S&T Perspectives on CO2 Sequestration Technology Science & Technology Perspectives on CCS for Carbon...

S&T Perspectives on C

O2 Sequestration Technology

Science & Technology Perspectives on CCS for Carbon Management in Atmosphere

Science & Technology Perspectives on CCS for Carbon Management in Atmosphere

Dr (Mrs) Malti Goel Department of Science and Technology,

New Delhi, India

INTERNATIONAL CONFERENCE ON CARBON CAPTURE AND STORAGE: R&D PRIORITIES FOR INDIA ON 22-23 JANUARY 2008 AT NEW DELHI



Contents of Presentation

• Introduction

• CCS as Agenda for Carbon Management

• Coal Based Capture Research

• Large-Scale Storage R&D

• Small Scale Storage R&D

• Conclusions



World Total CO2 and Per capita Emissions from Energy Sector



0

1000

2000

3000

4000

5000

6000

2003-04 2006-07 2011-12 2016-17 2021-22 2026-27 2031-320

200

400

600

800

1000

1200

1400

1600

1800

Total EnergyInstalled CapacityCoal

Source: Center for Global Change, India

Source- Integrated Energy Policy of India 2006

Current Coal Production in India is about 450 MT/ annum

India has set a goal of Sustained Energy Growth at 8-9 %

Coal is dominant primary energy resource having a share of 60 % and will continue to have significant share up to 2030

Per capita energy consumption and per capita CO2 emission is quite low

INDIA’S Energy Growth Scenario and CO2 Emissions and Projections



Future Share Of Different Resources

• Total Anticipated Capacity Addition 160GW

RenewableEnergy

50 GW20

GW15

GW 60-80 GW

NuclearEnergy

Hydropower

Remaining Share of

Fossil Fuels



India’s Energy Security: Challenges and

Response • Adoption of high efficiency in thermal

power generation through fuel and boiler technology -Super Critical Boiler technology in offing

• Increasing use of renewable energy sources

• Significant growth in Wind energy generation achieved – installed capacity approaching 7GW

• Growing nuclear power production• Energy efficiency programmes in end use

sectors• Initiated Joint Activities to be

implemented under JI/ AIJ mechanisms• Promotion of clean coal technology• Research on carbon capture and storage• Move towards hydrogen economy

Energy security in 21st century will rely on environmentally friendly use of fossil fuels




• Introduction





• Conclusions



Carbon Sources

Carbon cycle

S & T Perspectives

Natural Processes

Carbon Sinks

Carbon Capture

CarbonEmission Reduction

Carbon Storage

CARBON MANAGEMENT

Carbon Management in Atmosphere



Clean Coal

Technology

Capture Materials

& Processes

Modeling Studies ofSequesteredcarbon

Microbial Sequestration Terrestrial Carbon

Storage

Geological

Storage

S & T PERSPECTIVES

S & T Perspectives in Carbon Management



Indian Participation in CCS Research

• India has been one of the active member of CSLF and has supported R&D and Capacity Building activities within Country Policy Guidelines

• India has also signed Framework Protocol on FutureGen, a zero emission project, with USA

• Has been conducting Interaction Meets and organized International Workshop on R&D challenges in CCS for a Sustainable Future

• Indian CO2 Sequestration Applied Research network has been started to disseminate the information on latest developments among various Stakeholders.



Energy Resource Perspectives –Identification of Research Needs

COAL SECTOR• Specific absorption test data for coal composition• Reservoir screening criteria• Modeling studies for fluid flow• Gas injection studies• Advancements in Drilling Technology for safer disposalOIL SECTOR• Laboratory experiments of CO2 absorption/injection/swelling • Composition simulation of oil & gas samples collected from well

head• Effect of displacement rate/saturation• Developing equation of state for CO2 oil phase behavior • Investigations of Natural Analogues in Natural gas fields



Workshop On R&D Challenges

Topics Covered– CCS & Energy Security– Materials Research for Carbon

Capture– Enhance Oil & CBM Recovery – CO2 Injection and Monitoring

Research – Pre-combustion and Near Zero

Emission Energy Technology – International Initiatives, Programs and

Collaborations




• Introduction





• Conclusions



Why Capture CO2?

• CO2 has almost 50% contribution to global warming

• IPCC report defines CO2 capture as process of separation of CO2 from industrial and energy related sources

• 4946 fossil fuel based power generation sources are identified as having emission of more than 0.1 mt/annum adding to 10.5 BT/annum

• 2945 other sources adding to about 3 MT/annum

• CO2 has almost 50% contribution to global warming

• IPCC report defines CO2 capture as process of separation of CO2 from industrial and energy related sources

• 4946 fossil fuel based power generation sources are identified as having emission of more than 0.1 mt/annum adding to 10.5 BT/annum

• 2945 other sources adding to about 3 MT/annum



Precombustion R&D In Academic Institutions And Research Laboratories

• Quality enhancement of coal for its efficient utilization

• Evaluations of combustion behavior of coal at different ash levels

• Development of a new coal washability index.• A plant scale comparison of Vorsyl separator

and dense medium cyclone in coal treatment• Prospects of coal water slurry as support

fuel in thermal power plants• Super Clean Coal Development



Clean Coal Technology Initiatives in Industry

• In house R&D in Industry like BHEL, NTPC, Tatas, SAIL and Jindals to give thrust to R&D on Coal Beneficiation, Coal Gasification, Liquefaction and IGCC

• Policy guidelines to use coal with < 34% ash in power plants at 1000km from pit head or in urban areas

• Non-coking coal washing capacity of 70 MT has been established

• Technology development for Coal Preparation, Fluidized Bed Gasification, IGCC, Oxy-fuel combustion and others

• Feasibility studies on In-situ coal gasification

• In house R&D in Industry like BHEL, NTPC, Tatas, SAIL and Jindals to give thrust to R&D on Coal Beneficiation, Coal Gasification, Liquefaction and IGCC

• Policy guidelines to use coal with < 34% ash in power plants at 1000km from pit head or in urban areas

• Non-coking coal washing capacity of 70 MT has been established

• Technology development for Coal Preparation, Fluidized Bed Gasification, IGCC, Oxy-fuel combustion and others

• Feasibility studies on In-situ coal gasification



Coal Based Capture Research

There is need for CCT development with a target to make zero emission power generation a reality



Market Place

Commercial Scale Demonstration

Demonstration

Research

CO2 CAPTURE

Cost effective capture

Oxy fuel Combustion

Pre Combustion Separation

Separation from natural gas

Current Status - Carbon Capture Technologies




• Introduction





• Conclusions



Potential Sites For Carbon Dioxide Storage and Their Potential

• Empty oil fields

• Empty natural gas fields

• Enhanced oil recovery

• Enhanced coal bed methane

• Saline aquifers

1

2

3

4

56

1. N gas fields on- shore

2. N gas fields off- shore

3. Coal beds

4. Aquifers

5. Oil fields on- shore

6. Oil fields off- shore



Large Scale Carbon Sequestration Research In India

Evaluation of Basalt Formations of India for environmentally safe and irreversible long time storage of CO2

CO2 injection for EOR in Ankleshwar field from Hazira gas. Scoping studies proposed

Research on underground disposal and coal bed methane undertaken

Collaborative research on screening criteria development for geological sequestration in Saline Aquifersinitiated



Co2 Trapping In Geological Media

•Dense gas•Physico – chemical properties between those of liquid and gas.•Solubility approaching liquid phase• Diffusivity approaching gas phase

Characteristics of Supercritical CO2

Characteristics of Supercritical CO2

CO 2(g)

CO 2(j)

CO 2(s)

Y

X

31.1-56.4-78.5

1 atm

5.11atm

73atm

Pre

ssu

re

Tem perature ( C )

Phase Diagram for CO 2



Proposed studies on geophysical sounding and deep resistivity surveys using Schumberger method for preparation of 2D and 3D models of subsurface lithography up to the depth of 800 m

Proposed studies on geophysical sounding and deep resistivity surveys using Schumberger method for preparation of 2D and 3D models of subsurface lithography up to the depth of 800 m

Study on Saline Aquifersfor Carbon Dioxide Sequestration



Market Place

Commercial Scale Demonstration

Demonstration

Research

CO2 Storage

Silicate minerals & basalt rocks

Abandoned coalmines, ECBM

Depleted oil/gas fields, saline aquifers

Storage for enhanced oil recovery

Status of Large Scale Carbon Storage Technologies




• Introduction





• Conclusions



Small Scale Carbon Sequestration Research In India

• Materials Research for Cost Effective Carbon Capture Process Development

• Micro-algae and Microbial Fixation of CO2 from Industrial effluents for value added products as multi-institutional projects

• Terrestrial and agro-forestry modeling studies to enhance sequestration rate of CO2 in ecosystem

• Regenerative carbon dioxide removal by chemical and biological means are other areas

• Adaptive response of microalgae to high CO2

coupled with high temperature and reduced pH



DST Programmes - Capacity Building

• Workshops held. First Inter-Sectoral CO2 Sequestration Research Interaction Meet at New Delhi on February 28, 2004

• 2nd DST CO2 Sequestration Technology Interaction Meet at New Delhi on March 23, 2006

• International Workshop on R&D Challenges in Carbon Capture and Storage Technology on Jan. 12-13, 2007 at Hyderabad (80 Participants including 19 eminent experts from USA, UK, Australia, Denmark, UAE, France, Bangladesh, and Saudi Arabia and others)

• A number of academic institutions and R&D laboratories evinced interest in CCS scientific research

• DST support also given to Young Researchers’ participation in National and International Programmes




• Introduction





• Conclusions



Conclusions

• Fossil fuels will continue to have major share in primary energy fuels globally

• Coal is dominant fuel meeting 69% of nation’s current commercial energy demand

• Emerging CCS options would make coal based thermal power generation environmentally friendly

• High cost of carbon capture and carbon storage and fall in efficiency of a power plant remain main barriers

• Pre-combustion CO2 sequestration requires more technology development efforts but may provide cost-effective solutions in the long run and can be used in conjunction with renewables



Future Prospects

• Our energy capacity has to grow to meet basic needs of People and coal use need to be sustained

• Carbon capture technologies are not fully developed and the cost is prohibitively high.

• There is a need for Generation of Industry Support and Partnerships

• The cost of CO2 sequestration is also the main barrier in acceleration of research efforts. Other means of covering the cost through income from energy fuel recovery or carbon credits not adequate.

• Require more attention to Infrastructure Development as the CO2 Storage Projects are Large Scale projects



Goal - Zero Emission Coal Based Technology

THANK YOU

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