Solid Oxide Fuel Cells 14 (SOFC-XIV)
S. C. Singhal
K. Eguchi
Editors:
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Vol. 68, No. 1
High Temperature Materials
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v
ECS Transactions, Volume 68, Issue 1
Solid Oxide Fuel Cells 14 (SOFC-XIV)
Table of Contents
Preface iii
Chapter 1
Plenary Lectures - R&D Overviews
The Status of SOFC R&D in the Fuel Cell and Hydrogen Joint Undertaking Program
M. Atanasiu
3
Current Status of National SOFC Projects in Japan
M. Kadowaki
15
Accomplishments, Status, and Road Map for the US Department of Energy's Fossil
Energy SOFC Program
B. M. White, W. L. Lundberg, J. F. Pierre
23
The Promise and Challenges of Intermediate Temperature Fuel Cells
S. J. Litzelman, J. P. Lemmon
39
Chapter 2
Stack and System Designs, Performance and Durability
Recent Progress of SOFC Combined Cycle System with Segmented-in-Series Tubular
Type Cell Stack at MHPS
K. Miyamoto, M. Mihara, H. Oozawa, K. Hiwatashi, K. Tomida, M. Nishiura,
H. Kishizawa, R. Mori, Y. Kobayashi
51
Framework for Analysis of Irreversible Fuel Cell Heat Engine Hybrids
M. C. Williams, R. Gemmen, K. Gerdes
59
Operational Aspects for Direct Coupling of Gas Turbine and Solid Oxide Fuel Cells
M. Henke, C. Willich, M. Steilen, C. Schnegelberger, J. Kallo, K. A. Friedrich
79
vi
Construction of a 30kW SOFC Gas Turbine Hybrid Power Plant
M. Henke, M. Steilen, C. Schnegelberger, M. Riedel, M. Hohloch, S. Bücheler,
M. Herbst, A. Huber, J. Kallo, K. A. Friedrich
85
Development of Solid Oxide Fuel Cells at Versa Power Systems and FuelCell Energy
B. P. Borglum, H. Ghezel-Ayagh
89
Ceres Power Steel Cell Technology: Rapid Progress Towards a Truly Commercially
Viable SOFC
R. T. Leah, A. Bone, M. Lankin, A. Selcuk, M. Rahman, A. Clare, L. Rees, S. Phillip,
S. Mukerjee, M. Selby
95
Hexis and the SOFC System Galileo 1000 N: Experiences from Lab and Field Testing
A. Mai, J. A. Schuler, F. Fleischhauer, V. Nerlich, A. Schuler
109
Development, Manufacturing and Deployment of SOFC-Based Products at
SOLIDpower
M. Bertoldi, O. Bucheli, A. Ravagni
117
Sunfire Industrial SOC Stacks and Modules
T. Strohbach, F. Mittmann, C. Walter, D. Schimanke, C. Geipel
125
Application-Oriented Design and Field Trial of the Eneramic® Power Generator
S. Reuber, S. Megel, C. Jürgens, T. Pfeifer, M. Bednarz, C. Wunderlich, A. Michaelis
131
Standalone Portable SOFC Power Generator for Autonomous Operation
M. Reissig, J. Mathé, S. Planitzer, R. Vötter, J. Rechberger
143
Status of Solid Oxide Fuel Cell Development at Elcogen
M. Noponen, P. Torri, J. Göös, D. Chade, P. Hallanoro, A. Temmo, A. Koit,
E. Ounpuu
151
Solid Oxide Fuel Cell, Stack and System Development Status at Forschungszentrum
Jülich
L. Blum, P. Batfalsky, Q. Fang, L. G. J. de Haart, J. Malzbender, N. Margaritis,
N. H. Menzler, R. Peters
157
Smart Fuel Cell Demonstration Project: A Challenge to Realize SOFC-Powered
Campus
K. Sasaki, S. Taniguchi, Y. Shiratori, A. Hayashi, T. Oshima, M. Nishihara,
Y. Tachikawa, T. Daio, T. Kawabata, M. Fujita, A. Zaitsu
171
vii
A Case Study Analysis of System Efficiency, Viability and Energy Values of SOFC
Based Fuel Cell Micro-CHP for Office Buildings
A. T. Tesfai, A. Mylona, P. Connor, M. Cassidy, J. T. S. Irvine
179
Microtubular SOFC (mSOFC) System in Truck APU Application
K. Kendall, J. Newton, M. Kendall
187
Small Scale Power Generation for Road Trucks with Planar SOFC System
U. Bossel
193
Development of Micro Power Generator Using LPG-Fueled Microtubular Solid Oxide
Fuel Cells
H. Sumi, T. Yamaguchi, T. Suzuki, H. Shimada, K. Hamamoto, Y. Fujishiro
201
Status of Light Weight Cassette Design of SOFC
N. Margaritis, L. Blum, P. Batfalsky, D. Bohmann, S. Ceschini, Q. Fang,
D. Federmann, J. Kroemer, R. Peters, R. Steinberger-Wilckens
209
Thermal Integration of SOFC and Plate Heat Exchanger Desorber
V. Venkataraman, A. W. Pacek, R. Steinberger-Wilckens
221
Thermodynamic Performance of a High Efficient Power Plant Based on Faecal Biomass
Gasification, Solid Oxide Fuel Cells and Micro Steam Turbine
M. Recalde, T. Woudstra, M. Liu, P. V. Aravind
241
Analysis of Performance Limiting Factors in Solid-Oxide Iron-Air Redox Battery
Operated with Different Redox Couples
X. Jin, X. Zhao, R. E. White, K. Huang
251
Integrated Air Preheater and Anode Off-Gas Oxidizer
Y. De Vos, J. P. Janssens
269
Thermodynamic Evaluation of Integrated Heat-Pipe Reformer SOFC System
S. Herrmann, M. Jimenez Arreola, M. Gaderer, H. Spliethoff
277
Analysis of a Solid Oxide Fuel Cell System with Low Temperature Anode Off-Gas
Recirculation
M. Engelbracht, R. Peters, L. Blum, D. Stolten
283
viii
Numerical Simulation of SOFC System Performance at 90% Fuel Utilization with or
without Anode Off-Gas Recycle for Enhancing Efficiency
Y. Tanaka, T. Terayama, A. Momma, T. Kato
293
Effects of SOFC Exhaust Gas Recirculation on Performance of Solid Oxide Fuel
Cell-Gas Turbine Hybrid System Utilizing Renewable Fuels
D. Saebea, S. Authayanun, Y. Patcharavorachot, A. Arpornwichanop
301
Analysis of Transient Behavior of Fuel Reformer to Fuel Supply Variation in Solid
Oxide Fuel Cell Systems with Anode Off-Gas Recycle
T. Terayama, A. Momma, Y. Tanaka, T. Kato, N. Hoshi
315
Assessment of Possibilities for Operation of Ni-Catalyst Partial Oxidation Reformers in
SOFC Systems after Soot Formation
A. P. Baskakov, N. Plotnikov, W. Wang, J. Peng, Y. Volkova, Z. Dong, X. Lu, Q. Luo
327
Sensitivity Analysis for the Efficiency Improvement of a Light Integrated Gasification
Fuel Cell Power Plant
B. N. Taufiq, Y. Kikuchi, T. Ishimoto, K. Honda, M. Koyama
333
Catalytic Total Oxidation of SOFC Exhaust Gas on Cu-Mn Catalysts
J. G. Sung, K. H. Song, J. S. Chung, N. M. Sammes
343
Chapter 3
Electrolyte Materials, Fabrication and Performance
Synthesis, Characterization and Performance of Calcium and Samarium Co- doped
Ceria Electrolytes for Low and Intermediate Temperature Solid Oxide Fuel Cells
D. Pandey, S. Basu
351
Characterization of Terbium and Samarium Co-Doped Ceria Films as SOFC Electrolyte
Prepared by Using Ultrasonic Spray Pyrolysis Method
M. Vestli, G. Nurk
359
Praseodymium Doped Ceria: The Role of 4f-Electrons of Pr Dopant in Doped Ceria
M. Alaydrus, M. Sakaue, N. H. Linh, S. M. Aspera, T. D. K. Wungu, H. Kasai
369
High Temperature Strength and Elastic Properties of Doped Ceria under Various
Oxygen Partial Pressures
T. Taguchi, S. Watanabe, K. Sato, T. Hashida
375
ix
Effects of Copper Oxide Addition on the Electrochemical Properties of Samarium
Doped Ceria Electrolyte for Intermediate Temperature Solid Oxide Fuel Cells
S. Y. Toor, E. Croiset
387
Advanced Impedance Spectroscopy Study of the Influence of the Crystalline Structure
on the Ionic Conduction of Thin Solid-State Electrolytes
L. Fernandez Macia, D. Van Laethem, S. Van Steenberge, D. Depla, J. Deconinck,
A. Hubin
395
Effect of Ceria Content of CeScSZ Powder on the Phase Stability and Electrical
Conductivity of SOFC Electrolyte
S. W. Choi, K. J. Kim, M. Y. Kim, J. Lim, S. H. Yang, Y. S. Kim, H. S. Kim
405
Effect of Bismuth Oxide as Sintering Aid for Gadolinia-doped Ceria at 1050°C
V. De Marco, V. M. Sglavo
413
Single Cubic Phase Scandia-Stabilized Zirconia: Stabilization and Aging at 600oC
E. Z. Santos, R. Muccillo
421
Fabrication of Thin-Film Yttria-Stabilized Zirconia Electrolyte by Aerosol-Assisted
Chemical Vapor Deposition
D. Y. Jang, M. Kim, H. J. Kim, K. Bae, J. W. Kim, J. H. Shim
429
Dominant Factors Influencing the Electrochemical Performance of Plasma-Sprayed
LSGM Electrolyte
S. L. Zhang, C. X. Li, C. J. Li
433
Grain Size Effect on Conductivity of LSGM Thin Film Electrolyte for Solid Oxide Fuel
Cell
Y. Endo, A. Dempoh, T. Terai, A. Suzuki
441
Influence of Substrate on Conductivity of Sr and Mg Doped Lanthanum Gallate Thin
Film Electrolyte for Solid Oxide Fuel Cell
A. Dempoh, Y. Endo, T. Terai, A. Suzuki
449
Understanding the Aging Degradation of Doped Barium Cerate Proton Conductor in
Ambient Air at Room Temperature
N. Yan, T. Gao, W. Wang, J. L. Luo
457
Influence of Sintering Additive on the Electrical Conductivity, Chemical Stability and
Sinterability of BaCe0.55Zr0.3Y0.15O3-δ
H. An, D. Shin, S. M. Choi, J. Hong, K. J. Yoon, J. W. Son, B. K. Kim, J. H. Lee
467
x
Comparative Study of BaY0.1Ce0.9O3-δ Membrane with BaY0.1Zr0.9O3-δ Protective
Layers Synthesized with Spray Pyrolysis and Magnetron Sputtering Methods
M. Maide, O. Korjus, M. Vestli, T. Romann, G. Nurk
473
Low Temperature Synthesis of Sub-micrometer Yttria-doped Barium Zirconate Thin
Films by Modified Chemical Solution Deposition Technique
M. Biswas, H. Xie, P. C. Su
481
Cell Performance of Anode-Supported BaZr0.85Y0.15O3-δ/Carbonate Composite
Electrolyte at Intermediate Temperature
J. T. Kim, K. Y. Park, J. Y. Park
489
Evaluation of Gadolinium Doped Barium Zirconate Electrolyte for Solid Oxide Fuel
Cell
D. Z. de Florio
497
Yttrium and Nickel Co-Doped BaZrO3 as a Proton-Conducting Electrolyte for
Intermediate Temperature Solid Oxide Fuel Cells
S. P. Shafi, L. Bi, S. Boulfrad, E. Traversa
503
Synthesis of Pure La10-XSrxSi6O27-0.5x Apatites Using an Optimized Sol-Gel Process
Y. Ma, N. Fenineche, M. Moliere, O. El-Kedim, P. Briois
509
Degradation of Electrical Conductivity in Lanthanum Silicate Oxyapatite
T. Ishiyama, H. Maruyama, H. Kishimoto, K. D. Bagarinao, T. Horita, K. Yamaji,
A. Yamazaki
523
Doped Apatites for Novel Solid Oxide Fuel Cell Applications
J. W. N. E. Ow, F. Musso, M. Bertuzzo, M. Alfredsson, F. Corà
529
Physical-Chemical Properties of Bi13-XMexMo5O34±δ (Me = Mg, Ca, Sr, Ba) Solid
Solutions
Z. Mikhaylovskaya, E. Buyanova, M. Morozova, S. Petrova, I. Nikolaenko
539
Chapter 4
Cathode Materials, Fabrication and Performance
Materials Search of Perovskite Cathode in SOFC by Statistical Analysis
J. Hwang, Y. Ando, S. Watanabe
549
xi
Surface Composition and Oxygen Transport Properties of LSCF: From Bulk Ceramics
to Devices
J. Druce, H. Téllez, T. Ishihara, J. A. Kilner
557
Study of 2R-Cell Equipped with LSC and LSCF Cathodes under Thermic and Redox
Cycling
P. Coquoz, C. Grize, J. Ruiz, A. Bourradou, S. Diethelm, V. Singh, R. Ihringer
569
Influence of Hetero Grain Boundaries on Oxygen Exchange Activity: Investigation of
Two-Phase (La,Sr)CoO3-δ / (La,Sr)2CoO4+δ Cathode Materials
S. Stämmler, R. Merkle, B. Stuhlhofer, G. Logvenov, J. Maier
579
Soft X-Ray Absorption and Photoemission Study on the Electronic Structure of
(La,Sr)CoO3
S. Miyoshi, S. Yamaguchi
591
Quantifying Chemical Expansion of Non-Stoichiometric Oxide Thin Films: Challenges
and Opportunities
J. G. Swallow, J. J. Kim, D. Chen, S. R. Bishop, J. F. Smith, H. L. Tuller,
K. J. Van Vliet
599
Understanding the Operating Mechanisms of Mixed Ionic Electronic Conductors: From
Synchrotron-Based 3D Reconstruction to Electrochemical Characterization and
Modeling
M. Hubert, J. Laurencin, P. Cloetens, K. Couturier, F. Lefebvre-Joud, P. Bleuet,
E. Siebert
609
Quantitative Evaluation of Electrochemically Active Area in an SOFC Cathode by
Oxygen Isotopic Exchange Measurements of a Model Patterned Electrode
Y. Fujimaki, T. Nakamura, K. D. Bagarinao, K. Yamaji, K. Yashiro, T. Kawada,
F. Iguchi, H. Yugami, K. Amezawa
623
Confidence Limits in the Oxygen Transport Parameters of the
(La0.8Sr0.2)(Cr0.2Fe0.8)O3-δ Determined By the Isotopic Exchange, Depth Profiling
Method
R. J. Chater
631
Theoretical Study on Oxygen Dissociation Reaction on LaSrCoO3
T. Ishimoto, K. Sato, T. Tada, K. Amezawa, M. Koyama
651
xii
Evaluation of Exchange Current Density for LSM Porous Cathode Based on
Measurement of Three-Phase Boundary Length
K. Miyoshi, T. Miyamae, H. Iwai, M. Saito, M. Kishimoto, H. Yoshida
657
In-Situ Surface Analysis of SOFC Cathode Degradation Using High Temperature
Environmental Scanning Electron Microscopy
M. Niania, R. Podor, S. J. Skinner, J. A. Kilner
665
Changes in SOFC Cathode Crystallographic Structure Induced by Temperature,
Potential and Oxygen Partial Pressure Studied Using in-Situ HT-XRD
I. Kivi, J. Aruväli, K. Kirsimäe, A. Heinsaar, G. Nurk, E. Lust
671
Surface Segregation Phenomena in La0.6Sr0.4Co0.2Fe0.8O3-δ Subjected to Mechanical
Stress
W. Araki, W. Tanii, Y. Arai
681
Electrochemical Performance of Solid Oxide Cell Oxygen Electrodes Under
Pressurization
G. Hughes, J. Railsback, D. Butts, S. A. Barnett
687
Fundamental Impact of Humidity on SOFC Cathode Degradation
Y. L. Huang, C. Pellegrinelli, E. D. Wachsman
699
An Elementary Kinetic Model for the Electrochemical Reduction of Oxygen on
LSM/YSZ Composite Cathodes
A. Banerjee, O. Deutschmann
713
Surface Modification of La0.6Sr0.4Co0.2Fe0.8O3-δ Cathode by Atomic Layer Deposition of
La0.6Sr0.4CoO3-δ for High-Performance Solid Oxide Fuel Cells
H. J. Choi, K. Bae, D. Y. Jang, S. W. Park, G. D. Han, J. H. Shim
729
Thermodynamic Stability Assessment of MIEC Cathode Materials for Solid Oxide Fuel
Cells
D. Cetin, Y. Yu, H. Luo, X. Lin, U. B. Pal, S. N. Basu, S. Gopalan
735
An Interfacial Nanospike-Structured Cathode for Low Temperature Solid Oxide Fuel
Cells
H. Ding, X. Xue
743
Characterization of the Contact Resistance of Cathodic SOFC Contacting
D. Udomsilp, D. Roehrens, N. H. Menzler, R. Conradt, O. Guillon
751
xiii
Microstructure and Polarization characteristics of LSCF-GDC Composite Cathode with
Different Volume Fractions
Y. T. Kim, A. Ohi, A. He, Z. Jiao, T. Shimura, D. Klotz, S. Hara, N. Shikazono
757
High-Performance Cathode/Electrolyte Interfaces for SOFC
J. Szász, F. Wankmüller, V. Wilde, H. Störmer, D. Gerthsen, N. H. Menzler,
E. Ivers-Tiffée
763
Investigating the Relationship between Operating Conditions and SOFC Cathode
Degradation
C. Pellegrinelli, Y. L. Huang, J. A. Taillon, L. G. Salamanca-Riba, E. D. Wachsman
773
Solid Oxide Steam Electrolysis Anodes with Precisely Controlled Microstructure for
Performance Analysis
G. C. Clancy, B. A. Peppley, J. G. Pharoah, D. Ryland
785
Chromium Deposition and Poisoning of LSCF and LSM Oxygen Electrodes of Solid
Oxide Electrolysis Cells
K. Chen, W. Bo, J. Hyodo, T. Ishihara, S. P. Jiang
793
Surface Oxygen Exchange Properties of Sr Doped La2NiO4+δ as SOFC Cathode:
Thin-Film Electrical Conductivity Relaxation Investigation
B. Guan, W. Li, X. Zhang, X. Liu
801
Effect of Nature of the Ceramic Component of the Composite Electrodes Based on
La1.7Ca(Sr)0.3NiO4+δ on Their Electrochemical Performance
E. Pikalova, N. Bogdanovich, A. Kolchugin, A. Brouzgou, D. Bronin, S. V. Plaksin,
A. Khasanov, P. Tsiakaras
809
Ln2NiO4+δ (Ln = La, Pr) As Suitable Cathodes for Metal Supported Cells
A. D. Rougier, A. Flura, C. Nicollet, V. Vibhu, S. Fourcade, E. Lebraud, J. M. Bassat,
J. C. Grenier
817
Influence of La/Pr Ratio on the Ageing Properties of La2-XPrxNiO4+δ as Cathodes in
IT-SOFCs
V. Vibhu, J. M. Bassat, A. Flura, C. Nicollet, J. C. Grenier, A. Rougier
825
Lanthanum Nickelate Infiltration into Porous Gd-Doped Ceria As Cathode for Solid
Oxide Fuel Cells
C. Nicollet, A. Flura, V. Vibhu, A. Rougier, J. M. Bassat, J. C. Grenier
837
xiv
Elastoplastic Properties of (Pr, Ce)O2-δ Thin Films
J. G. Swallow, J. J. Kim, S. R. Bishop, J. F. Smith, H. L. Tuller, K. J. Van Vliet
847
Micro-Modelling of IT-SOFC Electrodes Manufactured through Electrospinning
A. Enrico, B. Aliakbarian, P. Perego, P. Costamagna
857
Stability of Bi2O3-Based Ionic Conductor and Its Application on Composite Cathode
S. Y. Tsai, K. Z. Fung, C. T. Ni, Y. F. Chang
867
Preparation and Characterization of Pr0.6Sr0.4CoO3-δ Cathodes in IT-SOFC
R. Kanarbik, I. Kivi, T. Tiirats, P. Möller, E. Lust
875
Solid Oxide Fuel Cells Using Novel Cathodes in the BaO-Co2O3-Fe2O3 Composited
with GDC10
P. Hing, M. Sukleung, N. Y. Voo, L. C. Lim, A. Atkinson
883
Fabrication of SmBa0.5Sr0.5Co2O5+δ Cathode Material and Its Application for Sr- and
Mg-Doped LaGaO3 Electrolyte-Supported Solid Oxide Fuel Cell
T. N. Lin, R. Y. Lee, J. Y. Kuo, T. Ishihara, K. Hosoi
895
Characterisation and Electrochemical Properties of Ce0.8Sr0.2Fe0.9Ir0.04Co0.06 (CSFIC)
Cathode Material for Application in Low Temperature SOFC
C. Njoku, B. O. Omondi, P. Ndungu
903
Material Characteristics and Electrochemical Performance of YxBa2-XCo2O5+δ Cathode
for Solid Oxide Fuel Cell
I. M. Hung, J. A. Wang, J. Y. Kuo, T. N. Lin
919
Metal-supported Solid Oxide Fuel Cell with La0.4Sr0.6Co0.2Fe0.7Nb0.1O3-δ Cathode
T. Zhu, M. Han, Z. Yang
927
Electrochemical Characterization of Ag-Y0.5Bi1.5O3 Composite Cathode on
8YSZ-Ce0.78Gd0.2Sr0.02O2-δ Electrolyte Using AC Impedance Spectroscopy
C. H. Hua, C. C. Chou
935
Development of La0.6Sr0.4TiXFe1-XO3-Based Composite Cathode Materials for Solid
Oxide Fuel Cells
H. Iwai, S. Suzuki, K. Inaoka, A. Murakami, Y. Takahashi
941
Pr2NiO4+δ Cathode Properties and Reaction at Interface with Ceria and Zirconia
R. Chiba, H. Ishii
947
xv
Enhancing Performance of Stabilized Bismuth Oxide-Based Cathodes via Infiltration
Process for LT-SOFCs
J. W. Park, B. H. Yun, D. W. Joh, K. T. Lee
957
PrBaCo2O6-δ - Ce0.8Sm0.2O1.9 Composite Cathodes for Intermediate Temperature Solid
Oxide Fuel Cells
D. S. Tsvetkov, N. S. Tsvetkova, I. L. Ivanov, D. Malyshkin, V. V. Sereda, A. Y. Zuev
965
Crystal Structure and Characterization of La1-xBixMnO3+δ
O. Kaimieva, M. Morozova, E. Buyanova, Z. Mikhaylovskaya, S. Petrova,
N. Tarakina
977
Rate Determining Step in ORR of PrOx-Based Film Cathodes
S. Okada, S. Miyoshi, S. Yamaguchi
987
Enhanced Chromium Tolerance of La0.6Sr0.4Co0.2Fe0.8O3-δ Cathode by BaO Infiltration
K. Chen, N. Ai, S. P. Jiang
995
Annealing-Induced Surface Segregation and SrSO4 Formation on La0.6Sr0.4Co0.2Fe0.8O3-
δ Cathodes
K. D. Bagarinao, J. C. De Vero, D. H. Cho, H. Kishimoto, K. Yamaji, T. Horita,
H. Yokokawa
1003
Sulfur Poisoning of LSCF Cathode in Single Step Co-fired SOFC
N. Mori, Y. Sato, M. Iha, T. Takada, T. Konoike, H. Kishimoto, K. Yamaji,
H. Yokokawa
1015
Mechanism of SO2 Poisoning on the Electrochemical Activity of LSCF and LSM
Electrodes
C. Wang, S. P. Jiang
1023
Influence of Cathode Polarization Change on Chromium Deposited on Electrolyte
Surface Near Cathode Reaction Sites of SOFC
D. Ishibashi, E. Park, S. Taniguchi, Y. Inoue, J. T. Chou, K. Sasaki
1031
Effect of Chromium Vapor Pressure on Accelerated Poisoning Tests for
(La0.6Sr0.4)(Co0.2Fe0.8)O3 Cathode
D. H. Cho, K. D. Bagarinao, H. Kishimoto, K. Yamaji, T. Horita, H. Yokokawa
1039
Degradation of LSCF Cathode Induced by SO2 in Air
H. Kishimoto, F. Wang, D. H. Cho, P. Lv, K. D. Bagarinao, K. Yamaji, T. Horita,
H. Yokokawa
1045
xvi
Chapter 5
Anode Materials, Fabrication and Performance
Thermal Gradients in Solid Oxide Fuel Cell Anodes: X-Ray Diffraction, Thermal
Imaging and Model Prediction
J. B. Robinson, E. Engebretsen, L. D. Brown, R. Clague, D. Eastwood, C. Reinhard,
P. Lee, D. J. Brett, P. R. Shearing
1053
Characterization of Cracks and their Effects on the Effective Transport Pathways in Ni-
YSZ Anodes after Reoxidation Using X-Ray Nanotomography
A. Nakajo, A. M. Kiss, A. P. Cocco, W. M. Harris, M. B. DeGostin, F. Greco,
G. J. Nelson, A. A. Peracchio, B. N. Cassenti, A. Deriy, S. Wang, Y. Chen-Wiegart,
J. Wang, J. Van herle, W. K. S. Chiu
1069
In-Operando Raman Spectroscopy Study on Oxygen Chemical Potential Gradient in Ni-
SDC Cermet Anode for SOFCs
T. Matsui, K. Eguchi, T. Furukawa, T. Okanishi, H. Muroyama, K. Eguchi
1083
In Operando Optical Studies of SOFCs Operating with Butanol
J. D. Kirtley, M. B. Pomfret, D. A. Steinhurst, J. C. Owrutsky, R. A. Walker
1091
Phase Transition Mapping by Means of Neutron Imaging in SOFC Anode Supports
during Reduction under Applied Stress
M. G. Makowska, M. Strobl, E. Mejdal Lauridsen, H. L. Frandsen, A. Tremsin,
T. Shinohara, L. T. Kuhn
1103
Visualization of SOFC Anode by Dual Imaging Method Using Infrared and Visible
Light Cameras
Y. Tachikawa, T. Kawabata, Y. Shiratori, K. Sasaki
1115
In Situ Tailored Nickel Nano-Catalyst Layer for Internal Reforming Hydrocarbon
Fueled SOFCs
J. Myung, D. Neagu, M. Tham, J. T. S. Irvine
1121
Electrochemical Oxidation of CO/H2 Mixtures on Ni and Ceria Pattern Anodes
A. N. Tabish, H. C. Patel, F. Comelli, P. V. Aravind
1129
Kinetics of Internal Methane Reforming on the Anodes of Low Temperature Ceres
Power Steel Cell SOFCs
R. T. Leah, M. Lankin, A. Bone, S. Mukerjee, M. Selby
1137
xvii
Gas Composition Analysis on Ni-YSZ Anode in Direct Internal Reforming Solid Oxide
Fuel Cell
H. Muroyama, D. Ando, T. Okanishi, T. Matsui, K. Eguchi
1151
Impedance Studies of the Reduction Process in NiO-YSZ SOFC Anodes
D. Vladikova, Z. Stoynov, Z. Wuillemin, D. Montinaro, P. Piccardo, I. Genov,
M. Rolland
1161
Kinetic Studies on Ni-YSZ Composite Electrodes
J. C. Njodzefon, B. R. Sudireddy, J. Hjelm, C. Graves
1169
Permeability of Gases in the Anode of an Anode Supported SOFC
M. Geagea, I. Genov, Z. Stoynov, D. Vladikova, A. Chesnaud, A. Thorel
1185
Evaluating the Behavior of CO/CO2 in Ni/GDC Solid Oxide Fuel Cell Anodes
L. Wang, G. S. Jackson
1193
Study of Water Gas Shift Reaction over Ceria Based Catalysts in Solid Oxide Fuel Cells
P. Tepamatr, E. Buarod, N. Laosiripojana, S. Charojrochkul
1207
Impregnation of Nanoparticle Scaffolds for Syngas-Fed Solid Oxide Fuel Cell Anodes
P. Boldrin, E. Ruiz-Trejo, C. Tighe, K. C. Chang, J. Darr, N. P. Brandon
1219
The Influence of Reduction Conditions on a Ni-YSZ SOFC Anode Microstructure and
Evolution
H. Monzón, M. A. Laguna-Bercero
1229
Local Evolution of Three-Dimensional Microstructure Morphology of Planar
Anode-Supported SOFC
G. A. Brus, H. Iwai, Y. Otani, A. Sciazko, M. Saito, H. Yoshida, J. S. Szmyd
1237
Stability of Nickel-Infiltrated Anodes in Intermediate Temperature SOFCs
E. C. Miller, Q. Sherman, Z. Gao, P. W. Voorhees, S. A. Barnett
1245
Enhancing the Stability of Infiltrated Ni/YSZ Anodes
P. Keyvanfar, A. R. Hanifi, P. Sarkar, T. H. Etsell, V. Birss
1255
Performance Optimization of Cermet SOFC Anodes: An Evaluation of
Nanostructured NiO
I. Burmistrov, D. Agarkov, I. Tartakovskii, V. Kharton, S. Bredikhin
1265
xviii
Boundary Observation and Contrast Tuning of Ni/YSZ Anode by TEM and FIB-SEM
S. S. Liu, S. Matsumura, M. Koyama
1275
Numerical Assessment of SOFC Anode Polarization with Microstructure Evolution
Z. Jiao, T. Shimura, N. Shikazono
1281
Residual Stress in NiO-YSZ Composites and Its Relationship to Microstructure
Y. Akaza, T. Syu, F. Iguchi, M. Shimizu, H. Yugami
1291
Development of High Performance Anodes for Metal-Supported Fuel Cells
V. Rojek, D. Roehrens, M. Brandner, N. H. Menzler, O. Guillon, A. K. Opitz,
M. Bram
1297
SOFC Anode Based on YSZ Pillars
K. Nagato, S. Shinagawa, N. Shikazono, S. Iwasaki, M. Nakao
1309
Overpotential and Interfacial Conductivity of Ni/YSZ Anode Based on Species
Territory Adsorption Model in SOFCs
T. Nagasawa, K. Hanamura
1315
Understanding the Rheology of Screen-Printing Inks for the Fabrication of SOFC Thick
Films
M. R. Somalu, A. Muchtar, N. P. Brandon
1323
Evaluation of Ni-YSZ Anode Degradation during Redox Cycling
T. Shimura, Z. Jiao, S. Hara, N. Shikazono
1333
Oxidation-Induced Degradation of SOFC Ni Anodes at High Fuel Utilizations
T. Kawasaki, J. Sugimoto, Y. Tachikawa, Y. Shiratori, S. Taniguchi, K. Sasaki
1345
Sulfur Tolerance of Au-Mo-Ni/GDC SOFC Anodes Under Various CH4 Internal Steam
Reforming Conditions
C. Neofytides, M. Athanasiou, S. G. Neophytides, D. K. Niakolas
1353
Performance Factors and Sulfur Tolerance of Metal Supported Solid Oxide Fuel Cells
with Nanostructured Ni:GDC Infiltrated Anodes
J. Nielsen, B. R. Sudireddy, A. Hagen, H. Persson
1361
Lifetime and Performance Prediction of SOFC Anodes Operated with Trace Amounts
of Hydrogen Sulfide
M. Riegraf, G. Schiller, R. Costa, K. A. Friedrich, A. Latz, V. Yurkiv
1373
xix
The Influence of Sulfur Poisoning and YSZ Substrate Orientation on Electrochemical
Properties of Nickel Pattern Anodes
M. C. Doppler, J. Fleig, A. K. Opitz
1383
Performance Recovery of Sulfur Poisoning Anode and Prevention of Sulfur Poisoning
by Shifting Anode Potential for Solid Oxide Fuel Cell
Y. Yamada, R. Okubo, M. Kinoshita, M. Yoshinaga, E. Niwa, T. Hashimoto,
K. Tomomichi, K. Sasaki
1391
Li/Na Modified Ni-SDC Anode for Methane-Fueled Solid Oxide Fuel Cells
L. Liu, Q. Yang, W. Yang, X. Qi, C. Sun, L. Chen
1403
Fabrication of a Ni/MgO Nanocomposite Catalyst by Exolution
Y. S. Lim, J. S. Yoon, B. H. Choi, W. S. Seo, H. J. Hwang
1411
Investigation of Novel Electrocatalysts for Metal Supported Solid Oxide Fuel Cells -
Ru:GDC
B. R. Sudireddy, J. Nielsen, K. T. S. Thydén, A. H. Persson, K. Brodersen
1417
Impedance Study of Anodic Properties of Ni-Fe Impregnated SDC
Y. Itagaki, T. Takemasa, S. Yamaguchi, H. Yahiro
1427
La, Y and Nb Doped SrTiO3 Anodes for Electrolyte Supported SOFC
P. K. Tiwari, S. Basu
1435
Development of Robust SOFC Anode Materials Using La-Doped SrTiO3
X. Shen, K. Sasaki
1447
Nickel Doped Lanthanum Chromite Perovskite: A Novel Regenerable Anode Material
for Solid Oxide Fuel Cells
Y. F. Sun, M. N. Wang, J. L. Luo
1455
Chemical Compatibility of A-site Deficient La Substituted SrTiO3 Anode and Stabilized
Zirconia Electrolyte
G. Chen, Y. Luo, Y. Gao, R. Guo, W. Ma, M. Liu, S. Geng
1465
Performance and Redox-stability of La and Ni Co-doped SrTiO3 Anode of Solid Oxide
Fuel Cell
B. H. Park, G. M. Choi
1473
xx
Characterization of Y-Doped SrTi1-XVxO3 (Y = 0.1, x = 0.1 and 0.2) Anodes for SOFCs
M. F. Mohammed Basheer, L. C. Ming, P. I. Petra, A. K. Azad
1481
Low Ni-Containing Anodes Using Titanate-Based Perovskites for Methane Direct
Internal Reforming Power Generation
R. Kikuchi, D. Minori, A. Takagaki, T. Sugawara, S. T. Oyama
1489
Screen Printed Porous La0.20Sr0.25Ca0.45TiO3 Fuel Electrode Scaffold Microstructures:
Optimisation of Interaction with Impregnated Catalysts for More Durable Performance
R. Price, M. Cassidy, J. A. Schuler, A. Mai, J. T. S. Irvine
1499
The Effect of Mn Co-doping on the Electrochemical Properties of Gd0.2Ce0.8O1.9-d/Pt
Model-composite Electrodes
P. Velicsanyi, M. Gerstl, A. Nenning, H. Hutter, J. Fleig, A. K. Opitz
1509
Evaluation of the Influence of Nickel Addition on LST-CGO Based Solid Oxide Fuel
Cell Anodes Performance
V. Yurkiv, G. Constantin, A. Gondolini, E. Mercadelli, A. Sanson, L. Dessemond,
R. Costa
1517
Gradient Anode Functional Layer for Thin Y:BaZrxCe1-XO3 Electrolyte in
Low-Temperature Solid Oxide Fuel Cells
K. Bae, S. Lee, D. Y. Jang, H. J. Kim, H. Lee, D. Shin, J. W. Son, J. H. Shim
1527
Fabrication of Bimetallic (NiFe) Anode-Supported SOFCs with Direct Ceramic Inkjet
Printing
A. Fakeeh, R. I. Tomov, V. R. Kumar, B. A. Glowacki
1531
In-Situ Exsolution of Nano Transition Metal Particles on Lanthanum Chromite
Perovskite Anode for Solid Oxide Fuel Cells
Y. F. Sun, M. N. Wang, J. L. Luo
1541
Coking-Resistance and Sulfur-Tolerance Study of La0.4Sr0.6Co0.2Fe0.7Nb0.1O3-δ Anode
M. Han, N. Xu, Z. Yang, T. Zhu
1549
Mechanistic Considerations of Liquid Metal Anode SOFCs Fueled with Hydrogen
A. Toleuova, W. C. Maskell, V. Yufit, P. R. Shearing, D. J. Brett
1557
xxi
Chapter 6
Interconnection and Metallic Components
Protective Coatings for Metallic Components in Solid Oxide Fuel Cell Systems
N. J. Kidner, S. Ibanez, G. Arkenberg, M. M. Seabaugh, S. L. Swartz
1569
Coatings for SOFC Interconnects in Fuel Side Environments
R. Sachitanand, M. Sattari, J. E. Svensson, J. Froitzheim
1575
Properties of Spinel Protective Coatings Prepared Using Wet Powder Spraying for
SOFC Interconnects
J. E. Hong, M. Bianco, J. Van herle, R. Steinberger-Wilckens
1581
High Durability Electrodeposition Painting for SOFC Metal Interconnector
S. Inoue, H. Nonaka, T. Saito, M. Yoda, T. Nakao, Y. Takuwa
1589
Evaluation of Protective Coatings for SOFC Interconnects
J. Tallgren, M. Bianco, O. Himanen, O. Thomann, J. Kiviaho, J. van Herle
1597
Fabrication of Mn1.5Co1.5O4 by Electrostatic Spray Deposition for Application as
Protective Coating on Alloy Interconnects for Solid Oxide Fuel Cells
L. D. Conceição, E. Djurado, L. Dessemond, E. N. S. Muccillo
1609
Pre-Coated Ce/Co-Coated Steel: Mitigating Cr Vaporization, Increasing Corrosion
Resistance at Competitive Cost
H. Falk Windisch, I. Mertzidis, J. E. Svensson, J. Froitzheim
1617
Evaluation of a Novel Perovskite-Based Conversion Coating for Corrosion Protection
of 13Cr Ferritic Stainless Steels under Relevant SOFC Oxidizing Conditions
A. Masi, S. Frangini, M. Carlini, A. Masci, S. J. McPhail
1625
Interaction between Crofer 22 APU Current Collector and LSCF Cathode Contacting
Layer under Cell Operation
R. Spotorno, P. Piccardo, F. Perrozzi
1633
Dependence of Electrical Properties on Thermal Reduction of Protecting Oxides for
SOFC Interconnect Applications
S. Y. Tsai, K. Z. Fung, C. T. Ni, H. C. Ho
1641
Self Healing of Precoated AISI 441 for Solid Oxide Fuel Cell Interconnects
R. Berger, M. W. Lundberg, J. Westlinder, H. Holmberg
1649
xxii
A Time Resolved Study of Precoated AISI 441 for SOFC Interconnects Using
STEM-EELS - Part I
L. S. Karlsson, M. W. Lundberg, R. Berger, J. Westlinder
1657
A Time Resolved Study of Precoated AISI 441 for SOFC Interconnects Using
STEM-EELS - Part II
L. S. Karlsson, M. W. Lundberg, R. Berger, J. Westlinder
1667
Multilayered Precoated AISI 441 for Solid Oxide Fuel Cell Interconnects
M. W. Lundberg, R. Berger, J. Westlinder, H. Holmberg
1681
Modeling of Ni Diffusion Induced Austenite Formation in Ferritic Stainless Steel
Interconnects
M. Chen, S. Molin, L. Zhang, N. Ta, P. V. Hendriksen, W. R. Kiebach, Y. Du
1691
Metallic/Ceramic (Fe-22Cr mesh/ LaNi0.6Fe0.4O3-δ) Composite as Contact Material for
SOFCs
A. Morán-Ruiz, K. Vidal, A. Larrañaga, P. R. Slater, M. I. Arriortua
1701
Interdiffusion and Charge Transport Across Surface-Modified Current Collectors in
Planar SOFCs
N. Demeneva, D. Matveev, V. Kharton, S. Bredikhin
1707
Electrical and Oxidation Resistance of Surface Oxide of Porous Fe-Cr-Al Alloy for the
Application of Metal Supported SOFCs
H. C. Pham, S. Taniguchi, Y. Inoue, J. T. Chou, T. Izumi, K. Matsuoka, K. Sasaki
1715
Development of Metal Supported Solid Oxide Fuel Cell Based on Interconnect Coating
K. Lee, S. Jin, J. Kang, S. Lee, J. Bae
1721
Electrical Conducting Properties of LSF-Based Composites as an Interconnection of
Tubular Type of Solid Oxide Fuel Cells
J. H. Yu, H. L. Lee, H. C. Shin, S. Cho, J. H. Joo, C. Y. Yoo
1727
Chapter 7
Cell Designs, Fabrication, Performance and Durability
Manufacture of Solid Oxide Fuel Cells Using Electroless Co-Deposition: A Review of
Work Carried out at Edinburgh Napier University
A. Davidson, C. Wilson, N. Shearer
1735
xxiii
Results for a New SOFC-Stack Design with Parallel-Connected Cells
C. Szepanski, C. Immisch, A. Lindermeir, M. Faulstich, L. Dörrer, U. Schmidt,
G. Borchardt, J. Hamje, V. Wesling
1749
Mobilty of Sr in Gadolinia Doped Ceria SOFC Chemical Barrier Layers Prepared Using
Spray Pyrolysis, Pulsed Laser Deposition and Magnetron Sputtering Methods
G. Nurk, P. Möller, M. Vestli, R. Jaaniso, M. Kodu, H. Mändar, R. Kanarbik, E. Lust
1757
Microstructure-Based Damage Modelling of Plasma Sprayed Ceramic Coatings in
SOFC-Layer Systems
V. Guski, A. Krebs, U. Weber, S. Schmauder
1765
Atmospheric Plasma-Sprayed Metal-Supported Solid Oxide Fuel Cells with Varying
Cathode Microstructures
J. Harris, J. Kuhn, O. Kesler
1779
Electrochemical Performance of Plasma Sprayed Metal Supported Planar Solid Oxide
Fuel Cells
M. Gupta, A. Weber, N. Markocsan, M. Gindrat
1791
Degradation Studies and Sr Diffusion Behaviour in Anode Supported Cell after 3,000 h
SOFC Short Stack Testing
V. Miguel-Pérez, J. P. Ouweltjes, A. Tarancón, M. Torrell, V. Bongiorno,
Z. Wuillemin, D. Montinaro, A. Morata
1803
Chromium-Related Degradation of Thin-Film Electrolyte Solid Oxide Fuel Cell Stacks
N. H. Menzler, D. Sebold, Q. Fang
1815
Current Status of Rapid Evaluation of Durability of Six SOFC Stacks within Nedo
Project
H. Yokokawa
1827
Effect of Nanocrystalline Perovskite-Based Cathode Compositions on SOFC
Performance: An Aspect of Cell Stability with Composite Interlayer
K. Banerjee, J. Mukhopadhyay, R. N. Basu
1837
Ni-Mo Porous Alloy Fabricated as Supporting Component for Metal-Supported Solid
Oxide Fuel Cell and Cell Performance
S. F. Yang, Z. Y. Chuang Shie, C. S. Hwang, C. H. Tsai, C. L. Chang, T. J. Huang,
R. Y. Lee
1849
xxiv
Multi Length-Scale Quantification of Hierarchical Microstructure in Designed
Microtubular SOFC Electrodes
S. J. Cooper, T. Li, R. S. Bradley, K. Li, N. P. Brandon, J. A. Kilner
1857
Design and Fabrication of a 600W Anode Supported Flat Tubular SOFC Stack
W. Ji, L. Zhang, L. Ming, Y. Jiang, B. Xie
1865
Development of a Novel Co-fired SOFC at Murata
N. Mori, Y. Sato, H. Nakai, M. Iha, T. Takada, T. Konoike
1871
Development of Modelling and Testing for Analysis of Degradation in Solid Oxide Fuel
Cells
J. G. Maillard, R. Steinberger-Wilckens
1879
Beyond the 3rd Generation of Planar SOFC: Development of Metal Foam Supported
Cells with Thin Film Electrolyte
F. Han, R. Semerad, G. Constantin, L. Dessemond, R. Costa
1889
Solid Oxide Cell and Stack Testing, Safety and Quality Assurance (SOCTESQA)
C. Auer, M. Lang, K. Couturier, E. R. Nielsen, S. J. McPhail, G. Tsotridis, Q. Fu,
S. H. Chan
1897
Development of Toho Gas SOFC Cell Stack
S. Masuda, Y. Ogura, J. Shimano
1907
Fabrication of Large-area Multi-scale-architectured Thin-Film SOFC via Commercially
Viable Thin-film Technology
H. S. Noh, J. Hong, H. Kim, K. J. Yoon, B. K. Kim, J. H. Lee, J. W. Son
1915
Thermo-Mechanical Reliability of SOFC Stacks during Combined Long-Term
Operation and Thermal Cycling
F. Greco, A. Nakajo, Z. Wuillemin, J. Van herle
1921
Development of Electrolyte Supported Cells Based on a Thin 3YSZ Substrate: Through
Optimized Contact Layer to High Power Density
N. Trofimenko, M. Kusnezoff, D. Klemm, D. Schimanke
1933
Effect of LSCF Microstructure on GDC Interlayer Stability and Cation Diffusion in
Porous and Dense LSCF/GDC/YSZ Triplets
J. De Vero, K. D. Bagarinao, D. H. Cho, H. Kishimoto, K. Yamaji, H. Yokokawa
1943
xxv
Accelerated Lifetime Tests for SOFCs
A. Weber, J. Szász, S. Dierickx, C. Endler-Schuck, E. Ivers-Tiffée
1953
A Parametric Study of SOFC Performances with Multi-Stage Electrochemical
Oxidation for Enhancement of Electric Efficiency
Y. Matsuzaki, Y. Tachikawa, T. Hatae, H. Matsumoto, S. Taniguchi, K. Sasaki
1961
Shaping of a Dual Membrane SOFC and First Electrochemical Tests in a Dedicated
3-Chamber Set-up
D. Masson, F. Perrozzi, P. Piccardo, M. Viviani, C. Pilot, Z. Stoynov, D. Vladikova,
A. Chesnaud, A. Thorel
1969
Development of a SOFC Performance Model to Analyze the Powder to Power
Performance of Electrode Microstructures
D. A. W. Gawel, J. G. Pharoah, S. B. Beale
1979
Study on Direct Flame Solid Oxide Fuel Cell Using Flat Burner and Ethylene Flame
M. M. Hossain, J. Myung, R. Lan, M. Cassidy, I. Burns, S. Tao, J. T. S. Irvine
1989
Redox-Stable High-Performance Thin-Film Solid Oxide Fuel Cell
T. Keuter, D. Roehrens, N. H. Menzler, R. Vaßen
2001
Electrochemical Impedance Spectroscopy Investigation of the Anodic Functionalities
and Processes in LSCM-CGO-Ni Systems
S. Boulfrad, A. Nechache, M. Cassidy, E. Traversa, J. T. S. Irvine
2011
Towards the Design-Led Optimization of Solid Oxide Fuel Cell Electrodes
M. Kishimoto, M. Lomberg, E. Ruiz-Trejo, N. P. Brandon
2019
Application of Exsolved Structures as a Route to More Robust Anodes for Improved
Biogas Utilisation in SOFCs
M. Cassidy, S. Gamble, J. T. S. Irvine
2029
The Effect of Electrode Morphology on Solid Oxide Fuel Cell Performance
J. G. Pharoah, L. Handl, V. Schmidt
2037
Development of Tailored Porous Microstructures for Infiltrated Catalyst Electrodes by
Aqueous Tape Casting Methods
M. Cassidy, D. J. Doherty, X. Yue, J. T. S. Irvine
2047
xxvi
Effective Conductivity of Solid Oxide Fuel Cell Electrodes
K. Zheng, M. Ni
2057
Advanced 3D Imaging and Analysis of SOFC Electrodes
F. Tariq, M. Kishimoto, G. Cui, V. Yufit, M. Lomberg, E. Ruiz-Trejo, Z. Chen,
N. P. Brandon
2067
Direct Observation of the Current Distributions across SOFC by Measuring the Lateral
Voltage Differences
A. S. Devaraj, K. Yashiro, S. I. Hashimoto, T. Kawada
2075
Methodology for Analysis of Solid Oxide Cells via Raman Spectroscopy
J. Manerova, A. V. Call, D. C. Sinclair, R. H. Elder
2083
Analysis of Interfacial Processes at the SOFC Electrodes by In-Situ Raman
Spectroscopy
D. Agarkov, I. Burmistrov, F. Tsybrov, I. Tartakovskii, V. Kharton, S. Bredikhin,
V. Kveder
2093
Characterization and Stack Testing of Solid Oxide Fuel Cells with Cathodes Prepared
by Infiltration
R. Küngas, T. B. Hertz, T. Heiredal-Clausen
2105
Additive Manufacturing for Solid Oxide Cell Electrode Fabrication
M. Lomberg, P. Boldrin, F. Tariq, G. Offer, B. Wu, N. P. Brandon
2119
Fabrication and Microstructure of Self-Supporting Thin Ceramic Electrolytes Prepared
by Laser Machining
J. A. Cebollero, R. Lahoz, M. A. Laguna-Bercero, J. I. Peña, A. Larrea, V. M. Orera
2129
Influence of Convective Heat Transfer by Air Flow on Local Current/Temperatures
along Microtubular Solid Oxide Fuel Cells In-situ Identified by Electrodesegmentation
Method for Co- and Counter-flow Configurations
O. Aydin, H. Nakajima, T. Kitahara
2141
A 2D Stationary FEM Model for Hydrocarbon Fuelled SOFC Stack Layers
H. Geisler, S. Dierickx, A. Weber, E. Ivers-Tiffée
2151
CFY-Stack Technology: The Next Design
C. Bienert, M. Brandner, S. Skrabs, A. Venskutonis, L. S. Sigl, S. Megel, W. Becker,
N. Trofimenko, M. Kusnezoff, A. Michaelis
2159
xxvii
The Impact of Pressurization on Anode-Supported and Electrolyte-Supported Planar
Solid Oxide Fuel Cells at 750oC ~ 850oC
S. S. Shy, Y. D. Hsieh, J. D. Liang
2169
A Simple Pressurized SOFC Test Rig for Measurements of Cell Performance,
Impedance, and Various Overvoltages
J. D. Liang, L. H. Hong, P. C. Wu, S. S. Shy
2179
Direct Utilization of Methane in Microtubular-SOFC
A. J. Majewski, A. Dhir
2189
Performance Degradation Analysis of Different Type SOFCs
M. Yoshikawa, T. Yamamoto, K. Asano, K. Yasumoto, Y. Mugikura
2199
Durability Assessment of SOFC Stacks with Several Types of Structures for Thermal
Cycles during Their Lifetimes on Residential Use
T. Hatae, K. Sato, T. Somekawa, Y. Matsuzaki, S. Amaha, M. Yoshikawa,
Y. Mugikura, K. Miyara, T. Oshima, S. Taniguchi, K. Sasaki, M. Shimazu,
Y. Takahashi, A. Kawakami, N. Mori, H. Yokokawa
2209
Direct Current Distribution Measurement of an Electrolyte-Supported Planar Solid
Oxide Fuel Cell under the Rib and Channel by Segmented Electrodes
T. Koshiyama, H. Nakajima, T. Karimata, T. Kitahara, K. Ito, S. Masuda, Y. Ogura,
J. Shimano
2217
Performance Degradation Prediction of a Low-Temperature SOFC via Impedance
Spectroscopy and CFD Modelling
C. Boigues Muñoz, D. Pumiglia, F. Santoni, S. J. McPhail, G. Comodi, M. Carlini
2227
Performance Characteristics of a Micro-tubular Solid Oxide Fuel Cell Operated with a
Fuel-rich Methane Flame
Y. Wang, Y. Shi, N. Cai, X. Ye, S. Wang
2237
Development of Intermediate Temperature (550 - 650oC) Metal Supported Solid Oxide
Fuel Cells (SOFCs) Using Plasma Processes
P. K. P. Rupa, V. R. Goli, K. Balasubramanian, R. I. Tomov, R. V. Kumar,
B. A. Glowacki, V. V. Krishnan
2245
A Novel Micro-Tubular Solid Oxide Fuel Cell with a Porous Zirconia Support for
Intermediate-Temperature Operation
D. Panthi, B. Choi, A. Tsutsumi
2259
xxviii
Tubular SOFC with Hollow Fiber Ceramic Support and Inner Coating
Z. Yang, T. Zhu, M. Han
2267
SOFC Stack Operation: Effects of Electrode-Interconnect Contacts
N. Minh, A. Budur, F. Dogan
2273
Micro-SOFC with High Performance and Fast Thermal-Cycling Ability
K. J. Kim, B. H. Park, S. J. Kim, H. Bae, G. M. Choi
2279
Investigation of 2R-Cell Degradation under Thermal Cycling and RedOx Cycling
Conditions by Electrochemical Impedance Spectroscopy
S. Diethelm, V. Singh, J. Van herle
2285
Suppression of Carbon Deposition on Ni Films by Redox Treatment of Ceria Substrates
F. Wang, H. Kishimoto, K. D. Bagarinao, K. Yamaji, T. Horita, H. Yokokawa
2295
Evaluation of a Metal Supported Ni-YSZ / YSZ / La2NiO4 IT-SOFC Elaborated by
Physical Surface Deposition Processes
J. Fondard, P. Bertrand, A. Billard, S. Skrabs, T. Franco, S. Fourcade, P. Batocchi,
F. Mauvy, G. Bertrand, P. Briois
2303
Three-dimensional Modeling of Internal Reforming SOFC with a Focus on the
Interconnect Size Effect
Q. Sun, M. Ni
2317
Shape Forming of Ceramic Tubes for Electrochemical Reactors by Gel-Casting Method
V. Chalkia, P. Pandis, V. Stathopoulos
2339
Design of New Power Source Based on Micro-SOFC for Mobile Electronic Devices
S. Murayama, F. Iguchi, M. Shimizu, S. Tanaka, H. Yugami
2349
Effects of Lamination Conditions on the Performance of Anode-Supported Solid Oxide
Fuel Cells
B. Timurkutluk, C. Timurkutluk, Y. Ciflik, H. Korkmaz, Y. Kaplan
2357
Electro-Chemical Potential Analysis of Zirconium Based on the Reaction-Diffusion
Equations of Oxygen Ion and Electron Considering Phase Transformation
M. Muramatsu, H. Kishimoto, K. Yamaji, K. Yashiro, T. Kawada, K. Terada,
H. Yokokawa
2363
xxix
Towards the Next-Generation of Solid Oxide Fuel Cell Systems
V. Singh, P. H. Wagner, Z. Wuillemin, S. Diethelm, J. Schiffmann, J. Van herle
2373
Electrochemical Model of a Triode Solid Oxide Fuel Cell
P. Caliandro, S. Diethelm, A. Nakajo, J. Van herle
2387
Prediction of SOFC Performance with or without Experiments: A Study on Minimum
Requirements for Experimental Data
T. Yang, H. Sezer, I. B. Celik, H. O. Finklea, K. Gerdes
2397
Performance Characteristics of 100 W Carbon Fuel Cell Stack Based on SOFC
Technology
U. Mushtaq, S. K. Kim, R. H. Song, T. H. Lim, J. W. Lee, S. B. Lee, S. J. Park
2413
Influence of Small Defects Produced in Electrolytes during Manufacturing Processes on
Operated SOFCs
S. Onuki, F. Iguchi, M. Shimizu, T. Kawada, H. Yugami
2421
Effect of Cathode Contacting on Anode Supported Cell Performances and Degradation
R. Spotorno, P. Piccardo, G. Schiller
2429
Understanding the Electrochemical Performance of SOFC Stacks
M. Lang, C. Auer, G. Braniek, F. Wenz, F. Hauler
2441
Anomalous Ohmic Loss in Solid Oxide Fuel Cells with Doped Ceria Interlayers
X. D. Zhou, Z. Lu, J. Templeton, J. W. Stevenson
2453
Microstructural Characterization of SrZrO3 Formation and the Influence to SOFC
Performance
S. Kanae, Y. Toyofuku, T. Kawabata, Y. Inoue, T. Daio, J. Matsuda, J. T. Chou,
Y. Shiratori, S. Taniguchi, K. Sasaki
2463
Theoretical Analysis of Cation Diffusion Pathway in SOFC Interlayer
C. T. Lin, T. Ishimoto, M. Koyama
2471
Electrochemical Performance of SOFC Components Fabricated by Spray Pyrolysis
Method
G. Tsimekas, E. Papastergiades, N. E. Kiratzis
2479
xxx
Direct Ceramic Inkjet Printing and Infiltration of Functional Coatings for Metal
Supported SOFC
R. I. Tomov, A. Fakeeh, V. V. Krishnan, K. Balasubramanian, V. R. Kumar,
B. A. Glowacki
2491
Improved Performance and Durability of Anode Supported SOFC Operating on Biogas
L. Troskialina, A. Dhir, R. Steinberger-Wilckens
2503
Electrochemical Behavior of Phosphine Induced Anode Performance Degradation in a
Planar SOFC: A Numerical Study
H. Sezer, I. B. Celik, T. Yang
2515
LSGM-based Cells for IT-SOFC Applications
E. Mercadelli, A. Sanson, A. Gondolini, P. Pinasco, F. Basoli, E. Di Bartolomeo
2527
Investigation of Time Stability of Sr-Doped Lanthanum Vanadium Oxide Anode and
Sr-Doped Lanthanum Cobalt Oxide Cathode Based on SDC Electrolyte Using SIMS
K. Tamm, P. Möller, G. Nurk, E. Lust
2535
Improvement of Protonic Ceramic Fuel Cells with Thin Film BCZY Electrolyte
Y. Okuyama, N. Ebihara, K. Okuyama, Y. Mizutani
2545
Electrochemical MEA Characterization: Area Specific Resistance Corrected to Fuel
Utilization as Universal Characteristic for Cell Performance
M. Kusnezoff, W. Beckert, N. Trofimenko, B. Jacobs, C. Dosch, S. Megel, M. Rachau,
C. Wieprecht, D. Gipp
2555
Role of Lattice Strain vs. Solid Solution Doping on Atomistic near Order and Oxygen
Ionic Transport for Ceria-based Micro-Energy Conversion Membranes
Y. Shi, I. Garbayo, J. L. M. Rupp
2565
Optimization of Tensile Strength Measurements on Glass-Ceramic Sealant Used for
SOFC Stacks
S. M. Gross-Barsnick, C. Babelot, D. Federmann, U. Pabst
2573
Production and Performance of Copper-based Anode-supported SOFCs
A. Azzolini, V. M. Sglavo, J. A. Downs
2583
Hybrid Fuel Cells with Carbonate/Oxide Composite Electrolytes: An Electrochemical
and Theoretical Insight
C. Ricca, B. Medina-Lott, V. Albin, F. Labat, C. Adamo, M. Hinojosa, M. Cassir Sr.,
A. Ringuedé
2597
xxxi
Ageing of Materials at Inlet and Outlet Fuel Manifolds in a SOFC Stack
P. Piccardo, A. Pecunia, V. Bongiorno, R. Spotorno, Z. Wuillemin, J. P. Ouweltjes
2611
Soft Sensor Design for Estimation of SOFC Stack Temperatures and Oxygen-to-Carbon
Ratio
B. Dolenc, D. Vrecko, D. Juricic, A. Pohjoranta, J. Kiviaho, C. Pianese
2625
In-Situ Temperature Sensing of SOFC during Anode Reduction and Cell Operations
Using a Multi-Junction Thermocouple Network
M. P. Ranaweera, J. S. Kim
2637
Impact of Spark Plasma Sintering Conditions on Ionic Conductivity in
La1.95Sr0.05Zr2O7-δ Electrolyte Material for Intermediate Temperature SOFCs
D. Huo, G. Baldinozzi, D. Siméone, H. Khodja, S. Surble
2645
Ni-based Alloys as Protective Layer for a Conventional Solid Oxide Fuel Cell Fed with
Biofuels
M. Lo Faro, S. Trocino, S. Campagna Zignani, R. Machado Reis, G. Monforte,
E. A. Ticianelli, A. S. Aricò
2653
Performance of Protonic Ceramic Fuel Cell with Thin Film Yttrium Doped Barium
Zirconate Electrolyte
K. Bae, D. Y. Jang, H. S. Noh, H. J. Kim, J. Hong, K. J. Yoon, B. K. Kim, J. W. Son,
J. H. Shim
2659
Electrochemical Synthesis of Ammonia with Proton Conducting Solid Electrolyte Fuel
Cells at Intermediate Temperatures
J. Otomo, N. Noda, F. Kosaka
2663
Protective Coating from Manganese Cobalt Oxide Powders Obtained By High Energy
Ball Milling: Materials Characterization and Cell Environment Testing
A. Masi, M. Bellusci, M. Carlini, S. J. McPhail, D. Pumiglia, P. Reale, A. Rinaldi,
F. Padella
2671
Chapter 8
Fuel Compatibility and Alternative Fuels
Utilisation of Coal in Direct Carbon Fuel Cells
J. Irvine, A. Fuentes Cuesta, A. Mottram, C. Jiang, C. Savaniu, S. Jain
2681
xxxii
Direct Coal Oxidation in Modified Solid Oxide Fuel Cells
L. Deleebeeck, V. Gil, D. Ippolito, R. Campana, K. K. Hansen, P. Holtappels
2685
Electrolyte Stability in Direct-Carbon Fuel Cells with Molten Sb Anodes
T. S. Oh, X. Zhou, J. M. Vohs, R. J. Gorte
2695
Introducing Anode Fluidization into a Tubular Liquid Antimony Anode Direct Carbon
Fuel Cell
T. Cao, Y. Shi, N. Cai
2703
The Fate of Phosphine in SOFC Fuels
H. O. Finklea, W. Zhang, M. Jony, B. Demirgok
2713
Impedance Spectroscopy Studies of the Behavior of MoNi-CeO2 Anode in SOFC Using
H2S-Containing Hydrogen as Fuel
M. J. Escudero, I. Gómez de Parada, A. Fuerte
2723
Development of a Direct Ammonia Fueled Hydrogen Membrane Fuel Cell
Y. Aoki, S. Kobayashi, E. Tsuji, H. Habazaki
2735
Mechanism and Activity of Ni-Based (Ni-M: M = Fe, Mo, W, Ta) Cermet Anodes for
Ammonia Oxidation in SOFCs
M. Hashinokuchi, R. Yokochi, W. Akimoto, T. Doi, M. Inaba, J. Kugai
2739
Effects of Nitride Formation on Anode Catalytic Activity in Ammonia-Fueled SOFCs
R. Yokochi, M. Hashinokuchi, T. Doi, M. Inaba
2745
Electrochemical and Catalytic Behavior of Ni-Based Cermet Anode for Ammonia-
Fueled SOFCs
A. F. S. Molouk, J. Yang, T. Okanishi, H. Muroyama, T. Matsui, K. Eguchi
2751
Syngas-fed SOFCs: Analysis of Performance Sensitivity to Fuel Composition
A. Baldinelli, L. Barelli, G. Bidini
2763
Low Temperature Methane Steam Reforming for SOFC
J. Sun, J. G. Li, Y. F. Zhu, J. J. Zhang, T. Zhou, L. Li, Y. G. Wang, S. Liu, Z. G. Jiang,
Z. C. Dong, C. W. Sun, H. Li, L. Q. Chen
2775
Performance of SOFC Power Unit Assisted by Paper-Structured Catalyst
Y. Shiratori, M. Sakamoto, Q. T. Tran, Y. Uchiyama, N. Uchiyama
2783
xxxiii
CeO2 - ZrO2 Catalysts for the Use of Biogas in IT-SOFC
A. Pappacena, R. Graziutti, M. Boaro, A. Trovarelli
2789
Infiltrated La0.8Sr0.2Ga0.8Mg0.2O3-δ Based Cells Fed with Biogas
E. Di Bartolomeo, I. Luisetto, F. Basoli, F. Zurlo, Z. Salehi, S. Licoccia
2797
Electrochemical Impedance Study of Ag/Cu-Ca0.2Ce0.8O2+δ Anode for SOFCs Operating
with Simulated Biogas
A. Fuerte, M. J. Escudero
2805
The Impact of Toluene on the Performance of Anode-Supported Ni-YSZ SOFC
Operated on Hydrogen and Biosyngas
H. Madi, S. Diethelm, C. Ludwig, J. Van herle
2811
Octane Steam Reforming and Electrochemical Reaction on Cu-GDC Cermet Anode of
Internal Reforming Solid Oxide Fuel Cell
K. Tomomichi, M. Kinoshita, S. Yamagami, Y. Yamada, T. Terai, K. Sasaki
2819
Cracking Reaction of Octane Fuel and Electrochemical Reaction on Ni-YSZ Cermet
Anode of Internal Steam Reforming Solid Oxide Fuel Cell
M. Kinoshita, K. Tomomichi, S. Yamagami, Y. Yamada, T. Terai, K. Sasaki
2831
Electrochemical Investigation of a Large SOFC Fed with n-Dodecane Reformate
S. Trocino, M. Lo Faro, S. Campagna Zignani, G. Monforte, A. S. Aricò
2845
Direct Ethanol Anode-Supported Solid Oxide Fuel Cell
S. D. Nóbrega, M. C. Steil, S. Georges, S. Uhlenbruck, F. C. Fonseca
2851
Chapter 9
Cell, Stack and System Modeling and Simulation
3D Multiscale-Multiphysics SOFC Modelling Status at the Institute of Electrochemical
Process Engineering, FZ Jülich
M. Peksen, A. Al-Masri, R. Peters, L. Blum, D. Stolten
2861
Simulation and Prediction of 3-D Microstructural Evolution and Long Term
Performance of Ni-YSZ Anode
X. Wang, A. Atkinson
2867
xxxiv
Systematic Modeling for Triple Phase Boundary of Ni/ZrO2 SOFC Anode from First
Principles
T. Tada
2875
Dusty-Gas Model with Uniform Pressure: A Numerical Study on the Impact of a
Frequent Inconsistent Assumption in SOFC Electrode Modeling
A. Bertei, C. Nicolella
2887
Effect of Non-Uniform Electrode Microstructure in Gas Diffusion Impedance
A. Bertei, G. Arcolini, C. Nicolella, P. Piccardo
2897
An Accurate and Reliable Computational Approach for the Mechanical Stress Analysis
of Planar SOFC Stack
X. Fang, A. Li, Z. Lin
2907
Molecular Dynamics Study of Ni/YSZ Systems Based on Improved Interatomic Model
A. M. Iskandarov, Y. Umeno
2919
The Effects of Cell Parameters on SOFC Cell Unit Performance
G. J. Moon, M. M. Ahn, Y. J. Choi, I. S. Kang
2927
Reactive Force-Field Development for Metal/Ceramic SOFC Anode Modeling
L. C. Saha, A. Iskandarov, K. Nakao, T. Ishimoto, Y. Umeno, M. Koyama
2943
Morphological Modelling of a Metal Foam Supported SOFC Configuration
D. Masson, B. Abdallah, F. Willot, D. Jeulin, E. Mercadelli, A. Sanson, A. Chesnaud,
A. Thorel
2951
Architectured Interfaces and Electrochemical Modelling in an Anode Supported SOFC
M. Geagea, J. Ouyang, B. Chi, F. Delloro, A. Chesnaud, A. Ringuedé, M. Cassir Sr.,
A. Thorel
2961
Modelling and Prediction of Deformation during Sintering of a Metal Foam Based
SOFC (EVOLVE)
M. Xu, D. Masson, D. Ryckelynck, A. Chesnaud, A. Thorel
2971
Simulation of Interfacial Cracking of the Joint between Glass-Ceramic Sealant and
Metallic Interconnect in a Planar Solid Oxide Fuel Cell Stack
C. K. Lin, W. H. Shiu, S. H. Wu, R. Y. Lee
2981
xxxv
Estimation of 3D Effective Properties from 2D Cross Sections in Porous Electrodes
T. Ferrari, A. Bertei, C. Nicolella
2991
Modeling of Solid Oxide Fuel Cell with Anisotropic Conductivity
M. Xu, M. Andersson, T. Li, B. Sundén, F. Chen
3003
Three-Dimensional Computational Fluid Dynamics Modelling for a Planar Solid Oxide
Fuel Cell of a New Design
P. Pianko-Oprych, T. Zinko, Z. Jaworski
3013
A High Resolution Multi-Physics Numerical Model for Planar SOFC Stack
A. Li, X. Fang, Z. Lin
3025
Stationary 2D FEM Model Framework for SOFC Stack Performance Prediction
H. Geisler, A. Kromp, J. Joos, A. Weber, E. Ivers-Tiffée
3043
Multi-scale Modeling of Biogas Fueled SOFC
V. M. Janardhanan
3051
Detailed H2 and CO Electrochemistry for a MEA Model Fueled by Syngas
W. Y. Lee, K. M. Ong, A. F. Ghoniem
3059
Three Dimensional Temperature Distribution Analysis in Directly Internal Reforming
SOFC Fuelled by Methane
T. Ogura, K. Wakamatsu
3075
Simulation of Start-up of Anode Gas Recycle SOFC System Using Catalytic
Combustion Method
S. Baba, N. Kobayashi, S. Takahashi, S. Hirano
3083
A Lumped Dynamic Modelling Approach for Model-Based Control and Diagnosis of
Solid Oxide Fuel Cell System with Anode Off-Gas Recycling
D. Marra, M. Sorrentino, A. Pohjoranta, C. Pianese, J. Kiviaho
3095
Process Analysis for Achieving Highly Enhanced Total Efficiency on Multi-Stage Fuel
Supplied SOFC System
Y. Tachikawa, Y. Matsuzaki, T. Hatae, S. Taniguchi, K. Sasaki
3107
High Efficient Combined Heat and Power SOFC System for Residential Power
Applications: Lifetime-Efficiency-Simulations Using AspenPlusTM
C. Spieker, C. Spitta, M. Noponen, P. Hallanoro, T. Ruetten
3115
xxxvi
A Thermo Fluid and Thermo Mechanical Modelling of a Microtubular Solid Oxide Fuel
Cell Stack for Unmanned Aerial Vehicles
B. Hari, A. Dhir, R. Steinberger-Wilckens
3133
FDI Oriented Simulation of an MSR Reactor for Application in SOFC Systems
P. Costamagna, S. Rossi, F. Pugliese, F. Gugliotta, A. Enrico
3143
Feedforward-Feedback Control of a SOFC Power System: A Simulation Study
D. Vrecko, G. Dolanc, B. Dolenc, D. Vrancic, B. Pregelj, D. Marra, M. Sorrentino,
C. Pianese, A. Pohjoranta, D. Juricic
3151
Modeling Intermediate Temperature Protonic Ceramic Fuel Cells
K. J. Albrecht, C. Duan, R. O'Hayre, R. J. Braun
3165
Theoretical Study of Inorganic Carbonaceous Species Reaction with the Surfaces of
BaTiO3(001)
D. S. Rivera Rocabado, T. Ishimoto, T. Quang-Tuyen, Y. Shiratori, M. Koyama
3177
Density Functional Theory Study of Dopant Effect on Sintering in the Anode of Solid
Oxide Fuel Cell
J. Xu, Y. Higuchi, N. Ozawa, M. Kubo
3187
Computational Materials Design of Rare-Earth-Based Fast Oxygen Ion Conductors by
First-Principles Simulation Based on Density Functional Theory
M. Sakaue, H. Kasai
3195
First-Principles Study of Surface Peroxo in Oxygen-Rich Yttria Stabilized Zirconia
(110)
S. Takemoto, T. Tada
3203
Modeling Water Reduction on Doped Ceria Thin Films
H. Valdes-Espinosa, E. M. Stuve, S. B. Adler
3209
Ab Initio Molecular Dynamics Simulation of Oxygen Adsorption and Electron Transfer
on SOFC Cathode
S. Sugiura, Y. Shibuta, K. Shimamura, M. Misawa, F. Shimojo, S. Yamaguchi
3229
xxxvii
Chapter 10
Solid Oxide Electrolysis and Reversible Cells
Reversible Oxygen-Ion Storage for Solid Oxide Cells
C. M. Berger, A. Hospach, N. H. Menzler, O. Guillon, M. Bram
3241
Reversible Fuel Cells with Tri-Layer Electrolytes
A. V. Virkar
3253
High Performance Air Electrode for Solid Oxide Regenerative Fuel Cells Fabricated by
Infiltration of Nano-Catalysts
K. J. Yoon, J. Hong, H. Kim, J. W. Son, J. H. Lee, B. K. Kim
3261
Thermodynamic and Exergy Analysis of Reversible Solid Oxide Cell Systems
G. Botta, H. C. Patel, F. Sebastiani, P. V. Aravind
3265
Reversible Type Solid Oxide Fuel Cells Using Ni-Fe-CeO2 Based Cermet Fuel
Electrode and Applied for Metal-Air Rechargeable Battery
T. Ishihara, A. Inoishi, H. Kim, S. Ida
3279
Energy Dense Storage Using Intermediate Temperature Reversible Solid Oxide Cells
A. Monti, C. Wendel, M. Santarelli, R. J. Braun
3289
Electrolysis Operating Mode for Reversible Solid Oxide Fuel Cells
N. Minh, M. C. Williams
3301
Effect of Microstructure on Performances of Hydrogen and Oxygen Electrodes for
Reversible SOEC/SOFC
H. Uchida, P. Puengjinda, K. Miyano, K. Shimura, H. Nishino, K. Kakinuma,
M. E. Brito, M. Watanabe
3307
Oxygen Nonstoichiometry and Cathodic Property of Ce0.6Mn0.3Fe0.1O2-δ for High
Temperature Steam Electrolysis Cell Using LaGaO3-Based Oxide Electrolyte
K. Hosoi, T. Sakai, S. Ida, T. Ishihara
3315
Influence of the Solid Oxide Electrolysis Component Characteristics on the
Electrochemical Performance of SOE Cells
K. Tamm, F. Kukk, L. K. Salvan, R. Kanarbik, P. Möller, G. Nurk, E. Lust
3323
xxxviii
Water Splitting on Model-Composite La0.6Sr0.4FeO3-δ (LSF) Electrodes in H2/H2O
Atmosphere
A. K. Opitz, A. Nenning, S. Kogler, C. Rameshan, R. Rameshan, R. Blume,
M. Haevecker, A. Knop-Gericke, G. Rupprechter, B. Kloetzer, J. Fleig
3333
Evaluation of La2NiO4 as Anode Material for Solid Oxide Electrolyser Cells
A. Egger, N. Schrödl, W. Sitte
3345
Life Time Performance Characterization of Solid Oxide Electrolysis Cells for Hydrogen
Production
X. Sun, M. Chen, Y. L. Liu, P. V. Hendriksen
3359
Assessment of Pressure Effects on High Temperature Steam Electrolysis Based on Solid
Oxide Technology
L. Bernadet, G. Gousseau, A. Chatroux, J. Laurencin, F. Mauvy, M. Reytier
3369
Electrochemical Characterization of Ni/Y2O3-ZrO2 Hydrogen Electrode for Water
Splitting in Solid Oxide Electrolysis Cells
W. Pan, K. Chen, N. Ai, Z. Lü, S. P. Jiang
3379
Steam Electrolysis by Proton-Conducting Solid Oxide Electrolysis Cells (SOECs) with
Chemically Stable BaZrO3-Based Electrolytes
L. Bi, E. Traversa
3387
Steam and Co-Electrolysis Sensitivity Analysis on Ni-YSZ Supported Cells
G. Rinaldi, S. Diethelm, J. Van herle
3395
Development of Medium-Temperature Solid Oxide Fuel Cells and CO2 and H2O
Co-Electrolysis Cells in Estonia
E. Lust, K. Tamm, G. Nurk, P. Möller, I. Kivi, R. Kanarbik, A. Heinsaar
3407
Electrochemical Impedance Spectroscopy Data from Solid Oxide Cells Undergoing
Co-Electrolysis: The Influence of Rig Inductance
A. R. Thompson, A. V. Call, D. J. Cumming, D. C. Sinclair, R. H. Elder
3417
Carbon Deposition during CO2 Electrolysis in Ni-Based Solid-Oxide-Cell Electrodes
T. L. Skafte, C. Graves, P. Blennow, J. Hjelm
3429
Carbon Tolerant Electrodes for SOFC and Reversible SOFC (RSOFC) Cells Operating
on Carbon Containing Fuels
D. K. Niakolas, C. Neofytides, S. G. Neophytides, D. Tsiplakides, K. M. Papazisi,
S. Balomenou
3439
xxxix
Effects of Current Collector Materials on Performances of Micro-Tubular Solid Oxide
Electrolysers for Splitting CO2
L. Kleiminger, G. H. Kelsall, T. Li, K. Li
3449
Development of Electrochemical Methanation Reactor with Co-Electrolysis of
Humidified CO2
T. Yamaguchi, H. Shimada, U. Honda, H. Kishimoto, T. Ishiyama, Y. Fujishiro
3459
Methane Synthesis Characteristics of H2O/CO2 Co-Electrolysis in Tubular Solid Oxide
Electrolysis Cells
Y. Luo, W. Li, Y. Shi, X. Ye, S. Wang, N. Cai
3465
Fabrication and Performance Evaluation of Solid Oxide Electrolysis Cell Integrated
with Metal Interconnect by Joining Process
Y. S. Yoo, M. Choi, S. Yang, H. J. Jin, M. A. Park, E. H. Kim
3475
9000 Hours Operation of a 25 Solid Oxide Cells Stack in Steam Electrolysis Mode
G. Corre, A. Brisse
3481
Performance and Degradation of Solid Oxide Electrolysis Cells in Stack
Q. Fang, L. Blum, N. H. Menzler
3491
Development of a Tubular Solid Oxide Cell for Co-Electrolysis of H2O and CO2 for
Syngas Production
Y. Tanaka, T. Kato, S. Nagata, A. Negishi
3505
Possibility of Methane Production from Steam and Carbon Dioxide by Using Solid
Oxide Electrolysis Cells
T. Kato, S. Nagata, T. Honda, A. Negishi, Y. Tanaka, A. Momma
3513
A Packaged and Efficient SOEC System Demonstrator
A. Chatroux, M. Reytier, S. Di Iorio, C. Bernard, G. Roux, M. Petitjean, J. Mougin
3519
Influence of Ni-YSZ Electrode Thickness on the Behaviour of Commercial Solid Oxide
Electrolysis Cells by Mean of Electrochemical Impedance Spectroscopy
A. Nechache, M. Cassir Sr., A. Ringuede
3527
Understanding of CO2 Electrochemical Reduction Reaction Process via High
Temperature Solid Oxide Electrolysers
X. Yue, J. T. S. Irvine
3535
xl
Systematic Parameter Study on the Influence of Humidification and Current Density on
SOEC Degradation
M. P. Hoerlein, G. Schiller, F. Tietz, K. A. Friedrich
3553
Challenges of Solid Oxide Electrolysis for Production of Fuel and Oxygen from Mars
Atmospheric CO2
J. J. Hartvigsen, S. Elangovan, D. Larsen, J. Elwell, M. Bokil, L. J. Frost,
L. M. Clark
3563
Author Index 3585
