Date post: | 12-Jan-2016 |
Category: |
Documents |
Upload: | poppy-french |
View: | 223 times |
Download: | 3 times |
Stereochemistry
Stereochemistry
•Any chemistry which involves orientation in space
Symmetry
•Referring to anything that can be divided on some plane into identical parts
Symmetry
•In molecules, planes of symmetry can be determined along any bond axis
Symmetric Compounds
•Compounds with at least one plane of symmetry
Name the Following
C C C
C-C-C-C-C-C-C
C-C
Asymmetric Compounds
•Compounds with no plane of symmetry
Symmetric Compounds
•The mirror images of symmetric compounds are identical
Symmetric Compounds• All completely
symmetric compounds are non-
polar
Asymmetric Compounds
•The mirror images of asymmetric compounds are not identical. They are optical isomers
Asymmetric Compounds
•Asymmetric compounds can be
polar if the bonds are polar
Polarity of Hydrocarbons
•Hydrocarbons are non-polar
Optical Isomers
•Mirror images of asymmetric compounds are optical isomers or stereoisomers
Stereoisomerism of C
•A carbon center must be bound to 4 different
things to be asymmetric
Stereoisomerism of C
•Any carbon center bound to 3 or less
things has at least one plane of symmetry
Stereoisomerism of C
•Use modeling
Stereoisomerism of Carbon Chains
•The constituents on two adjacent carbons spend
more time in the staggered position
Stereoisomerism of Carbon Chains
•Use modeling to show aligned & staggered
positions
Diffusion
•Movement down an energy gradient
Thermochemistry•Compounds will
eventually move to the lowest possible energy state (the most stable
state)
Thermochemistry of Organic Compounds•Stability is sometimes determined by how the
compound interferes with its surroundings
Thermochemistry of Organic Compounds•To increase stability,
organic compounds tend to curl up
Thermochemistry of Organic Compounds
•Organic compounds ring structures are more stable than their corresponding straight chain structures
Drill: Name:
Draw an optical isomer of:
H3C-CH2
H3C-C-CH2-CH2-CH3
H
Draw & Name at least 5 isomers of
C6H14