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(1/5) SAFETY DATA SHEET MSDS: 2013076010US Date Prepared: 2014/1/6 Date Revised: 1. Identification of the substance/mixture and of the company/undertaking 2. Composition/information on ingredients 30-40 25-45 5-25 1-15 1-15 3. Hazards identification Colored liquid. Slight characteristic odor. POTENTIAL HEALTH EFFECTS : : : : : 4. First-aid measures No identified health effects. Chronic Effects / Carcinogenicity : None of the components in this material is listed by IARC, NTP or ACGIH as a carcinogen. EMERGENCY OVERVIEW Eye Effects May cause eye and mucous membrane irritation. Skin Effects May cause slight skin irritation. Ingestion Effects May be harmful if swallowed. Inhalation Effects CAS# 7732-18-5 107-21-1 56-81-5 Water Ethylene glycol Glycerin Surfactant No exposure expected under normal conditions. Large amount of vapor or mist if inhaled, move victim to fresh air immediately. If symptoms occur, get medical attention. Wash with water and mild soap for 15 minutes. If symptoms occur, get medical attention. Immediately flush eyes with plenty of water for 15 minutes. Get medical attention immediately. Wash out mouth with water. Drink one or two glasses of water. Get medical attention immediately. ONLY induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. Mixture Concentr ationwt. % Ingredient Name Dye Product Name: Disperse Dye Ink Yellow Ingredients and Concentration Product Name: Identification of the supplier: Inhalation: Skin Contact: Eye Contact: Ingestion: 2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN Address: Charge section: (TEL:+81-42-589-3739,FAX:+81-42-589-3868) May be harmful if swallowed. Disperse Dye Ink Yellow Konica Minolta, Inc. Substance/Mixture: --- ---
Transcript
Page 1: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(1/5)

SAFETY DATA SHEETMSDS: 2013076010US

Date Prepared: 2014/1/6Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

30-4025-455-251-151-15

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

No identified health effects.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.Ingestion Effects May be harmful if swallowed.Inhalation Effects

CAS#

7732-18-5107-21-156-81-5

WaterEthylene glycolGlycerinSurfactant

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Mixture

Concentrationwt.

%Ingredient Name

Dye

Product Name: Disperse Dye Ink Yellow

Ingredients and Concentration

Product Name:Identification of thesupplier:

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

May be harmful if swallowed.

Disperse Dye Ink YellowKonica Minolta, Inc.

Substance/Mixture:

------

Page 2: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(2/5)

SAFETY DATA SHEETMSDS: 2013076010US

Date Prepared: 2014/1/6Date Revised:

Product Name: Disperse Dye Ink Yellow

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).

No information.

Storage Conditions:

Safety adequatecontainer materials:

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.

Use with adequate ventilation.

No information.No information.

Wear personal protective equipment(See Section 8).

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:Methods and materials forcontainment and cleaning up:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

Handling

Storage

Page 3: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(3/5)

SAFETY DATA SHEETMSDS: 2013076010US

Date Prepared: 2014/1/6Date Revised:

Product Name: Disperse Dye Ink Yellow

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

No data.

Form: LiquidColor: Colored

No data.

Flash point:

Dye

Ethylene glycol

Glycerin

Surfactant

Physical state: Liquid

Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

Product

Odor: Slight characteristic odorpH: No data.Melting point/freezingpoint:

No data.

Initial boiling pointand boiling range:

NoneAuto-ignitiontemperature:

No data.

Upper/lower flammabilityor explosive limits:

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.Hand protection:

Ingredient NameACGIH OSHA-PEL

Vapour pressure: No data.

Evaporation rate: No data.Vapour density: No data.

No data.

Specific Gravity: No data.Solubility: water:Completely soluble.

Decompositiontemperature:

Control parameters

Partition coefficient:n-octanol/water:

No data.

Personal Protective Equipment

Page 4: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(4/5)

SAFETY DATA SHEETMSDS: 2013076010US

Date Prepared: 2014/1/6Date Revised:

Product Name: Disperse Dye Ink Yellow

10. Stability and reactivity

11. Toxicological information

12. Ecological information

Persistence and degradability: Readily biodegradable

Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna] Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

IngredientEthylene glycol

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]

Mutagenicity: Ames Test:Negative

ProductNo Data

Skin corrosion/irritation: None P.I.I=0 [rabbit]Serious eye damage/irritation: Minimal [rabbit]

Carcinogenicity: IARC:UnlistedDye

Acute toxicity (oral): LD50:> 5000 mg/kg[rat]

Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

SurfactantMutagenicity: Ames Test:Negative

Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Minimal [rabbit]

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse],

LD50: 27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]

Serious eye damage/irritation: Mild [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]Skin corrosion/irritation: Mild [rabbit]

Mutagenicity: Ames Test:Negative

IngredientEthylene glycol

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Skin sensitization: None (Data of similar product)

Carbon monoxide, Carbon dioxide

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

Stable.No Information.

No Information.Oxidizers

Page 5: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(5/5)

SAFETY DATA SHEETMSDS: 2013076010US

Date Prepared: 2014/1/6Date Revised:

Product Name: Disperse Dye Ink Yellow

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

UN Class ---

------

---

313 ReportableIngredients:

Ethylene glycol

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their owninvestigation to determine the suitability of the information for theirparticular purposes.

None.

311/312 HazardCategories:

None.

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

This product is NOT considered hazardous under this standard.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000 lb(2270 kg)

Persistence and degradability: Readily biodegradable

When disposing of the waste or recovered material, consult federal, state and/or localregulations for the proper disposal method.

Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish] Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]

GlycerinEcotoxicity

Page 6: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(1/5)

SAFETY DATA SHEETMSDS: 2013076020US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

30-4025-455-251-151-15

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

Ingestion: Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation: No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Eye Contact: Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Skin Contact: Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

Ingestion Effects May be harmful if swallowed.Inhalation Effects No identified health effects.

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.

May be harmful if swallowed.

Dye ---

Glycerin 56-81-5Surfactant ---

Water 7732-18-5Ethylene glycol 107-21-1

Substance/Mixture: MixtureIngredients and Concentration

Ingredient NameConcentrationwt.

%CAS#

Product Name: Disperse Dye Ink Light Yellow

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

Product Name:Identification of thesupplier:

Disperse Dye Ink Light YellowKonica Minolta, Inc.

Page 7: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(2/5)

SAFETY DATA SHEETMSDS: 2013076020US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Yellow

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).

No information.

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Storage Conditions:

Safety adequatecontainer materials:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

No information.No information.

Wear personal protective equipment(See Section 8).

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:Methods and materials forcontainment and cleaning up:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

Handling

Storage

Page 8: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(3/5)

SAFETY DATA SHEETMSDS: 2013076020US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Yellow

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

Solubility:Partition coefficient:n-octanol/water:Decompositiontemperature:

No data.

Flash point:

pH:Melting point/freezingpoint:Initial boiling pointand boiling range:

LiquidLiquid

ProductPhysical state:Form:

No data.

Slight characteristic odorColor:Odor:

Ingredient NameACGIH OSHA-PEL

Control parameters

Upper/lower flammabilityor explosive limits:

Vapour density:Evaporation rate:Specific Gravity:

Vapour pressure:

Auto-ignitiontemperature:

No data.

Colored

Personal Protective Equipment

Ethylene glycol

Glycerin

Surfactant

Dye

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.

No data.

Hand protection:Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

No data.

No data.

No data.

None

No data.

No data.

water:Completely soluble.

No data.No data.

Page 9: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(4/5)

SAFETY DATA SHEETMSDS: 2013076020US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Yellow

10. Stability and reactivity

11. Toxicological information

12. Ecological information

Persistence and degradability: Readily biodegradable

Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna] Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

IngredientEthylene glycol

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]

Mutagenicity: Ames Test:Negative

ProductNo Data

Skin corrosion/irritation: None P.I.I=0 [rabbit]Serious eye damage/irritation: Minimal [rabbit]

Carcinogenicity: IARC:UnlistedDye

Acute toxicity (oral): LD50:> 5000 mg/kg[rat]

Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

SurfactantMutagenicity: Ames Test:Negative

Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Minimal [rabbit]

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse],

LD50: 27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]

Serious eye damage/irritation: Mild [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]Skin corrosion/irritation: Mild [rabbit]

Mutagenicity: Ames Test:Negative

IngredientEthylene glycol

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Skin sensitization: None (Data of similar product)

OxidizersCarbon monoxide, Carbon dioxide

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

Stable.No Information.

No Information.

Page 10: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(5/5)

SAFETY DATA SHEETMSDS: 2013076020US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Yellow

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

This product is NOT considered hazardous under this standard.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000lb(2270 kg)

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

None.

Persistence and degradability: Readily biodegradable

When disposing of the waste or recovered material, consult federal, state and/or localregulations for the proper disposal method.

UN Class

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their own investigationto determine the suitability of the information for their particularpurposes.

311/312 HazardCategories:

None.

313 ReportableIngredients:

Ethylene glycol

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

---

------

---

Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish] Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]

GlycerinEcotoxicity

Page 11: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(1/5)

SAFETY DATA SHEETMSDS: 2013076030US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

30-4020-255-251-151-15

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

Disperse Dye Ink MagentaKonica Minolta, Inc.

Product Name: Disperse Dye Ink Magenta

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

Product Name:Identification of thesupplier:

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

Substance/Mixture: MixtureIngredients and Concentration

Ingredient NameConcentrationwt.

%CAS#

Water 7732-18-5Ethylene glycol 107-21-1Glycerin 56-81-5Surfactant ---Dye ---

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.

May be harmful if swallowed.

Skin Effects May cause slight skin irritation.Ingestion Effects May be harmful if swallowed.Inhalation Effects No identified health effects.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

Page 12: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(2/5)

SAFETY DATA SHEETMSDS: 2013076030US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Magenta

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Handling

Storage

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:Methods and materials forcontainment and cleaning up:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

No information.No information.

Wear personal protective equipment(See Section 8).

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).No information.

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Storage Conditions:

Safety adequatecontainer materials:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

Page 13: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(3/5)

SAFETY DATA SHEETMSDS: 2013076030US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Magenta

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

Control parameters

Ethylene glycol

Glycerin

Surfactant

Ingredient NameACGIH OSHA-PEL

Dye

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.Hand protection:

Personal Protective Equipment

Color: Colored

Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

ProductPhysical state: LiquidForm: Liquid

Odor: Slight characteristic odorpH: No data.Melting point/freezingpoint:

No data.

Initial boiling pointand boiling range:

No data.

Flash point: NoneAuto-ignitiontemperature:

No data.

Upper/lower flammabilityor explosive limits:

No data.

Vapour pressure: No data.Vapour density: No data.Evaporation rate: No data.Specific Gravity: No data.Solubility: water:Completely soluble.Partition coefficient:n-octanol/water:

No data.

Decompositiontemperature:

No data.

Page 14: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(4/5)

SAFETY DATA SHEETMSDS: 2013076030US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Magenta

10. Stability and reactivity

11. Toxicological information

12. Ecological information

Carbon monoxide, Carbon dioxide

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

Stable.No Information.

No Information.Oxidizers

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Mutagenicity: Ames Test:Negative

IngredientEthylene glycol

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Mild [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse], LD50:

27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Minimal [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

SurfactantAcute toxicity (oral): LD50:> 40000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

DyeMutagenicity: Ames Test:Negative

ProductNo Data

IngredientEthylene glycol

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish] Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna] Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

Persistence and degradability: Readily biodegradable

Page 15: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(5/5)

SAFETY DATA SHEETMSDS: 2013076030US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Magenta

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

GlycerinEcotoxicity Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish]

When disposing of the waste, containers or recovered material, consult federal, stateand/or local regulations for the proper disposal method.

Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]Persistence and degradability: Readily biodegradable

None.

311/312 HazardCategories:

None.

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

This product is NOT considered hazardous under this standard.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000lb(2270 kg)

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their own investigationto determine the suitability of the information for their particularpurposes.

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

UN Class ---

------

---

313 ReportableIngredients:

Ethylene glycol

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

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(1/5)

SAFETY DATA SHEETMSDS: 2013076040US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

30-4020-255-251-151-15

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

Disperse Dye Ink Light MagentaKonica Minolta, Inc.

Product Name: Disperse Dye Ink Light Magenta

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

Product Name:Identification of thesupplier:

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

Substance/Mixture: MixtureIngredients and Concentration

Ingredient NameConcentrationwt.

%CAS#

Water 7732-18-5Ethylene glycol 107-21-1Glycerin 56-81-5Surfactant ---Dye ---

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.

May be harmful if swallowed.

Ingestion Effects May be harmful if swallowed.Inhalation Effects No identified health effects.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

Page 17: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(2/5)

SAFETY DATA SHEETMSDS: 2013076040US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Magenta

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Handling

Storage

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:Methods and materials forcontainment and cleaning up:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

No information.No information.

Wear personal protective equipment(See Section 8).

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).No information.

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Storage Conditions:

Safety adequatecontainer materials:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

Page 18: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(3/5)

SAFETY DATA SHEETMSDS: 2013076040US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Magenta

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

Control parameters

Specific Gravity: No data.

Personal Protective Equipment

Product

Evaporation rate: No data.

Vapour pressure: No data.Vapour density: No data.

Auto-ignitiontemperature:

No data.

Upper/lower flammabilityor explosive limits:

No data.

Initial boiling pointand boiling range:

No data.

Flash point: None

pH: No data.Melting point/freezingpoint:

No data.

Ethylene glycol

Glycerin

Surfactant

Ingredient NameACGIH OSHA-PEL

Odor: Slight characteristic odor

Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

Form: LiquidColor: Colored

Dye

Physical state: Liquid

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.Hand protection:

Solubility: water:Completely soluble.Partition coefficient:n-octanol/water:

No data.

Decompositiontemperature:

No data.

Page 19: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(4/5)

SAFETY DATA SHEETMSDS: 2013076040US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Magenta

10. Stability and reactivity

11. Toxicological information

12. Ecological information

Carbon monoxide, Carbon dioxide

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

Stable.No Information.

No Information.Oxidizers

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Mutagenicity: Ames Test:Negative

IngredientEthylene glycol

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Mild [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse], LD50:

27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Minimal [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

SurfactantAcute toxicity (oral): LD50:> 40000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

ProductNo Data

IngredientEthylene glycol

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish] Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna] Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

Persistence and degradability: Readily biodegradable

Page 20: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(5/5)

SAFETY DATA SHEETMSDS: 2013076040US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Magenta

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

Persistence and degradability: Readily biodegradable

GlycerinEcotoxicity Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish]

This product is NOT considered hazardous under this standard.

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

None.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000lb(2270 kg)

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their own investigationto determine the suitability of the information for their particularpurposes.

311/312 HazardCategories:

None.

313 ReportableIngredients:

Ethylene glycol

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

UN Class ---

------

---

When disposing of the waste or recovered material, consult federal, state and/or localregulations for the proper disposal method.

Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]

Page 21: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(1/5)

SAFETY DATA SHEETMSDS: 2013076050US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

30-4025-455-251-151-15

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

Ingestion Effects May be harmful if swallowed.Inhalation Effects No identified health effects.

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.

May be harmful if swallowed.

Dye ---

Glycerin 56-81-5Surfactant ---

Water 7732-18-5Ethylene glycol 107-21-1

Substance/Mixture: MixtureIngredients and Concentration

Ingredient NameConcentrationwt.

%CAS#

Eye Contact:

Ingestion:

Product Name: Disperse Dye Ink Cyan

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation:

Skin Contact:

Product Name:Identification of thesupplier:

Disperse Dye Ink CyanKonica Minolta, Inc.

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

Page 22: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(2/5)

SAFETY DATA SHEETMSDS: 2013076050US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Cyan

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).No information.

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Storage Conditions:

Safety adequatecontainer materials:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

No information.No information.

Wear personal protective equipment(See Section 8).

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Methods and materials forcontainment and cleaning up:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:

Handling

Storage

Page 23: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(3/5)

SAFETY DATA SHEETMSDS: 2013076050US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Cyan

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

No data.

Physical state: Liquid

Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

Not required under normal conditions.Respiratory Protection:

Form: LiquidColor: ColoredOdor: Slight characteristic odorpH:

Impervious gloves should be worn.Hand protection:

Ethylene glycol

Glycerin

Surfactant

Dye

Personal Protective Equipment

Ingredient NameACGIH OSHA-PEL

Control parameters

No data.Melting point/freezingpoint:

No data.

Initial boiling pointand boiling range:

No data.

Flash point: NoneAuto-ignitiontemperature:

No data.

No data.

Specific Gravity: No data.Solubility:

Product

water:Completely soluble.

Vapour density: No data.Evaporation rate: No data.

Upper/lower flammabilityor explosive limits:

No data.

Vapour pressure: No data.

Decompositiontemperature:

Partition coefficient:n-octanol/water:

Page 24: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(4/5)

SAFETY DATA SHEETMSDS: 2013076050US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Cyan

10. Stability and reactivity

11. Toxicological information

12. Ecological information

Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

Persistence and degradability: Readily biodegradable

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish] Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]

ProductNo Data

IngredientEthylene glycol

Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

DyeAcute toxicity (oral): LD50: 5000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]

Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

SurfactantAcute toxicity (oral): LD50:> 40000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]

Serious eye damage/irritation: Minimal [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]Skin corrosion/irritation: Mild [rabbit]

Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse], LD50:

27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]

Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Mild [rabbit]

IngredientEthylene glycol

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Mutagenicity: Ames Test:Negative

Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

No Information.

No Information.OxidizersCarbon monoxide, Carbon dioxide

Stable.Chemical stability:

Page 25: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(5/5)

SAFETY DATA SHEETMSDS: 2013076050US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Cyan

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

UN Class ---

------

---

When disposing of the waste or recovered material, consult federal, state and/or localregulations for the proper disposal method.

Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]Persistence and degradability:

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their own investigationto determine the suitability of the information for their particularpurposes.

311/312 HazardCategories:

None.

313 ReportableIngredients:

Ethylene glycol

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

This product is NOT considered hazardous under this standard.

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

None.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000 lb(2270 kg)

Readily biodegradable

GlycerinEcotoxicity Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish]

Page 26: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(1/5)

SAFETY DATA SHEETMSDS: 2013076060US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

30-4025-455-251-151-15

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

Product Name: Disperse Dye Ink Light Cyan

Product Name:Identification of thesupplier:

Disperse Dye Ink Light CyanKonica Minolta, Inc.

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

Substance/Mixture: MixtureIngredients and Concentration

Ingredient NameConcentrationwt.

%CAS#

Water 7732-18-5Ethylene glycol 107-21-1Glycerin 56-81-5Surfactant ---Dye ---

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.

May be harmful if swallowed.

Ingestion Effects May be harmful if swallowed.Inhalation Effects No identified health effects.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

Page 27: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(2/5)

SAFETY DATA SHEETMSDS: 2013076060US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Cyan

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Storage

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

No information.No information.

Wear personal protective equipment(See Section 8).

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Handling

Methods and materials forcontainment and cleaning up:

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).No information.

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Storage Conditions:

Safety adequatecontainer materials:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

Page 28: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(3/5)

SAFETY DATA SHEETMSDS: 2013076060US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Cyan

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

Control parameters

Personal Protective Equipment

Product

Glycerin

Surfactant

Dye

Ingredient NameACGIH OSHA-PEL

Odor: Slight characteristic odor

Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

Form: LiquidColor: Colored

Physical state: Liquid

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.Hand protection:

Ethylene glycol

pH: No data.Melting point/freezingpoint:

No data.

Initial boiling pointand boiling range:

No data.

Flash point: NoneAuto-ignitiontemperature:

No data.

Upper/lower flammabilityor explosive limits:

No data.

Vapour pressure: No data.Vapour density: No data.Evaporation rate: No data.Specific Gravity: No data.Solubility: water:Completely soluble.Partition coefficient:n-octanol/water:

No data.

Decompositiontemperature:

No data.

Page 29: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(4/5)

SAFETY DATA SHEETMSDS: 2013076060US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Cyan

10. Stability and reactivity

11. Toxicological information

12. Ecological information

OxidizersCarbon monoxide, Carbon dioxide

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

Stable.No Information.

No Information.

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Mutagenicity: Ames Test:Negative

IngredientEthylene glycol

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Mild [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse], LD50:

27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Minimal [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

SurfactantAcute toxicity (oral): LD50:> 40000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

DyeAcute toxicity (oral): LD50: 5000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

ProductNo Data

IngredientEthylene glycol

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish] Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna] Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

Persistence and degradability: Readily biodegradable

Page 30: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(5/5)

SAFETY DATA SHEETMSDS: 2013076060US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Cyan

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

Persistence and degradability: Readily biodegradable

GlycerinEcotoxicity Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish]

This product is NOT considered hazardous under this standard.

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

None.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000 lb(2270 kg)

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their own investigationto determine the suitability of the information for their particularpurposes.

311/312 HazardCategories:

None.

313 ReportableIngredients:

Ethylene glycol

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

UN Class ---

------

---

When disposing of the waste or recovered material, consult federal, state and/or localregulations for the proper disposal method.

Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]

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(1/5)

SAFETY DATA SHEETMSDS: 2013076070US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

30-4025-455-251-151-15

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

May be harmful if swallowed.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

Ingestion Effects May be harmful if swallowed.Inhalation Effects No identified health effects.

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.

Dye ---

Glycerin 56-81-5Surfactant ---

Water 7732-18-5Ethylene glycol 107-21-1

Substance/Mixture: MixtureIngredients and Concentration

Ingredient NameConcentrationwt.

%CAS#

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Product Name: Disperse Dye Ink Black

Product Name:Identification of thesupplier:

Disperse Dye Ink BlackKonica Minolta, Inc.

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

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(2/5)

SAFETY DATA SHEETMSDS: 2013076070US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Black

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

Storage Conditions:

Safety adequatecontainer materials:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:Methods and materials forcontainment and cleaning up:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

Wear personal protective equipment(See Section 8).

No information.No information.

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).No information.

Handling

Storage

Page 33: SAFETY DATA SHEET - konicaminolta.com · Konica Minolta, Inc. (2/5) SAFETY DATA SHEET MSDS: 2013076020US Date Prepared: 2014/01/06 Date Revised: Product Name: Disperse Dye Ink Light

(3/5)

SAFETY DATA SHEETMSDS: 2013076070US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Black

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

Decompositiontemperature:

No data.

Partition coefficient:n-octanol/water:

No data.

Liquid

Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

Color: ColoredOdor: Slight characteristic odorpH: No data.Melting point/freezingpoint:

Physical state: LiquidForm:

Product

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.Hand protection:

Ethylene glycol

Glycerin

Surfactant

Dye

Ingredient NameACGIH OSHA-PEL

Control parameters

No data.

No data.

Solubility: water:Completely soluble.

Personal Protective Equipment

Specific Gravity: No data.

Vapour density: No data.Evaporation rate:

Vapour pressure: No data.

No data.

Upper/lower flammabilityor explosive limits:

Flash point: NoneAuto-ignitiontemperature:

No data.

No data.

Initial boiling pointand boiling range:

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(4/5)

SAFETY DATA SHEETMSDS: 2013076070US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Black

10. Stability and reactivity

11. Toxicological information

12. Ecological information

Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]Persistence and degradability: Readily biodegradable

GlycerinEcotoxicity Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish]

Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

Persistence and degradability: Readily biodegradable

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish] Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]

ProductNo Data

IngredientEthylene glycol

Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

SurfactantAcute toxicity (oral): LD50:> 40000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]

Serious eye damage/irritation: Minimal [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]Skin corrosion/irritation: Mild [rabbit]

Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse], LD50:

27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]

Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Mild [rabbit]

IngredientEthylene glycol

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]

Skin sensitization: None (Data of similar product)Mutagenicity: Ames Test:Negative

Oxidizers

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]

Carbon monoxide, Carbon dioxideHazardous decompositionproducts:

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:

Stable.No Information.

No Information.

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(5/5)

SAFETY DATA SHEETMSDS: 2013076070US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Black

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassificationUN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

311/312 Hazard Categories: None.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000 lb(2270 kg)

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

This product is NOT considered hazardous under this standard.

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their own investigationto determine the suitability of the information for their particularpurposes.

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

313 ReportableIngredients:

Ethylene glycol

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

None.

UN3082Environmentally hazardous substance, liquid, n.o.s. (Dye)

UN Class

Persistence and degradability: Not biodegradable

When disposing of the waste or recovered material, consult federal, state and/or localregulations for the proper disposal method.

Class9

Daphnia acute toxicity: 48hrEC50: 24mg/l[Daphnia magna] Algae acute toxicity: EbC50(96hr):0.100mg/l, ErC50(0-24hr):0.375mg/l,

NOEL:0.0503mg/l [Selenastrum capricornutum]

DyeEcotoxicity Fish acute toxicity: 96hrLC50: >2.0mg/l[Rainbow trout]

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(1/5)

SAFETY DATA SHEETMSDS: 2013076080US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

30-4025-455-251-151-15

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

May be harmful if swallowed.

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation:

Product Name: Disperse Dye Ink Light Black

Product Name:Identification of thesupplier:

Disperse Dye Ink Light BlackKonica Minolta, Inc.

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Skin Contact:

Eye Contact:

Ingestion:

Substance/Mixture: MixtureIngredients and Concentration

Ingredient NameConcentrationwt.

%CAS#

Water 7732-18-5Ethylene glycol 107-21-1Glycerin 56-81-5Surfactant ---Dye ---

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.Ingestion Effects May be harmful if swallowed.Inhalation Effects No identified health effects.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

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(2/5)

SAFETY DATA SHEETMSDS: 2013076080US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Black

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Handling

Storage

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:Methods and materials forcontainment and cleaning up:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

No information.No information.

Wear personal protective equipment(See Section 8).

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).No information.

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Storage Conditions:

Safety adequatecontainer materials:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

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(3/5)

SAFETY DATA SHEETMSDS: 2013076080US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Black

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

Personal Protective Equipment

Control parameters

Glycerin

Surfactant

Dye

Ingredient NameACGIH OSHA-PEL

Odor: Slight characteristic odor

Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

Product

Form: LiquidColor: Colored

Physical state: Liquid

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.Hand protection:

Ethylene glycol

pH: No data.Melting point/freezingpoint:

No data.

Initial boiling pointand boiling range:

No data.

Flash point: NoneAuto-ignitiontemperature:

No data.

Upper/lower flammabilityor explosive limits:

No data.

Vapour pressure: No data.Vapour density: No data.Evaporation rate: No data.Specific Gravity: No data.Solubility: water:Completely soluble.Partition coefficient:n-octanol/water:

No data.

Decompositiontemperature:

No data.

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(4/5)

SAFETY DATA SHEETMSDS: 2013076080US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Black

10. Stability and reactivity

11. Toxicological information

12. Ecological information

Carbon monoxide, Carbon dioxide

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

Stable.No Information.

No Information.Oxidizers

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Skin sensitization: None (Data of similar product)Mutagenicity: Ames Test:Negative

IngredientEthylene glycol

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Mild [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse], LD50:

27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Minimal [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

SurfactantAcute toxicity (oral): LD50:> 40000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

ProductNo Data

IngredientEthylene glycol

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish] Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna] Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

Persistence and degradability: Readily biodegradable

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(5/5)

SAFETY DATA SHEETMSDS: 2013076080US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Light Black

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

GlycerinEcotoxicity Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish] Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]Persistence and degradability: Readily biodegradable

DyeEcotoxicity Fish acute toxicity: 96hrLC50: >2.0mg/l[Rainbow trout]

Algae acute toxicity: EbC50(96hr):0.100mg/l, ErC50(0-24hr):0.375mg/l,NOEL:0.0503mg/l [Selenastrum capricornutum]

Persistence and degradability: Not biodegradable

This product is NOT considered hazardous under this standard.

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

None.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000 lb(2270 kg)

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their owninvestigation to determine the suitability of the information for theirparticular purposes.

311/312 HazardCategories:

None.

313 ReportableIngredients:

Ethylene glycol

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

UN Class ---

------

---

Daphnia acute toxicity: 48hrEC50: 24mg/l[Daphnia magna]

When disposing of the waste or recovered material, consult federal, state and/or localregulations for the proper disposal method.

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(1/5)

SAFETY DATA SHEETMSDS: 2000012032US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

35-4515-2525-351-51-5

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

Ingestion Effects May be harmful if swallowed.Inhalation Effects No identified health effects.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.

Dye

EMERGENCY OVERVIEW

May be harmful if swallowed.

Eye Contact:

Ingestion:

7732-18-5

---

CAS#

WaterEthylene glycolGlycerin

Product Name: Disperse Dye Ink Orange

Ingredients and Concentration

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANAddress:

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Product Name:Identification of thesupplier:

Disperse Dye Ink OrangeKonica Minolta, Inc.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation:

Skin Contact:

Charge section:(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

Mixture

Surfactant ---56-81-5107-21-1

Substance/Mixture:

Concentrationwt.

%Ingredient Name

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(2/5)

SAFETY DATA SHEETMSDS: 2000012032US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Orange

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

Precautions:Precautions for safehandling:

Storage Conditions:

Safety adequatecontainer materials:

No information.No information.

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).No information.

No information.Environmental precautions:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

Technical Measures:

Ventilationrequirements:

Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.

Handling

Storage

Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Methods and materials forcontainment and cleaning up:

Personal precautions, protectiveequipment and emergency procedures:

Wear personal protective equipment(See Section 8).

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(3/5)

SAFETY DATA SHEETMSDS: 2000012032US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Orange

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

Decompositiontemperature:

No data.

NoneFlash point:

Form:Color:Odor:

Partition coefficient:n-octanol/water:

Specific Gravity:

Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.Hand protection:

Ethylene glycol

Glycerin

Surfactant

Dye

Ingredient NameACGIH OSHA-PEL

Solubility:No data.

Upper/lower flammabilityor explosive limits:

Vapour density:Evaporation rate:

Vapour pressure:

No data.

No data.

Slight characteristic odor

Control parameters

ProductPhysical state:

pH:Melting point/freezingpoint:Initial boiling pointand boiling range:

Auto-ignitiontemperature:

No data.

Colored

Personal Protective Equipment

LiquidLiquid

water:Completely soluble.

No data.

No data.

No data.

No data.

No data.

No data.

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(4/5)

SAFETY DATA SHEETMSDS: 2000012032US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Orange

10. Stability and reactivity

11. Toxicological information

12. Ecological information

Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]Persistence and degradability: Readily biodegradable

Ecotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish] Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]

ProductNo Data

IngredientEthylene glycol

Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

DyeAcute toxicity (oral): LD50:> 5000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]

SurfactantMutagenicity: Ames Test:NegativeCarcinogenicity: IARC:Unlisted

Serious eye damage/irritation: Minimal [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]Skin corrosion/irritation: Mild [rabbit]

Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse], LD50:

27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]

Skin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Mild [rabbit]

IngredientEthylene glycol

Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Mutagenicity: Ames Test:Negative

OxidizersCarbon monoxide, Carbon dioxide

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

Stable.No Information.

No Information.

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(5/5)

SAFETY DATA SHEETMSDS: 2000012032US

Date Prepared: 2014/01/06Date Revised:

Product Name: Disperse Dye Ink Orange

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

16. Other information

Ethylene glycol: Reportable Quantities 5000lb(2270 kg)

When disposing of the waste, containers or recovered material, consult federal, stateand/or local regulations for the proper disposal method.

This product is NOT considered hazardous under this standard.

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

None.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their own investigationto determine the suitability of the information for their particularpurposes.

311/312 HazardCategories:

None.

313 ReportableIngredients:

Ethylene glycol

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]Persistence and degradability: Readily biodegradable

UN Class ---

------

---

GlycerinEcotoxicity Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish]

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SAFETY DATA SHEETMSDS: 2000012022US

Date Prepared: 2014/01/06Date Revised:

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

40-501-1035-451-51-5

3. Hazards identification

Colored liquid. Slight characteristic odor.

POTENTIAL HEALTH EFFECTS::::

:

4. First-aid measures

Address:Charge section:

(TEL:+81-42-589-3739,FAX:+81-42-589-3868)

Product Name:Identification of thesupplier:

Disperse Dye Ink VioletKonica Minolta, Inc.

Product Name: Disperse Dye Ink Violet

2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN

No exposure expected under normal conditions. Large amount ofvapor or mist if inhaled, move victim to fresh air immediately.If symptoms occur, get medical attention.

Wash with water and mild soap for 15 minutes. If symptoms occur,get medical attention.

Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention immediately.

Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious person.

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

Substance/Mixture: MixtureIngredients and Concentration

Ingredient NameConcentrationwt.

%CAS#

Water 7732-18-5Ethylene glycol 107-21-1Glycerin 56-81-5Surfactant ---Dye ---

EMERGENCY OVERVIEW

Eye Effects May cause eye and mucous membrane irritation.Skin Effects May cause slight skin irritation.Ingestion Effects None currently known.Inhalation Effects No identified health effects.

Chronic Effects /Carcinogenicity :

None of the components in this material is listed by IARC, NTP orACGIH as a carcinogen.

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5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Handling

Storage

Personal precautions, protectiveequipment and emergency procedures:Environmental precautions:Methods and materials forcontainment and cleaning up:

Water spray, dry chemical, carbon dioxide, alcohol-resistantfoam.No information.Wear self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes. Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered position.

Suitable Extinguishing Media:

Extinguishing Media to Avoid:Fire Fighting:

No information.No information.

Wear personal protective equipment(See Section 8).

No information.Absorb spill with inert material(e.g. dry sand or earth), thenplace in a chemical waste container.

Keep container tightly closed. Store in a cool and dry place.Keep away from incompatible substances(See Section 10).No information.

Technical Measures:

Ventilationrequirements:Precautions:Precautions for safehandling:

Storage Conditions:

Safety adequatecontainer materials:

Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly afterhandling.Use with adequate ventilation.

Use process enclosures or local exhaust ventilation.Appropriate engineering controls:

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SAFETY DATA SHEETMSDS: 2000012022US

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Product Name: Disperse Dye Ink Violet

TLV-TWA TLV-STEL TWA STELNoneestablished

100mg/m3[C]

Noneestablished

Noneestablished

Noneestablished

Noneestablished

15mg/m3(totaldust)

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

Noneestablished

9. Physical and chemical properties

Unknown

No data.

water:Completely soluble.

No data.No data.

No data.

No data.

No data.

No data.

None

Form:

Ethylene glycol

Glycerin

Surfactant

Dye

Not required under normal conditions.Respiratory Protection:Impervious gloves should be worn.

Auto-ignitiontemperature:

No data.

Colored

No data.

Personal Protective Equipment

Upper/lower flammabilityor explosive limits:

Vapour density:Evaporation rate:Specific Gravity:

Vapour pressure:

Ingredient NameACGIH OSHA-PEL

Control parameters

Hand protection:Splash goggles should be worn.Eye/face protection:Not required under normal conditions.Skin Protection:

No data.

Slight characteristic odor

Liquid

Color:Odor:Odor threshold:

Liquid

ProductPhysical state:

Flash point:

pH:Melting point/freezingpoint:Initial boiling pointand boiling range:

Solubility:Partition coefficient:n-octanol/water:Decompositiontemperature:

No data.

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10. Stability and reactivity

11. Toxicological information

Stable.No Information.

No Information.OxidizersCarbon monoxide, Carbon dioxide

Chemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous decompositionproducts:

Serious eye damage/irritation:

ProductAcute toxicity (oral): LD50:> 2000 mg/kg[rat]Mutagenicity: Ames Test:Negative

Mild [rabbit]

Mild [rabbit]

Ingredient

GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse], LD50:

27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]

Ethylene glycolAcute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]Skin corrosion/irritation: Mild [rabbit]

Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

Surfactant

Serious eye damage/irritation: Minimal [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

Acute toxicity (inhalation): LC50:> 570 mg/m3/1h[rat]Skin corrosion/irritation:

Acute toxicity (oral): LD50:> 40000 mg/kg[rat]Skin corrosion/irritation: None [rabbit]Serious eye damage/irritation: None [rabbit]Mutagenicity: Ames Test:Negative

DyeAcute toxicity (oral): LD50:> 5000 mg/kg[mouse]Skin corrosion/irritation: Moderate [rabbit]Serious eye damage/irritation: Mild [rabbit]Mutagenicity: Ames Test:Negative

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12. Ecological information

13. Disposal considerations

Disposalmethods:

14. Transport information

UNclassification:

UN number:Proper shippingname:Packing group:

15. Regulatory information

ProductNo Data

Ingredient

Glycerin

Ethylene glycolEcotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish] Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]

Persistence and degradability: Readily biodegradable

Persistence and degradability: Readily biodegradable Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]

Ecotoxicity Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish]

This product is NOT considered hazardous under this standard.

SARA Title III (SuperfundAmendments andReauthorization Act) 302Extreme HazardousSubstance:

None.

CERCLA(ComprehensiveEnvironmental ResponseCompensation and LiabilityAct):

Ethylene glycol: Reportable Quantities 5000lb(2270 kg)

OSHA Hazard CommunicationStandard,29CFR 1910.1200:

311/312 HazardCategories:

None.

313 ReportableIngredients:

Ethylene glycol

UN Class ---

------

---

When disposing of the waste, containers or recovered material, consult federal, stateand/or local regulations for the proper disposal method.

Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

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SAFETY DATA SHEETMSDS: 2000012022US

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16. Other information

Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their own investigationto determine the suitability of the information for their particularpurposes.

HMIS Hazard Rating : Health : 1, Flammability : 1, Reactivity : 0


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