8/18/2019 result+DEST+lab

1/25

  TABLA DE CONTENIDO  TABLA DE CONTENIDO

NN00 PAG.PAG.

1.- INDICE DE TABLAS1.- INDICE DE TABLAS 22

2.- INDICE DE GRAFICOS2.- INDICE DE GRAFICOS 33

3.- RESUMEN3.- RESUMEN 44

4.- INTRODUCCION4.- INTRODUCCION 55

5.- PRINCIPIOS TEORICOS5.- PRINCIPIOS TEORICOS 66

6.- DETALLES EXPERIMENTALES6.- DETALLES EXPERIMENTALES 1010

7.- TABLAS DE DATOS Y RESULTADOS7.- TABLAS DE DATOS Y RESULTADOS 1111

8.- DISCUSION DE RESULTADOS8.- DISCUSION DE RESULTADOS 1414

.- CONCLUSIONES.- CONCLUSIONES 1515

8/18/2019 result+DEST+lab

2/25

INDICE DE TABLAS

 

NN00 PAG.PAG.

 T/%/ N 1 C&'(&"+ '" L/&,/&,&  11

 T/%/ N 2 D#"+&"+ '" %/ (&%*#/ 11

 T/%/ N 3 P,&$"'/'"+ F+(/+ '" %/+ S*+/(/+ 11

 T/%/ N 4 D/&+ E$",#"/%"+ 11

 T/%/ N 5 D/&+ '" &$",/( /& $/,/ "% &$" /%#"/( 9C&%/+.

12

 T/%/ N 6 D/&+ '" E:*%,& $/,/ "% ++"#/ E/&%-A;*/. 12

 T/%/ N7 F,/((&"+ #&%/,"+ '"% "/&% " "% '"+%/'& ,"+'*& 9/%#"/( 13

 T/%/ N 8 R"+*%/'&+ &"'&+ $/,/ %/ '"",#/( '"%

8/18/2019 result+DEST+lab

3/25

NPAG

.

G,)(/ N=1 G,)(/ N=1 D/;,/#/ M( C/" T>"%" $/,/ #*"+,/ 1 24

G,)(/ N=2 G,)(/ N=2 D/;,/#/ M( C/" T>"%" $/,/ #*"+,/ 2 

25

8/18/2019 result+DEST+lab

4/25

E %/ $,"+"" $,/((/ +" ,"/%?/ "% "+*'& '" %/ '"+%/( '" */#"?(%/ /,/ '" "/&%-/;*/ '"'" 6= 9 10= /%(&>%(&+ $/,/ %& (*/% +" *%?/ */(&%*#/ "#$/(/'/ (&""'& /%%&+ ,/+(>; (& ,"%*!& &/% +" ,//!/ /%/ $,"+ '" 4 $+.

P/,/ $&'", ,"/%?/, %&+ ()%(*%&+ +" / %&+ '/&+ '" ":*%,& '" "/&%-/;*/. L/ ($&+( '" "/&% " %/ /%#"/( "+ '" 0.03 9 0.01 #&%"+ '""/&% $&, #&% '" #"?(%/ / 6= 9 10= ,"+$"(@/#"". C*/'& %/+ "#$",/*,/+'" %/ (&%*#/ /& " "% &'& (& " "% &$" +" #/"" (&+/"+'"+$*+ '" * '"",#/'& "#$& +" / %/+ #*"+,/+ ,"+$"(@/#"".

L/ ($&+( $/,/ "% '"+%/'& "+ '" 0.78 9 0.85 #&%"+ '" "/&% $&,

#&% '" #"?(%/ / 6= 9 10= ,"+$"(@/#"". Y /%#"" %/ ($&+( $/,/,"+'*& "+ '" 0.016 9 0.026.

P/,/ '"",#/, "%

8/18/2019 result+DEST+lab

5/25

L/ +"$/,/( '" '(>/ #"?(%/ "+ $&, @/$&,?/( $/,(/% '" %/ #+#/ '"/% #/",/ :*" %/ ($&+( '"% @/$&, &"'& +"/ '+/ '" %/ ($&+('"% %:*'& '" $/,'/ ,"+*%/'& '+/ /# %/ ($&+( '"% %:*'&

,"+'*/%.

E %/+ &$",/(&"+ '+(&*/+ +" (/,;/ */ (/'/' (/% '" #/",/%" "% ":*$& 9 '*,/" %/ &$",/( +" ,",/ '" &,#/ (&*/ */ & #)+/+"+. U "!"#$%& /#%/, "+ %/ '"+%/( &,'/,/ '" %/&,/&,& " %/ :*" +"(/,;/ %:*'& " * (/%'", 9 +" (/%"/ >/+/ "*%%(. E% @/$&, :*" +" &,#/+" ,",/ 9 (&'"+/ '" &,#/ (&*/.

E %/+ +"$/,/(&"+ '+(&*/+ & +" /%(/?/ "% "+/'& "+/(&/,& 9 %/($&+( '" %/ (/,;/ (/% @/,/ (& "% "#$&. E+& '/ %*;/, / * /*#"&'" %/ "#$",/*,/ '"% ++"#/ 9 / */ '+#*( '" %/ (/'/' ,"%/@/ '" %&+($&""+ '" #"&, "#$",/*,/ '" "*%%( " %/ (/,;/ /% /@/?/, %/'"+%/(.

E% &!"@& '" %/ $,"+"" $,)((/ "+ '"",#/, "% /9 " */ '"+%/( '" */ #"?(%/ /,/ "/&% - /;*/ (&

,"%*!& &/% #"'/" "% #&'& '" M( C/".

8/18/2019 result+DEST+lab

6/25

DESTILACIÓN

E+ %/ &$",/( :*" "" $&, &!"& @/$&,?/, $/,(/%#"" */ #"?(%/ %:*'/+"$/,/'& "% @/$&, '"% %:*'& 9 (&'"+)'&%& + :*" >/9/ "," /#&+

$&+",&, ,/+","(/ '" #/",/. L&+ (&+*9""+ #)+ @&%)%"+ '" %/ #"?(%/ +" &"" $&, "% &$" '" %/(&%*#/ 9 %&+ #"&+ @&%)%"+ $&, "% &'&. E% $,($& +(&:*#(& '" %/'"+%/( "+ %/ '","(/ '" %/+ "#$",/*,/+ '" "*%%( '" %&+(&+*9""+ '" %/ #"?(%/.

E+/ &$",/( $*"'" ""(*/,+" '" 2 #/",/+

1.- D"+%/( " ":*%,& & '"+%/( +

8/18/2019 result+DEST+lab

7/25

'"+%/'& &"'& / %/ (/%'","/ >/+/ :*" +" (&+;/ %/+ (&'(&"+ '"":*%,&.

M!TODO DE MC CABE T"IELE 

E+ *& '" %&+ #&'&+ #)+ /$,&$/'&+ $/,/ '"",#/, "% /+/:*" /%#"" (*/'& R 4   LJK 1 9 %/+ %"/+ '" &$",/( '" %/+ '&++"((&"+ '" %/ (&%*#/ (&('" (& %/ '/;&/% '" 45Ε   (& " %/ ;*,/

8/18/2019 result+DEST+lab

8/25

Colu%na &e Relleno 

L/+ (&%*#/+ ,"%%"/+(&++" " * (%',&

@",(/% (/,;/'& (& *#/",/% '" ,"%%"& /'"(*/'&.E% %:*'& %*9" $&, %/+*$",(" '"% #/",/% '","%%"& " %)#/+ '"%;/'/+ 9&,"(" */ ;,/ +*$",("%:*'/ $/,/ "% (&/(&(& %&+ ;/+"+ :*" /+("'"

$&, %/ &,,". E% #/",/% '","%%"& "+) +&$&,/'&+&," * ","!/'& & $/,,%%/+*/'& " "% &'& '" %/ &,,".E% %:*'& +" (/,;/ $&, %/$/," +*$",&, '"% #/",/% '","%%"& #"'/" */$%/(/ '+,*'&,/

$%/(/ $",&,/'/ 9 "%@/$&, +" ,&'*(" $&,'"/!& '"% ","!/'&:*" +&+"" /% ,"%%"&.L/+ @"/!/+ '"% %*!&" (&,/(&,,"" 9(&/(&+ #

8/18/2019 result+DEST+lab

9/25

P'esión &e (a)o'

L/ P,"+ '" @/$&, '" * %:*'& "+ %/ $,"+ '" +* @/$&, / */"#$",/*,/ '/'/ " %/ (*/% %/+ /+"+ @/$&, 9 %:*'& '" %/ +*+/(/ $*"'" "+," ":*%,&.

P*& '" R&(&

E+ %/ "#$",/*,/ / %/ (*/% "% @/$&, +/*,/'& "#$"?/ / (&'"+/,.

P*& '" B*,*!/

E+ %/ "#$",/*,/ / %/ (*/% "% %:*'& "#$"?/ / >",@,.

K&%/%'/' R"%/@/

L/ @&%/%'/' ,"%/@/ "+ */ #"''/ ',"(/ '" %/ /(%'/' (& :*" +"+"$/,/ %&+ ($&""+ " * $,&("+& '" '"+%/( 9 $&, (&+;*"" %/+

+*+/(/+ :*" +" +"$/,/ )(%#"" #*"+,/ @/%&,"+ '" ∝ "+ ;*/% / %/ *'/'& "+ $&+%" ;*/ +"$/,/(.

( )

( )**

1

1

 y x

 x y

−

−

=α 

 y* F,/(( #&%/, '"% ($&"" " "% @/$&,.  x F,/(( #&%/, '"% ($&"" " "% %:*'&.

8/18/2019 result+DEST+lab

10/25

A+ DESCRIPCIÓN DEL E,UIPO-

E% ":*$& "$",#"/% "+) (&+*'& '"

1. U/ (&%*#/ '" '"+%/( "#$/(/'/ (& /%%&+ R/+(>;

2. U (&'"+/'&,

3. U (/%'", (/%"/'& (& @/$&,

4. U /%(&>&%#",&

5. 2 ",##",&+

6. 3 $,&"/+ 9 / #*"+,/+.

7. U (,&#",&

8. A;*/ ,/

B+ PROCEDIMIENTO E*PERIMENTAL-

S" $*,;/ "% (/'", 9 +" //'" %/ #"?(%/ '" "/&%-/;*/ /% 6 '" "/&%.

L*";& '" %%"/, "% (/%'", (",,/, >",#(/#"" (& "% /$ 9 (&%&(/, %&+

",##",&+ " %&+ %*;/,"+ ,"+$"(@&+ $/,/ %/+ #"''/+ '" "#$",/*,/. T/,

*/ #*"+,/ '" "+/ /%#"/( " * ,/+(& $/,/ %*";& #"', +* $&,("/!" "

@&%*#" '" /%(&>&% " * /%(&>&%#",& / 20=C 9 %*";& %/ '"+'/' / %/ #+#/

"#$",/*,/.

8/18/2019 result+DEST+lab

11/25

TABLAS DE DATOS . RESULTADOS

Ta/la N0 1- C&'(&"+ '" L/&,/&,&

CONDICIONES DELABORATORIO

Te%)e'atu'a

21

Ta/la N0 2- D#"+&"+ '" %/ (&%*#/

DIMENSIONES DE LA COLUMNA

A%*,/ '" "#$/:*" (# 88

D)#",& "",& '" /%%&+ R/+(>; ## 8

Ta/la N0 3- P,&$"'/'"+ F+(/+ '" %/+ S*+/(/+

PROPIEDADES F4SICAS DE LAS SUSTANCIAS UTILI5ADAS

Sustancia Fó'%ula

Peso

Molecula'678%ol97:

Densi&a& a2;+0C 678%L:

E/&% C25O 46 0.78

A;*/ 2O 18 0

8/18/2019 result+DEST+lab

12/25

Ta/la N0 =- D/&+ '" &$",/( /& $/,/ "% &$" /%#"/( 9 C&%/+.

DATOS DE OPERACIÓN

M&%/, '"E/&%

F,/(( #&%/,"/&%

M&%/, '"E/&% F,/(( #&%/, "/&%

X " "% %:*'& Y " "% @/$&,

0 0 0 0

30 00 30 00

830 08 830 08100 1 100 1

Ta/la N0 >- D/&+ '" E:*%,& $/,/ "% ++"#/ E/&%-A;*/.

DATOS DE E,UILIBRIO SISTEMA ETANOL9AGUA

 T"#$",/*,/ =C

M&%/, '"E/&%

F,/(( M&%/, '"E/&%

M&%/, '"E/&%

F,/(( M&%/, '"E/&%

X " "%%:*'& X " "% %:*'&

 Y " "%@/$&, Y " "% @/$&,

10000 000 00 000 00

550 10 00 1700 02800 721 01 381 04

8670 66 01 4375 04

85 30 12 38 0 1 47 04 0 5

8/18/2019 result+DEST+lab

13/25

Muest'a 1 Muest'a 2

XD 085 078XR 003 002

XF 003 002

Ta/la N0 @- R"+*%/'&+ &"'&+ $/,/ %/ '"",#/( '"%

8/18/2019 result+DEST+lab

14/25

",/#"& " %/ $/," +*$",&,. E% "#$/:*" '" %/ (&%*#/ (&+/ '" /%%&+

R/+(>;. L/+ "+$"((/(&"+ '" %/ (&%*#/ 9 '"% "#$/:*" +" #*"+,/ " %/

 T/%/ N=2.

L/ "$","(/ +" ,"/%?/ (& #"?(%/+ /,/+ '" /%(&>&% "%(& 9 /;*/ /

'",""+ (&(",/(&"+ '" /%#"/( */ / 6= /%(&>%(&+ 9 %/ &,/ / 10=

/%(&>%(&+. L*";& +" &"" * $,&'*(& '" &$" (& 2=/%(&>%(&+ 9 5=

/%(&>%(&+ ,"+$"(@/#"" /+#+#& %/ ($&+( '" %&+ &'&+ +& 5=/%(&>%(&+ 9 8 = /%(&>%(&+ " "% #+#& &,'".

P/,/ >/%%/, "% ; +" >/(" *+& '"% #&'& '" M( C/"T>"%". E%

;,)(& 1 9 2 #*"+,/ "% #&'& '" M( C/"T>"%" %/ (*,@/ '" &$",/( "+)

'/'/ $&, %/ %"/ '" 45= 9/ :*" +" ,//!& / ,"%*!& &/%. E%

8/18/2019 result+DEST+lab

15/25

CONCLUSIONES

1. E% &% "%(& 9 /;*/ "+ '" 5= /%(&>%(&+.

8/18/2019 result+DEST+lab

16/25

RECOMENDACIONES

1. S" '"" (&,&%/, " &'& #"& %/ $,"+ '" @/$&, $/,/ :*" /%;,"+/, /% (/%'", #/";/ * %*!& '" (/%&, (&+/" " "% &'& '" %/(&%*#/.

2. A+";*,/,+" :*" %/+ #*"+,/+ '" &'& 9 &$" "+ / 20C $/,/ $&'",*%?/, " &,#/ (&,,"(/ "% /%(&>&%#",& $/,/ /!/, / "+/ "#$",/*,/ +"

,"("'/ *+/, >"%& (& ,",;",/".

8/18/2019 result+DEST+lab

17/25

BIBLIOGRAF4A

1.  T,"9/%% R&", O$",/(&"+ '" T,/+","(/ '" M/+/ E'&,/%M( G,/ %% 2'/  E'( 180 P);+. 378-340 341 387 388 34-37 411 472-475.

8/18/2019 result+DEST+lab

18/25

AP!NDICE I- EEMPLO DE CÁLCULOS

1+ Clculo &e las #'acciones %ola'es &e la ali%entación &el &estila&o &el 'esi&uo en la &estilación a %ecla N; 1

1+1 F'acción %ola' &e etanol en el &estila&o-

B/+" 100 #% '" #*"+,/.

• Moles de Etanol:

)46(

)7856.0()95(

tan

52

52

52

5252

OH  H molC OH  H  gC 

OH  H mlC 

OH  H  gC OH  H C ml 

ol edemoles

⋅

=

molesol edemoles   62.1tan   =

• Moles de Agua:

OgH

8/18/2019 result+DEST+lab

19/25

B/+" 100 #% '" #*"+,/.

•

Moles de Etanol:

)46(

)7856.0()8(

tan

52

52

52

5252

OH  H molC 

OH  H  gC 

OH  H mlC 

OH  H  gC OH  H C ml 

ol edemoles

⋅

=

molesol edemoles   136.0tan   =

• Moles de Agua:

)

18

(

)9983.0()92(

2

2

2

22

OmolH 

O gH 

OmlH 

O gH O H ml 

aguademoles

⋅

=

molesaguademoles   10.5=

• Fracción Molar de Etanol:

8/18/2019 result+DEST+lab

20/25

)18(

)9983.0()90(

2

2

2

22

OmolH 

O gH 

OmlH 

O gH O H ml 

aguademoles

⋅

=

molesaguademoles   97.4=

• Fracción Molar de Etanol:

2+ Clculo &e las #'acciones %ola'es &e la ali%entación &el &estila&o &el 'esi&uo en la &estilación-Mecla N; 2

2+1 F'acción %ola' &e etanol en el &estila&o-

B/+" 100 #% '" #*"+,/.

• Moles de Etanol:

OHHC

8/18/2019 result+DEST+lab

21/25

2+2 F'acción %ola' &e etanol en el 'esi&uo-

B/+" 100 #% '" #*"+,/.

• Moles de Etanol:

)46(

)7856.0()5(

tan

52

52

52

5252

OH  H molC 

OH  H  gC 

OH  H mlC 

OH  H  gC OH  H C ml 

ol edemoles

⋅

=

molesol edemoles   085.0tan   =

• Moles de Agua:

)18(

)9983.0()95(

2

2

2

22

OmolH O gH 

OmlH 

O gH O H ml 

aguademoles

⋅

=

ldl 275

8/18/2019 result+DEST+lab

22/25

B/+" 100 #% '" #*"+,/.

• Moles de Etanol:

)46(

)7856.0()6(

tan

52

52

52

5252

OH  H molC 

OH  H  gC 

OH  H mlC 

OH  H  gC OH  H C ml 

ol edemoles

⋅

=

molesol edemoles   10.0tan   =

• Moles de Agua:

)18(

)9983.0()94(

2

2

2

22

OmolH 

O gH 

OmlH 

O gH O H ml 

aguademoles

⋅

=

molesaguademoles   23.5=

8/18/2019 result+DEST+lab

23/25

S" (&+,*9" * '/;,/#/ '" ":*%,& %:*'& - @/$&, %/+ ($&+(&"+ '"%%:*'& 9 "% @/$&, " (/'/ $%/& @"" '/'/+ $&, * $*& '" %/ (*,@/ '"":*%,&. D/'& :*" "% ,"%*!& "+ &/% (& %&+ '/&+ '" ":*%,& %:*'&-@/$&,

$/,/ */ #"?(%/ "/&%-/;*/ T/%/ N°6 +" (&+,*9" %/ ;,)(/ N° 1 9 ;,)(/

N° 2.

B/!& %/+ (&'(&"+ '" ,"%*!& &/% %/ %"/ '" &$",/( " "% '/;,/#/ '"":*%,& $/,/ "% #&'& '" M( C/" - T>"%" (&('" " %/ '/;&/% '" 45 $&,%& :*" "% ",@'&,.

L&+ @/%&,"+ '" XD 9 X +" *(/ " "% '/;,/#/ '" ":*%,& Y @+ X 9 +"'"",#/ "%

8/18/2019 result+DEST+lab

24/25

GRÁFICAS

G,)(/ N=1 D/;,/#/ M( C/" T>"%" $/,/ #*"+,/ 1

24

8/18/2019 result+DEST+lab

25/25

G,)(/ N=2 D/;,/#/ M( C/" T>"%" $/,/ #*"+,/ 2

25