MasterBlend • 5285 Fox Street • CO 80216 Denver • United States • Telephone: 303.373.0702 • Telefax 303.373.4968 • e-mail: [email protected] • Website: masterblend.net
Annex - Hazard class and category - Hazard statement code(s)
For full text of H-phrases: see SECTION 16.
SECTION 1: Identification
1.1 Product identifierTrade name Absorbent PowderOther means of identificationProduct code(s): 1862 Formula code: 04-981120
1.2 Relevant identified usesRelevant identified uses General use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency telephone numberChem-Tel 1.800.255.3924 (USA & Canada) 1.813.248.0585 (International)
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixtureClassification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
A.3 serious eye damage/eye irritation Cat. 2B (Eye Irrit. 2B) H320A.8R specific target organ toxicity - single expos-
ure (respiratory tract irritation)Cat. 3 (STOT SE 3) H335
Remarks
Hazards not otherwise classifiedMay be harmful if swallowed (GHS category 5: acutely toxic - oral).Harmful to aquatic life (GHS category 3: aquatic toxicity - acute).
2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word WARNINGPictogramsGHS07
Hazard statementsH320 Causes eye irritation.H335 May cause respiratory irritation.
Precautionary statementsPrecautionary statements - preventionAvoid breathing dust/fume/gas/mist/vapors/spray.Wash thoroughly after handling.
Precautionary statements - response
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There is no additional information.
not relevant (mixture)
For full text of abbreviations: see SECTION 16.
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms per-sist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give any-thing by mouth.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case ofrespiratory tract irritation, consult a physician. Provide fresh air.
Brush off loose particles from skin. - Rinse skin with water/shower.
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh waterfor at least 10 minutes, holding the eyelids apart.
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Call a POISON CENTER/doctor if you feel unwell.
Precautionary statements - storageStore in a well-ventilated place. Keep container tightly closed.
Hazardous ingredients for labelling Zeolite2.3 Other hazards
SECTION 3: Composition/information on ingredients
3.1 Substances
3.2 Mixtures3.2.1
Name of substance Identifier Wt%
Zeolite CAS No12173-10-3
50 - < 75
Calcium carbonate CAS No1317-65-3
25 - < 50
Sodium polyacrylate CAS No9003-04-7
1 - < 5
SECTION 4: First-aid measures
4.1 Description of firs- aid measuresGeneral notes
Following inhalation
Following skin contact
Following eye contact
Following ingestion
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Symptoms and effects are not known to date.
none
water, foam, alcohol resistant foam, ABC-powder
water jet
Deposited combustible dust has considerable explosion potential.
nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround-ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting waterseparately. Fight fire with normal precautions from a reasonable distance.
Remove persons to safety.
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose it.
Covering of drains. - Take up mechanically.
Take up mechanically.
Place in appropriate containers for disposal. Ventilate affected area.
Hazardous combustion products: see section 5. Personal precautions: see section 8. Incompatible materials:see section 10. Disposal considerations: see section 13.
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed
SECTION 5: Fire-fighting measures
5.1 Extinguishing mediaSuitable extinguishing media
Unsuitable extinguishing media
5.2 Special hazards arising from the substance or mixture
Hazardous combustion products
5.3 Advice for firefighters
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel
For emergency responders
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning upAdvices on how to contain a spill
Advices on how to clean up a spill
Other information relating to spills and releases
6.4 Reference to other sections
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Use local and general ventilation. Take precautionary measures against static discharge. Use only in well-ventilated areas. Ground/bond container and receiving equipment.
Dust deposits may accumulate on all deposition surfaces in a technical room. The product in the delivered formis not dust explosion capable; the enrichment of fine dust however leads to the danger of dust explosion.
Wash hands after use. Do not to eat, drink and smoke in work areas. Remove contaminated clothing and pro-tective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Neverplace chemicals in containers that are normally used for food or drink. Keep away from food, drink and animalfeedingstuffs.
Removal of dust deposits.
Observe compatible storage of chemicals.
Use local and general ventilation.
See section 16 for a general overview.
SECTION 7: Handling and storage
7.1 Precautions for safe handlingRecommendationsMeasures to prevent fire as well as aerosol and dust generation
Warning
Advice on general occupational hygiene
7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risks• Explosive atmospheres
Incompatible substances or mixtures
Consideration of other adviceVentilation requirements
7.3 Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)
Coun-try
Name of agent CAS No Identifier TWA[ppm]
TWA[mg/m³]
STEL[ppm]
STEL[mg/m³]
Source
US limestone (calcium carbon-ate)
1317-65-3 PEL 15 29 CFROSHA
US limestone (calcium carbon-ate)
1317-65-3 PEL 5 29 CFROSHA
notationSTEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period
unless otherwise specified.TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-
weighted average.
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No data available.
General ventilation.
Wear eye/face protection.
Wear protective gloves.
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom-mended. Wash hands thoroughly after handling.
Particulate filter device (EN 143).
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and groundwater.
Relevant DNELs/DMELs/PNECs and other threshold levels
8.2 Exposure controlsAppropriate engineering controls
Individual protection measures (personal protective equipment)Eye/face protection
Skin protection• hand protection
• other protection measures
Respiratory protection
Environmental exposure controls
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical propertiesAppearancePhysical state solidColor differentOdor freshOther physical and chemical parameterspH (value)Melting point/freezing point not determinedInitial boiling point and boiling range not determinedFlash point not applicableEvaporation rate not determinedFlammability (solid, gas)Explosion limits of dust clouds not determinedVapor pressure not determinedDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature not determinedViscosity not relevant (solid matter)Explosive properties noneOxidizing properties none
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Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".
See below "Conditions to avoid".
No known hazardous reactions.
There are no specific conditions known which have to be avoided.
The product in the delivered form is not dust explosion capable; the enrichment of fine dust however leads tothe danger of dust explosion.
strong shocks
There is no additional information.
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill andheating are not known. Hazardous combustion products: see section 5.
Test data are not available for the complete mixture.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Shall not be classified as acutely toxic.
Shall not be classified as corrosive/irritant to skin.
Causes eye irritation.
Shall not be classified as a respiratory or skin sensitizer.
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.
May cause respiratory irritation.
SECTION 10: Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
Hints to prevent fire or explosion
Physical stresses which might result in a hazardous situation and have to be avoided
10.5 Incompatible materials
10.6 Hazardous decomposition products
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Classification procedure
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Acute toxicity
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Summary of evaluation of the CMR properties
Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listedSpecific target organ toxicity (STOT)Specific target organ toxicity - single exposure
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Shall not be classified as a specific target organ toxicant (repeated exposure).
Shall not be classified as presenting an aspiration hazard.
Harmful to aquatic life.
The relevant substances of the mixture are readily biodegradable.
Data are not available.
Data are not available.
Data are not available.
Data are not available.
Data are not available.
Specific target organ toxicity - repeated exposure
Aspiration hazard
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity (acute)Aquatic toxicity (acute) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
Zeolite 12173-10-3 ErC50 130 mg/l algae 72 hours
Zeolite 12173-10-3 EC50 44 mg/l algae 72 hours
Aquatic toxicity (chronic)Aquatic toxicity (chronic) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
Zeolite 12173-10-3 EC50 680 mg/l aquatic inverteb-rates
21 d
Biodegradation
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
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Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the sub-stance itself.
Please consider the relevant national or regional provisions. Waste shall be separated into the categories thatcan be handled separately by the local or national waste management facilities.
There is no additional information.
The cargo is not intended to be carried in bulk.
Hazardous Materials Identification System (American Coatings Association)
SECTION 13: Disposal considerations
13.1 Waste treatment methodsSewage disposal-relevant information
Waste treatment of containers/packages
Remarks
SECTION 14: Transport information
14.1 UN number (not subject to transport regulations)14.2 UN proper shipping name not relevant14.3 Transport hazard class(es)
Class -
14.4 Packing group not relevant14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerous
goods regulations)
14.6 Special precautions for user
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in questionNational regulations (United States)
Industry or sector specific available guidance(s)NPCA-HMIS® III
Category Rating Description
Chronic / None.
Health 2 Temporary or minor injury may occur.
Flammability 1 Material that must be preheated before ignition can occur.
Physical hazard 0 Material that is normally stable, even under fire conditions, and will not react with water,polymerize, decompose, condense, or self-react. Non-explosive.
Personal protectiveequipment
-
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National Fire Protection Association: Standard System for the Identification of the Hazards of Materials forEmergency Response (United States)
NFPA® 704
Category Degree ofhazard
Description
Flammability 1 Material that must be preheated before ignition can occur.
Health 2 Material that, under emergency conditions, can cause temporary incapacitation or residualinjury.
Instability 0 Material that is normally stable, even under fire conditions.
Special hazard
Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryserious eye damage/eye irritation 2 (Eye Irrit. 2)specific target organ toxicity - single exposure (respir-atory tract irritation)
3 (STOT SE 3)
SECTION 16: Other information, including date of preparation or last revision
Abbreviations and acronymsAbbr. Descriptions of used abbreviations
29 CFR OSHA 29 CFR §1910.1001 - Occupational Safety and Health Standards: Toxic and Hazardous Substances (permissible ex-posure limits)
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
DMEL Derived Minimal Effect Level
DNEL Derived No-Effect Level
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
HMIS Hazardous Materials Identification System
IARC Mono-graphs
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)
NFPA® 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emer-gency Response (United States)
NPCA-HMIS®III
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition
OSHA Occupational Safety and Health Administration (United States)
PBT Persistent, Bioaccumulative and Toxic
PEL permissible exposure limit
PNEC Predicted No-Effect Concentration
ppm parts per million
STEL short-term exposure limit
TWA time-weighted average
vPvB very Persistent and very Bioaccumulative
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Physical and chemical properties: The classification is based on tested mixture.Health hazards/Environmental hazards: The method for classification of the mixture is based on ingredients ofthe mixture (additivity formula).
This information is based upon the present state of our knowledge. This SDS has been compiled and is solelyintended for this product.
Key literature references and sources for data- OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200- 49 CFR § 172.101 Hazardous Materials Table (DOT)
Classification procedure
List of relevant phrases (code and full text as stated in chapter 2 and 3)Code Text
H320 causes eye irritation
H335 may cause respiratory irritation
Disclaimer
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MasterBlend • 5285 Fox Street • CO 80216 Denver • United States • Telephone: 303.373.0702 • Telefax 303.373.4968 • e-mail: [email protected] • Website: masterblend.net
Annex - Hazard class and category - Hazard statement code(s)
For full text of H-phrases: see SECTION 16.
SECTION 1: Identification
1.1 Product identifierTrade name MasterGelOther means of identificationProduct code(s): 1822 Formula code: 06-150929
1.2 Relevant identified usesRelevant identified uses General use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency telephone numberChem-Tel 1.800.255.3924 (USA & Canada) 1.813.248.0585 (International)
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixtureClassification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
A.2 skin corrosion/irritation Cat. 2 (Skin Irrit. 2) H315A.3 serious eye damage/eye irritation Cat. 1 (Eye Dam. 1) H318Remarks
Hazards not otherwise classifiedMay be harmful if swallowed (GHS category 5: acutely toxic - oral).
2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word DANGERPictogramsGHS05
Hazard statementsH315 Causes skin irritation.H318 Causes serious eye damage.
Precautionary statementsPrecautionary statements - preventionWash thoroughly after handling.Wear protective gloves/eye protection/face protection.
Precautionary statements - responseIF ON SKIN: Wash with plenty of water.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Immediately call a POISON CENTER/doctor.Specific treatment (see on this label).Take off contaminated clothing and wash it before reuse.
Hazardous ingredients for labelling anionic surfactant
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Special danger of slipping by leaking/spilling product.
not relevant (mixture)
For full text of abbreviations: see SECTION 16.
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms per-sist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give any-thing by mouth.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case ofrespiratory tract irritation, consult a physician. Provide fresh air.
Wash with plenty of soap and water.
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh waterfor at least 10 minutes, holding the eyelids apart.
2.3 Other hazards
SECTION 3: Composition/information on ingredients
3.1 Substances
3.2 Mixtures3.2.1
Name of substance Identifier Wt%
Deionized Water CAS No7732-18-5
25 - < 50
Aqueous detergent CAS NoTrade Secret
15 - < 25
Soy methyl ester CAS No68919-53-9
15 - < 25
Synthetic hydrocarbon CAS NoTrade Secret
15 - < 25
Anionic surfactant CAS NoTrade Secret
1 - < 5
D-Limonene CAS No94266-47-4
1 - < 5
Sodium (C14-16) olefin sulfonate CAS No68439-57-6
1 - < 5
SECTION 4: First-aid measures
4.1 Description of firs- aid measuresGeneral notes
Following inhalation
Following skin contact
Following eye contact
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Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
Symptoms and effects are not known to date.
none
water spray, alcohol resistant foam, BC-powder, carbon dioxide (CO2)
water jet
nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround-ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting waterseparately. Fight fire with normal precautions from a reasonable distance.
Remove persons to safety.
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose it.
Covering of drains.
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand,universal binder).
Use of adsorbent materials.
Place in appropriate containers for disposal. Ventilate affected area.
Hazardous combustion products: see section 5. Personal precautions: see section 8. Incompatible materials:see section 10. Disposal considerations: see section 13.
Following ingestion
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed
SECTION 5: Fire-fighting measures
5.1 Extinguishing mediaSuitable extinguishing media
Unsuitable extinguishing media
5.2 Special hazards arising from the substance or mixtureHazardous combustion products
5.3 Advice for firefighters
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel
For emergency responders
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning upAdvices on how to contain a spill
Advices on how to clean up a spill
Appropriate containment techniques
Other information relating to spills and releases
6.4 Reference to other sections
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Use local and general ventilation. Use only in well-ventilated areas.
Wash hands after use. Do not to eat, drink and smoke in work areas. Remove contaminated clothing and pro-tective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Neverplace chemicals in containers that are normally used for food or drink. Keep away from food, drink and animalfeedingstuffs.
Observe compatible storage of chemicals.
frost
Only packagings which are approved (e.g. acc. to DOT) may be used.
See section 16 for a general overview.
No data available.
General ventilation.
Wear eye/face protection.
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Checkleak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them beforetaking off and air them well. For special purposes, it is recommended to check the resistance to chemicals ofthe protective gloves mentioned above together with the supplier of these gloves.
SECTION 7: Handling and storage
7.1 Precautions for safe handlingRecommendationsMeasures to prevent fire as well as aerosol and dust generation
Advice on general occupational hygiene
7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risksIncompatible substances or mixtures
Control of the effectsProtect against external exposure, such as
Consideration of other advicePackaging compatibilities
7.3 Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)Relevant DNELs/DMELs/PNECs and other threshold levels
8.2 Exposure controlsAppropriate engineering controls
Individual protection measures (personal protective equipment)Eye/face protection
Skin protection• hand protection
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Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom-mended. Wash hands thoroughly after handling.
In case of inadequate ventilation wear respiratory protection.
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and groundwater.
• other protection measures
Respiratory protection
Environmental exposure controls
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquid (gel)Color differentOdor characteristicOther physical and chemical parameterspH (value) not determinedMelting point/freezing point not determinedInitial boiling point and boiling range 176 °CFlash point >43 °CEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits• lower explosion limit (LEL) 0.7 vol%• upper explosion limit (UEL) 6.1 vol%Vapor pressure <2 mmHg at 20 °CDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature 237 °CViscosity not determinedExplosive properties noneOxidizing properties none
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Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".
See below "Conditions to avoid".
No known hazardous reactions.
There are no specific conditions known which have to be avoided.
strong shocks
There is no additional information.
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill andheating are not known. Hazardous combustion products: see section 5.
Test data are not available for the complete mixture.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Shall not be classified as acutely toxic.
Causes skin irritation.
Causes serious eye damage.
Shall not be classified as a respiratory or skin sensitizer.
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.
SECTION 10: Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
Physical stresses which might result in a hazardous situation and have to be avoided
10.5 Incompatible materials
10.6 Hazardous decomposition products
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Classification procedure
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Acute toxicity
Acute toxicity of components of the mixtureName of substance CAS No Exposure route ATE
aqueous detergent Trade Secret oral 500
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Summary of evaluation of the CMR properties
Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listed
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Shall not be classified as a specific target organ toxicant.
Shall not be classified as presenting an aspiration hazard.
Shall not be classified as hazardous to the aquatic environment.
The relevant substances of the mixture are readily biodegradable.
Data are not available.
Data are not available.
Specific target organ toxicity (STOT)
Aspiration hazard
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity (acute)Aquatic toxicity (acute) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
sodium (C14-16) olefinsulfonate
68439-57-6 LC50 4.2 mg/l fish 96 hours
sodium (C14-16) olefinsulfonate
68439-57-6 EC50 4.53 mg/l aquatic inverteb-rates
48 hours
sodium (C14-16) olefinsulfonate
68439-57-6 ErC50 5.2 mg/l algae 72 hours
Aquatic toxicity (chronic)Aquatic toxicity (chronic) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
sodium (C14-16) olefinsulfonate
68439-57-6 EC50 230 mg/l microorganisms 3 h
Biodegradation
12.2 Persistence and degradability
Degradability of components of the mixtureName of substance CAS No Process Degradation rate Time
sodium (C14-16) olefinsulfonate
68439-57-6 carbon dioxide genera-tion
80 % 28 d
sodium (C14-16) olefinsulfonate
68439-57-6 DOC removal 96 % 28 d
12.3 Bioaccumulative potential
Bioaccumulative potential of components of the mixtureName of substance CAS No BCF Log KOW BOD5/COD
sodium (C14-16) olefinsulfonate
68439-57-6 70.8 -1.3
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Data are not available.
Data are not available.
Data are not available.
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the sub-stance itself.
Please consider the relevant national or regional provisions. Waste shall be separated into the categories thatcan be handled separately by the local or national waste management facilities.
There is no additional information.
The cargo is not intended to be carried in bulk.
Hazardous Materials Identification System (American Coatings Association)
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
SECTION 13: Disposal considerations
13.1 Waste treatment methodsSewage disposal-relevant information
Waste treatment of containers/packages
Remarks
SECTION 14: Transport information
14.1 UN number14.2 UN proper shipping name not relevant14.3 Transport hazard class(es)
Class -
14.4 Packing group not relevant14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerous
goods regulations)
14.6 Special precautions for user
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in questionNational regulations (United States)
Industry or sector specific available guidance(s)NPCA-HMIS® III
Category Rating Description
Chronic / None.
Health 3 Major injury likely unless prompt action is taken and medical treatment is given.
Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.
Physical hazard 0 Material that is normally stable, even under fire conditions, and will not react with water,polymerize, decompose, condense, or self-react. Non-explosive.
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National Fire Protection Association: Standard System for the Identification of the Hazards of Materials forEmergency Response (United States)
Category Rating Description
Personal protectiveequipment
-
NFPA® 704
Category Degree ofhazard
Description
Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.
Health 3 Material that, under emergency conditions, can cause serious or permanent injury.
Instability 0 Material that is normally stable, even under fire conditions.
Special hazard
Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryskin corrosion/irritation 2 (Skin Irrit. 2)serious eye damage/eye irritation 1 (Eye Dam. 1)
SECTION 16: Other information, including date of preparation or last revision
Abbreviations and acronymsAbbr. Descriptions of used abbreviations
ATE Acute Toxicity Estimate
BCF BioConcentration Factor
BOD Biochemical Oxygen Demand
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
COD chemical oxygen demand
DMEL Derived Minimal Effect Level
DNEL Derived No-Effect Level
DOT Department of Transportation (USA)
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
HMIS Hazardous Materials Identification System
IARC Mono-graphs
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
log KOW n-octanol/water
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)
NFPA® 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emer-gency Response (United States)
NPCA-HMIS®III
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition
OSHA Occupational Safety and Health Administration (United States)
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Physical and chemical properties: The classification is based on tested mixture.Health hazards/Environmental hazards: The method for classification of the mixture is based on ingredients ofthe mixture (additivity formula).
This information is based upon the present state of our knowledge. This SDS has been compiled and is solelyintended for this product.
Abbr. Descriptions of used abbreviations
PBT Persistent, Bioaccumulative and Toxic
PNEC Predicted No-Effect Concentration
vPvB very Persistent and very Bioaccumulative
Key literature references and sources for data- OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200- 49 CFR § 172.101 Hazardous Materials Table (DOT)
Classification procedure
List of relevant phrases (code and full text as stated in chapter 2 and 3)Code Text
H315 causes skin irritation
H318 causes serious eye damage
Disclaimer
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MasterBlend • 5285 Fox Street • CO 80216 Denver • United States • Telephone: 303.373.0702 • Telefax 303.373.4968 • e-mail: [email protected] • Website: masterblend.net
Annex - Hazard class and category - Hazard statement code(s)
For full text of H-phrases: see SECTION 16.
The product is combustible and can be ignited by potential ignition sources.
SECTION 1: Identification
1.1 Product identifierTrade name MasterSpotterOther means of identificationProduct code(s): 1823 Formula code: 08-150421
1.2 Relevant identified usesRelevant identified uses General use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency telephone numberChem-Tel 1.800.255.3924 (USA & Canada) 1.813.248.0585 (International)
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixtureClassification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
B.6 flammable liquid Cat. 3 (Flam. Liq. 3) H226A.3 serious eye damage/eye irritation Cat. 1 (Eye Dam. 1) H318Remarks
The most important adverse physicochemical, human health and environmental effects
2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word DANGERPictogramsGHS02, GHS05
Hazard statementsH226 Flammable liquid and vapor.H318 Causes serious eye damage.
Precautionary statementsPrecautionary statements - preventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Precautionary statements - responseIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.
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There is no additional information.
not relevant (mixture)
For full text of abbreviations: see SECTION 16.
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms per-sist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give any-thing by mouth.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Providefresh air.
Wash with plenty of soap and water.
Precautionary statements - storageStore in a well-ventilated place. Keep cool.
Precautionary statements - disposalDispose of contents/container to industrial combustion plant.
Hazardous ingredients for labelling Ethoxylated Alcohols2.3 Other hazards
SECTION 3: Composition/information on ingredients
3.1 Substances
3.2 Mixtures3.2.1
Name of substance Identifier Wt%
Ethoxylated Alcohols CAS No68439-46-3
5 - < 15
D-Limonene CAS No94266-47-4
5 - < 15
Dipropylene Glycol Monomethyl Ether CAS No34590-94-8
5 - < 15
Cocamide DIPA CAS No68855-69-6
1 - < 5
Sodium thiosulphate CAS No7772-98-7
1 - < 5
B-Alanine, N-(2-carboxyethyl)-N-[3-(decyloxy)propyl]-, monosodi-um salt
CAS No64972-19-6
< 1
SECTION 4: First-aid measures
4.1 Description of firs- aid measuresGeneral notes
Following inhalation
Following skin contact
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Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh waterfor at least 10 minutes, holding the eyelids apart.
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
Symptoms and effects are not known to date.
none
water spray, alcohol resistant foam, BC-powder, carbon dioxide (CO2)
water jet
In case of insufficient ventilation and/or in use, may form flammable/explosive vapor-air mixture. Solvent va-pors are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated belowground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammablesubstances or mixtures.
nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround-ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting waterseparately. Fight fire with normal precautions from a reasonable distance.
Remove persons to safety.
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose it.
Covering of drains.
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand,universal binder).
Following eye contact
Following ingestion
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed
SECTION 5: Fire-fighting measures
5.1 Extinguishing mediaSuitable extinguishing media
Unsuitable extinguishing media
5.2 Special hazards arising from the substance or mixture
Hazardous combustion products
5.3 Advice for firefighters
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel
For emergency responders
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning upAdvices on how to contain a spill
Advices on how to clean up a spill
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Use of adsorbent materials.
Place in appropriate containers for disposal. Ventilate affected area.
Hazardous combustion products: see section 5. Personal precautions: see section 8. Incompatible materials:see section 10. Disposal considerations: see section 13.
Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - Nosmoking. Take precautionary measures against static discharge. Use only in well-ventilated areas. Due todanger of explosion, prevent leakage of vapours into cellars, flues and ditches. Ground/bond container and re-ceiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools.
Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits andshafts, are particularly prone to the presence of flammable substances or mixtures. Vapors are heavier thanair, spread along floors and form explosive mixtures with air. Vapors may form explosive mixtures with air.
Wash hands after use. Do not to eat, drink and smoke in work areas. Remove contaminated clothing and pro-tective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Neverplace chemicals in containers that are normally used for food or drink. Keep away from food, drink and animalfeedingstuffs.
Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool.Protect from sunlight.
Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flamesand other ignition sources. No smoking. Take precautionary measures against static discharge. Protect fromsunlight.
Observe compatible storage of chemicals.
Use local and general ventilation. Ground/bond container and receiving equipment.
Only packagings which are approved (e.g. acc. to DOT) may be used.
See section 16 for a general overview.
Appropriate containment techniques
Other information relating to spills and releases
6.4 Reference to other sections
SECTION 7: Handling and storage
7.1 Precautions for safe handlingRecommendationsMeasures to prevent fire as well as aerosol and dust generation
Warning
Advice on general occupational hygiene
7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risks• Explosive atmospheres
• Flammability hazards
Incompatible substances or mixtures
Consideration of other adviceVentilation requirements
Packaging compatibilities
7.3 Specific end use(s)
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No data available.
General ventilation.
Wear eye/face protection.
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Checkleak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them beforetaking off and air them well. For special purposes, it is recommended to check the resistance to chemicals ofthe protective gloves mentioned above together with the supplier of these gloves.
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom-mended. Wash hands thoroughly after handling.
In case of inadequate ventilation wear respiratory protection.
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and groundwater.
SECTION 8: Exposure controls/personal protection
8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)
Coun-try
Name of agent CAS No Identifier TWA[ppm]
TWA[mg/m³]
STEL[ppm]
STEL[mg/m³]
Source
US dipropylene glycol methylether
34590-94-8 PEL 100 600 29 CFROSHA
notationSTEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period
unless otherwise specified.TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-
weighted average.
Relevant DNELs/DMELs/PNECs and other threshold levels
8.2 Exposure controlsAppropriate engineering controls
Individual protection measures (personal protective equipment)Eye/face protection
Skin protection• hand protection
• other protection measures
Respiratory protection
Environmental exposure controls
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Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". The mixture containsreactive substance(s): risk of ignition
risk of ignition
See below "Conditions to avoid".
No known hazardous reactions.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquidColor amberOdor Orange Citrus AromaOther physical and chemical parameterspH (value) 7.5Melting point/freezing point not determinedInitial boiling point and boiling range >100 °CFlash point 52.2 °CEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits• lower explosion limit (LEL) 0.7 vol%• upper explosion limit (UEL) 14 vol%Vapor pressure <2 mmHg at 20 °CDensity 0.9982 kg/lSolubility(ies) not determinedAuto-ignition temperature 207 °CViscosity not determinedExplosive properties noneOxidizing properties none
SECTION 10: Stability and reactivity
10.1 Reactivity
• if heated
10.2 Chemical stability
10.3 Possibility of hazardous reactions
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Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge.
strong shocks
There is no additional information.
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill andheating are not known. Hazardous combustion products: see section 5.
Test data are not available for the complete mixture.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Shall not be classified as acutely toxic.
Shall not be classified as corrosive/irritant to skin.
Causes serious eye damage.
Shall not be classified as a respiratory or skin sensitizer.
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.
Shall not be classified as a specific target organ toxicant.
Shall not be classified as presenting an aspiration hazard.
10.4 Conditions to avoid
Hints to prevent fire or explosion
Physical stresses which might result in a hazardous situation and have to be avoided
10.5 Incompatible materials
10.6 Hazardous decomposition products
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Classification procedure
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Acute toxicity
Acute toxicity of components of the mixtureName of substance CAS No Exposure route ATE
Ethoxylated Alcohols 68439-46-3 oral 1,400
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Summary of evaluation of the CMR properties
Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listedSpecific target organ toxicity (STOT)
Aspiration hazard
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Shall not be classified as hazardous to the aquatic environment.
The relevant substances of the mixture are readily biodegradable.
Data are not available.
Data are not available.
Data are not available.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity (acute)Aquatic toxicity (acute) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
Dipropylene GlycolMonomethyl Ether
34590-94-8 LC50 >1,000 mg/l fish 96 hours
Dipropylene GlycolMonomethyl Ether
34590-94-8 ErC50 >969 mg/l algae 72 hours
Dipropylene GlycolMonomethyl Ether
34590-94-8 EC50 >969 mg/l algae 72 hours
Aquatic toxicity (chronic)Aquatic toxicity (chronic) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
Dipropylene GlycolMonomethyl Ether
34590-94-8 LC50 >1,000 mg/l aquatic inverteb-rates
24 h
Biodegradation
12.2 Persistence and degradability
Degradability of components of the mixtureName of substance CAS No Process Degradation rate Time
Dipropylene GlycolMonomethyl Ether
34590-94-8 oxygen depletion 75 % 10 d
Dipropylene GlycolMonomethyl Ether
34590-94-8 DOC removal 96 % 28 d
Dipropylene GlycolMonomethyl Ether
34590-94-8 carbon dioxide genera-tion
76 % 28 d
12.3 Bioaccumulative potential
Bioaccumulative potential of components of the mixtureName of substance CAS No BCF Log KOW BOD5/COD
Dipropylene GlycolMonomethyl Ether
34590-94-8 0.0043
12.4 Mobility in soil
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Data are not available.
Data are not available.
Solvent reclamation/regeneration.
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the sub-stance itself.
Please consider the relevant national or regional provisions. Waste shall be separated into the categories thatcan be handled separately by the local or national waste management facilities.
There is no additional information.
The cargo is not intended to be carried in bulk.
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
SECTION 13: Disposal considerations
13.1 Waste treatment methodsWaste treatment-relevant information
Sewage disposal-relevant information
Waste treatment of containers/packages
Remarks
SECTION 14: Transport information
14.1 UN number 199314.2 UN proper shipping name FLAMMABLE LIQUID, N.O.S.
Hazardous constituents d-Limonene14.3 Transport hazard class(es)
Class 3 (flammable liquids)
14.4 Packing group III (substance presenting low danger)
14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerousgoods regulations)
14.6 Special precautions for user
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Information for each of the UN Model Regulations• Transport of dangerous goods by road or rail (49 CFR US DOT)Index number 1993Proper shipping name Flammable liquid, n.o.s.Class 3Packing group IIIDanger label(s) 3
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Hazardous Materials Identification System (American Coatings Association)
Special provisions (SP) B1, B52, IB3, T4, TP1, TP29ERG No 128• International Maritime Dangerous Goods Code (IMDG)UN number 1993Proper shipping name FLAMMABLE LIQUID, N.O.S.Class 3Packing group IIIDanger label(s) 3
Special provisions (SP) 223, 274, 955Excepted quantities (EQ) E1Limited quantities (LQ) 5 LEmS F-E, S-EStowage category E• International Civil Aviation Organization (ICAO-IATA/DGR)UN number 1993Proper shipping name Flammable liquid, n.o.s.Class 3Packing group IIIDanger label(s) 3
Special provisions (SP) A3, 274Excepted quantities (EQ) E1Limited quantities (LQ) 10 L
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in questionNational regulations (United States)
Industry or sector specific available guidance(s)NPCA-HMIS® III
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National Fire Protection Association: Standard System for the Identification of the Hazards of Materials forEmergency Response (United States)
Category Rating Description
Chronic / None.
Health 3 Major injury likely unless prompt action is taken and medical treatment is given.
Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.
Physical hazard 0 Material that is normally stable, even under fire conditions, and will not react with water,polymerize, decompose, condense, or self-react. Non-explosive.
Personal protectiveequipment
-
NFPA® 704
Category Degree ofhazard
Description
Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.
Health 3 Material that, under emergency conditions, can cause serious or permanent injury.
Instability 0 Material that is normally stable, even under fire conditions.
Special hazard
Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryflammable liquid 3 (Flam. Liq. 3)serious eye damage/eye irritation 1 (Eye Dam. 1)
SECTION 16: Other information, including date of preparation or last revision
Abbreviations and acronymsAbbr. Descriptions of used abbreviations
29 CFR OSHA 29 CFR §1910.1001 - Occupational Safety and Health Standards: Toxic and Hazardous Substances (permissible ex-posure limits)
49 CFR USDOT
49 CFR § 40 U.S. Department of Transportation
ATE Acute Toxicity Estimate
BCF BioConcentration Factor
BOD Biochemical Oxygen Demand
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
COD chemical oxygen demand
DMEL Derived Minimal Effect Level
DNEL Derived No-Effect Level
DOT Department of Transportation (USA)
EmS Emergency Schedule
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Physical and chemical properties: The classification is based on tested mixture.Health hazards/Environmental hazards: The method for classification of the mixture is based on ingredients ofthe mixture (additivity formula).
This information is based upon the present state of our knowledge. This SDS has been compiled and is solelyintended for this product.
Abbr. Descriptions of used abbreviations
ERG No Emergency Response Guidebook - Number
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
HMIS Hazardous Materials Identification System
IARC Mono-graphs
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods Code
log KOW n-octanol/water
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)
NFPA® 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emer-gency Response (United States)
NPCA-HMIS®III
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition
OSHA Occupational Safety and Health Administration (United States)
PBT Persistent, Bioaccumulative and Toxic
PEL permissible exposure limit
PNEC Predicted No-Effect Concentration
ppm parts per million
STEL short-term exposure limit
TWA time-weighted average
vPvB very Persistent and very Bioaccumulative
Key literature references and sources for data- OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200- 49 CFR § 172.101 Hazardous Materials Table (DOT)
Classification procedure
List of relevant phrases (code and full text as stated in chapter 2 and 3)Code Text
H226 flammable liquid and vapor
H318 causes serious eye damage
Disclaimer
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MasterBlend • 5285 Fox Street • CO 80216 Denver • United States • Telephone: 303.373.0702 • Telefax 303.373.4968 • e-mail: [email protected] • Website: masterblend.net
Annex - Hazard class and category - Hazard statement code(s)
For full text of H-phrases: see SECTION 16.
The product is combustible and can be ignited by potential ignition sources.
SECTION 1: Identification
1.1 Product identifierTrade name POG - Paint Oil & Grease RemoverOther means of identificationProduct code(s): 1821 Formula code: 04-091110
1.2 Relevant identified usesRelevant identified uses General use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency telephone numberChem-Tel 1.800.255.3924 (USA & Canada) 1.813.248.0585 (International)
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixtureClassification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
B.6 flammable liquid Cat. 4 (Flam. Liq. 4) H227A.2 skin corrosion/irritation Cat. 2 (Skin Irrit. 2) H315A.3 serious eye damage/eye irritation Cat. 2B (Eye Irrit. 2B) H320Remarks
The most important adverse physicochemical, human health and environmental effects
2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word WARNINGPictogramsGHS07
Hazard statementsH227 Combustible liquid.H315+H320 Causes skin and eye irritation.
Precautionary statementsPrecautionary statements - preventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.Wear protective gloves/eye protection/face protection.
Precautionary statements - response
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This material is combustible, but will not ignite readily.
not relevant (mixture)
For full text of abbreviations: see SECTION 16.
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms per-sist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give any-thing by mouth.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case ofrespiratory tract irritation, consult a physician. Provide fresh air.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.If eye irritation persists: Get medical advice/attention.In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.
Precautionary statements - disposalDispose of contents/container to industrial combustion plant.
2.3 Other hazards
SECTION 3: Composition/information on ingredients
3.1 Substances
3.2 Mixtures3.2.1
Name of substance Identifier Wt%
Soy methyl ester CAS No68919-53-9
50 - < 75
Synthetic hydrocarbon CAS NoTrade Secret
15 - < 25
Cocamide DIPA CAS No68855-69-6
5 - < 15
Dipropylene Glycol Monomethyl Ether CAS No34590-94-8
1 - < 5
Pentyl acetate CAS No628-63-7
1 - < 5
2-methyl butyl acetate CAS No624-41-9
1 - < 5
D-Limonene CAS No94266-47-4
1 - < 5
SECTION 4: First-aid measures
4.1 Description of firs- aid measuresGeneral notes
Following inhalation
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Wash with plenty of soap and water.
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh waterfor at least 10 minutes, holding the eyelids apart.
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
Symptoms and effects are not known to date.
none
water spray, alcohol resistant foam, BC-powder, carbon dioxide (CO2)
water jet
In case of insufficient ventilation and/or in use, may form flammable/explosive vapor-air mixture. Solvent va-pors are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated belowground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammablesubstances or mixtures.
nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround-ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting waterseparately. Fight fire with normal precautions from a reasonable distance.
Remove persons to safety.
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose it.
Covering of drains.
Following skin contact
Following eye contact
Following ingestion
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed
SECTION 5: Fire-fighting measures
5.1 Extinguishing mediaSuitable extinguishing media
Unsuitable extinguishing media
5.2 Special hazards arising from the substance or mixture
Hazardous combustion products
5.3 Advice for firefighters
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel
For emergency responders
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning upAdvices on how to contain a spill
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Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand,universal binder).
Use of adsorbent materials.
Place in appropriate containers for disposal. Ventilate affected area.
Hazardous combustion products: see section 5. Personal precautions: see section 8. Incompatible materials:see section 10. Disposal considerations: see section 13.
Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - Nosmoking. Take precautionary measures against static discharge. Use only in well-ventilated areas. Due todanger of explosion, prevent leakage of vapours into cellars, flues and ditches. Ground/bond container and re-ceiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools.
Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits andshafts, are particularly prone to the presence of flammable substances or mixtures. Vapors are heavier thanair, spread along floors and form explosive mixtures with air. Vapors may form explosive mixtures with air.
Wash hands after use. Do not to eat, drink and smoke in work areas. Remove contaminated clothing and pro-tective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Neverplace chemicals in containers that are normally used for food or drink. Keep away from food, drink and animalfeedingstuffs.
Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool.Protect from sunlight.
Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flamesand other ignition sources. No smoking. Take precautionary measures against static discharge. Protect fromsunlight.
Observe compatible storage of chemicals.
Use local and general ventilation. Ground/bond container and receiving equipment.
Advices on how to clean up a spill
Appropriate containment techniques
Other information relating to spills and releases
6.4 Reference to other sections
SECTION 7: Handling and storage
7.1 Precautions for safe handlingRecommendationsMeasures to prevent fire as well as aerosol and dust generation
Warning
Advice on general occupational hygiene
7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risks• Explosive atmospheres
• Flammability hazards
Incompatible substances or mixtures
Consideration of other adviceVentilation requirements
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See section 16 for a general overview.
No data available.
General ventilation.
Wear eye/face protection.
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Checkleak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them beforetaking off and air them well. For special purposes, it is recommended to check the resistance to chemicals ofthe protective gloves mentioned above together with the supplier of these gloves.
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom-mended. Wash hands thoroughly after handling.
In case of inadequate ventilation wear respiratory protection.
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and groundwater.
7.3 Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)
Coun-try
Name of agent CAS No Identifier TWA[ppm]
TWA[mg/m³]
STEL[ppm]
STEL[mg/m³]
Source
US dipropylene glycol methylether
34590-94-8 PEL 100 600 29 CFROSHA
notationSTEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period
unless otherwise specified.TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-
weighted average.
Relevant DNELs/DMELs/PNECs and other threshold levels
8.2 Exposure controlsAppropriate engineering controls
Individual protection measures (personal protective equipment)Eye/face protection
Skin protection• hand protection
• other protection measures
Respiratory protection
Environmental exposure controls
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Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". The mixture containsreactive substance(s): risk of ignition
risk of ignition
See below "Conditions to avoid".
No known hazardous reactions.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquidColor dark amberOdor Citrus AromaOther physical and chemical parameterspH (value) not applicable (non-aqueous)Melting point/freezing point not determinedInitial boiling point and boiling range 176 °CFlash point 62.5 °CEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits• lower explosion limit (LEL) 0.7 vol%• upper explosion limit (UEL) 14 vol%Vapor pressure <2 mmHg at 20 °CDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature 207 °CViscosity not determinedExplosive properties noneOxidizing properties none
SECTION 10: Stability and reactivity
10.1 Reactivity
• if heated
10.2 Chemical stability
10.3 Possibility of hazardous reactions
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Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge.
strong shocks
There is no additional information.
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill andheating are not known. Hazardous combustion products: see section 5.
Test data are not available for the complete mixture.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Shall not be classified as acutely toxic.
Causes skin irritation.
Causes eye irritation.
Shall not be classified as a respiratory or skin sensitizer.
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.
Shall not be classified as a specific target organ toxicant.
Shall not be classified as presenting an aspiration hazard.
10.4 Conditions to avoid
Hints to prevent fire or explosion
Physical stresses which might result in a hazardous situation and have to be avoided
10.5 Incompatible materials
10.6 Hazardous decomposition products
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Classification procedure
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Acute toxicity
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Summary of evaluation of the CMR properties
Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listedSpecific target organ toxicity (STOT)
Aspiration hazard
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Shall not be classified as hazardous to the aquatic environment.
The relevant substances of the mixture are readily biodegradable.
Data are not available.
Data are not available.
Data are not available.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity (acute)Aquatic toxicity (acute) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
Dipropylene GlycolMonomethyl Ether
34590-94-8 LC50 >1,000 mg/l fish 96 hours
Dipropylene GlycolMonomethyl Ether
34590-94-8 ErC50 >969 mg/l algae 72 hours
Dipropylene GlycolMonomethyl Ether
34590-94-8 EC50 >969 mg/l algae 72 hours
Aquatic toxicity (chronic)Aquatic toxicity (chronic) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
Dipropylene GlycolMonomethyl Ether
34590-94-8 LC50 >1,000 mg/l aquatic inverteb-rates
24 h
Biodegradation
12.2 Persistence and degradability
Degradability of components of the mixtureName of substance CAS No Process Degradation rate Time
Dipropylene GlycolMonomethyl Ether
34590-94-8 oxygen depletion 75 % 10 d
Dipropylene GlycolMonomethyl Ether
34590-94-8 DOC removal 96 % 28 d
Dipropylene GlycolMonomethyl Ether
34590-94-8 carbon dioxide genera-tion
76 % 28 d
12.3 Bioaccumulative potential
Bioaccumulative potential of components of the mixtureName of substance CAS No BCF Log KOW BOD5/COD
Dipropylene GlycolMonomethyl Ether
34590-94-8 0.0043
12.4 Mobility in soil
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Data are not available.
Data are not available.
Solvent reclamation/regeneration.
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the sub-stance itself.
Please consider the relevant national or regional provisions. Waste shall be separated into the categories thatcan be handled separately by the local or national waste management facilities.
There is no additional information.
The cargo is not intended to be carried in bulk.
Hazardous Materials Identification System (American Coatings Association)
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
SECTION 13: Disposal considerations
13.1 Waste treatment methodsWaste treatment-relevant information
Sewage disposal-relevant information
Waste treatment of containers/packages
Remarks
SECTION 14: Transport information
14.1 UN number (not subject to transport regulations)14.2 UN proper shipping name not relevant14.3 Transport hazard class(es)
Class -
14.4 Packing group not relevant14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerous
goods regulations)
14.6 Special precautions for user
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in questionNational regulations (United States)
Industry or sector specific available guidance(s)NPCA-HMIS® III
Category Rating Description
Chronic / None.
Health 2 Temporary or minor injury may occur.
Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.
Physical hazard 0 Material that is normally stable, even under fire conditions, and will not react with water,polymerize, decompose, condense, or self-react. Non-explosive.
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National Fire Protection Association: Standard System for the Identification of the Hazards of Materials forEmergency Response (United States)
Category Rating Description
Personal protectiveequipment
-
NFPA® 704
Category Degree ofhazard
Description
Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.
Health 2 Material that, under emergency conditions, can cause temporary incapacitation or residualinjury.
Instability 0 Material that is normally stable, even under fire conditions.
Special hazard
Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryskin corrosion/irritation 2 (Skin Irrit. 2)serious eye damage/eye irritation 2 (Eye Irrit. 2)
SECTION 16: Other information, including date of preparation or last revision
Abbreviations and acronymsAbbr. Descriptions of used abbreviations
29 CFR OSHA 29 CFR §1910.1001 - Occupational Safety and Health Standards: Toxic and Hazardous Substances (permissible ex-posure limits)
BCF BioConcentration Factor
BOD Biochemical Oxygen Demand
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
COD chemical oxygen demand
DMEL Derived Minimal Effect Level
DNEL Derived No-Effect Level
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
HMIS Hazardous Materials Identification System
IARC Mono-graphs
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
log KOW n-octanol/water
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)
NFPA® 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emer-gency Response (United States)
NPCA-HMIS®III
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition
OSHA Occupational Safety and Health Administration (United States)
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Physical and chemical properties: The classification is based on tested mixture.Health hazards/Environmental hazards: The method for classification of the mixture is based on ingredients ofthe mixture (additivity formula).
This information is based upon the present state of our knowledge. This SDS has been compiled and is solelyintended for this product.
Abbr. Descriptions of used abbreviations
PBT Persistent, Bioaccumulative and Toxic
PEL permissible exposure limit
PNEC Predicted No-Effect Concentration
ppm parts per million
STEL short-term exposure limit
TWA time-weighted average
vPvB very Persistent and very Bioaccumulative
Key literature references and sources for data- OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200- 49 CFR § 172.101 Hazardous Materials Table (DOT)
Classification procedure
List of relevant phrases (code and full text as stated in chapter 2 and 3)Code Text
H227 combustible liquid
H315 causes skin irritation
H320 causes eye irritation
Disclaimer
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MasterBlend • 5285 Fox Street • CO 80216 Denver • United States • Telephone: 303.373.0702 • Telefax 303.373.4968 • e-mail: [email protected] • Website: masterblend.net
Annex - Hazard class and category - Hazard statement code(s)
For full text of H-phrases: see SECTION 16.
SECTION 1: Identification
1.1 Product identifierTrade name Protein SpotterOther means of identificationProduct code(s): 1831 Formula code: 02-960326
1.2 Relevant identified usesRelevant identified uses General use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency telephone numberChem-Tel 1.800.255.3924 (USA & Canada) 1.813.248.0585 (International)
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixtureClassification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
A.2 skin corrosion/irritation Cat. 2 (Skin Irrit. 2) H315A.3 serious eye damage/eye irritation Cat. 2 (Eye Irrit. 2) H319Remarks
2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word WARNINGPictogramsGHS07
Hazard statementsH315 Causes skin irritation.H319 Causes serious eye irritation.
Precautionary statementsPrecautionary statements - preventionWash thoroughly after handling.Wear protective gloves/eye protection/face protection.
Precautionary statements - responseIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Specific treatment (see on this label).If skin irritation occurs: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.
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There is no additional information.
not relevant (mixture)
For full text of abbreviations: see SECTION 16.
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms per-sist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give any-thing by mouth.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case ofrespiratory tract irritation, consult a physician. Provide fresh air.
Wash with plenty of soap and water.
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh waterfor at least 10 minutes, holding the eyelids apart.
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
2.3 Other hazards
SECTION 3: Composition/information on ingredients
3.1 Substances
3.2 Mixtures3.2.1
Name of substance Identifier Wt%
Deionized Water CAS No7732-18-5
75 - < 90
Dipropylene Glycol Monomethyl Ether CAS No34590-94-8
5 - < 15
2-butoxyethanol CAS No111-76-2
5 - < 15
2-aminoethanol CAS No141-43-5
1 - < 5
Ammonium lauryl sulfate CAS No2235-54-3
< 1
Ethoxylated Alcohols CAS No68439-46-3
< 1
SECTION 4: First-aid measures
4.1 Description of firs- aid measuresGeneral notes
Following inhalation
Following skin contact
Following eye contact
Following ingestion
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Symptoms and effects are not known to date.
none
water spray, alcohol resistant foam, BC-powder, carbon dioxide (CO2)
water jet
nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround-ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting waterseparately. Fight fire with normal precautions from a reasonable distance.
Remove persons to safety.
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose it.
Covering of drains.
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand,universal binder).
Use of adsorbent materials.
Place in appropriate containers for disposal. Ventilate affected area.
Hazardous combustion products: see section 5. Personal precautions: see section 8. Incompatible materials:see section 10. Disposal considerations: see section 13.
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed
SECTION 5: Fire-fighting measures
5.1 Extinguishing mediaSuitable extinguishing media
Unsuitable extinguishing media
5.2 Special hazards arising from the substance or mixtureHazardous combustion products
5.3 Advice for firefighters
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel
For emergency responders
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning upAdvices on how to contain a spill
Advices on how to clean up a spill
Appropriate containment techniques
Other information relating to spills and releases
6.4 Reference to other sections
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Use local and general ventilation. Use only in well-ventilated areas.
Wash hands after use. Do not to eat, drink and smoke in work areas. Remove contaminated clothing and pro-tective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Neverplace chemicals in containers that are normally used for food or drink. Keep away from food, drink and animalfeedingstuffs.
Observe compatible storage of chemicals.
frost
See section 16 for a general overview.
No data available.
SECTION 7: Handling and storage
7.1 Precautions for safe handlingRecommendationsMeasures to prevent fire as well as aerosol and dust generation
Advice on general occupational hygiene
7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risksIncompatible substances or mixtures
Control of the effectsProtect against external exposure, such as
7.3 Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)
Coun-try
Name of agent CAS No Identifier TWA[ppm]
TWA[mg/m³]
STEL[ppm]
STEL[mg/m³]
Source
US 2-butoxyethanol 111-76-2 PEL 50 240 29 CFROSHA
US dipropylene glycol methylether
34590-94-8 PEL 100 600 29 CFROSHA
US ethanolamine 141-43-5 PEL 3 6 29 CFROSHA
notationSTEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period
unless otherwise specified.TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-
weighted average.
Relevant DNELs/DMELs/PNECs and other threshold levels
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General ventilation.
Wear eye/face protection.
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Checkleak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them beforetaking off and air them well. For special purposes, it is recommended to check the resistance to chemicals ofthe protective gloves mentioned above together with the supplier of these gloves.
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom-mended. Wash hands thoroughly after handling.
In case of inadequate ventilation wear respiratory protection.
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and groundwater.
8.2 Exposure controlsAppropriate engineering controls
Individual protection measures (personal protective equipment)Eye/face protection
Skin protection• hand protection
• other protection measures
Respiratory protection
Environmental exposure controls
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquidColor differentOdor mild sweetOther physical and chemical parameterspH (value) 10Melting point/freezing point not determinedInitial boiling point and boiling range 167 °C at 101 kPaFlash point >96.1 °CEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits• lower explosion limit (LEL) 1.1 vol%• upper explosion limit (UEL) 14 vol%Vapor pressure 1 hPa at 20 °CDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature 207 °CViscosity not determined
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Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".
See below "Conditions to avoid".
No known hazardous reactions.
There are no specific conditions known which have to be avoided.
strong shocks
There is no additional information.
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill andheating are not known. Hazardous combustion products: see section 5.
Test data are not available for the complete mixture.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Shall not be classified as acutely toxic.
Explosive properties noneOxidizing properties none
SECTION 10: Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
Physical stresses which might result in a hazardous situation and have to be avoided
10.5 Incompatible materials
10.6 Hazardous decomposition products
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Classification procedure
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Acute toxicity
Acute toxicity of components of the mixtureName of substance CAS No Exposure route ATE
2-butoxyethanol 111-76-2 oral 1,414
2-butoxyethanol 111-76-2 dermal 1,100
2-butoxyethanol 111-76-2 inhalation: vapor 11
2-aminoethanol 141-43-5 oral 1,515
2-aminoethanol 141-43-5 dermal 1,100
2-aminoethanol 141-43-5 inhalation: vapor 11
Ammonium lauryl sulfate 2235-54-3 oral 500
Ethoxylated Alcohols 68439-46-3 oral 1,400
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Causes skin irritation.
Causes serious eye irritation.
Shall not be classified as a respiratory or skin sensitizer.
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.
Shall not be classified as a specific target organ toxicant.
Shall not be classified as presenting an aspiration hazard.
Shall not be classified as hazardous to the aquatic environment.
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Summary of evaluation of the CMR properties
Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs
Name of substance Name acc. to inventory CAS No wt% Classifica-tion
Number
2-butoxyethanol 2-Butoxyethanol 111-76-2 5 3 Volume 88
legend3 Not classifiable as to carcinogenicity in humans.
Specific target organ toxicity (STOT)
Aspiration hazard
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity (acute)Aquatic toxicity (acute) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
Dipropylene GlycolMonomethyl Ether
34590-94-8 LC50 >1,000 mg/l fish 96 hours
Dipropylene GlycolMonomethyl Ether
34590-94-8 ErC50 >969 mg/l algae 72 hours
Dipropylene GlycolMonomethyl Ether
34590-94-8 EC50 >969 mg/l algae 72 hours
2-butoxyethanol 111-76-2 LC50 1,474 mg/l fish 96 hours
2-butoxyethanol 111-76-2 EC50 1,550 mg/l aquatic inverteb-rates
48 hours
2-butoxyethanol 111-76-2 ErC50 1,840 mg/l algae 72 hours
2-aminoethanol 141-43-5 LC50 >300 mg/l fish 96 hours
2-aminoethanol 141-43-5 EC50 65 mg/l aquatic inverteb-rates
48 hours
2-aminoethanol 141-43-5 ErC50 2.8 mg/l algae 72 hours
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Data are not available.
Data are not available.
Data are not available.
Data are not available.
Aquatic toxicity (chronic)Aquatic toxicity (chronic) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
Dipropylene GlycolMonomethyl Ether
34590-94-8 LC50 >1,000 mg/l aquatic inverteb-rates
24 h
2-butoxyethanol 111-76-2 EC50 297 mg/l aquatic inverteb-rates
21 d
2-aminoethanol 141-43-5 LC50 525 mg/l fish 10 d
2-aminoethanol 141-43-5 EC50 120 mg/l aquatic inverteb-rates
24 h
12.2 Persistence and degradability
Degradability of components of the mixtureName of substance CAS No Process Degradation rate Time
Dipropylene GlycolMonomethyl Ether
34590-94-8 oxygen depletion 75 % 10 d
Dipropylene GlycolMonomethyl Ether
34590-94-8 DOC removal 96 % 28 d
Dipropylene GlycolMonomethyl Ether
34590-94-8 carbon dioxide genera-tion
76 % 28 d
2-butoxyethanol 111-76-2 carbon dioxide genera-tion
18.3 % 3 d
2-aminoethanol 141-43-5 DOC removal >90 % 21 d
12.3 Bioaccumulative potential
Bioaccumulative potential of components of the mixtureName of substance CAS No BCF Log KOW BOD5/COD
Dipropylene GlycolMonomethyl Ether
34590-94-8 0.0043
2-butoxyethanol 111-76-2 0.81
2-aminoethanol 141-43-5 0.75 -2.3
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
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Data are not available.
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the sub-stance itself.
Please consider the relevant national or regional provisions. Waste shall be separated into the categories thatcan be handled separately by the local or national waste management facilities.
There is no additional information.
The cargo is not intended to be carried in bulk.
Hazardous Materials Identification System (American Coatings Association)
12.6 Other adverse effects
SECTION 13: Disposal considerations
13.1 Waste treatment methodsSewage disposal-relevant information
Waste treatment of containers/packages
Remarks
SECTION 14: Transport information
14.1 UN number (not subject to transport regulations)14.2 UN proper shipping name not relevant14.3 Transport hazard class(es)
Class -
14.4 Packing group not relevant14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerous
goods regulations)
14.6 Special precautions for user
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in questionNational regulations (United States)
Industry or sector specific available guidance(s)NPCA-HMIS® III
Category Rating Description
Chronic / None.
Health 2 Temporary or minor injury may occur.
Flammability 1 Material that must be preheated before ignition can occur.
Physical hazard 0 Material that is normally stable, even under fire conditions, and will not react with water,polymerize, decompose, condense, or self-react. Non-explosive.
Personal protectiveequipment
-
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National Fire Protection Association: Standard System for the Identification of the Hazards of Materials forEmergency Response (United States)
NFPA® 704
Category Degree ofhazard
Description
Flammability 1 Material that must be preheated before ignition can occur.
Health 2 Material that, under emergency conditions, can cause temporary incapacitation or residualinjury.
Instability 0 Material that is normally stable, even under fire conditions.
Special hazard
Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryskin corrosion/irritation 2 (Skin Irrit. 2)serious eye damage/eye irritation 2 (Eye Irrit. 2)
SECTION 16: Other information, including date of preparation or last revision
Abbreviations and acronymsAbbr. Descriptions of used abbreviations
29 CFR OSHA 29 CFR §1910.1001 - Occupational Safety and Health Standards: Toxic and Hazardous Substances (permissible ex-posure limits)
ATE Acute Toxicity Estimate
BCF BioConcentration Factor
BOD Biochemical Oxygen Demand
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
COD chemical oxygen demand
DMEL Derived Minimal Effect Level
DNEL Derived No-Effect Level
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
HMIS Hazardous Materials Identification System
IARC Mono-graphs
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
log KOW n-octanol/water
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)
NFPA® 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emer-gency Response (United States)
NPCA-HMIS®III
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition
OSHA Occupational Safety and Health Administration (United States)
PBT Persistent, Bioaccumulative and Toxic
PEL permissible exposure limit
PNEC Predicted No-Effect Concentration
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Physical and chemical properties: The classification is based on tested mixture.Health hazards/Environmental hazards: The method for classification of the mixture is based on ingredients ofthe mixture (additivity formula).
This information is based upon the present state of our knowledge. This SDS has been compiled and is solelyintended for this product.
Abbr. Descriptions of used abbreviations
ppm parts per million
STEL short-term exposure limit
TWA time-weighted average
vPvB very Persistent and very Bioaccumulative
Key literature references and sources for data- OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200- 49 CFR § 172.101 Hazardous Materials Table (DOT)
Classification procedure
List of relevant phrases (code and full text as stated in chapter 2 and 3)Code Text
H315 causes skin irritation
H319 causes serious eye irritation
Disclaimer
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MasterBlend • 5285 Fox Street • CO 80216 Denver • United States • Telephone: 303.373.0702 • Telefax 303.373.4968 • e-mail: [email protected] • Website: masterblend.net
Annex - Hazard class and category - Hazard statement code(s)
For full text of H-phrases: see SECTION 16.
The product is combustible and can be ignited by potential ignition sources.
SECTION 1: Identification
1.1 Product identifierTrade name Volatile SolventOther means of identificationProduct code(s): 1811 Formula code: 02-090130
1.2 Relevant identified usesRelevant identified uses General use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency telephone numberChem-Tel 1.800.255.3924 (USA & Canada) 1.813.248.0585 (International)
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixtureClassification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
B.6 flammable liquid Cat. 4 (Flam. Liq. 4) H227A.10 aspiration hazard Cat. 1 (Asp. Tox. 1) H304Remarks
The most important adverse physicochemical, human health and environmental effects
2.2 Label elementsLabelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Signal word DANGERPictogramsGHS08
Hazard statementsH227 Combustible liquid.H304 May be fatal if swallowed and enters airways.
Precautionary statementsPrecautionary statements - preventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.Keep container tightly closed.Wear protective gloves/eye protection/face protection.
Precautionary statements - response
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This material is combustible, but will not ignite readily.
not relevant (mixture)
For full text of abbreviations: see SECTION 16.
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms per-sist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give any-thing by mouth.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Providefresh air.
Wash with plenty of soap and water.
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh waterfor at least 10 minutes, holding the eyelids apart.
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
Symptoms and effects are not known to date.
none
IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician.Do NOT induce vomiting.In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.
Precautionary statements - disposalDispose of contents/container to industrial combustion plant.
Hazardous ingredients for labelling C12-C14 isoalkanes2.3 Other hazards
SECTION 3: Composition/information on ingredients
3.1 Substances
3.2 Mixtures3.2.1
Name of substance Identifier Wt%
C12-C14 isoalkanes CAS No68551-19-9
100
SECTION 4: First-aid measures
4.1 Description of firs- aid measuresGeneral notes
Following inhalation
Following skin contact
Following eye contact
Following ingestion
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed
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water spray, alcohol resistant foam, BC-powder, carbon dioxide (CO2)
water jet
In case of insufficient ventilation and/or in use, may form flammable/explosive vapor-air mixture. Solvent va-pors are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated belowground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammablesubstances or mixtures.
nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround-ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting waterseparately. Fight fire with normal precautions from a reasonable distance.
Remove persons to safety.
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose it.
Covering of drains.
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand,universal binder).
Use of adsorbent materials.
Place in appropriate containers for disposal. Ventilate affected area.
Hazardous combustion products: see section 5. Personal precautions: see section 8. Incompatible materials:see section 10. Disposal considerations: see section 13.
SECTION 5: Fire-fighting measures
5.1 Extinguishing mediaSuitable extinguishing media
Unsuitable extinguishing media
5.2 Special hazards arising from the substance or mixture
Hazardous combustion products
5.3 Advice for firefighters
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel
For emergency responders
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning upAdvices on how to contain a spill
Advices on how to clean up a spill
Appropriate containment techniques
Other information relating to spills and releases
6.4 Reference to other sections
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Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - Nosmoking. Take precautionary measures against static discharge. Use only in well-ventilated areas. Due todanger of explosion, prevent leakage of vapours into cellars, flues and ditches. Ground/bond container and re-ceiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools.
Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits andshafts, are particularly prone to the presence of flammable substances or mixtures. Vapors are heavier thanair, spread along floors and form explosive mixtures with air. Vapors may form explosive mixtures with air.
Wash hands after use. Do not to eat, drink and smoke in work areas. Remove contaminated clothing and pro-tective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Neverplace chemicals in containers that are normally used for food or drink. Keep away from food, drink and animalfeedingstuffs.
Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool.Protect from sunlight.
Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flamesand other ignition sources. No smoking. Take precautionary measures against static discharge. Protect fromsunlight.
Observe compatible storage of chemicals.
Use local and general ventilation. Ground/bond container and receiving equipment.
See section 16 for a general overview.
No data available.
SECTION 7: Handling and storage
7.1 Precautions for safe handlingRecommendationsMeasures to prevent fire as well as aerosol and dust generation
Warning
Advice on general occupational hygiene
7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risks• Explosive atmospheres
• Flammability hazards
Incompatible substances or mixtures
Consideration of other adviceVentilation requirements
7.3 Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1 Control parametersNational limit valuesOccupational exposure limit values (Workplace Exposure Limits)Relevant DNELs/DMELs/PNECs and other threshold levels
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General ventilation.
Wear eye/face protection.
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Checkleak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them beforetaking off and air them well. For special purposes, it is recommended to check the resistance to chemicals ofthe protective gloves mentioned above together with the supplier of these gloves.
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom-mended. Wash hands thoroughly after handling.
In case of inadequate ventilation wear respiratory protection.
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and groundwater.
8.2 Exposure controlsAppropriate engineering controls
Individual protection measures (personal protective equipment)Eye/face protection
Skin protection• hand protection
• other protection measures
Respiratory protection
Environmental exposure controls
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical propertiesAppearancePhysical state liquidColor differentOdor characteristicOther physical and chemical parameterspH (value) not determinedMelting point/freezing point <-114 °C at 1 atmInitial boiling point and boiling range 189 °C at 1 atmFlash point 61.1 °C at 1 atmEvaporation rate not determinedFlammability (solid, gas) not relevant (fluid)Explosive limits not determinedVapor pressure not determinedDensity not determinedRelative density not determinedSolubility(ies) not determinedAuto-ignition temperature not determinedViscosity not determinedExplosive properties noneOxidizing properties none
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Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". The mixture containsreactive substance(s): risk of ignition
risk of ignition
See below "Conditions to avoid".
No known hazardous reactions.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge.
strong shocks
There is no additional information.
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill andheating are not known. Hazardous combustion products: see section 5.
Test data are not available for the complete mixture.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Shall not be classified as acutely toxic.
Shall not be classified as corrosive/irritant to skin.
Shall not be classified as seriously damaging to the eye or eye irritant.
Shall not be classified as a respiratory or skin sensitizer.
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.
SECTION 10: Stability and reactivity
10.1 Reactivity
• if heated
10.2 Chemical stability
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
Hints to prevent fire or explosion
Physical stresses which might result in a hazardous situation and have to be avoided
10.5 Incompatible materials
10.6 Hazardous decomposition products
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Classification procedure
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)Acute toxicity
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Summary of evaluation of the CMR properties
Carcinogenicity • National Toxicology Program (United States): none of the ingredients are listed • IARC Monographs none of the ingredients are listed
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Shall not be classified as a specific target organ toxicant.
May be fatal if swallowed and enters airways.
Shall not be classified as hazardous to the aquatic environment.
The relevant substances of the mixture are readily biodegradable.
Data are not available.
Data are not available.
Data are not available.
Data are not available.
Data are not available.
Solvent reclamation/regeneration.
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the sub-stance itself.
Please consider the relevant national or regional provisions. Waste shall be separated into the categories thatcan be handled separately by the local or national waste management facilities.
Specific target organ toxicity (STOT)
Aspiration hazard
SECTION 12: Ecological information
12.1 Toxicity
Biodegradation
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
SECTION 13: Disposal considerations
13.1 Waste treatment methodsWaste treatment-relevant information
Sewage disposal-relevant information
Waste treatment of containers/packages
Remarks
SECTION 14: Transport information
14.1 UN number (not subject to transport regulations)14.2 UN proper shipping name not relevant14.3 Transport hazard class(es)
Class -
14.4 Packing group not relevant14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerous
goods regulations)
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There is no additional information.
The cargo is not intended to be carried in bulk.
Hazardous Materials Identification System (American Coatings Association)
National Fire Protection Association: Standard System for the Identification of the Hazards of Materials forEmergency Response (United States)
14.6 Special precautions for user
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in questionNational regulations (United States)
Industry or sector specific available guidance(s)NPCA-HMIS® III
Category Rating Description
Chronic / None.
Health 0 No significant risk to health.
Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.
Physical hazard 0 Material that is normally stable, even under fire conditions, and will not react with water,polymerize, decompose, condense, or self-react. Non-explosive.
Personal protectiveequipment
-
NFPA® 704
Category Degree ofhazard
Description
Flammability 2 Material that must be moderately heated or exposed to relatively high ambient temperat-ures before ignition can occur.
Health 0 Material that, under emergency conditions, would offer no hazard beyond that of ordinarycombustible material.
Instability 0 Material that is normally stable, even under fire conditions.
Special hazard
Relevant European Union (EU) safety, health and environmental provisionsClassification according to GHS (1272/2008/EC, CLP)Hazard class Category Hazard class and categoryaspiration hazard 1 (Asp. Tox. 1)
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Physical and chemical properties: The classification is based on tested mixture.Health hazards/Environmental hazards: The method for classification of the mixture is based on ingredients ofthe mixture (additivity formula).
This information is based upon the present state of our knowledge. This SDS has been compiled and is solelyintended for this product.
SECTION 16: Other information, including date of preparation or last revision
Abbreviations and acronymsAbbr. Descriptions of used abbreviations
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
DMEL Derived Minimal Effect Level
DNEL Derived No-Effect Level
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
HMIS Hazardous Materials Identification System
IARC Mono-graphs
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant)
NFPA® 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emer-gency Response (United States)
NPCA-HMIS®III
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition
OSHA Occupational Safety and Health Administration (United States)
PBT Persistent, Bioaccumulative and Toxic
PNEC Predicted No-Effect Concentration
vPvB very Persistent and very Bioaccumulative
Key literature references and sources for data- OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200- 49 CFR § 172.101 Hazardous Materials Table (DOT)
Classification procedure
List of relevant phrases (code and full text as stated in chapter 2 and 3)Code Text
H227 combustible liquid
H304 may be fatal if swallowed and enters airways
Disclaimer
Safety Data Sheet Volatile SolventRevision date: 06/01/2015
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