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STATEMENT OF BASIS€¦ · STATEMENT OF BASIS for the issuance ofDraft Air Permit # 762-AOP-R13 1....

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STATEMENT OF BASIS for the issuance of Draft Air Permit # 762-AOP-R13 1. PERMITTING AUTHORITY: Arkansas Department of Environmental Quality 5301 Northshore Drive North Little Rock, AR 72118-5317 2. APPLICANT: Albemarle Corporation - South Plant Highway 79 South Magnolia, Arkansas 71756 3. PERMIT WRITER: Charles Hurt 4. PROCESS DESCRIPTION AND NAICS CODE: NAICS Description: All Other Miscellaneous Chemical Product and Preparation Manufacturing NAICS Code: 325998 5. SUBMITTALS: 11/13/2007,02/1912008 6. REVIEWER'S NOTES: Albemarle Corporation - South Plant owns and operates a chemical manufacturing facility on Highway 79, approximately seven miles south of Magnolia, Arkansas 71753. This modification incorporated all applicable requirements of 40 CFR Part 63, Subpart FFFF - National Emission Standardsfor Hazardous Air Pollutants Miscellaneous Organic Chemical Manufacturing and Miscellaneous Coating Manufacturing. Albemarle also requested to revise the short term emission limits under the MaN required testing scenarios. Due to the modification permitted HCI emissions decreased by 1.1 tpy. Based on the information submitted in the application the following limits were changed in the permit to comply with the MaN MACT. Source Pollutant MON MACT Limit Change (Ib HCI/yr) (Ib HCI/yr) AD-05 HCI 1,000 +1,000 DB-07 HCI 1,000 -3,200 7. COMPLIANCE STATUS: There are no enforcement issues or actions against the facility at this time. Albemarle was last inspected in October 2007 and determined to be in compliance.
Transcript

STATEMENT OF BASIS

for the issuance of Draft Air Permit # 762-AOP-R13

1. PERMITTING AUTHORITY:

Arkansas Department of Environmental Quality5301 Northshore DriveNorth Little Rock, AR 72118-5317

2. APPLICANT:

Albemarle Corporation - South PlantHighway 79 SouthMagnolia, Arkansas 71756

3. PERMIT WRITER: Charles Hurt

4. PROCESS DESCRIPTION AND NAICS CODE:

NAICS Description: All Other Miscellaneous Chemical Product and PreparationManufacturing

NAICS Code: 325998

5. SUBMITTALS: 11/13/2007,02/1912008

6. REVIEWER'S NOTES:

Albemarle Corporation - South Plant owns and operates a chemical manufacturing facilityon Highway 79, approximately seven miles south of Magnolia, Arkansas 71753. Thismodification incorporated all applicable requirements of 40 CFR Part 63, Subpart FFFF ­National Emission Standardsfor Hazardous Air Pollutants Miscellaneous Organic ChemicalManufacturing and Miscellaneous Coating Manufacturing. Albemarle also requested torevise the short term emission limits under the MaN required testing scenarios. Due to themodification permitted HCI emissions decreased by 1.1 tpy.

Based on the information submitted in the application the following limits were changed inthe permit to comply with the MaN MACT.

Source PollutantMON MACT Limit Change

(Ib HCI/yr) (Ib HCI/yr)AD-05 HCI 1,000 +1,000DB-07 HCI 1,000 -3,200

7. COMPLIANCE STATUS:

There are no enforcement issues or actions against the facility at this time. Albemarle waslast inspected in October 2007 and determined to be in compliance.

Permit #:762-AOP-R13AFIN: 14-00028Page 2 of25

8. APPLICABLE REGULATIONS:

PSD ApplicabilityDid the facility undergo PSD review in this permit (i.e., BACT,

Modeling, et cetera?Has this facility undergone PSD review in the past?

Is this facility categorized as a major source for PSD?<0 100 tpy and on the list of28 (100 tpy)?

<0 250 tpy all other

PSDNettingWas netting performed to avoid PSD review in this permit?

N

NYYy

N

Permit#

Source and Pollutant Specific Regulatory Applicability

Source PollutantRegulation [NSPS, NESHAP (part

61 & Part 63), or PSD onlYlFacility PM IO, SOb VOC, CO, NOx PSD

Facility VOC40 CFR Part 82 - Standards for the Protection

of Stratospheric Ozone

Facility PM/PM IO40 CFR Part 61, Subpart M - National

Emission Standard for AsbestosAD-17 DB-07AD-24 DE-04

40 CFR Part 60, Subpart Kb - Standards ofAD-25 DE-09AD-28 DE-12

VOCIHAP Performance for Volatile Organic Liquid

AD-29 DE-20 Storage Vessels

AB-15 TB-03flO CFR Part 61, Subpart FF - National

DECTP Process VOC/HAP IEmission Standards for Benzene Wastepperationsf:lo CFR Part 63, Subpart A - National Emission

AB-15 VOC/HAP Standards for Hazardous Air Pollutants forSource Categories, General Provisionsf:lo CFR Part 63, Subpart F - National EmissionStandards for Hazardous Air Pollutants from~e Synthetic Organic Chemical Manufacturing

AB-15ndustly

TB-03TB-31

TB-IITB-32 ~O CFR Part 63, Subpart G - National Emission

TB-17TB-33

VOCIHAPStandards for Hazardous Air Pollutants from

TB-25TB-34 he Synthetic Organic Chemical Manufacturing

TB-29TB-35 i1ndustly for Process Vents, Storage Vessels,

TB-30WW-OI Irransfer Operations, and Wastewater

~O CFR Part 63, Subpart H - National EmissionStandards for Organic Hazardous Air Pollutantsfor Equipment Leaks

Permit #:762-AOP-R13AFIN: 14-00028Page 30[25

Source PollutantRegulation [NSPS, NESHAP (part

61 & Part 63), or PSD onJyl40 CFR Part 60, Subpart VV - Standards of

TB-29 VOCIHAPPerfonnance for Equipment Leaks ofVOC inhe Synthetic Organic Chemical Manufacturingndustry

NC-1440 CFR Part 82, Part A - Protection of

ProcessOzone Depleting Substances Stratospheric Ozone, Production and

Consumption Controls40 CFR Part 82, Subpart E - Protection of

NC-14 Process Ozone Depleting Substances Stratospheric Ozone, The Labeling of ProductsUsing Ozone-Depleting Substances

NC-1740 CFR Part 63, Subpart A - National Emission

CMPUVOCfHAP Standards for Hazardous Air Pollutants for

Source Categories, General Provisions40 CFR Part 63, Subpart F - National Emission

NC-17VOCfHAP

Standards for Hazardous Air Pollutants fromCMPU he Synthetic Organic Chemical Manufacturing

Industry40 CFR Part 63, Subpart G - National Emission

NC-17 Standards for Hazardous Air Pollutants from

CMPUVOCfHAP he Synthetic Organic Chemical Manufacturing

ndustry for Process Vents, Storage Vessels,Transfer Operations, and Wastewater

NC-17 140 CFR Part 63, Subpart H - National Emission

CMPUVOCfHAP Standards for Organic Hazardous Air Pollutants

for Equipment Leaks

21-01 40 CFR Part 61, Subpart A - National Emission

21-02VOCfHAP Standards for Organic Hazardous Air

Pollutants, General Provisions

21-01 ~o CFR Part 61, Subpart J - National Emission

21-02VOCfHAP Standards for Equipment Leaks (Fugitive

Emission Sources) of Benzene

21-01 140 CFR Part 61 , Subpart V - National Emission

21-02VOCfHAP Standards for Equipment Leaks (Fugitive

Emission Sources)

21-01 ~o CFR Part 61, Subpart Y - National Emission

21-02VOCfHAP Standards for Benzene Emissions from Benzene

Storage Vessels

21-01 ~o CFR Part 61, Subpart FF - NationalVOCfHAP ~mission Standards for Benzene Waste

21-02 pperations~O CFR Part 63, Subpart JJ - National

MS-05 VOCfHAP IEmission Standards for Wood FurnitureManufacturing Operations~O CFR Part 82, Subpart E - Protection of

Facility Ozone Depleting Substances Stratospheric Ozone, The Labeling of ProductsIUsing Ozone-Depleting Substances

Pennit #:762-AOP-RI3

AFIN: 14-00028

Page 4 of25

Source PollutantRegulation [NSPS, NESHAP (part

61 & Part 63), or PSD onlylMCPU's:

DECTPDMTDA ~o CFR Part 63, Subpart FFFF - National

NC-12 !Emission Standards for Hazardous AirVOCfHAP !Pollutants: Miscellaneous Organic Chemical

NC-15 lManufacturing and Miscellaneous CoatingNC-17 lManufacturingNC-21NC-23

CCF ~O CFR Part 63, Subpart EEEE - National

All Ethylene Glycol VOCfllAP!Emission Standards for Hazardous AirlPollutants: Organic Liquids Distribution (Non-

Storage ~asoline)

9. EMISSION CHANGES:

The following table summarizes plant wide emission changes associated with this pennittingaction.

Plant Wide Permitted Emissions (ton/yr)Pollutant Air Permit 762-AOP-RI2 Air Permit 762-AOP-RI3 Chane;e

PM 130.46 130.46 0PM IO 119.36 119.36 0S02 3,312.19 3,312.19 0

VOC 569.92 569.92 0CO 209.09 209.09 0

NOx 471.37 471.37 0Xylene + Ethyl Benzene 15.35 15.35 0

1,1-Dichloroethane 0.39 0.39 01,2-Epoxybutane 0.20 0.20 0

Acetaldehyde 1.80 1.80 0Benzene 8.00 8.00 0

Bromoform 4.15 4.15 0Chloroethane 2.95 2.95 0Chloroform 0.39 0.39 0

Chlorine 3.42 3.42 0Ch + Br2 0.10 0.10 0

Ch or Halogens 13.32 13.32 0Dimethyl Formide 0.39 0.39 0Ethylene Chloride 0.88 0.88 0

Ethyl Benzene 0.01 0.01 0Ethylene Dibromide 5.50 5.50 0

Permit #:762-AOP-RI3AFlN: 14-00028Page 5 of25

Plant Wide Permitted Emissions ltonlvr)Pollutant Air Permit 762-AOP-R12 Air Permit 762-AOP-RI3 Chanee

Ethylene Dichloride 0.40 0.40 0Ethylene Glycol 5.45 5.45 0

HCI 41.00 38.9 -1.1Hexane 0.05 0.05 0

Iso-Octane 0.01 0.01 0Dichloromethane 7.70 7.70 0

Methanol 33.66 33.66 0Methyl Bromide 18.25 18.25 0

Methyl Naphthalene 5.59 5.59 0Phenol 0.09 0.09 0

Phthalic Anhydride 1.24 1.24 0Toluene Diamine 0.35 0.35 0

Toluene 24.78 24.78 0Xylene 0.02 0.02 0

Br2 + HBr 82.68 82.68 0Acetone 0.30 0.30 0

Ammonia 48.40 48.40 0Br2 26.73 26.73 0

BrCI 0.88 0.88 0H20 2 9.30 9.30 0H2S 4.04 4.04 0

H2SO4 0.06 0.06 0HBr 11.89 11.89 0

Non-YOC/Non-HAP4.64 4.64 0

Refrigerants

10. MODELING:

Criteria Pollutants

Criteria pollutant emission rates were not affected with this modification. Modeling listedbelow is was conducted for a previous modification.

*

Permit #:762-AOP-RI3AFIN: 14-00028Page 6 of25

EmissionNAAQS

AveragingHighest

%ofPollutant Standard Concentration

RateQb/hr)(p2lm~

Time(p2lm1*

NAAQS

PM 10 32.1850 Annual 39.03 78.1%150 24-hour 99.24 66.2%80 Annual 20.1 25.2%

SOz 756.6 1,300 3-hour 1,178.5 90.7%365 24-hour 330.0 90.5%

NOx 177.88 100 Annual 40.66 40.7%VOC** 566.60 0.12 I-hour (ppm) 0.0299 24.9%

CO 234.3210,000 8-hour 4927 49.3%40,000 I-hour 10,802 27.0%

Includes the background concentratIon** Scheffe Method

Other Modeling

Odor modeling for sources emitting styrene.

Albemarle is not a source for styrene emissions therefore odor modeling for styrene was notperformed.

A.C.A. §8-3-103 requires hydrogen sulfide emissions to meet specific standards.

Pollutant Threshold valueModeled Concentration

Pass?(ppb)20 parts per billion

0.6 y(5-minute average)

HzS I00 parts perbillion

0.1 y(8-hour average)

nonresidential area

Non-Criteria Pollutants

1st Tier Screening (PAER)

Estimated hourly emissions from the following sources were compared to the PresumptivelyAcceptable Emission Rate (PAER) for each compound. The Department deemed PAER tobe the product, in lb/hr, of 0.11 and the Threshold Limit Value (mg/m\ as listed by theAmerican Conference of Govemmentallndustrial Hygienists (ACGIH).

Permit #:762-AOP-R13AFIN: 14-00028Page 70f25

Non-Criteria Pollutants

lst Tier Screening (PAER)

Estimated hourly emissions from the following sources were compared to the PresumptivelyAcceptable Emission Rate (PAER) for each compound. The Department deemed PAER tobe the product, in Ib/hr, of 0.11 and the Threshold Limit Value (mg/m\ as listed by theAmerican Conference of Governmental Industrial Hygienists (ACGIH).

PollutantTLV PAER (lb/hr) Proposed

Pass?(mwm3) = O.l1*TLV Ib/hr

Benzene 1.6 0.176 8.00 NBromoform 5.16 0.567 5.03 N

Chlorine 1.45 0.160 5.36 NEthyl Chloride 262.78 28.91 2.60 Y

Dimethyl Formide 30.00 3.30 0.09 yEthylene Dibromide 154.00 16.94 4.60 yEthylene Dichloride 40.00 4.40 0.19 Y

Ethylene Glycol 125.00 13.75 1.17 yHCI 2.98 0.32 15.48 N

Methanol 262.08 28.82 61.23 NMethyl Bromide 19.00 2.09 17.91 N

Methyl Naphthalene 20.00 2.20 1.36 yMethylene Chloride 174.00 19.14 1.74 yPhthalic Anhydride 6.10 0.67 3.93 N

Toluene 188.40 20.72 50.95 NToluene Diamine 2.00 0.22 0.08 y

Xylene 434.00 47.74 4.03 yEthyl Benzene 434.00 47.74 3.56 Y

Phenol 19.00 2.09 0.10 yHexane 176.00 19.36 3.89 y

Acetaldehyde 45.04 4.95 0.20 YIso-Octane 25.00 2.75 0.40 y

1,2-Epoxybutane 117.99 12.98 0.20 y

ISCST3 air dispersion modeling was performed on the estimated hourly emissions from thefollowing sources, in order to predict ambient concentrations beyond the property boundary.The Presumptively Acceptable Impact Level (PAIL) for each compound was deemed by theDepartment to be one one-hundredth ofthe Threshold Limit Value, as listed by the ACGIH.

Permit #:762-AOP-RI3AFIN: 14-00028Page 8 of25

Pollutant(pAIL, pglm) = 11100 of Modeled Concentration

Pass?Threshold Limit Value (p.vm)

Benzene 16.0 15.78 y

Bromoform 51.6 21.02 y

Chlorine 14.5 5.76 y

HCI 30.00 20.70 y

Methanol 2620 1256.00 YMethyl Bromide 39.0 38.9 y

Phthalic Anhydride 61.00 53.75 y

Toluene 1884 1045 Y

11. CALCULATIONS:

Emission Emission ControlControl

Comments (Emission

SNFactor Source Factor and Equipment

Equipmentfactor

(AP-42, units (lbs/ton, Type (if controlled/uncontrolled,Testine;, etc) Ibs/hr, etc) any)

Efficiencyetc)

BR-OI Testing 1.5 Iblhr VOC Scrubber99% Control for Bromine

and ChlorineBR-04 Testing 3.81 Iblhr VOCBR-08 Tanks 0.04 Iblhr HCI

BR-09 Mass Balance0.02 Iblhr HBr0.02 Iblhr Br2

BR-12 Testing0.10 Iblhr Ciz

Scrubber 99.90.30 Iblhr Br2

BR-14 SOCMI 0.50 Iblhr VOC

BR-15 Testing1.63 IblhrHalogens

SL-Ol AP-42 See Section 14. ISL-02 Mass Balance 0.12 Iblhr VOCSR-OI AP-42 See Section 14.1SR-02 SOCMI 0.50 Iblhr VOCCB-OI Mass Balance 0.1 Ib/hr PM IO

CB-02 Mass Balance 0.27 Iblhr VOCCB-04 Mass Balance 26.00 Iblhr VOCCB-16 Mass Balance 0.27 Iblhr VOCCB-17 SOCMI 1.80 Iblhr VOCCB-18 Mass Balance 0.1 Iblhr PM IO

CB-02Test 9.00 Iblhr VOC

CB-16ADMA Brine Storage Tank

DE-OI Mass Balance 0.5 Iblhr VOC (Additional ADMA StorageScenario)

DE-04 Tanks 8.96 Iblhr VOC

Permit #:762-AOP-R13AFIN: 14-00028Page 9 0[25

Emission Emission ControlControl

Comments (Emission

SNFactor Source Factor and Equipment

Equipmentfactor

(AP-42, units Obs/ton, Type (if controUed/uncontroUed,Testine:, etc) Ibslhr, etc) any) Efficiency

etc)DE-06 Tanks 0.62 Ib/hr VOCDE-07 Tanks 0.62 Ib/hr VOCDE-08 Tanks 0.62 Ib/hr VOCDE-lO Tanks 0.62 Ib/hr VOCDE-II Tanks 0.62 Ib/hr VOCDE-12 Tanks 0.62 Ib/hr VOCDE-17 AP-42 See Section 14.1DE-18 AP-42 See Section 14.1DE-19 Mass Balance 8.00 Ib/hr VOCDE-20 Tanks 9.40 lb/hr VOCDE-21 AP-42 See Section 14.1DE-22 SOCMI 9.40 Ib/hr VOCDE-23 Mass Balance 2.83 Ib/hr VOCDE-24 Mass Balance 12.70 Ib/hr VOCDE-28 Mass Balance 23.60 Ib/hr VOCAD-OI Tanks 0.16 Ib/hr VOCAD-02 Tanks 0.16 Ib/hr VOCAD-03 Tanks 0.26 Ib/hr VOC

VOC Tanks0.20 Ib/hr VOC

AD-05 HCI MassBalance

0.10 lb/hr HCI

AD-07 Tanks 0.05 Ib/hr VOCAD-08 Tanks 0.05 Ib/hr VOCAD-09 Tanks 0.05 Ib/hr VOCAD-IO Tanks 0.26 Ib/hr VOCAD-II Tanks 0.26 Ib/hr VOCAD-12 Tanks 0.26 Ib/hr VOCAD-13 Tanks 0.26 lb/hr VOCAD-14 Tanks 0.26 Ib/hr VOCAD-15 Tanks 0.26 Ib/hr VOCAD-17 Tanks 0.26 Ib/hr VOCAD-18 Tanks 0.26 Ib/hr VOCAD-20 Tanks 0.16Ib/hrVOCAD-21 Tanks 3.45 Ib/hr VOCAD-23 Tanks 0.03 Ib/hr VOCAD-24 Tanks 0.26 Ib/hr VOCAD-25 Tanks 0.26 Ib/hr VOCAD-26 AP-42 See Section 14.1AD-27 Tanks 0.26 Ib/hr VOCAD-28 Tanks 0.08 Ib/hr VOC

Pennit #:762-AOP-RI3AFIN: 14-00028Page 10 of25

Emission Emission ControlControl

Comments (Emission

SNFactor Source Factor and Equipment

Equipmentfactor

(AP-42, units (Ibslton, Type (if controUedJuncontroUed,Testine, etc) Ibslhr, etc) any) Efficiency etc)

AD-29 Tanks 0.08 Ib/hr VOC0.22 Ib/hr PM IO

See0.09 lb/hr SOz

AD-35Application

1.22 lb/hr VOC0.06 Ib/hr CO0.701b/hrNOx

AD-36 SOCMI 4.13 lb/hr VOCAD-37 Tanks 0.05 lb/hr VOC

ADMA Additional Storage

AD-39 Mass Balance 0.1 lb/hr VOCAlternate OperatingScenario Loadout

EmissionsAD-40 Mass Balance 0.26 lb/hr VOCAB-15 Testing 1.20 lb/hr VOCAB-16 SOCMI 7.50 Ib/hr VOC

DB-OI Mass Balance0044 lb/hr

ScrubberIncludes assumed scrubber

Halogens efficiency of99.9%Manufacturer 1.8 Ib/hr PM IO

Specification 0.14 Ib/hr SOzDB-04 (combustion) 0.96 Ib/hr VOC

Mass Balance 3.6 Ib/hr CO(PM) 1.6 Ib/hr NOx

DB-OS Mass Balance 0.3 Ib/hr PM IO

DB-06 Mass Balance 0.3 Ib/hr PM IO

DB-07 Mass Balance O.IOlb/hrVOCDB-08 Mass Balance 1.I Ib/hr PM IO

DB-IO Mass Balance 0.01 Ib/hr VOCDB-16 SOCMI lAO Ib/hr VOC

DB-17 Mass BalanceO.IOlb/hrHalogens

DB-18 Mass Balance0.06 g/fe @ 460

99.9%fe/min

DB-19 Mass Balance1.00 Ib/hr Brz

40%+HBr

TB-03Mass Balance 2.57 Ib/hr VOC

(MeBr)TB-03

Mass BalanceO.IOlb/hr

(NaBr) HalogensTB-03

Mass Balance 10.70 lb/hr VOC(EtBr)

Permit #:762-AOP-R13AFIN: 14-00028Page II of25

Emission Emission ControlControl

Comments (Emission

SNFactor Source Factor and Equipment

Equipmentfactor

(AP-42, units (Ibs/ton, Type (if controlled/uncontrolled,Testin2, etc) Ibslbr, etc) any) Efficiency

etc)TB-04(NC- Mass Balance 0.90 Ib/hr PM IO

22)TB-08(NC- Mass Balance 0.30 lb/hr PM 10

22)TB-II

Tanks 2.91 Ib/hr VOC(MeBr)

ADMA Brine Storage TankTB-II Mass Balance 0.1 Ib/hr VOC (Additional ADMA Storage

Scenario)TB-12

Tanks 0.10 lb/hr VOC(MeBr)TB-12

Tanks 0.53 Ib/hr VOC(EtBr)TB-14

0.301b/hr(Stabro Mass Balance

Halogensm)

TB-14O.IOlb/hr

(NC- Mass BalanceHalogens

22)TB-25

Mass Balance 0.40 Ib/hr VOC(MeBr)TB-29

SOCMI 0.93 Ib/hr VOC(MeBr)TB-29

0.301b/hr(Stabro SOCMI

Halogensm)

TB-29SOCMI 3.47 lb/hr VOC

(EtBr)TB-29(NC- SOCMI 1.33 lb/hr VOC22)

TB-30Tanks 11.80 lb/hr VOC

(MeBr)TB-30

Tanks 11.30 lb/hr VOC(EtBr)TB-37

Mass Balance 1.34 Ib/hr VOC(EtBr)

Pennit #:762-AOP-RI3AFIN: 14-00028Page 12 of25

Emission Emission ControlControl

Comments (Emission

SNFactor Source Factor and Equipment

Equipmentfactor

(AP-42, units (Ibslton, Type (if controlled/uncontrolled,Testine:, etc) Ibs/hr, etc) any)

Efficiency etc)

TB-41(NC- Mass Balance 6.40 Ib/hr VOC22)

TB-42(NC- Tanks 0.09 Ib/hr HBr22)

TB-43(NC- Mass Balance 0.25 Ib/hr VOC22)

15-02 Mass Balance0.201b/hr

Scrubber 99.99%Halogens

15-09 Tanks 0.03 Ib/hr VOC15-12 AP-42 See Section 1.415-13 AP-42 0.07 Ib/hr VOC15-15 SOCMI 4.23 IbJhr VOC15-16 Mass Balance 1.20 Ib/hr VOC15-17 Mass Balance 0.69 Ib/hr VOC15-18 Mass Balance 0.10 Ib/hr VOC

16-01 Mass Balance0.50 Iblhr S020.10 Iblhr PM IO

16-02 Mass Balance0.40 Iblhr S02

0.10 Iblhr VOC16-05 Mass Balance 0.10 Iblhr VOC

16-06 Mass Balance0.10 Iblhr VOC0.40 Iblhr VOC

16-07 Testing 0.30 Iblhr PM 10

16-08 Testing 0.30 Iblhr PM IO

16-10 Testing 0.50 Iblhr PM IO

16-11 Testing 0.10 Iblhr PM IO

16-12 Testing 0.1 0 Iblhr PM 10

16-13 Mass Balance 0.10 Iblhr S0216-14 Mass Balance 0.10 Ib/hr VOC16-15 Mass Balance 0.01 Iblhr VOC16-16 Mass Balance 0.10 lblhr S0216-17 Mass Balance 0.02 Iblhr VOC16-18 AP-42 See Section 1.4

Testing

16-19(PM IO) 0.30 Iblhr PM 10

Mass Balance 0.10 Iblhr S02(S02)

Permit #:762-AOP-R13AFIN: 14-00028Page 130[25

Emission Emission ControlControl

Comments (Emission

SNFactor Source Factor and Equipment

Equipment factor(AP-42, units (Ibs/ton, Type (if controUed/uncontroUed,

Testin2, etc) Ibs/hr, etc) any)Efficiency

etc)7.6lb/MMscf

AP-42PM IO

(PM, S02,0.60 Ib/MMscf

S0216-20

NOx)100 Ib/MMscf

VendorNOxSpecification

0.19 Iblhr CO(CO, VOC)

0.13 Iblhr VOC

Testing

16-21(PMIO) 0.20 Ib/hr PM 10

Mass Balance 0.40 Ib/hr VOC(VOC)

16-22 Mass Balance0.01 Ib/hr PM IO

0.01 Iblhr VOC16-23 SOCMI 6.60 Ib/hr VOC16-24 Mass Balance 1.80 Iblhr S03

16-25 Mass Balance0.40 Iblhr PMIO Includes assumed 99%1.02 Iblhr VOC PM IO control efficiency

16-26 Testing 0.30 Iblhr PM16-27 Testing 0.30 Iblhr PM16-28 Mass Balance 0.10 Iblhr S0216-31 Mass Balance 3.83 Iblhr VOC

Testing2.59 Iblhr PM IO(S02, VOC,5.60 lblhr S02

Emission rates are for eachBH-OI NOx, CO) 1.87 Iblhr VOC

boiler except S02. TheBH-02 AP-42

13.60 Iblhr COemission rate for S02 is

(PM IO)47.601blhrNOx

bubbled for both sources.

Testing 0.10 Iblhr PM IO

(PM IO) 0.01 Iblhr S02 Emissions are calculated21-01 Mass Balance 1.71 Iblhr VOC

every six months.(VOC, S02, 3.80 Iblhr VOCCO, NOx) 0.50 Iblhr NOx

21-02 SOCMI 3.72 Iblhr VOC

21-03 Mass Balance 0.01 Iblhr VOCEmissions are calculated

annually.21-04 Testing 0.80 Ib/hr VOC23-01 SOCMI 1.12 Iblhr VOC23-02 Mass Balance 0.10 Iblhr PM IO

23-03 Testing 0.35 Iblhr VOC

Permit #:762-AOP-R13AFIN: 14-00028Page 14 of25

Emission Emission ControlControl

Comments (Emission

SNFactor Source Factor and Equipment Equipment

factor(AP-42, units Obs/ton, Type (if controlled/uncontrolled,

Testin2, etc) Ibslhr, etc) any)Efficiency

etc)23-04 Mass Balance 0.44 Iblhr VOC23-05 Testing 2.90 Iblhr VOC

23-06Mass Balance

23-07(PM 10) 0.30 Iblhr PM IO

23-08Testing 3.80 Iblhr VOC(VOC)

23-09 Mass Balance 0.10 Iblhr PM 10

23-10 Mass Balance 0.10 Iblhr PM \0

23-IIAMass Balance 0.10 Ib/hr PM 10

23-IIB23-12A

Mass Balance 0.101blhrPM 1o23-12B23-13 Mass Balance 0.10 Ib/hr PM IO

BT-Ol Mass Balance0.01 Ib/hr VOC0.141blhrH2S

0.01 Ib/hr VOC

BT-II0.01 Iblhr H2S Emission rates for each

BT-13Mass Balance 0.20 Iblhr NH3

0.03 Iblhrsource.

HalogensBT-12,BT-23,

0.01 Iblhr VOCBT-24, 0.20 Iblhr NH3 Emission rates for eachBT-25, Mass Balance

0.031blhrBT-26,

source.

BT-27,Halogens

BT-28BT-16,

Mass Balance30.00 Iblhr VOC Emission rates for each

BT-29 0.01 Iblhr H2S source.

BT-17 Tanks16.40 Iblhr VOC0.01 Iblhr H2S

4.121blhrPM IO

3.37 Iblhr VOCBT-21 Mass Balance 10.23 Iblhr NH3

2.891blhrHalogens

BT-22Engineering

0.02 Iblhr VOCEstimate

DM-OI Tanks 0.03 Iblhr VOCDM-02 AP-42 See Section 1.4

Permit #:762-AOP-R13AFIN: 14-00028Page 150[25

Emission Emission ControlControl

Comments (Emission

SNFactor Source Factor and Equipment

Equipmentfactor

(AP-42, units Obslton, Type (if controUed1uncontroUed,Testing, etc) Ibslhr, etc) any) Efficiency

etc)DM-03

Tanks 0.81 lb/hr HzOzEmission rates for each

DM-06 source.DM-07 SOCMI 3.18 lb/hr VOC

MS-Ol Mass Balance 4.00 lb/hr VOCCalculate emission rateonce every six months

MS-02 Mass Balance 0.10 lb/hr VOCCalculate emission rateonce every six months

MS-03 Mass Balance 0.30 Ib/hr VOCCalculate emission rateonce every six months

MS-05 Mass Balance 0.67 lb/hr VOC

MS-06 Mass Balance0.50 Ib/hr SOl7.00 lb/hr VOC

MS-07 Tanks 47.70 lb/hr VOCEmission rates are based on

3.00 lb/hr PM IO worst case fuel combustion.2.80 lb/hr SOz VOC emission rate includes

MS-08 AP-42 8.10 Ib/hr VOC an estimate for non-162.5 lb/hr CO combustion emissions

41.60 lb/hr NOx (evaporation, crankcase,and refueling losses).Combined all Non-

MS-12 SOCMI1.061b/hr VOClNon-HAP Refrigerant

Refrigerant emissions for the entirefacility

2.00 Ib/hr VOC Primary Operating

24-01 Mass Balance0.10 Ib/hr HBr VOC emissions from the

0.10 Ib/hr Acetone reactor before flaring are0.10 Ib/hr HCl 48.51b/hr

48.5 lb/hr VOCVOC missions are not sent

to a flare but emitted24-01 Mass Balance

0.10 lb/hr HBrdirectly to the atmosphere

0.10 Ib/hr AcetoneHBr and HCI are scrubbed

0.10 Ib/hr HCl out by the wash column.1.1 Ib/hr VOC0.1 lb/hr HBr

24-02 SOCMI0.1 Ib/hr Acetone

1.3 Ib/hr HCI0.1 lb/hr 1,2-Epoxybutane

Permit #:762-AOP-R13AFIN: 14-00028Page 16 of25

12. TESTING REQUIREMENTS:

This permit requires stack testing of the following sources.

SN(s) PollutantTest

Test IntervalJustification For Test

Method RequirementBR-Ol

VOC 18/25A 5 year Compliance VerificationBR-04BR-OI

Br2BR-04 26A 5 year Compliance VerificationBR-12

CI2

SR-OI S02 6C 5 year Compliance VerificationCB-02

Br2 26A 5 year Compliance VerificationCB-16CB-02

VOC 18or25AEvery 365

Compliance Verification(Alternate) days operation

CB-16VOC 18or25A

Every 365Compliance Verification

(A Iternate) days operationDE-21 VOC 18 or 25A 5 year Compliance VerificationDE-23 VOC 18or25A 5 year Compliance VerificationDE-23 HCI 26 5 year Compliance VerificationDE-23 Chloroethane 18 5 year Compliance VerificationAD-05 VOC 18 or 25A 5 year Compliance Verification

AD-05HBr 26A

5 year Compliance VerificationBr2 26A

PM 10 5S02 6C

AD-25 VOC 18/25A 2 years Compliance VerificationCO lOB

NOx 7E

AD-35HBr 26A

5 year Compliance VerificationBr2 26A

DB-OI Br2 26A 5 year Compliance VerificationDB-04 Br2 26A 5 year Compliance Verification

HBr 26AEvery 8760

TB-03Br2 26A

hrs of Compliance Verificationoperation

TB-14 Br2 26A Every 8760

(Stabrom)BrCI 26A hrs of Compliance VerificationCh 26A operation

15-12 VOC 18 or 25A 2 year Compliance Verification15-12 PM 10 5 2 year Compliance Verification15-12 Br2 26A 5 year Compliance Verification15-16 PM IO 5 2 year Compliance Verification

Permit #:762-AOP-R13AFIN: 14-00028Page 17 of25

SN(s) PoUutant Test Test IntervalJustification For Test

Method Requirement

16-01 S02Approved

5 year Compliance VerificationMethod

16-02 Br2 26A 5 year Compliance Verification

16-02 S02Approved

5 year Compliance VerificationMethod

16-24 S02Approved

5 year Compliance VerificationMethod

16-25 VOC 25 A 5 year Compliance VerificationSOl 6C

BH-OI VOC 18/25A5 year Compliance Verification

BH-02 CO lOBNOx 7E

Approved5 year after

21-04 VOC initial Compliance VerificationMethod

compliance23-03 VOC 18 5 year Compliance Verification23-05 VOC 18 5 year Compliance Verification

23-065 year, one

23-07 VOC 18silo, must be

Compliance Verificationin receiving

23-08mode

23-065 year, one

23-07 HBr 26Asilo, must be

Compliance Verificationin receiving

23-08mode

PM 10 5

DM-02VOC 18

5 year Compliance VerificationCO lOB

NOx 7EDM-02 S02 6C 2 year Compliance Verification

13. MONITORING OR CEMS

The permittee must monitor the following parameters with CEMs or other monitoringequipment (temperature, pressure differential, etc), frequency of recording and the need forrecords included in any annual, semiannual or other reports.

Parameter or Method of Monitoring (CEM, ReportSN PoUutant to be Frequency*

MonitoredPressure Gauge, etc) (Y/N)**

BR-OlFlow Rate Flow Rate Monitor Continuously y

BR-04SR-OI Temperature Thermocouple Continuously N

Pennit #:762-AOP-RI3AFIN: 14-00028Page 180[25

Parameter or Method of Monitoring (CEM, ReportSN Pollutant to be Frequency*

MonitoredPressure Gauge, etc) (YIN)**

DE-21 Temperature Thermocouple Continuously NDE-23 Flow Rate Flow Rate Monitor Continuously NAD-05 Flow Rate Flow Rate Monitor Continuously NAD-35 Temperature Thermocouple Continuously N

TB-13Liquid to Gas Mass

Flow Rate Monitor Continuously NFlow Rate

TB-13Stripper

Thermocouple Continuously NTemperature

TB-25 CoolantThennocouple Continuously N

(NC-24) Temperature15-02 Br2 CEM Continuously N15-12 Br2 CEM Continuously N

16-01Scrubber Media

Flow Rate Monitor Every 3 hours NFlow Rate

16-01 Scrubber Media pH pH Monitor Every 3 hours N

16-02Scrubber Media

Flow Rate Monitor Every 3 hours NFlow Rate

16-02 Scrubber Media pH pH Monitor Every 3 hours N

16-05Scrubber Media

Flow Rate Monitor Every 3 hours NFlow Rate

16-05 Scrubber Media pH pH Monitor Every 3 hours N

16-06Scrubber Media

Flow Rate Monitor Every 3 hours NFlow Rate

16-06 Scrubber Media pH pH Monitor Every 3 hours N

16-13Scrubber Media

Flow Rate Monitor Every 3 hours NFlow Rate

16-24Scrubber Media

Flow Rate Monitor Every 3 hours NFlow Rate

16-25Scrubber Media

Flow Rate Monitor Every 3 hours NFlow Rate

16-25 Scrubber Media pH pH Monitor Every 3 hours NContinuously for

BH-OI H2S Concentration / H2S Concentration Monitor / Flowconcentration

BH-02 Gas Flow Rate Rate MonitorOnce every six Nhours for flow

rate

21-01Process Gas Flow

Flow Rate Monitor Continuously NRate into Oxidizer

21-01Combustion Zone

Thermocouple Continuously NTemperature

Permit #:762-AOP-RI3AFIN: 14-00028Page 19 of25

Parameter orMethod of Monitoring (CEM, Report

SN Pollutant to be Frequency*Monitored

Pressure Gauge, etc) (YIN)**

23-03Scrubber media

Flow Rate Monitor Continuously NFlow Rate

23-05Scrubber media

Flow Rate Monitor Continuously NFlow Rate

DM-02Combustion Zone

Thermocouple Continuously NTemperature

Water Flow Rate Flow Rate Monitor24-01 Chilled Water

ThermocoupleContinuously N

Temperature* Indicate frequency of recordmg reqUIred for the parameter (Contmuously, hourly, dally, etc.)** Indicates whether the parameter needs to be included in reports.

14. RECORD KEEPING REQUIREMENTS

The following are items (such as throughput, fuel usage, VOC content of coating, etc) thatmust be tracked and recorded, frequency of recording and whether records are needed to beincluded in any annual, semiannual or other reports.

SN Recorded ItemLimit (as established in

Frequency*Report

permit) (YIN)**

BR-OIEstablished according to

BR-04Brine Solution Flow Rate most recent satisfactory Continuous Y

test

Pump Discharge Valve PositionEstablished according to

BR-12and Run Light

most recent satisfactory 3 hours y

testStrength of caustic

EachBR-12

Caustic Concentration of solution as established RailCar/Truck yScrubber Media according to most recent

Unloadingsatisfactory test

SR-OI Flare Temperature 1200 of or above Continuous N

CB-04 Methanol Throughput106 gallon per

Monthly Yconsecutive 12 months

CB-02 Batch Production 1460 batches perMonthly Y

CB-16 (Alternate Scenario) consecutive 12 monthsDE-21 Combustion Zone Temperature 1400 OF or above Continuous N

Established according toDE-23 Scrubber Media Flow Rate most recent satisfactory 3 hours N

test

Pennit #:762-AOP-R13AFIN: 14-00028Page 20 of25

SN Recorded ItemLimit (as established in Frequency*

Reportpermit) (YIN)**

Strength of causticEach

DE-23Caustic Concentration of solution as established

RailCar/Truck NScrubber Media according to most recent

Unloadingsatisfactory test

Established according toAD-05 Scrubber Media Flow Rate most recent satisfactory 4 hour N

testStrength of caustic

Caustic Concentration ofsolution and change out

AD-05Scrubber Media

as established according 12 hour Nto most recent satisfactory

testNot to exceed 4380 hours

AD-21 Period of Storage ofC8 Olefin per consecutive 12 Monthly Nmonths

AD-35 Flare Temperature I500 of or above Continuous NDuration of each Alternate 2.9 tpy VOC as

AD-39 Scenario Event and Vapor calculated from mass Per Event NPressure balance and records

Carbon Bed Regenerate every 12AB-15 Regeneration/Carbon hours N/A N

Replacement Replace Every 10,220 hrs

DB-OICaustic Concentration of

Must be greater than 5% 12 hour NScrubber Media

DB-07 Dried Tanks of Diphenyl Oxide 150 tanks per year Monthly N

TB-03Liquid to Gas Mass Flow Rate

L/G 2: 15.5 Continuous NRatio

TB-03 Stripper Temperature 169.7 of or above Continuous y

TB-03Hours of EtBr Production

1400 hours perMonthly y

(EtBr) consecutive 12 monthsTB-25

Glycol Coolant TemperatureMaximum Daily Ave

Daily N(NC-24) 40 of

15-18DPE Production By-Product 69,630 Ibs/week By-

Weekly NGeneration Product

16-01 Scrubber Media Flow Rate 6 gpm 3 hours NEstablished according to

16-01 Scrubber Media pH most recent satisfactory 3 hours Ntest

16-02 Scrubber Media Flow Rate 60gpm 3 hours NEstablished according to

16-02 Scrubber Media pH most recent satisfactory 3 hours Ntest

16-05 Scrubber Media Flow Rate 4gpm 3 hours N

Pennit #:762-AOP-RI3AFIN: 14-00028Page 21 of25

SN Recorded ItemLimit (as established in

Frequency* Reportpermit) (YIN)**

Established according to16-05 Scrubber Media pH most recent satisfactory 3 hours N

test16-06 Scrubber Media Flow Rate 6gpm 3 hours N

Established according to16-06 Scrubber Media pH most recent satisfactory 3 hours N

test16-13 Scrubber Media Flow Rate 4gpm 3 hours N16-14 Carbon Canister Replacement Once every year Annually N16-15 Carbon Canister Replacement Once every year Annually N16-22 Carbon Canister Replacement Once every year Annually N

-16-24 Hours of Operation 1,752 hours per year Per Event N16-24 Scrubber Media Flow Rate 6gpm 3 hours N16-25 Scrubber Media Flow Rate 25 gpm 3 hours N

Established according to16-25 Scrubber Media pH most recent satisfactory 3 hours N

test

16-31 Phthalic Anhydride Throughput18.25 MM Ib per

Monthly Yconsecutive 12 months

BH-OIEstablished according to

BH-02H2S Concentration in fuel most recent satisfactory 6 hours N

test for S02

BH-OIEstablished according to

BH-02Fuel Flow Rate most recent satisfactory 6 hours N

test21-01 Process Gas Velocity 19 ft/sec Continuous N21-01 Combustion Zone Temperature 1400 of Min. Continuous N

Number of Batches Produced

NC-22Scenario A Batches are

1,925 batches permultiplied by 1.54 Monthly Y

UnitScenario B Batches are

consecutive 12 months

multiplied by 1.00Minimum flow rate set

23-03 Scrubber Media Flow Ratepoint established

Continuous Naccording to most recent

satisfactory test.23-04 By-Product Drum Turnovers 96 turnovers per day Daily N

Minimum flow rate set

23-05 Scrubber Media Flow Ratepoint established

Continuous Naccording to most recent

satisfactory test.

Permit #:762-AOP-RI3AFIN: 14-00028Page 22 of25

SN Recorded ItemLimit (as established in

Frequency*Report

pennit) (YIN)**If less than 75 cycles per

year then monthlyMonthly

recordkeeping of number

23-14 Cleaning Cycles of cycles. yIfmore than 75 cycles per

year then complianceMonthly

demonstrated throughemission calculations.

NC-23 Primary Reactor Throughput for 1.725 Million Pounds ofMonthly Y

CMPU ABRMI ABRMI per year

DM-02 Combustion Zone Temperature 1200 OF or above 24 hours N

MS-02Amount of Solids Transferred to Based on Semi-Annual

Monthly NLandfill (MS-06) Emission Calculations

MS-03 Amount of Water Recovered82.0 million gallons per

Monthly Nyear (total)

MS-05 Coating and Adhesives Usage 100 gallons per year Monthly N

MS-06 All Matter Disposed24 million pounds per

Monthly Nconsecutive 12 months

MS-07 Gasoline Throughput200,000 gallons per

Monthly Nconsecutive 12 months

MS-08 Emergency Power Generation64,500 kW-hrs per

Monthly Yconsecutive 12 months

Emergency Power Maximum1000 kW (total) of which

MS-08Output

only 275.5 kW may be Monthly Ygenerated by gasoline

Water Flow RateMinimum Daily Ave.

24-011,500 Ib/hr

Daily NMaximum Daily Ave.

Chilled Water Temperature 60 OF

Duration of each event while0.60 tpy VOC calculated

24-01operating in alternate Scenario

based on mass balance andrecordkeeping

Gallons of Product 1,500,000 gallons per year1,2-Epoxybutane Usage 50,000 gallons per year

NC-24 24-hours per consecutive

Unit 12 months. Ifventing Monthly YVenting to SN-AD-26 exceeds 24 hours

calculate emissions foreach event.

Permit #:762-AOP-R13AFIN: 14-00028Page 24 of25

Compliance

Opacity JustificationMechanism (daily

SN% (NSPS limit, Dept. Guidance, etc)

observation, weekly,control equipment

operation, etc)15-02 5 Department Guidance Inspector's Observation15-12 5 Department Guidance Inspector's Observation15-16 5 Department Guidance Inspector's Observation15-18 5 Department Guidance Inspector's Observation16-01 5 Department Guidance Inspector's Observation16-02 5 Department Guidance Inspector's Observation16-06 5 Department Guidance Inspector's Observation16-07 5 Department Guidance Inspector's Observation16-08 5 Department Guidance Inspector's Observation16-10 5 Department Guidance Inspector's Observation16-11 5 Department Guidance Inspector's Observation16-12 5 Department Guidance Inspector's Observation16-18 5 Department Guidance Inspector's Observation16-19 5 Department Guidance Inspector's Observation16-20 5 Department Guidance Inspector's Observation16-21 5 Department Guidance Inspector's Observation16-22 5 Department Guidance Inspector's Observation16-25 5 Department Guidance Inspector's Observation16-26 5 Department Guidance Inspector's Observation16-27 5 Department Guidance Inspector's Observation16-29 5 Department Guidance Inspector's ObservationBH-Ol 5 Department Guidance Inspector's ObservationBH-02 5 Department Guidance Inspector's Observation21-01 5 Department Guidance Inspector's Observation23-02 5 Department Guidance Inspector's Observation23-06 5 Department Guidance Inspector's Observation

23-11A 5 Department Guidance Inspector's Observation23-11 B 5 Department Guidance Inspector's Observation23-12A 5 Department Guidance Inspector's Observation23-12B 5 Department Guidance Inspector's Observation23-13 5 Department Guidance Inspector's ObservationBT-ll 5 Department Guidance Inspector's ObservationBT-12 5 Department Guidance Inspector's ObservationBT-13 5 Department Guidance Inspector's ObservationBT-21 5 Department Guidance Inspector's Observation

Permit #:762-AOP-R13AFIN: 14-00028Page 23 of25

SN Recorded ItemLimit (as established in

Frequency*Report

permit) (YIN)**

DB-19T Hours ofOperation I, 080 hours totalPer Period of

NOperation

* Indicate frequency of recordmg reqUired for the Item (Continuously, hourly, daily, etc.)** Indicates whether the item needs to be included in reports

15. OPACITY

Compliance

Opacity JustificationMechanism (daily

SN observation, weekly,% (NSPS limit, Dept. Guidance, etc)

control equipmentoperation, etc)

BR-Ol 5 Department Guidance Inspector's ObservationBR-04 5 Department Guidance Inspector's ObservationBR-09 5 Department Guidance Inspector's ObservationBR-12 5 Department Guidance Inspector's ObservationSL-Ol 5 Department Guidance Inspector's ObservationSR-Ol 5 Department Guidance Inspector's ObservationCB-Ol 5 Department Guidance Inspector's ObservationCB-02 5 Department Guidance Inspector's ObservationCB-16 5 Department Guidance Inspector's ObservationCB-18 5 Department Guidance Inspector's ObservationDE-17 5 Department Guidance Inspector's ObservationDE-18 5 Department Guidance Inspector's ObservationDE-21 5 Department Guidance Inspector's ObservationDE-23 5 Department Guidance Inspector's ObservationAD-05 5 Department Guidance Inspector's ObservationAD-26 5 Department Guidance Inspector's ObservationAD-35 5 Department Guidance Inspector's ObservationDB-Ol 5 Department Guidance Inspector's ObservationDB-04 5 Department Guidance Inspector's ObservationDB-05 5 Department Guidance Inspector's ObservationDB-06 5 Department Guidance Inspector's ObservationDB-08 5 Department Guidance Inspector's ObservationDB-17 5 Department Guidance Inspector's ObservationDB-19 5 Department Guidance Inspector's Observation

DB-19T 5 Department Guidance Inspector's ObservationTB-04 5 Department Guidance Inspector's ObservationTB-08 5 Department Guidance Inspector's ObservationTB-14 5 Department Guidance Inspector's Observation

Permit #:762-AOP-R13AFIN: 14-00028Page 25 of25

Compliance

Opacity JustificationMechanism (daily

SN% (NSPS limit, Dept. Guidance, etc)

observation, weekly,control equipment

operation, etc)DM-02 5 Department Guidance Inspector's ObservationMS-08 20 §19.503 and Part 52, Subpart E Inspector's Observation

16. DELETED CONDITIONS:

No specific conditions were deleted for 762-AOP-12.

17. VOIDED, SUPERSEDED OR SUBSUMED PERMITS

List all active permits voided/superseded/subsumed by issuance of this permit for thisfacility.

Permit #

762-AOP-RI2

18. CONCURRENCE BY:

The following supervi or concurs with the permitting decision:

Fee Calculation for Major Source

$/ton factorPermit Type

Minor Modification Fee $Minimum Modification Fee $Renewal with Minor Modification $If Hold Active Pennit, Amt of Last Annual Air Pennit Invoice $

Total Permit Fee Chargeable Emissions (tpy)

Annual Chargeable Emission (tpy)Permit Fee $

4726.41000

Pollutant

Check ifChargeableEmission

OldPermit

NewPermit

Permit FeeChange in ChargeableEmissions Emissions

AnnualChargeableEmissions

PM

PM10

SOz

VOC

CO

NOx

Xylene + Ethyl Benzene

I, I Dichloroethane

1,2-Epoxybutane

Acetaldehyde

Benzene

Bromoform

Chloroethane

Chloroform

Chlorine (CI2)

Cl2 or Halogens

(C12 + Br2)

Dimethyl Formide

Ethylene Chloride

Ethyl Benzene

Ethylene Dibromide

Ethylene Dichloride

Ethylene Glycol

HCl

Hexane

Iso-Octane

Dichloromethane

Methanol

Methyl Bromide

Methyl Naphthalene

Phenol

Phthalic Anhydride

Toluene Diamine

Toluene

Xylene

Br2+HBr

Acetone

Ammonia (NH3)

Br2

BrCI

H202

H2S

H2S04

HBr

Pollutant )

Check ifChargeableEmission

OldPermit

NewPermit

Permit FeeChange in ChargeableEmissions Emissions

AnnualChargeableEmissions


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