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Spotting.ppt

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    SELECTIONCRITERIAFORSPOTTINGCHEMICALS

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    Spotting is the removal of stains from textiles

    during professional textile cleaning. Spotting

    solvents are used in textile and clothing

    manufacture to remove stains from fabrics.

    These can be caused by such things as loom

    and machine oils, feltpens,

    coffee, grease and finger marks.

    Spotting solvents are usually applied to the

    fabric by spray gun but a cloth soaked in solvent

    may also be used

    SPOTTING

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    Two main groups of spotting solvents are used

    Halogentated hydrocarbons and olefins.

    Halogentated hydrocarbons include

    trichloroethylene,* 1,1,1 trichloroethane,

    bromochloromethane and dichloromethane.

    Olefins include aliphatic hydrocarbon solvent

    blends and isoparafinic hydrocarbon blends.

    SPOTTINGCHEMICALS

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    Absorbents-Cornmeal, talcum powder,

    chalk, fullers earth and whiting

    Bleaches -Oxygen bleaches , chlorinebleaches, Hydrogen peroxide,vinegar,

    lemon juice and ammonia.

    Detergents- alone or in combination with

    mild bleaches are effective stain removers.

    Prewash soil and stain removers -contain

    dry cleaning solvents in combination with

    detergents, glycerin and water.

    SPOTTINGAGENTS

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    Enzyme presoaks and bleaches are used for

    protein-based stains, such as grass and blood.

    Solvents, such as dry cleaning fluids, amyl

    acetate, spot remover, rubbing alcohol,

    acetone, nail polish remover, and paint removeror stripper, are used on oily and combination

    stains.

    Soaps, such as laundry flakes, bars and liquids,

    are used on delicate fabrics.

    Miscellaneous products that may be used are

    oxalic acid, rust removers and glycerin.

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    Lighting of the spotting table with composite

    artificial light consisting of a bluish and ayellowish fluorescent tube attached above

    the table approx. 80 cm from the standing

    point is better suited than daylight.

    This ensures high-contrast, shadow-freelighting of the work surface and allows

    working without fatigue.

    LIGHTINGCONDITION

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    Basic equipment should comprise a spotting

    table with vacuum facility, sleeve board,

    steam and compressed air guns, and a spray

    gun for water.

    Spotting brushes should have soft bristles for

    gentle treatment of the textiles. Use brushes

    with bright bristles for bright textiles andbrushes with dark bristles for dark textiles.

    Use spatulas with rounded edges for

    removing substantial staining.

    EQUIPMENTS

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    It is recommended to integrate the three stagesof spotting

    Brushing

    Prespotting

    Postspotting

    into the operating procedures of textile cleaning.

    Perform brushing and special spotting when

    examining and sorting the textiles to be cleaned.

    CORRECTPROCEDUREFORSPOTTING

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    Examine textiles for excessive dirt, particularly

    at collars, pockets, sleeves, and trouser legs. If

    the textiles are to be dry cleaned check themparticularly for stains originating from food or

    body secretions.

    If the textiles are to be wetcleaned check themparticularly for grease stains.

    Apply small quantity of brushing agent onto the

    stained areas and allow to react for 10-20

    minutes before loading the cleaning equipment

    BRUSHING

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    Intensive staining found upon the examinationof the textiles can be treated with pre-spotting

    agents even before the actual cleaning.

    Pre-spotting, which involves dryside chemicalsto remove or loosen solvent-soluble stains

    PRE-SPOTTING

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    Stains that could not be removed during dry

    cleaning or wet cleaning with machines are

    subject to post-spotting.

    Post-spotting, which utilizes wetside

    chemicals to remove water-soluble stains

    POST-SPOTTING

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    EXAMPLESOFSPOTTEDGARMENTS

    White Shirt with BlueScreen Printing Ink.

    Blue Shirt with Black Latex

    Paint.

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    Tan Dockers

    with Red Nail

    Polish

    Beige Pants with

    Mascara.

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    Eliminate or reduce use -Think about

    how its use can be minimised. Household type

    water-based cleaning products be used

    Consider the solvents flammability -Avoid

    highly flammable solvents with risk phraseR11, flash point 21 C or less; the vapour

    from these can readily create a flammable

    atmosphere.

    STEPSTOSELECTINGASOLVENT

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    Health risksbecause hazardous solvent they

    may cause serious and irreversible ill-health

    effects such as asthma, dermatitis and cancer

    Check whether the solvent has an Occupational

    Exposure Limit (OEL) - There are two types of

    OELMaximum Exposure Limits (MELs) and

    Occupational Exposure Standards (OESs).

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    Store and dispense safely

    Avoid spraying

    Provide adequate ventilation

    Minimise skin contactProvide personal protective equipment

    (PPE)

    Ensure adequate personal hygiene

    Provide training for workers

    CONTROLLINGEXPOSURE

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    In California, four or five suppliers sell spotting agents in large quantities

    to distributors. The distributors, in some cases, repackage the spotting

    agents in smaller quantities and sell them to cleaners along with other

    supplies like filters, hangers and dry cleaning agents.

    The local air districts have regulatory authority over spotting chemicalssince they regulate VOCs and toxic materials used in industrial facilities.

    CARB may also have regulatory authority over spotting chemicals. CARB

    and local air districts do not currently have regulations that affect spotting

    chemicals.

    The regulatory agencies might forbid the use of spotting agents that

    contain chlorinated solvents like TCE or PERC, for example Thealternatives that were tested during this project were selected to have low

    toxicity and low VOC content.

    VOC: Volatile Organic Compounds

    CARB: California Air Resources Board

    AIRREGULATIONTHATAPPLIESTOSPOTTINGCHEMICALS

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    TCE and PERC are listed hazardous wastes under

    RCRA. Both chemicals are listed in RCRA under F001 and

    F002. F001 specifies TCE and PERC used indegreasing. F002 specifies TCE and PERC when they are

    spent and all spent solvent mixtures/blends containing,

    This applies to sludge generated from spin-disk filters , still

    bottoms generated from distillation, separator water and

    the effluent from waterbasedtechnologies

    RCRA: Resource Conservation and Recovery Act

    WASTEREGULATIONTHATAPPLIESTOSPOTTINGCHEMICALS

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    Today PERC and TCE are the POG spotting agents

    most widely used by cleaners, even those using

    alternative technologies for textile cleaning. PERC

    and TCE are both carcinogens.

    Because PERC, the major dry cleaning agent,

    received negative publicity because it is a

    carcinogen, the suppliers and distributors converted

    away from the chemical in POG spotting agents.PERC: perchloro ethelene

    TCE: Trichloro ethylene

    POG: Paint, Oil and Grease

    TOXICITYOFSPOTTINGAGENTS

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    The stain removing machines work on the

    scientific process of impact chemical spray

    cleaning.

    Vacuum removal of the residual spray.

    Subsequent drying through a steam gun

    and compressed air spray.

    SPOTTINGMACHINE

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    Air drier

    Spray gun

    Spotting working

    station

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    SPOTS STAINSREMOVALTABLES.NO: Stain Pretreatment Bleachable Non-bleachable1 Alcoholic

    drinksSponge with cool

    water. Soak at least

    30min. or overnight in

    cool water & detergent.

    Soak in solution of 2 T.

    (30 ml) chlorine bleach

    to 1 qt. (1 l) water. If fruit

    colored, use dry

    cleaning solvent. Rinse.

    Sponge with cool

    water. For stubborn

    stains, force water

    through stain.2 Anti-

    perspirant

    buildupWet. Rub in detergent

    or prewash soil & stain

    remover. Rinse. Air dry.Soak in solution of 1

    t. (8 ml) oxalic acid to 1

    c. (1/4 l) hot water for 1

    hr. Rinse; repeat two

    solution of c. (120 ml)

    vinegar to 1 gal. (3 l)

    water. Wash.

    Moisten area with

    hydrogen peroxide or

    oxygen bleach after

    testing fabric. Let

    stand for at least 30

    min. Rinse. To restore

    color, use equal parts

    ammonia & water.

    Rinse.3 Beer Blot. Rinse with coolwater.

    1) Apply solution of a

    few drops vinegar

    or lemon juice to 1

    c. (1/4 l) water.

    Agitate. Rinse.

    2) Work in enzyme

    paste. Wash.

    Same as for

    bleaches.

    4 Blood: dried Soak in cool soapy Apply enzyme paste Soak in solution of

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    4 Blood: dried

    or set-in

    Soak in cool soapy

    water changing water

    as stain releases.

    Rinse. Soak in solution

    of c. (60 ml)

    ammonia to 1 gal. (3

    l) water.

    Apply enzyme paste.

    Repeat several times if

    stain persists. Dry flat in

    full sun between

    treatments.

    Soak in solution of

    c. (60 ml) salt to 2

    qts. (2 l) cool water.

    Rinse. Soak in

    solution of c. (60

    ml) ammonia to 1 gal.

    (3 l) water. If stain

    persists, treat withenzyme presoak

    solution.5 Candle-wax: Remove surface wax

    with a dull knife.Place stain between

    paper towel and press

    with a warm iron.

    Replace towelsfrequently to absorb

    more wax. Launder with

    detergent. If traces of

    color remain, wash

    again using chlorine

    bleach.

    Same as for bleaches

    except, to launder

    replace chlorine

    bleach with hydrogenperoxide or oxygen

    bleach after testing

    fabric.

    6 Catsup,

    spaghetti or

    tomato sauceScrape off excess. Blot

    with moist cloth.

    Repeat until progress

    stops.

    Apply prewash soil &

    stain remover. Rinse.

    Repeat. Apply enzyme

    paste. Rinse; repeat if

    stain persists. Add

    vinegar to last rinse.

    Blot. Apply absorbent.

    Repeat. Work in

    cleaning fluid from

    underside. Feather

    edges.

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    7 Coffee, tea,

    chocolate,

    cocoaBlot well with damp

    cloth. Pour cool

    water through stain

    if possible.

    1) Soak in cool water. Work in detergent. Rinse. If

    stain remains, apply cleaning fluid.2) Apply enzyme paste to final traces. Wash in warm

    water.3) Force boiling water over stain from arms length

    above.8 Cosmetics:

    makeup,

    lipstickBlot well, being

    careful not to

    spread stain.1) Work in cleaning fluid, rubbing toward center. Spot

    wash with liquid detergent. Rinse. Air dry.2) Apply prewash soil & stain remover. Blot. Repeat.

    Rinse with solution of water & a few drops

    ammonia. Wash in warm water.3) Soak in enzyme solution for 30 min.

    9 Crayons:

    incidental

    marksScrape off excess. 1) Place stain between white tissues or paper towels.

    Press with warm iron. Pour small amount of

    cleaning fluid onto absorbent white towel; stroke

    across stain until stain is gone.2) Soak in hot enzyme presoak solution for at least 30

    min. rinse.

    10 Grease: car Blot. Protect otherclothing.

    Work in petroleum jelly. Sponge

    with cleaning fluid. Rinse; rinse

    well. Wash in hottest water safe

    for fabric; or use prewash soil &

    stain remover.

    Same as for

    bleachable.

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    www.hsebooks.co.uk

    www.google.com/textile/spottingchemic

    als

    www.wikipedia.com

    www.google.com/textileresearch

    www.sanitone.com

    BIBLIOGRAPHY

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    THANK YOU