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Quick-FDS [16105-64582-24827-015648] - 2012-02-03 - 17:56:22 Print Close 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Commercial Name: SILICA MIX Cu Definition: Unshaped refractory material Usage: Usages according to the ECHA (European CHemical Agency) - Guidance R.12 Use descriptor system - draft version 2.0 SU10; 13 + NACE C23.2 + PC 10 + PROC 1; 2; 3; 4; 5; 8a; 9; 13; 14; 19; 21; 22; 23; 24; 26 + ERC 2; 3; 5 + AC 12-1; 12-2 Restricted to industrial or professional users for application as safety or wear linings and maintenance of both in all industrial devices Installation Method Ramming Vibrating Creation date: Date : 08/02/2007 ( DD / MM / YY ) SDS status: Revision Manufacturer: Produced by CALDERYS within the EU Contact manufacturing: Dr. Dirk HOLLAND +49 (0)1 607 070 307 - CALDERYS Deutschland GmbH _ Co OHG - Research Centre - In der Sohl 122 - D-56564 Neuwied -- CALDERYS France - Research Centre - 4 allee de Lausanne - F-38070 Saint-Quentin Fallavier Supplier: CALDERYS Person to contact: J-P.Targe - Tel +33 (0)4.74.99.99.40 - Fax 33 (0)4.74.99.99.66 : CALDERYS France - Research Centre - 4 allee de Lausanne - F-38070 Saint Quentin Fallavier jean-[email protected] Emergency telephone: UK: Medical Toxicology Unit - Avonley Road - Cse14 ER London - Phone: 44 441 716 359 191 - Fax: 44 4 417 177 153 109 See enclosed annex for other Emergency telephone 2. HAZARDS IDENTIFICATION Miscellaneous (REACH - GHS/CLP): The product named above contains a notable proportion of particules which can be suspended in the workshop air by the processes used for installation and also can become respirable dust having an effect on health. The product should be installed in a ventilated area. To avoid risks to human health and the environment, comply with the instructions for use. Hazard linked to route of exposure: Eyes (REACH): Dust can cause eye irritation. Eyes (GHS/CLP): Dust can cause eye irritation. Skin (REACH): Possible temporary irritation. Skin (GHS/CLP): Possible temporary irritation. Inhalation (REACH): Prolonged inhalation of dust less than 12 µm may effect the lungs. Prolonged and/or massive inhalation of respirable crystalline silica dust (RCS) may cause lung SAFETY DATA SHEET SILICA MIX Cu Version : 10 MQD90029 Page 1 sur 17
Transcript
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Quick-FDS [16105-64582-24827-015648] - 2012-02-03 - 17:56:22

Print Close

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

Commercial Name:

SILICA MIX CuDefinition:

Unshaped refractory materialUsage:

Usages according to the ECHA (European CHemical Agency) - Guidance R.12 Use descriptor system - draft version 2.0

SU10; 13 + NACE C23.2 + PC 10 + PROC 1; 2; 3; 4; 5; 8a; 9; 13; 14; 19; 21; 22; 23; 24; 26 + ERC 2; 3; 5 + AC 12-1; 12-2

Restricted to industrial or professional users for application as safety or wear linings and maintenance of both in all industrial devices

Installation MethodRamming

VibratingCreation date:

Date : 08/02/2007 ( DD / MM / YY )

SDS status:

RevisionManufacturer:

Produced by CALDERYS within the EUContact manufacturing:

Dr. Dirk HOLLAND +49 (0)1 607 070 307 - CALDERYS Deutschland GmbH _ Co OHG - Research Centre - In der Sohl 122 - D-56564 Neuwied -- CALDERYS France - Research Centre - 4 allee de

Lausanne - F-38070 Saint-Quentin FallavierSupplier:

CALDERYSPerson to contact:

J-P.Targe - Tel +33 (0)4.74.99.99.40 - Fax 33 (0)4.74.99.99.66 : CALDERYS France - Research Centre - 4 allee de Lausanne - F-38070 Saint Quentin Fallavier

[email protected] telephone:

UK: Medical Toxicology Unit - Avonley Road - Cse14 ER London - Phone: 44 441 716 359 191 -Fax: 44 4 417 177 153 109

See enclosed annex for other Emergency telephone

2. HAZARDS IDENTIFICATION

Miscellaneous (REACH - GHS/CLP):

The product named above contains a notable proportion of particules which can be suspended in the workshop air by the processes used for installation and also can become respirable dust

having an effect on health.The product should be installed in a ventilated area.

To avoid risks to human health and the environment, comply with the instructions for use.Hazard linked to route of exposure:

Eyes (REACH):Dust can cause eye irritation.

Eyes (GHS/CLP):Dust can cause eye irritation.

Skin (REACH):Possible temporary irritation.

Skin (GHS/CLP):Possible temporary irritation.

Inhalation (REACH):Prolonged inhalation of dust less than 12 µm may effect the lungs.

Prolonged and/or massive inhalation of respirable crystalline silica dust (RCS) may cause lung

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fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and

breathlessness.May cause damage to lungs through prolonged or repeated exposure if inhaled.

See Section 16. OTHER INFORMATION. Additionnal safety information.Inhalation (GHS/CLP):

May cause respiratory irritation.Prolonged inhalation of dust less than 12 µm may effect the lungs.

Prolonged and/or massive inhalation of respirable crystalline silica dust (RCS) may cause lung fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and

breathlessness.May cause damage to lungs through prolonged or repeated exposure if inhaled.See Section 16. OTHER INFORMATION. Additionnal safety information.

Ingestion (REACH):Non relevant

Ingestion (GHS/CLP):Non relevant

Environnemental hazards :EU/REACH classification:

This preparation requires the danger label :Miscellaneous :

Owing to the potential for generation of airborne respirable crystalline silica dust (> 1% ; < 2,5 %), the product has been classified and labelled as follows:

EU/REACH classification:Xn : Harmful

EU/REACH Risk phrasesR48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation.

EU/REACH Safety phrasesS22: Do not breathe dust.

S38: In case of insufficient ventilation, wear suitable respiratory equipment.GHS/CLP classification

STOT RE2, H373GHS/CLP phrases (H - EUH)

H373: May cause damage to lung through prolonged or repeated exposure by inhalation.GHS/CLP phrases (P)

P260: Do not breathe dust.P285: In case of inadequate ventilation wear respiratory protection.

P501: Dispose of contents/containers in accordance with local regulation.REACH Pictograms

Classification GHS/CLP :This preparation does not require a hazard warning label in European Union

3. COMPOSITION / INFORMATION ON INGREDIENT

Data linked to the pure substance or its reglementary concentration

Non hazardous components

Component CAS N° EINEC N° Weight %

Alpha-quartzCAS : 14808-60-7

Einecs : 238-878-4>=50 <100

hazardous components

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Component CAS N° EINEC N° Weight %

Alpha-quartz (RCS)

REACH: Xn; R48/20--- CLP: STOT RE2; H373 -

R48/20

CAS : 14808-60-7

Einecs : 238-878-4>=1 <2.5

Boric acid

REACH: T ; Repr.Cat.2, R60-R61 --- CLP: Repr.1B; H360FD - R 60-R 61

CAS : 10043-35-3

Einecs : 233-139-2>=1 <2.5

Occupational illness

Commission Recommendation of 19 September 2003 concerning the European schedule of occupational diseases (Text with EEA relevance) (notified under document number C(2003) 3297)

301 Diseases of the respiratory system and cancers301.11 Silicosis

301.12 Silicosis combined with pulmonary tuberculosis301.31 Pneumoconioses caused by dusts of silicates

2.1 Diseases caused by the following agents:2.160 Silicium oxide

Other informations :Data linked to the pure substance or its reglementary concentration

Informations on substances - under EU/REACH :Alpha-quartz: CAS Nr.14808-60-7 - Einecs Nr.238-878-4 - R48/20 - Label: Xn; R48/20 if C = 10%

Boric acid: CAS Nr.10043-35-33 - Einecs Nr.233-139-2 - R60, R61 - Label: T; Repr.Cat.2, R60, R61 - Cn = 5,5 %

Informations on substances - under GHS/CLP :Alpha-quartz (RCS): CAS Nr.14808-60-7 - Einecs Nr.238-878-4 - H372 - Label: STOT RE1; H372 -

Danger - if C = 10% - H373 - Label: STOT RE2; H373 - Warning - if 10% = C = 1%Boric acid: CAS Nr.10043-35-33 - Einecs Nr.233-139-2 - Label: Repr.1B; H360F, H360D

4. FIRST AID MEASURES

Eyes (REACH):Rinse with water, if irritation persists seek medical advice.

Eyes (GHS/CLP):IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present

and easy to do. Continue rinsing.If eye irritation persists: Get medical advice/attention.

Skin (REACH):Wash with soap and water, if irritation persists seek medical advice.

Skin (GHS/CLP):IF ON SKIN: Gently wash with plenty of soap and water.

If skin irritation occurs: Get medical advice/attention.Ingestion (REACH):

Non relevantIngestion (GHS/CLP):

Non relevantInhalation (REACH):

If there is a sensation of nausea or dizziness, remove to fresh air and seek medical attention.Inhalation (GHS/CLP):

IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.Hazardous decomposition substances or volatiles

None

5. FIRE-FIGHTING MEASURES

Suitable fire-fighting methods :In case of fire use water based extinguishers or hosepipe.

Other preventive action:Non relevant

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Personal precautions:

Personal precautions : see Section 8.Hazardous decomposition substances or volatiles

None

6. ACCIDENTAL RELEASE MEASURES

Miscellaneous :

Personal precautions : see section 8.Neutralising reagents:

Non relevantEnvironment:

Non relevantMiscellaneous :

Avoid dust formation.Avoid dry sweeping and use water spraying or ventilated vacuum cleaning system to prevent dust

formation.

7. HANDLING AND STORAGE

Miscellaneous :

Engineering measures,such as local dust extraction, to ensure compliance with Occupational Exposure Limits.

Avoid dust formation.In case of insufficient ventilation, wear suitable respiratory equipment. Your supplier can advise

you on safe handling, please contact him.Handling:

Avoid bulk handling susceptible to create dust.Storage:

Store in dry conditionsStore the bagged products in a way preventing accidental bursting.

Recommended packing:Multi-ply paper sacks or big-bags.

Wooden pallet with shrink film.Always keep the main pallet label.

Unsuitable packaging.Non relevant

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Controls:Approved Occupational Exposure values for total inhalable dust.

Customers are advised to check National legislation for limit values and period of referenceThe chart below mentionnes the maximal exposure limit values known in the EU for each

substance.Technical measure:

Provide appropriate exhaust ventilation and filtering at the places where dust can be generated.Provide appropriate exhaust ventilation.

Environment protection measuresNon relevant

Substance:

Substance CAS Nr. EINEC Nr.

L.T.E - 8

hr TWA mg/m3

Alpha-quartz (RCS)

REACH: Xn; R48/20--- CLP: STOT RE2; H373 -

R48/20

CAS : 14808-60-7

Einecs : 238-878-40,1

Boric acidCAS : 10043-35-3

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REACH: T ; Repr.Cat.2, R60-R61 --- CLP: Repr.1B;

H360FD - R 60-R 61

Einecs : 233-139-22

Alpha-quartzCAS : 14808-60-7

Einecs : 238-878-40,1

Personal protection:

For details about the following HS personal devices, please see the annex dedicated to. (Section .17)

Eyes:Wear safety glasses with lateral protection

Skin :Standard industrial clothing is suitable for installations at ambient temperatures

Do not shake the working clothes. Do not remove dust with compressed air.

Hands:Wear leather security gloves

Respiratory protection for standard installation at ambiant temperature:

Maintain adequate ventilation whenever dust is present.Consult the local reglementation.

Wear appropriete anti-dust mask (EN149:2001 FFP3)Use a filtering respiratory device, in case of airbone concentrations are expected to exceed

exposure limits.

Respiratory protection for installation on hot lining, over 100°C:Wear appropriete anti-dust mask (EN149:2001 FFP3)

Exposure scenario :

Read carefully the relevant Installation Guideline that is indicated in the Technical Data Sheet.Read carefully the relevant Exposure Scenario for borates placed as annex of the §17

9. PHYSICAL AND CHEMICAL PROPERTIES

Characteristics

Name of the

characteristicValue

pH Non applicable

Melting point > 1500 °C

Packing Density: 1.65

Segregation: Non relevant

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Boiling point: Non relevant

Flash point: Non relevant

Inflammability: No

Explosive properties:

No

Combustive properties:

No

Vapour pressure: Non relevant

Solubility solvent: Non relevant

Partition coefficient

n-otanol/water:Non relevant

Viscosity: Non relevant

Vapour density: Non relevant

Miscibility: Slightly

Aspect: Dry mixture of aggregates and fine powders

Color: Grey

Odour: No particular odour

10. STABILITY AND REACTIVITY

Reaction:

NoHazardous decomposition substances or volatiles

NoneHazardous reactions:

NoExothermic reaction:

NoOther:

Depending of the service temperature and of the cooling slope of the lining, cristobalite might be found in the product after utilisation.

11. TOXICOLOGICAL INFORMATION

Data linked to the pure substance or its reglementary concentration

Substance

Substance CAS N° EINEC N°

Alpha-quartz (RCS)

REACH: Xn; R48/20--- CLP: STOT RE2; H373 - R48/20

CAS : 14808-60-7

Einecs : 238-878-4

Boric acid

REACH: T ; Repr.Cat.2, R60-R61 --- CLP: Repr.1B; H360FD -R 60-R 61

CAS : 10043-35-3

Einecs : 233-139-2

Substance as EU/REACH:Alpha-quartz: CAS Nr.14808-60-7 - Einecs Nr.238-878-4 - R48/20 - Label: Xn; R48/20 if C = 10%

Boric acid: CAS Nr.10043-35-33 - Einecs Nr.233-139-2 - R60, R61 - Label: T; Repr.Cat.2, R60, R61 - Cn = 5,5 %

Substance as GHS/CLP:Alpha-quartz (RCS): CAS Nr.14808-60-7 - Einecs Nr.238-878-4 - H372 - Label: STOT RE1; H372 -

Danger - if C = 10% - H373 - Label: STOT RE2; H373 - Warning - if 10% = C = 1%Boric acid: CAS Nr.10043-35-33 - Einecs Nr.233-139-2 - Label: Repr.1B; H360F, H360D

Classification C.M.R. - REACH - (Preparation)No

Classification C.M.R. - GHS/CLP - (Preparation)No

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Contact with eyes

Non relevantContact with skin:

Non relevantInhalation:

Prolonged and/or massive inhalation of respirable crystalline silica dust may cause lung fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and breathlessness.

Ingestion:Non relevant

Miscellaneous :Symptoms of lungoedema mostly reveal after a few hours, intensified by physical effort.

12. ECOLOGICAL INFORMATION

Comportement écologiqueAir :

Non relevantWater:

Non relevantSoil :

Non relevantEcotoxicity:

The unused product is not considered dangerous for the environmentMobility :

Non relevantDurability and biodegradablity :

Non relevantPotentially bioaccumulative :

Non relevantPBT Evaluation :

No

Persistent Organic Pollutants (POP):No

Other nocive effects :Non relevant

13. DISPOSAL CONSIDERATIONS

Potential danger from the waste:

The unused product is not considered dangerous for the environmentPlease consult local regulations and statuary European Union provisions

European waste catalogue16 03 03: inorganic wastes containing dangerous substances

Dumping measures :Used packaging should be treated in the same way as the received product

Unused material can be disposed according to local regulations and statuary EU provisionsPlease consult local regulations and statuary European Union provisions

Recycling and disposal of packaging has to be organised in cooperation with a suitable waste disposal company. The re-use of packaging is not recommended.

Waste treatment:

Please consult local regulations and statuary European Union provisionsPackaging : In all cases dust formation from residues in the packaging should be avoided and

suitable worker protection be assured.Packagings that cannot be cleaned are to be disposed of in the same manner as the product.

Miscellaneous :Before destruction and disposal of the refractory lining, customers are adviced to evaluate any

changes to the product that may be induced by the introduction of substances, or operating conditions outside the control of the Vendor

14. TRANSPORT INFORMATION

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According to IMDG, ADR/RID and ICAO/IATA, the preparation does not need any classification

15. REGULATORY INFORMATION

Product classification:This preparation requires the danger label :

Miscellaneous :Owing to the potential for generation of airborne respirable crystalline silica dust (> 1% ; < 2,5

%), the product has been classified and labelled as follows:EU/REACH classification:

Xn : HarmfulEU/REACH Risk phrases

R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation.EU/REACH Safety phrases

S22: Do not breathe dust.S38: In case of insufficient ventilation, wear suitable respiratory equipment.

GHS/CLP classificationSTOT RE2, H373

GHS/CLP phrases (H - EUH)H373: May cause damage to lung through prolonged or repeated exposure by inhalation.

GHS/CLP phrases (P)P260: Do not breathe dust.

P285: In case of inadequate ventilation wear respiratory protection.P501: Dispose of contents/containers in accordance with local regulation.

REACH Pictograms

Substance as EU/REACH:Alpha-quartz: CAS Nr.14808-60-7 - Einecs Nr.238-878-4 - R48/20 - Label: Xn; R48/20 if C = 10%

Boric acid: CAS Nr.10043-35-33 - Einecs Nr.233-139-2 - R60, R61 - Label: T; Repr.Cat.2, R60, R61 - Cn = 5,5 %

Substance as GHS/CLP:

Alpha-quartz (RCS): CAS Nr.14808-60-7 - Einecs Nr.238-878-4 - H372 - Label: STOT RE1; H372 -Danger - if C = 10% - H373 - Label: STOT RE2; H373 - Warning - if 10% = C = 1%

Boric acid: CAS Nr.10043-35-33 - Einecs Nr.233-139-2 - Label: Repr.1B; H360F, H360D

WgK: German Water hazard class (from the Administrative Regulation on substances hazardous to water -assessment):

The product, (according to German regulation) is classified as (in the sense of 17.05.1999):WGK 1: slightly hazardous to water

16. OTHER INFORMATION

Additionnal safety information:The following substances are present in the product, as announced in the §.3.Therefore, because their maximum amount are lower than those indicated in these UE directives, the product does

not need any specific label nor risk or safety sentences linked to these substances that are reminded only because of our voluntary health and safety policy.

Substance as EU/REACH:

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Boric acid: CAS Nr.10043-35-33 - Einecs Nr.233-139-2 - R60, R61 - Label: T; Repr.Cat.2, R60,

R61 - Cn = 5,5 %Substance as GHS/CLP:

Boric acid: CAS Nr.10043-35-33 - Einecs Nr.233-139-2 - Label: Repr.1B; H360F, H360DEU/REACH Risk phrases

R60: May impair fertility.R61: May cause harm to the unborn child.

Training:Workers must be informed of the presence of crystalline silica and trained in the proper use and

handling of this product as required under applicable regulations.Other informations :

This safety data sheet (SDS) has been compiled according to Directive 1999-45-CE

This safety data sheet (SDS) has been compiled according to annexe II of the CE 1907/2007 (18 december 2006) regulations concerning the adoption of REACH

The limits shown are from annex I of the European Directive 67/548 EEC modified 17th March 2007.

The limits shown are from annex VI of the GHS as of 27th June 2007.SDS status :

Modifier JP Targe Modification Date :

Modification:Modified section : 1

Modified section : 2Modified section : 3

Modified section : 4Modified section : 5

Modified section : 6Modified section : 7

Modified section : 8Modified section : 9

Modified section : 10Modified section : 11

Modified section : 12Modified section : 13

Modified section : 14Modified section : 15

Modified section : 16Acronyms and abbreviations used:

ADR: European regulation on transport of dangerous goods by road.CAS: Chemical Abstracts Service

CLP : Classification, Labelling and Packaging of chemicalsCMR : Carcinogenic, Mutagenic or Toxic for ReproductionCSA : Chemical Safety Assessment

CSR : Chemical Safety ReportDNEL : Derived No-Effect Level

DU : Downstream UsersECHA : European CHemical Agency

EINECS: European Inventory of Existing Commercial Chemical Substance.ES : Exposure Scenario

eSDS : extended Safety Data SheetGefStoffV: German regulation on hazardous substances.

GHS : Global Harmonized System of classification and labelling of chemicalsGHS/CLP: Gobally Harmonized System of Classification, Labelling and Packaging of chemicals

GLP : Good Laboratory PracticeHPV : High Production Volume chemicals

IATA: International Air Transport Association.IATA-DGR: Dangerous Goods Regulation by the International Air Transport Association

ICAO: International Civil Aviation Organization.ICAO-TI: Technical Instruction by the International Air Transport Association

IMDG: International Maritime code for Dangerous Goods.LC50: Lethal Contration, 50%.

LD50: Lethal Dose, 50%.M / I : Manufacturer / Importer

NLP : No-Longer PolymersOSOR : One Substance, One Registration

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PBT : Persistent, Bioaccumulative and Toxic

PEC : Predicted Environmental ConcentrationPNEC : Predicted No-Effect Concentration

POP : Persitent Organic PollutantPPORD : Product and Process Oriented Research and Development

RCS: respirable crystalline silicaREACH : Registration, Evaluation, Autorisation and restriction of CHemicals

RID: International regulation on transport of dangerous goods by railway.RIP : REACH Implementation Project

RMM : Risk Management MeasureSIEF : Substance Information Exchange ForumSME : Small and Medium sized Entreprises

SPORT : Strategic Partnership on REACH TestingSVHC : Substance of Very High Concern

TGD : Technical Guidance DocumentUEC : Use and Exposure Category

UVCB : Substances of Unknown Variable composition, complex reaction products or Biological materials

vPvB : very Persistent very Bioaccumulative(Q)SAR : (Quantitative or Qualitative) Structure Activity Relationship

17. ANNEXES

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Annex: MEDICAL TOXICOLOGY UNITS

Greece:

Childrens hospital "Aglaia kyriakou" – 11527 Athens - Tel: +30 1779 3777 – Fax : +30 1748 6114

United Kingdom:

The general Hospital – Great George Street – Leeds CLs1 EX - Phone: +44 1 132 430 715 –Fax: +44 1 132 445 849

Medical Toxicology Unit – Avonley Road – Cse14 ER London – Phone: +44 441 716 359 191 –Fax: +44 4 417 177 153 109

France:

système ORFILA, tél: 33 (0)1.45.42.59.59 (24h/24h)

Italia:

Centro antiveneli – Universita di Torino, Corso A.M Dogliotti, 14, 10126 Torino -Tel: +39 0 116 63 76 37

Nederland:

Rijkinstituut voor Volksgezondheid, Antonie van Leeuwenhoeklaan 9, 3720BA Bilthoven -Tel: +31 302 541 5 11 – Fax: +31 302 748 888

España:

Servicio Nacional de Toxicologia, c/Luis Cabrera, 9 – 28002 Madrid, Tel: +34 15 62 04 20

Magyar:

Hopital Elizabeth, Alsoerdoesor 7, Budapest VII, Phone: +36 1 21 52 – Fax: +36 1 22 94 60

Romania:S.O.S Vitan Birzesti 9, Sector 4, 75889 Bucuresti - Tel: +401 6 34 38 90 135 – Fax: +401 3 21 02 60

Belgique:Centre antipoisons, rue Stallaert Joseph N°1, Bte 15, 1060 Bruxelles, Tel: +32 70 24 52 46

Denmark:

Giftinformationscentralen, Rigshospitalet, 7122 Tagensvej 20, 2200 N Kobenhaven -Tel: +45 35 45 35 45 – Fax: +45 31 39 42 33

Osterreich:

General Hospital, Wachringer courroie 18-20, 1090 Wien -Tel: +43 (1) 404 00 22 22 / +43 (1) 406 43 43

Australia:

1- South Australian Poisons Information Centre Women's and Children's Hospital, 72 King William Road North Adelaide SA 5006 - Tel: +61 82 04 72 22 - Fax: +61 82 04 60 49

2 - Canberra A.C.T. Poisons Information Service, Woden Valley Hospital, Garran, Yamba Drive -Tel: +61 62443333 / +61 62852852 - Fax: +61 6244 3334

India:

Poison Information Centre National Institute of Occupational Health Meghani Nagar, Ahmedabad -India 320016 - Tel: +91-272-867351 - Fax: +91-272-866630

RSA :

Poison Information Centre, University of Cape Town, Department of Paediatrics and Child Health, Red Cross War Memorial Children's Hospital, Klipfontein Road, Rondesbosch, Cape 7700, South Africa -Tel: +27 21 658 5308 - Fax: +27 21 689 1287

Brazil:

Centro de Informacao Toxicologica, Rua Domingos Cresencio, 132/8 andar CEP 90650-090 Porto Alegre-RS - Tel: +55 51-223-6110 - Fax: +55 51 2299067

Polska:

Wojewodzki Osrodek Toksykologiczny, Szpital Praski III Oddzial Chorob Wewnetrznych, Pl. Weteranow 4, 03-701 Warsawa Poland - Tel: +48 22196654 - Fax: +48 22196943

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Quick-FDS [16105-64582-24827-015648] - 2012-02-03 - 17:56:22

ANNEX: EXPOSURE VALUES FOR

CHAP.8MOST SEVERE DATA FOUND WITHIN THE EU

Substances' names CASNr.

Short TWA

3

8hrs Long

TWA mg/m3

Relevant countries

Alkyl benzolsulfonat, Na 68411-30-3 No data No data

Alumina inhalable aerosol 1344-28-1 10 5 DFG MAK

Alumina respirable aerosol 1344-28-1 4 1,5 MAK

Alumina Magnesia Spinel 1302-67-6 No data No data

Aluminium Fluoride 7784-18-1 No data 2,5 UK

Aluminium hydroxide- Martin inhalable 21645-51-2 4 No data MAK

Aluminium hydroxide- Martin respirable 21645-51-2 1,5 No data MAK

Aluminium Orthophosphate 7784-30-7 No data No data

Aluminium oxide hydrate 1333-84-2 No data No data

Aluminium tris(dihydrogen phosphate) 13530-50-2 No data No data

Aluminium powder inhalable aerosol 7429-90-5 10 4 DNK DFG MAK

Aluminium powder respirable aerosol 7429-90-5 4 1,5 DNK DFG MAK

Aluminium sodium dioxide 1302-42-7 No data No data

Aluminium sulphate 10043-01-3 No data No data

Aluminium dihydrogen triphosphate 13939-25-8 No data No data

Andalusite 12183-80-1 No data No data

Anhydrous phosphoric acid 1314-56-3 2 1 AUS

Anionic ester- 209-40-64 No data No data

Naphtha (petroleum), heavy alkylate 64741-65-7 No data No data

Distillates (petroleum), hydrotreated light paraffinic 64742-55-8 No data No data

Aqueous solution of sodium alkyl sulphate

072906-11-7 No data No data

Barium sulphate inhalable aerosol 7727-43-7 No data 4 NL

Barium sulphate respirable aerosol 7727-43-7 No data 1,5

Bauxite calcined 92797-42-7 No data No data

Bentonit - 453t 85049-30-5 No data No data

Bentonite 1302-78-9 No data No data

Benzenesulfonic acid, mono-C10-14-alkyl derivs., compds. with ethanolamine 99924-49-9 No data No data

Benzo[a]Pyrene 50-32-8 No data 550 ng/m³ NL

Biphenyl-2-ol 90-43-7 No data No data

Boric acid10043-35-33 1 0,5

DFG MAK reprotox

Boron carbide 12069-32-8 No data No data

Diboron trioxide 1303-86-2 3 1GR 2000 reprotox

Boron orthophosphate 13308-51-5 No data No data

Boron orthophosphate 13308-51-8 No data No data

Alumina cement 65997-16-2 No data No data

Calcium carbonate inhalable aerosol 471-34-1 No data 10 EH

Calcium carbonate respirable aerosol 471-34-1 No data 3

Calcium fluoride 7789-75-5 No data No data

Calcium dihydroxide inhalable aerosol 1305-62-0 4 2

Calcium dihydroxide respirable aerosol 1305-62-0 No data No data

Carbon black 1333-86-4 7 3 DNK CH

Cellulose inhalable aerosol 9004-34-6 20 10 UK

Cellulose respirable aerosol 9004-34-6 No data 3 CH

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Slags, chromium-manufg., 84144-94-5 No data No data

Pigment Green 17 1308-38-9 No data 2 NL

Chrome (VI) trioxide 1333-82-0 0,05 0,025 NL

Dichromium iron tetraoxide 1308-31-2 No data No data

Citric acid 77-92-9 No data No data

Clay 014808-60-7

No data No data

Kaolinite 1318-74-7 No data No data

Pitch, coal tar, high-temp. 65996-93-2 0,4 0,2 DNK

Dialuminium chloride pentahydroxide 12042-91-0 No data No data

Cordierite 12330-40-4 No data No data

Kyanite 1302-76-7 No data No data

Dibutyl Phthalate 84-74-2 5 3 SVE DNK

Dodecylbenzenesulfonic acid 26836-07-7 No data No data

Ethane-1,2-diol 107-21-1 104 52 EU

Vermiculite 1318-00-9 No data No data

Feldspar 68476-25-5 No data No data

Ferrochromium 11114-45-8 No data No data

Iron silicide 12022-95-6 No data No data

Sulfuric acid, iron(2+) salt, heptahydrate 7782-63-0 No data 0,02 NL

Ashes (residues) 68131-74-8 No data No data

Formaldehyde 50-00-0 0,4 0,15 ESP NL

Fuel oil, heavy, high sulfur 92045-14-2 No data No data

Captan 133-06-2 10 5 DNK NL

Urea, N,N'-bis(hydroxymethyl)-, reaction products with 2-(2-butoxyethoxy)ethanol, ethylene glycol and formaldehyde

90604-54-9 No data No data

Benzene, (1-methylethyl)-, oxidized, polyphenyl residues 68333-89-1 No data No data

Fusible carbon 8052-42-4 2 0,5 DNK NL

Graphite inhalable aerosol 7782-42-5 No data 2 ESP

Graphite respirable aerosol 7782-42-5 5 1,5 DNK MAK

Methenamine 100-97-0 5 3 SVE

Cellulose, 2-hydroxyethyl ether 9004-62-0 No data No data

Diiron trioxide 1309-37-1 7 1,5 MAK

Iron oxide, FeOOH-bay920 20344-49-41

No data No data

Kieselguhr inhalable aerosol 61790-53-2 No data 4 MAK

Kieselguhr respirable aerosol 61790-53-2 3 1,5 DNK

Dodeca-aluminium calcium 12005-50-4 No data No data

Lignosulfonic acid, sodium salt 8061-51-6 No data No data

Calcium oxide 1305-78-8 2 1 CH SVE

Zirconium dioxide 1314-23-4 No data No data

Lithium carbonate 554-13-2 No data No data

Lithium hydroxid mono 1310-66-3 No data No data

Magnesia inhalable aerosol 1309-48-4 12 4 DNK MAK

Magnesia respirable aerosol 1309-48-4 1,5 3 MAK SVE

Magnesia chrome (III) 66402-68-4 No data No data

Magnesium Distearate 557-04-0 No data 10 NL

Magnesium sulfate 7487-88-9 No data No data

Magnesium-Lignosulfonate 8061-54-9 No data No data

DL-malic acid 617-48-1 No data No data

Metallurgical coke - Carb int 65996-772 No data No data

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Propane-1,2-diol 57-55-6 No data 10 UK

Chamotte - mullite 1302-93-8 No data No data

Naphthalenesulfonic acids, reaction products with formaldehyde, sodium

91078-68-1 No data No data

Pentasodium triphosphate 7758-29-4 No data No data

Nonylphenol 25154-52-3 No data 1,97 NL

Alcohols, C9-11, ethoxylated 68439-46-3 No data No data

Olivine 1317-71-1 No data No data

Oxalic acid 144-62-7 1 1 MAK

Perlite, expanded inhalable aerosol 93763-70-3 10 5 BEL - AUS

Perlite, expanded respirable aerosol 93763-70-3 No data 5

Coke (petroleum), calcined 64743-05-1 No data No data

Petroleum condensates, vacuum tower. 64741-49-7 No data No data

Phenol 108-95-2 15,6 7,8

Phosphate - Silicate Preparation 1344-09-08 No data No data

Orthophosphoric acid 7664-38-2 2 1

Polyglycol polymer inhalable aerosol 7631-86-9 4 2

Polyglycol polymer respirable aerosol 7631-86-9 No data 10

Portland cement 65997-15-1 10 4

Potassium fluosilicate 16871-90-2 No data 0,02 NL

Potassium hydrogenosulfate 7646-93-7 No data 0,06

Potassium nitrate 7757-79-1 No data No data

Silicic acid, potassium salt 1312-76-1 No data No data

Pyrophylitte 12269-78-2 No data No data

Alpha-quartz inhalable aerosol 14808-60-7 0,6 0,3 DNK

Alpha-quartz respirable aerosol 14808-60-7 0,2 0,1 DNK - FRA

Cristobalite 14464-46-1 0,1 0,05 EU

Fumes, silica 69012-64-2 4 2 DNK

Silica, vitreous 60676-86-0 0,2 0,1 DNK

Silicon carbide inhalable aerosol 409-21-2 No data 10 ESP

Silicon carbide respirable aerosol 409-21-2 No data 3 CH

Silicon nitride 12033-60-2 No data No data

Silicon powder inhalable aerosol 7440-21-3 20 10 DNK

Silicon powder respirable aerosol 7440-21-3 No data 3 CH

Sodium aluminate 11138-49-1 No data No data

Sodium carbonate 497-19-8 No data 0,24 NL

Sodium Fluoride 7681-49-4 3,5 2 NL F

Sodium fluorosilicate 16893-85-9 No data 0,02 NL

Sodium hydroxide 1310-73-2 1 0,5 PO

Disodium metasilicate 6834-92-0 No data 0,06 NL

2-Propenoic acid, 2-methyl-, homopolymer, sodium salt 54193-36-1 No data No data

Sodium potassium tartrate 6381-59-5 No data No data

Silicic acid, sodium salt 1344-09-8 No data No data

Disodium tetraborate, anhydrous 1303-96-4 2 0,5 PO

Solvent naphtha 64742-94-5 No data No data

sulfone melamine polymer 64787-97-9 No data No data

Tetrasodium ethylenediaminetetra 64-02-8 No data 0,06 NL

Titanium dioxide inhalable aerosol 13463-67-7 12 5 DNK SVE

Titanium dioxide respirable aerosol 13463-67-7 No data 3 CH

Wollastonite 13983-17-0 2 fibres/cm3 1 fibres/cm3 DNK

Xanthan Gum 11138-66-2 No data No data

Zircon 14940-68-2 No data No data

Zirconium dioxide 1314-23-4 No data No data

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Quick-FDS [16105-64582-24827-015648] - 2012-02-03 - 17:56:22

H&S Devices - Personal protection - EU regulation: CE/EN

ROUTE OF EXPOSURE

EYES SKIN HANDS INHALATION

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 340 rev 388 - 3111 FFP3

DEDICATED USAGE: Non labelled, cast, hydraulic bonded products, cold conditions.

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 ISO6942 407 - 2122 FFP3

DEDICATED USAGE: Non labelled, cast, hydraulic bonded products, hot conditions.

Face shield Clothes Gloves Mask

166 rev, F4KN2 340 rev 388 - 3111 FFP3

DEDICATED USAGE: Non labelled, gunned, hydraulic bonded products, cold conditions.

Face shield Clothes Gloves Mask

166 rev, F4KN2 ISO6942 407 - 2122 FFP3

DEDICATED USAGE: Non labelled, gunned, hydraulic bonded products, hot conditions.

Face shield Clothes Gloves Mask

166 rev, F4KN2 340 rev 388 - 3111 FFP3

DEDICATED USAGE: Non labelled chemical bonded gunning mixes, cold installation

Face shield Clothes Gloves Mask

166 rev, F4KN2 ISO6942 407 - 2122 FFP3

DEDICATED USAGE: Non labelled chemical bonded gunning mixes, hot installation

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 340 rev 388 - 3111 FFP3

DEDICATED USAGE: Labelled hydraulic bonded products, cold installation

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 ISO6942 407 - 2122 EN 141:2000

DEDICATED USAGE: Labelled hydraulic bonded products, hot installation

Face shield Clothes Gloves Mask

166 rev, F4KN2 ISO6529-463 3121 - 1994 Local rules

DEDICATED USAGE: Phosphate bonded products

Face shield Clothes Gloves Mask

166 rev, F4KN2 ISO17491-3 3121 - 1994 Local rules

DEDICATED USAGE: Sodium silicate bonded products

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 340 rev 388 - 3111 EN 141:2000

DEDICATED USAGE: Labelled dry mixes

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 340 rev 388 - 3111 FFP3

DEDICATED USAGE: Non labelled dry mixes

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 340 rev 388 - 3111 Local rules

DEDICATED USAGE: Non labelled plastics or ramming mixes

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 340 rev 388 - 3111 FFP3

DEDICATED USAGE: Resin bonded products, cold installation.

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 ISO6942 407 - 2122 EN 141:2000

DEDICATED USAGE: Resin bonded products, hot installation

Glasses with lateral protection Clothes Gloves Mask

166 rev, S4KN2 340 rev 388 - 3111 Local rules

DEDICATED USAGE: Non labelled cement, patched, sprayed or trowelled products

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Quick-FDS [16105-64582-24827-015648] - 2012-02-03 - 17:56:22

REACH Borates Consortium

Industrial use of refractory products

Sector of use SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites

Process category PROC19 Hand-mixing with intimate contact and only PPE available

PROC7 Industrial spraying

Chemical product category PC0 Refractory linings

Contributing scenario 1: preparing and applying refractory mixes

Product characteristics

There are a variety of refractory products containing borates. Products may be supplied in dry or as moist products with

liquid binders present containing between 0.7 and 5% borate. The equivalent boron content is between 0.08 and 1.1%.

The refractory mixes are supplied in bags and are mixed with aggregate and/or liquid binder, to produce a castable

Hot gunning refractory mixes are usually supplied in a moist state ready for use, or may be added to water and mixed

using a paddle mixer.

Amounts used:

The amount of refractory used will depend on the work being carried out. Some mixes are used to make repairs to

linings, which may only require a few kgs of material. Some refractory mixes are used for hot-gunning, where the

is sprayed onto the refractory lining as a coating. This activity may take several days, depending on the size of the

or kiln. Some refractories are cast into shapes for use e.g. crucibles. Some tasks may require several hundred kgs of

of refractory material.

Frequency and duration of use

The frequency and duration of use of refractory materials will depend on whether workers are working intermittently on

repairs and relinings of furnaces or kilns in their own workplaces, or whether the workers are specialists who carry out

type of work on a daily basis.

Human factors not influenced by risk management

None

Other given operational conditions affecting workers’ exposure

The work takes place indoors. If carrying out hot gunning repairs, the temperature will be high.

Workers may be working in a confined spaces inside kilns and furnaces.

Technical conditions and measures at process level (source) to prevent release

None

Technical conditions and measures to control dispersion from source towards the worker

Refractory materials are sometimes supplied in a damp, ready to use form.

If spraying, the mixture is wet.

Organisational measures to prevent/limit releases, dispersion and exposure

Training of operatives and routine maintenance and testing of equipment.

Conditions and measures related to personal protection, hygiene and health evaluation

Operatives wear overalls, gloves, safety glasses/goggles. If spraying inside a kiln/furnace, a full-face, powered

should be worn to give protection against airborne dust. If there is potential for oxygen deficiency, a suitable

airline should be used in conjunction with the full-face respirator to provide an independent supply of fresh air.

Where RPE is used, the worker should be ace-fit tested to ensure that a good face seal can be obtained.

The RPE above rely on a tight face seal and will not provide the required protection unless they fit the contours of the

properly and securely. The employer and self-employed persons have legal responsibilities for the maintenance and

of respiratory protective equipment and the management of their correct use in the workplace. Therefore, they should

and document a suitable policy for a respiratory protective equipment programme including training of the workers.

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Quick-FDS [16105-64582-24827-015648] - 2012-02-03 - 17:56:22

Information on estimated exposure

There is no exposure data available for using refractory materials. ART has been used to model exposure during

and spraying of refractory coatings. The estimated inhalation exposure for these activities is 0.012mgB/m3.

This estimation takes no account of respiratory protective equipment.

This value is well below the inhalation DNEL of 1.45mgB/day.

There is no data available for dermal exposure. Dermal exposure has been modelled using MEASE.

The estimated exposure for hand-mixing the refractory is 0.04mgB/day assuming that the boron content of the

mix is between 1 and 5%. The estimated exposure during spraying is 0.002mgB/day.

The total value for these activities is 0.042mgB/day. This value is well below the dermal DNEL of 24mgB/day.

Refractory material may be applied by hand in or behind moulds. The refractory material will be wet, so the opportunity

inhalation exposure will be negligible, but there will be the potential for dermal exposure. MEASE was used to estimate

dermal exposure during this activity. The estimated dermal exposure during this activity was 0.24mgB/day, taking into

account the use of suitable gloves. This value is well below the dermal DNEL of 24mgB/day.

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