REFERENCE: Environmental Soil Sampling Report …...644611 / 2017 02 14 P:\CP\MoTI\644611_Vernon...

$Page 1: REFERENCE: Environmental Soil Sampling Report …...644611 / 2017 02 14 P:\CP\MoTI\644611_Vernon Right Turn Lane\4.0\4.72017 02 - Drill Report\ATTACHMENTS\Tables - issued,complete\$
SNC-Lavalin Inc.

Suite 100 – 1358 St. Paul Street Kelowna, British Columbia, Canada, V1Y 2E1

250-861-9070 250-862-9070

February 23, 2017 Project: 644611 Ministry of Transportation and Infrastructure Engineering – Highways Department Suite 4B – 940 Blanshard Street Victoria, BC V8W 9T5 ATTENTION: Paul Savinkoff, Senior Geoscientist REFERENCE: Environmental Soil Sampling Report Highway 97 South at 43rd Avenue, Right Turn Lane, Vernon, BC At the request of the Ministry of Transportation and Infrastructure (MoTI), SNC-Lavalin Inc. (SNC-Lavalin) has completed environmental soil sampling at three borehole locations along Highway 97 South at 43rd Avenue in Vernon, BC (hereinafter referred to as the Site or investigation area).

Refer to the appended Location Plan (Drawing 644611-001) and Site and Borehole Location Plan (Drawing 644611-002) for a visual representation of the Site and location of boreholes.

Background and Objectives The MoTI undertook the project work in preparation for improvements to the right turn lane along Highway 97 South at 43rd Ave in Vernon, BC. The project scope involved a geotechnical investigation, including the drilling of three boreholes to a depth of approximately 4.5 m below ground surface (bgs). Klohn Crippen Berger (KCB) completed the geotechnical work, and was responsible for coordinating the work using contractors for utility locates, drilling and traffic control, and was also the prime contractor for health and safety.

The purpose of SNC-Lavalin’s work was to collect environmental soil samples during the geotechnical drilling process in order to characterize soil at the investigation locations, and to provide recommendations on soil disposal options if contamination in soil was identified. SNC-Lavalin worked under the KCB Health and Safety program, and all work was carried out in accordance with the terms and conditions of the MoTI As and When contract 860 CS 4975.

Suspected areas of potential environmental concern (APECs), identified based on SNC-Lavalin’s general knowledge of the area, included a Safeway gas station located adjacent to the west side of the investigation area, and the likely presence of imported fill of unknown origin. The potential contaminants of concern (PCOCs) related to the Safeway gas bar include gasoline and diesel; the associated regulated parameters in soil include: benzene, ethylbenzene, toluene and xylenes (BETX), volatile petroleum hydrocarbons (VPH), light and heavy extractable petroleum hydrocarbons (LEPH/HEPH), polycyclic aromatic hydrocarbons (PAHs) and methyl tertiary butyl ether (MTBE). Metals are the potential contaminants of concern related to imported fill. Additional APECs and

Infrastructure

Ministry of Transportation and Infrastructure – Page 2 of 3 Project 644611 February 23, 2017

PCOCs may be applicable; however, a Stage 1 Preliminary Site Investigation (PSI) would be required to confirm this and this was not included within the current scope of work.

Scope of Work The scope of work for SNC-Lavalin included the following tasks:

› Preparation of a health and safety plan specific to our work (i.e., travel, working around a drill rig and soil sampling).

› Travel from SNC-Lavalin’s Kelowna office to the Site. › Observing the drilling of three boreholes, including recording soil profiles, visual and/or olfactory

evidence of contamination, field screening for hydrocarbon vapours using a EAGLE 2 portable gas detector , and collection of soil samples from each borehole for testing in general accordance with Contaminated Sites Regulation1 (CSR) Technical Guidance 12.

› Submitting two samples per borehole for laboratory analysis of PCOCs. › Comparison of the soil laboratory analytical results to the applicable standards. › Preparation of this letter report summarizing the findings and recommendations for soil

management and disposal options, if required.

Regulatory Framework The Site is currently in use as a MoTI roadway/right-of-way curbside median, thus applicable standards for the investigation area are the CSR Industrial Land Use (IL) standards.

The planned project work may involve removal and disposal of soil from the investigation area; therefore soil testing results were also compared to CSR Schedule 7 soil relocation standards for non-agricultural land (NAL).

Summary of Investigation › The field work was completed on February 6, 2017. › Geotech Drilling Services Ltd. completed the auger drilling to advance three boreholes at the Site,

identified as TH01-17, TH02-17 and TH03-17 (SNC-Lavalin utilized KCB’s borehole/sample IDs for this project). Boreholes TH01-17 and TH02-17 were located to the west of Highway 97 (i.e., west of the curb lane), and borehole TH03-17 was located in the southbound curb lane.

› The soil conditions observed comprised the following: › BH TH01-17: Organics/topsoil overlying clay and sand. › BH TH02-17: Organics/topsoil overlyling sand, over silt/sand and then clay. › BH TH03-17: Asphalt, over sand and gravel fill, over clay.

1 Contaminated Sites Regulation (CSR), B.C. Reg. 375/96, includes amendments up to B.C. Reg. 184/2016, July 19, 2016.

2 Technical Guidance Document 1 (TG1) Site Characterization and Confirmation Testing, BC Ministry of Environment, January 2009.

Infrastructure

Ministry of Transportation and Infrastructure – Page 3 of 3 Project 644611 February 23, 2017

Infrastructure

› A total of 17 soil samples were collected from the boreholes. No headspace vapour concentrations were detected in any of the samples. Refer to the appended borehole logs for recorded details.

› A total of six soil samples, two per borehole, were submitted to Caro Analytical Services in Richmond, BC for select analysis of BETX, VPH, MTBE, LEPH, HEPH, PAHs and metals. SNC-Lavalin tabulated the analytical results and compared them to the applicable CSR standards. The soil samples were selected for testing based on field observations and screening, moisture content and the planned future excavation depth up to 2.5 m for the new pavement structure. Results of analysis found concentrations of all parameters in all samples analyzed were less than the applicable CSR IL and NAL standards.

Conclusions and Recommendations All tested parameter concentrations were less than applicable site standards, as well as soil relocation standards for non-agricultural land. As such, the soil is classified as residential/parkland use (RL/PL) quality soil, and is suitable for re-use on-site if deemed geotechnically suitable, or can be relocated to any non-agricultural property.

We trust this report suits your current requirements. If you have any questions, please contact me in our Burnaby office at 604-515-5151 or [email protected].

Paul Embregts Dave Bridger Operations Manager Project Manager

Environment & Geoscience Environment & Geoscience Infrastructure Infrastructure DWB/NF/PSE/rck P:\CP\MoTI\644611_Vernon Right Turn Lane\5.0\5.5\L223nfa_BH Sampling Rpt.docx enc. Tables 1. Summary of Analytical Results for Hydrocarbons in Soil 2. Summary of Analytical Results for PAHs in Soil 3. Summary of Analytical Results for Metals in Soil Drawings

› 644611-001 – Location Plan

› 644611-002 – Site and Borehole Location Plan Attachments 1. Borehole Logs 2. Laboratory Analytical Report

TABLES

1. Summary of Analytical Results for Hydrocarbons in Soil 2. Summary of Analytical Results for PAHs in Soil 3. Summary of Analytical Results for Metals in Soil

SNC-LAVALIN INC. Page 1 of 1

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TABLE 1: Summary of Analytical Results for Hydrocarbons in Soil

Monocyclic Aromatic Hydrocarbons Gross Parameters MTBESample Depth Field Ethyl- VPH EPHc EPHc

Sample Sample Date Interval Screena Benzene benzene Toluene Xylenes Styrene (C6-C10) (C10-C19) (C19-C32) MTBELocation ID (yyyy mm dd) (m) (ppm) µg/g µg/g µg/g µg/g µg/g µg/g µg/g µg/g µg/gTH01-17 TH01-17-01-01-170206 2017 02 06 0.9 - 1.5 0 < 0.02 < 0.05 < 0.20 < 0.10 < 0.05 < 20 < 50d < 50d < 0.04

TH01-17-01-02-170206 2017 02 06 1.5 - 2.1 0 < 0.02 < 0.05 < 0.20 < 0.10 < 0.05 < 20 < 50 < 60 < 0.04TH02-17 TH02-17-02-01-170206 2017 02 06 0.0 - 0.5 0 < 0.02 < 0.06 < 0.22 < 0.10 < 0.06 < 20 < 50d 91d < 0.04

TH02-17-02-03-170206 2017 02 06 1.5 - 2.1 - < 0.02 < 0.05 < 0.20 < 0.10 < 0.05 < 20 < 50d < 50d < 0.04TH03-17 TH03-17-03-01-170206 2017 02 06 0.3 - 0.6 0 < 0.02 < 0.05 < 0.20 < 0.10 < 0.05 < 20 < 50d < 50d < 0.04

TH03-17-03-02-170206 2017 02 06 0.8 - 1.4 - < 0.02 < 0.05 < 0.20 < 0.10 < 0.05 < 20 < 50 < 50 < 0.04BC Standard

CSR Schedule 7 - Non-Agricultural Land Use (NAL) 0.04 1 1.5 5 5 200 1,000 1,000d n/aCSR Industrial Land Use (IL)b 0.04 7 2.5 20 50 200 2,000d 5,000d 700

Associated Caro file(s): 7020468.All terms defined within the body of SNC-Lavalin's report.< Denotes concentration less than indicated detection limit or RPD less than indicated value.- Denotes analysis not conducted.n/a Denotes no applicable standard/guideline.

BOLD Concentration greater than CSR Schedule 7 - Non-Agricultural Land Use (NAL) Standard

SHADOW Concentration greater than CSR Industrial Land Use (IL) Standard

a Field screening results are measured based on a 'dry headspace' method using a combustible gas meter calibrated to a hexane standard.b The site-specific factors used for determining the matrix standards for this site include: intake of contaminated soil, groundwater used for drinking water, toxicity to soil invertebrates and plants, and groundwater flow to surface water used by freshwater aquatic life (whichever is most stringent).c EPH has no applicable CSR standard, however results have been compared to LEPH and HEPH standards, which are conservative comparisons.d Value has been corrected for the presence of individual PAH.



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QAQC: PSE 2017 02 14

TABLE 2: Summary of Analytical Results for PAH in Soil

Sample Location TH01-17 TH02-17 TH03-17 BC StandardSample ID TH01-17-01-01-170206 TH02-17-02-01-170206 TH02-17-02-03-170206 TH03-17-03-01-170206 CSR Schedule 7 CSR

Sample Date (yyyy mm dd) 2017 02 06 2017 02 06 2017 02 06 2017 02 06 Non-Agricultural IndustrialDepth Interval (m) 0.9 - 1.5 0.0 - 0.5 1.5 - 2.1 0.3 - 0.6 Land Use Land Use

Field Screen (ppm)a 0 0 - 0 (NAL) (IL)b

Parameter Units Analytical ResultsPolycyclic Aromatic HydrocarbonsNaphthalene µg/g < 0.05 < 0.05 < 0.05 < 0.05 5 50Acenaphthylene µg/g < 0.05 < 0.05 < 0.05 < 0.05 n/a n/aAcenaphthene µg/g < 0.05 < 0.05 < 0.05 < 0.05 n/a n/aFluorene µg/g < 0.05 < 0.05 < 0.05 < 0.05 n/a n/aPhenanthrene µg/g < 0.05 < 0.05 < 0.05 < 0.05 5 50Anthracene µg/g < 0.05 < 0.05 < 0.05 < 0.05 n/a n/aFluoranthene µg/g < 0.05 0.07 0.07 < 0.05 n/a n/aPyrene µg/g < 0.05 0.06 0.10 < 0.05 10 100Benzo(a)anthracene µg/g < 0.05 < 0.05 < 0.05 < 0.05 1 10Chrysene µg/g < 0.05 < 0.05 0.06 < 0.05 n/a n/aBenzo(b)fluoranthene µg/g < 0.05 0.06 0.07 < 0.05 1 10Benzo(b+j)fluoranthene µg/g < 0.10 < 0.10 0.12 < 0.10 n/a 10Benzo(k)fluoranthene µg/g < 0.05 < 0.05 < 0.05 < 0.05 1 10Benzo(a)pyrene µg/g < 0.05 < 0.05 0.08 < 0.05 1 10Indeno(1,2,3-cd)pyrene µg/g < 0.05 < 0.05 0.08 < 0.05 1 10Dibenz(a,h)anthracene µg/g < 0.05 < 0.05 < 0.05 < 0.05 1 10Benzo(g,h,i)perylene µg/g < 0.05 0.07 0.08 < 0.05 n/a n/a

Associated Caro file(s): 7020468.All terms defined within the body of SNC-Lavalin's report.< Denotes concentration less than indicated detection limit or RPD less than indicated value.n/a Denotes no applicable standard/guideline.


SHADOW Concentration greater than CSR Industrial Land Use (IL) Standarda Field screening results are measured based on a 'dry headspace' method using a combustible gas meter calibrated to a hexane standard.b The site-specific factors used for determining the matrix standards for this site include: intake of contaminated soil, groundwater used for drinking water, toxicity to soil invertebrates and plants, and groundwater flow to surface water used by freshwater aquatic life (whichever is most stringent).



x214nna.xlsx QAQC: PSE 2017 02 14

TABLE 3: Summary of Analytical Results for Total Metals in Soil

Sample Location TH01-17 TH02-17 TH03-17 BC StandardSample ID TH01-17-01-01-170206 TH02-17-02-01-170206 TH02-17-02-03-170206 TH03-17-03-01-170206 CSR Schedule 7 CSR

Sample Date (yyyy mm dd) 2017 02 06 2017 02 06 2017 02 06 2017 02 06 Non-Agricultural IndustrialDepth Interval (m) 0.9 - 1.5 0.0 - 0.5 1.5 - 2.1 0.3 - 0.6 Land Use Land Use

Parameter Units Analytical Results (NAL) (IL)a

Physical ParameterspH pH 8.8 7.7 9.0 9.6 n/a n/aTotal MetalsAntimony µg/g 0.3 0.6 0.2 0.2 20 40Arsenic µg/g 6.1 3.9 4.0 3.4 15 15Barium µg/g 265 135 125 127 400 400Beryllium µg/g 0.9 0.5 0.4 0.4 4 8Boron µg/g < 2 5 < 2 < 2 n/a n/aCadmium µg/g 0.33 0.38 0.28 150 (pH>=8.0)

0.70 25 (pH 7.5-<8.0)Chromium µg/g 85.0 38.4 31.2 27.9 150b 150b

Cobalt µg/g 24.3 10.2 12.9 12.3 50 300Copper µg/g 59.2 43.5 31.4 25.8 90 250 (pH >6.0 )Lead µg/g 14.8 21.9 5.5 3.5 100 2,000 (pH >6.0 )Lithium µg/g 37.7 16.8 9.4 6.3 n/a 20,000Manganese µg/g 888 479 582 594 n/a 19,000Mercury µg/g < 0.04 0.10 < 0.04 < 0.04 15 150Molybdenum µg/g 1.5 1.6 1.4 0.8 10 40Nickel µg/g 69.3 28.9 37.4 39.2 100 500Selenium µg/g < 0.5 0.5 < 0.5 < 0.5 3 10Silver µg/g < 0.2 0.3 < 0.2 < 0.2 20 40Strontium µg/g 144 74.5 130 105 n/a 100,000Thallium µg/g 0.3 0.2 0.1 < 0.1 n/a n/aTin µg/g 1.0 0.9 0.5 0.4 50 300Uranium µg/g 1.70 1.17 0.62 0.44 n/a 200Vanadium µg/g 88.6 46.7 81.4 71.9 200 n/aZinc µg/g 119 126 79 68 150 600 (pH >7.0 )

Associated Caro file(s): 7020468.All terms defined within the body of SNC-Lavalin's report.< Denotes concentration less than indicated detection limit or RPD less than indicated value.n/a Denotes no applicable standard/guideline.


SHADOW Concentration greater than CSR Industrial Land Use (IL) Standarda The site-specific factors used for determining the matrix standards for this site include: intake of contaminated soil, groundwater used for drinking water, toxicity to soil invertebrates and plants, and groundwater flow to surface water used by freshwater aquatic life (whichever is most stringent).b Table 1, Regional Background Soil Quality Estimates for Inorganic Substances, Okanagan Region, BC Ministry of Environment Protocol 4 for Contaminated Sites, Determining Background Soil Quality, October 12, 2010.

1.5

DRAWINGS

› 644611-001 – Location Plan › 644611-002 – Site and Borehole Location Plan

0 525 1,050 1,575 2,100262.5Meters

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Site Location

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Notes:1. Intended for Illustration purposes only.2. Original in colour.3. Site location is approximate.References:Sources: Esri, HERE, DeLorme, Intermap,increment P Corp., GEBCO, USGS, FAO, NPS,NRCAN, GeoBase, IGN, Kadaster NL, OrdnanceSurvey, Esri Japan, METI, Esri China (HongKong), swisstopo, MapmyIndia, ©OpenStreetMap contributors, and the GIS UserCommunity

REV:

PROJECT LOCATION:Highway 97 South at 43rd AvenueVernon, BC

CLIENT NAME:Ministry of Transportation andInfrastructure

LOCATION PLANRef Num:

644611-001DATE: 2017/02/17 SCALE: 1:24,000COORD SYS: NAD 1983 UTM Zone 11N

CHK'D: NFBY: DM

Legend_̂ Site Location

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SafewayGas Station

SafewayStore

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LegendSanitary mainStorm mainRailway

·ª Boreholes

REFERENCES:1. BCGOV ILMB Crown Registry and Geographic BaseBranch (CRGB)(data accessed through www.GeoBC.gov.bc.ca)2. Borehole locations are approximative

NOTES:1. Original in colour.2. Numerical scale reflects full-size print. Print scaling willdistort this scale, however scale bar will remain accurate.3. Intended for illustration purposes, accuracy has not beenverified for construction or navigation purposes.

REVISIONS:0 - DM - 2017-02-17 - Issued to client

CLIENT:Ministry of Transportation and Infrastructure

PROJECT LOCATION:Highway 97 South at 43rd Avenue,Vernon, BC

REF No:

644611-002DATE: 2017/02/21SCALE: 1:750BY: DM

Proj Coord Sys: NAD 1983 UTM Zone 10NCHK'D: NF

Site and Borehole Location PlanREV: 0

ATTACHMENT 1

Borehole Logs

8345

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13192220

ORGANICS (TOPSOIL), woody, medium brown, frozen.

CLAY, trace silt, medium brown, moist.

Below 1.7 m - stiff to very stiff.

SAND, fine to medium grained, trace silt, light brown, dry.

Below 4.4 m - some fine to coarse subrounded gravel.Bottom of hole at 4.6 m.

01-01

01-02

01-03

01-04

01-05

CUTTINGS

BENTONITE

CUTTINGS

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Soil Description Str

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Soil Vapour(ppm)

104103102101

Borehole Dia. (m)Pipe/Slotted Pipe Dia. (m)

Top of Casing Elev. (m)Borehole Logged By:Date Drilled:Log Typed By: NN

Bold samples denotes samples analyzed.NOTES

Drilling ContractorDrilling Method

Date MonitoredGround Surface Elev. (m)

Project Number: 644611IPC

Location

ClientMin. of Transportation and Infrastructure

Reading outsideindicated scale

2017 02 06

Water/ Levels

PAGE 1 OF 1

Northing: n/a Easting: n/a

Water Level 1

Water Level 2

Hollow Stem Auger0.20none/none

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Borehole No. : TH01-17

Geotech Drilling Services Ltd.

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ORGANICS (TOPSOIL), some silt, some sand, dark brown,frozen.

SAND, fine to coarse grained, some subrounded gravel, fine tocoarse, medium brown, damp.

Below 0.9 m - gravelly, subangular, some silt.

Below 1.8 m - moist.

SILT and SAND, some subrounded gravel, medium brown,moist.

Below 3.4 m - silty.

CLAY, sandy, some silt, medium grey, damp.

Bottom of hole at 4.6 m.

02-01

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Bold samples denotes samples analyzed.NOTES




Location



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ASPHALT.SAND and GRAVEL, fine to coarse grained sand, fine tocoarse subrounded gravel, some silt, medium brown, damp.Below 0.5 m - coarse subangular gravel.

CLAY, trace silt, medium brown, stiff, moist.

SAND, fine to coarse grained, some angular gravel, some silt.CLAY, trace silt, medium brown, stiff, moist.

Below 3.1 m - medium stiff.

Below 3.5 m - stiff.

Between 4.0 m and 4.1 m - seam of SAND and GRAVEL, fineto coarse grained sand, fine to coasre gravel, trace silt,medium brown, moist.CLAY.Bottom of hole at 4.6 m.

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Bold samples denotes samples analyzed. Sample 03-A is a blind fieldduplicate of sample 03-6.

NOTES




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ATTACHMENT 2

Laboratory Analytical Report

REPORTED TO SNC-Lavalin Inc. (Burnaby)

Burnaby, BC V5A 4N6

TEL

FAX

ATTENTION WORK ORDER

General Comments:

CARO Analytical Services employs methods which are conducted according to procedures accepted by appropriate

regulatory agencies, and/or are conducted in accordance with recognized professional standards using accepted testing

methodologies and quality control efforts, except where otherwise agreed to by the client.

The results in this report apply to the samples analyzed in accordance with the Chain of Custody or Sample Requisition

document. This analytical report must be reproduced in its entirety. CARO is not responsible for any loss or damage

resulting directly or indirectly from error or omission in the conduct of testing. Liability is limited to the cost of analysis .

Samples will be disposed of 30 days after the test report has been issued unless otherwise agreed to in writing.

Authorized By:

#110 4011 Viking Way #102 3677 Highway 97N 17225 109 Avenue

Richmond, BC V6V 2K9 Kelowna, BC V1X 5C3 Edmonton, AB T5S 1H7

Tel: 604-279-1499 Tel: 250-765-9646 Tel: 780-489-9100

www.caro.ca

Locations:

7020468

CERTIFICATE OF ANALYSIS

PO NUMBER RECEIVED / TEMP 2017-02-08 08:45 / 8°C

PROJECT REPORTED 2017-02-15

PROJECT INFO COC NUMBER B46711-12

8648 Commerce Court (604) 515-5151

(604) 515-5150

Dave Bridger

644611

Account Manager

Bryan Shaw, Ph.D., P.Chem.

Work Order Comments: Custody Seals Intact: YES

This is a revised report. Refer to Appendix 3 for details

If you have any questions or concerns, please contact me at [email protected]

Page 1 of 19CARO Analytical ServicesRev 2017-01-05 Page 1 of 19

REPORTED TO

PROJECT

SNC-Lavalin Inc. (Burnaby) WORK ORDER

REPORTED 2017-02-15

TABLE OF CONTENTS

644611

7020468

Analysis Information Page 3

Analysis Descriptions, Method References, Glossary of Terms

Sample Analytical Data Page 4

Test Results, Reporting Limits, Analysis Dates, Sample & Analysis Notes

Quality Control Data Appendix 1

Method Blanks, Duplicates, Spikes, Reference Materials

Analytical Summary Appendix 2

Tabulated data in condensed format to assist with comparisons

Revision History

List of changes made to the current report since the original report was issued

Appendix 3


REPORTED TO

PROJECT


REPORTED 2017-02-15

ANALYSIS INFORMATION

644611

7020468

Technique LocationAnalysis Description Method Reference

BTEX in Soil EPA 5035A/5030B /

EPA 8260B

Methanol Extract, Purge&Trap / GC-MS (SIM) Richmond

EPH in Soil EPA 3570* / BCMOE

EPHs

Shaker Extraction (Hexane-Acetone 1:1) / Gas

Chromatography (GC-FID)

Richmond

HEPHs in Soil BCMOE LEPH/HEPH Calculation N/A

LEPHs in Soil BCMOE LEPH/HEPH Calculation N/A

Moisture in Soil ASTM D2974-87* Gravimetry (Dried at 105C) N/A

pH (1:2 Soil/Water) in Soil Carter 16.2 / APHA

4500-H+ B

1:2 Soil/Water Slurry / Electrometry Richmond

Polycyclic Aromatic Hydrocarbons in

Soil

EPA 3570* / EPA

8270D

Shaker Extraction (Hexane-Acetone 1:1) / GC-MS

(SIM)

Richmond

SALM by ICPMS in Soil BCMOE SALM V.2 /

EPA 6020A

HNO3+HCl Hot Block Digestion / Inductively Coupled

Plasma-Mass Spectroscopy (ICP-MS)

Richmond

VH in Soil EPA 5035A/5030B /

BCMOE VHs

Methanol Extract, Purge&Trap / Purge&Trap or

Headspace, Gas Chromatography (GC-FID)

Richmond

VPHs in Soil BCMOE VPH Calculation: VH - (Benzene + Toluene + Ethylbenzene

+ Xylenes + Styrene)

N/A

Note: An asterisk in the Method Reference indicates that the CARO method has been modified from the reference method

Method Reference Descriptions:

APHA Standard Methods for the Examination of Water and Wastewater, 22nd Edition, American Public Health

Association/American Water Works Association/Water Environment Federation

ASTM ASTM International Test Methods

BCMOE British Columbia Environmental Laboratory Manual, 2013, British Columbia Ministry of Environment

EPA United States Environmental Protection Agency Test Methods

Glossary of Terms:

MRL Method Reporting Limit

Less than the Reported Detection Limit (RDL) - the RDL may be higher than the MRL due to various factors such

as dilutions, limited sample volume, high moisture, or interferences

<

Percent (wet weight)% wet

Milligrams per kilogram (dry weight)mg/kg dry

pH < 7 = acidic, ph > 7 = basicpH units


REPORTED TO

PROJECT


REPORTED 2017-02-15

SAMPLE ANALYTICAL DATA

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Analyte Result /

Recovery

MRL /

Limits

Units Prepared Analyzed Notes

Sample ID: TH01-17-01-01-170206 (7020468-01) [Soil] Sampled: 2017-02-06 08:30

General Parameters

% wet27.3Moisture 2017-02-090.1 N/A

pH units8.8pH (1:2 H2O Solution) 2017-02-090.1 2017-02-09

Strong Acid Leachable Metals

mg/kg dry0.3Antimony 2017-02-090.1 2017-02-08

mg/kg dry6.1Arsenic 2017-02-090.4 2017-02-08

mg/kg dry265Barium 2017-02-091 2017-02-08

mg/kg dry0.9Beryllium 2017-02-090.1 2017-02-08

mg/kg dry< 2Boron 2017-02-092 2017-02-08

mg/kg dry0.33Cadmium 2017-02-090.04 2017-02-08

mg/kg dry85.0Chromium 2017-02-091.0 2017-02-08

mg/kg dry24.3Cobalt 2017-02-090.1 2017-02-08

mg/kg dry59.2Copper 2017-02-090.2 2017-02-08

mg/kg dry14.8Lead 2017-02-090.2 2017-02-08

mg/kg dry37.7Lithium 2017-02-090.1 2017-02-08

mg/kg dry888Manganese 2017-02-090.4 2017-02-08

mg/kg dry< 0.04Mercury 2017-02-090.04 2017-02-08

mg/kg dry1.5Molybdenum 2017-02-090.1 2017-02-08

mg/kg dry69.3Nickel 2017-02-090.4 2017-02-08

mg/kg dry< 0.5Selenium 2017-02-090.5 2017-02-08

mg/kg dry< 0.2Silver 2017-02-090.2 2017-02-08

mg/kg dry144Strontium 2017-02-090.2 2017-02-08

mg/kg dry0.3Thallium 2017-02-090.1 2017-02-08

mg/kg dry1.0Tin 2017-02-090.2 2017-02-08

mg/kg dry1.70Uranium 2017-02-090.05 2017-02-08

mg/kg dry88.6Vanadium 2017-02-090.4 2017-02-08

mg/kg dry119Zinc 2017-02-092 2017-02-08

BCMOE Aggregate Hydrocarbons

mg/kg dry< 20VHs (6-10) 2017-02-0920 2017-02-06

mg/kg dry< 20VPHs N/A20 N/A

mg/kg dry< 50EPHs10-19 2017-02-1050 2017-02-08

mg/kg dry< 50EPHs19-32 2017-02-1050 2017-02-08

mg/kg dry< 50LEPHs N/A50 N/A

mg/kg dry< 50HEPHs N/A50 N/A

2017-02-1091 60-140Surrogate: 2-Methylnonane 2017-02-08%

Polycyclic Aromatic Hydrocarbons (PAH)

mg/kg dry< 0.05Acenaphthene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Acenaphthylene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Anthracene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Benz (a) anthracene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Benzo (a) pyrene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Benzo (b) fluoranthene 2017-02-100.05 2017-02-08

mg/kg dry< 0.10Benzo (b+j) fluoranthene 2017-02-100.10 2017-02-08

mg/kg dry< 0.05Benzo (g,h,i) perylene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Benzo (k) fluoranthene 2017-02-100.05 2017-02-08


REPORTED TO

PROJECT


REPORTED 2017-02-15


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Analyte Result /

Recovery

MRL /

Limits


Sample ID: TH01-17-01-01-170206 (7020468-01) [Soil] Sampled: 2017-02-06 08:30, Continued

Polycyclic Aromatic Hydrocarbons (PAH), Continued

mg/kg dry< 0.05Chrysene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Dibenz (a,h) anthracene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Fluoranthene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Fluorene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Indeno (1,2,3-cd) pyrene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Naphthalene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Phenanthrene 2017-02-100.05 2017-02-08

mg/kg dry< 0.05Pyrene 2017-02-100.05 2017-02-08

2017-02-10115 72-117Surrogate: Naphthalene-d8 2017-02-08%

2017-02-10104 74-111Surrogate: Acenaphthene-d10 2017-02-08%

2017-02-10101 60-106Surrogate: Phenanthrene-d10 2017-02-08%

2017-02-1099 60-125Surrogate: Chrysene-d12 2017-02-08%

2017-02-1093 60-121Surrogate: Perylene-d12 2017-02-08%

Volatile Organic Compounds (VOC)

mg/kg dry< 0.02Benzene 2017-02-090.02 2017-02-06

mg/kg dry< 0.05Ethylbenzene 2017-02-090.05 2017-02-06

mg/kg dry< 0.04Methyl tert-butyl ether 2017-02-090.04 2017-02-06

mg/kg dry< 0.05Styrene 2017-02-090.05 2017-02-06

mg/kg dry< 0.20Toluene 2017-02-090.20 2017-02-06

mg/kg dry< 0.10Xylenes (total) 2017-02-090.10 2017-02-06

2017-02-09135 60-140Surrogate: Toluene-d8 2017-02-06%

2017-02-09130 60-140Surrogate: 4-Bromofluorobenzene 2017-02-06%

2017-02-09117 60-140Surrogate: 1,4-Dichlorobenzene-d4 2017-02-06%


General Parameters

% wet29.6Moisture 2017-02-090.1 N/A


mg/kg dry< 20VHs (6-10) 2017-02-0920 2017-02-06


mg/kg dry< 50EPHs10-19 2017-02-1050 2017-02-08

mg/kg dry< 60EPHs19-32 2017-02-1050 2017-02-08 RS3



mg/kg dry< 0.02Benzene 2017-02-090.02 2017-02-06



mg/kg dry< 0.05Styrene 2017-02-090.05 2017-02-06

mg/kg dry< 0.20Toluene 2017-02-090.20 2017-02-06






REPORTED TO

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REPORTED 2017-02-15


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Analyte Result /

Recovery

MRL /

Limits



General Parameters

% wet27.7Moisture 2017-02-090.1 N/A




mg/kg dry3.9Arsenic 2017-02-090.4 2017-02-08

mg/kg dry135Barium 2017-02-091 2017-02-08


mg/kg dry5Boron 2017-02-092 2017-02-08

mg/kg dry0.70Cadmium 2017-02-090.04 2017-02-08


mg/kg dry10.2Cobalt 2017-02-090.1 2017-02-08

mg/kg dry43.5Copper 2017-02-090.2 2017-02-08

mg/kg dry21.9Lead 2017-02-090.2 2017-02-08

mg/kg dry16.8Lithium 2017-02-090.1 2017-02-08


mg/kg dry0.10Mercury 2017-02-090.04 2017-02-08


mg/kg dry28.9Nickel 2017-02-090.4 2017-02-08

mg/kg dry0.5Selenium 2017-02-090.5 2017-02-08

mg/kg dry0.3Silver 2017-02-090.2 2017-02-08

mg/kg dry74.5Strontium 2017-02-090.2 2017-02-08


mg/kg dry0.9Tin 2017-02-090.2 2017-02-08

mg/kg dry1.17Uranium 2017-02-090.05 2017-02-08


mg/kg dry126Zinc 2017-02-092 2017-02-08


mg/kg dry< 20VHs (6-10) 2017-02-0920 2017-02-06


mg/kg dry< 50EPHs10-19 2017-02-1050 2017-02-08

mg/kg dry91EPHs19-32 2017-02-1050 2017-02-08


mg/kg dry91HEPHs N/A50 N/A








mg/kg dry0.06Benzo (b) fluoranthene 2017-02-100.05 2017-02-08


mg/kg dry0.07Benzo (g,h,i) perylene 2017-02-100.05 2017-02-08


REPORTED TO

PROJECT


REPORTED 2017-02-15


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Analyte Result /

Recovery

MRL /

Limits



Polycyclic Aromatic Hydrocarbons (PAH), Continued




mg/kg dry0.07Fluoranthene 2017-02-100.05 2017-02-08





mg/kg dry0.06Pyrene 2017-02-100.05 2017-02-08






Volatile Organic Compounds (VOC) RS2

mg/kg dry< 0.02Benzene 2017-02-090.02 2017-02-06



mg/kg dry< 0.06Styrene 2017-02-090.05 2017-02-06

mg/kg dry< 0.22Toluene 2017-02-090.20 2017-02-06






General Parameters

% wet8.3Moisture 2017-02-090.1 N/A




mg/kg dry4.0Arsenic 2017-02-090.4 2017-02-08

mg/kg dry125Barium 2017-02-091 2017-02-08


mg/kg dry< 2Boron 2017-02-092 2017-02-08

mg/kg dry0.38Cadmium 2017-02-090.04 2017-02-08


mg/kg dry12.9Cobalt 2017-02-090.1 2017-02-08

mg/kg dry31.4Copper 2017-02-090.2 2017-02-08

mg/kg dry5.5Lead 2017-02-090.2 2017-02-08

mg/kg dry9.4Lithium 2017-02-090.1 2017-02-08


mg/kg dry< 0.04Mercury 2017-02-090.04 2017-02-08


REPORTED TO

PROJECT


REPORTED 2017-02-15


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Analyte Result /

Recovery

MRL /

Limits



Strong Acid Leachable Metals, Continued


mg/kg dry37.4Nickel 2017-02-090.4 2017-02-08


mg/kg dry< 0.2Silver 2017-02-090.2 2017-02-08



mg/kg dry0.5Tin 2017-02-090.2 2017-02-08

mg/kg dry0.62Uranium 2017-02-090.05 2017-02-08


mg/kg dry79Zinc 2017-02-092 2017-02-08


mg/kg dry< 20VHs (6-10) 2017-02-0920 2017-02-06


mg/kg dry< 50EPHs10-19 2017-02-1050 2017-02-08

mg/kg dry< 50EPHs19-32 2017-02-1050 2017-02-08









mg/kg dry0.08Benzo (a) pyrene 2017-02-100.05 2017-02-08

mg/kg dry0.07Benzo (b) fluoranthene 2017-02-100.05 2017-02-08

mg/kg dry0.12Benzo (b+j) fluoranthene 2017-02-100.10 2017-02-08

mg/kg dry0.08Benzo (g,h,i) perylene 2017-02-100.05 2017-02-08


mg/kg dry0.06Chrysene 2017-02-100.05 2017-02-08


mg/kg dry0.07Fluoranthene 2017-02-100.05 2017-02-08


mg/kg dry0.08Indeno (1,2,3-cd) pyrene 2017-02-100.05 2017-02-08



mg/kg dry0.10Pyrene 2017-02-100.05 2017-02-08







mg/kg dry< 0.02Benzene 2017-02-090.02 2017-02-06



REPORTED TO

PROJECT


REPORTED 2017-02-15


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Analyte Result /

Recovery

MRL /

Limits



Volatile Organic Compounds (VOC), Continued


mg/kg dry< 0.05Styrene 2017-02-090.05 2017-02-06

mg/kg dry< 0.20Toluene 2017-02-090.20 2017-02-06






General Parameters

% wet5.3Moisture 2017-02-090.1 N/A




mg/kg dry3.4Arsenic 2017-02-090.4 2017-02-08

mg/kg dry127Barium 2017-02-091 2017-02-08


mg/kg dry< 2Boron 2017-02-092 2017-02-08

mg/kg dry0.28Cadmium 2017-02-090.04 2017-02-08


mg/kg dry12.3Cobalt 2017-02-090.1 2017-02-08

mg/kg dry25.8Copper 2017-02-090.2 2017-02-08

mg/kg dry3.5Lead 2017-02-090.2 2017-02-08

mg/kg dry6.3Lithium 2017-02-090.1 2017-02-08


mg/kg dry< 0.04Mercury 2017-02-090.04 2017-02-08


mg/kg dry39.2Nickel 2017-02-090.4 2017-02-08


mg/kg dry< 0.2Silver 2017-02-090.2 2017-02-08


mg/kg dry< 0.1Thallium 2017-02-090.1 2017-02-08

mg/kg dry0.4Tin 2017-02-090.2 2017-02-08

mg/kg dry0.44Uranium 2017-02-090.05 2017-02-08


mg/kg dry68Zinc 2017-02-092 2017-02-08


mg/kg dry< 20VHs (6-10) 2017-02-0920 2017-02-06


mg/kg dry< 50EPHs10-19 2017-02-1050 2017-02-08

mg/kg dry< 50EPHs19-32 2017-02-1050 2017-02-08




REPORTED TO

PROJECT


REPORTED 2017-02-15


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Analyte Result /

Recovery

MRL /

Limits



BCMOE Aggregate Hydrocarbons, Continued








mg/kg dry< 0.05Benzo (b) fluoranthene 2017-02-100.05 2017-02-08


mg/kg dry< 0.05Benzo (g,h,i) perylene 2017-02-100.05 2017-02-08




mg/kg dry< 0.05Fluoranthene 2017-02-100.05 2017-02-08





mg/kg dry< 0.05Pyrene 2017-02-100.05 2017-02-08







mg/kg dry< 0.02Benzene 2017-02-090.02 2017-02-06



mg/kg dry< 0.05Styrene 2017-02-090.05 2017-02-06

mg/kg dry< 0.20Toluene 2017-02-090.20 2017-02-06






General Parameters

% wet7.1Moisture 2017-02-090.1 N/A


mg/kg dry< 20VHs (6-10) 2017-02-0920 2017-02-06


mg/kg dry< 50EPHs10-19 2017-02-1050 2017-02-08

mg/kg dry< 50EPHs19-32 2017-02-1050 2017-02-08


REPORTED TO

PROJECT


REPORTED 2017-02-15


644611

7020468

Analyte Result /

Recovery

MRL /

Limits



BCMOE Aggregate Hydrocarbons, Continued



mg/kg dry< 0.02Benzene 2017-02-090.02 2017-02-06



mg/kg dry< 0.05Styrene 2017-02-090.05 2017-02-06

mg/kg dry< 0.20Toluene 2017-02-090.20 2017-02-06





Sample / Analysis Qualifiers:

RS2 Reported Detection Limits (RDL) for this sample have been raised due to limited sample volume.

RS3 Reported Detection Limits (RDL) for this sample have been raised due to high moisture and/or organic

content.


REPORTED TO

PROJECT


REPORTED 2017-02-15

APPENDIX 1: QUALITY CONTROL DATA

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7020468

The following section displays the quality control (QC) data that is associated with your sample data. Groups of samples are prepared

in �batches� and analyzed in conjunction with QC samples that ensure your data is of the highest quality. Common QC types include:

� Method Blank (Blk): Laboratory reagent water is carried through sample preparation and analysis steps. Method Blanks indicate

that results are free from contamination, i.e. not biased high from sources such as the sample container or the laboratory

environment

� Duplicate (Dup): Preparation and analysis of a replicate aliquot of a sample. Duplicates provide a measure of the analytical

method�s precision, i.e. how reproducible a result is. Duplicates are only reported if they are associated with your sample data.

� Blank Spike (BS): A known amount of standard is carried through sample preparation and analysis steps. Blank Spikes, also

known as laboratory control samples (LCS), are prepared from a different source of standard than used for the calibration. They

ensure that the calibration is acceptable (i.e. not biased high or low) and also provide a measure of the analytical method�s

accuracy (i.e. closeness of the result to a target value).

� Standard Reference Material (SRM): A material of similar matrix to the samples, externally certified for the parameter(s) listed.

Standard Reference Materials ensure that the preparation steps in the method are adequate to achieve acceptable recoveries of

the parameter(s) tested.

Each QC type is analyzed at a 5-10% frequency, i.e. one blank/duplicate/spike for every 10 samples. For all types of QC, the specified

recovery (% Rec) and relative percent difference (RPD) limits are derived from long-term method performance averages and/or

prescribed by the reference method.

Analyte Result MRL UnitsSpike

Level

Source

Result% REC

REC

Limit% RPD

RPD

LimitNotes

BCMOE Aggregate Hydrocarbons, Batch B7B0467

Blank (B7B0467-BLK1) Prepared: 2017-02-08, Analyzed: 2017-02-09

mg/kg wetEPHs10-19 < 50 50

mg/kg wet< 50EPHs19-32 50

mg/kg wet 60-140Surrogate: 2-Methylnonane 8814.6 16.6

LCS (B7B0467-BS2) Prepared: 2017-02-08, Analyzed: 2017-02-09

70-13077mg/kg wetEPHs10-19 2200 50 2870

mg/kg wet 70-130763100EPHs19-32 50 4140


Duplicate (B7B0467-DUP1) Prepared: 2017-02-08, Analyzed: 2017-02-10Source: 7020468-01

mg/kg dryEPHs10-19 < 50< 50 4050

mg/kg dry< 50 < 50EPHs19-32 4050

mg/kg dry 60-140Surrogate: 2-Methylnonane 9219.7 21.5

Reference (B7B0467-SRM2) Prepared: 2017-02-08, Analyzed: 2017-02-10

65-13084mg/kg wetEPHs10-19 2500 50 3020

mg/kg wet 65-1301024400EPHs19-32 50 4330


BCMOE Aggregate Hydrocarbons, Batch B7B0476


mg/kg wetVHs (6-10) < 20 20


70-13091mg/kg wetVHs (6-10) 380 20 413

General Parameters, Batch B7B0463


4.6% wetMoisture 29.631.0 8.30.1


REPORTED TO

PROJECT


REPORTED 2017-02-15


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Level

Source

Result% REC

REC

Limit% RPD

RPD

LimitNotes

General Parameters, Batch B7B0498


< 1pH unitspH (1:2 H2O Solution) 9.69.5 40.1


95-105102pH unitspH (1:2 H2O Solution) 6.1 0.1 6.01

Polycyclic Aromatic Hydrocarbons (PAH), Batch B7B0467


mg/kg wetAcenaphthene < 0.05 0.05

mg/kg wet< 0.05Acenaphthylene 0.05

mg/kg wet< 0.05Anthracene 0.05

mg/kg wet< 0.05Benz (a) anthracene 0.05

mg/kg wet< 0.05Benzo (a) pyrene 0.05

mg/kg wet< 0.05Benzo (b) fluoranthene 0.05

mg/kg wet< 0.10Benzo (b+j) fluoranthene 0.10

mg/kg wet< 0.05Benzo (g,h,i) perylene 0.05

mg/kg wet< 0.05Benzo (k) fluoranthene 0.05

mg/kg wet< 0.05Chrysene 0.05

mg/kg wet< 0.05Dibenz (a,h) anthracene 0.05

mg/kg wet< 0.05Fluoranthene 0.05

mg/kg wet< 0.05Fluorene 0.05

mg/kg wet< 0.05Indeno (1,2,3-cd) pyrene 0.05

mg/kg wet< 0.05Naphthalene 0.05

mg/kg wet< 0.05Phenanthrene 0.05

mg/kg wet< 0.05Pyrene 0.05

mg/kg wet 72-117Surrogate: Naphthalene-d8 1121.86 1.66

mg/kg wet 74-111Surrogate: Acenaphthene-d10 1041.72 1.66

mg/kg wet 60-106Surrogate: Phenanthrene-d10 991.64 1.66

mg/kg wet 60-125Surrogate: Chrysene-d12 981.62 1.66

mg/kg wet 60-121Surrogate: Perylene-d12 921.53 1.66


70-115102mg/kg wetAcenaphthene 1.55 0.05 1.52

mg/kg wet 70-1141121.71Acenaphthylene 0.05 1.52

mg/kg wet 70-1101061.61Anthracene 0.05 1.52

mg/kg wet 66-1141011.54Benz (a) anthracene 0.05 1.52

mg/kg wet 62-122961.46Benzo (a) pyrene 0.05 1.52

mg/kg wet 54-1211171.78Benzo (b) fluoranthene 0.05 1.52

mg/kg wet 70-1301113.38Benzo (b+j) fluoranthene 0.10 3.04

mg/kg wet 64-1171081.65Benzo (g,h,i) perylene 0.05 1.52

mg/kg wet 69-1191091.66Benzo (k) fluoranthene 0.05 1.52

mg/kg wet 67-120991.50Chrysene 0.05 1.52

mg/kg wet 63-1151021.56Dibenz (a,h) anthracene 0.05 1.52

mg/kg wet 72-1121111.68Fluoranthene 0.05 1.52

mg/kg wet 70-108971.47Fluorene 0.05 1.52

mg/kg wet 65-1181031.57Indeno (1,2,3-cd) pyrene 0.05 1.52

mg/kg wet 70-115861.32Naphthalene 0.05 1.52

mg/kg wet 70-1111051.59Phenanthrene 0.05 1.52

mg/kg wet 73-1121111.69Pyrene 0.05 1.52







REPORTED TO

PROJECT


REPORTED 2017-02-15


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7020468


Level

Source

Result% REC

REC

Limit% RPD

RPD

LimitNotes

Polycyclic Aromatic Hydrocarbons (PAH), Batch B7B0467, Continued


mg/kg dryAcenaphthene < 0.05< 0.05 500.05

mg/kg dry< 0.05 < 0.05Acenaphthylene 500.05

mg/kg dry< 0.05 < 0.05Anthracene 500.05

mg/kg dry< 0.05 < 0.05Benz (a) anthracene 500.05

mg/kg dry< 0.05 < 0.05Benzo (a) pyrene 500.05

mg/kg dry< 0.05 < 0.05Benzo (b) fluoranthene 500.05

mg/kg dry< 0.10 < 0.10Benzo (b+j) fluoranthene 500.10

mg/kg dry< 0.05 < 0.05Benzo (g,h,i) perylene 500.05

mg/kg dry< 0.05 < 0.05Benzo (k) fluoranthene 500.05

mg/kg dry< 0.05 < 0.05Chrysene 500.05

mg/kg dry< 0.05 < 0.05Dibenz (a,h) anthracene 500.05

mg/kg dry< 0.05 < 0.05Fluoranthene 500.05

mg/kg dry< 0.05 < 0.05Fluorene 500.05

mg/kg dry< 0.05 < 0.05Indeno (1,2,3-cd) pyrene 500.05

mg/kg dry< 0.05 < 0.05Naphthalene 500.05

mg/kg dry< 0.05 < 0.05Phenanthrene 500.05

mg/kg dry< 0.05 < 0.05Pyrene 500.05

mg/kg dry 72-117Surrogate: Naphthalene-d8 1152.48 2.15

mg/kg dry 74-111Surrogate: Acenaphthene-d10 1052.26 2.15

mg/kg dry 60-106Surrogate: Phenanthrene-d10 1012.18 2.15

mg/kg dry 60-125Surrogate: Chrysene-d12 1012.16 2.15

mg/kg dry 60-121Surrogate: Perylene-d12 932.01 2.15


6.69-19339mg/kg wetAcenaphthene 0.10 0.05 0.260

mg/kg wet 34.45-165450.17Anthracene 0.05 0.390

mg/kg wet 70-130932.59Benz (a) anthracene 0.05 2.80

mg/kg wet 0.02-200300.12Benzo (a) pyrene 0.05 0.406

mg/kg wet 56-1441221.90Benzo (b) fluoranthene 0.05 1.56

mg/kg wet 35-165894.22Benzo (g,h,i) perylene 0.05 4.72

mg/kg wet 50-1501304.96Benzo (k) fluoranthene 0.05 3.82

mg/kg wet 53-1471006.79Chrysene 0.05 6.79

mg/kg wet 43-1581095.23Dibenz (a,h) anthracene 0.05 4.80

mg/kg wet 57-1431154.45Fluoranthene 0.05 3.87

mg/kg wet 54-146623.53Fluorene 0.05 5.67

mg/kg wet 42-158991.82Indeno (1,2,3-cd) pyrene 0.05 1.84

mg/kg wet 50-150941.13Naphthalene 0.05 1.20

mg/kg wet 55-1461162.20Phenanthrene 0.05 1.90

mg/kg wet 58-1421210.75Pyrene 0.05 0.620






Strong Acid Leachable Metals, Batch B7B0450


mg/kg dryAntimony < 0.1 0.1

mg/kg dry< 0.4Arsenic 0.4

mg/kg dry< 1Barium 1

mg/kg dry< 0.1Beryllium 0.1

mg/kg dry< 2Boron 2

mg/kg dry< 0.04Cadmium 0.04

mg/kg dry< 1.0Chromium 1.0

mg/kg dry< 0.1Cobalt 0.1


REPORTED TO

PROJECT


REPORTED 2017-02-15


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Level

Source

Result% REC

REC

Limit% RPD

RPD

LimitNotes

Strong Acid Leachable Metals, Batch B7B0450, Continued

Blank (B7B0450-BLK1), Continued Prepared: 2017-02-08, Analyzed: 2017-02-09

mg/kg dry< 0.2Copper 0.2

mg/kg dry< 0.2Lead 0.2

mg/kg dry< 0.1Lithium 0.1

mg/kg dry< 0.4Manganese 0.4

mg/kg dry< 0.04Mercury 0.04

mg/kg dry< 0.1Molybdenum 0.1

mg/kg dry< 0.4Nickel 0.4

mg/kg dry< 0.5Selenium 0.5

mg/kg dry< 0.2Silver 0.2

mg/kg dry< 0.2Strontium 0.2

mg/kg dry< 0.1Thallium 0.1

mg/kg dry< 0.2Tin 0.2

mg/kg dry< 0.05Uranium 0.05

mg/kg dry< 0.4Vanadium 0.4

mg/kg dry< 2Zinc 2


mg/kg dryAntimony 0.20.2 600.1

mg/kg dry 103.1 3.4Arsenic 420.4

mg/kg dry 23101 127Barium 381

mg/kg dry0.4 0.4Beryllium 370.1

mg/kg dry< 2 < 2Boron 292

mg/kg dry 120.25 0.28Cadmium 320.04

mg/kg dry RPD4142.2 27.9Chromium 321.0

mg/kg dry 249.7 12.3Cobalt 260.1

mg/kg dry 2120.9 25.8Copper 380.2

mg/kg dry < 13.6 3.5Lead 460.2

mg/kg dry 177.5 6.3Lithium 280.1

mg/kg dry 18498 594Manganese 230.4

mg/kg dry< 0.04 < 0.04Mercury 420.04

mg/kg dry 150.7 0.8Molybdenum 520.1

mg/kg dry 2430.8 39.2Nickel 290.4

mg/kg dry< 0.5 < 0.5Selenium 190.5

mg/kg dry< 0.2 < 0.2Silver 350.2

mg/kg dry 1987.0 105Strontium 250.2

mg/kg dry0.1 < 0.1Thallium 270.1

mg/kg dry0.3 0.4Tin 850.2

mg/kg dry 90.48 0.44Uranium 360.05

mg/kg dry 2257.7 71.9Vanadium 230.4

mg/kg dry 2155 68Zinc 302


73-13888mg/kg dryAntimony 5.5 0.1 6.27

mg/kg dry 87-10610315.8Arsenic 0.4 15.4

mg/kg dry 72-1199879Barium 1 80.6

mg/kg dry 73-128900.5Beryllium 0.1 0.544

mg/kg dry 58-1391043Boron 2 2.68

mg/kg dry 88-121930.21Cadmium 0.04 0.230

mg/kg dry 91-11310027.3Chromium 1.0 27.2

mg/kg dry 90-10910112.6Cobalt 0.1 12.5

mg/kg dry 92-11210145.2Copper 0.2 44.9

mg/kg dry 89-1118912.8Lead 0.2 14.4

mg/kg dry 73-1241029.4Lithium 0.1 9.26

mg/kg dry 93-112931020Manganese 0.4 1100

mg/kg dry 74-126770.08Mercury 0.04 0.0980

mg/kg dry 93-1201020.8Molybdenum 0.1 0.738

mg/kg dry 93-11010017.3Nickel 0.4 17.4


REPORTED TO

PROJECT


REPORTED 2017-02-15


644611

7020468


Level

Source

Result% REC

REC

Limit% RPD

RPD

LimitNotes

Strong Acid Leachable Metals, Batch B7B0450, Continued

Reference (B7B0450-SRM1), Continued Prepared: 2017-02-08, Analyzed: 2017-02-09

mg/kg dry 85-1169310.8Strontium 0.2 11.6

mg/kg dry 78-120790.9Tin 0.2 1.10

mg/kg dry 80-102890.84Uranium 0.05 0.940

mg/kg dry 87-1169853.6Vanadium 0.4 54.9

mg/kg dry 91-1139564Zinc 2 67.5

Volatile Organic Compounds (VOC), Batch B7B0476


mg/kg wetBenzene < 0.02 0.02

mg/kg wet< 0.05Ethylbenzene 0.05

mg/kg wet< 0.04Methyl tert-butyl ether 0.04

mg/kg wet< 0.05Styrene 0.05

mg/kg wet< 0.20Toluene 0.20

mg/kg wet< 0.10Xylenes (total) 0.10

mg/kg wet 60-140Surrogate: Toluene-d8 999.94 10.0

mg/kg wet 60-140Surrogate: 4-Bromofluorobenzene 979.66 10.0

mg/kg wet 60-140Surrogate: 1,4-Dichlorobenzene-d4 888.83 10.0


70-130113mg/kg wetBenzene 2.26 0.02 2.00

mg/kg wet 70-1301112.21Ethylbenzene 0.05 2.00

mg/kg wet 70-130921.84Methyl tert-butyl ether 0.04 2.00

mg/kg wet 70-1301042.08Styrene 0.05 2.00

mg/kg wet 70-1301132.26Toluene 0.20 2.00

mg/kg wet 70-1301086.47Xylenes (total) 0.10 6.00

mg/kg wet 60-140Surrogate: Toluene-d8 10110.1 10.0

mg/kg wet 60-140Surrogate: 4-Bromofluorobenzene 989.77 10.0

mg/kg wet 60-140Surrogate: 1,4-Dichlorobenzene-d4 10310.3 10.0

QC Qualifiers:

RPD Relative percent difference (RPD) of duplicate analysis are outside of control limits for unknown reason(s).


REPORTED TO

PROJECT


REPORTED 2017-02-15

APPENDIX 2: ANALYTICAL SUMMARY

644611

7020468

7020468-01 7020468-02 7020468-06 7020468-08 7020468-12 7020468-13

Soil Soil Soil Soil Soil Soil

2017-02-06 2017-02-06 2017-02-06 2017-02-06 2017-02-06 2017-02-06

TH01-17-01-01

-170206

TH01-17-01-02

-170206

TH02-17-02-01

-170206

TH02-17-02-03

-170206

TH03-17-03-01

-170206

TH03-17-03-02

-170206

General Parameters Moisture (% wet) 27.3 29.6 27.7 8.3 5.3 7.1

pH (1:2 H2O Solution) (pH units) 8.8 7.7 9.0 9.6

Strong Acid Leachable

Metals

Antimony (mg/kg dry) 0.3 0.6 0.2 0.2

Arsenic (mg/kg dry) 6.1 3.9 4.0 3.4

Barium (mg/kg dry) 265 135 125 127

Beryllium (mg/kg dry) 0.9 0.5 0.4 0.4

Boron (mg/kg dry) < 2 5 < 2 < 2

Cadmium (mg/kg dry) 0.33 0.70 0.38 0.28

Chromium (mg/kg dry) 85.0 38.4 31.2 27.9

Cobalt (mg/kg dry) 24.3 10.2 12.9 12.3

Copper (mg/kg dry) 59.2 43.5 31.4 25.8

Lead (mg/kg dry) 14.8 21.9 5.5 3.5

Lithium (mg/kg dry) 37.7 16.8 9.4 6.3

Manganese (mg/kg dry) 888 479 582 594

Mercury (mg/kg dry) < 0.04 0.10 < 0.04 < 0.04

Molybdenum (mg/kg dry) 1.5 1.6 1.4 0.8

Nickel (mg/kg dry) 69.3 28.9 37.4 39.2

Selenium (mg/kg dry) < 0.5 0.5 < 0.5 < 0.5

Silver (mg/kg dry) < 0.2 0.3 < 0.2 < 0.2

Strontium (mg/kg dry) 144 74.5 130 105

Thallium (mg/kg dry) 0.3 0.2 0.1 < 0.1

Tin (mg/kg dry) 1.0 0.9 0.5 0.4

Uranium (mg/kg dry) 1.70 1.17 0.62 0.44

Vanadium (mg/kg dry) 88.6 46.7 81.4 71.9

Zinc (mg/kg dry) 119 126 79 68

BCMOE Aggregate

Hydrocarbons

VHs (6-10) (mg/kg dry) < 20 < 20 < 20 < 20 < 20 < 20

VPHs (mg/kg dry) < 20 < 20 < 20 < 20 < 20 < 20

EPHs10-19 (mg/kg dry) < 50 < 50 < 50 < 50 < 50 < 50

EPHs19-32 (mg/kg dry) < 50 < 60 91 < 50 < 50 < 50

LEPHs (mg/kg dry) < 50 < 50 < 50 < 50

HEPHs (mg/kg dry) < 50 91 < 50 < 50

Sur: 2-Methylnonane (%) 91 92 87 88 85 93

Polycyclic Aromatic

Hydrocarbons (PAH)

Acenaphthene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Acenaphthylene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Anthracene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Benz (a) anthracene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Benzo (a) pyrene (mg/kg dry) < 0.05 < 0.05 0.08 < 0.05

Benzo (b) fluoranthene (mg/kg dry) < 0.05 0.06 0.07 < 0.05

Benzo (b+j) fluoranthene (mg/kg dry) < 0.10 < 0.10 0.12 < 0.10

Benzo (g,h,i) perylene (mg/kg dry) < 0.05 0.07 0.08 < 0.05

Benzo (k) fluoranthene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Chrysene (mg/kg dry) < 0.05 < 0.05 0.06 < 0.05

Dibenz (a,h) anthracene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Fluoranthene (mg/kg dry) < 0.05 0.07 0.07 < 0.05


REPORTED TO

PROJECT


REPORTED 2017-02-15

APPENDIX 2: ANALYTICAL SUMMARY

644611

7020468

7020468-01 7020468-02 7020468-06 7020468-08 7020468-12 7020468-13

Soil Soil Soil Soil Soil Soil

2017-02-06 2017-02-06 2017-02-06 2017-02-06 2017-02-06 2017-02-06

TH01-17-01-01

-170206

TH01-17-01-02

-170206

TH02-17-02-01

-170206

TH02-17-02-03

-170206

TH03-17-03-01

-170206

TH03-17-03-02

-170206

Polycyclic Aromatic

Hydrocarbons (PAH)

Fluorene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Indeno (1,2,3-cd) pyrene (mg/kg dry) < 0.05 < 0.05 0.08 < 0.05

Naphthalene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Phenanthrene (mg/kg dry) < 0.05 < 0.05 < 0.05 < 0.05

Pyrene (mg/kg dry) < 0.05 0.06 0.10 < 0.05

Sur: Naphthalene-d8 (%) 115 111 112 108

Sur: Acenaphthene-d10 (%) 104 99 101 98

Sur: Phenanthrene-d10 (%) 101 96 98 94

Sur: Chrysene-d12 (%) 99 92 97 94

Sur: Perylene-d12 (%) 93 88 93 86

Volatile Organic

Compounds (VOC)

Benzene (mg/kg dry) < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02

Ethylbenzene (mg/kg dry) < 0.05 < 0.05 < 0.06 < 0.05 < 0.05 < 0.05

Methyl tert-butyl ether (mg/kg dry) < 0.04 < 0.04 < 0.04 < 0.04 < 0.04 < 0.04

Styrene (mg/kg dry) < 0.05 < 0.05 < 0.06 < 0.05 < 0.05 < 0.05

Toluene (mg/kg dry) < 0.20 < 0.20 < 0.22 < 0.20 < 0.20 < 0.20

Xylenes (total) (mg/kg dry) < 0.10 < 0.10 < 0.10 < 0.10 < 0.10 < 0.10

Sur: Toluene-d8 (%) 135 110 94 97 96 98

Sur: 4-Bromofluorobenzene (%) 130 104 89 94 90 91

Sur: 1,4-Dichlorobenzene-d4 (%) 117 95 79 84 84 84


REPORTED TO

PROJECT


REPORTED 2017-02-15

APPENDIX 3: REVISION HISTORY

644611

7020468

AnalysisChangeChangedSample ID Analyte(s)

Sample ID2017-02-157020468-06 N/A N/A

Sample ID2017-02-157020468-07 N/A N/A

Sample ID2017-02-157020468-08 N/A N/A

Sample ID2017-02-157020468-09 N/A N/A

Sample ID2017-02-157020468-10 N/A N/A

Sample ID2017-02-157020468-11 N/A N/A

Sample ID2017-02-157020468-12 N/A N/A

Sample ID2017-02-157020468-13 N/A N/A

Sample ID2017-02-157020468-14 N/A N/A

Sample ID2017-02-157020468-15 N/A N/A

Sample ID2017-02-157020468-16 N/A N/A

Sample ID2017-02-157020468-17 N/A N/A


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REFERENCE: Environmental Soil Sampling Report …...644611 / 2017 02 14 P:\CP\MoTI\644611_Vernon...

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