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Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11, 2004
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Page 1: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Status of the Acumentrics SOFC Program

Dr. Norman BessetteSECA Annual Workshop

Boston, MA.May 11, 2004

Page 2: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 2

Acumentrics Corporation • ~ 75 Employees• Manufacturing since 1994•Based in Westwood, Mass.•~40,000 sq. ft facility• Critical disciplines in-house

Electrical EngineeringMechanical Engineering

Chemical EngineeringThermal ModelingCeramics ProcessingManufacturingSales & MarketingAutomationFinanceCourtesy of the NASA & EIT Consortium

Page 3: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 3

d

Industrial-UPS®Commercial

Rugged-UPS®Military

Acumentrics Battery based UPS500Watts - 20kWatts

Uninterruptible Power Supplies for Harsh

Environments

Features:• Sealed electronics• Able to withstand vibration• Unity power factor input• Wide input 80VAC - 265VAC• Isolated 120 / 240VAC output• Hot swap battery case• Parallelable to 20 kWatts

Page 4: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 4

Acumentrics CorporationAlliance Investments

Northeast Utilities

ChevronTexaco

Connecticut Innovations

NiSource

Sumitomo

General Dynamics

Morgan Stanley

Page 5: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 5

How Acumentrics Fuel Cells Work

Page 6: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 6

Q1 Q3 Q1 Q32000 2000 2001 2001

10 Watts25 Watts

200 Watts

700 Watts2000 – 2001Electrolyte supported

Tubular SOFC Systems

Acumentrics Fuel Cell EvolutionAcumentrics Fuel Cell Evolution

Copyright 2003 Acumentrics Corporation

Page 7: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 7

Stack Design Attributes

• Anode support tubes• Brazed seals• Stackable design• Welded electric connections• Low thermal mass• Withstands heat expansion

Acumentrics Fuel Cell EvolutionAcumentrics Fuel Cell EvolutionStackable Manifold design

High Power Anode Tubes

2002 – 2003Anode supportedTubular SOFC Systems

5 WattTubesQ2 2002

20 WattTubes

Q3 2003

Page 8: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 8

Acumentrics Tubular SOFC POX System Overview

Page 9: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 9

Acumentrics Tubular SOFC Steam Reformed System Overview

Page 10: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 10

Operates on line pressure natural gasFuel internally reformed by partial oxidationSystem Efficiency capable of mid 30% range

Acumentrics 2kW UPSAcumentrics 2kW UPSFull on-line UPS

For Cable/Broadband

Page 11: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 11

APU Core Module

• 45 minute start-up• Excellent cycle capability• Excellent load following • Low pressure gas feed• Direct in-cell reforming

Q4 - 2002

Acumentrics Fuel Cell EvolutionAcumentrics Fuel Cell Evolution2002

Anode supportedTubular SOFC Systems

5,000 Watt

Copyright 2003 Acumentrics Corporation

Page 12: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 12

5kW Auxiliary Power Unit

Page 13: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 13

5kW Stationary CHP Unit

Page 14: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

SECA Program

Page 15: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 15

Product Objectives

• Culminate in a 10kW modular stack capable of meeting a number of market requirements.

• Widen our fuel choices.• Build upon our knowledge of “ruggedized”

products for harsh environments.• Allow for modular build up to the 100kW class

size.• Allow for integration with military towable power

units in the 5-20kW size.

Page 16: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 16

Cell Production

• Tasks:– Improve Anode Conductivity– Accelerate Tube Firing– Reduce Silver Content

• Accomplishments to date:– Bisque firing capable of reduction from 48 to

12 hours– Silver Content reduced by over 50%

Page 17: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 17

Cell Production ProcessMixing Extrude Tube Dry Tube Cut to Size

Bisque Fire tube Slurry Deposit Electrolyte Sinter Electrolyte

Cathode Deposition Cathode Firing Apply Cathode CC

Finished Cell

Page 18: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 18

Anode Tube Extrusion

Page 19: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 19

Anode Tube Bisque Firing

Page 20: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 20

Electrolyte Deposition

Page 21: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 21

Cathode Coating Operation

Page 22: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 22

Brazing Apparatus

Page 23: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 23

Brazing Apparatus operating

Page 24: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 24

Comparison of poorly brazed and well-brazed Joint

Page 25: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 25

Low Cost Braze-Life Graph

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

1.1

0 200 400 600 800 1000 1200 1400 1600 1800 2000

Etime, hr

Pote

ntia

l, V

or C

urre

nt D

ensi

ty, A

/cm

2

Page 26: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 26

Brazing

New Braze Materials have been validated reducing cost from over $1400/kW to less than $1/kW.

New Braze Cap manufacturing process has reduced cost from ~$6/cell to ~$0.50/cell

Page 27: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 27

SECA Cell Testers

Page 28: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 28

Two 7mm diameter cells on lifetest

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

1.1

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000Elapsed Time, hr

Cel

l Pot

entia

l, V

0

100

200

300

400

500

600

700

800

900

Rec

orde

d fu

rnac

e te

mpe

ratu

re, C

120202-01 P3, V 121902-01 2L, VTemperature, C

Page 29: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 29

Present 15mm History

0.000

0.100

0.200

0.300

0.400

0.500

0.600

0.700

0.800

0.900

1.000

0 168 336 504 672 840 1008

Elapsed Time of Test (hours)

Volta

ge (V

olts

)

Page 30: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 30

Cell Power Trend

0

10

20

30

40

50

60

0 10 20 30 40 50 60 70 80 90 100 110 120

Cell Current, A

Cel

l Pow

er, W

Electrolyte Supported Cells- Through December 20017mm Anode Supported Tubes - January 2002

15mm (22 cm length) Anode Supported Tubes- Oct 2002

15mm (33 cm length) Anode Supported Tubes- December 2002

15mm (45cm length) Anode Supported Tubes-January 2003

22mm anode supported tube- Projected December 2004

Page 31: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 31

Cell Technology

• Phase I will continue our evolution from 5W –15W/tube to 25W/tube

• Phase II/III will further that work to 50W/tube

• The first 6 mo. of SECA funding has helped us advance 33% toward the first goal.

Page 32: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 32

• Excellent start-up• Excellent cycle capability• Excellent load following • No fuel pumps.• Direct reformation

Anode supportedTubular SOFC Systems

Acumentrics Generator DesignAcumentrics Generator Design

Page 33: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 33

Generator Cost Reductions

• Early SECA work on manifolds has shown the potential for cost reduction from $690/kW to $80/kW with further advancement to <$50/kW expected.

• Work on recuperators has shown a path to <$25/kW – final designs are being validated.

Page 34: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 34

Bended Tube Recuperator

Page 35: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 35

Ceramic Recuperator

Page 36: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 36

Control Electronics Evolution

• Programmable Logic Controllers, PLCs– Size 24” X 15”, $6000 per System

• Printed Circuit Board, PCB, Controller– Size 11” X 7.5”, $400 per System

Page 37: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 37

System Pictures

• PLC System • Control PCB

Page 38: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 38

Control System Wiring

• Discrete wiring harness • 150 through bulkhead connections• Centralized control board• System wiring cost $500

– Limited opportunities for cost reduction• The wiring costs more than the electronics!

Page 39: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 39

Distributed vs. Centralized Control

• Several small intelligent I/O boards.• CAN bus communication.• Eliminates substantial wiring and cost.• Modular, incremental and applicable to a

wide variety of systems.• Redundancy and fault tolerance is easier

and more cost effective to achieve.

Page 40: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 40

Fuel Cell Interface Converter, FC-IC

• Interfaces fuel cell to energy storage system• Controls fuel cell output current• Utilizes efficient automotive MOSFETs• Interleaved buck – boost topology• 6kW building block• 30 - 90 V input, 30 - 60V output, 200 amps

Page 41: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 41

SECA Power Conversion Tasks• Complete design, fabrication and test of a

98% efficient 48VDC power electronics front end.

Page 42: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 42

Low Voltage Inverter Development

• The FC-IC topology can be configured into an inverter.

• An interleaved topology and high frequency MOSFETs greatly reduce output filter requirements and cost.

• Preliminary efficiency measurements are in the 96-97% range.

Page 43: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 43

FC-IC Based Inverter Development Platform

Page 44: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 44

SECA Inverter EfficiencyFuel Cell Power Inverter Efficiency

80.00%

82.00%

84.00%

86.00%

88.00%

90.00%

92.00%

94.00%

96.00%

98.00%

100.00%

0 2000 4000 6000

Power Output (Watts)

Effic

ienc

y

Overall

Transformer

Inverter

Page 45: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 45

Power System Projections

• Cost will be $100-$150/kW with the appropriate volumes.

• Efficiency will be 92-95%• Device efficiency and packaging advances

in the automotive industry will drive the cost towards the $50/kW goal.

Page 46: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 46

Conclusions• Been in the fuel cell business for 4 years.• Completed over 1 year operation on previous generation

cell technology.• We have shipped 14 alpha & Beta units for field testing.• Demonstrated the ability to operate complete systems on

lie-pressure natural gas and commercial propane.• Developed a scalable low-cost manufacturing process.• Enhanced cell power by 15x in 3 years & are proceeding

toward an additional 2-3x• Developed the hardware & firmware for a low cost

controller.• Prototyped a low cost, high efficiency inverter capable of

achieving SECA cost & efficiency targets.

Page 47: Status of the Acumentrics SOFC Program Library/Events/2004/seca/Acumentrics... · Status of the Acumentrics SOFC Program Dr. Norman Bessette SECA Annual Workshop Boston, MA. May 11,

Copyright 2004 Acumentrics Corporation 47

Acknowledgement

Department of Energy-National Energy Technology Laboratory

Don Collins, Project Manager


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