Revision date: 11/2/2016 11. Identification Product Identifier Product name Product number Revision: 3.5 BE*.&' SAFETY DATA SHEET BELZONA® 1111 (SUPER METAL) SOLIDIFIER BELZONA® 1111 (SUPER METAL) SOLIDIFIER SN2598 Recommended use of the chemical and restrictions on use Application Uses advised against Engineering grade repair system for repairing and rebuilding machinery and equipment. For industrial use only. The product should not be used for purposes other than those recommended in the appropriate Instructions For Use (IFU) leaflet. Details of the supplier of the safety data sheet Supplier Manufacturer Emergency telephone number Emergency telephone 12. Hazard(s) Identification Belzona Inc. 2000 N.W. 88 Court Miami FL 33172 UNITED STATES 1-305-594-4994 [email protected]Belzona Polymerics Limited Claro Road, Harrogate HG14DS United Kingdom +44 1423 567641 [email protected]ChemTel: 1-800-255-3924 (North America) ChemTel: +1 813-248-0585 (International) Belzona Canada Inc. 51-588 Edward Avenue Richmond Hill Ontario, L4C 9Y6 CANADA 1-905-737-2225 [email protected]Classification of the substance or mixture OSHA Regulatory Status Physical hazards Health hazards Environmental hazards Reference Label elements This Product is Hazardous under the OSHA Hazard Communication Standard. Not Classified Skin Carr. 1 B- H314 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Not Classified The full text for all hazard statements is displayed in Section 16. 1/13
Transcript
Revision date: 11/2/2016
11. Identification
Product Identifier
Product name
Product number
Revision: 3.5
BE*.&' SAFETY DATA SHEET
BELZONA® 1111 (SUPER METAL) SOLIDIFIER
BELZONA® 1111 (SUPER METAL) SOLIDIFIER
SN2598
Recommended use of the chemical and restrictions on use
Application
Uses advised against
Engineering grade repair system for repairing and rebuilding machinery and equipment. For industrial use only.
The product should not be used for purposes other than those recommended in the appropriate Instructions For Use (IFU) leaflet.
The full text for all hazard statements is displayed in Section 16.
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BELZONA® 1111 (SUPER METAL) SOLIDIFIER
Pictogram
~<9 Signal word Danger
Hazard statements
Precautionary statements
Contains
Other hazards
Not applicable.
Hazards not otherwise classified (HNOC)
H314 Causes savere skin bums and eye damage. H317 May causa an allergic skin reaction.
P260 Do nat breathe vapors. P264 Wash contaminated skin tt10roughly after handling. P2n Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective clothing, gloves, eye and faca protection. P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P303+361 +353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351 +P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P31 0 Immediately call a poison canter or doctor. P333+3131fskin initation or rash occurs: Get medical attention. P362+P364 Take off contaminated clothing and wash it before reuse. P405 Store locked up. P501 Dispose of contents/container in aocordanca with all Federal, State/Provincial and local regulations.
Diethylenetriamine is toxic by inhalation when aerosolized or sprayed, however the chemical vapors show no signs of toxicity. If the product is not aerosolized or sprayed, inhalation toxicity does not apply when the toxicity of the finished product is calculated.
Description of first aid measures
General information
Inhalation
Ingestion
Skin Contact
Eye contact
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
Remove to fresh air. Keep the patient warm and at rest. Give nothing by mouth.
If accidentally swallowed obtain immediate medical attention. Keep at rest. Rinse mouth with plenty of water. Do NOT induce vomiting.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. If irritation or inflammation persists, seek medical attention.
Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart, and seek medical advice.
Most important symptoms and effects, both acute and delayed
Inhalation
Ingestion
Skin contact
Eye contact
Exposure to vapors may result in irritation of the mucous membrane and the respiratory system; in severe cases burns may occur.
May cause chemical bums in mouth, esophagus and stomach.
Skin contact causes chemical bums. Symptoms may include pain, severe local redness and tissue damage. May cause allergic skin reaction.
Contact with eyes may cause severe irritation with corneal injury, which may result in permanent impairment of vision.
Indication of immediate medical attention and special treatment needed
Notes for the doctor None.
!s. Fire-fighting measures
Extinguishing media
Suitable extinguishing media Use: sand, alcohol resistant foam, carbon dioxide, chemical powder, or water fog for larger fires. Do NOT use water jet.
Special hazards arising from the substance or mixture
Flammability Class
Hazardous combustion products
Advice for firefighters
3.2 Combustible Liquid I liB
In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen and ammonia may be produced.
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Protective actions during firefighting
[s. Accidental release measures
Fire will produce dense black smoke containing hazardous products of combustion. Exposure to decomposition products may be a hazard to health. Appropriate positive-pressure selfcontained breathing apparatus (SCBA) and full fire fighting tum-out gear (Bunker gear) should be worn. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains, sewers, ditches or waterways.
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Exclude non-essential personnel. Keep up-wind of spill to avoid breathing vapors. Do not get on skin or in eyes.
Prevent spills from entering drains or sewers. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
Methods and material for containment and cleaning up
Methods for cleaning up Scrape the majority of the product into a suitable labeled container. Cover the spill area with sand or other suitable inert material and sweep up into the container. Clean surfaces down with a water and detergent mixture. Do not allow spilled product or the associated washings to enter surface water drains or watercourses.
Reference to other sections For personal protection, see Section 8. For waste disposal, see section 13 ..
[7. Handling and storage
Precautions for safe handling
Usage precautions
Advice on general occupational hygiene
Keep the container tightly closed when not in use. Vapors may collect in the container headspace during transit or prolonged storage. Avoid breathing vapor when opening the container. Where possible open containers and mix components in a well ventilated place away from the application area. Exclude non-essential personnel. Minimise the number of employees exposed and the duration of their exposure. Do not get on skin or in eyes. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection see Section 8. Always keep in containers made of the same material as the supply container. Ensure emergency equipment (for fires, spills, leaks, etc.) is readily available. Good housekeeping methods and regular safe removal of waste materials should be observed. FIRE/EXPLOSION This product is combustible. Exclude sources of heat, sparks and open flame.
Wash at the end of each work shift and before eating, smoking and using the toilet. Ensure eye wash facilities (fountain, bottle, vials, etc.) are readily available. Do not put contaminated articles or equipment e.g. spatulas, applicators, brushes, cloths etc., into pockets. Where necessary, contaminated work clothing and shoes should be removed to prevent cross contamination of surfaces and the risk of inadvertent skin contact and ingestion.
Conditions for safe storage, including any incompatibilities
Storage precautions
Specific end uses(s)
Observe the label precautions. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Store separately from oxidizing agents and strongly acidic materials. ENVIRONMENTAL STORAGE PRECAUTIONS Spillage, incorrect storage of chemicals or waste materials or unsuitable disposal activities can result in pollutants seeping through the soil, causing serious harm to groundwater- which is a vital source of drinking water. All wastes, especially liquid wastes, should be securely stored on site in designated areas that are isolated from waterways and groundwater and diked to contain any spillages.
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Specific end use(s)
Revision: 3.5
BELZONA® 1111 (SUPER METAL} SOLIDIFIER
Application by plastic applicator or spatula provided. Mix with Base component before use. Please refer to the relevant Belzona® Instructions For Use for further information.
Sk ACGIH =American Conference of Governmental Industrial Hygienists.
Sk = Danger of cutaneous absorption.
Ingredient comments
Exposure controls
Appropriate engineering controls
Eye/face protection
Hand protection
other skin and body protection
The risk of exposure by inhalation to hazardous concentrations of diethylenetriamine under normal working conditions in a well ventilated area is minimal.
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of vapors below the relevant occupational exposure limits, suitable respirators should be worn (see 'Respiratory protection' below).
It is recommended that eye protection, for example safety glasses with side shields or goggles are worn at all times during the handling and use of this material. . During subsequent machining, grinding, abrasion or removal of this product appropriate eye protection should be selected according to the type of tools or equipment used .
. The breakthrough time of the gloves selected should exceed the expected use period. Where this is not possible, gloves should be changed in good time, and in any case before the breakthrough time is exceeded. Where doubt exists, advice should be sought from manufacturers or vendors of protective gloves in order to determine appropriate types for the particular circumstances. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. SPECIFIC RECOMMENDATIONS Wear protective gloves made ofthe following material: Neoprene. Nitrile rubber. STANDARD APPLICATIONS I EMERGENCY SITUATIONS Medium-heavy weight gauntlet type gloves that provide wrist protection are suitable. EMERGENCY REPAIRS OR APPLICATION OF SINGLE UNITS light weight disposable gloves are normally suitable.
STANDARD APPLICATIONS Synthetic polyethylene coveralls such as the Tyvek PRoTECH® or equivalent coveralls manufactured to provide protection against liquid chemicals should be worn. Grossly contaminated dothing should be removed and the skin washed with soap and water or a proprietary skin deaner. EMERGENCY REPAIRS OR APPLICATION OF SINGLE UNITS Cotton overalls are normally suitable.
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Respiratory protection Respirators are not normally required, but may be required when this product is used in confined spaces or where adequate ventilation cannot be achieved. It is essential that the concentration of the contaminant(s) in the application environment does not exceed the applicable occupational exposure limit(s) multiplied by the Assigned Protection Factor (APF) quoted for the respiratory protective equipment selected. Where necessary, it is recommended that an OSHAfNIOSH approved air-purifying full facepiece or half-face respirator equipped with appropriate vapor cartridge(s) should be worn. Where the application environment is likely to be contaminated by significant concentrations of dust then the appropriate particulate prefilter (N-, R- or, P-series) should be worn in combination with the above. It is essential that the facepiece is correctly fitted and the filter is changed in accordance with the manufacturer's instructions.
Immediate danger to life and health
Where entry into unknown or Immediately Dangerous To Life or Health (IDLH) atmospheres is required, an OSHAfNIOSH approved pressure-demand self-contained breathing apparatus (SCBA) with a full facepiece or a pressure-demand supplied-air respirator (SAR) with a full facepiece in combination with an auxiliary pressure-demand SCBA respirator should be worn.
[9. Physical and Chemical Properties
Information on basic physical and chemical properties
Appearance Paste.
Color Light gray.
Odor Amine.
Odor threshold Not applicable.
pH Alkaline.
Melting point Not available.
Initial boiling point and range >100°C/>212°F@ 760 mm Hg
Flash point >100°C/>212°F CC (Closed cup).
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or Not applicable. explosive limits
Vapor pressure Low.
Vapor density > 1
Relative density 1.62- 1.72@ 20"C/68"F
Solubility(ies) Immiscible with water.
Partition coefficient Not available.
Auto-ignition temperature Not available.
Decomposition Temperature Not available.
Viscosity Not available.
Explosive properties Not applicable.
Oxidizing properties Not applicable.
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Other information
I 1 0. Stability and reactivity
Reactivity
Stability
Possibility of hazardous reactions
Conditions to avoid
Materials to avoid
Hazardous decomposition products
I 11. Toxicological information
Revision: 3.5
BELZONA® 1111 (SUPER METAL} SOLIDIFIER
This section contains typical values for Health, Safety and Environmental guidance only and is not intended to represent a technical specification for the product.
There are no known reactivity hazards associated with this product.
Stable under recommended storage and handling conditions (see Section 7).
No hazardous reactions expected when stored and handled as recommended.
There are no known conditions that are likely to result in a hazardous situation.
Keep away from oxidizing agents and strongly acidic materials to prevent the possibility of exothermic reaction.
Does not decompose when used and stored as recommended.
Information on toxicological effects
Notes (oral LD!!O)
Notes (dermal LD~~a)
Acute toxicity - inhalation
Notes (inhalation LCIIO)
Skin corrosion/irritation
Animal data
Serious eye damage/irritation
Based on available data the dassification criteria are not met.
Based on available data the dassification criteria are not met.
Based on available data the dassification criteria are not met.
Corrosive to skin.
Serious eye damage/irritation Skin corrosive, assume corrosivity to eyes. No testing is needed.
Respiratory sensitization
Respiratory sensitization
Skin sensitization
Skin sensitization
Germ cell mutagenicity
Genotoxicity - in vitro
Genotoxicity - in vivo
Carcinogenicity
Carcinogenicity
IARC carcinogenicity
NTP carcinogenicity
OSHA Carcinogenicity
Reproductive toxicity
Based on available data the dassification criteria are not met.
May cause skin sensitization or allergic reactions in sensitive individuals.
Based on available data the dassification criteria are not met.
Based on available data the dassification criteria are not met.
Based on available data the dassification criteria are not met.
Not listed.
Not listed.
Not listed.
Reproductive toxicity- fertility Based on available data the dassification criteria are not met.
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BELZONA® 1111 (SUPER METAL} SOLIDIFIER
Reproductive toxicitydevelopment
Based on available data the classification aiteria are not met.
Specific target organ toxicity - single exposure
STOT- single exposure Based on available data the classification aiteria are not met.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure Based on available data the classification aiteria are not met.
Aspiration hazard
Aspiration hazard Based on available data the classification aiteria are not met.
Route of entry Skin and/or eye contact Skin absorption
Medical considerations Skin contact constitutes a pronounced hazard. Persons with a history of skin sensitization problems should only be employed in processes in which this product is used under appropriate medical supervision.
Toxicological information on ingredients.
Toxicological effects
Acute toxicity - oral
Acute toxicity oral (LOt.. mg/kg)
Species
ATE oral (mg/kg)
Acute toxicity - dermal
Acute toxicity dermal (LD., mg/kg)
Species
ATE dermal (mglkg)
Acute toxicity - inhalation
Acute toxicity inhalation (LCso dust/mist mg/1)
Species
Notes (inhalation LC..)
ATE inhalation (dusts/mists mg/1)
Toxicological effects
Acute toxicity - oral
DIETHYLENETRIAMINE
May be absorbed through the skin. During standard, non-spray applications, the risk of exposure by inhalation to hazardous concentrations of diethylenetriamine under normal working conditions in a well ventilated area is minimal.
There is no data on the product itself. The following information is provided on the basis of the individual component data available.
Based on the individual component data, the product is expected to have experimental LC50/EC50/IC50 values between 1 and 1 0 mg/1 in most sensitive species.
Persistence and degradability Based on the individual component data, the product is not expected to be rapidly biodegradable according to OECD/EC guidelines.
Bioaccumulative potential
Bio-Accumulative Potential
Partition coefficient
Mobility in soil
Mobility
Based on the individual component data, the product is expected to bioaccumulate.
Not available.
There is no data available on the product itself.
ResuHs of PBT and vPvB assessment
ResuHs of PBT and vPvB assessment
other adverse effects
other adverse effects
I 13. Disposal considerations
Waste treatment methods
Disposal methods
Waste dass
Not applicable.
None known.
Do NOT dump into any sewers, on the ground, or into any body of water. Controlled wastes indude non-hazardous industrial and hazardous chemical wastes. Disposal must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations are the responsibility solely of the waste generator ... COMPONENT DISPOSAL TRANSIT PACKAGING: shrink or stretch wrap, boxes and fittings that have not been contaminated with product should be re-used or recyded. UNREACTED PRODUCT, uncleaned containers and contaminated packaging may qualify as hazardous chemical waste as defined in 40 CFR 261.20-24. REACTED PRODUCT, that has been mixed and cured in accordance with the relevant 'Instructions For Use' will form an inert filled polymeric compound that may be able to be disposed of as non-hazardous solid waste. Refer to your local licensed, permitted waste agent or facility .
. . Waste dass is not relevant. .
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BELZONA® 1111 (SUPER METAL} SOLIDIFIER
I 14. Transport Information
General Labeling and packaging requirements may vary with pack and load size. Please refer to the
current transport regulations. Transport within user's premises: always transport in closed
containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage.
UN Number
UN No. (TOG)
UN No. (IMDG)
UN No. (ICAO)
UN No. (DOT)
UN proper shipping name
3259
3259
3259
3259
Proper shipping name (TOG) Amines, solid, corrosive, n.o.s. (containing Diethylenetriamine and Formaldehyde oligomeric
copolymer mixture)
Proper shipping name (IMDG) Amines, solid, corrosive, n.o.s. (containing Diethylenetriamine and Formaldehyde oligomeric copolymer mixture)
Proper shipping name (ICAO) Amines, solid, corrosive, n.o.s. (containing Diethylenetriamine and Formaldehyde oligomeric
copolymer mixture)
Proper shipping name (DOT) Amines, solid, corrosive, n.o.s. (containing Diethylenetriamine and Formaldehyde oligomeric
copolymer mixture)
Transport hazard class(es)
DOT hazard class
TOG class
IMDGCiass
ICAO class/division
Packing group
8
8
8
8
TOG Packing Group Ill
IMDG packing group Ill
ICAO packing group Ill
DOT packing group Ill
Environmental hazards
Environmentally Hazardous Substance
Yes. Not a marine pollutant under US DOT.
Special precautions for user
Not applicable.
Transport in bulk according to Not carried in bulk.
Annex II of MARPOL 73f78 and the IBC Code
I 15. Regulatory Information
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International Regulations
US Federal Regulations
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BELZONA® 1111 (SUPER METAL} SOLIDIFIER
SARA 313 Emission Reporting SECTION 313: This product does not contain toxic dlemical subject to the reporting requirements of Section 313 of Title Ill of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372.
SARA (311/312) Hazard Categories Acute
US State Regulations
State Regulations Comments U.S California Safe Drinking Water & Toxic Enforcement Act (Proposition 65): To the best of our knowledge, this product does not contain any dlemicals known to the State of California to cause cancer or reproductive toxicity.
Inventories
Canada- DSUNDSL All the ingredients are listed or exempt.
US-TSCA All the ingredients are listed or exempt.
[ 16. Other information
General information
Key literature references and sources for data
Training advice
Revision comments
Revision date
Revision
SDS No.
SDS status
The information contained within this safety data sheet does not constitute the users own assessment of workplace risks as may be required by other Local Regulations. /ls the specific conditions of use of the product are outside the supplier's control, the user is responsible for ensuring that the requirements of relevant Local Regulations are complied with. To the best of our knowledge, the information contained herein is accurate. However, some of the information presented and condusions drawn are derived from sources other than direct test data on the product itself and while Belzona Inc. believes such sources to be reliable, the information is provided without any warranty regarding its correctness. Since Belzona Inc. has no control over the conditions under which the product will be used, liability will not be assumed to exceed replacement or refund of the purchase price of this product. Except as stated herein, there are no express or implied warranties including implied warranties of merchantability or fitness for a particular purpose. Belzona Inc. assumes no liability for injury or incidental or consequential damage arising out of the storage, handling, use or, disposal of this product.
For further information please contact your supplier, Belzona consultant or Belzona direct.
REVISION. This safety data sheet has been revised in the following Section(s): 1, 3, 4, 5, 7, 8, 9, 11, 13, 16, Please observe the REVISION DATE. Should you be reading a material safety data sheet that is more than 24 months old or have concerns over its validity, please contact your local Belzona Distributor or Belzona direct ([email protected]) and the most current information will be sent to you.
1112/2016
3.5
11266
English (North American). Approved.
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Hazard statements in full
Revision: 3.5
BELZONA® 1111 (SUPER METAL} SOLIDIFIER
H314 Causes severe skin bums and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage.
NFPA- health hazard Temporary incapacitation, injury. (2)
NFPA- flammability hazard Bums only if pre-heated. (1)
