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SELECTIONCRITERIAFORSPOTTINGCHEMICALS
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Spotting is the removal of stains from textiles
during professional textile cleaning. Spotting
solvents are used in textile and clothing
manufacture to remove stains from fabrics.
These can be caused by such things as loom
and machine oils, feltpens,
coffee, grease and finger marks.
Spotting solvents are usually applied to the
fabric by spray gun but a cloth soaked in solvent
may also be used
SPOTTING
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Two main groups of spotting solvents are used
Halogentated hydrocarbons and olefins.
Halogentated hydrocarbons include
trichloroethylene,* 1,1,1 trichloroethane,
bromochloromethane and dichloromethane.
Olefins include aliphatic hydrocarbon solvent
blends and isoparafinic hydrocarbon blends.
SPOTTINGCHEMICALS
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Absorbents-Cornmeal, talcum powder,
chalk, fullers earth and whiting
Bleaches -Oxygen bleaches , chlorinebleaches, Hydrogen peroxide,vinegar,
lemon juice and ammonia.
Detergents- alone or in combination with
mild bleaches are effective stain removers.
Prewash soil and stain removers -contain
dry cleaning solvents in combination with
detergents, glycerin and water.
SPOTTINGAGENTS
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Enzyme presoaks and bleaches are used for
protein-based stains, such as grass and blood.
Solvents, such as dry cleaning fluids, amyl
acetate, spot remover, rubbing alcohol,
acetone, nail polish remover, and paint removeror stripper, are used on oily and combination
stains.
Soaps, such as laundry flakes, bars and liquids,
are used on delicate fabrics.
Miscellaneous products that may be used are
oxalic acid, rust removers and glycerin.
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Lighting of the spotting table with composite
artificial light consisting of a bluish and ayellowish fluorescent tube attached above
the table approx. 80 cm from the standing
point is better suited than daylight.
This ensures high-contrast, shadow-freelighting of the work surface and allows
working without fatigue.
LIGHTINGCONDITION
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Basic equipment should comprise a spotting
table with vacuum facility, sleeve board,
steam and compressed air guns, and a spray
gun for water.
Spotting brushes should have soft bristles for
gentle treatment of the textiles. Use brushes
with bright bristles for bright textiles andbrushes with dark bristles for dark textiles.
Use spatulas with rounded edges for
removing substantial staining.
EQUIPMENTS
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It is recommended to integrate the three stagesof spotting
Brushing
Prespotting
Postspotting
into the operating procedures of textile cleaning.
Perform brushing and special spotting when
examining and sorting the textiles to be cleaned.
CORRECTPROCEDUREFORSPOTTING
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Examine textiles for excessive dirt, particularly
at collars, pockets, sleeves, and trouser legs. If
the textiles are to be dry cleaned check themparticularly for stains originating from food or
body secretions.
If the textiles are to be wetcleaned check themparticularly for grease stains.
Apply small quantity of brushing agent onto the
stained areas and allow to react for 10-20
minutes before loading the cleaning equipment
BRUSHING
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Intensive staining found upon the examinationof the textiles can be treated with pre-spotting
agents even before the actual cleaning.
Pre-spotting, which involves dryside chemicalsto remove or loosen solvent-soluble stains
PRE-SPOTTING
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Stains that could not be removed during dry
cleaning or wet cleaning with machines are
subject to post-spotting.
Post-spotting, which utilizes wetside
chemicals to remove water-soluble stains
POST-SPOTTING
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EXAMPLESOFSPOTTEDGARMENTS
White Shirt with BlueScreen Printing Ink.
Blue Shirt with Black Latex
Paint.
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Tan Dockers
with Red Nail
Polish
Beige Pants with
Mascara.
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Eliminate or reduce use -Think about
how its use can be minimised. Household type
water-based cleaning products be used
Consider the solvents flammability -Avoid
highly flammable solvents with risk phraseR11, flash point 21 C or less; the vapour
from these can readily create a flammable
atmosphere.
STEPSTOSELECTINGASOLVENT
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Health risksbecause hazardous solvent they
may cause serious and irreversible ill-health
effects such as asthma, dermatitis and cancer
Check whether the solvent has an Occupational
Exposure Limit (OEL) - There are two types of
OELMaximum Exposure Limits (MELs) and
Occupational Exposure Standards (OESs).
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Store and dispense safely
Avoid spraying
Provide adequate ventilation
Minimise skin contactProvide personal protective equipment
(PPE)
Ensure adequate personal hygiene
Provide training for workers
CONTROLLINGEXPOSURE
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In California, four or five suppliers sell spotting agents in large quantities
to distributors. The distributors, in some cases, repackage the spotting
agents in smaller quantities and sell them to cleaners along with other
supplies like filters, hangers and dry cleaning agents.
The local air districts have regulatory authority over spotting chemicalssince they regulate VOCs and toxic materials used in industrial facilities.
CARB may also have regulatory authority over spotting chemicals. CARB
and local air districts do not currently have regulations that affect spotting
chemicals.
The regulatory agencies might forbid the use of spotting agents that
contain chlorinated solvents like TCE or PERC, for example Thealternatives that were tested during this project were selected to have low
toxicity and low VOC content.
VOC: Volatile Organic Compounds
CARB: California Air Resources Board
AIRREGULATIONTHATAPPLIESTOSPOTTINGCHEMICALS
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TCE and PERC are listed hazardous wastes under
RCRA. Both chemicals are listed in RCRA under F001 and
F002. F001 specifies TCE and PERC used indegreasing. F002 specifies TCE and PERC when they are
spent and all spent solvent mixtures/blends containing,
This applies to sludge generated from spin-disk filters , still
bottoms generated from distillation, separator water and
the effluent from waterbasedtechnologies
RCRA: Resource Conservation and Recovery Act
WASTEREGULATIONTHATAPPLIESTOSPOTTINGCHEMICALS
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Today PERC and TCE are the POG spotting agents
most widely used by cleaners, even those using
alternative technologies for textile cleaning. PERC
and TCE are both carcinogens.
Because PERC, the major dry cleaning agent,
received negative publicity because it is a
carcinogen, the suppliers and distributors converted
away from the chemical in POG spotting agents.PERC: perchloro ethelene
TCE: Trichloro ethylene
POG: Paint, Oil and Grease
TOXICITYOFSPOTTINGAGENTS
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The stain removing machines work on the
scientific process of impact chemical spray
cleaning.
Vacuum removal of the residual spray.
Subsequent drying through a steam gun
and compressed air spray.
SPOTTINGMACHINE
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Air drier
Spray gun
Spotting working
station
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SPOTS STAINSREMOVALTABLES.NO: Stain Pretreatment Bleachable Non-bleachable1 Alcoholic
drinksSponge with cool
water. Soak at least
30min. or overnight in
cool water & detergent.
Soak in solution of 2 T.
(30 ml) chlorine bleach
to 1 qt. (1 l) water. If fruit
colored, use dry
cleaning solvent. Rinse.
Sponge with cool
water. For stubborn
stains, force water
through stain.2 Anti-
perspirant
buildupWet. Rub in detergent
or prewash soil & stain
remover. Rinse. Air dry.Soak in solution of 1
t. (8 ml) oxalic acid to 1
c. (1/4 l) hot water for 1
hr. Rinse; repeat two
solution of c. (120 ml)
vinegar to 1 gal. (3 l)
water. Wash.
Moisten area with
hydrogen peroxide or
oxygen bleach after
testing fabric. Let
stand for at least 30
min. Rinse. To restore
color, use equal parts
ammonia & water.
Rinse.3 Beer Blot. Rinse with coolwater.
1) Apply solution of a
few drops vinegar
or lemon juice to 1
c. (1/4 l) water.
Agitate. Rinse.
2) Work in enzyme
paste. Wash.
Same as for
bleaches.
4 Blood: dried Soak in cool soapy Apply enzyme paste Soak in solution of
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4 Blood: dried
or set-in
Soak in cool soapy
water changing water
as stain releases.
Rinse. Soak in solution
of c. (60 ml)
ammonia to 1 gal. (3
l) water.
Apply enzyme paste.
Repeat several times if
stain persists. Dry flat in
full sun between
treatments.
Soak in solution of
c. (60 ml) salt to 2
qts. (2 l) cool water.
Rinse. Soak in
solution of c. (60
ml) ammonia to 1 gal.
(3 l) water. If stain
persists, treat withenzyme presoak
solution.5 Candle-wax: Remove surface wax
with a dull knife.Place stain between
paper towel and press
with a warm iron.
Replace towelsfrequently to absorb
more wax. Launder with
detergent. If traces of
color remain, wash
again using chlorine
bleach.
Same as for bleaches
except, to launder
replace chlorine
bleach with hydrogenperoxide or oxygen
bleach after testing
fabric.
6 Catsup,
spaghetti or
tomato sauceScrape off excess. Blot
with moist cloth.
Repeat until progress
stops.
Apply prewash soil &
stain remover. Rinse.
Repeat. Apply enzyme
paste. Rinse; repeat if
stain persists. Add
vinegar to last rinse.
Blot. Apply absorbent.
Repeat. Work in
cleaning fluid from
underside. Feather
edges.
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7 Coffee, tea,
chocolate,
cocoaBlot well with damp
cloth. Pour cool
water through stain
if possible.
1) Soak in cool water. Work in detergent. Rinse. If
stain remains, apply cleaning fluid.2) Apply enzyme paste to final traces. Wash in warm
water.3) Force boiling water over stain from arms length
above.8 Cosmetics:
makeup,
lipstickBlot well, being
careful not to
spread stain.1) Work in cleaning fluid, rubbing toward center. Spot
wash with liquid detergent. Rinse. Air dry.2) Apply prewash soil & stain remover. Blot. Repeat.
Rinse with solution of water & a few drops
ammonia. Wash in warm water.3) Soak in enzyme solution for 30 min.
9 Crayons:
incidental
marksScrape off excess. 1) Place stain between white tissues or paper towels.
Press with warm iron. Pour small amount of
cleaning fluid onto absorbent white towel; stroke
across stain until stain is gone.2) Soak in hot enzyme presoak solution for at least 30
min. rinse.
10 Grease: car Blot. Protect otherclothing.
Work in petroleum jelly. Sponge
with cleaning fluid. Rinse; rinse
well. Wash in hottest water safe
for fabric; or use prewash soil &
stain remover.
Same as for
bleachable.
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www.hsebooks.co.uk
www.google.com/textile/spottingchemic
als
www.wikipedia.com
www.google.com/textileresearch
www.sanitone.com
BIBLIOGRAPHY
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