Results EUPT-FV21 and EUPT-SM11 - EURL | Pesticides€¦ · EUPT-FV21 Results EUPT- FV21 CALENDAR...

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Results

EUPT-FV21 and EUPT-SM11


OfLsOfLs

European Union Proficiency Tests

EUPTs


European Union Proficiency Tests

EUPTs

Organised

EURLs

All laboratories analysing samples for the

official control of pesticide residues,

which shall participate in the European

Union Proficiency Tests (EUPTs) for

pesticide residues organised by the

European Union


DG SANTE

Mrs. Almut Bitterhof

ORGANISING GROUP

Amadeo R. Fernández-AlbaCarmen Ferrer

Octavio Malato

QUALITY CONTROL GROUP

Antonio Valverde

Paula Medina

ADVISORY GROUP

Michelangelo AnastassiadesMiguel Gamón

Magnus Jezussek

André de Kok

Ralf Lippold

Sonja Masselter

Tuija Pihlström

Mette Erecius PoulsenFinbarr O’ReganPatrizia Pelosi

Hans Mol

EUPT-Panel

Mr. Stephanos Kirkagaslis

EUPT-FV21 Results

EUPT-FV21 Results

EUPT- FV21 CALENDAR

Activity Date

Registration period in EURL Data Pool. 20th December- 25th January

Specific Protocol published on the Web site. 11th February 2019 at the latest

Sample distribution 25th February 2019

Deadline for receiving sample acceptance 4th March 2019

Deadline for receiving results 25th March 2019

Filling in additional information, if necessary 25th March – 1th April 2019

Preliminary Report: only results, no estatical treatment May 2019

Final Report distribuited to the Laboratories August 2019

Calendar

EUPT-FV21 Results

205 pesticides

Target List

Acephate

Acetamiprid

Acrinathrin

Aldicarb

Aldicarb Sulfone

Aldicarb Sulfoxide

Aldrin

Amectrotadin

Azinphos-methyl

Azoxystrobin

Benfuracarb

Bifenthrin (sum of isomers)

Biphenyl

Bitertanol(sum of isomers)

Boscalid

Bromopropylate

Bromuconazole (sum of diastereoisomers)

Bupirimate

Buprofezin

Cadusafos

Carbaryl

Carbendazim and benomyl (sum of benomyl and carbendazim

expressed as carbendazim)

Carbofuran

Carbofuran-3-hydroxy

Carbosulfan

Chlorantraniliprole

Chlorfenapyr

Chlorfenvinphos

Chlorobenzilate

Chlorothalonil

Chlorpropham

Chlorpyrifos

Chlorpyrifos-methyl

Clofentezine

Clothianidin

Cyazofamid

Cyfluthrin (cyfluthrin incl. other mixtures of constituent isomers

(sum of isomers))

Cymoxanil

Cypermethrin (cypermethrin incl. other mixtures of constituent

isomers (sum of isomers))

Cyproconazole

Cyprodinil

Deltamethrin (cis-deltamethrin)

Demeton-S-methylsulfone

Diazinon

Dichlofluanid

Dichlorvos

Dicloran

Dicofol (sum of p, p´ and o,p´ isomers)

Dieldrin

Diethofencarb

Difenoconazole

Diflubenzuron

Dimethoate

Dimethomorph (sum of isomers)

Dimethylaminosulfotoluidide (DMST)

Diniconazole (sum of isomers)

Diphenylamine

Endosulfan alpha

Endosulfan beta

Endosulfan sulfate

EPN

Epoxiconazole

Ethion

Ethirimol

Ethoprophos

Etofenprox

Etoxazole

Famoxadone

Fenamidone

Fenamiphos

Fenamiphos sulfone

Fenamiphos sulfoxide

Fenarimol

Fenazaquin

Fenbuconazole

Fenhexamid

Fenitrothion

Fenpropidin

Fenpropimorph

Fenpyroximate

Fenthion

Fenthion oxon

Fenthion oxon sulfone

Fenthion oxon sulfoxide

Fenthion sulfone

Fenthion sulfoxide

Fenvalerate

Fipronil

Fipronil sulfone

Flonicamid

Flubendiamide

Fludioxonil

Flufenoxuron

Fluopicolide

Fluopyram

Fluquinconazole

Flusilazole

Flutolanil

Flutriafol

Fluxapyroxad

Formetanate

Fosthiazate

Hexaconazole

Hexythiazox

Imazalil

Imidacloprid

Indoxacarb

Iprodione

Iprovalicarb

Isocarbophos

11 New compounds

EUPT-FV21 Results

Target List

Isofenphos-methyl

Isoprothiolane

Kresoxim-methyl

Lambda-Cyhalothrin

Linuron

Lufenuron

Malaoxon

Malathion

Mandipropamid

Mepanipyrim

Metalaxyl and metalaxyl-M

Metalaxyl and metalaxyl-M

Methiocarb

Methiocarb sulfone

Methiocarb sulfoxide

Methomyl

Methoxyfenozide

Metrafenone

Monocrotophos

Myclobutanyl

Omethoate

Orthophenylphenol

Oxadixyl

Oxamyl

Oxydemeton-methyl

Paclobutrazole

Paraoxon-methyl

Parathion-ethyl

Parathion-methyl

Penconazole

Pencycuron

Pendimethalin

Permethrin (sum of isomers)

Phenthoate

Phosalone

Phosmet

Phosmet oxon

Phoxim

Pirimicarb

Pirimicarb-desmethyl

Pirimiphos-methyl

Prochloraz

Procymidone

Profenofos

Propamocarb (only parent compound)

Propargite

Propiconazole (sum of isomers)

Prothiofos

Pyraclostrobin

Pyridaben

Pyrimethanil

Pyriproxyfen

Quinoxyfen

Spinosad (sum of spinosad A and spinosad D)

Spirodiclofen

Spirotetramat

Spirotetramat metabolite BYI08330-enol

Spirotetramat metabolite BYI08330-ketohydroxy

Spirotetramat metabolite BYI08330-monohydroxy

Spirotetramat metabolite BYI08330 enol-glucoside

Spiromesifen

Spiroxamine

Tau-Fluvalinate

Tebuconazole

Tebufenozide

Tebufenpyrad

Teflubenzuron

Tefluthrin

Terbuthylazine

Tetraconazole

Tetradifon

Thiabendazole

Thiacloprid

Thiamethoxam

Thiodicarb

Thiamethoxam

Thiodicarb

Thiophanate-methyl

Tolclofos-methyl

Tolylfluanid

Triadimefon

Triadimenol (any

proportion of

constituent isomers)

Triazophos

Trichlorfon

Trifloxystrobin

Triflumuron

Trifluralin

Triticonazole

Vinclozolin

Zoxamide

11 New compounds

205 pesticides

EUPT-FV21 Results

34 pesticides

Voluntary Target List

Working Document SANCO/12745/2013(Working document on pesticides to be considered for inclusion in the

national control programmes to ensure compliance with maximum residue

levels of pesticides residues in and on food of plant and animal origin)

Benalaxyl including other mixtures of constituent isomers including benalaxyl-M

(sum of isomers)

Benzovindiflupyr

Chlorfluazurone

Clomazone

Cyazofamid

Cyflufenamid

Fenpyrazamine

Flufenacet (only parent compound)

Heptachlor

Heptachlor epoxide

Isoxaflutole

Isoxaflutole diketonitrile degradate

Isopyrazam

Metconazole

Molinate

Novaluron

Penflufen

Penthiopyrad

Picolinafen

Propaquizafop

Pyrethrins

Quintozene

Pentachloro-aniline

Proquinazid

Pyridalil

Pyriofenone

Quinoclamine

Rotenone

Spinetoram

Sulfaxaflor

Tetramethrin

Tricyclazole

Tritosulfuron

10 New compounds

EUPT-FV21 Results

Red Cabbage

EUPT-FV21 Results

Pesticides used for the treatment

Acetamiprid Metaflumizone

Chlorantraniprole Penthiopyrad

Chlorpropham Propamocarb

Chlorpyrifos Propyzamide

Chlothianidin Pyraclostrobin

Diazinon Spinetoram

Difenoconazole Teflubenzuron

Dimethoate Trofloxystrobin

Fenamidone Triflumuron

Fluxapyroxad Tritosulfuron

Voluntary pesticides

Total: 20

EUPT-FV21 Results

Red cabbages were grown in a greenhouse in Almería, Spain.

Preparation of the test item

EUPT-FV21 Results

Before harvest, the red cabbages were treated with pesticides available as

commercial formulations


EUPT-FV21 Results

After harvesting, they were spiked with analytical standards


EUPT-FV21 Results


EUPT-FV21 Results


EUPT-FV21 Results


EUPT-FV21 Results

Pesticides applied

as commercial formulationsPesticides applied as

analytical standards

Chlorpropham

Chlorpyrifos

Chlothianidin

Diazinon

Fenamidone

Fluxapyroxad

Propyzamide

Pyraclostrobin

Spinetoram

Teflubenzuron

Triflumuron

Tritosulfuron

Acetamiprid

Chlorantraniliprole

Difenoconazole

Dimethoate

Metaflumizone

Penthiopyrad

Propamocarb

Trifloxystrobin

EUPT-FV21 Results

The homogeneity in the

treated sample was studied

using the 2006 Harmonised

Protocol.

Homogeneity

All the pesticides passed the homogeneity and

stability tests

Stability

2nd Analysis - after the deadline for

reporting results

1st Analysis - prior to the sample

shipment

3rd Analysis - reproducing the delivery

conditions that the samples experienced during 48 hours

EUPT-FV21 Results

Total No. of Labs = 190

EU/EFTA Labs = 173

Other countries Labs =17

Participation

Total No. of Countries = 42

EU/EFTA countries = 31

Other countries = 11

EUPT-FV21 Results

Total No. of Labs = 190

EU/EFTA Labs = 173

Other countries Labs =17

Participation

Total No. of Countries = 42

EU/EFTA countries = 31

Other countries = 11

1 participant did not submit results

(cancelled its participation)

172 EU/EFTA Labs

EUPT-FV21 Results

Participation

Member State No. LabsAustria 1Belgium 6Bulgaria 4Croatia 8Cyprus 1

Czech Republic 3

Denmark 2Estonia 2Finland 3France 8

Germany 28Greece 4Hungary 4Iceland 1Ireland 1

Italy 25

Member State No. LabsLatvia 1Lithuania 1

Luxembourg 2Malta 2

Norway 1Poland 12

Portugal 3

Romania 5Slovakia 1

Slovenija 2

Spain 33

Sweden 2Switzerland 4The Netherlands 2

United Kingdom 4

Non-EU/EFTA No. LabsChina 5Colombia 1Costa Rica 1Kenya 1Peru 1Saudi Arabia 1Serbia 3Singapore 1Thailand 1Turkey 1Uruguay 1

EUPT-FV21 Results

Participation

EUPT-FV21 Results

Results

EUPT-FV21 Results

Assigned values

Voluntary Pesticides

Robust Mean X* (mg/kg)

Omethoate 0,008

Chlorpyrifos 0,051

Chlothianidin 0,052

Spinetoram 0,056

Tritosulfuron 0,066

Pyraclostrobin 0,076

Diazinon 0,077

Propyzamide 0,083

Chlorpropham 0,084

Teflubenzuron 0,110

Dimethoate 0,124

Chlorantraniprole 0,136

Difenoconazole 0,169

Propamocarb (only

parent compound)0,170

Acetamiprid 0,174

Metaflumizone (sum of

E- and Z- isomers)0,210

Penthiopyrad 0,223

Trifloxystrobin 0,230

Triflumuron 0,469

Fluxapyroxad 0,536

Fenamidone 0,615

EUPT-FV21 Results

Assigned values


0.008-0.084 mg/kg


Omethoate 0,008

Chlorpyrifos 0,051

Chlothianidin 0,052

Spinetoram 0,056

Tritosulfuron 0,066


Diazinon 0,077

Propyzamide 0,083

Chlorpropham 0,084

Teflubenzuron 0,110

Dimethoate 0,124



Propamocarb (only


Acetamiprid 0,174



Penthiopyrad 0,223


Triflumuron 0,469

Fluxapyroxad 0,536

Fenamidone 0,615

EUPT-FV21 Results

Assigned values


0.008-0.084 mg/kg


Omethoate 0,008

Chlorpyrifos 0,051

Chlothianidin 0,052

Spinetoram 0,056

Tritosulfuron 0,066


Diazinon 0,077

Propyzamide 0,083

Chlorpropham 0,084

Teflubenzuron 0,110

Dimethoate 0,124



Propamocarb (only


Acetamiprid 0,174



Penthiopyrad 0,223


Triflumuron 0,469

Fluxapyroxad 0,536

Fenamidone 0,615

0.110-0.615 mg/kg

EUPT-FV21 Results

MRRL (mg/kg)

Robust Mean (mg/kg)

CV (%)Uncertainty

(mg/kg)

Acetamiprid 0,010 0,174 13,0 0,002

Chlorantraniprole 0,010 0,136 15,2 0,002

Chlorpropham 0,010 0,084 14,0 0,001

Chlorpyrifos 0,010 0,051 17,6 0,001

Chlothianidin 0,010 0,052 15,5 0,001

Diazinon 0,005 0,077 15,3 0,001

Difenoconazole 0,010 0,169 17,2 0,003

Dimethoate 0,003 0,124 13,0 0,002

Fenamidone 0,010 0,615 15,2 0,009

Fluxapyroxad 0,010 0,536 12,4 0,008

Metaflumizone (sum of E-and Z- isomers)

0,010 0,210 23,6 0,006

Omethoate 0,003 0,008 22,3 0,000

Penthiopyrad* 0,010 0,223 12,4 0,004

Propamocarb (onlyparent compound)

0,010 0,170 17,8 0,003

Propyzamide 0,010 0,083 15,0 0,001

Pyraclostrobin 0,010 0,076 15,2 0,001

Spinetoram* 0,010 0,056 21,6 0,002

Teflubenzuron 0,010 0,110 18,4 0,002

Trofloxystrobin 0,010 0,230 13,4 0,003

Triflumuron 0,010 0,469 17,3 0,009

Tritosulfuron* 0,010 0,066 19,7 0,002

* Voluntary compounds

EUPT-FV21 Results

MRRL (mg/kg)

Robust Mean (mg/kg)

CV (%)Uncertainty

(mg/kg)

Acetamiprid 0,010 0,174 13,0 0,002


Chlorpropham 0,010 0,084 14,0 0,001

Chlorpyrifos 0,010 0,051 17,6 0,001

Chlothianidin 0,010 0,052 15,5 0,001

Diazinon 0,005 0,077 15,3 0,001

Difenoconazole 0,010 0,169 17,2 0,003

Dimethoate 0,003 0,124 13,0 0,002

Fenamidone 0,010 0,615 15,2 0,009

Fluxapyroxad 0,010 0,536 12,4 0,008


0,010 0,210 23,6 0,006

Omethoate 0,003 0,008 22,3 0,000

Penthiopyrad* 0,010 0,223 12,4 0,004


0,010 0,170 17,8 0,003

Propyzamide 0,010 0,083 15,0 0,001

Pyraclostrobin 0,010 0,076 15,2 0,001

Spinetoram* 0,010 0,056 21,6 0,002

Teflubenzuron 0,010 0,110 18,4 0,002


Triflumuron 0,010 0,469 17,3 0,009

Tritosulfuron* 0,010 0,066 19,7 0,002


EUPT-FV21 Results

MRRL (mg/kg)

Robust Mean (mg/kg)

CV (%)Uncertainty

(mg/kg)

Acetamiprid 0,010 0,174 13,0 0,002


Chlorpropham 0,010 0,084 14,0 0,001

Chlorpyrifos 0,010 0,051 17,6 0,001

Chlothianidin 0,010 0,052 15,5 0,001

Diazinon 0,005 0,077 15,3 0,001

Difenoconazole 0,010 0,169 17,2 0,003

Dimethoate 0,003 0,124 13,0 0,002

Fenamidone 0,010 0,615 15,2 0,009

Fluxapyroxad 0,010 0,536 12,4 0,008


0,010 0,210 23,6 0,006

Omethoate 0,003 0,008 22,3 0,000

Penthiopyrad* 0,010 0,223 12,4 0,004


0,010 0,170 17,8 0,003

Propyzamide 0,010 0,083 15,0 0,001

Pyraclostrobin 0,010 0,076 15,2 0,001

Spinetoram* 0,010 0,056 21,6 0,002

Teflubenzuron 0,010 0,110 18,4 0,002


Triflumuron 0,010 0,469 17,3 0,009

Tritosulfuron* 0,010 0,066 19,7 0,002


Assigned value < 3 x MRRL

EUPT-FV21 Results

MRRL (mg/kg)

Robust Mean (mg/kg)

CV (%)Uncertainty

(mg/kg)

Acetamiprid 0,010 0,174 13,0 0,002


Chlorpropham 0,010 0,084 14,0 0,001

Chlorpyrifos 0,010 0,051 17,6 0,001

Chlothianidin 0,010 0,052 15,5 0,001

Diazinon 0,005 0,077 15,3 0,001

Difenoconazole 0,010 0,169 17,2 0,003

Dimethoate 0,003 0,124 13,0 0,002

Fenamidone 0,010 0,615 15,2 0,009

Fluxapyroxad 0,010 0,536 12,4 0,008


0,010 0,210 23,6 0,006

Omethoate 0,003 0,008 22,3 0,000

Penthiopyrad* 0,010 0,223 12,4 0,004


0,010 0,170 17,8 0,003

Propyzamide 0,010 0,083 15,0 0,001

Pyraclostrobin 0,010 0,076 15,2 0,001

Spinetoram* 0,010 0,056 21,6 0,002

Teflubenzuron 0,010 0,110 18,4 0,002


Triflumuron 0,010 0,469 17,3 0,009

Tritosulfuron* 0,010 0,066 19,7 0,002


Assigned value < 3 x MRRL

Not included in the evaluation

Information shown only for informative purposes

EUPT-FV21 Results

Dispersion of Results


EUPT-FV21 Results

Dispersion of results

EUPT-FV1-FV21

(1996-2019)

EUPT-FV21 Results

Dispersion of results

EUPT-FV1-FV21

(1996-2019)

EUPT-FV21 Results

PesticidesNo. of Reported

Results

No. of False Negative

Results

No. of Not Analysed

Results

Percentage of Labs

Reporting Results (out

of 172)

Acetamiprid 154 3 15 89

Chlorantraniliprole 139 5 28 80

Chlorpropham 159 4 9 92

Chlorpyrifos 168 1 3 97

Clothianidin 149 4 19 86

Diazinon 166 0 6 96

Difenoconazole 166 3 3 96

Dimethoate 166 0 6 96

Fenamidone 156 4 12 90

Fluxapyroxad 110 5 57 64

Metaflumizone (sum

of E- and Z- isomers)119 6 47 69

Omethoate 122 - 14 71

Penthiopyrad* 87 9 76 50

Propamocarb (only

parent compound)146 4 22 84

Propyzamide 158 1 13 91

Pyraclostrobin 154 4 14 89

Spinetoram* 86 8 78 50

Teflubenzuron 131 6 35 76

Trifloxystrobin 162 2 8 94

Triflumuron 137 5 30 79

Tritosulfuron* 44 15 113 25

EU/EFTA Laboratories


EUPT-FV21 Results


Results


Results

No. of Not Analysed

Results

Percentage of Labs


of 172)






Diazinon 166 0 6 96





Metaflumizone (sum




Propamocarb (only











EUPT-FV21 Results


Results


Results

No. of Not Analysed

Results

Percentage of Labs


of 172)






Diazinon 166 0 6 96





Metaflumizone (sum




Propamocarb (only











EUPT-FV21 Results


Results


Results

No. of Not Analysed

Results

Percentage of Labs


of 172)






Diazinon 166 0 6 96





Metaflumizone (sum




Propamocarb (only











EUPT-FV21 Results


Results


Results

No. of Not Analysed

Results

Percentage of Labs


of 172)






Diazinon 166 0 6 96





Metaflumizone (sum




Propamocarb (only











EUPT-FV21 Results

z-Scores

EUPT-FV21 Results

Z Scores classification

|z| ≤ 2.0 Acceptable

2.0 < |z| < 3.0 Questionable

|z| ≥ 3.0 Unacceptable

EUPT-FV21 Results

PesticidesRobust Mean

(mg/kg)% Acceptable

z scores% Questionable

z scores% Unacceptable

z scores

Acetamiprid 0,174 94,3 1,9 3,8

Chlorantraniliprole 0,136 94,4 0,7 4,9

Chlorpropham 0,084 95,7 0,6 3,7

Chlorpyrifos 0,051 96,4 1,8 1,8

Clothianidin 0,052 96,7 0,0 3,3

Diazinon 0,077 96,4 3,0 0,6

Difenoconazole 0,169 92,3 3,6 4,1

Dimethoate 0,124 97,0 0,0 3,0

Fenamidone 0,615 95,0 1,9 3,1

Fluxapyroxad 0,536 92,2 1,7 6,1

Metaflumizone (sum of E- and Z- isomers)

0,210 87,2 5,6 7,2

Omethoate 0,008 92,6 3,3 4,1

Penthiopyrad* 0,223 89,6 0,0 10,4


0,170 93,3 2,0 4,7

Propyzamide 0,083 98,1 0,6 1,3

Pyraclostrobin 0,076 92,4 4,4 3,2

Spinetoram* 0,056 85,1 4,3 10,6

Teflubenzuron 0,110 92,7 0,7 6,6

Trifloxystrobin 0,230 97,6 0,6 1,8

Triflumuron 0,469 93,0 2,1 4,9

Tritosulfuron* 0,066 72,9 1,7 25,4

EU/EFTA Laboratories Z Scores classification* Voluntary compounds

EUPT-FV21 Results


(mg/kg)% Acceptable



z scores

Acetamiprid 0,174 94,3 1,9 3,8


Chlorpropham 0,084 95,7 0,6 3,7

Chlorpyrifos 0,051 96,4 1,8 1,8

Clothianidin 0,052 96,7 0,0 3,3

Diazinon 0,077 96,4 3,0 0,6


Dimethoate 0,124 97,0 0,0 3,0

Fenamidone 0,615 95,0 1,9 3,1

Fluxapyroxad 0,536 92,2 1,7 6,1


0,210 87,2 5,6 7,2

Omethoate 0,008 92,6 3,3 4,1

Penthiopyrad* 0,223 89,6 0,0 10,4


0,170 93,3 2,0 4,7

Propyzamide 0,083 98,1 0,6 1,3


Spinetoram* 0,056 85,1 4,3 10,6



Triflumuron 0,469 93,0 2,1 4,9

Tritosulfuron* 0,066 72,9 1,7 25,4


EUPT-FV21 Results


(mg/kg)% Acceptable



z scores

Acetamiprid 0,174 94,3 1,9 3,8


Chlorpropham 0,084 95,7 0,6 3,7

Chlorpyrifos 0,051 96,4 1,8 1,8

Clothianidin 0,052 96,7 0,0 3,3

Diazinon 0,077 96,4 3,0 0,6


Dimethoate 0,124 97,0 0,0 3,0

Fenamidone 0,615 95,0 1,9 3,1

Fluxapyroxad 0,536 92,2 1,7 6,1


0,210 87,2 5,6 7,2

Omethoate 0,008 92,6 3,3 4,1

Penthiopyrad* 0,223 89,6 0,0 10,4


0,170 93,3 2,0 4,7

Propyzamide 0,083 98,1 0,6 1,3


Spinetoram* 0,056 85,1 4,3 10,6



Triflumuron 0,469 93,0 2,1 4,9

Tritosulfuron* 0,066 72,9 1,7 25,4


EUPT-FV21 Results


(mg/kg)% Acceptable



z scores

Acetamiprid 0,174 94,3 1,9 3,8


Chlorpropham 0,084 95,7 0,6 3,7

Chlorpyrifos 0,051 96,4 1,8 1,8

Clothianidin 0,052 96,7 0,0 3,3

Diazinon 0,077 96,4 3,0 0,6


Dimethoate 0,124 97,0 0,0 3,0

Fenamidone 0,615 95,0 1,9 3,1

Fluxapyroxad 0,536 92,2 1,7 6,1


0,210 87,2 5,6 7,2

Omethoate 0,008 92,6 3,3 4,1

Penthiopyrad* 0,223 89,6 0,0 10,4


0,170 93,3 2,0 4,7

Propyzamide 0,083 98,1 0,6 1,3


Spinetoram* 0,056 85,1 4,3 10,6



Triflumuron 0,469 93,0 2,1 4,9

Tritosulfuron* 0,066 72,9 1,7 25,4


15 False Negative Results

EUPT-FV21 Results

Acceptable Questionable Unacceptable

Z Scores classification EU/EFTA Laboratories

Voluntary compounds

%

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

696

Lab

738

Lab

896

Lab

878

Lab

754

Lab

608

Lab

704

Lab

766

Lab

780

Lab

550

Lab

594

Lab

772

Lab

800

Lab

904

Lab

656

Lab

796

Lab

654

Lab

778

Lab

636

Lab

768

Lab

870

Lab

920

Lab

558

Lab

798

Lab

598

Lab

730

Lab

882

Lab

720

Lab

728

Lab

828

Lab

672

Lab

548

Lab

932

Lab

680

Lab

914

Lab

586

Lab

610

Lab

622

Lab

602

Lab

650

Lab

666

Lab

692

Lab

804

Lab

820

Lab

844

Lab

582

Lab

880

Lab

786

Lab

836

Lab

700

Lab

740

Lab

792

Lab

818

Lab

872

Lab

734

Lab

752

Lab

618

Lab

658

Lab

746

Lab

794

Lab

580

Lab

736

Lab

596

Lab

662

Lab

676

Lab

916

Lab

764

Lab

544

Lab

546

Lab

632

Lab

640

Lab

668

Lab

698

Lab

830

Lab

850

Lab

908

Lab

912

Lab

638

Lab

910

Lab

928

Lab

560

Lab

570

Lab

690

Lab

732

Lab

566

Lab

748

Lab

770

Lab

784

Lab

924

Lab

648

Lab

534

Lab

552

Lab

562

Lab

710

Lab

604

Lab

708

Lab

670

Lab

760

Lab

524

Lab

572

Lab

744

Lab

876

Lab

682

Lab

528

Lab

838

Lab

852

Lab

756

Lab

564

Lab

616

Lab

532

Lab

556

Lab

758

Lab

892

Lab

536

Lab

624

Lab

848

Lab

706

Lab

742

Lab

918

Lab

584

Lab

606

Lab

726

Lab

826

Lab

902

Lab

1116

Lab

644

Lab

590

Lab

840

Lab

592

Lab

702

Lab

568

Lab

540

Lab

718

Lab

854

Lab

858

Lab

922

Lab

926

Lab

634

Lab

686

Lab

684

Lab

750

Lab

588

Lab

614

Lab

674

Lab

788

Lab

868

Lab

782

Lab

814

Lab

802

Lab

862

Lab

678

Lab

774

Lab

626

Lab

538

Lab

628

Lab

810

Lab

576

Acetamiprid

LL LL L L

or G = GC

or L = LC

or N = No Data***

94,3 % Acceptable

1,9 % Questionable

3,8 % Unacceptable

Robust Mean: 0,174 mg/kg

CV*: 13,0 %

n=154


3 False Negatives

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

576

Lab

600

Lab

814

Lab

896

Lab

1116

Lab

878

Lab

602

Lab

656

Lab

720

Lab

736

Lab

800

Lab

932

Lab

778

Lab

916

Lab

548

Lab

674

Lab

828

Lab

830

Lab

908

Lab

676

Lab

680

Lab

598

Lab

728

Lab

904

Lab

622

Lab

816

Lab

926

Lab

792

Lab

672

Lab

752

Lab

786

Lab

636

Lab

706

Lab

734

Lab

594

Lab

632

Lab

754

Lab

558

Lab

726

Lab

562

Lab

618

Lab

818

Lab

574

Lab

666

Lab

692

Lab

682

Lab

596

Lab

640

Lab

690

Lab

784

Lab

556

Lab

586

Lab

742

Lab

794

Lab

872

Lab

768

Lab

560

Lab

582

Lab

920

Lab

524

Lab

650

Lab

670

Lab

756

Lab

772

Lab

804

Lab

820

Lab

844

Lab

922

Lab

566

Lab

760

Lab

580

Lab

546

Lab

624

Lab

638

Lab

686

Lab

876

Lab

540

Lab

644

Lab

802

Lab

880

Lab

528

Lab

592

Lab

718

Lab

836

Lab

910

Lab

924

Lab

590

Lab

614

Lab

840

Lab

634

Lab

654

Lab

826

Lab

710

Lab

852

Lab

544

Lab

858

Lab

914

Lab

862

Lab

708

Lab

892

Lab

610

Lab

764

Lab

902

Lab

788

Lab

918

Lab

564

Lab

758

Lab

796

Lab

532

Lab

700

Lab

572

Lab

584

Lab

616

Lab

678

Lab

702

Lab

810

Lab

534

Lab

604

Lab

684

Lab

750

Lab

766

Lab

570

Lab

568

Lab

668

Lab

698

Lab

870

Lab

730

Lab

626

Lab

838

Lab

606

Lab

782

Lab

868

Lab

848

Lab

648

Lab

704

Lab

770

Lab

552

Lab

740

Lab

588

Lab

608

Lab

696

Lab

744

Lab

538

Lab

850

Chlorantraniprole

or G = GC

or L = LC

or N = No Data

LL L L L LN

*****

94,4 % Acceptable

0,7 % Questionable

4,9 % Unacceptable


CV*: 15,2 %

n=139


5 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

680

Lab

736

Lab

896

Lab

1116

Lab

748

Lab

932

Lab

724

Lab

914

Lab

738

Lab

788

Lab

616

Lab

778

Lab

602

Lab

854

Lab

594

Lab

828

Lab

822

Lab

596

Lab

566

Lab

584

Lab

640

Lab

876

Lab

588

Lab

728

Lab

892

Lab

870

Lab

568

Lab

786

Lab

684

Lab

908

Lab

598

Lab

792

Lab

916

Lab

862

Lab

784

Lab

600

Lab

888

Lab

618

Lab

668

Lab

674

Lab

734

Lab

818

Lab

706

Lab

726

Lab

820

Lab

524

Lab

556

Lab

670

Lab

700

Lab

746

Lab

796

Lab

800

Lab

538

Lab

690

Lab

758

Lab

772

Lab

794

Lab

802

Lab

868

Lab

544

Lab

564

Lab

756

Lab

764

Lab

610

Lab

634

Lab

658

Lab

742

Lab

614

Lab

626

Lab

656

Lab

666

Lab

678

Lab

708

Lab

752

Lab

836

Lab

874

Lab

548

Lab

582

Lab

612

Lab

628

Lab

676

Lab

798

Lab

850

Lab

662

Lab

664

Lab

696

Lab

710

Lab

718

Lab

804

Lab

830

Lab

816

Lab

698

Lab

814

Lab

762

Lab

904

Lab

552

Lab

554

Lab

572

Lab

592

Lab

768

Lab

838

Lab

760

Lab

546

Lab

622

Lab

858

Lab

924

Lab

528

Lab

550

Lab

574

Lab

604

Lab

702

Lab

770

Lab

810

Lab

532

Lab

580

Lab

638

Lab

920

Lab

922

Lab

558

Lab

686

Lab

750

Lab

880

Lab

902

Lab

918

Lab

644

Lab

852

Lab

704

Lab

910

Lab

586

Lab

590

Lab

540

Lab

744

Lab

754

Lab

636

Lab

654

Lab

848

Lab

878

Lab

882

Lab

826

Lab

872

Lab

926

Lab

534

Lab

672

Lab

560

Lab

562

Lab

692

Lab

776

Lab

682

Lab

720

Lab

624

Lab

648

Lab

688

Lab

840

Lab

844

Lab

730

Lab

570

Lab

782

Lab

632

Lab

740

Lab

774

Lab

606

Lab

766

Lab

576

Chlorpropham

GGGGGLN

or G = GC

or L = LC

or N = No Data

****

95,7 % Acceptable

0,6 % Questionable

3,7 % Unacceptable


CV*: 14,0 %

n=159


4 False Negatives

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

868

Lab

856

Lab

738

Lab

724

Lab

748

Lab

756

Lab

602

Lab

718

Lab

896

Lab

674

Lab

728

Lab

594

Lab

584

Lab

836

Lab

786

Lab

778

Lab

818

Lab

614

Lab

662

Lab

670

Lab

772

Lab

820

Lab

908

Lab

870

Lab

544

Lab

726

Lab

768

Lab

800

Lab

912

Lab

548

Lab

552

Lab

566

Lab

788

Lab

568

Lab

766

Lab

862

Lab

678

Lab

792

Lab

804

Lab

844

Lab

888

Lab

892

Lab

920

Lab

828

Lab

734

Lab

550

Lab

554

Lab

596

Lab

746

Lab

752

Lab

794

Lab

914

Lab

618

Lab

684

Lab

610

Lab

524

Lab

558

Lab

562

Lab

640

Lab

672

Lab

690

Lab

932

Lab

882

Lab

682

Lab

588

Lab

658

Lab

664

Lab

872

Lab

816

Lab

784

Lab

600

Lab

644

Lab

736

Lab

764

Lab

810

Lab

830

Lab

878

Lab

636

Lab

656

Lab

916

Lab

904

Lab

586

Lab

706

Lab

708

Lab

802

Lab

814

Lab

854

Lab

762

Lab

634

Lab

574

Lab

604

Lab

654

Lab

754

Lab

838

Lab

858

Lab

874

Lab

648

Lab

760

Lab

532

Lab

556

Lab

576

Lab

582

Lab

622

Lab

686

Lab

796

Lab

798

Lab

822

Lab

902

Lab

710

Lab

546

Lab

628

Lab

676

Lab

680

Lab

696

Lab

704

Lab

742

Lab

522

Lab

564

Lab

580

Lab

698

Lab

730

Lab

744

Lab

750

Lab

922

Lab

924

Lab

540

Lab

572

Lab

780

Lab

880

Lab

852

Lab

598

Lab

560

Lab

702

Lab

626

Lab

926

Lab

528

Lab

638

Lab

770

Lab

632

Lab

650

Lab

826

Lab

876

Lab

1116

Lab

538

Lab

776

Lab

592

Lab

612

Lab

624

Lab

668

Lab

758

Lab

840

Lab

848

Lab

590

Lab

692

Lab

918

Lab

616

Lab

782

Lab

534

Lab

606

Lab

700

Lab

774

Lab

910

Lab

850

Lab

570

Lab

688

Lab

666

Lab

720

Lab

740

Lab

608

Chlorpyrifos

GGGNGGLGN

or G = GC

or L = LC

or N = No Data

*

96,4 % Acceptable

1,8 % Questionable

1,8 % Unacceptable


CV*: 17,6 %

n=168


1 False Negative

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

738

Lab

896

Lab

912

Lab

1116

Lab

878

Lab

792

Lab

562

Lab

656

Lab

704

Lab

820

Lab

692

Lab

754

Lab

608

Lab

766

Lab

698

Lab

772

Lab

794

Lab

862

Lab

676

Lab

870

Lab

598

Lab

548

Lab

552

Lab

680

Lab

780

Lab

904

Lab

882

Lab

752

Lab

800

Lab

804

Lab

786

Lab

564

Lab

644

Lab

778

Lab

734

Lab

558

Lab

690

Lab

706

Lab

618

Lab

746

Lab

818

Lab

844

Lab

932

Lab

648

Lab

828

Lab

594

Lab

700

Lab

902

Lab

684

Lab

570

Lab

580

Lab

596

Lab

726

Lab

796

Lab

836

Lab

784

Lab

556

Lab

604

Lab

616

Lab

650

Lab

654

Lab

720

Lab

742

Lab

908

Lab

910

Lab

916

Lab

610

Lab

662

Lab

668

Lab

740

Lab

744

Lab

782

Lab

876

Lab

914

Lab

590

Lab

632

Lab

524

Lab

546

Lab

582

Lab

626

Lab

638

Lab

732

Lab

852

Lab

566

Lab

640

Lab

670

Lab

758

Lab

764

Lab

636

Lab

682

Lab

674

Lab

858

Lab

586

Lab

532

Lab

666

Lab

728

Lab

826

Lab

848

Lab

854

Lab

872

Lab

922

Lab

760

Lab

710

Lab

924

Lab

550

Lab

624

Lab

718

Lab

736

Lab

540

Lab

588

Lab

592

Lab

748

Lab

756

Lab

810

Lab

838

Lab

840

Lab

926

Lab

634

Lab

534

Lab

544

Lab

702

Lab

708

Lab

880

Lab

920

Lab

538

Lab

750

Lab

528

Lab

572

Lab

584

Lab

686

Lab

730

Lab

892

Lab

536

Lab

614

Lab

678

Lab

802

Lab

918

Lab

770

Lab

568

Lab

602

Lab

774

Lab

622

Lab

788

Lab

830

Lab

850

Lab

606

Lab

768

Lab

560

Lab

576

Lab

696

Lab

672

Lab

814

Lab

628

Chlothianidin

L L L L L LL

or G = GC

or L = LC

or N = No Data

****

96,7 % Acceptable

0,0 % Questionable

3,3 % Unacceptable


CV*: 15,5 %

n=149


4 False Negatives

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

748

Lab

594

Lab

602

Lab

588

Lab

724

Lab

778

Lab

892

Lab

584

Lab

728

Lab

822

Lab

798

Lab

896

Lab

596

Lab

742

Lab

772

Lab

876

Lab

568

Lab

786

Lab

640

Lab

828

Lab

662

Lab

648

Lab

558

Lab

792

Lab

820

Lab

726

Lab

888

Lab

548

Lab

932

Lab

818

Lab

524

Lab

604

Lab

674

Lab

858

Lab

684

Lab

644

Lab

862

Lab

678

Lab

702

Lab

810

Lab

912

Lab

668

Lab

746

Lab

764

Lab

882

Lab

598

Lab

868

Lab

908

Lab

710

Lab

784

Lab

552

Lab

800

Lab

544

Lab

816

Lab

766

Lab

614

Lab

752

Lab

804

Lab

836

Lab

802

Lab

566

Lab

734

Lab

610

Lab

600

Lab

654

Lab

664

Lab

916

Lab

920

Lab

618

Lab

760

Lab

538

Lab

556

Lab

564

Lab

750

Lab

754

Lab

794

Lab

874

Lab

902

Lab

904

Lab

762

Lab

676

Lab

706

Lab

796

Lab

636

Lab

670

Lab

680

Lab

690

Lab

878

Lab

914

Lab

870

Lab

770

Lab

814

Lab

550

Lab

768

Lab

830

Lab

838

Lab

844

Lab

922

Lab

590

Lab

572

Lab

592

Lab

622

Lab

626

Lab

700

Lab

704

Lab

758

Lab

826

Lab

924

Lab

580

Lab

708

Lab

926

Lab

532

Lab

554

Lab

574

Lab

628

Lab

634

Lab

756

Lab

848

Lab

560

Lab

562

Lab

638

Lab

658

Lab

776

Lab

682

Lab

606

Lab

692

Lab

736

Lab

852

Lab

522

Lab

624

Lab

650

Lab

730

Lab

872

Lab

546

Lab

698

Lab

918

Lab

720

Lab

854

Lab

880

Lab

910

Lab

666

Lab

780

Lab

744

Lab

1116

Lab

570

Lab

672

Lab

686

Lab

696

Lab

774

Lab

840

Lab

850

Lab

528

Lab

586

Lab

534

Lab

616

Lab

688

Lab

718

Lab

788

Lab

782

Lab

576

Lab

540

Lab

740

Lab

608

Lab

632

Lab

582

Lab

738

Diazinon

GGGGLGLGGL

or G = GC

or L = LC

or N = No Data

96,4 % Acceptable

3,0 % Questionable

0,6 % Unacceptable


CV*: 15,3 %

n=166


0 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

576

Lab

896

Lab

1116

Lab

748

Lab

594

Lab

724

Lab

778

Lab

882

Lab

584

Lab

656

Lab

796

Lab

786

Lab

800

Lab

828

Lab

932

Lab

862

Lab

710

Lab

602

Lab

868

Lab

912

Lab

648

Lab

600

Lab

640

Lab

746

Lab

876

Lab

818

Lab

544

Lab

524

Lab

558

Lab

908

Lab

554

Lab

548

Lab

736

Lab

596

Lab

752

Lab

916

Lab

598

Lab

756

Lab

618

Lab

768

Lab

870

Lab

674

Lab

742

Lab

784

Lab

794

Lab

804

Lab

820

Lab

922

Lab

644

Lab

888

Lab

838

Lab

914

Lab

626

Lab

754

Lab

734

Lab

728

Lab

776

Lab

836

Lab

904

Lab

682

Lab

592

Lab

622

Lab

680

Lab

538

Lab

588

Lab

610

Lab

744

Lab

772

Lab

816

Lab

920

Lab

670

Lab

706

Lab

708

Lab

750

Lab

928

Lab

874

Lab

562

Lab

814

Lab

536

Lab

582

Lab

636

Lab

692

Lab

760

Lab

858

Lab

700

Lab

872

Lab

522

Lab

638

Lab

650

Lab

654

Lab

730

Lab

762

Lab

826

Lab

844

Lab

574

Lab

902

Lab

566

Lab

764

Lab

556

Lab

580

Lab

586

Lab

590

Lab

690

Lab

662

Lab

684

Lab

704

Lab

726

Lab

624

Lab

686

Lab

926

Lab

534

Lab

606

Lab

668

Lab

770

Lab

830

Lab

560

Lab

664

Lab

758

Lab

918

Lab

546

Lab

604

Lab

698

Lab

892

Lab

552

Lab

632

Lab

792

Lab

570

Lab

924

Lab

634

Lab

672

Lab

676

Lab

720

Lab

852

Lab

528

Lab

840

Lab

540

Lab

850

Lab

678

Lab

848

Lab

532

Lab

658

Lab

774

Lab

880

Lab

564

Lab

702

Lab

718

Lab

550

Lab

572

Lab

696

Lab

616

Lab

568

Lab

666

Lab

798

Lab

910

Lab

688

Lab

802

Lab

732

Lab

740

Lab

788

Lab

766

Lab

810

Lab

782

Lab

878

Lab

628

Lab

614

Lab

608

Lab

854

Lab

738

Lab

780

Difenoconazole

LLLGLLLLGGGLGGLG

or G = GC

or L = LC

or N = No Data***

92,3 % Acceptable

3,6 % Questionable

4,1 % Unacceptable


CV*: 17,2 %

n=166


3 False Negatives

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

600

Lab

656

Lab

766

Lab

780

Lab

754

Lab

664

Lab

850

Lab

574

Lab

724

Lab

896

Lab

594

Lab

868

Lab

854

Lab

608

Lab

598

Lab

688

Lab

914

Lab

870

Lab

690

Lab

888

Lab

904

Lab

816

Lab

916

Lab

672

Lab

704

Lab

800

Lab

696

Lab

568

Lab

586

Lab

778

Lab

820

Lab

844

Lab

682

Lab

876

Lab

570

Lab

882

Lab

932

Lab

666

Lab

752

Lab

792

Lab

534

Lab

700

Lab

802

Lab

822

Lab

558

Lab

582

Lab

610

Lab

742

Lab

872

Lab

880

Lab

548

Lab

618

Lab

648

Lab

732

Lab

680

Lab

796

Lab

862

Lab

818

Lab

524

Lab

550

Lab

650

Lab

654

Lab

706

Lab

734

Lab

748

Lab

804

Lab

830

Lab

836

Lab

908

Lab

1116

Lab

728

Lab

776

Lab

784

Lab

828

Lab

544

Lab

564

Lab

566

Lab

632

Lab

676

Lab

562

Lab

596

Lab

692

Lab

540

Lab

580

Lab

658

Lab

698

Lab

740

Lab

744

Lab

746

Lab

786

Lab

794

Lab

902

Lab

536

Lab

662

Lab

552

Lab

554

Lab

622

Lab

636

Lab

726

Lab

736

Lab

892

Lab

590

Lab

604

Lab

638

Lab

702

Lab

764

Lab

838

Lab

858

Lab

624

Lab

686

Lab

730

Lab

768

Lab

826

Lab

910

Lab

922

Lab

560

Lab

640

Lab

644

Lab

670

Lab

684

Lab

708

Lab

718

Lab

924

Lab

710

Lab

756

Lab

848

Lab

920

Lab

760

Lab

852

Lab

770

Lab

814

Lab

592

Lab

758

Lab

788

Lab

878

Lab

918

Lab

556

Lab

616

Lab

528

Lab

572

Lab

584

Lab

588

Lab

772

Lab

840

Lab

546

Lab

750

Lab

634

Lab

926

Lab

606

Lab

668

Lab

674

Lab

798

Lab

912

Lab

532

Lab

720

Lab

774

Lab

782

Lab

614

Lab

602

Lab

678

Lab

538

Lab

626

Lab

576

Lab

810

Lab

628

Lab

738

Dimethoate

NLL L L L LLLL LLLLLLLGLLL

or G = GC

or L = LC

or N = No Data

97,0 % Acceptable

0,0 % Questionable

3,0 % Unacceptable


CV*: 13,0 %

n=166


0 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

772

Lab

896

Lab

914

Lab

1116

Lab

738

Lab

656

Lab

602

Lab

778

Lab

576

Lab

844

Lab

600

Lab

918

Lab

828

Lab

554

Lab

588

Lab

800

Lab

640

Lab

932

Lab

818

Lab

584

Lab

596

Lab

548

Lab

882

Lab

558

Lab

724

Lab

750

Lab

568

Lab

636

Lab

728

Lab

544

Lab

868

Lab

594

Lab

550

Lab

766

Lab

798

Lab

908

Lab

644

Lab

698

Lab

804

Lab

820

Lab

618

Lab

648

Lab

786

Lab

794

Lab

754

Lab

784

Lab

746

Lab

872

Lab

768

Lab

690

Lab

700

Lab

734

Lab

604

Lab

622

Lab

830

Lab

904

Lab

682

Lab

710

Lab

736

Lab

792

Lab

598

Lab

916

Lab

662

Lab

726

Lab

888

Lab

922

Lab

838

Lab

752

Lab

776

Lab

852

Lab

686

Lab

902

Lab

586

Lab

780

Lab

810

Lab

826

Lab

876

Lab

910

Lab

590

Lab

862

Lab

920

Lab

732

Lab

836

Lab

674

Lab

566

Lab

730

Lab

528

Lab

760

Lab

670

Lab

858

Lab

574

Lab

572

Lab

654

Lab

926

Lab

616

Lab

638

Lab

546

Lab

610

Lab

880

Lab

624

Lab

626

Lab

742

Lab

796

Lab

680

Lab

770

Lab

706

Lab

744

Lab

924

Lab

802

Lab

676

Lab

816

Lab

534

Lab

650

Lab

580

Lab

582

Lab

664

Lab

708

Lab

692

Lab

788

Lab

764

Lab

912

Lab

536

Lab

756

Lab

560

Lab

592

Lab

606

Lab

556

Lab

696

Lab

538

Lab

562

Lab

540

Lab

892

Lab

848

Lab

552

Lab

666

Lab

632

Lab

672

Lab

532

Lab

720

Lab

634

Lab

668

Lab

628

Lab

840

Lab

702

Lab

878

Lab

748

Lab

704

Lab

614

Lab

870

Lab

740

Lab

758

Lab

718

Lab

570

Lab

678

Lab

782

Lab

564

Lab

850

Lab

684

Lab

814

Lab

524

Fenamidone

NLG LLLL LL GGLG

or G = GC

or L = LC

or N = No Data****

95,0 % Acceptable

1,9 % Questionable

3,1 % Unacceptable


CV*: 15,2 %

n=156


4 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

550

Lab

706

Lab

892

Lab

896

Lab

1116

Lab

778

Lab

904

Lab

596

Lab

828

Lab

918

Lab

584

Lab

602

Lab

818

Lab

544

Lab

618

Lab

788

Lab

558

Lab

792

Lab

786

Lab

598

Lab

784

Lab

710

Lab

690

Lab

734

Lab

648

Lab

566

Lab

594

Lab

916

Lab

548

Lab

820

Lab

644

Lab

758

Lab

794

Lab

700

Lab

838

Lab

588

Lab

826

Lab

858

Lab

914

Lab

752

Lab

692

Lab

814

Lab

640

Lab

876

Lab

698

Lab

910

Lab

920

Lab

582

Lab

742

Lab

524

Lab

830

Lab

624

Lab

718

Lab

796

Lab

604

Lab

708

Lab

654

Lab

636

Lab

680

Lab

726

Lab

728

Lab

744

Lab

534

Lab

686

Lab

670

Lab

704

Lab

756

Lab

674

Lab

768

Lab

872

Lab

560

Lab

590

Lab

880

Lab

770

Lab

804

Lab

546

Lab

528

Lab

730

Lab

836

Lab

922

Lab

556

Lab

926

Lab

540

Lab

764

Lab

902

Lab

702

Lab

924

Lab

750

Lab

610

Lab

532

Lab

592

Lab

666

Lab

676

Lab

844

Lab

616

Lab

810

Lab

606

Lab

882

Lab

760

Lab

568

Lab

848

Lab

634

Lab

668

Lab

622

Lab

580

Lab

720

Lab

586

Lab

562

Lab

626

Lab

564

Lab

802

Lab

684

Lab

632

Lab

840

Lab

628

Fluxapyroxad

L L L L L L L G L G L L L L

or G = GC

or L = LC

or N = No Data*****

92,2 % Acceptable

1,7 % Questionable

6,1 % Unacceptable


CV*: 12,4 %

n=110


5 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

550

Lab

600

Lab

668

Lab

738

Lab

896

Lab

1116

Lab

908

Lab

802

Lab

594

Lab

544

Lab

828

Lab

592

Lab

596

Lab

676

Lab

644

Lab

560

Lab

742

Lab

616

Lab

892

Lab

648

Lab

562

Lab

634

Lab

910

Lab

670

Lab

680

Lab

752

Lab

870

Lab

756

Lab

794

Lab

772

Lab

868

Lab

902

Lab

682

Lab

576

Lab

736

Lab

760

Lab

836

Lab

690

Lab

624

Lab

602

Lab

666

Lab

546

Lab

810

Lab

548

Lab

924

Lab

568

Lab

558

Lab

584

Lab

606

Lab

770

Lab

590

Lab

684

Lab

726

Lab

840

Lab

876

Lab

534

Lab

872

Lab

750

Lab

862

Lab

904

Lab

706

Lab

744

Lab

916

Lab

788

Lab

918

Lab

564

Lab

702

Lab

728

Lab

700

Lab

678

Lab

730

Lab

754

Lab

618

Lab

720

Lab

528

Lab

538

Lab

674

Lab

758

Lab

580

Lab

556

Lab

598

Lab

614

Lab

654

Lab

686

Lab

778

Lab

604

Lab

922

Lab

536

Lab

622

Lab

764

Lab

692

Lab

818

Lab

734

Lab

792

Lab

796

Lab

786

Lab

582

Lab

610

Lab

880

Lab

784

Lab

920

Lab

858

Lab

586

Lab

740

Lab

914

Lab

540

Lab

718

Lab

636

Lab

848

Lab

704

Lab

632

Lab

710

Lab

826

Lab

768

Lab

698

Lab

708

Lab

532

Lab

782

Lab

566

Lab

640

Lab

820

Lab

804

Lab

626

Lab

570

Lab

838

Metaflimizone (sum of E- and Z- isomers)

L L L L L L L

****** or G = GC

or L = LC

or N = No Data

87, 2 % Acceptable

5,6 % Questionable

7,2 % Unacceptable


CV*: 23,6 %

n=119


6 False Negatives


EUPT-FV21 Results

EUPT-FV21 Results

Metaflumizone

EUPT-FV21 Results

Metaflumizone

EUPT-FV20 EUPT-FV21

EUPT-FV21 Results

92,6 % Acceptable

3,3 % Questionable

4,1 % Unacceptable


CV*: 22,6 %

n=122


For informative purposes. Only z scores of reported results

(evaluation of false negatives not assessed)

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

600

Lab

878

Lab

896

Lab

1116

Lab

628

Lab

738

Lab

602

Lab

576

Lab

754

Lab

656

Lab

552

Lab

718

Lab

882

Lab

736

Lab

608

Lab

674

Lab

562

Lab

704

Lab

566

Lab

614

Lab

592

Lab

636

Lab

726

Lab

908

Lab

570

Lab

622

Lab

610

Lab

800

Lab

574

Lab

586

Lab

740

Lab

534

Lab

648

Lab

848

Lab

780

Lab

556

Lab

710

Lab

548

Lab

590

Lab

746

Lab

584

Lab

606

Lab

662

Lab

666

Lab

772

Lab

594

Lab

744

Lab

536

Lab

792

Lab

818

Lab

604

Lab

580

Lab

684

Lab

788

Lab

916

Lab

640

Lab

770

Lab

550

Lab

644

Lab

750

Lab

756

Lab

802

Lab

830

Lab

844

Lab

904

Lab

544

Lab

700

Lab

582

Lab

546

Lab

626

Lab

764

Lab

810

Lab

786

Lab

632

Lab

650

Lab

676

Lab

804

Lab

902

Lab

910

Lab

564

Lab

686

Lab

794

Lab

850

Lab

892

Lab

752

Lab

816

Lab

682

Lab

692

Lab

796

Lab

616

Lab

596

Lab

624

Lab

680

Lab

734

Lab

924

Lab

828

Lab

852

Lab

598

Lab

618

Lab

670

Lab

678

Lab

742

Lab

760

Lab

826

Lab

920

Lab

560

Lab

708

Lab

702

Lab

720

Lab

876

Lab

528

Lab

784

Lab

572

Lab

588

Lab

820

Lab

922

Lab

836

Lab

782

Lab

926

Lab

862

Lab

748

Lab

840

Lab

730

Lab

872

Lab

914

Lab

858

Lab

540

Lab

932

Lab

532

Lab

698

Lab

634

Lab

654

Lab

690

Lab

798

Lab

838

Lab

558

Lab

778

Lab

768

Lab

538

Lab

668

Lab

868

Lab

728

Lab

880

Lab

774

Lab

568

Lab

706

Lab

918

Lab

814

Lab

758

Lab

696

Propamocarb

LL L L L LL LLL N

or G = GC

or L = LC

or N = No Data****

93,3 % Acceptable

2,0 % Questionable

4,7 % Unacceptable


CV*: 17,8 %

n=146


4 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

896

Lab

802

Lab

738

Lab

748

Lab

554

Lab

788

Lab

908

Lab

828

Lab

602

Lab

594

Lab

800

Lab

568

Lab

640

Lab

724

Lab

544

Lab

786

Lab

914

Lab

698

Lab

804

Lab

868

Lab

862

Lab

584

Lab

588

Lab

726

Lab

792

Lab

892

Lab

596

Lab

728

Lab

758

Lab

778

Lab

796

Lab

618

Lab

548

Lab

690

Lab

764

Lab

818

Lab

876

Lab

920

Lab

610

Lab

636

Lab

626

Lab

644

Lab

648

Lab

668

Lab

706

Lab

888

Lab

784

Lab

600

Lab

794

Lab

820

Lab

844

Lab

734

Lab

550

Lab

558

Lab

700

Lab

902

Lab

604

Lab

670

Lab

746

Lab

754

Lab

810

Lab

816

Lab

564

Lab

582

Lab

736

Lab

674

Lab

772

Lab

822

Lab

566

Lab

708

Lab

710

Lab

858

Lab

552

Lab

556

Lab

580

Lab

622

Lab

678

Lab

838

Lab

882

Lab

614

Lab

780

Lab

850

Lab

854

Lab

916

Lab

590

Lab

524

Lab

574

Lab

676

Lab

770

Lab

836

Lab

532

Lab

826

Lab

874

Lab

904

Lab

760

Lab

672

Lab

798

Lab

880

Lab

616

Lab

628

Lab

688

Lab

922

Lab

870

Lab

546

Lab

680

Lab

720

Lab

756

Lab

872

Lab

910

Lab

924

Lab

540

Lab

592

Lab

696

Lab

776

Lab

650

Lab

878

Lab

598

Lab

926

Lab

560

Lab

658

Lab

742

Lab

768

Lab

830

Lab

918

Lab

654

Lab

718

Lab

624

Lab

662

Lab

682

Lab

912

Lab

612

Lab

684

Lab

562

Lab

814

Lab

704

Lab

686

Lab

692

Lab

634

Lab

534

Lab

730

Lab

744

Lab

782

Lab

848

Lab

752

Lab

840

Lab

586

Lab

528

Lab

570

Lab

632

Lab

750

Lab

740

Lab

766

Lab

538

Lab

1116

Lab

656

Lab

702

Lab

852

Lab

606

Lab

576

Propyzamide

LGNNNGLLGGLG

or G = GC

or L = LC

or N = No Data

*

98,1 % Acceptable

0,6 % Questionable

1,3 % Unacceptable


CV*: 15,0 %

n=158


1 False Negative

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

724

Lab

738

Lab

896

Lab

1116

Lab

850

Lab

800

Lab

732

Lab

594

Lab

778

Lab

584

Lab

844

Lab

624

Lab

748

Lab

820

Lab

828

Lab

756

Lab

932

Lab

558

Lab

596

Lab

746

Lab

802

Lab

916

Lab

904

Lab

548

Lab

764

Lab

914

Lab

610

Lab

536

Lab

602

Lab

614

Lab

710

Lab

786

Lab

674

Lab

538

Lab

818

Lab

670

Lab

690

Lab

794

Lab

544

Lab

524

Lab

692

Lab

682

Lab

622

Lab

592

Lab

640

Lab

772

Lab

874

Lab

908

Lab

912

Lab

598

Lab

636

Lab

760

Lab

556

Lab

560

Lab

814

Lab

566

Lab

870

Lab

582

Lab

680

Lab

728

Lab

736

Lab

742

Lab

826

Lab

880

Lab

882

Lab

576

Lab

618

Lab

656

Lab

768

Lab

784

Lab

798

Lab

830

Lab

858

Lab

920

Lab

706

Lab

796

Lab

684

Lab

644

Lab

734

Lab

604

Lab

752

Lab

770

Lab

570

Lab

666

Lab

700

Lab

718

Lab

758

Lab

528

Lab

540

Lab

672

Lab

696

Lab

632

Lab

532

Lab

562

Lab

686

Lab

750

Lab

872

Lab

650

Lab

662

Lab

720

Lab

804

Lab

868

Lab

910

Lab

648

Lab

654

Lab

676

Lab

702

Lab

838

Lab

586

Lab

924

Lab

862

Lab

638

Lab

744

Lab

836

Lab

852

Lab

902

Lab

590

Lab

550

Lab

708

Lab

726

Lab

922

Lab

564

Lab

634

Lab

580

Lab

840

Lab

876

Lab

892

Lab

704

Lab

588

Lab

678

Lab

926

Lab

810

Lab

848

Lab

546

Lab

780

Lab

792

Lab

918

Lab

788

Lab

572

Lab

730

Lab

774

Lab

754

Lab

616

Lab

552

Lab

534

Lab

698

Lab

568

Lab

668

Lab

658

Lab

626

Lab

878

Lab

740

Lab

554

Lab

606

Lab

608

Lab

782

Lab

766

Lab

628

Pyraclostrobin

LLLGL

or G = GC

or L = LC

or N = No Data

****

92,4 % Acceptable

4,4 % Questionable

3,2 % Unacceptable


CV*: 15,2 %

n=154


4 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

532

Lab

576

Lab

668

Lab

814

Lab

896

Lab

1116

Lab

802

Lab

732

Lab

792

Lab

548

Lab

594

Lab

916

Lab

564

Lab

602

Lab

818

Lab

932

Lab

584

Lab

676

Lab

786

Lab

828

Lab

756

Lab

728

Lab

684

Lab

550

Lab

636

Lab

838

Lab

876

Lab

622

Lab

734

Lab

674

Lab

610

Lab

632

Lab

902

Lab

920

Lab

618

Lab

592

Lab

870

Lab

562

Lab

624

Lab

672

Lab

692

Lab

616

Lab

524

Lab

536

Lab

538

Lab

586

Lab

606

Lab

644

Lab

670

Lab

868

Lab

922

Lab

582

Lab

598

Lab

614

Lab

736

Lab

794

Lab

758

Lab

926

Lab

566

Lab

690

Lab

784

Lab

552

Lab

640

Lab

872

Lab

654

Lab

596

Lab

778

Lab

858

Lab

904

Lab

580

Lab

768

Lab

710

Lab

544

Lab

572

Lab

678

Lab

742

Lab

798

Lab

804

Lab

844

Lab

892

Lab

702

Lab

682

Lab

686

Lab

708

Lab

780

Lab

590

Lab

568

Lab

726

Lab

680

Lab

914

Lab

746

Lab

760

Lab

764

Lab

540

Lab

718

Lab

840

Lab

910

Lab

924

Lab

650

Lab

706

Lab

836

Lab

788

Lab

918

Lab

666

Lab

796

Lab

848

Lab

648

Lab

810

Lab

546

Lab

634

Lab

880

Lab

750

Lab

698

Lab

560

Lab

626

Lab

820

Lab

604

Lab

556

Lab

754

Lab

558

Lab

770

Lab

720

Lab

570

Lab

826

Lab

908

Lab

704

Lab

730

Lab

744

Lab

628

Lab

534

Lab

862

Lab

700

Lab

782

Lab

830

Lab

588

Lab

528

Lab

752

Teflubenzuron

L L L LL L LL L

or G = GC

or L = LC

or N = No Data

******

92,7 % Acceptable

0,7 % Questionable

6,6 % Unacceptable


CV*: 18,4 %

n=131


6 False Negatives

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

576

Lab

896

Lab

554

Lab

820

Lab

594

Lab

728

Lab

838

Lab

600

Lab

828

Lab

904

Lab

584

Lab

868

Lab

916

Lab

724

Lab

778

Lab

818

Lab

596

Lab

640

Lab

756

Lab

538

Lab

876

Lab

922

Lab

732

Lab

598

Lab

920

Lab

558

Lab

690

Lab

726

Lab

544

Lab

602

Lab

804

Lab

568

Lab

794

Lab

932

Lab

914

Lab

888

Lab

524

Lab

550

Lab

800

Lab

618

Lab

654

Lab

548

Lab

552

Lab

746

Lab

556

Lab

622

Lab

752

Lab

816

Lab

536

Lab

574

Lab

644

Lab

648

Lab

680

Lab

928

Lab

702

Lab

754

Lab

768

Lab

638

Lab

670

Lab

706

Lab

764

Lab

772

Lab

908

Lab

912

Lab

1116

Lab

562

Lab

736

Lab

882

Lab

750

Lab

604

Lab

662

Lab

760

Lab

852

Lab

874

Lab

858

Lab

704

Lab

788

Lab

830

Lab

762

Lab

710

Lab

656

Lab

784

Lab

798

Lab

826

Lab

682

Lab

586

Lab

902

Lab

636

Lab

792

Lab

872

Lab

610

Lab

758

Lab

776

Lab

532

Lab

616

Lab

560

Lab

664

Lab

836

Lab

862

Lab

850

Lab

546

Lab

650

Lab

674

Lab

730

Lab

734

Lab

796

Lab

742

Lab

566

Lab

582

Lab

590

Lab

718

Lab

692

Lab

700

Lab

802

Lab

534

Lab

770

Lab

780

Lab

880

Lab

614

Lab

814

Lab

924

Lab

626

Lab

632

Lab

658

Lab

668

Lab

844

Lab

580

Lab

686

Lab

910

Lab

570

Lab

634

Lab

878

Lab

676

Lab

528

Lab

708

Lab

892

Lab

720

Lab

678

Lab

698

Lab

840

Lab

624

Lab

592

Lab

744

Lab

666

Lab

672

Lab

918

Lab

786

Lab

572

Lab

848

Lab

540

Lab

696

Lab

870

Lab

774

Lab

588

Lab

688

Lab

926

Lab

564

Lab

606

Lab

766

Lab

810

Lab

782

Lab

740

Lab

684

Lab

628

Trifloxystrobin

L LLGGLLLL L LNL

or G = GC

or L = LC

or N = No Data**

97,6 % Acceptable

0,6 % Questionable

1,8 % Unacceptable


CV*: 13,4 %

n=162


2 False Negatives

EUPT-FV21 Results

-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

576

Lab

598

Lab

628

Lab

814

Lab

896

Lab

594

Lab

844

Lab

656

Lab

698

Lab

756

Lab

750

Lab

748

Lab

602

Lab

828

Lab

778

Lab

674

Lab

904

Lab

876

Lab

584

Lab

838

Lab

732

Lab

624

Lab

550

Lab

916

Lab

818

Lab

548

Lab

618

Lab

680

Lab

524

Lab

870

Lab

908

Lab

566

Lab

558

Lab

734

Lab

820

Lab

534

Lab

784

Lab

690

Lab

588

Lab

700

Lab

872

Lab

932

Lab

918

Lab

752

Lab

744

Lab

914

Lab

544

Lab

592

Lab

672

Lab

858

Lab

670

Lab

920

Lab

826

Lab

862

Lab

666

Lab

586

Lab

794

Lab

924

Lab

622

Lab

640

Lab

760

Lab

754

Lab

564

Lab

706

Lab

882

Lab

596

Lab

662

Lab

536

Lab

676

Lab

792

Lab

556

Lab

852

Lab

702

Lab

786

Lab

616

Lab

692

Lab

718

Lab

780

Lab

902

Lab

728

Lab

880

Lab

730

Lab

922

Lab

764

Lab

590

Lab

684

Lab

560

Lab

742

Lab

770

Lab

654

Lab

528

Lab

644

Lab

686

Lab

636

Lab

710

Lab

650

Lab

726

Lab

810

Lab

868

Lab

878

Lab

634

Lab

570

Lab

788

Lab

538

Lab

708

Lab

836

Lab

802

Lab

678

Lab

910

Lab

580

Lab

704

Lab

604

Lab

798

Lab

546

Lab

606

Lab

772

Lab

840

Lab

568

Lab

540

Lab

892

Lab

782

Lab

572

Lab

532

Lab

758

Lab

610

Lab

848

Lab

768

Lab

562

Lab

736

Lab

614

Lab

804

Lab

682

Lab

648

Lab

668

Lab

626

Lab

740

Lab

582

Lab

720

Lab

696

Lab

1116

Lab

632

Lab

796

Triflumuron

L L L G L LLL

or G = GC

or L = LC

or N = No Data*****

93,0 % Acceptable

2,1 % Questionable

4,9 % Unacceptable


CV*: 17,3 %

n=137


5 False Negatives

EUPT-FV21 Results

Voluntary Componds

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

558

Lab

756

Lab

758

Lab

802

Lab

882

Lab

892

Lab

896

Lab

908

Lab

1116

Lab

602

Lab

778

Lab

584

Lab

610

Lab

858

Lab

596

Lab

838

Lab

710

Lab

594

Lab

868

Lab

786

Lab

622

Lab

532

Lab

916

Lab

548

Lab

546

Lab

792

Lab

820

Lab

544

Lab

818

Lab

618

Lab

744

Lab

902

Lab

598

Lab

654

Lab

734

Lab

562

Lab

640

Lab

670

Lab

830

Lab

836

Lab

682

Lab

718

Lab

784

Lab

768

Lab

560

Lab

752

Lab

796

Lab

826

Lab

922

Lab

706

Lab

918

Lab

556

Lab

764

Lab

624

Lab

582

Lab

730

Lab

564

Lab

760

Lab

876

Lab

574

Lab

666

Lab

794

Lab

804

Lab

844

Lab

920

Lab

566

Lab

534

Lab

700

Lab

626

Lab

580

Lab

680

Lab

924

Lab

690

Lab

708

Lab

880

Lab

590

Lab

770

Lab

686

Lab

632

Lab

636

Lab

702

Lab

672

Lab

674

Lab

746

Lab

816

Lab

540

Lab

726

Lab

586

Lab

720

Lab

528

Lab

728

Lab

568

Lab

606

Lab

750

Lab

742

Lab

810

Penthiopyrad

L L L L L L L G L G L

or G = GC

or L = LC

or N = No Data* * * * * * * * *

89,6 % Acceptable

0,0 % Questionable

10,4 % Unacceptable


CV*: 12,4 %

n=87


9 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

614

Lab

558

Lab

576

Lab

582

Lab

758

Lab

766

Lab

896

Lab

1116

Lab

584

Lab

756

Lab

778

Lab

760

Lab

810

Lab

636

Lab

908

Lab

594

Lab

796

Lab

602

Lab

830

Lab

710

Lab

548

Lab

786

Lab

586

Lab

598

Lab

534

Lab

674

Lab

794

Lab

878

Lab

656

Lab

820

Lab

784

Lab

610

Lab

818

Lab

680

Lab

744

Lab

770

Lab

734

Lab

564

Lab

670

Lab

692

Lab

804

Lab

880

Lab

632

Lab

618

Lab

544

Lab

556

Lab

596

Lab

704

Lab

546

Lab

918

Lab

622

Lab

924

Lab

640

Lab

706

Lab

838

Lab

686

Lab

802

Lab

902

Lab

920

Lab

532

Lab

836

Lab

634

Lab

700

Lab

792

Lab

528

Lab

624

Lab

702

Lab

826

Lab

862

Lab

560

Lab

768

Lab

590

Lab

568

Lab

926

Lab

678

Lab

876

Lab

872

Lab

654

Lab

690

Lab

566

Lab

740

Lab

922

Lab

682

Lab

730

Lab

562

Lab

708

Lab

728

Lab

892

Lab

720

Lab

570

Lab

666

Lab

626

Lab

844

Lab

858

Spinetoram

N L L L L L N

or G = GC

or L = LC

or N = No Data

** * * * * * *

85,1 % Acceptable

4,3 % Questionable

10,6 % Unacceptable


CV*: 21,6 %

n=86


8 False Negatives

EUPT-FV21 Results-5

-4

-3

-2

-1

0

1

2

3

4

5

Lab

532

Lab

558

Lab

594

Lab

666

Lab

678

Lab

730

Lab

734

Lab

758

Lab

800

Lab

810

Lab

838

Lab

844

Lab

892

Lab

896

Lab

1116

Lab

826

Lab

548

Lab

778

Lab

584

Lab

744

Lab

742

Lab

796

Lab

674

Lab

564

Lab

720

Lab

804

Lab

686

Lab

858

Lab

760

Lab

556

Lab

830

Lab

586

Lab

622

Lab

540

Lab

680

Lab

634

Lab

624

Lab

786

Lab

750

Lab

868

Lab

918

Lab

718

Lab

728

Lab

756

Lab

922

Lab

560

Lab

788

Lab

820

Lab

926

Lab

764

Lab

876

Lab

528

Lab

708

Lab

902

Lab

924

Lab

546

Lab

880

Lab

572

Lab

802

Tritosulfuron

L L L L

or G = GC

or L = LC

or N = No Data

* * * * * * * * * * * * * * *

72,9 % Acceptable

1,7 % Questionable

25,4 % Unacceptable


CV*: 19,7 %

n=45


15 False Negatives

EUPT-FV21 Results

Combined z-Scores

EUPT-FV21 Results

Average of Squared z-Scores

AZ2 ≤ 2.0 Good

2.0 < AZ2 < 3.0 Satisfactory

AZ2 ≥ 3.0 Unsatisfactory

Category A

Laboratories that were able to analyse at least 90% of the

compulsory pesticides in the target pesticides list, that detected

and quantified at least 90 % of the pesticides present in the Test Item

and reported no false positives.

EUPT-FV21 Results

Category A: 65 % of the EU/EFTA Laboratories


96 % Good 4 % Satisfactory 0 % Unsatisfactory

24 NRLs in Category A

5 NRLs in Category B

NRLs

OfLs

Category A Clasification

EUPT-FV21 Results

EUPT-FV20 : 94 % Good 5 % Satisfactory 1 % Unsatisfactory

Category A: 65 % of the EU/EFTA Laboratories


EUPT-FV20: 66 % of the EU/EFTA Laboratories

96 % Good 4 % Satisfactory 0 % Unsatisfactory

24 NRLs in Category A

5 NRLs in Category B

NRLs

OfLs

Category A Clasification

EUPT-FV21 Results

False Positives

8 laboratories reported 6 pesticides as false

positives (including non-EU/EFTA)

Lab Code PesticideReporting level

(mg/kg)

Concentration

(mg/kg)

Determination

technique

608

Benalaxyl including other

mixtures of constituent isomers

including benalaxyl-M (sum of

isomers)

0.01 0.048 GC-MS/MS (QQQ)

786

Benalaxyl including other

mixtures of constituent isomers

including benalaxyl-M (sum of

isomers)

0.01 0.0159 GC-MS/MS (QQQ)

716 Chlorfenapyr 0.01 0.14 LC-MS/MS QQQ

868 Chlorpyrifos-methyl 0.01 0.05 GC-MS/MS (QQQ)

758 Diflubenzuron 0.01 0.038 GC-MS/MS (QQQ)

884 Diflubenzuron 0.01 0.064 GC-MS

882 Diphenylamine 0.01 0.0136 LC-MS/MS QQQ

722 Fluopicolide 0.01 0.137 GC- (µ) ECD

EUPT-SM10 Results

4th Joint Workshop of the European Union Reference Laboratories for Residues of PesticidesAlmería 23rd-25th October 2013

EUPT-FV18 Preliminary Results 18th May 2016EUPT-SM11 Results

ACTIVITY DATE

Publishing the Calendar and Matrix on the Web page. January 2019

Receiving Application Form from invited laboratories. 28th

Dec – 25th

Jan 2019

Specific Protocol published on the Web site. 11th

Feb 2019 at the latest

Sample distribution. 25th

February 2019

Deadline for receiving results: Fill in “Results Page” 72 hours after receiving the sample

Preliminary Report: only results. no statistical treatment. Last week of March 2019

Final Report distributed to the Laboratories. August 2019






Pesticides used for the treatment

Bifenazate Metrafenone

Etoxazole Orthosulfamuron

Fenpyrazamine Penthiopyrad

Flubendiamide Propoxur

Flufenacet Pyridalil

Fluopicolide Spinetoram

Isoprothiolane Tricyclazole

Isopyrazam Valifenalate



20 EU/EFTA

CountriesChina

Costa Rica

Kenya

Turkey

4 Non EU/EFTA

Countries

AustriaBelgiumCroatiaCzech Republic DenmarkFinlandFranceGermanyHungaryIrelandItalyLithuaniaMaltaNetherlandsNorway

SloveniaSpainSwedenSwitzerlandUnited Kingdom

Participation

67 Participants



EUPT-FV-SM011- Participants

COUNTRY No. COUNTRY No.

Austria 1 Italy 7

Belgium 5 Kenia 1

China 3 Lithuania 1

Costa Rica 1 Malta 1

Croatia 1 Norway 1

Czech Republic 2 Slovenia 1

Denmark 1 Spain 10

Finland 1 Sweden 2

France 4 Switzerland 2

Germany 12 The Netherlands 2

Hungary 4 Turkey 1

Ireland 1 UK 1

67 Participants

Participation



RESULTS



Concentrations

Pesticid

es

No of

Detections

Nº of Labs

detected

the

pesticide

% of Labs

detected the

pesticide

No of

concentrations

Reported

Robust

mean

(mg/kg)

CV

(%)

Bifenazate 58 53 79 43 0.037 44.9

Bifenazate-

diazene*15 15 22 9 0.031 46.2

Etoxazole 69 62 93 58 0.060 20.7

Fenpyrazamine 58 52 78 47 0.052 17.2

Flubendiamide 56 52 78 47 0.065 22.8

Flufenacet 62 57 85 49 0.085 21.1

Fluopicolide 64 60 90 54 0.084 19.5

Isoprothiolane 65 58 87 55 0.067 18.5

Isopyrazam 55 51 76 44 0.057 22.0

Metrafenone 65 59 88 54 0.064 20.8

Orthosulfamuron 28 26 39 18 0.119 79.8

Penthiopyrad 56 51 76 44 0.054 17.9

Propoxur 68 62 93 57 0.081 18.1

Pyridalil 55 50 75 42 0.041 12.9

Spinetoram 71 54 81 49 0.052 35.1

Tricyclazole 62 57 85 51 0.082 15.2

Valifenalate 44 42 63 31 0.043 20.2



Concentrations

Pesticid

es

No of

Detections

Nº of Labs

detected

the

pesticide

% of Labs

detected the

pesticide

No of

concentrations

Reported

Robust

mean

(mg/kg)

CV

(%)

Bifenazate 58 53 79 43 0.037 44.9

Bifenazate-

diazene*15 15 22 9 0.031 46.2

Etoxazole 69 62 93 58 0.060 20.7

Fenpyrazamine 58 52 78 47 0.052 17.2

Flubendiamide 56 52 78 47 0.065 22.8

Flufenacet 62 57 85 49 0.085 21.1

Fluopicolide 64 60 90 54 0.084 19.5

Isoprothiolane 65 58 87 55 0.067 18.5

Isopyrazam 55 51 76 44 0.057 22.0

Metrafenone 65 59 88 54 0.064 20.8


Penthiopyrad 56 51 76 44 0.054 17.9

Propoxur 68 62 93 57 0.081 18.1

Pyridalil 55 50 75 42 0.041 12.9

Spinetoram 71 54 81 49 0.052 35.1

Tricyclazole 62 57 85 51 0.082 15.2

Valifenalate 44 42 63 31 0.043 20.2



Concentrations

Pesticid

es

No of

Detections

Nº of Labs

detected

the

pesticide

% of Labs

detected the

pesticide

No of

concentrations

Reported

Robust

mean

(mg/kg)

CV

(%)

Bifenazate 58 53 79 43 0.037 44.9

Bifenazate-

diazene*15 15 22 9 0.031 46.2

Etoxazole 69 62 93 58 0.060 20.7

Fenpyrazamine 58 52 78 47 0.052 17.2

Flubendiamide 56 52 78 47 0.065 22.8

Flufenacet 62 57 85 49 0.085 21.1

Fluopicolide 64 60 90 54 0.084 19.5

Isoprothiolane 65 58 87 55 0.067 18.5

Isopyrazam 55 51 76 44 0.057 22.0

Metrafenone 65 59 88 54 0.064 20.8


Penthiopyrad 56 51 76 44 0.054 17.9

Propoxur 68 62 93 57 0.081 18.1

Pyridalil 55 50 75 42 0.041 12.9

Spinetoram 71 54 81 49 0.052 35.1

Tricyclazole 62 57 85 51 0.082 15.2

Valifenalate 44 42 63 31 0.043 20.2



Concentrations

Pesticid

es

No of

Detections

Nº of Labs

detected

the

pesticide

% of Labs

detected the

pesticide

No of

concentrations

Reported

Robust

mean

(mg/kg)

CV

(%)

Bifenazate 58 53 79 43 0.037 44.9

Bifenazate-

diazene*15 15 22 9 0.031 46.2

Etoxazole 69 62 93 58 0.060 20.7

Fenpyrazamine 58 52 78 47 0.052 17.2

Flubendiamide 56 52 78 47 0.065 22.8

Flufenacet 62 57 85 49 0.085 21.1

Fluopicolide 64 60 90 54 0.084 19.5

Isoprothiolane 65 58 87 55 0.067 18.5

Isopyrazam 55 51 76 44 0.057 22.0

Metrafenone 65 59 88 54 0.064 20.8


Penthiopyrad 56 51 76 44 0.054 17.9

Propoxur 68 62 93 57 0.081 18.1

Pyridalil 55 50 75 42 0.041 12.9

Spinetoram 71 54 81 49 0.052 35.1

Tricyclazole 62 57 85 51 0.082 15.2

Valifenalate 44 42 63 31 0.043 20.2



Concentrations

Pesticid

es

No of

Detections

Nº of Labs

detected

the

pesticide

% of Labs

detected the

pesticide

No of

concentrations

Reported

Robust

mean

(mg/kg)

CV

(%)

Bifenazate 58 53 79 43 0.037 44.9

Bifenazate-

diazene*15 15 22 9 0.031 46.2

Etoxazole 69 62 93 58 0.060 20.7

Fenpyrazamine 58 52 78 47 0.052 17.2

Flubendiamide 56 52 78 47 0.065 22.8

Flufenacet 62 57 85 49 0.085 21.1

Fluopicolide 64 60 90 54 0.084 19.5

Isoprothiolane 65 58 87 55 0.067 18.5

Isopyrazam 55 51 76 44 0.057 22.0

Metrafenone 65 59 88 54 0.064 20.8


Penthiopyrad 56 51 76 44 0.054 17.9

Propoxur 68 62 93 57 0.081 18.1

Pyridalil 55 50 75 42 0.041 12.9

Spinetoram 71 54 81 49 0.052 35.1

Tricyclazole 62 57 85 51 0.082 15.2

Valifenalate 44 42 63 31 0.043 20.2



Bif

en

azat

e

Bif

en

azat

e-d

iaze

ne

*

Eto

xazo

le

Fen

pyr

azam

ine

Flu

be

nd

iam

ide

Flu

fen

acet

Flu

op

ico

lide

Iso

pro

thio

lan

e

Iso

pyr

azam

Met

rafe

no

ne

Ort

ho

sulf

amu

ron

Pe

nth

iop

yrad

Pro

po

xur

Pyr

idal

il

Spin

eto

ram

Tric

ycla

zole

Val

ife

nal

ate

Total Number of

Reported

Pesticides53 15 62 52 52 57 60 58 51 59 26 51 62 50 54 57 42

% of Reported

Pesticides 79 22 93 78 78 85 90 87 76 88 39 76 93 75 81 85 63

16 Evaluated Pesticides + bifenazate diazene (only informative)67 Laboratories

16 Pesticides= 1+1+14

Results



*



Results



58%

Results



58%

Results

72%



82% 58%

Results

72%



mg

/kg



No HRMS

HRMS

+25%

-25%

mg

/kg

Homogeneity: 0.045 mg/kg

No of Detections(% of Laboratories)

No of ConcentrationReported

58 (79%) 43



+25%

-25%

mg

/kg



15 (22%) 9

No HRMS

HRMS

-

*Only for informative purposes



+25%

-25%

mg

/kg




69 (93%) 58

No HRMS

HRMS



+25%

-25%

mg

/kg




58 (78%) 47

No HRMS

HRMS



+25%

-25%




56 (78%) 47

No HRMS

HRMS



+25%

-25%




62 (85%) 49

No HRMS

HRMS



+25%

-25%




64 (90%) 54

No HRMS

HRMS



+25%

-25%




65 (87%) 55

No HRMS

HRMS



+25%

-25%




55 (76%) 44

No HRMS

HRMS



+25%

-25%




65 (88%) 54

No HRMS

HRMS



+25%

-25%




28 (39%) 18

No HRMS

HRMS



+25%

-25%




56 (76%) 44

No HRMS

HRMS



+25%

-25%




68 (93%) 57

No HRMS

HRMS



+25%

-25%




55 (75%) 42

No HRMS

HRMS



+25%

-25%




71 (81%) 49

No HRMS

HRMS



+25%

-25%


No HRMS

HRMS



62 (85%) 51



+25%

-25%




44 (63%) 31

No HRMS

HRMS



Results

Other compounds (pesticides, natural products….)

reported by laboratories:

Reported below 0.01 mg/kg or not quantified

Buprofezin Phenylphenol

Diuron Propiconazole (sum of isomers)

Fenoxycarb Spirotetramat

Flupyradifurone Sulphur

Goitrine Tembotrione

Paraquat Tetraconazole

Permethrin Thiamethoxam

Phenothrin Trifluralin



Results

Other compounds reported by laboratories:

Reported ABOVE 0.01 mg/kg

Aldimorph Isocarbophos Spinosad

Cymiazole Isoxaflutole Spiroxamine

Diuron Metconazole Sulfamethoxazole

Triticonazole

EUPT-SM10 Results

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