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Radioisotopes

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Radioisotopes The nuclei of some atoms are unstable and undergo spontaneous changes called radioactive decay. One such change is called beta decay. - PowerPoint PPT Presentation
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Radioisotopes The nuclei of some atoms are unstable and undergo spontaneous changes called radioactive decay. One such change is called beta decay. During beta decay a neutron changes into a proton and an electron transforming the atom to an element with an atomic number which is one
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Page 1: Radioisotopes

RadioisotopesThe nuclei of some atoms are unstable and undergo spontaneous changes called radioactive decay.One such change is called beta decay.During beta decay a neutron changes into a proton and an electron transforming the atom to an element with an atomic number which is one higher while the atomic mass barely changes.

Page 2: Radioisotopes

+

Tritium atoms, H-3, undergo spontaneous beta decay. Shown below is a tritium nucleus.

1 proton2 neutrons

Page 3: Radioisotopes

+ 2 proton1 neutron1 electron

+

vvvvv

The highly energetic electron is ejected from the nucleus as radiation.It travels at a speed of 1.3 x 105 km/s. The equation is:

1H3

2He3

+ 1-e0

Page 4: Radioisotopes

Two other forms of radiation from radioactive decay are:alpha particle emission andgamma rays.An alpha particle contains 2 protons and 2 neutrons while gamma rays do not result in the release of particles.The rate of release of radiation is expressed as a half-life.A half-life is the length of time required for half of the original material to decay.

Page 5: Radioisotopes

Tritium has a half-life of 12.26 years.12.26 a (annum is latin for years)If 10 g of tritium were left for 12.26 a there would be 5 g left.After 24.52 a there would be 2.5 g left.Here is a table showing the quantity of tritium remaining after different time periods.

Page 6: Radioisotopes

Time (a)Mass of

Tritium (g)

0.00 10.0012.26 5.0024.52 2.5036.78 1.2549.04 0.6361.30 0.3173.56 0.16

Page 7: Radioisotopes

Mass of Tritium vs Time

10.00

5.00

2.50

1.25

0.630.31 0.16 0.080.00

2.00

4.00

6.00

8.00

10.00

12.00

0.00 20.00 40.00 60.00 80.00 100.00

Time (a)

Mas

s (g

)

Page 8: Radioisotopes

Here is an example of Alpha decay.Alpha decay involves the emission of a helium-4 nucleus. Write an equation which shows how uranium-235 undergoes alpha decay.

92

235U 2

4He +

90

231Th

Page 9: Radioisotopes

Different radioactive isotopes decay at different rates.If 100 g of a radioactive material decays for 10 years and 50 g remains this substance is said to have a half life of 10 years.

5 y 5 y

After 10 y only 50 g remain

If 200 g of a radioactive material with a half-life of 5 years, is left to decay for 10 years how much of the original material is left?

200 g -------> 100 g -------> 50 g

Page 10: Radioisotopes

If 200 g of a radioactive material with a half-life of 5 years, is left to decay for 10 years how much of the original material is left?

200 g ------->

200 g

Page 11: Radioisotopes

If 200 g of a radioactive material with a half-life of 5 years, is left to decay for 10 years how much of the original material is left?

200 g -------> 100 g

100 g left after 5 years

Page 12: Radioisotopes

If 200 g of a radioactive material with a half-life of 5 years, is left to decay for 10 years how much of the original material is left?

200 g -------> 100 g -------> 50 g

50 g left after 10 years

Page 13: Radioisotopes

If 200 g of a radioactive material with a half-life of 5 years, is left to decay for 10 years how much of the original material is left?

200 g -------> 100 g -------> 50 g ----> 25g

25 g left after 15 years

Page 14: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

512 g

Page 15: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

256 g

512 g ---> 256 g25 da

Page 16: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

128 g

512 g ---> 256 g ---> 128 g25 da 25 da

Total - 50 da

Page 17: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

64 g

512 g ---> 256 g ---> 128 g ---> 64 g25 da 25 da 25 da

Total - 75 da

Page 18: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

32 g

512 g ---> 256 g ---> 128 g ---> 64 g ---> 32 g25 da 25 da 25 da 25 da

Total - 100 da

Page 19: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

16 g

512 g ---> 256 g ---> 128 g ---> 64 g ---> 32 g25 da 25 da 25 da 25 da

Total - 125 da 16 g25 da

Page 20: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

512 g ---> 256 g ---> 128 g ---> 64 g ---> 32 g25 da 25 da 25 da 25 da

Total - 150 da 16 g25 da

8 g

8 g

25 da

Page 21: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

512 g ---> 256 g ---> 128 g ---> 64 g ---> 32 g25 da 25 da 25 da 25 da

Total - 175 da 16 g25 da

4 g

8 g

25 da

4 g

25 da

Page 22: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

512 g ---> 256 g ---> 128 g ---> 64 g ---> 32 g25 da 25 da 25 da 25 da

Total - 200 da 16 g25 da

2 g

8 g

25 da

4 g

25 da

2 g25 da

Page 23: Radioisotopes

Show the decay sequence for 512 g of a substance with a half-life of 25 da.

512 g ---> 256 g ---> 128 g ---> 64 g ---> 32 g25 da 25 da 25 da 25 da

Total - 225 da 16 g25 da

1 g

8 g

25 da

4 g

25 da

2 g25 da

1 g25 da

Page 24: Radioisotopes

If U-235 has a half-life of 7.1 x 108 y. How many years would it take 32 g to decay to 2 g?32 g --> 16 g --> 8 g --> 4 g --> 2 g4 half lifes2.84 x 109 y.

Cs-136 has a half-life of 13 da. If 1024 g was left to decay for 65 da how much of the original material would be left?65/13 = 5 hl1024 g -> 512 g -> 256 g -> 128 g -> 64 g -> 32 g

or 1024 g x (1/2)5 = 32 g

Page 25: Radioisotopes

To find the quantity of material remaining use this formula

Massremaining =

OriginalMass

x 12

# of Half-lives

Pb-212 has a half-life of 10.6 h. If 12.5 g of Pb-212 is left for 84.8 h how much of the original material is left?

Massremaining =

OriginalMass

x 12

# of Half-lives

12.5 g x (0.5)84.8/10.6

= 0.0488 g


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