Revision date: 14/11/2019 Revision: 6.1 Supersedes date: 10/12/2018
SAFETY DATA SHEETHYPOSAN
According to Regulation (EC) No 1907/2006, Annex II, as amended.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name HYPOSAN
Internal identification C020
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Detergent. Disinfectant.
Uses advised against Use only for intended applications.
1.3. Details of the supplier of the safety data sheet
Supplier ARROW SOLUTIONSRAWDON ROADMOIRASWADLINCOTEDERBYSHIREDE12 6DATEL: +44 (0)1283 221044FAX: +44 (0)1283 [email protected]
1.4. Emergency telephone number
Emergency telephone +44 (0) 777 8505 330 (24 hrs).
SECTION 2: Hazards identification
2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified
Health hazards Skin Irrit. 2 - H315 Eye Dam. 1 - H318
Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410
2.2. Label elements
Hazard pictograms
Signal word Danger
Hazard statements H315 Causes skin irritation.H318 Causes serious eye damage.H410 Very toxic to aquatic life with long lasting effects.
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Precautionary statements P273 Avoid release to the environment.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P280 Wear protective gloves, eye and face protection.P310 Immediately call a POISON CENTER/ doctor.P501 Dispose of contents/ container in accordance with national regulations.
UFI UFI: 5Q10-00GQ-U005-N1KF
Contains SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE
Biocide Labelling Contains active substance: Sodium Hypochlorite
Detergent labelling < 5% chlorine-based bleaching agents
2.3. Other hazards
This product does not contain any substances classified as PBT or vPvB.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE 1-5%
CAS number: 7681-52-9 EC number: 231-668-3 REACH registration number: 01-2119488154-34-XXXX
M factor (Acute) = 10 M factor (Chronic) = 1
ClassificationMet. Corr. 1 - H290Skin Corr. 1B - H314Eye Dam. 1 - H318Aquatic Acute 1 - H400Aquatic Chronic 1 - H410
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information Show this Safety Data Sheet to the medical personnel. Move affected person to fresh air andkeep warm and at rest in a position comfortable for breathing. Get medical attention if anydiscomfort continues. If medical advice is needed, have product container or label at hand.
Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable forbreathing.
Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Get medical attentionimmediately.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if any discomfort continues.
Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wideapart. Continue to rinse. Get medical attention immediately.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation Coughing, chest tightness, feeling of chest pressure.
Ingestion Gastrointestinal symptoms, including upset stomach.
Skin contact Causes skin irritation.
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Eye contact Causes serious eye damage.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
Hazardous combustionproducts
Thermal decomposition or combustion products may include the following substances:Chlorine. Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen chloride (HCl).
5.3. Advice for firefighters
Protective actions duringfirefighting
No specific firefighting precautions known.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,clothing or apron, as appropriate. Provide adequate ventilation. Do not touch or walk intospilled material. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapours. Avoidcontact with contaminated tools and objects. Do not handle broken packages withoutprotective equipment. Take care as floors and other surfaces may become slippery. Washthoroughly after dealing with a spillage.
6.2. Environmental precautions
Environmental precautions Do not discharge into drains or watercourses or onto the ground.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,clothing or apron, as appropriate. Absorb spillage with inert, damp, non-combustible material.Collect and place in suitable waste disposal containers and seal securely. Containers withcollected spillage must be properly labelled with correct contents and hazard symbol. Flushcontaminated area with plenty of water. Wash thoroughly after dealing with a spillage.
6.4. Reference to other sections
Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Usage precautions Use biocides safely. Always read the label and product information before use. Provideadequate ventilation. Do not mix with acid. Wear protective gloves, eye and face protection.Avoid contact with skin, eyes and clothing. Avoid inhalation of vapours. Avoid spilling. Avoidthe formation of mists. Avoid contact with contaminated tools and objects. Avoid release to theenvironment. Contact with acids liberates toxic gas. Protect from freezing and direct sunlight.Do not close container tightly, due to the risk of excessive pressure build-up. Do not keep thecontainer sealed. Do not eat, drink or smoke when using this product. Do not reuse emptycontainers. Do not handle broken packages without protective equipment. Wash skinthoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Store at temperatures between 5°C and 25°C. Protect from sunlight.
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Storage class Acid-reactive storage.
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE (CAS: 7681-52-9)
DNEL Consumer - Oral; Long term systemic effects: 0.26 mg/kg/dayProfessional - Inhalation; Short term systemic effects: 3.1 mg/m³Professional - Inhalation; local effects: 3.1 mg/m³Consumer - Inhalation; Long term local effects: 1.55 mg/m³Professional - Inhalation; Long term local effects: 1.55 mg/m³Consumer - Inhalation; Long term systemic effects: 1.55 mg/m³Professional - Inhalation; Long term systemic effects: 1.55 mg/m³
PNEC - Fresh water; 0.00021 mg/l- Intermittent release; 0.00026 mg/l- marine water; 0.000042 mg/l- STP; 0.03 mg/l
8.2. Exposure controls
Protective equipment
Appropriate engineeringcontrols
Provide adequate ventilation. As this product contains ingredients with exposure limits,process enclosures, local exhaust ventilation or other engineering controls should be used tokeep worker exposure below any statutory or recommended limits, if use generates dust,fumes, gas, vapour or mist.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. The following protection should be worn: Chemical splash goggles.Personal protective equipment for eye and face protection should comply with EuropeanStandard EN166.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is possible. To protect hands from chemicals, glovesshould comply with European Standard EN374. The selected gloves should have abreakthrough time of at least 4 hours. The breakthrough time for any glove material may bedifferent for different glove manufacturers. Considering the data specified by the glovemanufacturer, check during use that the gloves are retaining their protective properties andchange them as soon as any deterioration is detected. Protective gloves should have aminimum thickness of 0.5 mm. Glove thickness is not necessarily a good measure of gloveresistance as the permeation rate will depend on the exact glove composition. The choice ofprotective gloves depends upon the chemicals being handled, and the conditions of work anduse. Repeated exposure to chemicals will degrade the ability of the glove to provideresistance to chemicals. Specific work environments and material handling practices mayvary, therefore safety procedures should be developed for each intended application. Glovesmade from the following material may provide suitable chemical protection: Butyl rubber.Chloroprene rubber. Polyvinyl chloride (PVC).
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Other skin and bodyprotection
Provide eyewash station.
Hygiene measures Wash contaminated clothing before reuse. Wash hands after handling.
Respiratory protection No specific requirements are anticipated under normal conditions of use. Respiratoryprotection complying with an approved standard should be worn if a risk assessment indicatesinhalation of contaminants is possible. Use approved respirator if air contamination is abovean acceptable level. Respirator selection must be based on exposure levels, the hazards ofthe product and the safe working limits of the selected respirator. Ensure all respiratoryprotective equipment is suitable for its intended use and is ‘CE’-marked. Respiratoryprotection must be used if the airborne contamination exceeds the recommendedoccupational exposure limit. Half mask and quarter mask respirators with replaceable filtercartridges should comply with European Standard EN140. Gas and combination filtercartridges should comply with European Standard EN14387. Particulate filters should complywith European Standard EN143. Disposable filtering half mask respirators should comply withEuropean Standard EN149 or EN405. Check that the respirator fits tightly and the filter ischanged regularly. Wear a respirator fitted with the following cartridge: Combination filter, typeB+E/P3.
Environmental exposurecontrols
Store in a demarcated bunded area to prevent release to drains and/or watercourses. The riskmanagement measures that adequately control exposure of the environment are set out in theexposure scenarios in the annex to this Safety Data Sheet.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Liquid.
Colour Green-yellow.
Odour Chlorine.
Odour threshold Not determined.
pH pH (concentrated solution): 13.0
Melting point Not determined.
Initial boiling point and range 102°C @ 760 mm Hg
Flash point Not relevant.
Evaporation rate Not determined.
Flammability (solid, gas) Not applicable.
Upper/lower flammability orexplosive limits
Not determined.
Other flammability Not relevant.
Vapour pressure Not determined.
Relative density 1.07 @ 20°C
Solubility(ies) Soluble in water.
Partition coefficient Not determined.
Auto-ignition temperature Not determined.
Decomposition Temperature Not determined.
Viscosity Not determined.
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Explosive properties There are no chemical groups present in the product that are associated with explosiveproperties.
Oxidising properties There are no chemical groups present in the product that are associated with oxidisingproperties.
Comments Information declared as "Not available" or "Not applicable" is not considered to be relevant tothe implementation of the proper control measures.
9.2. Other information
Other information Not determined.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity Reactions with the following materials may generate heat: Acids. Generates toxic gas incontact with acid.
10.2. Chemical stability
Stability Avoid the following conditions: Avoid contact with acids.
10.3. Possibility of hazardous reactions
Possibility of hazardousreactions
Not determined.
10.4. Conditions to avoid
Conditions to avoid Avoid contact with the following materials: Strong mineral acids.
10.5. Incompatible materials
Materials to avoid Strong acids. Amines.
10.6. Hazardous decomposition products
Hazardous decompositionproducts
Thermal decomposition or combustion products may include the following substances:Chlorine. Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen chloride (HCl).
SECTION 11: Toxicological information
11.1. Information on toxicological effectsAcute toxicity - oralNotes (oral LD₅₀) Based on available data the classification criteria are not met.
Acute toxicity - dermalNotes (dermal LD₅₀) Based on available data the classification criteria are not met.
Acute toxicity - inhalationNotes (inhalation LC₅₀) Based on available data the classification criteria are not met.
Skin corrosion/irritationSkin corrosion/irritation Causes skin irritation.
Serious eye damage/irritationSerious eye damage/irritation Causes serious eye damage.
Respiratory sensitisationRespiratory sensitisation Based on available data the classification criteria are not met.
Skin sensitisationSkin sensitisation Based on available data the classification criteria are not met.
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Germ cell mutagenicityGenotoxicity - in vitro Based on available data the classification criteria are not met.
CarcinogenicityCarcinogenicity Based on available data the classification criteria are not met.
Reproductive toxicityReproductive toxicity - fertility Based on available data the classification criteria are not met.
Specific target organ toxicity - single exposureSTOT - single exposure Based on available data the classification criteria are not met.
Specific target organ toxicity - repeated exposureSTOT - repeated exposure Based on available data the classification criteria are not met.
Aspiration hazardAspiration hazard Not anticipated to present an aspiration hazard, based on chemical structure.
Inhalation Coughing, chest tightness, feeling of chest pressure.
Ingestion Gastrointestinal symptoms, including upset stomach.
Skin contact Causes skin irritation.
Eye contact Causes serious eye damage.
Acute and chronic healthhazards
Irritating to skin. Irritation of eyes and mucous membranes.
Route of exposure Skin and/or eye contact
Target organs Skin Eyes
Medical symptoms Skin irritation. Irritation of eyes and mucous membranes. Coughing, chest tightness, feeling ofchest pressure.
Medical considerations Skin disorders and allergies.
Toxicological information on ingredients.
SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE
Acute toxicity - dermal
Notes (dermal LD₅₀)
Skin sensitisation
Skin sensitisation - Guinea pig: Not sensitising.
SECTION 12: Ecological information
Ecotoxicity Very toxic to aquatic life with long lasting effects.
12.1. ToxicityAcute aquatic toxicityAcute toxicity - fish Not determined.
Chronic aquatic toxicityChronic toxicity - fish early lifestage
Not determined.
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Ecological information on ingredients.
SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE
Acute aquatic toxicity
LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1
M factor (Acute) 10
Acute toxicity - fish LC50, 96 hours: 0.22 - 0.62 mg/l, Pimephales promelas (Fat-head Minnow)LC₅₀, 96 hours: 0.1 <L(E)C50 <=1.0 mg/l, Fish
Acute toxicity - aquaticinvertebrates
EC₅₀, 96 hours: 2.1 mg/l, Daphnia magna
Acute toxicity - aquaticplants
EC₅₀, : 28 mg/l, Scenedesmus subspicatus
Chronic aquatic toxicity
M factor (Chronic) 1
12.2. Persistence and degradability
Persistence and degradability The product is expected to be biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.
Partition coefficient Not determined.
12.4. Mobility in soil
Mobility Soluble in water.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvBassessment
This product does not contain any substances classified as PBT or vPvB.
12.6. Other adverse effects
Other adverse effects Not determined.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal methods Disposal of this product, process solutions, residues and by-products should at all timescomply with the requirements of environmental protection and waste disposal legislation andany local authority requirements.
SECTION 14: Transport information
Special Provisions note
14.1. UN number
UN No. (ADR/RID) 3082
UN No. (IMDG) 3082
UN No. (ICAO) 3082
14.2. UN proper shipping name
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Proper shipping name(ADR/RID)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (sodium hypochlorite)
Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (sodium hypochlorite)
Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (sodium hypochlorite)
14.3. Transport hazard class(es)
ADR/RID class 9
ADR/RID classification code M6
ADR/RID label 9
IMDG class 9
ICAO class/division 9
Transport labels
14.4. Packing group
ADR/RID packing group III
IMDG packing group III
ICAO packing group III
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
14.6. Special precautions for user
EmS F-A, S-F
ADR transport category 3
Emergency Action Code •3Z
Hazard Identification Number(ADR/RID)
90
Tunnel restriction code (-)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code
Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
UFI UFI: 5Q10-00GQ-U005-N1KF
National regulations Control of Substances Hazardous to Health Regulations 2002 (as amended).
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EU legislation Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March2004 on detergents (as amended).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16December 2008 on classification, labelling and packaging of substances and mixtures (asamended).Commission Regulation (EU) No 2015/830 of 28 May 2015.
Guidance Workplace Exposure Limits EH40.
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
SECTION 16: Other information
Abbreviations and acronymsused in the safety data sheet
ATE: Acute Toxicity Estimate.ADR: European Agreement concerning the International Carriage of Dangerous Goods byRoad.CAS: Chemical Abstracts Service.DNEL: Derived No Effect Level.EC₅₀: 50% of maximal Effective Concentration.LC₅₀: Lethal Concentration to 50 % of a test population.LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).IATA: International Air Transport Association.IMDG: International Maritime Dangerous Goods.PBT: Persistent, Bioaccumulative and Toxic substance.PNEC: Predicted No Effect Concentration.REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation(EC) No 1907/2006.UN: United Nations.vPvB: Very Persistent and Very Bioaccumulative.
Classification abbreviationsand acronyms
Aquatic Acute = Hazardous to the aquatic environment (acute)Aquatic Chronic = Hazardous to the aquatic environment (chronic)Eye Dam. = Serious eye damageMet. Corr. = Corrosive to metalsSkin Corr. = Skin corrosionSkin Irrit. = Skin irritationSTOT SE = Specific target organ toxicity-single exposure
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision date 14/11/2019
Revision 6.1
Supersedes date 10/12/2018
SDS number 29396
Hazard statements in full H290 May be corrosive to metals.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H318 Causes serious eye damage.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.
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This information relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurateand reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability orcompleteness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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Exposure scenarioHYPOSAN - Use in Cleaning Agents
Identification
Product name HYPOSAN
REACH registration number 01-2119488154-34-XXXX
CAS number 7681-52-9
EC number 231-668-3
EU index number 017-011-00-1
Revision date 22/02/2018
Version number 1.0
Supplier ARROW SOLUTIONSRAWDON ROADMOIRASWADLINCOTEDERBYSHIREDE12 6DATEL: +44 (0)1283 221044FAX: +44 (0)1283 [email protected]
1. Title of exposure scenario
Main title HYPOSAN - Use in Cleaning Agents
Process scope Covers the use as a component of cleaning products, including pouring/unloading from drumsor containers and exposures during mixing/diluting in the preparatory phase and cleaningactivities (including spraying, brushing, dipping, wiping, automated and by hand).
Main sector SU22 Professional uses
Sector of use SU22 Professional uses
Environment
Cleaning Liquid cleaners Spray cleaners Surface cleaning
Environmental releasecategory
ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,indoor)ERC8b Widespread use of reactive processing aid (no inclusion into or onto article, indoor)ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,outdoor)ERC8e Widespread use of reactive processing aid (no inclusion into or onto article, outdoor)
SPERC AISE SPERC 8a.1.a.v1
Worker
Cleaning Liquid cleaners Spray cleaners Surface cleaning
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Process category PROC5 Mixing or blending in batch processesPROC9 Transfer of substance or mixture into small containers (dedicated filling line, includingweighing)PROC10 Roller application or brushingPROC11 Non industrial sprayingPROC13 Treatment of articles by dipping and pouring.PROC15 Use as laboratory reagent.
2. Conditions of use affecting exposure (Industrial - Environment 1)
Control of environmental exposure
Environmental releasecategory
ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,indoor)ERC8b Widespread use of reactive processing aid (no inclusion into or onto article, indoor)ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,outdoor)ERC8e Widespread use of reactive processing aid (no inclusion into or onto article, outdoor)
SPERC AISE SPERC 8a.1.a.v1
Product characteristics
Physical state Liquid
Concentration details Concentration of substance in product: 0-10%
Amounts used
Annual amount used in the EU: 999999 tonnes
Frequency and duration of use
Application duration: 360 days
Other given operational conditions affecting environmental exposure
Emission factor - air Emission factor to air: N/A
Emission factor - soil Not applicable - no direct release to soil.
Environmental factors not influenced by risk management measures
Dilution Receiving surface water flow: 18,000 m³/day
Other factors Professional and Consumer product use leading to disposal via the wastewater.
Risk management measures
Good practice Clear up spills immediately and dispose of waste safely. Good housekeeping, e.g. inspectionprocedures, will ensure that there are no leaks to soil.
Technical measures Bund storage facilities to prevent soil and water pollution in the event of spillage.
Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Air emission controls are not applicable as there is no direct release to air.
Water Risk from environmental exposure is driven by fresh water. No discharge of substance intowaste water. Onsite wastewater treatment required.
Soil Not applicable - no direct release to soil.
Conditions and measures related to external treatment of waste for disposal
Waste treatment All contaminated waste water must be processed in an industrial or municipal wastewatertreatment plant that incorporates both primary and secondary treatments.
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Disposal method Product residual disposal complies with applicable regulations.
2. Conditions of use affecting exposure (Workers - Health 1)
Control of workers exposure
Process category PROC11 Non industrial spraying
Product characteristics
Physical state Liquid
Vapour pressure Vapour pressure > 10 kPa at STP.
Concentration details Covers concentrations up to 0 - 0.05 %.
Amounts used
Amount per use: 0.005 kg
Frequency and duration of use
Application duration: 120 minutesCovers daily exposure up to 1hour
Other given operational conditions affecting workers exposure
Setting Indoor/outdoor use.
Temperature Assumes activities are at ambient temperature (unless stated differently).
Ventilation rate Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).Open windows during application to ensure natural ventilation.
Organisational measures to prevent/limit releases, dispersion and exposure
Organisational measures Ensure control measures are regularly inspected and maintained.
Risk management measures
General ventilation.Wear suitable gloves (tested to EN374) and eye protection.Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Weargloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spillsas soon as they occur. Wash off any skin contamination immediately. Provide basic employeetraining to prevent/minimise exposures and to report any skin problems that may develop.
2. Conditions of use affecting exposure (Workers - Health 2)
Control of workers exposure
Process category PROC5 Mixing or blending in batch processesPROC9 Transfer of substance or mixture into small containers (dedicated filling line, includingweighing)PROC10 Roller application or brushingPROC11 Non industrial spraying
Product characteristics
Physical state Liquid
Vapour pressure Vapour pressure > 10 kPa at STP.
Concentration details Covers concentrations up to 0-10 %.
Frequency and duration of use
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Application duration: 8 hoursCovers weekly exposure up to 5days
Other given operational conditions affecting workers exposure
Setting Indoor/outdoor use.
Temperature Operation is carried out at elevated temperature (> 20°C above ambient temperature).
Technical conditions and measures at process level (source) to prevent release
Technical protective measures Minimise exposure by partial enclosure of the operation or equipment and provide extractventilation at openings. Partial personal enclosure with ventilation.
Organisational measures to prevent/limit releases, dispersion and exposure
Organisational measures Ensure control measures are regularly inspected and maintained. Ensure operatives aretrained to minimise exposures. Other protection measures such as segregation of activity,minimisation of personnel, respiratory protection, impervious suits and face shields shouldalso be considered for high dispersion activities which are likely to lead to substantial aerosolor vapour release, e.g. spraying.
Risk management measures
General ventilation.Gloves should comply with the requirements of EN 374.Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Weargloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spillsas soon as they occur. Wash off any skin contamination immediately. Provide basic employeetraining to prevent/minimise exposures and to report any skin problems that may develop.
3. Exposure estimation (Environment 1)
Environmental releasecategory
ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,indoor)ERC8b Widespread use of reactive processing aid (no inclusion into or onto article, indoor)ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,outdoor)ERC8e Widespread use of reactive processing aid (no inclusion into or onto article, outdoor)
Sector of use SU22 Professional uses
Assessment method EASE v2.0
3. Exposure estimation (Health 1)
Process category PROC11 Non industrial spraying
Assessment method EASE v2.0
Exposure Worker - inhalation, long-term - systemic: Exposure 0.0017 mg/m³, DNEL 1.55 mg/m³, RCR0.0011
4. Guidance to check compliance with the exposure scenario (Health 1)
Guidance is based on assumed operating conditions which may not be applicable to all sites,thus, scaling may be necessary to define appropriate site-specific risk managementmeasures.
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