SAFETY DATA SHEET ALU D1050 PR CODE: SG-07-RP-627 DATE OF ISSUANCE: SEPTEMBER 2018. DATE OF NEXT REVISION: SEPTEMBER 2020 REVISION: 1 PAGE 1 OF 13 CD-16 1.1 NAME OF THE CHEMICAL SUBSTANCE: Aluminum powder 1.2 OTHER IDENTIFICATION MEANS: ALU D1050 PR. UN NUMBER: 1309 EC NUMBER: 231-072-3 CAS NUMBER: 7429-90-5 1.3 RECOMMENDED APPLICATION (FIELD OF APPLICATION): Master batch, screen printing, and powder coating. MANUFACTURER/SUPPLIER: METAPOL, S.A. DE C.V. TELEPHONE: 52+ (241) 413 01 26 FAX: ADDRESS: 52+ (241) 413 01 56 STREET: Carretera Federal a Veracruz Km 144 CITY: San Cosme Xaloztoc ZIP CODE: 90460 STATE: Tlaxcala COUNTRY: FOR FURTHER INFORMATION ON THIS MSDS México email: [email protected]1.4 IN CASE OF EMERGENCY: METAPOL, S.A. DE C.V. 52+(241) 413 01 63 SECCTION 1. IDENTIFICATION OF THE HAZARDOUS CHEMICAL SUBSTANCE OR MIXTURE AND MANUFACTURER’S
Transcript
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
DATE OF ISSUANCE: SEPTEMBER 2018.
DATE OF NEXT REVISION: SEPTEMBER 2020
REVISION: 1
PAGE 1 OF 13
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1.1 NAME OF THE CHEMICAL SUBSTANCE: Aluminum powder
1.2 OTHER IDENTIFICATION MEANS: ALU D1050 PR.
UN NUMBER: 1309 EC NUMBER: 231-072-3 CAS NUMBER: 7429-90-5
1.3 RECOMMENDED APPLICATION (FIELD OF APPLICATION): Master batch, screen printing, and powder coating.
SECCTION 1. IDENTIFICATION OF THE HAZARDOUS CHEMICAL SUBSTANCE OR MIXTURE AND MANUFACTURER’S
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
DATE OF ISSUANCE: SEPTEMBER 2018.
DATE OF NEXT REVISION: SEPTEMBER 2020
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2.1 SUBSTANCE CLASSIFICATION
CLASSIFICATION OF THE CHEMICAL PRODUCT SGA Flammable solids Category 1 H228
Substances and mixtures that in contact with water emit gases Category 3 H261
Acute toxicity, Oral Category 4 H302
Acute toxicity, cutaneous Category 5 H313
Acute toxicity, Inhalation Category 4 H332
2.2 LABEL ELEMENT Substance chemical identification: Aluminum Powder Hazard pictograms:
Hazard statement: DANGER
Hazard Statements: H228: Flammable solid H261: In contact with water releases flammable gas H302: Harmful if swallowed H332: Harmful if inhaled H313: May be harmful in contact with skin.
Precautionary statements: PREVENTION P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P223: Do not allow contact with water. P240: Ground bond container and receiving equipment P241: Use explosion-proof electrical, ventilating, lighting equipment P261: Avoid breathing dust, fumes or vapors. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke while using this product.
P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves, protective clothing, eye protection, face protection
SECTION 2. HAZARDS IDENTIFICATION
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
DATE OF ISSUANCE: SEPTEMBER 2018.
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ANSWERS P302+P334+P335: IF ON SKIN: Brush off loose particles from skin and Immerse in cool water.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312: Call a TOXICOLOGY CENTER or a doctor if you feel unwell. P314: Get medical advice attention if you feel unwell. P330: Rinse mouth. P370+P378: In case of fire: Use a fire extinguisher type D Other Hazards: ND STORAGE
P402+P404: Store in a dry place. Store in a closed container. DISPOSITION P501: Dispose of contents in accordance with local/regional regulations.
Identification of the chemical substance: Aluminum powder Common Name: ALU D1050 PR Description: Non leafing Aluminum Pigment in Powder. Components:
CAS NO. COMPONENT COMPOSITION
7429-90-5 Aluminum >99%
4.1 FIRST AID DESCRIPTION
IN CASE OF INHALATION: Remove person affected into a well-ventilated place, away from exposure. If subacute or chronic symptoms show, call immediately a doctor.
IN CASE OF SKIN CONTACT: Remove contaminated clothing. Rinse the area affected with soap and plenty of water. Consult a doctor/seek medical assistance if irritation persists.
IN CASE OF CONTACT WITH EYES: Immediately rinse eyes with plenty of fresh water for an extended time, no less than 15 minutes. Make sure to rinse thoroughly. Consult a doctor/seek medical assistance if irritation persists.
SECTION 4. FIRST AID
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
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IN CASE OF INGESTION (SWALLOWING): Consult a doctor.
4.2 ACUTE OR CHRONIC SYMPTOMS:
If ingested, may cause a slight abdominal pain and vomit. Inhalation of metallic dust or fumes may cause slight irritation and dryness in the upper respiratory tract (mouth, nose and throat), mild cough and headache and tearing. Direct contact may cause slight swelling, irritation, edema and erythema, reddening and rashes in the affected area. In contact with the eyes, may cause slight irritation and reddening.
4.3 INDICATIONS FOR IMMEDIATE TREATMENT AND SYMPTOMATIC TREATMENT: Consult
a doctor.
5.1 EXTINGUISHING MEDIA
SUITABLE EXTINGUISHING AGENTS Carbon Dioxide
Product dry chemical
foam water spray or fog
Fire extinguishers type D
X
Other means: fine, dry sand.
NO ADEQUATE MEANS: Water extinguishers, carbon dioxide, and halogenated agents.
5.2 SPECIFIC RISKS AND HAZARDS OF CHEMICAL PRODUCTS
UNUSUAL HAZARDS OF FIRE AND EXPLOSION: They may produce organic fumes that, when in contact with air, and a strong ignition may generate an explosion. HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, metal fumes, flammable hydrogen gas.
5.3 SPECIAL MEASURES FOR FIREFIGHTING PERSONNEL
Use fire protection equipment, together with respiratory protective equipment. Downwind, identify the hot spots, proper ventilation. Control the sources of ignition, avoid the movement of the ignited material to prevent (to all coast) dust cloud formation. Spade anti spark (aluminum) sand against fire gently around and over the fire to prevent it from spreading. Cut currents air sealing doors or where possible with sand or cover the wind material and leave it cool
SECTION 5. FIRE FIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEALSE MEASURES
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
DATE OF ISSUANCE: SEPTEMBER 2018.
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REVISION: 1
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6.1 PERSONAL PRECAUTIONS, PROTECTION EQUIPMENTS AND EMERGENCY PROCEDURES Evacuate and/or isolate the risk area, demarcate such areas. Restrict access to all personnel especially without the proper protection equipment and training. Avoid direct contact with skin, eyes, clothing by wearing personal protection equipment (refer to Section 8 in these MSDS). Place downwind. Ventilate the area. Eliminate all sources of ignition. Avoid and prevent formation of dust clouds.
6.2 ENVIRONMENTAL PRECAUTIONS Avoid material contaminating ground water. Avoid product to leak into the sewage.
6.3 MEANS AND MATERIALS FOR CONTAINMENT AND SPILLS CLEAN UP. Prevent new spills. Contain and secure material. Absorb with inert material, (for instance sand, dirt, sawdust and/or vermiculite). Do not cleanse nor wash the area using aqueous cleaning products. Pick up manually with non-sparking tools and place in clean, dry airtight containers, properly identified. Dispose as hazardous waste.
7.1 PRECAUTIONS FOR SAFE HANDLING
RECOMMENDATIONS FOR SAFE HANDLING: Keep containers dry and airtight sealed in order to avoid moisture absorption and contamination. Use only in a well-ventilated area and wear personal protective equipment (refer to Section 8 of these MSDS). Keep clean the working area. There should be no presence of the substance in larger amounts than the required. Avoid formation of dust clouds. Take precautionary measures against electrostatic discharges.
HYGIENE AND SAFETY RECOMMENDATIONS: Wash hands thoroughly before breaks and after working hours. Do not eat, drink or smoke while using the product. Keep containers sealed. Avoid spills and increase of dust during handling. Avoid inhaling dust and small particles as well as contact with skin and eyes. Wear personal protection equipment. (Refer to Section 8 in these MSDS).
7.2 CONDITIONS FOR SAFE STORAGE:
CONDITIONS TO AVOID: Store together with incompatible substances such as flammables, alkalis, highly oxidizing substances, chlorinated and halogenated hydrocarbons.
CONDITIONS FOR STORAGE: keep containers sealed in a dry, well-ventilated location, away from sources of heat, ignition and direct sun light. All containers must be clearly and permanently identified. If it is possible, store in original containers.
SECTION 8. EXPOSURE CONTROLS AND/OR PERSONAL PROTECTION
SECTION 7. HANDLING AND STORAGE
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
DATE OF ISSUANCE: SEPTEMBER 2018.
DATE OF NEXT REVISION: SEPTEMBER 2020
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8.1 CONTROL PARAMETERS
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME CAS # VLE-PPT VLE-CT VLE-P IBE
Aluminum 7429-90-5 1 mg/m3
--- --- ---
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME CAS # NIOSH REL - TWA ACGIH – TLV OSHA PEL- TWA
Aluminum 7429-90-5 10 mg/m3
--- 15 mg/m3
8.2 EXPOSURE CONTROLS Provide proper ventilation to keep, to prevent routine inhalation Ventilation must be adequate to keep the work atmosphere below the exposure limits pointed out in these MSDS. Keep in mind the usual occupational hygienic measures when handling chemical substances, Wash hands thoroughly before breaks and after working hours and apply skin care products afterwards. Avoid dust of inhalation.
8.3 EQUIPMENT FOR PERSONAL PROTECTION
PROTECTION OF AIRWAYS AND RESPIRATORY TRACT: Use half-mask or full-face mask respirator with cartridges for powder.
EYES PROTECTION: wear safety glasses with side shields.
Physical state solid
Color silver
Odour characteristic
Melting temperature, °C 660
Steam pressure, mmHg at 20°C ND
Solubility in water g/ml Insoluble
Flash point, °C NA
SECTION 9. PHYSYCAL AND CHEMICAL PROPERTIES
SAFETY DATA SHEET ALU D1050 PR
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Boiling temperature, °C >2400
Ignition temperature, °C ND
Particle size, micrometer 46-54
Bulk density, Kg/L NA
Explosivity limit: >30 gr/m³
NA: Not applicable ND: Not defined
10.1 REACTIVITY: Flammable solid
10.2 CHEMICAL STABILITY: Product is stable in environmental and pressure conditions. Reacts exothermically in the presence of compounds of active hydrogen atoms (such as acids and water) to produce flammable hydrogen gas.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: Reacts with acids, alkalis, and oxidizing agents. Generation of dust clouds may be explosive. If it comes into contact with acids and bases, hydrogen is formed.
10.4 INCOMPATIBLE MATERIALS: Strong oxidizing agents, strong acids, strong bases, alkalis and chlorinated and halogenated hydrocarbons.
INGESTION: It may cause mild abdominal pain and vomit.
INHALATION: It may cause slight irritation and dryness in throat and nose, cough, headache and tearing.
CUTANEOUS: It may cause slight swelling and irritation, erythema, reddening and rash in the affected area.
EYES: It may cause slight irritation and reddening.
11.2 SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL CHARACTERISTICS.
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
SAFETY DATA SHEET ALU D1050 PR
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CORROSION/SKIN IRRITATION: as per information available from trials on rats, Aluminum causes a mild irritation and rash that disappears when area affected is washed with water.
SEVERE EYE INJURIES/EYE IRRITATION: as per available information of tests on rabbits, aluminum causes slight irritation and reddening that disappears before 21 days under observation.
RESPIRATORY SENSITIZATION: as per available information from tests applied to rats, prolonged contact and in high doses causes lung damage
SKIN SENSITIZATION: As per available information from tests applied in rats, components mixtures do not cause skin sensitization
GERM CELL MUTAGENICITY: As per available information from tests applied in mice in vitro/in
vivo, t does not show alterations or damages in the structure of its DNA. CARCINOGENICITY: According to the available information, it is not classified as a carcinogenic
product in IARC
REPRODUCTIVE TOXICITY: There is enough information
SPECIFIC TARGET ORGAN TOXICITY AFTER SOLE EXPOSITION: There is enough information. SPECIFIC TARGET ORGAN TOXICITY AFTER REPEATED EXPOSURES: There is no available information on this risk.
ASPIRATION HAZARD: There is no available information.
11.3 CHRONIC EFFECTS FROM SHORT- AND LONG-TERM EXPOSURE:
INHALATION: Inhalation of dust and metallic fumes, organic vapors above permissible values (Refer to Section 8 in these MSDS) may cause irritation of movement control. and dry throat, cough, headache and tearing
INGESTION: Under normal use the product has no chronic effects. An intake in excessive amounts can cause gastrointestinal ulceration
11.4 NUMERAL MEASURES OF TOXICITY Organism DL50/CL50 Exposition time Reference
Rat
ALUMINUM: DL50=1130mg/Kg-Oral
ND Prediction of Rodent Oral Toxicity. http://tox.charite.de/tox/
ALUMINUM: DL50=370mg/Kg-Oral
48 hours
PubChem. Open Chemistry Database. U.S. National Library of Medicine. https://puchem.ncbi.nlm.nlh.gov
11.5 OTHER TOXICOLOGICAL INFORMATION: ND.
12.1 ECOTOXICITY According to the information available, the coated aluminum does not have toxicity
effects in the environment
12.2 PERSISTENCE AND DEGRADABILITY: There is not enough information.
12.3 BIOACCUMULATION POTENTIAL: There is not enough information
SECTION 12. ECOLOGICAL INFORMATION
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
DATE OF ISSUANCE: SEPTEMBER 2018.
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12.4 MOBILITY IN SOIL: According to available information, coated Aluminum has no adverse effects on
soil.
12.5 OTHER ADVERSE EFFECTS: ND.
Disposal of Aluminum residues and its containers should be performed in accordance with local, regional, national and international existing regulations. Wear personal protective equipment (refer to Section 8 in these MSDS). Keep product in a clean, hermetically sealed container and labelled as hazardous material. Do not reuse the containers after it has been used. It must not be disposed of in the normal domestic waste. Do not flush into sanitary sewer system. Request specialist assistance if necessary. UN Number 1309 United Nations Proper Shipping Name Powder coated aluminum. (Transport) Hazard Class 4.1
Subsidiary risk NA
Packing Group III
Special provisions (guide number) 170
Transport Pictogram
Category/Land Transport, ADR/RID class YES ( X ) NO ( ) CLASS: 4.1 PACKING GROUP: III
Environmental Risks, IMDG Marine Pollutant YES ( ) NO ( X ) CLASS: 4.1 PACKING GROUP: III EMF Guide: F-G, S-G
Category/Air Transport, IATA/ICAO class YES ( X ) NO ( ) CLASS: 4.1 PACKING GROUP: III
14.1 SPECIAL PRECAUTIONS FOR USERS: ND.
SECTION 13. DISPOSAL CONSIDERATIONS
SECTION 14. TRANSPORT INFORMATION
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
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15.1 INTERNATIONAL REGULATIONS FOR HAZARDOUS CHEMICAL SUBSTANCES
Chemical Name
CAS number TSCA (EU)
California Preposition 65
AICS (Australia)
KECI (Korea)
CERCLA (EU)
DSL (Canada)
Aluminum 7429-90-5 X NL X X X X
Chemical Name
N. CAS ENCS (Japan)
NZloC (New Zealand)
IECSC (China)
PICSS (Philippines)
EINECS (Europe)
SVHC
Aluminum 7429-90-5 NL X X X X NL X: Listed NL: Not Listed
15.2 MEXICAN REGULATIONS ON HAZARDOUS AND ENVIRONMENTAL CHEMICAL SUBSTANCES Chemical Name CAS number SINSQ PROFEPA Montreal
Protocol Stockholm Protocol
Rotterdam Protocol
Aluminum 7429-90-5 X X NL NL NL X: Listed NL: Not Listed
16.1 ABBREVIATIONS ACGIH:
American Conference of Governmental Industrial Hygienists.
ACIS: Australian Inventory of Chemical Substances
ADR: Accord European sur le transport des merchandises danger uses par route (Europe Agreement concerning the International Carriage of Dangerous Goods by Road)
ANSI: American National Standards Institute
CE50: Average Specific Concentration, Specific Concentration 50.
CERCLA: Comprehensive Environmental Response Compensation and Liability Act.
LC50: Average lethal concentration; lethal concentration 50.
LD50: Median lethal dose; lethal dose 50.
DSL: Household chemicals list
EINECS: European Inventory of Existing Commercial Chemical Substances.
ENCS: Inventory of Existing and New Chemical Substances.
MSDS: Material Safety Data Sheet.
HIMS: Healthcare Information Management System.
IARC: International Agency for Research on Cancer.
IATA: International Air Transport Association.
SECTION 15. REGULATORY INFORMATION
SECTION 16. OTHER INFORMATION
SAFETY DATA SHEET ALU D1050 PR
CODE: SG-07-RP-627
DATE OF ISSUANCE: SEPTEMBER 2018.
DATE OF NEXT REVISION: SEPTEMBER 2020
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IBE: Biological Exposure Index.
ICAO: International Civil Aviation Organization.
IMDG: International Maritime Dangerous Goods.
IUPAC: International Union of Pure and Applied Chemistry.
IECSC: Inventory of Existing Chemical Substances Produced or Imported in China.
KECI: Korea Existing Chemicals Inventory.
Log Kow: n-Octanol/Water Partition Coefficient
mg/l: Milligram per liter. Concentration Unit.
mg/m3: Milligram per cubic meter. Concentration Unit.
mg/Kg: Milligram per kilogram. Concentration Unit.
NA Not applicable.
ND Not defined.
N.E.P: No Especificado en otra Parte. (not specified somewhere else)
NIOSH: National Institute for Occupational Safety and Health.
CAS number: Assigned number to a chemical substance or compound.
EC number: European Community number.
UN number: Identification number for transportation of hazardous chemical substances as classified by the United Nations Organization
NZIoC: New Zealand Inventory of Chemicals.
OEL: Occupational Exposure Limit.
OSHA: Occupational Safety and Health Administration, US Department of Labor.
PEL: Permissible Exposure Limit
PICSS: Philippine Inventory of Chemical Substances.
Ppm: Parts per million.
PROFEPA: Federal Attorney’s Office for Environmental Protection
RID: Regulations Concerning the International Transport of Dangerous Goods by Rail (European law)
SGA: Globally Harmonized System of Classification and Labelling of Chemicals. (GHS)
SINSQ: National Chemical Substances Inventory System
SCBA: Self-Contained Breathing Apparatus
SVHC: Substances of Very High Concern.
TLV: Threshold Limit Value.
TSCA: Toxic Substances Control Act.
TWA: Time Weighted Average.
VLE-PPT: Occupational Exposure limit values-time weighted average
VLE-CT: Occupational Exposure Limit-short term.
VLE-P: Peak Exposure Limit Value.
16.2 REFERENCES
ACGIH® 2017 Threshold Limit Values for Chemical Substances in the Work Environment. Adopted by ACGIH® with Intended
Changes. See http://www.acgih.org/
Updates of the Stockholm and Rotterdam Conventions- 2017, The Parties to the Basel, Rotterdam and Stockholm
Conventions at a UNEP meeting in May 2017 have decided to add new chemicals in the Stockholm and Rotterdam
Conventions http://www.toxicologia.org.ar
California Division of Occupational Safety and Health (Cal/OSHA) Permissible Exposure Limits (PELs) from Table AC-1 last
viewed December 19, 2016, viewable at http://www.dir.ca.gov/title8/5155table_ac1.html.
California Preposition 65. State Of California Office Of Environmental Health Hazard Assessment Safe Drinking Water And
