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Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2...

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Several RT FE/AFE Organics from BI
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Page 1: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

Several RT FE/AFE Organicsfrom BI

Page 2: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

What are the organics?

Page 3: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

BI

• Chemical formula: C7H6N2

• Crystal structure: Pna21

Page 4: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

MBI

• Chemical formula: C8H8N2

• Crystal structure: Pn

• Room temperature ferroelectricity.

• PS is ~5μC/cm2 , polarization in a and c.

• Layer by layer.

a

c

a

b

Page 5: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

TFMBI

• Chemical formula: C8H5F3N2

• Crystal structure: P21/c

• Room temperature antiferroelectricity.

• Polarization along a.

a

c

Page 6: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

View from B direction in CA, BI, MBI and TFMBI

CA

TFMBI

MBI

BI

Page 7: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

View from c direction of CA and MBI

CA

MBI

Page 8: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

MBI deviceSolution shearing

polarization

Page 9: Several RT FE/AFE Organics from BI - Thin Film Materials ... · MBI • Chemical formula: C8H8N2 • Crystal structure: Pn • Room temperature ferroelectricity. ... polarization

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