • • • • i • • • • i • • • • i • • • • i • i < i | i i < ' | i i ' ' |i i > .i....|....|....| ....|....|....|40 69 89 199 128 149 169 189

AR203220

GC/MS PERFORMANCE STANDARD r-« ,i o < Bromofluorobenzene (BFB)

% Relative AbundanceIon Abundance Base Appropriate

m/z Criteria Peak Peak Status50 15-40% of mass 95 ! 26.84 26.84 Ok75 30-60% of mass 95 59.42 59.42 Ok95 Base peak, 100% relative abundance 100.00 100.00 Ok96 5-9% of mass 95 7.12 7.12 Ok173 Less than 2% of mass 174 0.00 0.00 Ok174 Greater than 50% of mass 95 67.49 67.49 Ok175 5-9% of mass 174 5.36 7.94 Ok176 95-101% of mass 174 64.15 95.05 Ok177 5-9% of mass 176 4.10 6.39 Ok

Injection Date: 11/26/91Infection Time: 08:36

Data File: >A3732Scan: 175

>A3732 BFB SONG175 SUB NRM

File: >A3732 Scan #: 175 Retn. time: 7.25m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.36.00 1.134 58.00 .126 71.15 1.071 81.05 5.608 96.15 7.12037.10 7.120 59.95 2.079 73.15 7.372 87.05 2.331 174.05 67.48638.10 6.427 61.15 4.978 74.15 21.739 88.05 2.268175.15 5.35639.10 2.836 62.15 5.923 75.15 59.420 92.15 3.340 176.05 64.14649.10 5.104 63.15 6.427 76.15 5.167 93.15 5.545 177.10 4.09650.10 26.843 68.15 14.178 77.05 .567 94.15 11.153 207.20 3.65551.10 7.057 69.15 13.296 79.05 4.663 95.15 100.000 208.30 2.14257.10 2.773 70.15 1.638

AR20322I

Filt >fl

10000

8009;

6009;

4009

2000-

4

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3732 35.9-266

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1 i189 ' 298

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-88

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-100

-88

-68

-48

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BR203222

GC/MS PERFORMANCE STANDARD r , ,


Ion Abundance Base Appropriatem/z Criteria ; Peak Peak Status50 15-40% of mass 95 24.81 24.81 Ok75 30-60% of mass 95 50.71 50.71 Ok95 Base peak, 100% relative abundance 100.00 100.00 Ok96 5-9% of mass 95 8.83 8.83 Ok173 Less than 2% of mass 174 0.00 0.00 Ok174 Greater than 50% of mass 95 60.37 60.37 Ok175 5-9% of mass 174 4.33 7.17 Ok176 95-101% of mass 174 59.20 98.07 Ok177 5-9% of mass 176 5.08 8.58 Ok



>C1612 BFB SONG89 SUB NRM

File: >C1612 Scan #: 89 Retn. time: 7.34m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

37.10 7.910 60.10 .333 73.10 4.580 86.00 2.082 96.00 8.82638.10 6.661 60.40 1.332 74.00 17.402 86.90 6.495 101.80 1.74938.80 4.413 62.00 3.664 75.00 50.708 88.10 4.246 119.10 2.58141.10 2.082 63.10 4.163 78.40 2.082 92.20 3.081 174.00 60.36647.70 .999 67.30 2.165 78.90 2.748 93.00 3.997 175.00 4.33049.10 5.079 68.10 11.324 80.80 4.496 94.00 12.490 176.00 59.20150.10 24.813 69.00 9.992 81.80 1.332 95.10 100.000 177.00 5.07951.10 6.994 70.10 1.665 83.10 2.415

AR203223

File >C1612 35.0-260.0 amu. BFB 50NSTIC

_

6009-

4000-

-2000-

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File >C1612Bpk flb 1201.

1200-

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-49

-9.0

Scan 897.34 min.

'*

177

188 289 2.

-199

-89

-69

•49

-29

•8>8

AR20322U

GC/MS PERFORMANCE STANDARD ., , , _1 . 5*8Bromofluorobenzene (BFB)% Relative Abundance

Ion Abundance Base Appropriatem/z Criteria Peak Peak Status50 15-40% of mass 95 22.97 22.97 Ok75 30-60% of mass 95 56.44 56.44 Ok95 Base peak, 100% relative abundance 100.00 100.00 Ok96 5-9% of mass 95 7.71 7.71 Ok173 Less than 2% of mass 174 0.00 0.00 Ok174 Greater than 50% of mass 95 59.07 59.07 Ok175 5-9% of mass 174 3.31 5.60 Ok176 95-101% of mass 174 57.29 96.99 Ok177 5-9% of mass 176 4.49 7.84 Ok



FMGR : NRM,100FMGR : TAB


File: >C1621 Scan #: 89 Retn. time: 7.33

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.37.10 7.034 51.10 9.237 68.10 7.881 87.00 7.373 115.10 1.52538.10 6.186 55.10 2.712 69.00 11.949 88.10 9.407 141.00 5.25439.00 3.983 56.00 1.949 71.10 1.441 89.00 2.203 169.10 3.47540.00 52.542 57.00 9.576 73.00 9.576 93.10 3.898 170.10 4.49243.10 7.203 58.10 6.102 74.00 17.881 94.10 10.847 174.00 59.06844.10 32.966 59.80 1.017 75.10 56.441 95.00 100.000 175.00 3.30545.10 9.237 61.00 4.661 76.10 6.780 96.10 7.712 176.00 57.28849.10 3.898 62.00 3.729 78.80 2.881 103.00 1.864176.90 4.49250.00 22.966 63.00 3.220 80.70 3.983

FMGR : AL, Move cursor; then press carriage return :

AR203225

FiU >C1621 35.0-260.0 amu. BFB 59N6TIC

-199A

6009-

4000-

H492000-1

-29

-89

-69

L84'.0 ' 5'.9 ' 6^8 ' 7'.0 " 8'.0 ' 9l8 ' 19.8

File >C1621 BFB 59NG Scan 89Bpk flb 1189. 7.33 min.

951299- / -108

-88800-

-68

III

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1

59

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,

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7-

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489- / w'-28

.,..„,.-.. .,,,™r__ .™™ ,....,....,....,....,....,....,...!<48 68 88 198 129 148 168

AR203226

GC/MS PERFORMANCE STANDARD J '" "'


Ion Abundance Base Appropriatem/z Criteria Peak Peak Status50 15-40% of mass 95 15.24 15.24 Ok75 30-60% of mass 95 39.78 39.78 Ok95 Base peak, 100% relative abundance 100.00 100.00 Ok96 5-9% of mass 95 6.75 6.75 Ok173 Less than 2% of mass 174 0.00 0.00 Ok174 Greater than 50% of mass 95 73.52 73.52 Ok175 5-9% of mass 174 6.24 8.48 Ok176 95-101% of mass 174 71.27 96.94 Ok177 5-9% of mass 176 4.81 6.74 Ok




File: >C1636 Scan #: 87 Retn. time: 7.22m/z Int. m/z Int. m/z Int. m/z Int. m/z Int..9.10 5.010 50.00 15.235 70.70 1.125 76.90 2.658 94.10 10.22540.00 78.221 56.30 1.636 71.00 1.022 78.80 5.010 95.00 100.00040.90 2.045 57.10 5.726 71.80 1.022 79.00 5.112 96.00 6.74842.00 2.045 59.10 1.534 72.30 1.125 80.90 4.192 118.80 2.35243.10 10.634 62.00 4.601 73.00 6.339 87.00 6.442 173.90 73.51744.00 36.503 63.00 4.192 74.10 14.008 88.00 10.123 175.00 6.23745.00 12.577 68.10 9.407 75.10 39.775 89.00 4.192 175.90 71.26846.80 2.658 69.00 11.043 76.10 3.885 93.10 5.215 176.90 4.80649.00 5.726

AR203227

File >C163635.9-269.0 amu. B F B 5 0 N GTIC

-100M

6009

4000-1

-48I \2000-

1-28

5.0 6.0 7.0 8.0 9.0 10.0

File >C1636 BFB 50NG Scan 87Bpk flb 100. NRM 7.22 min.

1 9S109- """ -199

' ** 174 '80- p^ / -89

60- -6975

49- ' -49

.......... , , ,40 68 88 188 128 148 168 188

40

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AR203228

GC/MS PERFORMANCE STANDARD L,'i

Bromofluorobenzene (BFB)

% Relative AbundanceIon Abundance Base Appropriate

m/z Criteria Peak Peak Status

50 15-40% of mass 95 24.12 24.12 Ok75 30-60% of mass 95 43.05 43.05 Ok95 Base peak, 100% relative abundance 100.00 100.00 Ok96 5-9% of mass 95 7.27 7.27 Ok173 Less than 2% of mass 174 0.00 0.00 Ok174 Greater than 50% of mass 95 61.27 61.27 Ok175 5-9% of mass 174 4.82 7.87 Ok176 95-101% of mass 174 59.68 97.41 Ok177 5-9% of mass 176 4.82 8.08 Ok


Data File: >A3758Scan: 171

>A3758 BFB SONG171 SUB NRM

File: >A3758 Scan #: 171 Retn. time: 7.10m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

37.10 8.207 57.10 2.736 75.15 43.053 88.05 1.656 133.15 1.80038.10 6.551 61.15 .504 76.15 6.335 92.15 3.960174.05 61.26739.10 1.728 62.15 6.839 78.95 4.536 93.15 5.256 175.05 4.82449.10 5.256 63.15 4.968 80.15 2.016 94.15 14.471 176.05 59.68350.10 24.118 68.15 14.759 81.05 6.551 95.15 100.000 177.20 4.82451.10 6.839 73.15 4.320 87.05 1.656 96.15 7.271 207.20 6.55156.10 3.600 74.15 18.862

AR203229

File >fl375810009-

8089

6000--

4000-

2000- \_ j

4.0

File >fl3758Bpk flb 1389

-1200-

-

800--

499-

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59\

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35.0-260.0 amu. BFB 59NG

5

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95

75

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Scan 1717.10 min.

174

133

, N89 ' 199 ' 129 ' 149 ' 163

297

1 1

-199

-89

-69

•49

-29

-8188 ' 288

flR203230

GC/MS PERFORMANCE STANDARD- .1

Decaf luorot r ipheny Iphosp ihe CDFTPP) ->

9. Relative AbundanceIon Abundance : Base Appropriate

m/z C r i t e r i a : Peak Peak Status

51 30-60% of mass 198 \ 55.14 55.14 Ok68 Less than 29. of mass 69 ' 0.00 0.00 Ok69- (reference only) ! 72.16 • 72.16 Ok70 Less than 2X of mass 69 i ' 0.00 0.00 Ok127 40-609$ of mass 198 ; 43.81 43.81 Ok197 Less than 196 of mass 199 \ 0.00 0.00 Ok198 Base peak, 100?. relative abundance : 100.00 100.00 Ok199 5-9*1 of mass 198 6.39 6.39 Ok275 10-30* of mass 198 , 18.72 18.72 Ok365 Greater than IX of mass 198 1.40 1.40 Ok441 0-100H of mass 443 ; 7.42 75.37 Ok442 Greater than 40H of mass 198 : 56.17 56.17 Ok443 17-239. of mass 442 ( 9.84 17.52 Ok

Injection Date; 11/25/91Injection Time: 15:47

Data File: >B8496Scan: 331

AR20323I

Fil« >88496 35.0-500.0 *,nu. 30 NS DFTPP Il/a5.'91 PMTIC

320 324 323i i i120000-

~

80000-

-

40000-

332 336 340

/ \13.75

File >B8-96Bpk Rb 100

100-

80-

60-

40-

20-

;100

-80

60

L40

r20In

13.30 13.85 13.90 13.95 14.00

50 NS DFTPPNRM

198""

C.Q • !

(

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127/1 :1 167J....Y.1.,

H/25'91 PM Scan 33113.90 ruin.

442\

255206/

1 ill, L120 ' 160 ' 260 ' 240

275/ 296

. i f . 3/6a

-100

-80

-60

-40

-20

-o280 ' 320 ' 360 ' 400 ' 440

AR203232

>B8496 50 NG DFTPP 11/25/91 PM r, ° £331 • NRM Uw°

i l e : >B8496 Scan #: 331 Retn. time: 13.90

m/z Int. m/z Int. m/z Int. rn/z Int. m/z I nt.

39.10 4.869 83.00 .873 127.00 43.807 187.10 2.613 245.10 1.00640.00 1.299 86.00 .901 128.10 3.178 192.00 .747 246.10 1.22250.00 14.027 91.00 .950 129.00 19.134 193.00 .310 255.10 35.45951.00 55.138 92.00 .782 130.00 1. 446; 196.10 2.780 256.10 4.91852.00 2.627 93.00 4.869 135.00 1.460 198.00 100.000 258.10 1.68456.00 1.698 98.00 3.430 141.00 2.026' 199.00 6.392 273.10 1.20257.00 3.947 99.00 3.046 147.00 .922; 204.10 2.459 274.10 3.07463.10 2.061 101.00 1.809 148.00 2.019:205.10 3.898 275..10 18.72269.00 72.155 104.00 1.006 155.00 1.076206.10 17.024276.10 2.08274.00 4.219 105.00 1.076 156.10 1.481 207.10 2.103 277.10 1.17475.00 7.908 107.00 11.673 167.10 3.695. 217.00 4.450 296.10 3.75876.10 2.403 108.00 1.649 168.00 1.390 221.10 6.064 323.10 1.36977.10 48.774 110.00 32.448 175.10 1.271 223.00 .831 365.10 1.40478.10 3.151 111.00 4.233 179.00 2.620! 224.10 9.396 423.20 3.07479.00 3.360 117.00 7.342 180.10 1.705 225.10 2.187441.20 7.41930.00 2.731 122.00 .761 185.10 1.216 227.10 3.241 442.20 56.17281.00 3.716 123.00 1.299 186.16 9.983 244.10 7.775 443.20 9.84382.00 1.006

AR203233

GC/MS PERFORMANCE STANDARD . ° t

Decafluorotriphenylphospine t DFTPP)

9. R e l a t i v e RbundanceIon Abundance Base Appropriate

m/z C r i t e r i a Peak Peak Status

51 30-609. of rnass; 198 49.40 49.40 . Ok68 Less than 29. of mass 69 0.00 0.00 _ Ok69 Creference only) 66.72 66.72 Ok70 Less than 2* of mass 69 0.00 0.00 Ok127 40-60% of mass 198 44.15 44.15 Ok197 Less than 19. of mass 198 0.00 0.00 Ok198 Base peak, 1009. r e lative abundance 100.00 100.00 Ok199 5-99. of mass 198 6.40 6.40 Ok275 10-309. of mass 198 17.63 17.63 Ok365 Greater than 19. of mass 198 1.31 1.31 Ok441 0-1009. of mass; 443 6.75 74.48 Ok442 Greater than 409. of mass 198 50.73 50.73 Ok443 17-239. of mass; 442 9.06 17.87 Ok

'. Injection Date: 11/27/91Injection Time: 07:51

Data File: >88525Scan: 327

AR203231.

Fila >B8525

J

80000

BfeOOOO-

40000

2QOQC-

35.0-500.0 amu. 50_NS OFTPP 11/27/91316

TIC320 324 328 332 :336 340

f\13.70 1 O ~7K -1 O OH -1 OJ. J « i 3 XO.Ov J. w

File >B8525Bpk fib 100

100-

80-

60-

40-

20-

0-

50 N6 DFTPPNRM

193"

69

t ,\ j

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It. 1 ll.lldo '

127t

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167

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11/27/91 , Scan 32713 .85 min .

442\

255?n&CUD

/

J uL lI 1 ' 1 ' 1 ' 1 ' 1 ' 1

120 160 200 240

/275

296 ;

xx • 36?It S f . . 1i • i • i • l • l • i • i * i • i • i280 320 360 400 44

-100

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-00

AR203235

>B8525 50 NG DFTPP 11/27/91327 NRM r r*.~

u ~ CJ

'ile: >B8525 Scan ft: : 327 Retn. time: 13.85

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

39.00 4.123 82.00 .894 128.10 3.424 186.00 10.491 245.10 .99150.00 13.375 36.00 . 1.029 129.00 20.029 187.10 2.779 255.10 34.83851.00 49.399 92.00 .916 130.00 1.660 196.00 3.011 256.10 5.09252.00 2.651 93.00 5.415 141.00 2.178 198.00 100.000 258.00 1.78056.00 1.585 98.00 3.590 147.00 .886 199.00 6.398 273.10 1.02957.00 3.687 99.00 2.936 148.00 2.328 204.10 2.538 274.10 2.70463.00 2.065 101.00 1.817 155.00 1.029 205.10 3.807 275.10 17.63369.00 66.717 104.00 1.021 156.10 1.637 206.10 17.212 276.10 2.36674.10 4.581 105.00 1.149 161.00 1.006 207.10 2.208 296.10 3.64275.00 8.283 107.00 12.151 167.00 3.913 217.00 4.603 323.10 1.38276.00 2.351 108.00 1.915 168.10 1.449 221.10 6.301 365.10 1.31477.00 47.649 110.00 29.701 174.00 .349 224.10 9.365 423.10 2.97478.10 3.079 111.00 4.138 175.10 1.352 225.10 2.215 441.10 6.75179.00 3.402 117.00 8.614 179.00 2.809 227.00 3.650 442.10 50.72880.00 2.471 123.00 1.202 180.00 1.983 244.10 6.977 443.20 9.06481.00 3.815 127.00 :44.150 185.00 1.337

AR203236

GC/MS PERFORMANCE STANDARD' «~> . •

Dec a fluorotriphenylphospine f. DFTPP )

96 Relative AbundanceIon Abundance : Base Appropriate

m/z Criteria ' Peak Peak Status

51 30-60H of mass 198 . ! 52.64 52.64 Ok68 Less than 29. of mass 69 '•• .74 1.25 Ok69 (reference only) ' 59.00 59.00 Ok70 Les's than 29. of mass 69 ! 0.00 0.00 Ok127 40-609. of mass 198 i 48.98 48.93 Ok197 Less than 19. of mass 198 ! 0.00 0.00 Ok198 Base peak, 1005. relative abundance : 100.00 100.00 Ok199 5-99$ of mass 198 . 7.42 7.42 Ok275 10-309. of mass 198 20.08 20.08 Ok365 Greater than 1?. of mass 198 ! 2.12 2.12 Ok441 0-1009. of mass 443 ', 8.73 65.63 Ok442 Greater than 409. of mass 193 :. 70.15 70.15 Ok443 17-239. of mass 442 ; 13.31 18.97 Ok


Data File: >D7739Scan: 208

AR203237

>D7739 50 NG DFTPP 11/27/91 r "208 NRM Os^

'ile: >D7739 Scan ft: 208 Retn. time: 13.12


37.80 .539 90.75 .749 142.00 .713 192.V5 1.123 245.85 1.51139.00 6.353 91.95 .896 142.90 .834 195.95 2.635 254.95 46.22450.00 14.190 92.95 4.529 146.9Q 1.520 197.95 100.000 255.95 6.39251.00 52.643 93.85 .397 148.00 2.434 198.95 7.418 256.95 .61152.00 3.089 97.95 : 3.526 148.90 .544 201.50 .700 257.95 2.36756.00 1.881 98.95 3.495 152.90 1.204 202.90 .629 264.85 1.26657.00 4.529 100.95 2.216 153.30 .736 203.9Q 2.759 272.35 .99461.00 .606 103.85 .932 155.00 1.623 204.90 5.109 273.95 3.67862.00 1.052 104.95 1.324 155.85 1.373 206.00 21.206 274.95 20.08362.90 2.180 106.95 '. 14.698 159.95 .869 207.00 2.751 276.05 2.47065.00 1.199 107.95 2.167 160.95 1.074 207.80 .544 276.85 1.73467.85 .736 109.95 33.247 165.95 .593 210.30 .432 295.80 4.42268.85 58.996 111.05 4.899 166.85 4.355 211.00 .780 296.80 .44173.95 4.017 117.00 7.868 167.95 1.997 217.00 5.399 323.00 1.56574.95 8.162 121.80 .829 173.95 -.923 217.90 1.119 333.85 1.10675.95 2.648 122.90 1.743 174.95 2.483 221.00 7.039 352.95 .54476.95 45.908 123.80 1.030 175.95' .713 222.90 .695 364.95 2.11877.95 3.045 126.90 48.983 176.95 .945 224.00 11.131 371.95 .86578.95 3.392 128.00 3.664 178.85 3.067 224.90 3.473 402.90 .66479.95 2.091 128.90 21.755 179.85 2.755 226.90 4.195 422.85 3.75480.85 3.687 130.00 1.850 180.85 1.164 227.90 .678 440.95 8.7381.85 1.413 135.00 1.819 184.95 1.761 229.00 1.150 441.95 70.1582.85 .347 135.90 .522 186.05 11.787 230.90 .383 442.85 13.3085.05 .883 137.00 .909 186.95 3.308 243.95 9.950 443.95 .95485.85 .909 140.90 2.889 192.05 .963 244.95 1.177

AR203238

FiU >07739 35.0-500.0 *mu. 50 NG DFTPP ll/27/91:TIC '

196

200000-

Hbooo-100000-

50000-

0

200 204 2081 1 1

212 216 : £201 I ' 1

Ais '.66 '

File >D7739Bpk flb 100.

100-•

80-,

60-

40-

20-

0-

13.05 13.10

50 NS DFTPPNRM

193

69

'•>•

'

i

110

\

•,4*180

127

1,,

167

l. !,« ». i i.t J .1

13 '.IS' ' ' ' 'l3l_o' ' ' ' ' 13 '.25

-100

-80

;60

-40

Cll''£7/91 , Scan 209

13 .12 min ,

442V

^

255

206

Ink L120 ' 160 ' 200 r 240"

275f 296 :1 / 334 365 403 '

280 ' 320 ' 360 '' 400 ' 44

-100

-80

-60

-40

-20

-0.

rv> <

AR203239

; GC/MS PERFORMANCE STANDARD

Decaf luorot r ipheny Iphosp i n« '.DFTPP )

°. R e l a t i v e AbundanceIon Abundance Base Appropriate

m/z Criteria Peak Peak Status

51 30-60H of mass J198 58.87 58.37 '" Vv63 Less than 2\ ofj mass 69 .90 1 . HO Gk69 (reference only!) 62.89 62.39 Qk70 Less than 29. of! mass 69 0.00 O.UO lik127 40-60% of mass 193 44.90 44. ? 0 U1,197 Less than 19. of mass 198 0.00 0 .'J 0 ~ Ik193 Base peak, 100% r e l a t i v e abundance 100.00 100.00 01-199 5-99. of mass 19,8 6.34 6.34 " Ok275 10-309. of mass 198 19.45 19.45 Ok365 Greater than 19. of mass 198 1.91 1.91 Uk441 0-10 OH of mass '443 . 7.21 66.02 Qk442 Greater than 409. of mass 193 58.26 53.26 Ok443 17-239. of mass 442 10.92 18.75 Ok.


; Data Fi le: >D7773Scan: 196

AR2032l*0

>D7773 50 NG DFTPP 12/03/91196 NRM ; r...

File: >D7773 Scan ft: 196 Retn. t i m e : 1 13.04


33/00 .581 93.75 .383 140.90 2.437 190.65 .311 244.65 .53139.00 5.925 97.95 3.580 142.00 .972 191.75 1.101 245.35 1.43950.00 14.369 98.95 3.386 147.00 .979 193.05 1.169 253.95 .33051.00 53.367 100.95 2.255 147.90 2.445 195.95 3.762 254.95 45.04652.00 3.200 102.95 .736 148.80 .569 197.95 100.000 255.95 6.51055.90 1.518 104.05 .350 152.90 .771 193.95 6.844 257.95 1.21156.90 4.396 105.05 1.321 153.90 .790 199.90 .440 264.95 .50960.90 .771 106.95 14.060 154.90 1.025 201.40 1.032 273.05 1.03263.00 2.000 107.95 2.084 155.95 2.008 203.90 3.728 273.95 3.24265.00 1.063 109.95 33.305 158.95 .516 204.90 5.026 274.95 19.44668.05 .900 110.95 4.540 159.85 .516 206.00 17.886 275.95 2.31668.95 62.891 111.80 .531 161.05 1.021 207.00 2.304 276.95 1.11673.95 5.200 115.90 .501 164.85 .736 210.40 .429 295.90 4.82174.95 7.763 116.10 .493 166.05 .585 211.00 .945 296.70 .80576.05 2.228 116.90 9.072 166.95 4.327 216.90 4.472 323.00 1.81876.95 43.338 117.90 .683 167.95 1.985 217.90 .721 333.85 .38177.95 3.496 121.90 .900 173.95 1.097 220.90 6.073 353.85 .53578.85 3.712 123.00 1.556 174.95 1.776 221.60 1.082 364.95 1.90679.95 2.600 124.00 .869 175.95 .698 223.90 9.702 372.05 1.08980.95 4.308 126.90 44.898 176.85 .865 225.00 2.866 422.85 2.52082.95 .957 128.00 4.191 178.95 3.447 226.10 .326 423.85 .83185.05 .444 128.90 20.612 179.95 1.811 227.00 4.138 440.95 7.21285.95 1.078 129.80 1.313 184.85 1.746 228.90 .934 441.95 58.26490.85 .733 134.90 1.560 135.95 12.508 242.00 .505 442.95 10.92591.85 .945 135.90 .687 187.05 2.798 243.95 10.002 443.95 .86592.95 5.166 137.00 .740

AR2Q32M

f", fe ",o?~f 3 35.0-500.0 amu. 50_N8 OFTPP 12^03/91 |1S4

•200000-

160000-

20000-

30000-

40000-

TIC188 132 196i ! 1.rj

•1 =• a K 1 } i-| |-l ' •< O

Fil* ^07773Bpk flb 100

100-

30-

6'>

40-

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50 N6 DFTPPNRM

19S"""

69

i.:., 1

"110xx

,..„,.[1 ' 180

127

ii..167

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£00 204 303

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12/03/91 'Bear. 19613.04 mm.

442

255

206,/

j.llk 1.. . . .

120 160 200 240

275/ 296

is T?4 ARr .7 .v. , ,i • i ' i • i • i • i ' i • i ' i • i

-100

-30

-60

-40

-20

•-0280 320 360 400 440

AR20321.2

GC/MS PERFORMANCE STANDARD GC6

Decafluorotriphenylphospine (DFTPP)% Relative Abundance

Ion Abundance Base Appropriatem/z Criteria Peak Peak Status

51 30-60% Of mass 198 58.23 58.23 Ok68 Less than 2% of mass 69 0.00 0.00 Ok69 (reference only) 59.53 59.53 Ok70 Less than 2% of mass 69 0.00 o.oo ok127 40-60% of mass 198 44.48 44.48 Ok197 Less than 1% of mass 198 0.00 0.00 Ok198 Base peak, 100% relative abundance 100.00 100.00 Ok199 5-9% of mass 198 6.74 6.74 Ok275 10-30% of mass 198 17.13 17.13 Ok365 Greater than 1% of mass 198 2.23 2.23 Ok441 0-100% Of mass 443 10.07 79.74 Ok442 Greater than 40% of mass 198 56.60 56.60 Ok443 17-23% Of mass 442 12.63 22.31 Ok


Data File: >D7801Scan: 184

AR20321.3

>D7801 50 NG DFTPP 12/06/91184 NRM r; 7

"••'le: >D7801 Scan #: 184 Retn. time: 12.98


37.90 .452 86.85 .516 134.90 1.421 192.05 .961 245.85 1.70039.00 5.136 90.95 1.033 136.00 .965 192.95 1.221 254.95 45.51948.90 .418 91.95 .984 141.00 2.318 195.95 3.346 255.95 6.23750.00 13.570 92.95 !4.273 142.90 .633 197.95 100.000 257.95 1.86951.00 58.230 97.95 3.365 147.00 1.289 198.95 6.738 264.95 1.11952.00 3.086 98.95 2.902 148.00 1.820 201.50 .833 272.95 1.32356.00 1.522 100.85 2.073 152.90 .697 203.90 3.923 273.95 3.39557.00 4.473 102.85 .705 153.90 .467 205.00 4.809 274.95 17.12862.00 .844 104.05 1.391 155.85 1.805 206.00 18.352 275.95 2.27663.00 2.679 104.95 1.093 164.75 .765 206.90 3.173 276.95 1.50064.90 .980 106.95 13.789 166.95 4.010 207.90 .614 295.90 4.22468.85 59.527 108.05 2.412 167.95 1.707 210.50 .912 322.90 1.38773.95 4.217 109.95 34.267 172.85 .705 216.90 4.647 333.75 .99574.95 7.876 111.05 4.473 173.95 1.025 217.70 .618 334.75 .35876.05 2.864 115.90 .720 174.95 1.522 221.00 6.727 353.95 .58476.95 48.926 116.90 6.689 175.95 .641 224.00 9.651 364.85 2.23577.95 3.226 117.90 .814 176.85 .584 224.90 2.789 372.05 .79178.95 3.637 122.00 .950 178.95 3.135 226.90 3.275 422.95 2.65379.95 3.075 122.90 1.232 179.85 2.287 227.80 .803 423.85 .94680.85 4.243 127.00 44.483 180.95 1.187 229.00 .701 440.95 10.06981.95 .935 127.90 3.328 184.95 1.236 242.90 .750 441.95 56.59883.05 .795 128.90 21.262 185.95 13.208 243.95 7.469 442.85 12.62884.85 .731 130.00 1.440 186.95 3.968 244.95 1.458 443.85 .93186.05 .980 133.80 .422

AR2032H

File >D'

250008-

•30000-

150083-

100000-

58888-

?801 35.8-588.8 amu. 5® N<3 DFTPP 12/06/91TIC

172 176 188 184 188 192 196

ia'.sa ' 12 '.98 ' 12.95 ' is'.ee ' is'.es ' is'.ie

j-100

:80768

•48

;28

-8

File >D7881 58 N6 DFTPP 12/86/91 Scan 184Bpk flb 188. NRM 12.98 min.

188-

88-

60-

40-

28-

ft *

198^

69 442

118 «7 2X5S 1

\ 286, 167 / 2/5 296

1 \ l 1 1 X 334 365i. lf-rl. l ...... Vjl. ,. I, ,|L L - 1 f / /.

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-88

-68

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88 ' 128 ' 168 ' 280 ' 248 ' 288 ' 328 ' 368 ' 480 ' 448

IR20321.5

r'" io ^ .j

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