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SAFC Hitech Insight Newsletter - March 2009

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2008 was an extremely successful year for SAFC Hitech with significant growthachieved despite the downturn in general economic conditions during the latter stages of the year. As well as increasing our revenues, we continued to invest inseveral areas: in expanding our manufacturing footprint in growth opportunity areas;in the development of new and innovative materials; and in the equipment with whichthese materials can be delivered to the process chamber most effectively.
12
SAFC Hitech and Air Water Inc. (AWI) have a long history working together to develop and provide performance chemicals to both the silicon and compound semiconductor markets in Japan. Molecular engineering of compounds to tailor physical properties is an involved process that relies heavily on source assessment under actual usage conditions. The correlation of performance results in a deposition process to novel chemistry highlighting beneficial changes is used to ensure continuous improvement in precursor performance. Obviously layer growth and characterisation capabilities must be to the highest standards and in the last 12 months long-term plans have been established to provide high quality research and development facilities to support the needs of the end user Integrated Device Manufacturer (IDM) and Original Equipment Manufacturer (OEM) in Japan. It is essential that a locally available fast and responsive reaction to their research needs is accessible as they develop new integrated circuits and the tools to build them for the rapidly expanding market for state-of-the-art electronic semiconductor devices. AWI’s central research facility is located at Matsumoto in the Nagano prefecture of Japan and a wide range of high purity gas and chemical related research is performed under the directorship of Hirohisa Hiramatsu. Within this facility there are laboratories and clean rooms where SAFC Hitech and AWI together investigate the performance of new chemicals required by the semiconductor industry. The inclusion of electrical measurement equipment along with deposition tools allows the researcher to establish I-V and C-V plots and thus establish the flow of current (or not) through the surface of the grown films and their substrates all in one centre of excellence. Such superb facilities have attracted a number of Japanese multinational IDMs and OEMs to send their research engineers to Matsumoto to work alongside our researchers on specific projects under strict non-disclosure agreements. Continued on page 5 Insight A regular update to the semiconductor industry March 2009 SAFC Hitech ® and AWI Strengthen Long Term Research Collaboration Page 2 2008 in Review Page 3 Customer Satisfaction Survey Results Page 4 Halide Mediated Improvement of Lateral Growth of InN in MOCVD Page 6 REACH Pre-registration Accomplished A Focus on Procurement in a Global Supply Chain Page 7 Tungsten Carbonitride Thin Films Page 8 Improved Processes and Materials for Energy Saving Glazing New Regulations for Certification of Containers Page 9 Crystal Grade Metal Halides Make Big Impact Geoff Irvine Expanded Role Page 10 Cadmium Oxide as an Alternative TCO Page 11 Conference Representation 2009 Page 12 Contact Details www.safchitech.com
Transcript

SAFC Hitech and Air Water Inc. (AWI) have a long history working together to develop and

provide performance chemicals to both the silicon and compound semiconductor markets in

Japan. Molecular engineering of compounds to tailor physical properties is an involved

process that relies heavily on source assessment under actual usage conditions. The

correlation of performance results in a deposition process to novel chemistry highlighting

beneficial changes is used to ensure continuous improvement in precursor performance.

Obviously layer growth and characterisation capabilities must be to the highest standards and

in the last 12 months long-term plans have been established

to provide high quality research and development facilities

to support the needs of the end user Integrated Device

Manufacturer (IDM) and Original Equipment Manufacturer

(OEM) in Japan. It is essential that a locally available fast

and responsive reaction to their research needs is

accessible as they develop new integrated circuits and the

tools to build them for the rapidly expanding market for

state-of-the-art electronic semiconductor devices.

AWI’s central research facility is located at Matsumoto in the Nagano prefecture of Japan and

a wide range of high purity gas and chemical related research is performed under the

directorship of Hirohisa Hiramatsu. Within this facility there are laboratories and clean rooms

where SAFC Hitech and AWI together investigate the performance of new chemicals required

by the semiconductor industry. The inclusion of electrical measurement equipment along with

deposition tools allows the researcher to establish I-V and

C-V plots and thus establish the flow of current (or not)

through the surface of the grown films and their substrates

all in one centre of excellence. Such superb facilities have

attracted a number of Japanese multinational IDMs and

OEMs to send their research engineers to Matsumoto to

work alongside our researchers on specific projects under

strict non-disclosure agreements.

Continued on page 5

InsightA regular update to the semiconductor industry

March 2009

SAFC Hitech® and AWIStrengthen Long TermResearch Collaboration

Page 22008 in Review

Page 3Customer SatisfactionSurvey Results

Page 4Halide MediatedImprovement of LateralGrowth of InN in MOCVD

Page 6REACH Pre-registrationAccomplished

A Focus onProcurement in aGlobal Supply Chain

Page 7Tungsten CarbonitrideThin Films

Page 8Improved Processesand Materials forEnergy Saving Glazing

New Regulations forCertification ofContainers

Page 9Crystal Grade MetalHalides Make BigImpact

Geoff Irvine ExpandedRole

Page 10Cadmium Oxide as anAlternative TCO

Page 11ConferenceRepresentation 2009

Page 12Contact Details

www.safchitech.com

2008 was an extremely successful year for SAFC Hitech with significant growth

achieved despite the downturn in general economic conditions during the latter

stages of the year. As well as increasing our revenues, we continued to invest in

several areas: in expanding our manufacturing footprint in growth opportunity areas;

in the development of new and innovative materials; and in the equipment with which

these materials can be delivered to the process chamber most effectively.

Page 2 SAFC Hitech News

2008 in Review - Barry Leese

During the year several effective campaigns have emphasised our ongoing commitment to leadership in the compound

semiconductor market, expanded our presence in the silicon semiconductor area and also entered into numerous

emerging markets for ‘performance’ or ‘specialist’ chemicals where we see substantial future business opportunities.

Investment in production facilities has seen the opening of our $9 million 5000ft² cleanroom at

Sheboygan, Wisconsin along with commissioning of additional plant capacity at

Bromborough, Haverhill and Taiwan. These expansions enable us to produce, package and

analyse products in multiple locations in higher volumes, completing the total supply chain to

ensure our customers an uninterrupted supply of the highest quality materials globally.

We hosted extremely successful media visits to both the Sheboygan and Bromborough

facilities in 2008. These visits not only gave us a chance to update our friends in the editorial

community about our ongoing investment program but also an opportunity to qualify these

investments in tangible terms by actually showing them around the expanded facilities.

Furthermore product developments were highlighted to demonstrate the advances made in

precursor technologies by our highly active Research team. In particular novel materials for

Germanium Antimony Telluride (GexSbyTez or GST) for use in high volume manufacturing phase change memory (PCM)

applications generated significant interest from several very large customers.

In October we announced the availability of our portfolio of Crystal Growth Halides representing the first launch from the

‘Performance Materials’ range of SAFC Hitech. This new element of product offerings focuses on applications outside

the “standard” Compound and Silicon areas to enhance our ability to service a wider

range of customers in the electronics and related industries. The rapidly-developing

solar market falls into this category with sol-gel, chemical bath deposition (CBD) and

other techniques as well as CVD requiring HVM of high quality chemicals. We are

already seeing major requirements for materials for CBD CIGS (copper indium

gallium selenide) and CdTe/CdSe (cadmium telluride/selenide) to complement the

existing range of CVD precursors. III-V and Si CVD sources complete the SAFC

Hitech ability to supply precursors to all the conventional competing technologies and

future investment in the organic electronics area will ensure full coverage of future

fabrication methods.

In addition to expanding our product range we have developed our equipment offering to enhance the delivery of

precursors to the deposition equipment. The introduction of the OM700, a bubbler that offers customers a cost-efficient

migration path to controlled precursor delivery for larger lot sizes, and the EpiVapor™, a cost-effective metalorganic

vapour phase distribution system that eliminates the need for localised tool bubblers and TCUs by delivering vapours

from highly volatile and sensitive pyrophoric liquids directly to MOCVD systems, has been very well received in the

market place. These enabling technologies afford a reduction in process downtime and increased safety controls.

Looking forward to 2009, we aim to maintain our highest standards of service to an expanding compound and silicon

semiconductor industry, to invest in locations and technologies that we feel will enhance our capabilities in emerging

areas such as photovoltaics, and to provide a stable supply chain to all of our customers.

Page 3

Customer Satisfaction Survey ResultsSAFC Hitech strives to achieve the highest standards of customer service and to assess performance in this area conductsan annual survey to allow customer perceptions to be evaluated. Feedback is highly valued and numerous improvementprojects have been implemented based on this customer input. The objective is always to maintain our highly valuedrelationship with product users and ensure all areas of the SAFC Hitech/customerinterface remain at the highest level.

SAFC Hitech would like to thank all of the respondees for their time andcomments which will be used to improve our performance. A prize drawwas held for all completed forms and this year’s winner of a state-of-the-art iPod is Tom Katona in USA.

Overall Rating

Positive

Negative

Detailed Results

Are orders dealt with and delivered as promised?

Are you satisfied with the level of service from the technical support team?

Are you satisfied with the level of servicefrom the customer service team?

Is product packaging and safetyinformation to standard?

The findings of the survey allow corrective actions to beestablished to counter negative experiences as well as

ensuring newly introduced protocols are successful. Positive feedbackdemonstrates that dealing with SAFC Hitech has met or surpassedcustomer expectations.

Overall this year the majority of responses were positive with an increasedratio compared to negative items indicating the already excellentperception of SAFC Hitech as a precursor supplier from previous yearshas been improved upon. Last year’s issue relating to the communicationof the change from Epichem to SAFC Hitech has been resolved and thenew brand has become widely recognised as a premier precursorsupplier across an increasingly wide range of application technologies.This expansion in remit for SAFC Hitech may explain the commentsreceived relating to a customer requirement for more products to meettheir needs. The SAFC Hitech research team is highly active to developnew materials to meet these demands. Due to the range of chemicalsinvolved and the volumes, their introduction to the full catalogue does taketime hence specific technical contact with customers is employed todisseminate new offer areas. Further efforts to exhibit the full range ofcapabilities to supply compounds specifically matched to customerprocesses in an ad-hoc manner suited to new material processdevelopment are planned for the coming months to address this lack ofcommunication. Again it should be stressed that those customers dealingwith the Technical team were highly appreciative of the support and thisservice is to be further highlighted for new customers to access anddiscuss alternative precursor strategies. In recent months the upgradedwebsite has improved the availability of technical data on standardproducts and continuous assessment is performed to maintain andupdate this database of precursor properties.

As in previous years customers who returned negative comments will becontacted directly by their account manager to discuss these concernsand determine a strategic plan to resolve any difficulties. A key target for2009 will be to maintain effective communications between all ourcustomer and SAFC Hitech contacts in Sales, Customer Services,Technical Services and beyond. Coupled with the planned improvementsto product offer communications we hope to demonstrate the extensiveoptions available to all customers to ensure purchase of the precursorsbest suited to their processes in the most efficient manner.

Are there specific products requiredto be introduced?

How do you rate the website?

In this work, we present our results regarding the progress in MOVPEgrowth of InN achieved in the INDOT project thanks to inputs from allpartners to optimise materials and processes (see inset for INDOTdetails or www.indot-project.net). First, we attempted to reproduce thesuccessful two-step growth method which is commonly used to formepitaxial GaN layers on a sapphire substrate, also with a large latticemismatch. In-depth analysis of the structure and morphology of a GaNnucleation layer in order to transpose this knowledge to theInN/GaN/sapphire system was performed. The detailed study of suchan annealed GaN buffer revealed the presence of a typical density of1011 per cm2 crystal grains, with a quality analysed by grazing X-raydiffraction that showed a full width at half maximum of 3600 arcsecondsfor the (10-10) diffraction peak. Such a test structure was producedusing the required low temperature MOVPE growth of InN on sapphire,however, it was not possible to obtain high crystal quality due to the lackof surface mobility and lateral growth, which limits the coalescence of InN during growth.

Due to the restriction of thermal energy that can be inputted to the InN system to avoid product evaporation duringgrowth, a novel chemical approach has been studied to enhance surface mobilities and allow high quality films to bedeposited. This technique involves modification of the gas phase chemistry to enhance lateral growth of InN by alteringthe surface species and increasing their ability to move on a surface even at the low temperatures dictated for InN. Indetail CBrCl3 was co-injected during growth to form volatile halides that have proven successful in enhancing the finaldeposited film quality significantly.

In Figure 1, we report the X-ray diffraction patterns obtained on differentInN layers grown under increasing CBrCl3/TMIn ratios. Interferencefringes, known as “Pendellosung fringes” are clearly observed as theinjected CBrCl3 amount increases. This is proof of a high in-planecoherence, due to a spectacular improvement of the layer morphologies.

Atomic force microscopy investigations were carried out to preciselyquantify the surface rms roughness, and the results clearly demonstratethat the lateral growth is immensely improved by the use of CBrCl3 toform halides (see images in Figure 2, showing a strong decrease of thesurface roughness, see z-scale). Another representation, demonstratingthat surface roughness is drastically reduced, is given in the graph inFigure 2 where we plotted the distribution of surface features mean heightsversus CBrCl3 content.

Combined with the use of low temperature buffer layer, this approach leads to a breakthrough in InN material quality.Roughness values are now such that device fabrication is possible and further work is ongoing to develop this excitingtechnology.

Recently, a lot of research efforts have been devoted to InN, the least known of the semiconducting

group-III nitrides. The growth using the Molecular Beam Epitaxy (MBE) technique has been more

investigated, while fewer studies used the Metal Organic Vapor Phase Epitaxy (MOVPE) method.

Whatever the approach, the growth of InN has proved extremely challenging; in particular due to the

fact that no lattice matched substrate is available.

Page 4 SAFC Hitech News

Halide Mediated Improvement of theLateral Growth of InN in MOCVD

MOCVD technology for production of

indium nitride based nanophotonic devices

Participant name Country

AIXTRON AG Germany

GES UMR5650 CNRS France

SAFC Hitech Limited UK

SAES Getters SpA Italy

Figure 1 XRD results using CBrCl3

Page 5

Related communications output from project:

Int. Workshop on Nitride Semiconductors (IWN2008), Montreux, Switzerland, October 2008

● Halide mediated improvement of the lateral growth of InN in MOCVDO. Briot, S. Ruffenach, M. Moret, B. Gil, Ch. Giesen, M. Heuken, S. Rushworth, T. Leese and M. Succi

● Growth and doping of InN films by MOVPEO. Briot, S. Ruffenach, M. Moret, B. Gil, Ch. Giesen, M. Heuken, S. Rushworth, T. Leese and M. Succi

2nd Int. Symposium on Growth of III-Nitride Semiconductors (ISGN2), Shuzenji, Japan, July 2008

● Growth of InN films and nanostructures by MOVPEO. Briot, S. Ruffenach, M. Moret, B. Gil, Ch. Giesen, M. Heuken, S. Rushworth, T. Leese and M. Succi

● MOVPE growth of InN buffer layers on sapphireO. Briot, S. Ruffenach, M. Moret, B. Gil, Ch. Giesen, M. Heuken, S. Rushworth, T. Leese and M. Succi

● Alternative precursors for MOVPE growth of InN and GaN at low temperatureS. Ruffenach, M. Moret, O. Briot, B. Gil, Ch. Giesen, M. Heuken, S. Rushworth, T. Leese and M. Succi

AWI Facility Details cont’d from page 1

Frequent meetings and conference calls between the research group in Matsumoto and the research groups in the USA

and the UK allow for recently achieved data to be discussed internally, commented upon and then made available to our

customer base on an individual and confidential basis.

Three ALD Reactors situated in a Class 1000 clean room are available to deposit thin films, layer by layer in a controlled

sequence cycle using specially designed and fit for purpose chemical precursors. Close by is situated a Rapid Thermal

Annealer (RTA) to stabilise the crystal structure of the thin film formed. Further microscopy equipment including a Scanning

Electron Microscope (SEM) and Transmission Electron Microscope (TEM) is used to examine the surface of the film in

extremely fine detail. Ellipsometry techniques are also available in-house to measure film thicknesses very accurately and

an X-ray Diffractometer (XRD) is used to measure not only chemical composition of the film but also its crystallographic

structure. Included in the characterisation tools available is also an Inductively Coupled Plasma Optical Emission

Spectrometer (ICP-OES) which measures extremely accurately the qualitative and quantitative components of the material

composition of the films deposited.

Ti SourceAssessment

Number of ALD cycles

Thic

knes

s (Å

)

350

300

250

200

150

100

50

00 100 200 300 400 500

Figure 2 Surface roughness data using CBrCl3

Page 6 SAFC Hitech News

REACH Pre-registrationSuccessfully AccomplishedSigma-Aldrich is proud to announce that the first hurdle of the REACH legislation

process has been successfully completed by the pre-registering of several hundred

chemical substances.

On December 1st, 2008 at 24:00 GMT the official REACH pre-registration period ended. During the 6-month period prior

to this date importers and manufacturers of chemicals or formulations in quantities >1000kg per year in the EU had the

opportunity to pre-register their substances at the European Chemicals Agency (ECHA) to benefit from longer transition

periods for final registration. According to the latest info from the ECHA more than 47,000 companies have made more

than 2.2 million (!) pre-registrations for around 54,000 different substances - much higher than expected.

Sigma-Aldrich pre-registered over 1000 entries for 10 different legal entities in Europe. This was only the first little step of

a long ongoing and challenging process of REACH implementation, however, Sigma-Aldrich is committed to complying

with the highest safety standards to assure customer confidence and provide comprehensive information for chemical

handling and usage.

Information for customers about REACH can be found on our website:

http://www.sigmaaldrich.com/customer-service/reach.html

Sigma-Aldrich collectively purchases about one billion dollars per year of materials and services and a key factor is

ensuring the full value of the Company’s buying leverage to obtain the best quality items for the best price. Just as our

customers wish to obtain the best deal for our products we must review our own supply chain. This involves both

“direct” spend, the materials utilised in manufacturing end products sold to customers, as well as “indirect” spend - all

other goods and services needed to do business. Historically we have performed well in this area but there is always

room for improvement.

A global review is currently ongoing to ensure the most efficient

protocols are in place and the resulting benefits will be better

connectivity with suppliers and an enhanced supply chain which can

provide higher quality, time to delivery and value for money. IT solutions

will reduce paper usage in line with the corporate Green policy as well as

speeding cycle time, provide facile tracking of the status of the

requisition and purchase orders electronically including follow up with

vendors directly. These outcomes will in turn lead to reduced cost and

optimum value that can be passed on to our customers to maintain the

high quality of service they require and demand.

A Focus on Procurement in a Global Supply Chain

Sigma-Aldrich® Global Supply ChainCommon Processes - Seamless Integration - Outstanding Service

Page 7

Tungsten Carbonitride Thin FilmsA long-standing collaboration between University College London (UK) and SAFC Hitech has seen recent advances in the

field of coatings on glass. The principles behind these advances can be applied to a wide range of material systems and

have applications in a number of electronic devices to increase speed and reduce feature size.

Claire Carmalt's group at University College London, in collaboration with the SAFC Hitech

research team in Bromborough, used chemical vapour deposition (CVD) to produce thin films

of tungsten carbonitride (WNxCy) from new precursors. WNxCy can be used as an effective

barrier layer to prevent Cu migration from circuit wires into semiconducting components and

the application of CVD to apply coherent films over reduced areas significantly helps scaling

efficiencies.

The precursors investigated included a range of tungsten imido complexes to produce

compounds with ideal thermal properties for CVD. Careful tuning of the ligands surrounding

the tungsten centre was performed to optimise these thermal properties to enhance the

fabrication of tungsten carbonitride thin films in the parameter space necessary for devices. The decomposition

mechanism studies and explanation of observed thermal events for each precursor was key in determining storage stability,

transport properties and deposition temperature capabilities. A structured approach was followed to identify the highest

potential molecules in the shortest timeframe and then to demonstrate their effective use in CVD.

In practice four closely related precursors were established for growth trials and all yielded

WNxCy thin films on glass using Low pressure CVD at 550°C. The actual molecules were:

[W(µ-NtBu)(NtBu)Cl2(H2NtBu)]2, [W(NtBu)2Cl2(TMEDA)] (TMEDA = N,N,N',N'-

tetramethylethylenediamine), [W(NtBu)2Cl2(py)2] (py = pyridine) and

[W(NtBu)2Cl(N{SiMe3}2)]. Grey mirror-like films were grown with a nitrogen or ammonia

bleed gas and in all cases the chlorine content of the deposited films was less than 1 at%.

Oxygen levels were decreased using ammonia and, surprisingly, this did not significantly

change the carbon content of the resulting films. The films were uniform, adhesive, abrasion

resistant, conformal and hard, being resistant to scratching with a steel scalpel. X-ray powder

diffraction patterns of all the films showed the formation of ß-WNxCy.

As a comparison the team also investigated aerosol-assisted chemical vapour deposition

(AA)CVD using one of the precursors [W(µ-NtBu)(NtBu)Cl2(H2NtBu)]2 and found the resulting layers to be amorphous

tungsten carbonitride films. Further studies are ongoing to understand the differences seen between precursors and

deposition techniques.

Full results have been published (http://www.rsc.org/Publishing/Journals/DT/article.asp?doi=b808650h)

For further information contact Claire Carmalt at [email protected]

Chemical vapour depositionproduces hard thin films of

tungsten carbonitride

pyCl

Cl

tBuN

tBuNpy

py = pyridine

W

Improved Processes and Materialsfor Energy Saving Glazing

Page 8 SAFC Hitech News

New Regulations for Certification of ContainersThe build of SAFC Hitech bubblers, ampoules and cylinders is to the highest of standards

and certification of these containers must follow legislative regulations due to their

classification as pressure vessels. This pressure rating demonstrates that the vessel is

safe and the methods employed also ensure DOT certification is met in

all cases. It is clearly important that the transport of hazardous

chemicals is performed in the safest manner possible and that the strict

road, sea and air regulations are adhered to. DOT certified containers

are guaranteed to meet all specifications and are also a legal

requirement for safe, trouble-free shipping of products both nationally

and internationally.

Each vessel is individually tested using robust protocols when it is fabricated and first

placed into service. With the increasing requirement to re-use containers and extend

their lifetime, the situation regarding retest of the bubblers has risen to a higher profile

and recent new regulations relating to the pressure testing of ampoules have

introduced a validity of 5 years for the certification.

SAFC Hitech must therefore fully re-test every container by the 5th anniversary of its construction to maintain its pressure

rating. The identification of bubblers globally that are at risk of having the pressure certificate expire is currently

underway and customers will be notified of their containers’ status if the time limit

is pressing. SAFC Hitech will offer a pressure re-test and certification service

to ensure customer owned ampoules remain in a transportable state

and issues of shipment blockage due to legislative and safety

concerns are avoided.

For further information of the impact of the impending new protocols

please contact your local SAFC Hitech representative.

To further expand the areas under investigation at SAFC Hitech, a study into coatings on glass was

proposed. A partnership with Liverpool University and Pilkington was developed to focus the

research direction and due to the highly relevant nature of this work funding support from the UK

government has been granted. In detail a successful application was made to the Technology

Steering Board (TSB) competition relating to Low Impact Building Innovation Platform and a three-year project

(PROMISE) will run to develop new technologies to enhance glazing performance.

Low emissivity glass is playing an increasing role in improving building energy efficiency with a key feature a thin coating

with appropriate refractive index to capture solar energy and reduce heat loss. Alternative precursors and deposition

technologies will be developed to enable next generation products to be brought to market for low impact buildings.

Partners: SAFC Hitech, Liverpool University, PilkingtonRoles: Precursor selection, Process demonstration, Process scale up

Page 9

Crystal Grade Metal Halides Make Big ImpactSAFC Hitech proudly introduced its first line of products targeted for the radiation

detection market, Crystal Grade Metal Halides, at the IEEE Nuclear Science

Symposia-Medical Imaging Conference (NSS-MIC) that was held in Dresden,

Germany Q4 2008. These products mark a new direction for SAFC Hitech as we

continue to integrate our capabilities and resources and craft offers to new

segments of the electronics market.

The launch at the show was highly successful from the perspectives of sales

performance and branding with many customers visiting our booth for information

on the new product range.

The crystal grade metal halides find applications as scintillation detectors in medical imaging, security detection and

astrophysical equipment. Our high purity products, manufactured at the AAPL facility in Urbana Il in the US, include iodide

salts of sodium, cesium and thallium with new halide salts of lanthanum, strontium and europium under development.

To further support our customers’ efforts, we offer key services that ease

processing, reduce waste disposal complexities and improve overall cost of

ownership. First SAFC Hitech can provide blended halides for doped crystal

growth with high accuracy and control to reduce handling necessities on site.

Secondly we will accept return of unused or scrap Na, Cs or Tl materials for

reprocessing to minimise hazardous waste disposal procedures and cost for the

customer.

In this exciting new area, new and existing SAFC Hitech customers have

approached us for material supply and invitations to participate in joint

development projects. For example, the new scintillator SrI2:Eu has gained significant interest due to its improved

properties. In 2009 our goal is to continue to deliver an exemplary service to our customers. Furthermore, we aim to

reinforce our manufacturing capabilities at Urbana through capital investment and to expand on our current offers to meet

future market demands.

Geoff Irvine Expanded RoleWe are pleased to announce the promotion of Geoff Irvine to VP Business Development for SAFC

Hitech. In his new role he will have responsibility for new business development through organic

growth and acquisition, and marketing for Hitech as well as responsibility for AAPL, the Aldrich-APL

Joint Venture, where he serves as President.

Geoff joined Sigma-Aldrich Corporation in 2001 with responsibility for identifying and capitalising

on marketing opportunities to grow the organometallics product line revenue. Geoff’s

responsibilities quickly broadened to include new product development and overall product line

strategy. In early 2003, Geoff moved to the SAFC business unit segment that would subsequently

become SAFC Hitech and indeed was instrumental in the acquisition of the Epichem Group in

2007 and the subsequent integration with the traditional Hitech business to make a powerful force

in the electronics industry.

Cadmium Oxide as an Alternative TCOTransparent conducting oxides (TCOs) have found use in a broad array of applications including photovoltaic (PV) cells,

flat panel displays, and light emitting diodes. The dominant material system currently is indium tin oxide (ITO), however,

alternatives are being sought due to the price and availability of In. Face-centred cubic cadmium oxide has a relatively

low intrinsic band gap of 2.28 eV, while its low effective carrier mass allows for heavily doped samples which can have

band gaps as high as 3.35 eV. Sn-doped CdO has been shown to allow access to mobilities of 607 cm2 V-1 s-1 [1]

making it suitable for a large number of TCO applications.

CVD is particularly attractive for TCO synthesis because of its use in conformal, large volume, thin film manufacturing

processes. A key prerequisite for CVD is a volatile precursor and at present only a limited number of examples are

available. Historically, CdO films have been grown via CVD using the combination of dimethylcadmium as a precursor

and butanol as an oxygen source [2]. This dual-source approach leads, naturally, to speculation as to the likelihood of

organocadmium alkoxides as intermediates in this process, and thus such species would be potential single-source

precursors (SSP) in their own right. Indeed, work on the analogous ZnO process identified MeZn(OiPr) as just such an

SSP. [3]

The focus of interest at Bath has been to exploit donor-functionalised alkoxides and so exploration of a series of

reactions between Me2Cd and the requisite alcohol have been performed, and the resulting materials assessed for use

as CVD precursors. In detail the compounds studied involved the ligands in Figure 1.

Page 10 SAFC Hitech News

Me2N

OH

Me2N

OH

NMe2 Me2N

OH

NMe2

NMe2

I: Hdmae II: Hbdmap III: HtdmapFigure 1 Functionalised alcohols employed to react with Me2Cd to form MeCd(L) compounds

Characterisation of each of the resulting compounds (MeCd(L)) highlighted

the dimeric nature of the highest potential CVD source, [MeCd(tdmap)]2,

(see Figure 2) and this material was studied in a simple hot wall low pressure

chemical vapour deposition (LPCVD) reactor which has been described in

detail elsewhere.[4] Films were deposited on 76 × 26 × 1.0 mm microscope

slides. A 0.15 g quantity of [MeCd(tdmap)]2 was heated to 140 °C in a tube

furnace under a vacuum of about 0.1 mmHg; the glass substrate was also

heated to 140 °C and the run time was 30 min.

Figure 2 Crystal structure of[MeCd(tdmap)]2 highlightingCdOCdO central ring

Page 11

Thermal treatment of the source showed some decomposition at

T>100 °C with complete decomposition by 300 °C leaving a mass

corresponding to CdO and indeed in the LPCVD trials at 140 °C smooth,

pale yellow films of approximately 300 nm thickness were formed, which

energy-dispersive X-ray spectroscopy (EDXS) clearly showed contained

cadmium and oxygen (Figure 3). The XRD of these films (Figure 4)

shows crystallinity despite the low deposition temperature and the peaks

can be indexed to cubic CdO highlighting the nature of the film as that

targeted. Interestingly, no carbon was observed in the final film which

suggests a clean decomposition pathway that is accentuated under

vacuum conditions. No ancillary oxygen source was used, making this

the first true example of CdO deposition from an SSP.

Further work has also been performed using the ZnO analogues and

also CVD trials on mixed ZnO/CdO systems undertaken. Full details of

the results are published [5] and highlight the great promise of these new

precursor families for low temperature TCO deposition.

References

[1] Yan, M. L. M.; Kannewurf, C. R.; Chang, R. P. H. Appl. Phys. Lett. 2001, 78, 234[2] Irvine, S. J. C.; Ellis, D. M. J. Mater. Sci. 2004, 15, 369[3] Auld, J., Houlton, D. J., Jones, A.C., Rushworth, S.A., Malik, M. A., O'Brien, P.,

Critchlow, G.W., J. Mater. Chem., 1994, 4(8), 1249-1253[4] Horley, G. A.; Mahon, M. F.; Molloy, K. C.; Haycock, P. W.; Myers, C. P., Inorg.

Chem. 2002, 41, 5052–5058.[5] Johnson, A. L., Hollingsworth, N., Kociok-Kohn, G., Molloy, K. C., Inorg. Chem.

2008, 47, 9706-9715

Conference Representation for 2009SAFC Hitech personnel will again be at all the key semiconductor conferences and

workshops around the world to network with customers and the scientific community. We

are dedicated to providing state-of-the-art chemicals and services across a wide spectrum

of application areas and deposition technologies to offer a competitive advantage for the

end user.

To convey the full range of our products, both standard and

developmental, our expert representatives will be pleased

to meet you at one of a multitude of forthcoming events, so

please look out for our booth and come along for a chat

about sales enquiries, technical support or just the weather

back home.

Details of events that SAFC Hitech will be attending during the year are detailed on our

website www.safchitech.com and it is updated regularly to be sure the latest information is

available to our customers

Figure 4 XRD of the as deposited film. Thefilm is indexed to cubic cadmiumoxide (PDF 75-1529)

Figure 3 EDXS of LPCVD film highlighting Cd and Ocontent (C, Au peaks are due to the samplepreparation, Si results from the exposedglass substrate)

The work reported was performed by postgraduate student Nathan Hollingsworth

with the support of SAFC Hitech in the group of Dr A Johnson and Prof KC Molloy.

LHV

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