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Study of Dissolved Gas Analysis under Electrical and Thermal Stresses for Natural Esters used in Power Transformers A thesis submitted to The University of Manchester for the degree of MPhil in the Faculty of Engineering and Physical Sciences Sitao Li School of Electrical and Electronic Engineering
Transcript

Study of Dissolved Gas Analysis under Electrical

and Thermal Stresses for Natural Esters used in

Power Transformers

A thesis submitted to The University of Manchester for the degree of MPhil in the Faculty of

Engineering and Physical Sciences

Sitao Li

School of Electrical and Electronic Engineering

2

3

Contents

Contents ..................................................................................................................................... 3

List of Figures ........................................................................................................................... 7

List of Tables ........................................................................................................................... 11

Abstract ................................................................................................................................... 13

Declaration .............................................................................................................................. 15

Copyright Statement .............................................................................................................. 17

Acknowledgement .................................................................................................................. 19

Chapter 1 Introduction .......................................................................................................... 21

1.1 Background Study ............................................................................................. 21

1.2 Research Objectives .......................................................................................... 22

1.3 Outline of Thesis ................................................................................................ 22

Chapter 2 Literature Review of Dissolved Gas Analysis on Natural Ester ...................... 25

2.1 Introduction of Transformer Liquid ............................................................... 25

2.1.1 Mineral Oil – Nytro Gemini X .................................................................. 25

2.1.2 Natural Ester – FR3 ................................................................................... 26

2.1.3 Sample Processing Methodology ............................................................... 27

2.2 Transformer Faults ........................................................................................... 28

2.2.1 Partial Discharge Fault .............................................................................. 28

2.2.2 Electrical Sparking Fault ........................................................................... 29

2.2.3 Thermal Fault ............................................................................................. 29

2.3 Dissolved Gas Analysis ...................................................................................... 29

2.3.1 Gas Formation ............................................................................................ 31

2.3.2 Headspace Method ..................................................................................... 33

2.3.3 Gas Chromatograph................................................................................... 34

2.3.4 Duval Triangle Interpretation Method ..................................................... 34

2.3.5 Online DGA and Laboratory DGA Comparison ..................................... 35

2.4 Serveron Online Transformer Monitor TM8.................................................. 36

2.4.1 Working Principle ...................................................................................... 36

2.4.2 Dual-Column GC Analysis ........................................................................ 37

4

2.4.3 PC Data Analysis ......................................................................................... 38

2.5 Previous Work Review ...................................................................................... 39

2.5.1 Electrical Sparking ..................................................................................... 39

2.5.2 Electrical PD Test ........................................................................................ 40

2.5.3 Thermal Test ................................................................................................ 43

2.6 Tests Comparison and Summary ..................................................................... 48

Chapter 3 Experimental Study on DGA under Sparking Faults ....................................... 51

3.1 Introduction ........................................................................................................ 51

3.2 Experiment Setup .............................................................................................. 51

3.2.1 Test Circuit Design ...................................................................................... 51

3.2.2 Test Vessel Design ........................................................................................ 53

3.3 Test Procedure .................................................................................................... 56

3.3.1 Drain Oil out of System .............................................................................. 57

3.3.2 Clean Test System and Fill Processed Oil into the System ...................... 58

3.3.3 Measuring Background DGA level............................................................ 59

3.3.4 Generating Sparking Faults ....................................................................... 59

3.4 Data Measurement and Analysis ...................................................................... 60

3.4.1 GIG and GIT ............................................................................................... 60

3.4.2 Dissolved Gas Generation Calculation ..................................................... 61

3.4.3 Sparking Energy Calculation .................................................................... 63

3.5 Test Condition and Observation ....................................................................... 69

3.6 Test Result and Analysis .................................................................................... 70

3.6.1 Gas Generation of Sparking Faults ........................................................... 70

3.6.2 Energy of Sparking Faults ......................................................................... 71

3.6.3 Gas generation rate (per J) ........................................................................ 72

3.6.4 Absolute Gas generation rate (per J) ........................................................ 74

3.6.5 Gemini X and FR3 Comparison ................................................................ 74

3.6.6 Duval Triangle Analysis .............................................................................. 75

3.6.7 Laboratory DGA and Online Monitor Comparison ................................ 77

3.7 Summary ............................................................................................................. 78

Chapter 4 Experimental Study on DGA under PD Faults .................................................. 79

5

4.1 Introduction ....................................................................................................... 79

4.2 Experiment Setup .............................................................................................. 79

4.3 Test Procedure ................................................................................................... 80

4.3.1 Calibrate the PD Detector ......................................................................... 81

4.3.2 Measuring Background PD Noise ............................................................. 82

4.3.3 Generating PD Faults ................................................................................. 82

4.4 Data Measurement and Process Method ......................................................... 83

4.4.1 Total Gas Generation Calculation ............................................................ 83

4.4.2 PD Energy Calculation .............................................................................. 84

4.5 Test Condition and Observation ...................................................................... 88

4.6 Test Result and Analysis ................................................................................... 89

4.6.1 PD Fault Gas Generation .......................................................................... 89

4.6.2 PD Fault Energy ......................................................................................... 91

4.6.3 Gas generation rate (per J) ........................................................................ 93

4.6.4 Absolute Gas generation rate (per J) ........................................................ 95

4.6.5 Duval Triangle Analysis ............................................................................. 96

4.6.6 Laboratory DGA and Online Monitor Comparison ............................... 98

4.7 Summary ............................................................................................................ 99

Chapter 5 Experimental Study on DGA under Thermal Fault ....................................... 101

5.1 Introduction ..................................................................................................... 101

5.2 Experiment Setup ............................................................................................ 101

5.2.1 Test Circuit Design ................................................................................... 101

5.2.2 Test Vessel Design ..................................................................................... 102

5.3 Test Procedure ................................................................................................. 103

5.3.1 Generate Thermal Faults ......................................................................... 104

5.4 Measurement Methods.................................................................................... 104

5.4.1 Temperature Measurement Method ....................................................... 104

5.4.2 Heating & Cooling Method ..................................................................... 105

5.5 Test Conditions and Observations ................................................................. 107

5.6 Test Result and Analysis ................................................................................. 107

5.6.1 Thermal Fault Gas Generation ............................................................... 108

6

5.6.2 Gas Generation Rate Comparison under Different Temperatures ...... 109

5.6.3 Duval Triangle Analysis ............................................................................ 111

5.6.4 Laboratory DGA and Online Monitor Comparison .............................. 113

5.7 Summary ........................................................................................................... 113

Chapter 6 Conclusions and Future Work .......................................................................... 115

6.1 Conclusions ....................................................................................................... 115

6.1.1 Research Areas .......................................................................................... 115

6.1.2 Main Findings ........................................................................................... 116

6.2 Future Work ..................................................................................................... 117

Reference ............................................................................................................................... 119

Appendix I. Matlab Code Used In the Thesis .................................................................... 123

I.1 Sparking Energy Calculation ..................................................................................... 123

I.1.1 High Frequency Energy Calculation .......................................................... 123

I.1.2 Low Frequency Energy Calculation ........................................................... 125

I.2 PD Energy Calculation ............................................................................................... 128

Appendix II. The Results Used in the Thesis ...................................................................... 131

Words count: 34975

7

List of Figures

Figure 2.1 Basic Hydrocarbon Structures in Mineral Oil [20] ................................. 25

Figure 2. 2 Molecular Structure of FR3 [23] .............................................................. 27

Figure 2. 3 Diagram of Indicator Gases and Faulty Type and Severity in

Transformers Filled By Mineral Oil [38] ............................................................ 32

Figure 2. 4 Headspace Sampling Method [39] ............................................................ 33

Figure 2. 5 Gas Chromatograph Concept Diagram [41] ........................................... 34

Figure 2. 6 Duval Triangle Diagrams .......................................................................... 35

Figure 2. 7 TM8 Online Transformer Monitor .......................................................... 36

Figure 2. 8 The Working Principle Diagram of TM8 ................................................ 37

Figure 2. 9 Dual- Column GC Analysis Diagram ....................................................... 38

Figure 2. 10 Example of Analysis Diagram of TM8 Viewer [17] .............................. 38

Figure 2. 11 Photo of Lighting Impulse Sparking Test Vessel [12] .......................... 39

Figure 2. 12 Comparision of Fault Gas-in-Oil Generation between Lyra X and FR3

[12] .......................................................................................................................... 40

Figure 2. 13 Electrical PD Test Diagram [10] ............................................................ 40

Figure 2. 14 Test Vessel Diagram of PD Test [10] ...................................................... 41

Figure 2. 15 Thermal Test 1(Heating Element) [11] .................................................. 44

Figure 2. 16 Thermal Test 2 (Heating Element) [12] ................................................. 45

Figure 2. 17 Thermal Test 3 ......................................................................................... 47

Figure 2. 18 Gas-in-Oil Generations in Different Oils under Various

Temperatures ......................................................................................................... 48

Figure 3.1 Schematic View of Electrical Sparking Test Circuit ............................... 52

Figure 3.2 Test Vessel Design Diagram ....................................................................... 54

Figure 3.3 Photo of Sealing Test 1 ............................................................................... 55

Figure 3.4 Pressure Versus. Time of Sealing Test 1 ................................................... 56

Figure 3.5 Partial Coefficients for FR3 and Gemini X .............................................. 61

Figure 3.6 Example of High Frequency Component of Sparking Current ............. 65

Figure 3.7 Example of Power Frequency Component of Sparking Current ........... 66

8

Figure 3.8 Example Filtered Waveform of Power Frequency Sparking Current ... 66

Figure 3.9 Different Types of Sparking ....................................................................... 67

Figure 3.10 Total Gas Generation in Gemini X /FR3 Tests ....................................... 70

Figure 3.11 GIT Generation rate (per) J in Gemini X and FR3 Sparking Tests ..... 73

Figure 3.12 GIT Generation rate (per J) Comparison between Gemini X and FR3

................................................................................................................................. 75

Figure 3.13 Duval Triangle Evaluation (GIO) of Sparking Fault in Gemini X and

FR3 .......................................................................................................................... 77

Figure 4.1 Schematic Diagram of Electrical PD Test Circuit .................................... 80

Figure 4.2 PD Calibration Panel of PD Measuring System Software ....................... 81

Figure 4.3 PD Noise in FR3 under 60 kV .................................................................... 82

Figure 4.4 Example of PD Test DGA Peak Value ....................................................... 84

Figure 4.5 PD Noise Filter ............................................................................................. 85

Figure 4.6 Gas Generation in Gemini X and FR3 PD Test ........................................ 90

Figure 4.7 PD Patterns of Gemini X (60 Minutes PD signals from the 3000 pC Test)

and FR3 (1 Minute PD signals from 3000 pC Test 1) ......................................... 91

Figure 4.8 GIT Generation rate (per J) Comparison between 2000 pC Tests of

Gemini X and FR3 ................................................................................................. 93

Figure 4.9 GIT Generation rate (per J) Comparison between 3000 pC Tests of

Gemini X and FR3 ................................................................................................. 94

Figure 4.10 GIT gas Generation rate (per J) Comparison between 4000 pC Tests of

Gemini X and FR3 ................................................................................................. 95

Figure 4.11 Duval Triangle Evaluations for Gemini X and FR3 PD Tests .............. 98

Figure 5.1 CIrcuit Diagram of Hot-Spot Thermal Test Circuit .................... 102

Figure 5.2 Test Vessel Design ...................................................................................... 103

Figure 5.3 Thermocouples and Heating Element Configuration ............................ 105

Figure 5.4 Heating and Cooling Procedure ............................................................... 106

Figure 5.5 GIT Generation Rate of Fault Gases in Gemini X and FR3 ................. 109

Figure 5.6 GIT Generation Rate Comparisons between Gemini X and FR3 ........ 110

9

Figure 5.7 Duval Triangle Evaluation of Gemini X and FR3 Thermal Fault ....... 112

10

11

List of Tables

Table 2.1 Key Properties of Nytro Gemini X [18] ...................................................... 26

Table 2.2 Key Properties of FR3 [24] .......................................................................... 27

Table 2.3 Water Content and Relative Humidity of Processed Liquid Samples at

Room Temperature [25] ....................................................................................... 28

Table 2.4 Bond Dissociation Energy [33] .................................................................... 31

Table 2.5 GIO DGA Results under PD Fault of Various Amplitudes [10] .............. 42

Table 2.6 GIO DGA Results under PD Fault of Various Energy [10] ..................... 43

Table 2.7 GIO DGA Result of Thermal Test 1 (Heating Element)........................... 45

Table 2.8 GIO DGA Results in both Liquids .............................................................. 46

Table 2.9 Tests Features Comparison ......................................................................... 49

Table 3.1 Example GIO Concentration in Gemini X ................................................. 62

Table 3.3 Sparking Types ............................................................................................. 67

Table 3.4 Example of Group Sparking Energy Calculation ..................................... 68

Table 3.6 Sparking Energy for Each Test Group inside Gemini X/ FR3 ................ 71

Table 3.7 Absolute GIT Generation Rate (μt/J) of Sparking Tests .......................... 74

Table 3.8 GIO Generation Rate (ppm/J) .................................................................... 76

Table 3.9 Comparison of GIO Results between TM8 and Laboratory Analysis .... 78

Table 4.1 Example of PD Test Energy Calculation .................................................... 88

Table 4.2 List of PD Tests ............................................................................................. 89

Table 4.3 PD Energy and Distribution for each Test inside Gemini X/ FR3 ........... 92

Table 4.4 Absolute GIT Generation Rate (μa/J) ........................................................ 96

Table 4.5 GIO Generation Rate (ppm/J) .................................................................... 97

Table 4.6 Comparison of GIO DGA Results between TM8 and Laboratory .......... 98

Table 5.1 Thermal Test Conditions and Observations ............................................ 107

Table 5.2 GIO Generation Rate (ppm/J) .................................................................. 111

12

Table 5.3 Comparison of GIO DGA Results between TM8 and Laboratory

Analysis ................................................................................................................. 113

13

Abstract Mineral oil has been traditionally used as an insulating liquid in power transformers for over a

century, and Dissolved Gas Analysis (DGA) technique has been used for decades as one of the most useful

diagnosis tools to assess the conditions of mineral oil filled transformers. However, due to increasing

awareness of environmental protection and fire safety, there is a trend of replacing mineral oil with

environmentally friendly natural esters; DGA data interpretation method should then be studied, if necessary

revised, in order to be applicable for natural ester filled transformers.

This thesis covers experimental studies on performances of a mineral oil (Gemini X) and a natural

ester (FR3) in terms of fault gas generation. Laboratory simulated faults include electrical sparks, electrical

partial discharges (PD) and high temperature thermal hotspot types.

The electrical sparking fault was generated by using a sharp needle electrode with a tip radius of

curvature of 5 micrometers, a 2.57 L sealed test vessel was designed and built with the TM8 online DGA

monitoring system, and two CTs were used to measure the high frequency and power frequency components

of the sparking current, respectively. The electrical PD fault was simulated using the same test system but

under lower voltages, and a traditional PD detector was used to record the characteristics of PD signals,

including the repetition rate and amplitude. The hotspot thermal fault was generated by heating up a copper

element locally in a 2.73 L sealed test vessel, and three thermocouples were used to measure the temperatures

of the heating element.

Furthermore, the dissolved fault gases in oil were measured by both the online DGA monitoring

system and the oil analysis laboratory, and the DGA results were also compared.

The main findings of this thesis are outlined below:

FR3 generates similar amounts of fault gases to Gemini X under sparking faults. Under the same

sparking energy (per J), FR3 generates fault gases 25% higher than Gemini X.

FR3 generates higher amounts of fault gases than Gemini X under PD faults. Under the same PD

amplitude, the gas generation in FR3 is much higher than that in Gemini X due to a higher PD repetition

rate in FR3.

FR3 generates less amount of fault gases than Gemini X under high temperature thermal faults (>300

ºC). This indicates that FR3 is more thermally stable than Gemini X.

DGA results obtained by the TM8 online monitor are comparable to those from laboratory analysis,

within a deviation of 30% under all the faults.

14

15

Declaration

I declare that no part of the work referred to in the thesis has been submitted in support of an

application for another degree or qualification of this or any other university or other institutes

of learning.

16

17

Copyright Statement I. The author of this thesis (including any appendices and/or schedules to this thesis) owns

certain copyright or related rights in it (the “Copyright”) and he has given The University of

Manchester certain rights to use such Copyright, including for administrative purposes.

II. Copies of this thesis, either in full or in extracts and whether in hard or electronic copy,

may be made only in accordance with the Copyright, Designs and Patents Act 1988 (as

amended) and regulations issued under it or, where appropriate, in accordance with

licensing agreements which the University has from time to time. This page must form part of

any such copies made.

III. The ownership of certain Copyright, patents, designs, trade marks and other

intellectual property (the “Intellectual Property”) and any reproductions of copyright

works in the thesis, for example graphs and tables (“Reproductions”), which may be

described in this thesis, may not be owned by the author and may be owned by third parties.

Such Intellectual Property and Reproductions cannot and must not be made available for

use without the prior written permission of the owner(s) of the relevant Intellectual Property

and/or Reproductions.

IV. Further information on the conditions under which disclosure, publication and

commercialisation of this thesis, the Copyright and any Intellectual Property and/or

Reproductions described in it may take place is available in the University IP Policy (see

http://www.campus.manchester.ac.uk/medialibrary/policies/intellectual-property.pdf), in any

relevant Thesis restriction declarations deposited in the University Library, The University

Library’s regulations (see http://www.manchester.ac.uk/library/aboutus/regulations) and in

The University’s policy on Presentation of Theses.

18

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Acknowledgement Firstly I would like to express my sincerely gratitude to my supervisor Professor Zhondong

Wang for her support and guidance during my MPhil research study at the University of

Manchester. My MPhil research project would not succeed without her hard work and patient

guidance.

I am also truly grateful to all the sponsoring companies, i,e. Serveron and TJH2B who provided

continuous support to this project at the University of Manchester. In particular, John Hinshaw

from Severon and John Noakhes from TJ2HB are extremity helpful. I would also like to thank

Cooper Power System for providing natural ester over the years.

To all my colleagues in the transformer research group , I appreciate for your company

and thank you for offering me an enjoyable working environment. Special thanks to Dr.

Xin Wang who taught me so much on test cell design, experimental setup and thesis writing

through all the project and Dr. Xiao Yi who offered many patient and wise suggestions.

Last but not least, I would like to take this opportunity to thank my parents for their continuous

support and understanding, to my girlfriend Miss Jinping Huang for her support and selfless

love. They encouraged me to go through all the hard work all the time.

20

21

Chapter 1 Introduction

1.1 Background Study

Mineral oil has been used as a traditional insulating liquid for power transformers for over a

century. However, in face of the increasing awareness of environmental protection recently,

applying environmental friendly transformer liquids such as natural esters or synthetic esters

in transformers of distribution or transmission level is getting more and more popular [1, 2, 3].

Up to now, ester based transformer liquids have been widely used in distribution transformers

and there are more and more development work in the aim of used by esters in power

transformers [4, 5].

DGA, short for dissolved gas analysis, is one of the most useful diagnosis tools for incipient

fault indication of oil-filled transformers [6]. When either thermal or electrical faults are

occurred, transformer oil will decompose and recombine into many kinds of fault gases. In the

past several decades, experience of DGA based fault interpretation of mineral oil-filled

transformers has been accumulated after a wide range of lab research and on-site operation

practices. Many standards were established for assessing conditions of mineral oil-filled

transformers, such as IEC 60599 and IEEE C57.104 [7, 8]. Among all kinds of DGA

interpretation methods listed in the above guide, the most comprehensive one is Duval triangle

which was established by Michal Duval offering graphical interpretation [9].

Due to the increased use of environmental friendly transformer liquids, mineral oil based

diagnosis methods need to be revised for the use of fault indication for nature ester-filled

transformers. Researchers have already carried out some experiments on studying the gas

generation characteristics of nature ester FR3 under thermal or electrical transformer faults

[10-15]. Based on the results of large amount of experiments, the Duval triangle interpretation

method was revised for FR3 in 2008 [16].

Traditionally, laboratory DGA technique, which required taking oil samples from transformers

periodically and then sending them to the analytical laboratory, becomes mature for fault

indication. Recently, affordable online transformer monitoring products, which are able to

provide results based on up to hourly oil sampling, are installed at power level transformers for

predicting faults and avoiding failures [17]. However, due to the lack of experience, there are

22

still many concerns about the measurement accuracies of online transformer monitoring

equipment. In this aspect, this thesis will compare DGA results from the analytical laboratory

and the online transformer monitor TM8 to verify if the monitor’s results are reliable or not.

1.2 Research Objectives

This MPhil thesis aims at comparing the fault gas generations, under electrical and thermal

fault of conventional mineral oil Gemini X and new alternative natural ester FR3 under thermal

and electrical faults. Furthermore, it is hoped that the test results could contribute to the revision

of the DGA interpretation methods for mineral oil when used for vegetable oil based

transformer liquids.

The objectives of this MPhil thesis are:

Study the gas generation performances of FR3 under hotspot thermal faults, electrical

sparking faults and partial discharge (PD) faults, using Gemini X as a benchmark.

Compare the DGA results obtained from online and laboratory methods for the same fault.

Evaluate the simulated fault using the original and revised Duval triangle methods,

providing suggestions for natural ester DGA interpretation method.

1.3 Outline of Thesis

The chapters presented in this thesis are listed below:

Chapter 1 Introduction

This chapter includes a brief description of the research background, the objectives of the

project and the outline of the thesis.

Chapter 2 Literature Review of Dissolved Gas Analysis on Natural Ester

This chapter gives a brief description of transformer liquids used in the experiments, Gemini

X as a mineral oil and FR3 as a natural ester, the dissolved gas analysis (DGA) technique, the

23

development of TM8 online DGA monitor, the three main types of transformer fault and a

recent experimental study of natural ester DGA.

Chapter 3 Experimental Study on DGA under Sparking Fault

This chapter shows the method to generate the sparking fault and also the method to measure

the sparking current. By using a needle to plate electrode configuration, a test cell is designed.

It has achieved a good sealing state and complete oil circulation. The sealing state of the

electrical test cell is verified by a pressure gauge based sealing test. A proper test procedure is

carefully followed to use the test cell – TM8 close loop measuring system in order to obtain

reliable test results. The experiment in this chapter shows the gas generation characteristics of

Gemini X and FR3 under the sparking faults. The simulated faults for both liquids are also

evaluated by using the original and revised Duval triangle. Furthermore, oil samples are

collected after the electrical sparking test and sent out for laboratory DGA analysis.

Chapter 4 Experimental Study on DGA under PD Fault

This chapter describes the method to generate the PD fault using similar configuration to

previous sparking test under lower voltage/ electrical fields and also the method to calculate

the PD energy. The same electrical test cell as Chapter 3 is used and the proper test procedure

is carefully followed to reduce gas leakage. The experiments in this chapter study the gas

generation of Gemini X and FR3 under the controlled PD faults up to 2 days.

Chapter 5 Experimental Study on DGA under Thermal Fault

This chapter shows the method used to simulate the thermal fault inside the transformer via the

“W” shaped copper heating element, the method to measure the temperature of the heating

element is also given. A thermal test cell is designed to achieve a good sealing state, complete

oil circulation and oil expansion protection. A proper test procedure is made for using the test

cell – TM8 measureming system. The experiments in this chapter study the gas generations of

Gemini X and FR3 under the simulated thermal faults. The simulated faults inside both liquids

are evaluated by using the original and revised Duval triangle. Oil samples are collected after

the thermal tests and sent out for laboratory DGA analysis.

24

Chapter 6 Conclusions and Further Work

This chapter summarizes the main conclusions of the thesis and also gives some suggestions

for future studies.

25

Chapter 2 Literature Review of Dissolved Gas Analysis on Natural Ester

2.1 Introduction of Transformer Liquid

This MPhil thesis explores the differences of fault gas generation characteristics between

conventional mineral oil which is widely used in large power transformers, and natural ester

which is expected to be an alternative for mineral oil. From now on, Gemini X will stand for

the mineral oil and FR3 will represent natural ester.

2.1.1 Mineral Oil – Nytro Gemini X

Nytro Gemini X, a type of inhibited insulating transformer oil, which is produced by Nynas

Oil Company to replace the previous uninhibited Nytro 10GBN, consists of saturated

hydrocarbon molecules, like paraffins and naphthenes and unsaturated aromatics and

polyaromates as shown in Figure 2.1.

Figure 2.1 Basic Hydrocarbon Structures in Mineral Oil [20]

The main advantages of Gemini X are good heat transfer, excellent oxidation stability, good

low temperature properties and high dielectrically strength [18]. Gemini X is chemically stable

26

with a high anti-oxidation ability. The dielectric strength of Gemini X is higher than 70 kV

(measurement based on IEC 60156 with a 2.5 mm gap distance) when the liquid is preserved.

However, once it has been contaminated by water or particles, the dielectric strength will

reduce accordingly [19]. The major drawbacks of Gemini X are fire hazards and less

biodegradability. The water saturation level of Gemini X is 55 Parts per Million (ppm) at room

temperature. Table 2.1 shows the key properties of Gemini X.

Table 2.1 Key Properties of Nytro Gemini X [18]

Property Unit Test Method Typical Data

Physical

Density,20 ºC kg/dm3 ISO12185 0.882

Viscosity,40 ºC mm2/s ISO3104 8.7

Flash point ºC ISO2719 144

Pour point ºC ISO3016 -60

Chemical

Acidity mg KOH/g IEC62021 <0.01

Aromatic content % IEC60590 3

Water content mg/Kg IEC60814 <20

Electrical

Breakdown voltage kV IEC60156

before treatment 40-60

after treatment >70

2.1.2 Natural Ester – FR3

FR3, a type of natural ester based transformer oil, which has been used for decades in over

450,000 transformers. [21] It is manufactured by Cargill Company from edible vegetable oils,

mainly consists of triglycerides, a special structure made of double carbon bonds or even triple

carbon bonds [10]. The molecular structure is shown in Figure 2.2.

27

Figure 2.2 Molecular Structure of FR3 [23]

FR3 is highly biodegradable but can also oxidize easily due to the structure of triglycerides.

The dielectric strength of FR3 is above 56 kV (measured by ASTM D1816 using a 2 mm gap

distance). FR3 is now mainly applied in distribution transformers in North and South America

[22]. The water saturation level of FR3 is 1100 ppm at room temperature which is 20 times

higher than that of Gemini X. Table 2.2 shows the key properties of FR3.

Table 2.2 Key Properties of FR3 [24]

Property Unit Test Method Typical Data

Physical

Density,20 ºC kg/dm3 ASTM D1298 0.92

Viscosity,40 ºC mm2/s ASTM D445 32

Flash point ºC ASTM D92 330

Pour point ºC ASTM D97 -20

Chemical

Acidity mg KOH/g ASTM D974 0.02

Water content mg/Kg ASTM D1533 30

Electrical

Breakdown voltage kV ASTM D1816 56 (2 mm)

2.1.3 Sample Processing Methodology

Although the quality of transformer liquid is controlled during manufacture, its quality could

deteriorate in transportation or long-term storage mainly due to contamination. To maximally

limit the influence of dissolved gas and water content on the test, all oil samples used in this

thesis were well dehydrated and degassed. The liquid is put into the vacuum oven for 48 hours

28

under 5 mbar inner pressure and 85 ºC, a further 24 hours cooling down is also required

afterwards. The qualities of both Gemini X and FR3 are trusted to be the same. The water

content was measured according to the Karl Fisher titration analysis, using Metrohm 684

coulometer and 832 Termoprep ovens [25]. The dissolved gas is measured by the TM8 online

transformer monitor. The result of relative humidity (water content versus saturation level) and

dissolved gas for the processed liquid sample are below 5% and very close to 0 ppm

respectively [10]. Table 2.3 shows the water content and relative humidity of processed

samples.

Table 2.3 Water Content and Relative Humidity of Processed Liquid Samples at Room

Temperature [25]

2.2 Transformer Faults

The IEC standard 60599 [7] classifies the DGA detectable transformer faults into 2 categories:

the electrical fault and the thermal fault. These two main categories can be further sorted into

6 types of transformer fault, according to the magnitudes of the fault energy: the electrical fault:

partial discharge (PD ), D1 (discharge of low energy) and D2 (discharge of high energy); the

thermal fault: T1 (Thermal fault of low temperature range, T < 300 ºC), T2 (Thermal fault of

medium temperature range, 300 ºC < T < 700 ºC) and T3 (Thermal fault of high temperature

range, T >700 ºC) [6, 7].

2.2.1 Partial Discharge Fault

Partial discharge stands for the kind of discharge that only partially bridges the insulation gap

between conductors/electrodes. The discharge may happen totally inside the transformer

insulation or adjacent to the conductors. The PD around an electrode in gases is called corona,

29

while the others such as the one which occurs in a transformer liquid is commonly named as

streamer [7, 8].

Partial discharges, known as one of the most influencing reasons for insulator degradation,

could lead to electric breakdown when they accumulate and propagate fully between two

conductors. To avoid costly transformer failures, it is critically important to monitor the PD

activities for early detection of the incipient of transformer fault. Dissolved gas analysis (DGA)

is now the most widely used method to determine the condition of transformer insulation liquid

as it is a non-destructive technique [26-30].

2.2.2 Electrical Sparking Fault

After decades of study, it is now generally accepted that the breakdown occurs after the

streamers fully propagate through the gap of the electrodes. When the energy of dielectric

breakdown is limited, it will act as small arcs which are named as sparking faults [7]. In

comparison with PD faults, sparking fault generate much more amount of fault gases under the

same fault time and could be critical for transformer operation.

2.2.3 Thermal Fault

Sometimes bad connections when exclusive currents keep circulating in the conductor parts of

the transformer, or leakage flux will lead to localized overheating. Thermal fault will change

the transformer liquid performance by increasing the liquid temperature. In comparison with

electrical type of transformer fault, thermal faults generate much more amount of fault gases

under the same fault duration. Different types of fault gases will be formed under different

temperature range; therefore, the fault gases could be used to diagnose the transformer fault

temperature.

2.3 Dissolved Gas Analysis

30

Dissolved gas analysis (DGA) is known as one of the most widely used diagnosis tools of oil-

filled transformers, it is noted as the non-interrupt test method which has already functioned

for decades. Furthermore, DGA is also famous for the reliable fault forecast tool that is

developed based on a vast amount of faulty oil-filled equipment in service and laboratory

experiment results worldwide [7, 8].

In general, DGA can be divided into 4 steps: collect oil sample, extract dissolved gas, gas

chromatograph measurement and data interpretation. The oil sample collection is based on the

international standard IEC 60567 which gives the recommended procedure for taking an oil

sample from oil filled equipment. The oil sample collection is considered to be the first primary

factor of a good DGA result; therefore, the recommended procedure needs to be followed

carefully.

The extraction of dissolved gas from the oil sample is the second step. The traditional vacuum

method or the alternative vacuum pump method such as headspace and stripper methods are

also available in IEC60567 [31]. The headspace method is used in the TM8 and will be

explained in Section 2.3.2.

The third step is the gas chromatograph (GC) which could separate and analyze different gas

components. Detail of the GC will be described in Section 2.3.3.

The last step will use the DGA results to interpret the transformer conditions. The international

standards IEC 60599 and IEEE C57.104 provide many diagnosis tools for DGA results, such

as the key gas method, the Roger ratio method and the Duval triangle method. Among all the

diagnosis methods, the Duval triangle method seems to be the most popular one in fault

prediction [32]. However, because the interpretation methods are all developed based on the

known transformer fault data, it may not be correct for some other cases, such as application

of new ester liquids. The range and typical values of those interpretation methods might need

to be changed as the database is updated. The Duval triangle is used as the interpretation

method in this thesis of which the detail will be shown in Section 2.3.4.

31

2.3.1 Gas Formation

The transformer liquid consists of different hydrocarbon atomic groups like CH3, CH2 and CH.

The molecular bond which is used to link the molecular group together, such as C-H and C-C

bonds, will be broken when electrical or thermal energy is applied. Newly formed unstable

radical or ionic fragments will recombine swiftly into gas molecules like hydrogen (H-H),

methane (CH3-H), ethane (CH3-CH3), ethylene (CH2=CH2), acetylene (CH≡CH), CO (C≡O)

and CO2 (O=C=O). Different energy levels are required to break different kind of molecular

bonds, as a result, different types and amounts of fault gases will be formed according to the

severity and category of the transformer fault. The energy which is mandatory to crack the

typical molecular bond inside the transformer oil is shown in Table 2.4.

Table 2.4 Bond Dissociation Energy [33]

Bond C-C (CH3-

CH3)

C-H

(average)

C=C

(H2C=CH2)

C≡C

(HC≡CH)

Dissociation

energy

(kJ/mol)

356 410 632 837

Arcing, low energy sparking, PD and overheating are some of the common faults that could

happen in the oil-filled transformers. Once any of these faults occurs, the insulation liquid will

be decomposed and then a certain amount of combustible and non-combustible faulty gases

will be formed. Generally speaking, there are 7 types of fault gases that could be generated

after the transformer faults; they are hydrogen (H2), methane (CH4), ethane (C2H6), ethylene

(C2H4), acetylene (C2H2), carbon dioxide (CO2) and carbon monoxide (CO) [7, 8, 34].

Due to the different amounts of energy required to break different kinds of molecular bonds,

the type and amount of fault gas generation vary and depend upon the magnitude of the fault

energy. As a result, there exists a relationship between the fault type and fault gas generation

which can be used to interpret the DGA results.

Figure 2.3 shows the diagram of the indicator gases related to each fault type.

32

Figure 2.3 Diagram of Indicator Gases and Faulty Type and Severity in Transformers Filled By Mineral

Oil [38]

For example, C2H2 and C2H4 which have C≡C bond and C=C bond require a higher energy to

be formed than CH4 and C2H6. In other words, the generation of C2H2 and C2H4 stands for the

significant faults for oil-filled transformers like an electrical arcing and some hotspot of very

high temperatures. As a result, these two types of fault gases have higher weighing factors in

the industry scoring system of transformer operation condition assessment [35-37]. Even a

small amount of C2H2 would raise concerns of utility companies who own and operate the

transformers.

33

2.3.2 Headspace Method

Headspace method is a calculation method used to compute gas-in-total or gas-in-oil

concentration using gas-in-gas (GIG) concentration. The case shown in Figure 2.4 is an oil-

filled vial with VL volume of oil and left a VG volume of headspace.

Figure 2.4 Headspace Sampling Method [39]

Some of the dissolved gas will spread to the headspace from the oil until the equilibrium

condition of a certain temperature, agitation and pressure is reached. Afterwards, the headspace

gas will be passed to the gas chromatograph (GC) columns. Then the obtained gas

concentration in headspace, GIG, will be used to calculate gas-in-oil (GIO) or gas-in-total (GIT)

according to Henry’s law.

GIT = GIG × (K (T, gas) + β) × P/P0 × T0/T (2.1)

Equation (2.1) shows the calculation method to convert GIG value into gas-in-total [34]. The

parameters in the Equation are described below:

GIT, represented as GIT is the concentration of total gas generation including the gas in both

oil and headspace.

GIG, represented as GIG is the concentration of gas that acquired from GC system directly,

which stands for the gas concentration in headspace.

34

K, partition coefficient, is a ratio of concentrations of gas compound between the two solutions,

such as transformer liquid and air.

β, phase ratio, is a ratio of gas volume over liquid volume.

P and T are the atmospheric pressure and temperature when the oil sample was measured.

Po and To are the standard pressure and temperature. (Po is the 14.7 psi while To is 273.2 K)

2.3.3 Gas Chromatograph

Gas chromatograph is a type of chromatograph that is widely used in chemical analysis in order

to separate and measure evaporable gas substances [40]. Figure 2.5 shows the diagram of gas

chromatograph concept. As shown in Figure 2.5, the mobile phase flow, such as fault gases, is

carried through the stationary phase which is used to retain the gas components. In the

stationary phase, the weak retain substance will move faster while the strong retain substance

will move more slowly. Consequently, different gas components will pass the stationary phase

and reach the gas detector in different time ranges. Finally, the gas detector will give out the

individual amounts of each gas according to the analysis time range [41].

Figure 2.5 Gas Chromatograph Concept Diagram [41]

2.3.4 Duval Triangle Interpretation Method

The Duval triangle graphic method was established firstly by Michel Duval in the 1960s. It is

widely used all around the world for its comprehensive user-friendly graphic interface. The

Duval triangle method is updated several times as the database range gets wider. Recently, the

original Duval triangle method was developed into 8 triangles including the ones for non-

35

mineral oil filled transformers, load tap changers (LTCs) of the oil type and the low temperature

fault. The triangle coordinates value can be computed by the DGA results in ppm as below:

% C2H2 = 100 * C2H2 / (C2H2 + C2H4 + CH4);

% C2H4 = 100 * C2H4 / (C2H2 + C2H4 + CH4);

% CH4 = 100 * CH4 / (C2H2 + C2H4 + CH4);

In this thesis, the original mineral oil Duval triangle and the revised FR3 Duval triangle will

be used to interpret the simulated transformer faults [16].

(a) Traditional Duval Triangle (b) Revised FR3 Duval Triangle

Figure 2.6 Duval Triangle Diagrams

2.3.5 Online DGA and Laboratory DGA Comparison

The online transformer monitor that can ensure a fully sealed system and also provide timely

DGA curves is gaining popularity all around the world. Online DGA measurement equipment

shortens the infrequent sampling period to an hourly measurement which shows the dynamic

behavior of gas generation during the transformer operation. Online DGA monitors are now

available to provide up to 8 types of gases, when we consider the previous online DGA device

developed in early days such as HYDRAN, can only tell the equivalent H2 value in ppm for a

36

fault. With the help of software, those monitors will be able to calculate and display some of

the interpretation results like the Duval triangle [42].

2.4 Serveron Online Transformer Monitor TM8

The Online DGA monitor used in this thesis is Serveron TM8 (shown in Figure 2.7). It is able

to provide useful and timely information for oil-filled transformer condition assessment. With

the help of the built-in sensors and special chromatographic columns, TM8 can provide up to

hourly DGA sampling covering all 8 types of transformer fault gases with ±5% accuracy [17].

Figure 2.7 TM8 Online Transformer Monitor

2.4.1 Working Principle

The working principle diagram of TM8 is shown in Figure 2.8. In general, the whole TM8

measurement system can be divided into 4 parts: the oil loop part, the gas loop part, the gas

chromatograph (GC) part and the PC analysis part. The oil loop part includes all the oil flow

pointers (blue arrows); The gas loop is made up of all the gas flow indicators (green arrows);

The GC part is the analysis section for all gases and the PC analysis part receives the raw data

from GC part (black arrows) for the graphically presentation of dissolved gas concentration.

37

Transformer oilTransformer

gas

Liquid

blockage

membrane

Gas flow

Selective

columns

Dual-column

GC analysis

Extractor

Oil flow

Carrier gases

Helium

flow

PC based

TM8

system

Data flow

Test cell/

transformer

Figure 2.8 The Working Principle Diagram of TM8

In the closed loop system, transformer oil keeps circulating between the test vessel/ transformer

and the oil chamber of the TM8 extractor. The gases dissolved inside the transformer oil will

go through the liquid blockage membrane into the gas chamber of the TM8 extractor. The

carrier gas helium flow (red arrows) will carry the dissolved gases into the extractor gas

chamber and will go to the selective columns. These will separate all 8 kinds of gases and let

them reach the GC analysis part at different times. Lastly, in the GC analysis part, the fault

gases are analyzed by the sequence as shown in next Section.

2.4.2 Dual-Column GC Analysis

Figure 2.9 shows an example of the Dual-column GC analysis diagram of TM8. TM8 actually

consists of two GC selective columns: column A and column B. Column A keeps those gases

with large molecules and passes them to the GC analyzer in a fixed sequence first; afterwards,

Column B passes the gases with small molecules like Hydrogen and methane to the GC

analyzer one by one. Both selective columns will let special types of fault gases pass in a fixed

response time range. The GC analyzer measures the area of each gas peak and gives out the

result according to the individual response time of each type of fault gases.

38

Figure 2.9 Dual- Column GC Analysis Diagram

2.4.3 PC Data Analysis

The raw result from the GC analyzer will be further computed based on the built-in partition

coefficient K, the measured oil temperature and the equilibrium pressure in the extractor. The

result plots out timely DGA curves (Figure 2.10 (a)) and can also provide an automatic

diagnosis like the Duval triangle interpretation (Figure 2.10 (b)).

(a) Timely DGA Curves (b) Duval Triangle

Figure 2.10 Example of Analysis Diagram of TM8 Viewer [17]

39

2.5 Previous Work Review

Many researchers made great efforts to understand the FR3 performance under electrical and

thermal fault conditions such as [10-15]. Their research is studied and described below.

2.5.1 Electrical Sparking

Figure 2.11 shows the lighting impulse sparking experiment carried out by Mark. Jovalekic to

investigate the fault gas generation under the lighting impulse sparking fault in mineral oil,

Lyra X and natural ester FR3.

Figure 2.11 Photo of Lighting Impulse Sparking Test Vessel [12]

A 4-stage impulse generator is used as the voltage supply. The test configuration is with a 4

mm gap distance and a 134 kV impulse voltage which results in a 4096 J fault energy. Most of

the fault energy is converted into heat and less than 1% of it is consumed to generate fault

gases.

The test result after 90 lighting impulse sparking is shown in Figure 2.12. It can be seen from

this figure that, C2H2 and H2 are the key indicator for the impulse sparking fault inside both

oils, as much as 50.0% and 41.8% in Lyra X and 46.7% and 29.7% in FR3. The total gas

generation of Lyra X is twice that of FR3. The CO is only significant in FR3 which makes up

to 7.6% of total gas generation.

40

Figure 2.12 Comparision of Fault GIO Generation between Lyra X and FR3 [12]

2.5.2 Electrical PD Test

Figure 2.13 shows the electrical PD test that was designed by X. Wang [10]. As we can see

from the circuit diagram, the 50 Hz power transformer is used to provide up to 70 kV test

voltage. A 500 pF discharge free capacitor is connected in parallel with the test vessel. The

measuring impedance of the LDS-6 PD detector is connected in series with the capacitor. The

PD detector is calibrated and used to measure the PD signal with less than 5 pC noise (70 kV

test voltage).

Figure 2.13 Electrical PD Test Diagram [10]

0

500

1000

1500

2000

2500

3000

3500

4000

4500

CO2 C2H4 C2H2 C2H6 H2 CH4 CO TDCG

Lyra X 219 214 2100 0 1775 155 0 4244

FR3 182 229 953 0 605 99 155 2041

μL/L

41

The test vessel diagram is shown in Figure 2.14. It can be seen from the diagram that the 100

ml glass vial sealed by an aluminum crimp cap is fully filled with test oil. The needle electrode

is penetrated into the rubber sealing whose tip radius of curvature is 6-7 μm from front view

and 2-3 μm from lateral view.

Figure 2.14 Test Vessel Diagram of PD Test [10]

The assemble of the test vessel and the needle electrode is immersed inside an insulating oil

filled container. A copper base of 100 mm diameter is placed under the bottom of the test vessel

as a plate electrode. The gap distance between the needle and plate electrode is kept as 50 mm

for all tests. A new needle electrode will be replaced after each test. The oil sample is

immediately sealed by the Acrylic-based sealing compound from RS Ltd [43] and is then sent

to the TJH2B analytical laboratory for DGA measurement.

The test results of FR3 and Gemini X are compared by the PD amplitude and PD energy. As

can be seen from Table 2.5, FR3 generates around twice the amounts of total combustible gases

(TCG) of Gemini X under large PD amplitudes (when the PD amplitudes is over 500 pC). The

fault gas generation increases as the PD amplitude rises.

42

Table 2.5 GIO DGA Results under PD Fault of Various Amplitudes [10]

Oil Test PD amplitude (pC) DGA(ppm)

C2H4 C2H2 C2H6 H2 CH4 CO TCG

Gemini X

G.Test1 200 0.2 0.2 0.4 12.4 0.9 21.7 35.8

G.Test2 300 0.2 0.1 0.2 7 0.5 12.4 20.4

G.Test3 500 0.2 0.3 0.3 62.4 0.4 13.9 77.5

G.Test4 1000 1.5 3.5 0.9 163 2.9 13.6 185.4

FR3

F.Test1 200 0.2 0 44.7 29.9 1.2 20.1 96.1

F.Test2 300 2.7 5 83.4 63.7 3.9 36.2 194.9

F.Test3 500 5.5 11.5 46 69.1 5.8 30 167.9

F.Test4 1000 9.1 22.4 63.4 140 11.4 49.9 296.2

Note: Those unexpected results listed in bold and italic style may be caused by leakage.

The difference is mainly contributed by C2H6 which makes up to 46.5% (200 pC), 42.8% (300

pC), 80.5% (500 pC), and 21.4% (1000 pC) of the total gas generation for FR3. H2 is the most

significant hydrocarbon gases except C2H6. H2 is making up to 34.6% (200 pC), 34.3% (300

pC), 27.4% (500 pC), and 87.9% (1000 pC) of the total gas generation in Gemini X tests while

that is only 31.1% (200 pC), 32.7% (300 pC), 41.2% (500 pC), and 47.3% (1000 pC) in FR3.

The concentration of CO in FR3 is around twice of that in Gemini X. C2H2 starts to generate

under the 1000 pC PD fault inside Gemini X while the trace of it could be found inside FR3

under 300 pC PD fault.

Another 8 groups of tests of both the FR3 and Gemini X under the 500 pC PD fault and different

time durations are carried out; the test results are calculated into μl/J for comparison as shown

in Table 2.6.

43

Table 2.6 GIO DGA Results under PD Fault of Various Energy [10]

Oil Test Times

(mins)

PD

ener

gy

(mJ)

DGA(ppm)

μl/J C2H4 C2H2 C2H6 H2 CH4 CO TCG

Gemi

ni X

1 15 7.7 0.5 0.4 0.2 31.3 1.7 10.9 45.0 584.4

2 30 8.1 0.2 0.3 0.3 62.4 0.4 13.9 77.5 956.7

3 45 9.2 0.3 0.5 0.2 70.9 0.9 12.5 85.3 927.2

4 60 15.7 0.6 0.7 0.3 110.0 1.8 40.5 153.9 980.3

FR3

1 15 148.2 0.4 0.6 12.7 46.7 0.7 10.1 71.2 48.0

2 30 161.4 1.5 3.1 18.2 88.4 1.9 17.9 131.0 81.2

3 45 486.6 3.3 7.0 28.0 74.7 3.9 29.7 146.6 30.1

4 60 1020 6.0 13.6 63.5 138.0 6.6 39.6 267.3 26.2

Note: The unexpected result in bold and italic style may be caused by leakage.

It can be seen from Table 2.6 that the PD fault in Gemini X generates around half of total fault

gases than FR3 under the same test conditions. However, when the PD energy is taken into

consideration, the amount of gas generation rate (per J) in Gemini X is 10 times higher than

that in FR3. The reason is that PD repetition rate in FR3 is much higher than that Gemini X.

For the same type of liquid, the gas generation is increased as the voltage applying time

becomes longer. However, the amount of gas generation rate (per J) in FR3 test is not linear

for different voltage applying times because the needle electrode changed as the test carried on.

The energy calculation method used in this test is also applied in this thesis. The energy is

calculated by using the sum of PD discharge magnitude times the instantaneous voltage when

each PD discharge occurs. As stated before, there is some leakage during sample transportation;

the new design therefore uses a sealed online DGA system to avoid such an influence. The oil

volume is also increased from 100 ml to 2.57 L in this thesis in order to obtain a more stable

result even when accident occurred.

2.5.3 Thermal Test

2.5.3.1 Thermal Test 1

Imad designed his heating element thermal test as shown in Figure 2.15 [11].

44

Figure 2.15 Thermal Test 1(Heating Element) [11]

In this design, the copper heating element which is made of 7 strands of copper wires (each

strand is 7cm long and 0.5mm in diameter) is used to simulate the hotspot thermal fault. A

single phase, 50 Hz loading transformer with 240/3.5V and 45-90/3000A rating is chosen as

the current supply of the heating element. The thermocouple sensor was twisted into the copper

strands for temperature measurement. The Perspex test vessel was kept open during the tests

for safety reasons; as a result, the generated gas will partially leak out. The transformer liquid

is heated up to 700°C and the total heating duration is up to 50 minutes. Huge bubbles are

generated in the mineral oil during the test while fewer fumes are formed in the FR3 test [11].

Table 2.7 shows the DGA result of heating element thermal test. It could be noticed that all

GIO fault gas concentration in FR3 is much higher than that of the mineral oil. However, the

dissolved gas cannot represent the total generated gas because the test vessel was kept open

45

during the test. The test is then redesigned so that it can be carried out inside a sealed closed

loop system in this thesis.

Table 2.7 GIO DGA Result of Thermal Test 1 (Heating Element)

Oil Times

(mins)

DGA(ppm/min)

C2H4 C2H2 C2H6 H2 CH4 CO TCG

Gemini X 35 0.1 0.0 0.3 1.2 4.7 13.8 20.1

FR3 50 20.9 0.0 16.9 1.7 6.7 14.4 60.7

2.5.3.2 Thermal Test 2

Mark designed a localized heating element test using a special material which linearly changed

the resistor in a wide range of temperatures up to 550°C [12]. Figure 2.16 shows Mark’s test

design. As shown in the figure below, the special material Resistherm is used as the heating

element and put inside the oil-filled sealed test vessel. A funnel is set upside down to collect

the generated fault gases; the fault gases will finally go into the top syringe and held there.

Another syringe is used to release the pressure that is caused by the oil expansion during the

test. The voltage across the heating element and the current that passes through it are recorded

for temperature calculation.

Figure 2.16 Thermal Test 2 (Heating Element) [12]

46

The heating element is maintained at 300°C to 600°C for 1 to 6 hours. Higher temperatures

cannot be achieved due to the melting of the Resistherm. The DGA results for all tests in both

liquids are shown below in Table 2.8.

Table 2.8 GIO DGA Results in both Liquids

(a) GIO DGA Results in FR3

Temperature

(°C) Duration(h)

DGA(μl/J)

CO2 C2H4 C2H2 C2H6 H2 CH4 CO TCG

300 6 1353 27 0 489 92 33 932 1573

400 6 2973 209 0 934 278 214 4219 5854

500 2 3698 631 0 1005 472 351 3095 5554

600 1 3923 1061 0 1307 382 453 5148 8351

(b) GIO DGA Results in Lyra X

Temperature

(°C) Duration(h)

DGA(μl/J)

CO2 C2H4 C2H2 C2H6 H2 CH4 CO TCG

300 1.5 57 8 0 2 11 20 510 551

400 1 169 198 38 7 70 149 687 1149

It can be seen from the table that the total generated fault gases in Lyra X is around 5 times

higher than that in FR3 under 400°C thermal stress. CO and CO2 are the main generated fault

gases under the thermal fault for both oils. C2H4, CH4 and C2H6 are also significant in FR3

tests while the C2H4 and CH4 are significant in Lyra X. C2H2 was already generated in Lyra

X 400°C thermal test which indicates that the fault temperature in some areas is already much

higher than the calculated average temperature. The temperature distribution of the heating

element is therefore not even.

2.5.3.3 Thermal Test 3

Dave designed the following experiment to heat up different transformer liquids under various

temperatures. The test equipment shown in the Figure 2.17 includes:

47

1. An expansion chamber which is maintained at atmospheric pressure. An insolation valve is

installed between the connection of equipment 1 and 3.

2. A pressure gauge.

3. A gas chamber that can be sealed by the isolation valve.

4. A liquid reservoir.

5. A pump that circulates liquid between 4 and 6. .

6. An oven.

Figure 2.17 Thermal Test 3

The natural ester (the soybean oil, the high oleic sunflower oil) and the mineral oil are all heated

for 8 hours. The test results are shown below in Figure 2.18. It can be seen from Figure 2.18

there is a 50°C temperature difference for main fault gases yielding between the soybean oil

and the high oleic sunflower oil; a 50°C difference between the high oleic sunflower oil and

the mineral oil and a 100°C difference between the soybean oil and the mineral oil.

48

(a) Gas Generation in Soybean Oil under Various Temperatures

(b) Gas Generation in Oleic Sunflower Oil under various Temperatures

(c) Gas Generation in Mineral Oil under Various Temperatures

Figure 2.18 GIO Generations in Different Oils under Various Temperatures [14]

2.6 Tests Comparison and Summary

Table 2.9 summaries main features of the tests reviewed in this chapter. Laboratory DGA

analysis method and GIO computation method were applied for all the tests.

49

Table 2.9 Tests Features Comparison

Test

type

Test

No.

Features

On-line or

Lab DGA

GIT

or

GIO

Sea

ling Energy

calculation

Long

term

test

Temperature

measurement

Heating

element or

oven

Sparki

ng test

Test

1 Lab DGA GIO Yes No N/A N/A N/A

PD

test

Test

1 Lab DGA GIO Yes Yes No N/A N/A

Therm

al test

Test

1 Lab DGA GIO No No N/A

Thermal

couple

Heating

element

Test

2 Lab DGA GIO Yes No N/A Resisthermal

Heating

element

Test

3 Lab DGA GIO Yes No N/A N/A Oven

In comparison, On-line DGA which can ensure a fully sealed system and provide hourly DGA

sample for more reliable fault indication is getting more and more popular all around the world.

On the other hand, GIT fault gas concentration reflects real fault gas generation which is better

than GIO, since the GIG compound is also taken into consideration in GIT calculation. To

achieve better test result, the GIO calculation and on-line DGA method are used in this thesis.

Thermal test 1 is an open test in case the oil expansion will damage the test vessel. However,

the generated gas leaked out during the test, making the result unreliable. The test system in

this thesis is designed as fully sealed for reliable result.

Resisthermal is used in thermal test 2 for temperature measurement. This measurement method

obtained the average temperature by using voltage and current going through the heating

element. The thermal couple which could be used to measure the hot spot temperature is used

to get the hot spot temperature in this thesis.

Thermal oven which can offer relatively balanced heating up process for whole oil is used in

thermal test 3. Thermal fault in real transformers occurs more like a hot spot instead of oven;

therefore, the heating element are chosen as the heating method in this thesis.

50

51

Chapter 3 Experimental Study on DGA under Sparking Faults

3.1 Introduction

With the purpose of applying the standard diagnosis method for traditional mineral oil to

alternative natural esters, the gas performances of a mineral oil, Gemini X, and a natural ester,

FR3, are studied in this chapter under electrical sparking faults. A specially designed test vessel

with a good sealing capability was tested and used in this study, and the needle to plate

electrode configuration was used to produce electrical sparking faults. It was found that the

amount of fault gases is closely related with the fault energy; therefore the gas generation rate

(per J) was considered as a good parameter to compare the gas performance between FR3 and

Gemini X. The TM8 DGA monitor was used to measure the DGA results. Additionally, some

oil samples were also sent to TJH2B for laboratory analysis in order to compare with online

DGA methods. The results indicated that the two methods agree with each other with an

acceptable deviation.

3.2 Experiment Setup

3.2.1 Test Circuit Design

As the circuit design shown in Figure 3.1, a variac controller offering variable turns ratio was

used to control the voltage output of the 240 V/80 kV transformer (the voltage source in the

test).

52

R1

R2

Test vessel

Voltage

divider

Ratio

10000:1

TM8

Over Current

Protection

relay

5 A 240V/80kV

Power

frequency

CTOutput

V/A=1/100

Output

V/A =

1/10

CT

500 pF

600 kΩ Water resistor

CT

High frequency CT

PC based TM8

control software

The cage

100 MHz

oscilloscope 1

100 MHz

oscilloscope 2

Oil

inlet

Oil

outlet

Variac

0-240 V

Figure 3.1 Schematic View of Electrical Sparking Test Circuit

Due to the limitation of the voltage divider, the maximum voltage used in the test was 70 kV.

The over current protection relay was set to 5 A to trigger the sparking faults. A 600 kΩ water

resistor was connected between the HV output and the test vessel to reduce the sparking current

in case any damage is made to the gas tight system. The cylinder shaped gas tight test vessel,

which was made of transparent Perspex contains a needle - plate electrode system. The needle

electrode was connected to the high voltage output and the bottom plate electrode was

connected to earth. A TM8 on-line DGA monitor was connected to the test vessel to measure

the fault gases generated in the sparking tests.

During the test, the HV voltage was measured by the 10 k: 1 voltage divider which was

connected in parallel with the test vessel. Two current transformers were used to measure the

sparking current, in which a power frequency current transformer (CHAUVIN ARNOUX MN

53

60 current clamp, bandwidth from 40 Hz to 40 kHz) with a 1/100 output ratio was used to

measure the power frequency component of the sparking current, and another high frequency

current transformer (Stangenes pulse current transformer, model No. 0.5-0.1, Square Pulse

Rise Time = 20 ns) with a 1/10 ratio was used to measure the high frequency component of the

sparking current. The results of the two current transformers were combined together to get the

total result of current.

3.2.2 Test Vessel Design

To generate a proper amount of fault gases, the gap distance between the needle-to-plate

electrodes is chosen as 35 mm. The plate electrode was made of brass and has a diameter of 20

mm. The needle electrode was a medical needle with a tip radius of curvature in the range from

6-7 μm from front view.

3.2.2.1 Main Design Advantages

To obtain a reliable result, the test vessel should be kept in a good sealing state and a complete

oil circulation should be maintained in the test. As the photo of the test vessel that is shown in

Figure 3.2, two design factors were tried in this thesis to keep the test working in sealed

condition, they are: inner cap and o-rings. The inner cap is a cap that placed right close to the

inner wall of the test cell which can block the oil and gas from leaking out. To keep the fault

gases staying in the circulation system, the test vessel is sealed by using rubber O ring (gasket)

at each joint. The main body of the test vessel is sealed with 8 groups of screws and an inner

cap system, providing two layers of protections from leakage. The screws can press the O ring

tightly and the inner cap can also stop the oil and gas from leaking. Once sealed, the main body

of the test vessel should never be unraveled to maintain a well-sealing state.

54

(a) Design Diagram

(b) Photo of Electrical Test Cell

Figure 3.2 Test Vessel Design Diagram

In order to obtain a complete oil circulation, several methods were applied as follows. Firstly,

the headspace was completely removed before test. Secondly, the 20 degree slope at the vessel

top is designed to remove the headspace and collect the fault gases. Thirdly, the oil inlet pipe

55

and outlet pipe are installed at the top/bottom of the test vessel to make sure that all oil is in

the circulation loop. Finally, the tube between the inlet pipe of TM8 and the syringe adaptor

was as short as possible to reduce the “dead volume”, since oil in this area is barely circulated

and it represents “dead volume”.

The syringe of 50 ml connecting to the top of the test cell is also used to remove the gas bubbles

during test setup and also balance the inner system pressure with outside atmosphere pressure

during test operation.

3.2.2.2 Sealing Tests

Two sealing tests are carried out to check whether the sealing state is qualified for both the

electrical sparking and electrical partial discharge (PD) tests.

Sealing test 1 is designed to check how much pressure difference between the inner and outside

of the test vessel is reduced in a period of 23 hours. The setup of sealing test 1 is shown in

Figure 3.3.

Figure 3.3 Photo of Sealing Test 1

The empty test vessel is sealed and connected to the pressure gauge with a maximum 100 mbar

measurement range. A syringe pressurized the test vessel until the pressure difference between

the inside and the outside of the test vessel reached 100 mbar. Then, the syringe was removed

56

and the test vessel was kept for a further 23 hours. Figure 3.4 plots the pressure difference with

time (the pressure data is not recorded at night).

Figure 3.4 Pressure Versus. Time of Sealing Test 1

Sealing test 1 showed that the test vessel was in a good sealing state, and the pressure difference

between the inside and the outside of the test vessel fell from 98 mbar to 89 mbar after 23 hours.

This means only 10% gas leaked out within 23 hours and equivalent 0.4% in the first hour.

Sealing test 2 aimed at finding out the relationship between pressure, gas volume and sparking

numbers. A test circuit was built up according to Figure 3.1 (the TM8 was not connected in the

circuit) with the same electrode configuration. The test vessel was fully filled with FR3. After

50 sparking tests, a 51.5 mbar pressure difference was detected by the pressure gauge and the

pressure difference is maintained the same half hour after the test.

Sealing test 1 and 2 indicate the test vessel can be used for the sparking test which only has 15

sparking tests for each case, and for the PD test which could last for 2 days. Only 20% will

leak during the test maximally.

3.3 Test Procedure

With the purpose to compare the gas performances of two transformer liquids under electrical

sparking faults, the test procedure described below was strictly followed.

0

20

40

60

80

100

0 5 10 15 20 25

Sealing test

Pressure(mbar)

Pressure(mbar)

Time(h)

57

Process transformer oil as described in Section 2.1.3.

Drain oil out of the system.

Clean test system, fill processed oil into the system (eliminate the headspace).

Measure background gases.

Generate sparking faults.

Use syringe to push fault gases to be dissolved back into the oil circulation, and measure

the amount of fault gases.

Process and analyze test data.

3.3.1 Drain Oil out of System

After fresh oil is well processed, it needs to be filled into the TM8 – test vessel system. To do

this, transformer oil from the previous test should be drained out first by TM8 which can pump

oil forwards and backwards for several times (normally 2 times). Some of the oil trapped in

TM8 would not be drained out easily if only forward pumping is applied; accordingly, pumping

oil in both directions is helpful to remove the residual oil efficiently. Detail of the steps is

described below.

First of all, the oil inlet pipe of TM8 needs to be disconnected and put into a waste oil barrel.

Secondly, the “xtr suspend” command needs to be used to suspend the extractor of TM8. The

extractor of TM8 needs to be suspended before the pump starts to rotate backwards because

the TM8 does not allow oil pump to rotate backwards when the extractor is in operation

otherwise the TM8 extractor would be damaged. Thirdly, the “pump –f oil rev 35” command

will be used to pump the oil backwards at the maximum speed (875 rpm) for 5 minutes. The

reason that the oil inlet pipe of TM8 needs to be disconnected instead of the oil outlet pipe is

because the oil outlet pipe is at the bottom of the test vessel. This kind of setup allows all the

oil inside test vessel to be drained out.

Afterwards, the oil pump must be pumped forwards in order to get rid of some oil residue.

Firstly, the “pump oil off” command needs to be used to stop the oil pump; then the oil outlet

58

pipe of TM8 needs to be disconnected and put into the waste oil barrel while the oil inlet pipe

needs to be taken out from the waste oil barrel and then put on to an empty oil beaker. Next,

the “pump oil 35” command needs to be used, making the oil pump rotate forwards at the

maximum pumping speed. Wait around 10 minutes and repeat the pump oil backward and

forward procedures again to make sure most of the oil is drained out from TM8. According to

the test experiment, the previous dissolved gas residue can be reduced to less than 10% after

this procedure.

Sometimes the needle electrode needs to be changed before the processed oil is filled into the

system. In the sparking test, the needle electrode needs to be changed only when the oil is

changed from Gemini X to FR3. To change the needle electrode, the top brass cap nut needs

to be screwed out first and then the needle fixer has to be released to remove the medical needle.

A new medical needle is put into the needle fixer. The needle is carefully measured by ruler,

making sure the gap distance is 35 mm.

3.3.2 Clean Test System and Fill Processed Oil into the System

Processed oil can be filled into the system after the previous oil residue was cleaned. The oil

outlet pipe of TM8 needs to be connected back to the bottom of the test vessel while the inlet

pipe of TM8 needs to be put into the processed oil test vessel. The oil outlet valve of the test

vessel needs to be set in a closed state, the oil inlet valve should be kept in an open state and

the syringe valve of the test vessel needs to be set as open, letting the air go out. The “pump

oil 35” command needs to be used to make TM8 pump the oil from the oil beaker to the test

vessel, oil will then go through the TM8 extractor and be filled into the test vessel from bottom

to top. The “pump oil off” command is used to stop the oil pump when the oil is close to the

top of the test vessel. The oil inlet pipe of TM8 needs to be connected with the oil outlet valve

of test vessel; the valve should be set to the open state afterwards. The oil filled 50 ml syringe

needs to be connected with the syringe valve to replace the headspace gas with processed oil.

Lastly, the syringe will be used to apply some negative pressure to the sealed system, checking

whether the sealing state of the system is reliable or not. If any gas bubbles come into the

59

system when the pressure is applied, the leakage place of the vessel or the connection must be

checked and sealed.

Normally the GIO concentration of previous test will reduce to nil after procedure 3.3.1,

therefore the test system didn’t require a formal clean procedure. However, the test system

needs to be washed and cleaned by processed oil under two certain circumstances: (1) the GIO

concentration is too high, i.e. several thousand ppm, (2) the next test oil type is different with

previous one.

In this two cases, the Procedure 3.3.1 and 3.3.2 needs to be repeated for a totally clean

background.

3.3.3 Measuring Background DGA level

Before measuring the background dissolved gas value of test oil, the gas extractor chamber

needs to be cleaned. Gas residue inside the gas chamber could be pumped out by using the “xtr

resume” command and “xtr gas.purge” command in sequence, resuming TM8 extractor to

normal operation state and then making the oil pump rotate forwards at the maximum speed.

The “pre” command could be used to print out the gas chamber pressure; the gas chamber

pressure will reduce down to 3 psi and then rise back up to around 15 psi (1 atmosphere) within

a couple of hours. The oil filled syringe needs to be connected to the top syringe valve to

balance the system pressure to the atmosphere pressure in case the pressure difference damages

the system sealing state.

Lastly, the “ts –s ‘date’T‘time’ ” command will be used to control TM8 for starting hourly oil

sampling after the gas purge procedure is finished. The background DGA GIG reading, relative

equilibrium pressure and oil temperature are noted for further calculation.

3.3.4 Generating Sparking Faults

60

During the sparking test, the output voltage was increased at a rate of 2 kV/s until a sparking

(an interrupted breakdown) occurred. The reason 5 kV/s is applied is to avoid any sparking

will be formed due to the fast increasing voltage. The sparking voltage and current (high

frequency and power frequency) were recorded for further analysis. This procedure was

repeated 15 times for each liquid sample.

3.4 Data Measurement and Analysis

3.4.1 GIG and GIT

As mentioned in Section 2.3.2, the TM8 on-line DGA monitor measures the amount of gases

using the headspace method. The headspace method actually measures the amount of fault

gases in the gas phase at equilibrium states and then calculates the amount of dissolved fault

gases or the total amount of fault gases. The total amount of fault gases can be calculated by

the Equation (2.1), in which GIT and GIG are the concentrations of total fault gases and fault

gases in gas phase respectively. K, partition coefficient, is a ratio of GIO over GIG at

equilibrium.

The K under different temperatures and pressures can be derived from TM8 monitor. Figure

3.5 plots the partition coefficient K for FR3 and Gemini X at different temperatures.

61

FR3 Gemini X

Figure 3.5 Partial Coefficients for FR3 and Gemini X

In Equation (2.1), β is the ratio of gas volume and oil volume inside the oil circulation system.

In the sparking test and PD test, β =Vgas/Voil= 77 ml/ 2570 ml = 0.02996. P0 is the equilibrium

pressure given by the unit of psi and P is the pressure of one atmosphere that is equal to 14.67

psi. T0 is the oil temperature and T is the standard temperature that is equal to 25 ºC which is

298.2 K.

When the test data were plotted in Duval triangle, the GIG value should be converted into GIO

value first. The way to calculate GIO is shown in Equation (3.1) [39].

GIO = GIG × K (T, gas) × P/P0 × T0/T (3.1)

The parameter used in Equation (3.1) is the same as that in Equation (2.1).

3.4.2 Dissolved Gas Generation Calculation

Based on the test observation, the amount of dissolved gas reached a peak within 3 hours after

the sparking tests were finished. An example is shown in Table 3.1 for Gemini X. GIG0 is the

background GIG value measured before the sparking test, GIG1, GIG2, GIG3 are the GIG

values measured at 1, 2 and 3 hours after the test. P and T represent the equilibrium pressure

and the oil temperature. Table 3.1 shows that the GIG value of H2 reached a peak at the 2nd

0.01

0.1

1

10

0 40 80 120 160

H2

N2

CO

O2

CH4

CO2

C2H4

C2H2

C2H6

°C

0.01

0.1

1

10

0 40 80 120 160

H2

N2

CO

O2

CH4

CO2

C2H4

C2H2

C2H6

°C

62

hour after the sparking test, and then it started to fluctuate and fell due to leakage, consumption

and temperature change. On the other hand, the GIG values of C2H4, C2H2, CH4 and CO

reached their peaks at the 3rd hour after the sparking test. Since all the GIG values will reach

their peaks within 3 hours, the average values around 3rd hour (result from 2nd 3rd and 4th hours)

after the test were reported as the final results in order to minimize the error. The GIT amount

can be obtained as the difference between the background and the final results using the

equation below:

ΔGIT = GIT average - GIT0.

Taking H2 value as an example, the background GIT value can be calculated as GIT = GIG ×

(K + β) × P/P0 × T0/T = 48.4 ppm × (K+0.02996) × 14.3 psi/14.7 psi × 298.2 K / 295.5 K.

According to Figure 3.5, K = 0.044 when T is 22.3 ºC. Substitute K = 0.044 into the above

Equation, we have GIT = 3.5 ppm.

Following the same calculation step, the GIT1, GIT2 and GIT3 can be obtained as 135.3 ppm,

152.1 ppm, 151.0 ppm. The average GIT is GIT average = (GIT1 + GIT2 + GIT3)/ 3 = (135.3

ppm + 152.1 ppm + 151.0 ppm) / 3 = 146.1 ppm. Therefore, the total amount of H2 generated

during the test is GIT = GIT average - GIT0 = 146.1 ppm – 3.5 ppm = 142.6 ppm.

Table 3.1 Example GIO Concentration in Gemini X

Mineral oil test 1 GIO (ppm) P T

No. C2H4 C2H2 C2H6 H2 O2 CH4 CO

GIG0 0 2.8 0.3 48.4 138031.8 0 42.9 14.3 22.3

GIG1 8.2 70.1 0 1835 136751.1 28.8 39.7 14.5 22.6

GIG2 10.4 85.8 0 2047.5 135906.6 36.4 40.7 14.6 22.6

GIG3 11.2 86.7 0 2032.6 135336.6 36.8 51.4 14.6 22.7

Table 3.2 shows the calculation results of all gases in the example. The Total Dissolved

Combustible Gas (TDCG) is also listed as the sum of hydrocarbons, hydrogen and carbon

monoxide. For gases with a generation amount less than 0, such as C2H6 -0.7, the GIT is

regarded as 0.

63

Table 3.2 Example GIT Concentration in Gemini X

Mineral oil test 1 GIT (ppm)

No. C2H4 C2H2 C2H6 H2 O2 CH4 CO

GIT0 0 3 -0.7 3.5 21037.1 0 6.2

GIT1 11.9 76 0 135.3 21111.9 11.3 5.8

GIT2 15.2 93.7 0 152.1 21126.3 14.4 6

GIT3 16.4 94.5 0 151 21030.5 14.5 7.5

Average GIT 14.5 88.1 0 146.1 21089.6 13.4 6.4

Generation GIT 14.5 85.1 0 142.6 52.5 9.8 0.3

TDCG 252.2

3.4.3 Sparking Energy Calculation

The sparking energy for each test could be quite different even when the test condition was

well controlled. As shown in Figure 3.1, the fault current was measured by using two current

transformers with one in the power frequency (50 Hz) range and the other in the high frequency

range (5 MHz). The voltage was measured using a voltage divider. Two 100 MHz oscilloscopes

made by Lecroy were used to record low frequency signal and high frequency signal separately.

High frequency sparking current and voltage signals were recorded with 500 k sample points

at a 1 GHz sampling rate while power frequency sparking signals were recorded with a 500 k

sample points at a 5 MHz sampling rate. The sparking energy can be calculated following

Equation (3.2), in which 0 - tn is recorded duration.

W = ∫ V (t) × I (t) 𝑡𝑛

0× dt (3.2)

It should be noted that the time scale set by the oscilloscopes for the high frequency and low

frequency currents are different. For the high frequency current, the time scale is usually 160

ns (one high frequency current pulse) and for low frequency current, the time scale is usually

40 ms. Consequently, Equation (3.2) can be written into Equation (3.3), in which n is the

number of sample points and Δt is the time step between sample points.

W = ∑ (𝑉(𝑛) × 𝐼(𝑛) × ∆𝑡)𝑛0 (3.3)

64

In Section 3.5, it could be found that the oscilloscopes were set to compensate the CT output

ratio and as a result, thus the CT ratios have been taken in account in the recorded readings and

therefore will not affect the calculation equation. On the other hand, as stated in section 3.1,

the voltage divider is used to reduce the voltage to 1/10 k and the probe of the oscilloscope is

also set to 10:1 in compensation, Equation (3.3) needs to be rewritten into Equation (3.4).

W = ∑ (𝑉(𝑛) × 𝐼(𝑛) × ∆𝑡)𝑛0 × 10000/10

W = ∑ (𝑉(𝑛) × 𝐼(𝑛) × ∆𝑡)𝑛0 × 1000 (3.4)

3.4.3.1 High Frequency Component of Sparking Signal

For the calculation of high frequency energy, the V (n) and I (n) were converted into absolute

value since sparking in both the negative and positive direction will produce fault gases.

Consequently, Equation (3.4) can be rewritten into Equation (3.5).

W h = ∑ (|𝑉(𝑛)| × |𝐼(𝑛)| × ∆𝑡)𝑛0 × 1000 (3.5)

Figure 3.6 shows an example of a high frequency component. Channel 1 records the sparking

voltage while channel 3 records the high frequency sparking current. Figure 3.6(a) shows a full

time scale of high frequency sparking signals which includes 2 pulses in a 200 µs time range.

Figure 3.6(b) is the zoom-in view of Figure 3.6(a), focusing on the first pulse in a 2 µs time

range.

It should be noted that noises exist in the recordings and should be filtered. In this example,

the noise is about 5 A while the maximum pulse signal is 250 A (channel 3 voltage to current

ratio is 1: 1, therefore 250 V noise signal from oscilloscope stands for 250 A). Matlab was used

to calculate the energy for the high frequency component. 200 k points are recorded for each

test and therefore n in Equation (3.5) is 200,000. V[n] and I[n] are stored in two arrays and

time step Δt is set to 1 ns.

65

(a) 200 µs time range (b) 2 µs time range

Figure 3.6 Example of High Frequency Component of Sparking Current

3.4.3.2 Power Frequency Component of Sparking Signal

For the calculation of power frequency energy, the power frequency current was measured in

the primary winding side of the voltage supply transformer because the current is too small to

be measured in the secondary winding side. Therefore, the measured current should be

converted to the value at the secondary winding side by a factor of 240/ 80k. Equation (3.4)

can be rewritten into Equation (3.6) to compute power frequency power.

W p = ∑ (V(n) × I(n) × ∆t)n0 × 1000 × 240/ 80000

W p = ∑ (V(n) × I(n) × ∆t)n0 × 1000 ×3 / 1000

W p = ∑ (V(n) × I(n) × ∆t)n0 × 3 (3.6)

Figure 3.7 shows an example of power frequency energy calculation for the same sparking test

shown in Figure 3.6. Channel 1 (yellow) shows the sparking voltage and channel 2 (pink)

shwos the power frequency current. Theoretically the background relative power before

sparking should be 0, however, there is a slight phase difference between the current from the

primary and the secondary winding, making the reactive power not equal to zero. Therefore,

the background energy should be eliminated in the energy calculation. Since the background

energy within any period before the sparking faults is a constant W0, the actual sparking energy

66

can be obtained by using the sparking energy W1 (as shown in Figure 3.7) minus the

corresponding background energy W0.

Figure 3.7 Example of Power Frequency Component of Sparking Current

It should be noted that the power frequency current transformer (made by Chauvin Arnoux)

has a frequency range from 40 to 10 kHz. Therefore, the high frequency noises should be

filtered. A Matlab ellipse filter is applied to filter the current signals for two times. As shown

in Figure 3.8, the high frequency noises contained in the original power frequency current (blue

curve) were removed, leaving only the filtered power frequency current (red curve).

Figure 3.8 Example Filtered Waveform of Power Frequency Sparking Current

67

Similar to the high frequency energy, Matlab is used to calculate the power frequency energy.

500 k points are recorded for each sparking test and therefore n in Equation (3.6) is 500,000.

The V[n] and I[n] are stored in two arrays and time step Δt = 1 ns.

3.4.3.3 Sparking Types

Since sparking (interrupted breakdown) is of the random nature, three different types of

sparking were observed during the tests even under the similar test conditions. The sparking

could be classified as normal sparking, slight sparking and continuous sparking as shown in

Table 3.3.

Table 3.3 Sparking Types

Sparking type cut off or not dips before cut off

Normal sparking Yes 1

Slight sparking No 1

Continuous sparking Yes 2 or more

A normal sparking is followed by the interruption of the current relay, after which the applied

voltage is cut off. A slight sparking is not followed by the interruption of the current relay, and

the voltage is continuously applied on the sample liquid after having a slight voltage dip.

Therefore, the energy of the slight sparking was not calculated since the amount of fault gases

is small and the sparking energy is also small. A continuous sparking contains two or more

sparking faults before the current relay cuts off the voltage. Therefore, the energy of all

sparking faults contained in a continuous sparking was calculated. The waveforms of different

types of spankings are shown in Figure 3.9.

(a) Normal sparking (b) Slight sparking (c) Continuous sparking

Figure 3.9 Different Types of Sparking

68

3.4.3.4 Example of Sparking Energy Calculation

To calculate the energy for each sparking test, firstly, the number of sparking faults should be

determined. Secondly, the average high frequency power and power frequency power need to

be used for group sparking energy estimation.

For example, Table 3.4 shows the energy of Gemini X sparking test group 2. This group

contains 13 normal sparking and 1 continuous sparking (including two consecutive sparking)

which in total form 15 sparking in this group. When the double sparking occurred, the power

frequency signal is completely recorded as shown in Figure 3.9 (c) while the high frequency

pulse of the second consecutive sparking (Sparking 10 b) is missed for the sampling period of

the oscilloscope is too short (200 μs) to catch the second pulse.

Table 3.4 Example of Group Sparking Energy Calculation

Test 2

PF

Energy(J

)

HF

Energy(J

)

Test 2 PF Energy(J) HF Energy(J)

Sparking 1 1.77 2.02 Sparking 10 a 4.93

1.55

Sparking 2 1.37 1.07 Sparking 10 b Missed

Sparking 3 1.64 1.42 Sparking 11 1.75 1.73

Sparking 4 1.63 1.79 Sparking 12 1.81 1.89

Sparking 5 1.51 1.42 Sparking 13 2.04 2.3

Sparking 6 4.01 2.24 Sparking 14 1.92 2.07

Sparking 7 1.77 1.64 average 1.96 1.75

Sparking 8 1.92 2.25 total 29.37 26.2

Sparking 9 1.3 1.04 Group

energy (J) 55.57

As shown in Table 3.4, the power frequency energy of sparking 10 (4.93 J), the double sparking,

is roughly the double of the power frequency energy of other sparking in this group (average

1.96 J). In this case the average power frequency energy is equal to 1/15 of the sum of all

sparking which is (1.77 J + 1.37 J +… 4.93 J+ 1.75 J+… 1.92 J)/ 15 = 1.96 J, the total power

frequency energy is then 15 × 1.96 J = 29.37 J.

69

On the other hand, the high frequency energy of sparking 10 only stands for the first

consecutive sparking (Sparking 10 a) whose energy (1.55 J) is close to the average value (1.75

J). The sum of high frequency power is 15 × average energy of high frequency energy (1.75 J)

and such the total energy is 1.75 J × 15 = 26.20 J. Group energy is the summary of total power

frequency energy and high frequency energy which is 29.37 J +26.20 J = 55.57 J.

3.5 Test Condition and Observation

Detail of the oscilloscope setting is listed below in Table 3.5. All 13 groups of test including

13× 15 normal sparking are controlled in the same conditions for a better comparison. In this

setting, the oil volume of the whole TM8 – test vessel system contains 2.57 L oil and 77 ml

headspace.

Table 3.5 Oscilloscope Settings

Oscilloscope Setting

Power frequency current High frequency current

Channel 1 Channel 1

Voltage div 50 V Voltage div 50 V

probe 10/1 probe 10/1

Voltage divider ratio 1/10 k Voltage divider ratio 1/10 k

Channel 2 Channel 3

Current div 1 V Current div 100 V

probe 10/1 probe 100/1

CT ratio 1/10 CT ratio 1/100

Trigger Trigger

Coupling HF reject Coupling DC

Time Time

Delay 0 Delay -80 μs

Point number 500 k Point number 200 k

div 10 ms div 20 μs

The average sparking voltage for FR3 is 51 kV with a ± 3 kV fluctuation and is 54 kV for

Gemini X with a ± 3 kV fluctuation. Compared with FR3, under the same test conditions,

70

Gemini X requires higher energy for the incipient of sparking and will also generate a higher

amount of gas bubbles after each sparking.

3.6 Test Result and Analysis

3.6.1 Gas Generation of Sparking Faults

The amount of total fault gases is summarized in Figure 3.10 for both Gemini X and FR3.

(a) GIT of Gemini X Tests

(b) GIT of FR3 Tests

Figure 3.10 Total Gas Generation in Gemini X /FR3 Tests

0.0

50.0

100.0

150.0

200.0

250.0

C2H4 C2H2 C2H6 H2 CH4 CO

Test group 1 14.5 85.1 0.0 142.6 9.8 0.3

Test group 2 17.7 100.6 1.4 207.1 14.4 0.9

Test group 3 18.0 103.3 1.8 211.6 14.3 2.0

Test group 4 17.8 101.3 0.0 228.3 14.9 0.7

Test group 5 15.6 90.4 0.5 156.4 12.9 1.2

ppm

0.0

50.0

100.0

150.0

200.0

250.0

C2H4 C2H2 C2H6 H2 CH4 CO

Test group 1 14.5 92.5 0.6 194.1 6.2 42.0

Test group 2 11.6 84.5 0.1 194.3 6.2 38.2

Test group 3 13.0 84.6 0.0 170.4 7.5 31.2

Test group 4 13.8 100.7 0.6 212.2 6.7 49.9

Test group 5 13.0 86.0 1.1 179.3 5.9 45.0

Test group 6 11.4 92.5 0.0 218.6 6.1 47.9

ppm

71

It can be seen that the total amount of fault gases of Gemini X and FR3 are similar at about

200 ppm. However, the fault gases generation of FR3 is relatively stable compared with Gemini

X, and the fault gas amount varies in each group probably due to different energies even when

the test condition was well controlled. Therefore, the sparking energy should be taken into

account to compare the gas performance of different oils. Generally speaking, fault gas

generation is relatively similar when the same numbers of sparking faults are applied. However,

when the sparking energy is taken into consideration, the conclusion is varied slightly.

3.6.2 Energy of Sparking Faults

The calculated energy of each test is listed below in Table 3.6, using the energy calculation

method described in Section 3.4.3.

Table 3.6 Sparking Energy for Each Test Group inside Gemini X/ FR3

Gemini X test group Average(J) Total(J) PF average(J) HF average(J)

1 2.96 44.47 1.71 1.25

2 3.7 55.57 1.96 1.75

3 3.52 52.74 1.77 1.75

4 3.65 54.79 1.76 1.89

5 3.6 54.05 1.73 1.87

Average of Gemini X 3.49 52.32 1.79 1.70

FR3 test group Average(J) Total(J) PF average(J) HF average(J)

1 3.20 48.04 1.97 1.23

2 2.89 43.32 1.63 1.26

3 2.78 41.76 1.53 1.25*

4 2.77 41.51 1.63 1.14

5 2.89 43.28 1.65 1.24

6 2.19 32.82 1.38 0.81

Average of FR3 2.79 41.79 1.63 1.15

Note: * The original test data are damaged, 1.25 J is estimated data

72

The sparking energy for each test group is different with the maximum deviation of 20%. FR3

has a 20% lower energy compared with Gemini X. The difference of the energy is mainly

attributed to the high frequency component of the sparking faults, since the difference of high

frequency component energy for Gemini X and FR3 is 48% while that of power frequency

component energy is only 9%.

3.6.3 Gas generation rate (per J)

Figure 3.11 shows the amount of gas generation rate (per J) for Gemini X and FR3. It can be

noticed that the gas generation rate (per J) was different from the total gas amount as shown in

Figure 3.10. Taking H2 generation of Gemini X test as an example, the H2 generation of test

group 5 (156.4 ppm) is larger than that of test group 1 (142.6 ppm) in Figure 3.10; however,

the H2 generation (per J) of test group 5 (3.0 ppm / J) is less than that of test group 1 (3.2 ppm

/ J) in Figure 3.11.

73

(a) Gas generation rate (per J) in Gemini X tests

(b) Gas generation rate (per J) in FR3 tests

Figure 3.11 GIT Generation rate (per) J in Gemini X and FR3 Sparking Tests

0.0

2.0

4.0

6.0

8.0

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

Test group 1 0.3 1.9 0.0 3.2 0.2 0.0 5.6

Test group 2 0.3 1.9 0.0 3.9 0.3 0.0 6.5

Test group 3 0.4 2.0 0.0 4.2 0.3 0.0 7.0

Test group 4 0.3 1.9 0.0 4.4 0.3 0.0 6.9

Test group 5 0.3 1.8 0.0 3.0 0.2 0.0 5.4

Average of groups 0.3 1.9 0.0 3.7 0.3 0.0 6.3

ppm/ J

0.00

2.00

4.00

6.00

8.00

10.00

12.00

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

Test group 1 0.36 2.29 0.01 4.80 0.15 1.04 8.66

Test group 2 0.26 1.88 0.00 4.32 0.14 0.85 7.45

Test group 3 0.30 1.97 0.00 3.97 0.17 0.73 7.15

Test group 4 0.28 2.07 0.01 4.37 0.14 1.03 7.90

Test group 5 0.30 1.99 0.02 4.15 0.14 1.04 7.65

Test group 6 0.35 2.81 0.00 6.65 0.18 1.46 11.45

Average of groups 0.3 2.2 0.0 4.7 0.2 1.0 8.4

ppm/ J

74

It can also be seen from Figure 3.11 that the gas generation rate (per J) is repeatable for all

groups. For both liquids, H2 is the main fault indicator which takes up to 60% of the total fault

gases, followed by C2H2 which takes up to 25% of the total fault gases. However, CO is only

significant in FR3 which always takes up to 12% of total fault gases, which probably due to

the ester part in the FR3 molecular structure.

3.6.4 Absolute Gas generation rate (per J)

When considering the oil volume of the test system (2.57 L), the gas generation rate in the unit

of ppm/J can be calculated into the absolute gas generation rate in the unit of μl/J, as listed in

Table 3.7. It can be seen from Table 3.7 that the gas generation rates of the sparking fault reach

21 μl/J for FR3 and 16 μl/J for Gemini X, which is comparable with that of Dr. X. Wang’s test

conclusion. [10]

Table 3.7 Absolute GIT Generation Rate (μt/J) of Sparking Tests

Oil Test J/BD ppm/BD ul/BD ppm/J ul/J ml/test

Gemini

X

1 3.0 16.8 43.2 5.59 14.4 0.65

2 3.5 22.8 58.6 6.46 16.6 0.88

3 3.4 23.4 60.1 6.96 17.9 0.90

4 3.5 24.2 62.2 6.94 17.8 0.93

5 3.4 18.5 47.5 5.37 13.8 0.71

Average 3.4 21.1 54.3 6.3 16.1 0.8

FR3

1 2.69 23.32 59.94 8.66 22.25 0.90

2 3.00 22.33 57.40 7.45 19.15 0.86

3 2.86 20.44 52.52 7.15 18.38 0.79

4 3.24 25.59 65.77 7.90 20.30 0.99

5 2.88 22.02 56.58 7.65 19.67 0.85

6 2.19 25.10 64.49 11.45 29.41 0.97

Average 2.8 23.1 59.5 8.4 21.5 0.9

3.6.5 Gemini X and FR3 Comparison

As stated in Section 3.5, sparking test conditions were well controlled and therefore results

from all test groups can be used in an average value calculation. The average value of all test

groups in FR3 and Gemini X was calculated and compared in Figure 3.12.

75

Figure 3.12 GIT Generation rate (per J) Comparison between Gemini X and FR3

It can be seen that the sparking faults in FR3 generates 33% higher amount of total fault gases

than that in Gemini X. The amount of H2 in FR3 is 27% higher than that in Gemini X, while

the amount of C2H2 in FR3 is 16% higher. Furthermore, CO takes up to 12% in FR3 while it

is almost 0 for Gemini X.

3.6.6 Duval Triangle Analysis

All the DGA data from sparking tests need to be calculated into GIO value before the Duval

triangle method applied. The GIO concentration are calculated based on Equation (3.1) and

shown in table 3.8.

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

Gemini X 0.3 1.9 0.0 3.7 0.3 0.0 6.3

FR3 0.3 2.2 0.0 4.7 0.2 1.0 8.4

ppm/ J

76

Table 3.8 GIO Generation Rate (ppm/J)

Mineral oil GIO DGA(ppm)

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

Test group 1 14.2 82.7 0 84.9 9 0.2 191.1

Duval ratio 13.40% 78.10% 8.50%

Test group 2 17.4 97.8 1.4 123.4 13.3 0.7 254.1

Duval ratio 13.50% 76.10% 10.40%

Test group 3 17.6 100.4 1.8 125.9 13.2 1.6 260.6

Duval ratio 13.40% 76.50% 10.10%

Test group 4 17.8 101.3 0 228.3 14.9 0.7 363.1

Duval ratio 13.30% 75.60% 11.10%

Test group 5 15.2 87.9 0.5 93.7 1191.20% 1 210.1

Duval ratio 13.20% 76.40% 10.40%

FR3 GIO DGA(ppm)

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

Test group 1 14.2 91.3 0.6 123.1 5.8 33.2 268.1

Duval ratio 12.80% 82.10% 5.20%

Test group 2 11.4 83.5 0.1 123.4 5.7 30.2 254.3

Duval ratio 11.40% 83.00% 5.70%

Test group 3 12.8 83.5 0 108.2 6.9 24.6 236

Duval ratio 12.40% 81.00% 6.70%

Test group 4 13.5 99.5 0.6 134.5 6.2 39.4 293.7

Duval ratio 11.30% 83.50% 5.20%

Test group 5 12.8 84.9 1 114.9 5.5 35.6 254.7

Duval ratio 12.40% 82.30% 5.30%

Test group 6 11.2 91.4 0 136.4 5.6 37.7 282.3

Duval ratio 10.30% 84.50% 5.20%

The Duval triangle method can then be applied as shown in Figure 3.13. The FR3 Duval

Triangle used here is obtained from the latest publications by M. Duval [16]. It should be noted

77

that the Duval triangle plots for different tests of the same oil are quite close to one another,

indicating that the test repeatability is good. It can be seen that the sparking faults in Gemini X

and FR3 were all plotted in D1 area (low energy discharge), indicating that the energy of

sparking faults was not very high because the sparking current was interrupted by the current

protection relay immediately after the fault occurred. Therefore, a continuous arcing path could

not be formed in the oil.

Figure 3.13 Duval Triangle Evaluation (GIO) of Sparking Fault in Gemini X and FR3

3.6.7 Laboratory DGA and Online Monitor Comparison

To make sure that the results from TM8 are reliable, some of the oil samples are sent to TJH2B

analytical laboratory for DGA analysis as a reference. Table 3.9 shows an example of the DGA

comparison between the TM8 and the analytical laboratory. The DGA results using the online

TM8 monitor was obtained 3 hours after 15 sparking tests for FR3. The laboratory DGA

analysis was carried out 16 hours later than that. Table 3.6 shows that the laboratory result and

online monitor results agree with each other within a deviation of 30%. However, the amount

of O2 using laboratory analysis is 3 times higher than that using TM8, indicating a leakage

might occur during the sample transportation.

78

Table 3.9 Comparison of GIO Results between TM8 and Laboratory Analysis

Oil type GIO (ppm)

FR3 C2H4 C2H2 C2H6 H2 O2 CH4 CO

TM8 sample 24 197.3 3 80.4 14190.4 12.1 53.5

Laboratory sample 19 151 3 59 59060 8 34

Laboratory / TM8 79.08% 76.52% 99.84% 73.43% 416.20% 65.91% 63.60%

3.7 Summary

In this chapter, the amount of total fault gases in FR3 and Gemini X are measured using a

sealed online DGA test system.

The main summaries are listed as follows:

1. FR3 generates a similar amount of fault gases to Gemini X under sparking faults.

2. Considering the sparking energy, FR3 generates fault gases (per J) 25% higher than

Gemini X.

3. The fault gas generation (per J) might be a more reasonable parameter to evaluate the

gas performances of different liquids.

4. The Duval triangle method can recognize these sparking faults as low energy

discharges for both liquids.

5. TM8 online monitor result is comparable with laboratory DGA analysis method with a

deviation of 30%.

79

Chapter 4 Experimental Study on DGA under PD Faults

4.1 Introduction

In this chapter, the electrical partial discharge (PD) faults is studied using the needle to plate

electrodes and the online DGA monitor and oil circulation system which is similar to the one

described in last chapter. Although in previous publications the PD faults was usually presented

by the PD amplitude [11], it is found in this chapter that the PD energy can be correlated with

the amount of s gases much better. As a result, the gas generation rate (versus energy) is proved

to be a useful parameter to show the gas performances of Gemini X and FR3. In order to

compare the DGA results between online and laboratory methods, some oil samples were also

sent to TJH2B for laboratory analysis.

4.2 Experiment Setup

The experimental setup of PD test is similar to the sparking test, as shown in Figure 4.1. The

same test container was connected with the TM8 online monitor using the same method,

providing a good sealing capability of the oil circulation system. However, the distance

between the needle and plate electrodes was increased to 50 mm. Furthermore, the PD signals

produced in the test were monitored by a LDS-6 PD detector, with the measuring impedance

connected in series with the 500 pF capacitor, providing a traditional PD test circuit. The LDS-

6 PD detector can record the magnitude of each PD signal, as well as the appearance time and

the instantaneous voltage.

80

R1

R2

Test vessel

Voltage

divider

Ratio

10000:1

TM8

Over Current

Protection relay

6.5 A

240 V/80 kV

500 pF

600 kΩ Water resistor

PC based TM8

control software

The cage

100 MHz

oscilloscope

Oil

inlet

Oil

outlet

Zm

Measuring

impedence

500 kHz PC

based PD

detector

Variac

0-240 V

Figure 4.1 Schematic Diagram of Electrical PD Test Circuit

4.3 Test Procedure

Since the fault gases in PD tests were generated in quite small amount, special care should be

taken to avoid the gas leakage. The test procedure of PD test is listed as follows. It should be

noted that the oil circulation was always suspended during the PD test until measuring the fault

gases, in order to reduce the gas leakage from the circulation.

Process transformer oil (Chapter 2).

Drain oil out of the system.

81

Clean test system, fill processed oil into the system (eliminate the headspace). (Chapter

3.3)

Calibrate PD detector.

Measure the background gases.

Generate PD faults.

Measure the amounts of fault gases.

Data processing and analysis.

4.3.1 Calibrate the PD Detector

A PD experiment system is required to be calibrated and PD background noise needs to be

measured before the start of test.

To calibrate the LEMKE LDS-6 PC based PD detector, both the PD amplitude and voltage

readings need to be calibrated. The PD calibrator was connected in parallel to the test vessel in

order to apply a 50 pC PD signal to the test vessel. The PD detector will then be used to check

and calibrate the measured signal to see if it is 50 pC. The PD calibrator needs to be removed

and a 30 kV voltage will be applied to the test vessel. The measured voltage from the PD

detector was checked and adjusted until the voltage reading matches that of the oscilloscope.

Figure 4.2 shows the screen shot of the software.

Figure 4.2 PD Calibration Panel of PD Measuring System Software

82

4.3.2 Measuring Background PD Noise

Before the PD test, the maximum background PD noise signal in air should be determined. The

needle electrode was firstly removed, and the test circuit was set up as shown in Figure 4.1.

Then, the maximum applied voltage of 60 kV was applied to the test vessel. The PD signal was

recorded for 1 minute and the result are shown in Figure 4.3.

As we can see from Figure 4.3, the maximum PD noise in FR3 under 60 kV is only 30 pC

which is extremely low in comparison with 4000 pC PD amplitude when the needle electrode

is installed. For this case, the background PD noise could be ignored since the noise is much

lower than the noise cutoff level when the needle electrode is in use. The noise cutoff level was

used to remove the background noise in the PD test, and the detail is described in Section

4.4.2.1.

Figure 4.3 PD Noise in FR3 under 60 kV

4.3.3 Generating PD Faults

Before the PD faults are generated, TM8 needs to be suspended and the oil inlet and outlet

valve should be turned off to keep a better sealing state of the test system. Unlike the sparking

test which only lasts for 10 minutes, the PD test lasted up to 2 days. Therefore, the sealing state

83

is of vital importance for a reliable test result. For this reason, anything could reduce the

dissolved gas concentration such as (1) leakage caused by oil flow or (2) gas consumption

caused by TM8 sampling must be prevented.

To generate a PD fault, the applied voltage is raised at the rate of 2 kV/s until the target voltage

is reached. The voltage is then kept for a certain period of time according to the fault gas

generation rate of each liquid. In FR3 test, because the PD repetition rate is high, the PD signal

was recorded for 1 minute in every 15 minutes; On the other hand, the PD signal in Gemini X

test was recorded from the beginning to the end due to a much lower repetition rate. The test

voltage was reduced to zero after the test is finished. Then the oil valves were re-opened and

the oil circulation was resumed before the measurement of fault gases by TM8.

4.4 Data Measurement and Process Method

4.4.1 Total Gas Generation Calculation

The calculation method of total fault gases is almost the same as that described in Section 3.4.

The only difference between the total gas generation calculation of the sparking test and the

PD test is that the GIT and GIO are calculated by the peak value instead of the average value.

In the sparking test, dissolved gas reached a peak within 3 hours, thus the average of the amount

of fault gases within 3 hours was used as the final result (the average value is similar to the

peak value). However, in the PD test, because the oil circulation is suspended during the test,

the dissolved gas reading will reach a peak within 6-7 hours after the test. The average value

within this duration is quite difference from the peak value, and therefore, the peak value (based

on H2) is used as the final result. TM8 viewer software could be used to observe the peak of

fault gases as shown in Figure 4.4.

84

Figure 4.4 Example of PD Test DGA Peak Value

The H2 is the most significant and easy-leaking gas among all generated fault gases. The H2

peak is therefore chosen as the sign for peak value to obtain a maximum H2 reading. As we

can see from Figure 4.4, the H2 (dark blue curve) reaches a peak in 4 hours after the test.

Therefore, the readings of fault gases at the 4th hour after the test should be used as the results.

4.4.2 PD Energy Calculation

It was observed that the PD power during the long-period PD test might vary a lot due to the

electrical erosion of the needle electrode by the discharge. In order to calculate the PD power

and PD energy, the PD signals were recorded periodically for short durations due to storage

limitation of the software, i.e. one minute in every 15 minutes. As a result, each PD test was

recorded into several short-duration PD files. During the recording, there are several time

periods cannot be recorded due to operation, the energy of this period is estimated according

to recorded PD files. Consequently, the PD energy for each PD test was obtained by linearly

extending those PD energy of each short-duration PD files to the full test duration. It should be

85

noted that the noise of the PD signal should be filtered out via LDS-6 PD measurement software

before the calculation.

4.4.2.1 Instrument Noise Filtering

During the PD recording, the PD detector was able to remove the small PD noises. This was

achieved by applying a cut-off level manually provided by the operator, and any PDs or noises

with magnitude less than the threshold level was removed. The cut-off level was determined

as a level slightly higher than the PD noise, i.e. a cut-off level of 50 pC based on the noise

result in Figure 4.3. Figure 4.5 shows the effect of noise filtering of a 44 kV test of FR3. As

shown in Figure 4.5, the filtered PD signal (Figure 4.5 (b)) was obtained by removing the noises

less than 130 pC in the recording of all signals (Figure 4.5 (a)).

(a) Orginal PD signal (b) Filtered PD signal

Figure 4.5 PD Noise Filter

4.4.2.2 PD Energy Calculation Method

As it stated before that several PD files were used to record a PD test, as a result, the energy

for each test PD test can be linearly extrapolated

The PC-based PD detector recorded 4 parameters of each PD signal: the PD sequence number,

the PD occurrence phase when a PD was detected, the PD apparent charge (Q in the unit of pC)

and the instantaneous voltage (in the unit of kV). The PD charge and PD voltage can be used

to calculate the PD energy using Equation (4.1).

86

W = (4.1)

where the unit of Q is pC and the unit of V is kV. If we convert the pC to C, kV to V, Equation

(4.1) can be rewritten into Equation (4.2) to get the energy in J.

W = (4.2)

In order to judge the PD energy distribution to each band of PD amplitude, the PD energy is

calculated according to 6 PD amplitude bands: 0-1000 pC, 1000-2000 pC, 2000-3000 pC,

3000-4000 pC, 4000-5000 pC, and 5000-6000 pC (barely used). The “Find” function of Matlab

will be used here to pick out these PD that are within the proper amplitude band. Equation (4.2)

is still capable for PD energy computation after the qualified PDs are picked out by the Find

function.

In order to calculate the overall PD energy, the PD power should be obtained by following

Equation (4.3) and linearly extrapolated to the overall period.

P = W/ t (4.3)

Substitute Equation (4.2) into Equation (4.3), we have:

P = (4.4)

Equation (4.4) could be used to calculate energy for each PD record file. In Equation (4.4), t is

the sampling period of the PD record file. The unit of P is W, in order to convert the unit of

power into standard unit mW, Equation (4.4) then needs to be rewritten into Equation (4.5):

P =

P = (4.5)

87

As stated at the beginning of Chapter 4.4, the PD signal is recorded into several individual PD

files, after the power of each individual file is calculated by Equation (4.5); the average power

needs to be acquired by Equation (4.6):

(4.6)

Lastly, the PD energy can now be computed by Equation (4.7):

(4.7)

Where ttotal is the full time duration for each PD test. Equation (4.7) is used to compute the total

PD faults energy by Excel, example shown in next Section.

4.4.2.3 Example of PD Energy Calculation

Table 4.1 presents the detail of PD files of the 2000 pC Gemini X PD test which lasts for 1380

minutes. This continuous PD test is separated into 5 PD files. The PD detector recorded 5 PD

files for this continuous PD test with a 60 minutes interval. In this case, according to Equation

(4.6), the average power Paverage of all PD files is equal to (0.02mW*60minutes +

0.08mW*60minutes +0.12mW*60minutes +0.12mW*120minutes +0.06mW*1020 minutes)/

(60 minutes +60 minutes +60 minutes +120 minutes +1020 minutes) = 0.07mW. Because there

are 60 minutes of the PD tests was not recorded by the PD detector due to operation during the

test; the recorded total test duration is then 1320 minutes instead of the full test period of 1380

minutes. The total PD energy of the PD test needs to be linearly extended, the result could be

achieved based on Equation (4.7): 0.07mW * 1380 minutes = 5.61 J.

88

Table 4.1 Example of PD Test Energy Calculation

PD file of Gemini X test

3

Recording

duration

(minutes)

PD

power(mW) Energy(J)

1 60 0.02 0.08

2 60 0.08 0.30

3 60 0.12 0.44

4 120 0.12 0.86

5 1020 0.06 3.63

6(not recorded) 60 0.07(not

recorded)

0.3(not

recorded)

Total 1380 0.07 5.61

4.5 Test Condition and Observation

Table 4.2 shows the list of PD tests. It can be seen that 4 PD tests were carried out in Gemini

X with the PD amplitude of 1500 pC, 2000 pC, 3000 pC and 4000 pC. On the other hand, 8

PD tests were carried out in FR3 with the PD amplitude from 1000 pC to 4000 pC. The PD

faults were applied for different test durations (from 62 minutes to 2880 minutes) until a proper

amount of fault gases was generated. Details of the test conditions are listed in Table 4.2.

89

Table 4.2 List of PD Tests

Oil Test Test

Voltage(kV)

Test duration

(minutes)

PD

amplitude

(pC)

Needle

Gemini X

1 50 2880 1500 New

2 50 2580 3000 After test 1

3 58 1380 2000 New

4 58 1290 4000 After test 3

FR3

1 34 390 1000 New

2 34 360 1000 New

3 44 180 2000 New

4 44 235 2000 After test1

5 57 70 3000 After test 3

6 57 150 3000 After test 5

7 57 70 3000 New

8 61 62 4000 After test 7

All headspace is eliminated from the test vessel before the test started. The oil and headspace

volume of the whole TM8-test vessel system are 2.57 L oil and 77 ml which is the same as the

sparking test.

Compared with Gemini X, under the same test condition, FR3 generated much higher amounts

of fault gases.

4.6 Test Result and Analysis

4.6.1 PD Fault Gas Generation

90

Figure 4.6 shows the gas generation rate per hour for Gemini X (Figure 4.6 (a)) and FR3

(Figure 4.6 (b)). The result of FR3 shows in Figure 4.6(b) is the average of two tests with the

same PD magnitude.

(a) Gas generation per hour in Gemini X

(b) Gas generation per hour in FR3

Figure 4.6 Gas Generation in Gemini X and FR3 PD Test

It can be seen that the generation rate increases as the PD amplitude increases for both liquids.

An exception is that, in Gemini X, the gas generation rate under 2000 pC PD fault is slightly

higher than that under a 3000 pC PD fault. This might be caused by different needle states,

0.0

1.0

2.0

3.0

4.0

5.0

6.0

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

1500pC 0.0 0.1 0.0 0.1 0.0 0.1 0.4

2000pC 0.0 0.5 0.0 0.7 0.1 0.2 1.5

3000pC 0.1 0.3 0.1 0.6 0.1 0.1 1.2

4000pC 0.3 1.2 0.2 3.2 0.6 0.2 5.6

ppm/h

0.0

50.0

100.0

150.0

200.0

250.0

300.0

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

1000 pC 0.0 0.0 0.1 1.3 0.0 0.6 2.1

2000 pC 0.8 5.3 0.7 10.6 0.7 2.9 20.9

3000 pC 6.9 24.8 1.9 107.6 6.2 18.8 166.2

4000 pC 13.4 36.5 6.0 185.4 9.8 33.8 285.0

ppm/h

91

since the repetition rate of 2000 pC test is higher than that of 3000 pC test. Among all PD tests

of Gemini X, the amount of H2 takes up to 50% of the total gas generation while C2H2 takes

up to around 25% of total gas generation. Similarly, H2 and C2H2 are also the key indicators

for the PD test in the FR3 test whose contributions to the total gas generation are 60% and 15%

respectively.

However, the CO generation is only significant in FR3, which might be attributed to the ester

part in the FR3 structure. It is also observed that the gas generation rate of FR3 is much higher

(5 -150 times higher) than that of Gemini X for the same magnitude. Considering the difference

between the PD characteristics of Gemini X and FR3 [10], a larger fault gases concentration

in FR3 does not necessarily indicate a higher PD magnitude in FR3. Therefore, the gas

generation rate per hour may not be a good parameter to compare the gas performance between

different oils, and the PD energy should be taken into consideration.

4.6.2 PD Fault Energy

Therefore, the PD pattern of both transformer liquids need to be studied first.

Figure 4.7 (a) is the PD pattern of Gemini X under 3000 pC PD fault lasting for 60 minutes

while Figure 4.7 (b) shows the PD pattern of the FR3 with a maximum 3000 pC PD amplitude

lasting for only 1 minute. It can be seen that PD activities in Gemini X are all distributed at a

positive half cycle and that in FR3 are distributed in both positive and negative half cycles.

(a) Gemini X PD pattern (b) FR3 PD pattern

Figure 4.7 PD Patterns of Gemini X (60 Minutes PD signals from the 3000 pC Test) and FR3 (1

Minute PD signals from 3000 pC Test 1)

92

The difference of PD patterns between both oils leads to the different energy distribution as

shown in Table 4.3.

Table 4.3 PD Energy and Distribution for each Test inside Gemini X/ FR3

Oil Test Power(mW) Duration

(mins) Energy(J)

below

1000

pC

1000-

2000

pC

2000-

3000

pC

3000-

4000

pC

4000-

5000

pC

5000-

6000

pC

Gemin

i x

1500 pC 0.02 2880 3.21 77.95

%

22.05

%

2000 pC 0.07 1380 5.61 26.69

%

73.22

% 0.09%

3000 pC 0.03 2580 5.05 10.85

%

86.09

% 3.03% 0.02%

4000 pC 0.13 1290 10.44 12.41

%

46.99

%

40.01

% 0.59% 0.05%

FR3

1000 pC-

1 0.32 390 7.41

85.54

%

14.46

%

1000 pC-

2 0.16 360 3.53

88.59

%

11.41

%

2000 pC-

1 0.65 180 7.04

46.93

%

52.65

% 0.42%

2000 pC-

2 0.83 235 11.76

51.58

%

48.03

% 0.39%

3000 pC-

1 6.13 70 25.74

70.31

%

19.00

%

10.34

% 0.35%

3000 pC-

2 3.35 150 30.14

74.88

%

14.57

% 9.83% 0.71%

3000 pC-

3 5.82 70 24.43

65.89

%

25.70

% 8.11% 0.30%

4000 pC 7.34 62 27.29 64.74

%

21.35

% 9.21% 4.57% 0.11% 0.02%

Table 4.3 shows that the PD power is not only related to the PD amplitude but also linked to

the PD repetition rate. For example, the Gemini X 2000 pC test had a 0.07mW power while

the Gemini X 3000 pC only had a 0.03mW power for the reason that the PD repetition rate in

Gemini X 2000 pC test was much higher than that of the Gemini X 3000 pC test. It can also be

seen that PD energy distribution in Gemini X is mainly concentrated in the middle range of the

PD activities while that of the FR3 is mainly contributed by the low energy PDs located in the

negative half cycle. The different energy distributions for both liquids require PD power to be

the characteristic parameter to be corresponding to the total gas generation rather than PD

amplitude or the PD number.

93

4.6.3 Gas generation rate (per J)

After the PD energy considered, the gas generation rates (per J) of Gemini X and FR3 are

compared in Figure 4.8 (2000 pC tests), Figure 4.9 (3000 pC tests) and Figure 4.10 (4000 pC

tests).

Figure 4.8 shows the gas generation rate (per J) plot under 2000 pC PD tests. It can be seen

that the total gas generation rate (per J) of FR3 test is 7.7 ppm/J and is only 10% higher than

that of Gemini X, which is 6.6 ppm/J. H2 (4 ppm/J) and CO (1 ppm/J) in FR3 are 30% higher

than that of Gemini X which are 3.1 ppm/J and 0.7 ppm/J respectively. The gas generation

rates of C2H2 in both liquids are almost the same which is 1.9 ppm/ J. Other hydrocarbons in

both liquids are all below 10% of the total gas generation which are not significant.

Consequently, the H2 and C2H2 are the key indicators for the 2000 pC PD test of both Gemini

X and FR3.

Figure 4.8 GIT Generation rate (per J) Comparison between 2000 pC Tests of Gemini X and

FR3

Figure 4.9 shows the gas generation rate (per J) plot under 3000 pC PD tests. It can be seen

that total gas generation rate (per J) of the FR3 test is 9 ppm/J and is about 10% lower than that

of Gemini X which is 10.5 ppm/J. As in the 2000 pC PD tests, H2 (5.9 ppm/J) and CO (1

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

Mineral oil 0.0 1.9 0.0 3.1 0.5 0.7 6.6

FR3 0.3 1.9 0.3 4.0 0.3 1.0 7.7

ppm/ J

94

ppm/J) in FR3 are slightly higher than that of Gemini X which are 5 ppm/J and 0.7 ppm/J

respectively. The gas generation rate of C2H2 in Gemini X is 2.5 ppm/J and is twice that in

FR3 which is 1.3ppm/J. Other hydrocarbons in both liquids are still all below 10% of total gas

generation. Consequently, the H2 and C2H2 are the key indicators for the 3000 pC PD test of

both Gemini X and FR3.

Figure 4.9 GIT Generation rate (per J) Comparison between 3000 pC Tests of Gemini X and

FR3

Figure 4.10 shows the amount of gas generation rate (per J) for both Gemini X and FR3 under

4000 pC PD tests. It can be seen that the total gas generation rate (per J) of the FR3 test is 10.8

ppm/J and is about 7% lower than that of Gemini X which is 11.6 ppm/J. Similar as that in the

2000 pC PD tests and the 3000 pC PD tests, H2 (7 ppm/J) in FR3 are 8% higher than that of

Gemini X (6.6 ppm/J). GIT of CO in FR3 (1.3 ppm/J) is 3 times as that in Gemini X (0.4

ppm/J). respectively. The gas generation rate of C2H2 in Gemini X is 2.5 ppm/J and is about

twice as that of FR3 which is 1.4 ppm/J. Other hydrocarbons in both liquids are all below 10%

of total gas generation.

0.0

2.0

4.0

6.0

8.0

10.0

12.0

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

Mineral oil 0.5 2.5 0.7 5.0 1.1 0.7 10.5

FR3 0.4 1.3 0.1 5.9 0.3 1.0 9.0

ppm/ J

95

Figure 4.10 GIT gas Generation rate (per J) Comparison between 4000 pC Tests of Gemini X

and FR3

Accordingly, for all PD tests under different PD amplitudes, the amounts of gas generation rate

(per J) of both oils are comparable. The gas generation rates increase slightly from around 7

ppm/J to around 11 ppm/J as the PD amplitude increases from 2000 pC to 4000 pC. This

phenomenon shows that those PD with large amplitudes actually contribute more to the total

gas generation. The gas generation rates of H2 and CO in FR3 are always slightly higher than

that in Gemini X. On the other hand, the gas generation rates of C2H2 in Gemini X tests are

always higher than those in FR3. H2 and C2H2 are the key indicators for PD fault in both

Gemini X and FR3. H2 is significant in FR3 when PD amplitude is high enough (4000 pC).

4.6.4 Absolute Gas generation rate (per J)

The gas generation rate in Section 4.6.3 is quite low in the unit of ppm/J because the oil volume

of the test system is 2.57 L. The absolute gas generation rate in the unit of μl/J can be seen in

Table 4.4. It can be seen from Table 4.4 that the gas generation rate of the high energy PD test

can reach 20 μl/J (when PD amplitudes > 1500 pC). These results are quite comparable with

those of the sparking tests in Chapter 3.

96

Table 4.4 Absolute GIT Generation Rate (μl/J)

Test GIT (μl/J)

FR3 C2H4 C2H2 C2H6 H2 CH4 CO TDCG

1000 pC 0.00 0.00 0.38 4.10 0.00 1.68 6.17

2000 pC 0.74 4.93 0.65 10.22 0.66 2.70 19.89

3000 pC 0.98 3.39 0.25 15.15 0.86 2.61 23.24

4000 pC 1.30 3.55 0.59 18.04 0.95 3.29 27.73

Test GIT(μl/J)

Mineral oil C2H4 C2H2 C2H6 H2 CH4 CO TDCG

1500 pC 0.00 5.08 1.33 4.06 0.00 3.12 13.59

2000 pC 0.00 4.79 0.00 7.88 1.18 1.84 15.69

3000 pC 1.26 6.53 1.76 12.93 2.93 1.83 27.24

4000 pC 1.63 6.31 1.16 16.85 3.00 0.90 29.84

4.6.5 Duval Triangle Analysis

All the DGA data from PD tests need to be calculated into GIO value before the Duval triangle

method applied. The GIO concentration are calculated based on Equation (3.1) and shown in

table 4.5.

97

Table 4.5 GIO Generation Rate (ppm/J)

Test GIO (ppm/J)

Mineral oil C2H4 C2H2 C2H6 H2 CH4 CO TDCG

1500 pC 0 1.9 0.5 0.9 0 1 4.3

Duval ratio 0.00% 100.00% 0.00%

2000 pC 0.1 0.3 0 0.7 0 0.2 1.4

Duval ratio 11.70% 77.90% 10.40%

3000 pC 0.5 2.5 0.7 3 1.1 0.6 8.2

Duval ratio 12.00% 61.70% 26.30%

4000 pC 0.6 2.4 0.4 3.9 1.1 0.3 8.7

Duval ratio 15.20% 58.40% 26.40%

Test GIO (ppm/J)

FR3 C2H4 C2H2 C2H6 H2 CH4 CO TDCG

1000 pC 0 0 0.1 1.6 0 0.7 2.4

Duval ratio 0.00% 0.00% 0.00%

2000 pC 0.3 1.9 0.3 4 0.3 1 7.7

Duval ratio 11.70% 77.90% 10.40%

3000 pC 0.4 1.3 0.1 5.9 0.3 1 9

Duval ratio 18.70% 64.90% 16.40%

4000 pC 0.5 1.4 0.2 7 0.4 1.3 10.8

Duval ratio 22.50% 61.20% 16.40%

The Duval triangle method can then be applied as shown in Figure 4.11. It can be seen that PD

faults in Gemini X and FR3 all move from D1 towards D2 area as PD amplitudes increase from

2000 pC to 4000 pC which indicate the fault severity increases as the PD amplitude grows.

Meanwhile, the FR3 plots are all located in the revised D1 area (low energy discharge area),

which conform to the Duval’s new triangle quite well. It should be noted that the 1000 pC FR3

test results is not plotted due to low gases levels.

98

(a) Gemini X tests (b) FR3 tests

Figure 4.11 Duval Triangle Evaluations for Gemini X and FR3 PD Tests

It could be seen from Table 4.5 that C2H4 and CH4 are 0 ppm/J in 1000 pC PD test inside FR3

and 1500 pC PD test inside Gemini X. The low GIO concentration does not allow the

application of Duval triangle.

4.6.6 Laboratory DGA and Online Monitor Comparison

After the test, some of the oil samples were sent to TJH2B analytical laboratory for DGA

analysis as a comparison to the result of TM8 online monitor. Table 4.6 shows an example of

the DGA comparison between TM8 and the analytical laboratory.

Table 4.6 Comparison of GIO DGA Results between TM8 and Laboratory

Oil type GIO(ppm)

Mineral oil C2H4 C2H2 C2H6 H2 O2 CH4 CO

TM8 sample 12 41 12 46 18118 23 9

Laboratory

sample 1 17 44 10 58 20819 24 10

Laboratory

sample2 13 27 7 57 20206 19 9

Laboratory

average 15 36 9 58 20513 22 10

Laboratory / TM8 125.35% 86.98% 71.07% 124.14% 113.22% 91.55% 105.69%

99

The Gemini X oil sample was taken after 23 hours 2000 pC PD fault and 21.5 hours 4000 pC

PD fault. The oil sample is analyzed by TM8 with the headspace method before the sample

collection. The laboratory result was obtained 7 days later. Table 4.6 indicates that for most

fault gases, the laboratory results and monitor results agree with each other within a deviation

of 30%.

4.7 Summary

In this chapter, the amount of fault gases in FR3 and Gemini X tests were measured using a

sealed test system with an online DGA monitor. The main summaries are drawn as follows:

1. At the same PD amplitude, the higher PD repetition rate in FR3 than that in Gemini X

leads to a much higher PD energy in FR3 for a given period of time.

2. The gas generation rate (per J) in FR3 is slightly higher than that in Gemini X.

3. For each liquid, the gas generation rates (per J) are similar to each other, and increase

slightly for increased PD amplitudes. This indicates that: The total gas generations under

PD faults are determined by energy instead of PD amplitude or PD numbers only; a PD

with higher energy contributes more to the total gas generation.

4. The PD faults in FR3 can be recognized correctly as low energy discharge from the

adjusted Duval triangle method.

5. The TM8 online monitor result using the headspace method is comparable with the

laboratory DGA analysis result by the Toepler pump method with a maximum of 30%

deviation.

100

101

Chapter 5 Experimental Study on DGA under Thermal Fault

5.1 Introduction

In order to apply the standard method for mineral oil to alternative natural esters, the gas

performances of a mineral oil, Gemini X, and a natural ester, FR3, are studied in this chapter

under thermal faults, simulating the hot-spot thermal faults in power transformers. A special

designed test vessel with a good sealing capability was used in this study, and “W” shaped

copper wires were used as the heating elements to produce high temperatures. To achieve more

confident DGA results, the fault gases were measured by an online TM8 DGA monitor as well

as the laboratory DGA method by sending some oil samples to TJH2B for laboratory analysis.

5.2 Experiment Setup

5.2.1 Test Circuit Design

The experimental circuit is shown in Figure 5.1. A variable voltage controller (Variac) was

used to control the voltage applied to a 45A/ 3000A load transformer, which was used as the

current source in the test. The high current was fed into the test vessel by a 700A cable, and a

“W” shaped copper bar is used as the heating element in the test vessel. The inlet and outlet of

the test vessel connected with an on-line TM8 DGA monitor, providing a sealing path for the

oil circulation. During the test, the high current went through the heating element was measured

by a clamp-type current meter (measurement range up to 1200 A), and the temperature of the

copper heating element was measured by three K type thermocouples.

102

Figure 5.1 CIrcuit Diagram of Hot-Spot Thermal Test Circuit

5.2.2 Test Vessel Design

Figure 5.2 shows the schematic design of the test vessel used in the experiment. The cylinder

shaped vessel is made of transparent Perspex, and the heating element is made of a ‘W’ shaped

copper wire. When fault gases are generated, the gases are collected by the 20-degree-slope

cavity at the top of the test vessel. Then, the gases are carried by the oil circulation in a 1–

meter-long silicon pipe, connecting the test vessel with a 3-phase outlet adapter. One outlet of

the adapter is connected with a 50 ml syringe, and the other outlet is connected with a TM8

monitor. When the test vessel is fully filled, the overall volume of oil in the circulation system

is about 2.73 L.

103

(a) Schematic design (b) Photo

Figure 5.2 Test Vessel Design

Compared with the previous studies [11], such a design provides several advantages. Firstly,

by carefully using rubber gaskets in each joint, the vessel has an excellent sealing capability.

Secondly, by using the 20-degree-slope cavity at the top, the test vessel provides a complete

oil circulation and ensures the collection of all the fault gases generated in the tests. Finally, by

using the syringe assists the removal of headspace before the tests and the collection of large

gas bubbles during the tests and push-back fault gases into oil circulation after the tests.

Furthermore, the pressure inside and outside the test vessel could also be balanced by the

syringe.

5.3 Test Procedure

In order to better compare the gas performances of Gemini X and FR3 under thermal faults,

the test procedure is strictly followed for both oils, as shown below.

Process transformer oil, as described in Chapter 2.

Drain oil out of the system.

104

Clean test system, fill processed oil into the system (eliminate the headspace). (Chapter

3.3)

Measure the background gases.

Generate thermal faults.

Push fault gases back into the oil circulation, and measure the amounts of fault gases.

Data processing and analysis.

5.3.1 Generate Thermal Faults

During the test, the fault current is increased as follows. Firstly, the current needs to be raised

at the rate of 30 A/s when the current is below 300 A. After the current reaches 300 A, the

temperature rising rate will be reduced even when the same voltage raising speed is applied

because the resistor of the thermocouple increased significantly. As a result, the voltage rising

speed must be slowed down in case the heating element melts down.

In high temperature thermal tests (thermocouple displayed fault temperature > 300 ºC), the

difference between the thermocouple displayed temperature and the hotspot temperature gets

larger as the resistor of the hotspot gets much higher than the other part of the copper heating

element. Consequently, the thermal fault heating period needs to be counted after the

thermocouple display temperature reaches 80% of the aimed temperature. The voltage, the

current and the heating period need to be recorded for further calculation. The GIG data needs

to be measured by the TM8 online monitor immediately after the test is finished.

5.4 Measurement Methods

5.4.1 Temperature Measurement Method

During the tests, the temperature of the heating element is measured by thermocouples, and the

so-called ‘insertion method’ is used to provide a more reliable measurement result. Figure 5.3

shows the configuration of such method, using three thermocouples and a copper wire (heating

element).

105

Figure 5.3 Thermocouples and Heating Element Configuration

The heating element was bent into a ‘W’ shape, and 3 holes were drilled at each corner of the

heating element, with 10 mm in depth and 0.5 mm in diameter. The thermocouples with 0.5

mm in diameter were inserted into these holes.

Such a design ensures that the thermocouples are in good contact with the heating element,

thus the measurement result is close to the actual hot spot temperature. This is evidenced by a

verification test in air, that the measured temperature reached 900 ºC when the heating element

melted (1100 ºC), which indicated a measurement error of only 22%. In this chapter, the

average of the three thermocouple recordings is reported as the final measured temperature.

5.4.2 Heating & Cooling Method

When the fault temperature is above 300 ºC, a significant amount of fault gases is produced in

a short duration. Thus no special method needs to be performed to control the fault temperature.

106

However for a thermal fault with temperature less than 300 ºC, the gas generation rate is so

slow that it may take several hours to generate a measurable amount of fault gases. During this

period, the temperature of the bulk oil will be gradually increased. Since the oil temperature

limitation of the TM8 monitor is 50 ºC, the maximum temperature of the bulk oil should be

controlled. Therefore, a special heating and cooling procedure was applied as shown in Figure

5.4.

Figure 5.4 Heating and Cooling Procedure

The procedure includes the following three steps: the temperature raising period, the heating

period and the cooling period. In the temperature raising period, the current gradually increases

until the fault temperature reaches the aimed temperature. During the heating period, the

current is kept the same until the bulk oil temperature reaches 50 ºC or the oil expands by a

volume of 50 ml. In the cooling period, the current is quickly reduced to zero and the

temperature gradually cools down to the environmental temperature. The three steps are

repeated until enough fault gases are produced.

Taking 300 ºC thermal fault for FR3 as an example, the fault temperature increased from room

temperature to 300 ºC in about 30 seconds in the temperature raising period. Afterwards in the

heating period, the current was kept stable and lasted for 30 minutes, during which time the

fault temperature stayed 300 ºC and the oil temperature increased to 50 ºC. Finally, the current

supply was stopped and the oil was cooled down for 20 minutes until the temperature was

107

reduced to room temperature. The procedure was repeated six times until enough gases were

detected.

5.5 Test Conditions and Observations

Table 5.1 lists the thermal test conditions and observations for all thermal tests. For each liquid,

4 tests with different fault temperatures were carried out. For FR3, the test temperatures were

measured between 300 °C and 600 °C; but for Gemini X, the maximum measured temperature

was 400°C. In test 3 and 4 for Gemini X, the temperature measured by thermocouple was even

less than 400°C when the heating element melted down, which indicated that the fault

temperatures were 1100 °C, Therefore, the test 3 and 4 for Gemini X are named as apparent

400°C A and apparent 400°C B, indicating the fault temperatures were much higher than 400°C.

Table 5.1 Thermal Test Conditions and Observations

Test temperature

(°C)

Total

heating

time

(min)

Voltage Current Input

power

Free

gas

evolved

(ml)

Diameter

of

heating

element

Heating

element

melted? (V) (A) (W) (mm)

Gemini

X

1 300 60 0.4 261 104 5.5 1.9 N

2 400 5 1.3 600 780 10 1.9 N

3 apparent

400 A 16(s) 2 510 1020 0 1.5 Y

4 apparent

400 B 50(s) 1.3 600 780 30 1.9 N

FR3

1 300 270 0.4 260 104 0 1.9 N

2 400 270 0.6 310 186 2 1.9 N

3 500 50 1.7 424 721 27 1.5 N

4 600 3 2.9 554 1607 17 1.5 N

* Apparent 400 A and 400 B: during the test, the displayed temperature is 400 ºC; however the

real temperature should be higher than 400 ºC, due to a melting element (A) or a high

generation rate of fault gases (B).

5.6 Test Result and Analysis

108

5.6.1 Thermal Fault Gas Generation

The generation rate of fault gases under thermal faults for Gemini X and FR3 tests are

summarized in Figure 5.5 (a) and 5.5 (b) respectively. It was observed that the generation rate

of fault gases for Gemini X is much higher than FR3 under thermal faults. Therefore, the

generation rate of FR3 is plotted in the unit of ppm per hour while that of Gemini X is plotted

in the unit of ppm per minute.

In Figure 5.5 (a), it can be seen that the fault gas generation rate is increased with the increase

of the fault temperature for Gemini X. It also shows that the CH4 and C2H4 take up the most

part of the total fault gases. Under 300 º C thermal faults, CH4 takes up 43% of the total fault

gases. Under 400 ºC thermal fault, CH4 and C2H4 take up 66% of the total fault gases. When

the temperature is further increased, the percentage of CH4 and C2H4 increased to 77% for both

400 ºC A and apparent 400 ºC B tests. This indicates that CH4 and C2H4 are the key gases of

high-temperature thermal faults in Gemini X.

Similar conclusions can be drawn from Figure 5.5 (b) for FR3, that the fault gas generation

rate is increased with the increase of the fault temperature. However, different with the result

in Gemini X, CO and C2H6 play the most important role in FR3, taking up to 29.3% and 28.0%

of total gas generation separately, followed by CH4 and C2H4, which only contribute less

important part in total gas generation which varies from 40.5% to 45.6%. It should be noted

that CO and C2H6 always takes up more than 25% of total fault gases for all temperatures in

FR3, which indicates that the key gases of high-temperature thermal faults in FR3 are CO and

C2H6 followed by CH4 and C2H4. The reason that carbon monoxide produced in FR3 in such

a larger amount than that in Gemini X might be attributed to the oxygen atoms contained in the

ester part of FR3 molecules.

109

(a) Fault gases generation rate in Gemini X

(b) Fault gases generation rate in FR3

Figure 5.5 GIT Generation Rate of Fault Gases in Gemini X and FR3

5.6.2 Gas Generation Rate Comparison under Different Temperatures

The comparison between the generation rate of Gemini X and FR3 is shown in Figure 5.6(a),

Figure 5.6(b) and Figure 5.6(c) for different temperatures.

In Figure 5.6 (a), the gas generation rate of FR3 is twice that of Gemini X under the 300 ºC

thermal fault. However in Figure 5.6 (b), the gas generation rate of Gemini X under 400 ºC is

20 times higher than that of FR3. Even when the results of Gemini X under 400 ºC fault and

that of FR3 under 500 ºC fault are compared, the gas generation rate of Gemini X is still 5

times higher. This further proves that the gas generation rate of FR3 is much lower than Gemini

X, and FR3 is more thermally stable than Gemini X under the high temperature thermal fault.

1.0

10.0

100.0

1000.0

10000.0

100000.0

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

300C-104W 0.0 0.0 0.0 0.0 0.6 0.8 1.4

400C-780W 109.4 0.4 23.1 68.2 114.2 23.6 338.8

apparent 400C A 179.9 14.2 26.7 48.8 135.7 6.1 411.6

apparent 400C B 8295.3 89.3 1324.7 2952.2 6064.0 37.2 18762.6

ppm/ min

1.0

10.0

100.0

1000.0

10000.0

100000.0

C2H4 C2H2 C2H6 H2 CH4 CO TDCG

300 C-104W 1.6 0.3 54.8 7.3 17.3 95.7 176.9

400 C-186W 15.7 0.7 213.0 75.3 47.1 294.5 646.4

500 C-721W 312.7 0.5 1598.2 148.0 311.0 1577.6 3947.9

600 C -1607W 6470.6 27.6 7327.8 994.3 3711.2 7671.7 26203.2

ppm/h

110

(a) GIT generation rate comparisons between Gemini X and FR3 under 300 ºC thermal fault

(b) GIT generation rate comparisons between Gemini X and FR3 under 400 ºC thermal fault

(c) Comparison of GIT generation rate between Gemini X under 400 ºC faults and FR3 under 500 º

C thermal faults

Figure 5.6 GIT Generation Rate Comparisons between Gemini X and FR3

111

5.6.3 Duval Triangle Analysis

Since the Duval Triangle method recognizes the fault type by GIO concentration. The GIG

concentration is calculated to GIO concentration by Equation (3.1). The calculated GIO results

are listed in Table 5.2.

Table 5.2 GIO Generation Rate (ppm/J)

Mineral oil GIO (ppm)

C2H4 C2H2 C2H6 H2 CH4 CO

300 ºC 0 0 0 0 0.6 0.7

Duval ratio 0.40% 1.40% 98.20%

400 ºC 532.7 1.7 113.6 210.4 521.5 90.6

Duval ratio 50.50% 0.20% 49.40%

400 ºC A 47 3.7 7 8 33.6 1.3

Duval ratio 55.80% 4.40% 39.80%

400 ºC B 6716.6 71.6 1085.3 1292.8 4539.5 5.2

Duval ratio 59.30% 0.60% 40.10%

FR3 GIO (ppm)

C2H4 C2H2 C2H6 H2 CH4 CO

300 ºC 2.4 0.4 81 7.2 24.1 115.3

Duval ratio 8.80% 1.40% 89.70%

400 ºC 23.8 0.8 328.8 75.5 66.4 361.5

Duval ratio 26.20% 0.90% 73.00%

500 ºC 5 0 25.3 1.5 4.6 19.5

Duval ratio 52.00% 0.00% 48.00%

600 ºC 107 0.5 121.5 13.5 59.5 116.4

Duval ratio 64.10% 0.30% 35.60%

The test results of Gemini X and FR3 could then be plotted in the Duval triangles as shown in

Figure 5.7 (a) and (b).

112

(a) Duval triangle evaluation of Gemini X tests

(b) Duval triangle evaluation of FR3 tests

Figure 5.7 Duval Triangle Evaluation of Gemini X and FR3 Thermal Fault

For Gemini X, the thermal faults at different temperatures are recognized correctly by the

Duval triangle method in Figure 5.7 (a). The results also verify the assumption that the actual

temperature of the apparent 400 ºC A and apparent 400 ºC B tests are higher than the 400 ºC

test. For FR3, most thermal faults (300 ºC, 500 ºC and 600 ºC) are recognized correctly by the

revised Duval Triangle method. However, the 400 ºC thermal fault is recognized as a thermal

fault below 300 ºC. This might be caused by the excellent sealing state of the oil circulation

system, which leads to a higher CH4 percentage among the three indicated gases.

113

5.6.4 Laboratory DGA and Online Monitor Comparison

To make sure the results from TM8 are reliable, some of the oil samples are also sent to TJH2B

analytical laboratory for DGA analysis as a comparison. Table 5.3 shows an example of the

DGA comparison between TM8 and analytical laboratory. After the apparent 400 ºC test for

FR3, which lasts for 5 minutes, the oil sample is collected and sent to TJH2b. The oil sample

is analyzed immediately after the test is finished by TM8 with the headspace method and 8

hours later in the laboratory by the Toepler pump method. Table 5.3 indicates that the

laboratory results and online monitor results agree with each other with a 30% deviation. On

the other hand, the O2 result from the laboratory is 70% higher than that from TM8 which

indicates a leakage could have occurred during the sample transportation.

Table 5.3 Comparison of GIO DGA Results between TM8 and Laboratory Analysis

Oil type GIO (ppm)

Mineral oil C2H4 C2H2 C2H6 H2 O2 CH4 CO

TM8 sample 6149.45 58.56 1060.74 945.86 14751.58 2956.23 186.84

Laboratory sample 1 6798 67 961 928 29506 4033 99

Laboratory sample2 5889 55 836 924 20823 3614 77

Laboratory average 6343.5 61 898.5 926 25164.5 3823.5 88

Laboratory / TM8 103.16% 104.17% 84.70% 97.90% 170.59% 129.34% 47.10%

5.7 Summary

In this chapter, the total gas generation in FR3 and mineral oil are measured with a proper

sealed with an online DGA monitor test system.

The main summaries that can be drawn are:

1. The generation rates of fault gases are mainly determined by the hotspot temperature rather

than the average temperature.

114

2. FR3 generates less amount of fault gases than Gemini X at higher temperatures (>300 ºC).

This indicates that FR3 is more thermally stable than Gemini X.

3. The key indicator gases for thermal faults in Gemini X are CH4 and C2H4; while those for

FR3 also include CO and C2H6.

4. The Duval triangle method can recognize all thermals fault in Gemini X while a little

revision should be made for the Duval triangle method in order to recognize the thermal

faults in FR3 (most of the FR3 results fit the revised Duval triangle method).

5. TM8 online monitor result is comparable with laboratory analysis by the Toepler pump

method.

115

Chapter 6 Conclusions and Future Work

6.1 Conclusions

6.1.1 Research Areas

This thesis focuses on the differences of gas performance between traditional mineral oil,

Gemini X and vegetable oil based insulating liquid, FR3 under fault conditions, including the

electrical sparking fault, the electrical PD fault and the hotspot thermal fault. Through

experimental studies and data analysis, the objectives of this research have been fulfilled.

In this thesis, the main areas of research covered are:

DGA under sparking faults

Test cell design for electrical tests

Test procedure for DGA measurements under the sparking fault

Sparking energy measurement and calculation method

Differences of gas performance between the mineral oil and the natural ester under

the sparking fault

DGA under PD faults

Test procedure for DGA measurement under the PD fault

Differences of gas performance between the mineral oil and the natural ester under

the PD fault

DGA under thermal faults

Test cell design for thermal tests

Test procedure for DGA measurement under the hotspot thermal fault

Fault temperature measurement method

Differences of gas performance between the mineral oil and the natural ester under

the thermal fault

116

6.1.2 Main Findings

Through experimental studies, this thesis obtained useful results on the DGA fingerprints of

FR3 under the electrical sparking faults, the PD faults and the thermal faults. The main findings

are summarized below:

Under electrical sparking faults:

FR3 generates the amount of fault gases similar to Gemini X.

Considering the sparking energy, FR3 generates fault gases (per J) 25% higher than

Gemini X.

The fault gas generation rate (per J) might be a more reasonable parameter to evaluate

the gas performances of different liquids.

The Duval triangle method can recognize these sparking faults as low energy

discharges for both liquids.

Under electrical PD faults:

At the same amplitude, the higher PD repetition rate of FR3 leads to a much higher

PD energy in FR3 than that in Gemini X for a given period of time.

The gas generation rate (per J) in FR3 is slightly higher than that in Gemini X.

For each liquid, the gas generation rate (per J) increases for PDs with higher

amplitudes.

The PD faults in FR3 can be recognized correctly as low energy discharge from the

adjusted Duval triangle method.

Total gas generation under PD faults is determined by the overall PD energy instead

of either PD amplitude or PD number, and PDs with higher energy contribute more to

the total gas generation.

Under hotspot thermal faults:

The generation rates of fault gases are mainly determined by the hotspot temperature.

FR3 generates less fault gases than Gemini X at higher temperatures (>300 ºC). This

indicates that FR3 is more thermally stable than Gemini X.

117

The key gases for thermal faults in Gemini X are CH4 and C2H4; while those for FR3

also include CO and C2H6.

The Duval triangle method can recognize correctly all thermals fault in Gemini X,

while slight revision should be made for the Duval triangle method in order to

recognize the thermal faults in FR3.

The DGA result obtained using TM8 online monitor is comparable with the laboratory

analysis within a deviation of 30% under the electrical sparking faults, the PD faults and

the thermal faults.

6.2 Future Work

This thesis conducts studies concerning the gas performances of two transformer liquids

under both the electrical and the thermal faults. The results show that the gas performances

of a traditional mineral oil (Gemini X) and an alternative natural ester (FR3) are different.

During the studies, some new questions were found and therefore further studies are

required.

For the electrical PD test, further work can be carried out according to the following

suggestion:

The low amplitude PD fault (PD amplitude <1000 pC) was not studied in this thesis

because the gas generation rate is too small. In order to obtain measurable fault

gases, the test duration needs to be extended to more than 4 days. Consequently,

the sealing state of the system needs to be further improved to provide no or less

gas leakage for the PD test.

For the hotspot thermal test, further work can be carried out according to the following

suggestions:

A more accurate temperature measurement method is needed to help the

investigation.

The Resistherm used in [12] might be a good alternative to the copper heating

element, in order to evaluate the thermal fault using average temperature.

118

A thermal camera could be used to film and measure the thermal distribution

along the heating element. However, the way to deal with the blockage of test

vessel need to be further studied.

Some insulation paper could be wrapped on the heating element to simulate

the paper wrapped windings in power transformers.

119

Reference [1] I. U. Khan, Z.D. Wang, I. Cotton, and S. Northcote, "Dissolved gas analysis of alternative

fluids for power transformers”, Electrical Insulation Magazine, IEEE, vol. 23, pp. 5-14,

2007.

[2] C. Perrier and A. Beroual, “Experimental investigations on insulating liquids for power

transformers: mineral, ester, and silicone oils”, Electrical Insulation Magazine, IEEE, Vol.

25, 2009.

[3] EPRI, ”EPRI Report 1000438: Environmentally acceptable transformer fluids; Phase 1

state of the art review; Phase 2 Laboratory testing of fluids”, Palo Alto, CA, Nov. 2000.

[4] K. Rapp, and P. Stenborg, “Cooper Power Systems field analysis of Envirotemp FR3 fluid

in sealed versus free-breathing transformers”, CP0414, Cooper Power Systems, Waukesha,

WI, 2004.

[5] D. Martin, I. U. Khan, J. Dai, and Z.D. Wang, “An overview of the suitability of vegetable

oil dielectrics for use in large power transformers”, in Proc. 5th Annual Euro TechCon,

Chester, United Kingdom, November 28–30, 2006.

[6] M. Duval, "A review of faults detectable by gas-in-oil analysis in transformers”, Electrical

Insulation Magazine, IEEE, vol. 18, pp. 8-17, 2002.

[7] IEC, "IEC60599: Mineral oil-impregnated electrical equipment in service-guide to the

interpretation of dissolved and free gases analysis”, 1999.

[8] IEEE, "IEEE Std C57.104-IEEE guide for the interpretation of gases generated in oil-

immersed transformers”, 2008.

[9] M. Duval and A. de Pablo, “Interpretation of gas-in-oil analysis using new IEC Publication

60599 and IEC TC10 databases”, IEEE Electr. Insul. Mag., vol. 17, no. 2, pp. 31–41, 2001.

[10] X. Wang, “Partial discharge behaviors and breakdown mechanisms of ester transformer

liquids under AC stress”, in Department of Electrical and Electronic Engineering,

University of Manchester, 2011.

[11] U. K. Imad, “Assessment of the performance of ester based oils in transformers under the

application of thermal and electrical stress”, in Department of Electrical and Electronic

Engineering, University of Manchester, 2009.

120

[12] M. Jovalekic, D. Vukovic and S. Tenbohlen, “Dissolved gas analysis of alternative

dielectric fluids under thermal and electrical stress”, in 2011 IEEE International

Conference on Dielectric Liquids, 2011.

[13] D. Hanson, J. Luksich, K. Li, A. Lemm and J. Plascencia, “Understanding dissolved gas

analysis of ester fluids – Part 1: “stray” gas production under normal operating conditions”,

Siemens Transformer Conference, 2010.

[14] C.C. Claiborne, D. Hanson, D.B. Cherry and G.K. Frimpong, “Understanding dissolved

gas analysis – Part 2: Thermal decomposition of ester fluids”, in 2011 Euro TechCon,

Warwick, UK, 2011.

[15] M. Jovalekic, D. Vukovic and S. Tenbohlen, ”Dissolved gas analysis of natural ester fluids

under electrical and thermal stress”, in 2011 IEEE International Conference on Dielectric

Liquids, 2011.

[16] M. Duval, “The Duval Triangle for load tap changers, non-Mineral oils and low

temperature faults in transformers”, IEEE Electrical Insulation Magazine, vol. 24, pp. 22-

29, 2008.

[17] Severon, “Serveron® TM8™ online transformer monitor”, Retrieved 1st July 2011, from

http://www.bplglobal.net/eng/knowledge-center/download.aspx?id=398.

[18] www.nynas.com, “Product data sheet – Nytro Gemini X”, 2008.

[19] X. Wang and Z.D. Wang, “Particle Effect on Breakdown Voltage of Mineral and Ester

Based Transformer Oils”, in 2008 Conference on Electrical Insulation and Dielectric

Phenomena, Quebec, Canada, 2008, pp. 598-602.

[20] www.nynas.com, “Base oil handbook”, Sweden, 2001,

[21] Cooper power system, “Envirotemp™ FR3™ dielectric fluid”, retrieved 1st July 2011,

from http://www.cargill.com/products/industrial/dielectric-fluid/index.jsp.

[22] Cooper Power Systems, "Medium and large power transformer users list Envirotemp

FR3 fluid", Retrieved 17th August 2011, from

http://www.cooperindustries.com/content/public/en/power_systems/products/dielectric_f

luid/envirotemp_fr3_fluid.resources.html, 2011.

[23] D. Martin, "Evaluation of the dielectric capability of ester based oils for power

transformers", in Department of Electrical Engineering and Electronics, University of

Manchester, 2007, p. 225.

121

[24] Cooper power system, "Envirotemp FR3 Fluid - Testing Guide”, Retrieved 1st July 2011,

from:http://www.spxtransformersolutions.com/assets/documents/R900-20-12

FR3testingGuideApril2008 .pdf.

[25] Q. Liu, “Electrical performance of ester liquids under impulse voltage for application in

power transformer”, in Department of Electrical and Electronic Engineering, University

of Manchester, 2011.

[26] G.P. Cleary and M.D. Judd, "UHF and current pulse measurements of partial discharge

activity in mineral oil”, Science, Measurement and Technology, IEE Proceedings -, vol.

153, pp. 47-54, 2006.

[27] R. Patsch, J. Menzel, and D. Benzerouk, "The use of the pulse sequence analysis to monitor

the condition of oil”, in IEEE Conference on electrical insulation and dielectric phenomena,

2006, 2006, pp. 660 - 663.

[28] M. Elborki, N. Jenkins, P. A.Crossley, and Z.D. Wang, "Power transformer PD sources

determination using current signals waveshape and pattern distributions”, in The 15th

International Symposium on Electrical Insulation (ISEI 2004) Indianapolis, Indiana, USA,

September, 2004, pp. 178-181.

[29] Z.D. Wang, S.N. Hettiwatte, and P.A. Crossley, "A measurements-based discharge

location algorithm for plain disc winding power transformers”, IEEE Transactions on

Dielectrics and Electrical Insulation, vol. 12, pp. 416-422, June, 2005.

[30] Y. P. Nerkar, R. N. Narayanachar, and R. S. Nema, "Characterisation of partial discharges

in oil impregnated pressboard insulation systems”, in 11th International Symposium on

High Voltage Engineering, 1999. vol. 3, 1999, pp. 364 - 367.

[31] ASTM D3612, “Standard test method for analysis of gases dissolved in electrical

insulating oil by gas chromatography”, ASTM standard, 2009.

[32] N.A. Muhamad, B.T. Phung, T.R. Blackburn, and K.X. Lai, "Comparative study and

analysis of DGA methods for transformer mineral oil”, in Power Tech, 2007 IEEE

Lausanne, 2007, pp. 45-50.

[33] S.J. Blanksby, G.B. Ellison, “Bond Dissociation Energies of Organic Molecules “, Acc.

Chem. Res. vol. 36, no. 4, pp. 255-263, 2003.

[34] IEC, “IEC 60567: Oil-filled electrical equipment — Sampling of gases and of oil for

analysis of free and dissolved gases — Guidance”, IEC standard, 2005.

122

[35] J. Lapworth, "A novel approach (scoring system) for integrating dissolved gas analysis

results into a life management system”, in Electrical Insulation, 2002. Conference Record

of the 2002 IEEE International Symposium on, 2002, pp. 137-144.

[36] A. Naderian, S. Cress, R. Piercy, F. Wang, and J. Service, "An Approach to Determine the

Health Index of Power Transformers”, in Electrical Insulation, 2008. ISEI 2008.

Conference Record of the 2008 IEEE International Symposium on, 2008, pp. 192-196.

[37] A. Jahromi, R. Piercy, S. Cress, J. Service, and W. Fan, "An approach to power transformer

asset management using health index”, Electrical Insulation Magazine, IEEE, vol. 25, pp.

20-34, 2009.

[38] S. Singh and M. N. Bandyopadhyay, "Dissolved gas analysis technique for incipient fault

diagnosis in power transformers: A bibliographic survey", Electrical Insulation Magazine,

IEEE, vol. 26, pp. 41-46, 2010.

[39] Severon, “Theory of headspace sampling” (for internal use).

[40] Linde AG, “Gas chromatograph”, retrieved 1st July 2011, from http://hiq.linde-

gas.com/international/web/lg/spg/like35lgspg.nsf/docbyalias/anal_gaschrom.

[41] Severon, “TMX training tutorial for users” (for internal use).

[42] Severon, “Serveron White Paper: DGA Diagnostic Methods”, retrieved 1st July 2011, from

http://www.bplglobal.net/eng/knowledge-center/download.aspx?id=217.

[43] RS Components, “RS Arcrylic Based Sealing Compound” retrieved 1st July 2011, from

www.rswww.co.uk.

123

Appendix I. Matlab Code Used In the Thesis

I.1 Sparking Energy Calculation

I.1.1 High Frequency Energy Calculation clear all;clc; startnumber=781; endnumber=865; k=1; header='J:\test data\10-7BD.F\hf\XIAO0'

% FID=fopen(strcat(header,num2str(startnumber),'_',num2str(endnumber))); %

xlswrite(strcat(header,num2str(startnumber),'_',num2str(endnumber)),{'filen

ame','energy'});

for seq=startnumber:endnumber

timedelta=csvread(strcat(header,num2str(seq),'.csv'),5,1,[5 1 5 1]); voltagediv=csvread(strcat(header,num2str(seq),'.csv'),12,1,[12 1 12

1]); currentdiv=csvread(strcat(header,num2str(seq),'.csv'),14,1,[14 1 14

1]); alllecroy=csvread(strcat(header,num2str(seq),'.csv'),30,0); delay=csvread(strcat(header,num2str(seq),'.csv'),4,1,[4 1 4 1]); voltage=alllecroy(:,1); current=alllecroy(:,3);

tt=size(current,1); time=(1:tt)*timedelta;

%fcutoff=15000; % [B,A]=ellip(4,0.5,20,fcutoff*2*timedelta); %[H,w] = freqz(B,A,512); %f = w/(2*pi)/timedelta; %lfcurrent = filter(B,A,current); %subplot(3,1,1); %plot(f,abs(H));hold on;

%subplot(3,1,2); % bar(abs(fft(current))); %ff=fftshift(fft(current)); % ww=linspace(-0.5/timedelta,0.5/timedelta,tt); % plot(ww,abs(ff));

%subplot(3,1,3); %plot(time,current,'b');hold on;plot(time,lfcurrent,'r');

124

%%%%%%%%%%%%%%%%%%%%%% %add you energy calculation segment here, give the final energy value %to the variable 'energy'% if currentdiv==500 noise = 25; end if currentdiv==200 noise =15; end if currentdiv==100 noise =5; end

M=current; N=voltage; SIZE=size(M); SIZ=SIZE(1); for i=1:SIZ if abs (M(i,1)) <noise M(i,1)=0; end end

k=k+1; SIZ=SIZ*1;

g=fix(0.1*SIZ); f=fix(0.2*SIZ); HIGH = 0; for i=g:SIZ HIGH = HIGH + M(i,1) *N(i,1)*timedelta*1000; end

energy=HIGH b=[char(66),num2str(k)]; c=[char(65),num2str(k)];

title(strcat(header,num2str(seq),'fig')); % add title to the figure,

and display the title in the figure saveas(gcf, strcat(header,num2str(seq))); % save the figure with a new

name close all; % close this figure, especially when you are using the 'for'

loop xlswrite('energy_cal.xls',{'BD number','energy'},'HF'); %xlswrite(strcat(header,num2str(seq),'.xls'),lfcurrent,strcat('A2:A',nu %m2str(tt+1)));

%xlswrite(strcat(energy_cal,'.xls'),energy,'LF',a); xlswrite('energy_cal.xls',energy,'HF',b);

xlswrite('energy_cal.xls',cellstr(strcat('XIAO0',num2str(seq))),'HF',c); %xlswrite(strcat(header,num2str(seq),'.xls'),energy,'LF');

end

125

I.1.2 Low Frequency Energy Calculation

I.1.2.1 Normal type sparking energy clear all;clc; startnumber=100; endnumber=; k=1; header='J:\test data\10-7BD.F\lf\WASC0'

% FID=fopen(strcat(header,num2str(startnumber),'_',num2str(endnumber))); %

xlswrite(strcat(header,num2str(startnumber),'_',num2str(endnumber)),{'filen

ame','energy'});

for seq=startnumber:endnumber

timedelta=csvread(strcat(header,num2str(seq),'.csv'),5,1,[5 1 5 1]); voltagediv=csvread(strcat(header,num2str(seq),'.csv'),12,1,[12 1 12

1]); currentdiv=csvread(strcat(header,num2str(seq),'.csv'),13,1,[13 1 13

1]); alllecroy=csvread(strcat(header,num2str(seq),'.csv'),30,0); delay=csvread(strcat(header,num2str(seq),'.csv'),4,1,[4 1 4 1]); voltage=alllecroy(:,1); current=alllecroy(:,2);

tt=size(current,1); time=(1:tt)*timedelta;

fcutoff=15000; [B,A]=ellip(4,0.5,20,fcutoff*2*timedelta); [H,w] = freqz(B,A,512); f = w/(2*pi)/timedelta; lfcurrent = filter(B,A,current); llfcurrent = filter(B,A,lfcurrent);

plot(time,current,'b');hold on;plot(time,llfcurrent,'r');

M=llfcurrent; N=voltage; SIZE=size(M); SIZ=SIZE(1); k=k+1;

126

SIZ=SIZ;

g=fix(0.45*SIZ);ffff=fix(0.65*SIZ); gb=1; ffffb=fix(0.2*SIZ);

LOW = 0; BASE= 0; BASE2 = 0; for i=g:ffff LOW = LOW + M(i,1) *N(i,1)*timedelta*3; end for i=gb:ffffb BASE=BASE+ M(i,1) *N(i,1)*timedelta*3; end for i=300000:400000 BASE2=BASE2+ M(i,1) *N(i,1)*timedelta*3; end

energy=LOW-BASE b=[char(66),num2str(k)]; c=[char(65),num2str(k)];

title(strcat(header,num2str(seq),'fig')); % add title to the figure,

and display the title in the figure saveas(gcf, strcat(header,num2str(seq))); % save the figure with a new

name close all; % close this figure, especially when you are using the 'for'

loop xlswrite('energy_cal.xls',{'after_lowpass_filter','energy'},'LF'); %xlswrite(strcat(header,num2str(seq),'.xls'),lfcurrent,strcat('A2:A',nu %m2str(tt+1)));

%xlswrite(strcat(energy_cal,'.xls'),energy,'LF',a); xlswrite('energy_cal.xls',energy,'LF',b);

xlswrite('energy_cal.xls',cellstr(strcat('WASCO0',num2str(seq))),'LF',c); %xlswrite(strcat(header,num2str(seq),'.xls'),energy,'LF');

end

I.1.2.2 Double type sparking energy

clear all;clc; startnumber=187; endnumber=187; k=1; header='J:\test data\10-15BD.M\lf\WASC0'

127

% FID=fopen(strcat(header,num2str(startnumber),'_',num2str(endnumber))); %

xlswrite(strcat(header,num2str(startnumber),'_',num2str(endnumber)),{'filen

ame','energy'});

for seq=startnumber:endnumber

timedelta=csvread(strcat(header,num2str(seq),'.csv'),5,1,[5 1 5 1]); voltagediv=csvread(strcat(header,num2str(seq),'.csv'),12,1,[12 1 12

1]); currentdiv=csvread(strcat(header,num2str(seq),'.csv'),13,1,[13 1 13

1]); alllecroy=csvread(strcat(header,num2str(seq),'.csv'),30,0); delay=csvread(strcat(header,num2str(seq),'.csv'),4,1,[4 1 4 1]); voltage=alllecroy(:,1); current=alllecroy(:,2);

tt=size(current,1); time=(1:tt)*timedelta;

fcutoff=15000; [B,A]=ellip(4,0.5,20,fcutoff*2*timedelta); [H,w] = freqz(B,A,512); f = w/(2*pi)/timedelta; lfcurrent = filter(B,A,current); llfcurrent = filter(B,A,lfcurrent);

subplot(2,1,1); % plot(f,abs(H));hold on;

plot(time,current,'b');hold on;plot(time,llfcurrent,'r'); subplot(2,1,2); % bar(abs(fft(current))); %ff=fftshift(fft(current)); %ww=linspace(-0.5/timedelta,0.5/timedelta,tt); % plot(ww,abs(ff));

% subplot(3,1,3); plot(time,current,'b');hold on;plot(time,lfcurrent,'r');

%%%%%%%%%%%%%%%%%%%%%% %add you energy calculation segment here, give the final energy value %to the variable 'energy'% M=lfcurrent; N=voltage; SIZE=size(M); SIZ=SIZE(1); k=k+1; SIZ=SIZ;

128

g=fix(0.3*SIZ);ffff=fix(0.7*SIZ); gb=1; ffffb=fix(0.2*SIZ);

LOW = 0; BASE= 0; for i=g:ffff LOW = LOW + M(i,1) *N(i,1)*timedelta*3; end for i=gb:ffffb BASE=BASE+ M(i,1) *N(i,1)*timedelta*3; end for i=170000:370000 BASE2=BASE+ M(i,1) *N(i,1)*timedelta*3; end

energy= LOW-2*BASE b=[char(66),num2str(k)]; c=[char(65),num2str(k)];

title(strcat(header,num2str(seq),'fig')); % add title to the figure,

and display the title in the figure saveas(gcf, strcat(header,num2str(seq))); % save the figure with a new

name close all; % close this figure, especially when you are using the 'for'

loop xlswrite('energy_cal.xls',{'after_lowpass_filter','energy'},'LF'); %xlswrite(strcat(header,num2str(seq),'.xls'),lfcurrent,strcat('A2:A',nu %m2str(tt+1)));

%xlswrite(strcat(energy_cal,'.xls'),energy,'LF',a); xlswrite('energy_cal.xls',energy,'LF',b);

xlswrite('energy_cal.xls',cellstr(strcat('WASCO0',num2str(seq))),'LF',c); %xlswrite(strcat(header,num2str(seq),'.xls'),energy,'LF');

end

I.2 PD Energy Calculation clear all;clc; x='F:\Users\sitao li\Desktop\6-12-2011\filter\58kV-186-1146.txt'; [a b c d]=textread(x,' %f %f %f %f','headerlines',14); % a: period number % b: phase % c: charge % d: voltage

P_number=size(find(b<180));

129

P_number=P_number(1); P_max=max(abs(c(find(b<180)))); N_number=size(find(b>180)); N_number=N_number(1); if N_number>0 N_max=max(abs(c(find(b>180)))); N_phi_min=min(b(find(b>180))); else N_max=0; N_phi_min=360; end Alltime=(max(a)-min(a))*0.02;% unit s P_power=sum(abs(c(find(b<180)).*d(find(b<180))))*1e-12*1000/Alltime*1000;%

kv* pc*1000=mW N_power=sum(abs(c(find(b>180)).*d(find(b>180))))*1e-12*1000/Alltime*1000; current=sum(abs(c))*1e-12/Alltime*1000; P_phi_min=min(b(find(b<180))); Energy= (P_power+N_power)*Alltime/1000; c_1000=c(find(abs(c(find(b<180)))<1000)); d_1000=d(find(abs(c(find(b<180)))<1000)); %d_1000=find(abs(d(find(b<180))<=1000);

P_Energy_1000=sum(abs(c(find(abs(c(find(b<180)))<1000)).*d(find(abs(c(find(

b<180)))<1000))))*1e-12*1000*1000/1000;% kv* pc*1000=mW;mW*s=mJ N_Energy_1000=sum(abs(c(find(abs(c(find(b>180)))<1000)).*d(find(abs(c(find(

b>180)))<1000))))*1e-12*1000*1000/1000;% kv* pc*1000=mW;mW*s=mJ Energy_1000=P_Energy_1000+N_Energy_1000; P_Energy_2000=sum(abs(c(find(abs(c(find(b<180)))<2000)).*d(find(abs(c(find(

b<180)))<2000))))*1e-12*1000;% kv* pc*1000=mW;mW*s=mJ N_Energy_2000=sum(abs(c(find(abs(c(find(b>180)))<2000)).*d(find(abs(c(find(

b>180)))<2000))))*1e-12*1000;% kv* pc*1000=mW;mW*s=mJ Energy_2000=P_Energy_2000+N_Energy_2000; P_Energy_3000=sum(abs(c(find(abs(c(find(b<180)))<3000)).*d(find(abs(c(find(

b<180)))<3000))))*1e-12*1000;% kv* pc*1000=mW;mW*s=mJ N_Energy_3000=sum(abs(c(find(abs(c(find(b>180)))<3000)).*d(find(abs(c(find(

b>180)))<3000))))*1e-12*1000;% kv* pc*1000=mW;mW*s=mJ Energy_3000=P_Energy_3000+N_Energy_3000; P_Energy_4000=sum(abs(c(find(abs(c(find(b<180)))<4000)).*d(find(abs(c(find(

b<180)))<4000))))*1e-12*1000*1000/1000;% kv* pc*1000=mW;mW*s=mJ N_Energy_4000=sum(abs(c(find(abs(c(find(b>180)))<4000)).*d(find(abs(c(find(

b>180)))<4000))))*1e-12*1000*1000/1000;% kv* pc*1000=mW;mW*s=mJ Energy_4000=P_Energy_4000+N_Energy_4000; P_Energy_5000=sum(abs(c(find(abs(c(find(b<180)))<5000)).*d(find(abs(c(find(

b<180)))<5000))))*1e-12*1000*1000/1000;% kv* pc*1000=mW;mW*s=mJ N_Energy_5000=sum(abs(c(find(abs(c(find(b>180)))<5000)).*d(find(abs(c(find(

b>180)))<5000))))*1e-12*1000*1000/1000;% kv* pc*1000=mW;mW*s=mJ Energy_5000=P_Energy_5000+N_Energy_5000; P_Energy_6000=sum(abs(c(find(abs(c(find(b<180)))<6000)).*d(find(abs(c(find(

b<180)))<6000))))*1e-12*1000*1000/1000;% kv* pc*1000=mW;mW*s=mJ N_Energy_6000=sum(abs(c(find(abs(c(find(b>180)))<6000)).*d(find(abs(c(find(

b>180)))<6000))))*1e-12*1000*1000/1000;% kv* pc*1000=mW;mW*s=mJ Energy_6000=P_Energy_6000+N_Energy_6000;

Number_1000=size(find(abs(c)<1000)); Number_1000=Number_1000(1); Number_2000=size(find(abs(c)<2000));

130

Number_2000=Number_2000(1); Number_3000=size(find(abs(c)<3000)); Number_3000=Number_3000(1); Number_4000=size(find(abs(c)<4000)); Number_4000=Number_4000(1); Number_5000=size(find(abs(c)<5000)); Number_5000=Number_5000(1); Number_6000=size(find(abs(c)<6000)); Number_6000=Number_6000(1);

fprintf(' %s\n\n',x); fprintf(' Allamplitude\t\t=%f\t\t\t\n',max(P_max,N_max)); fprintf(' Allnumber\t\t=%f\t\t\t\n',P_number+N_number); fprintf(' Allpower\t\t=%f\t\tmW\t\n',P_power+N_power); fprintf(' Allcurrent\t\t=%f\t\tmA\t\n\n',current);

fprintf(' P_max\t\t=%f\t\t\t\n',P_max); fprintf(' P_number\t\t=%f\t\t\t\n',P_number); fprintf(' P_phi_min\t\t=%f\t\t\t\n\n',P_phi_min);

fprintf(' N_max\t\t=%f\t\t\t\n',N_max); fprintf(' N_number\t\t=%f\t\t\t\n',N_number); fprintf(' N_phi_min\t\t=%f\t\t\t\n\n',N_phi_min);

%fprintf(' Energy \t\t=%f\t\tJ\t\n',Energy); fprintf(' Energy \t\t=%f\t\tJ\t\n',Energy_6000); fprintf(' Energy below 1000\t\t=%f\t\tJ\t\n',Energy_1000); fprintf(' Energy from 1000 to 2000\t\t=%f\t\tJ\t\n',Energy_2000-

Energy_1000); fprintf(' Energy from 2000 to 3000\t\t=%f\t\tJ\t\n',Energy_3000-

Energy_2000); fprintf(' Energy from 3000 to 4000\t\t=%f\t\tJ\t\n',Energy_4000-

Energy_3000); fprintf(' Energy from 4000 to 5000\t\t=%f\t\tJ\t\n',Energy_5000-

Energy_4000); fprintf(' Energy from 5000 to 6000\t\t=%f\t\tJ\t\n',Energy_6000-

Energy_5000);

fprintf(' PD number below 1000\t\t=%f\t\t\t\n',Number_1000); fprintf(' PD number from 1000 to 2000\t\t=%f\t\t\t\n',Number_2000-

Number_1000); fprintf(' PD number from 2000 to 3000\t\t=%f\t\t\t\n',Number_3000-

Number_2000); fprintf(' PD number from 3000 to 4000\t\t=%f\t\t\t\n',Number_4000-

Number_3000); fprintf(' PD number from 4000 to 5000\t\t=%f\t\t\t\n',Number_5000-

Number_4000); fprintf(' PD number from 5000 to 6000\t\t=%f\t\t\t\n',Number_6000-

Number_5000);

131

Appendix II. The Results Used in the Thesis AII.1 Gemini X Sparking test 1- DGA data

Test 1 Oil Type Date Oil Volume

(ml)

Headspace

(ml)

Mineral

Oil

11/10/201

1 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-

Background

11/10/12:0

0 4008 318.8 0.0 2.8 0.3 48.4

138031.

8 0.0

42.

9

14.

3

22.

3

Gas-in-gas_TM8 1 11/10/13:1

7 4009 316.9 8.2 70.1 0.0

1835.

0

136751.

1 28.8

39.

7

14.

5

22.

6

Gas-in-gas_TM8 2 11/10/14:1

7 4010 317.3 10.4 85.8 0.0

2047.

5

135906.

6 36.4

40.

7

14.

6

22.

6

Gas-in-gas_TM8 3 11/10/15:1

7 4011 317.5 11.2 86.7 0.0

2032.

6

135336.

6 36.8

51.

4

14.

6

22.

7

Gas-in-total calculated 11/10/12:0

0 4008

364.6

9 0.00 3.00 0.74 3.52

21037.0

6 0.00

6.1

6

Gas-in-total calculated 11/10/13:1

7 4009

366.2

9 11.94 76.01 0.00

135.3

5

21111.9

3

11.2

8

5.7

8

Gas-in-total calculated 11/10/14:1

7 4010

369.2

8 15.25 93.68 0.00

152.0

6

21126.2

6

14.3

5

5.9

6

Gas-in-total calculated 11/10/15:1

7 4011

369.0

8 16.40 94.55 0.00

150.9

7

21030.5

4

14.5

0

7.5

3

Average GIT 368.2

2 14.53 88.08 0.00

146.1

3

21089.5

8

13.3

8

6.4

2

Generation GIT 3.53 14.53 85.07 (0.74) 142.6

1 52.52 9.76

0.2

6

AII.2 Gemini X Sparking test 2- DGA data

Test 2 Oil Type Date Oil Volume

(ml)

Headspace

(ml)

Mineral

Oil

11/10/201

1 2570.00 0.00

132

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-

Background

11/10/15:1

7 4011 317.5 11.2 86.7 0.0

2032.

6

135336.

6 36.8

51.

4

14.

6

22.

7

Gas-in-gas_TM8 1 11/10/17:1

7 4013 316.9 23.1 178.0 0.0

4826.

3

133433.

3 84.9

60.

5

14.

7

22.

9

Gas-in-gas_TM8 2 11/10/18:1

7 4014 317.3 23.4 177.7 0.8

4766.

9

132604.

2 87.5

57.

0

14.

7 23

Gas-in-gas_TM8 3 11/10/19:1

7 4015 315.6 23.0 177.4 0.9

4734.

5

131960.

5 86.6

54.

5

14.

8

22.

8

Gas-in-total calculated 11/10/15:1

7 4011

369.0

8 16.40 94.55 0.00

150.9

7

21030.5

4

14.5

0

7.5

3

Gas-in-total calculated 11/10/17:1

7 4013

370.0

4 33.97 194.99 0.00

361.0

2

20862.7

0

33.6

4

8.9

2

Gas-in-total calculated 11/10/18:1

7 4014

370.0

7 34.36 194.44 2.01

356.6

2

20726.0

7

34.6

5

8.4

0

Gas-in-total calculated 11/10/19:1

7 4015

371.4

6 34.09 195.88 2.28

356.5

2

20779.8

0

34.5

7

8.0

9

Average GIT 370.5

2 34.14 195.10 1.43

358.0

5

20789.5

2

34.2

8

8.4

7

Generation GIT 1.44 17.74 100.55 1.43 207.0

8 (241.02)

14.4

4

0.9

4

AII.3 Gemini X Sparking test 3- DGA data

Test 3 Oil Type Date Oil Volume

(ml)

Headspace

(ml)

Mineral

Oil

12/10/201

1 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-

Background

12/10/09:1

7 4029

312.

9 21.5 164.4 0.7

3940.

1

124208.

8 79.8

60.

4

15.

2

22.

1

Gas-in-gas_TM8 1 12/10/10:4

2 4030

313.

5 31.2 243.2 1.6

6625.

2

123849.

0

124.

7

72.

1

15.

2

22.

2

Gas-in-gas_TM8 2 12/10/11:4

2 4031

313.

7 34.0 258.4 1.0

6680.

8

123064.

9

128.

8

71.

3

15.

3

22.

2

133

Gas-in-gas_TM8 3 12/10/12:4

2 4032

314.

5 34.2 260.4 1.6

6639.

0

122858.

7

127.

3

76.

0

15.

3

22.

3

Gas-in-total calculated 12/10/09:1

7 4029

381.

4 33.0 188.0 1.8 304.5 20135.4 32.9 9.2

Gas-in-total calculated 12/10/10:4

2 4030

381.

6 47.9 277.7 4.2 512.0 20070.3 51.3

11.

0

Gas-in-total calculated 12/10/11:4

2 4031

384.

4 52.5 297.0 2.6 519.7 20074.4 53.3

11.

0

Gas-in-total calculated 12/10/12:4

2 4032

384.

9 52.7 299.0 4.2 516.5 20034.0 52.7

11.

7

Average GIT 383.

7 51.0 291.2 3.7 516.1 20059.5 52.5

11.

2

Generation GIT 2.3 18.0 103.3 1.8 211.6 (75.8) 14.3 2.0

AII.4 Gemini X Sparking test 4- DGA data

Test 4 Oil Type Date Oil Volume (ml) Headspace (ml)

Mineral Oil 40828.0 2570.0 0.0

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-Background 12/10/12:42 4032 314.5 34.2 260.4 1.6 6639.0 122858.7 127.3 76.0 15.3 22.3

Gas-in-gas_TM8 1 12/10/13:42 4033 313.4 44.2 338.4 1.5 9645.4 121926.4 176.5 84.3 15.3 22.3

Gas-in-gas_TM8 2 12/10/14:42 4034 313.8 46.1 353.1 1.7 9536.6 121347.0 176.1 80.1 15.3 22.4

Gas-in-gas_TM8 3 12/10/15:42 4035 314.5 46.7 352.5 1.4 9474.8 120980.6 176.5 77.2 15.4 22.3

134

Gas-in-total calculated 12/10/12:42 4032 384.9 52.7 299.0 4.2 516.5 20034.0 52.7 11.7

Gas-in-total calculated 12/10/13:42 4033 383.6 68.2 388.5 4.0 750.4 19882.0 73.1 13.0

Gas-in-total calculated 12/10/14:42 4034 383.6 71.0 404.9 4.5 742.0 19780.8 72.8 12.3

Gas-in-total calculated 12/10/15:42 4035 387.4 72.5 407.4 3.7 742.0 19856.7 73.5 11.9

Average GIT 384.9 70.6 400.3 4.0 744.8 19839.8 73.1 12.4

Generation GIT (0.0) 17.8 101.3 (0.2) 228.3 (194.2) 14.9 0.7

AII.5 Gemini X Sparking test 5- DGA data

Test 5 Oil Type Date Oil Volume (ml) Headspace (ml)

Mineral Oil 40829.0 2570.0 0.0

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-Background 13/10/09:40

4053 313.2 43.9 333.3 2.0 7807.6 113151.5 166.4 83.8 15.7 21.9

Gas-in-gas_TM8 1 13/10/11:18

4054 315.3 52.6 404.9 1.9 9841.8 113234.0 205.7 88.9 15.7 22.2

Gas-in-gas_TM8 2 13/10/12:18

4055 317.0 54.8 416.2 2.5 9801.2 112841.4 209.5 99.5 15.6 22.4

Gas-in-gas_TM8 3 13/10/13:18

4056 319.7 55.4 420.5 2.2 9769.1 112704.1 213.2 87.9 15.6 22.6

135

Gas-in-total calculated 13/10/09:40 4053 395.2 69.8 394.5 5.4 623.0 18959.1 70.9 13.2

Gas-in-total calculated 13/10/11:18 4054 396.5 83.4 477.6 5.1 785.6 18953.7 87.4 14.0

Gas-in-total calculated 13/10/12:18 4055 395.1 86.1 486.7 6.7 777.6 18755.0 88.4 15.6

Gas-in-total calculated 13/10/13:18 4056 397.6 86.8 490.6 5.9 775.2 18719.5 89.8 13.8

Average GIT 396.4 85.4 484.9 5.9 779.5 18809.4 88.5 14.5

Generation GIT 1.2 15.6 90.4 0.5 156.4 (149.8) 12.9 1.2

AII.6 FR3 Sparking test 1- DGA data

Test 1 Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

FR3 09/23/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-Background 23/9/10:00 3660 379.5 0.0 0.0 0.0 155.4 143204.8 0.0 44.7 11.9 24.6

Gas-in-gas_TM8 1 23/9/12:20 3662 379.8 9.8 41.2 0.0 2960.3 139280.7 27.2 379.9 12.2 25.4

Gas-in-gas_TM8 2 23/9/13:20 3663 381.1 10.4 45.1 0.4 3002.0 138406.2 27.3 404.5 12.4 25.7

Gas-in-gas_TM8 3 23/9/14:20 3664 381.5 10.9 46.3 0.6 2947.4 136897.9 26.6 394.9 12.5 25.9

Gas-in-total calculated 23/9/10:00 3660 471.0 0.0 0.0 0.0 10.2 20198.7 0.0 5.1

136

Gas-in-total calculated 23/9/12:20 3662 479.7 13.5 85.3 0.0 200.5 20281.2 8.5 44.9

Gas-in-total calculated 23/9/13:20 3663 487.9 14.6 94.5 0.7 207.1 20537.7 8.7 48.6

Gas-in-total calculated 23/9/14:20 3664 491.4 15.4 97.6 1.1 205.3 20513.2 8.5 47.9

Average GIT 486.3 14.5 92.5 0.6 204.3 20444.0 8.6 47.1

Generation GIT 15.4 14.5 92.5 0.6 194.1 245.3 6.2 42.0

AII.7 FR3 Sparking test 2- DGA data

Test 2 Oil

Type Date

Oil Volumn

(ml)

Headspace

(ml) V (V) I (A)

FR3 09/23/201

1 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-

Background

23/9/15:2

0 3665 379.8 10.4 47.5 0.6

2903.

7

135679.

5 25.4

391.

7

12.

6

26.

1

Gas-in-gas_TM8 1 23/9/16:2

0 3666 380.4 17.6 81.1 0.5

5802.

5

134164.

4 50.7

686.

8

12.

7

26.

1

Gas-in-gas_TM8 2 23/9/17:2

0 3667 378.6 18.7 88.2 1.1

5541.

9

132916.

2 52.4

708.

1

12.

8

26.

1

Gas-in-gas_TM8 3 23/9/18:2

0 3668 373.9 18.6 88.4 0.4

5403.

6

132023.

3 49.7

686.

1

12.

9

25.

9

Gas-in-total calculated 23/9/15:2

0 3665

492.2

8 14.75 100.69 1.08

204.1

5

20528.8

4 8.19

47.8

7

Gas-in-total calculated 23/9/16:2

0 3666

496.9

7 25.16 173.27 0.90

411.1

9

20460.7

1

16.4

9

84.6

0

137

Gas-in-total calculated 23/9/17:2

0 3667

498.5

1 26.94 189.93 2.01

395.8

1

20429.9

6

17.1

7

87.9

1

Gas-in-total calculated 23/9/18:2

0 3668

497.0

7 27.05 192.30 0.74

388.4

1

20415.8

4

16.4

2

85.8

0

Average GIT 497.5

2 26.38 185.16 1.22

398.4

7

20435.5

0

16.6

9

86.1

0

Generation GIT 5.24 11.63 84.48 0.14 194.3

2 (93.34) 6.20

38.2

4

AII.8 FR3 Sparking test 3- DGA data

Test 3 Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

FR3 26/09/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-Background 26/9/15:07 3690 389.2 16.3 77.3 0.6 3191.1 120188.8 37.7 545.1 15.4 25.2

Gas-in-gas_TM8 1 23/9/16:07 3691 388.4 23.1 107.3 0.3 5323.6 118951.4 63.0 686.8 15.5 25.5

Gas-in-gas_TM8 2 23/9/17:07 3692 388.2 24.1 109.4 0.0 5094.4 118121.0 63.0 783.8 15.5 25.5

Gas-in-gas_TM8 3 23/9/18:07 3693 387.1 23.6 110.4 0.6 4977.1 117724.1 63.2 770.6 15.6 25.5

Gas-in-total calculated 26/9/15:07 3690 621.6 28.4 202.4 1.3 272.5 22053.2 14.9 81.3

Gas-in-total calculated 23/9/16:07 3691 622.7 40.5 281.8 0.7 458.5 22025.3 25.0 103.1

Gas-in-total calculated 23/9/17:07 3692 622.4 42.2 287.3 0.0 438.8 21871.5 25.0 117.7

138

Gas-in-total calculated 23/9/18:07 3693 624.6 41.6 291.8 1.3 431.4 21938.6 25.3 116.4

Average GIT 623.2 41.4 287.0 0.7 442.9 21945.1 25.1 112.4

Generation GIT 1.6 13.0 84.6 0.0 170.4 (108.1) 7.5 31.2

AII.9 FR3 Sparking test 4- DGA data

Test 4 Oil Type Date Oil Volumn (ml) Headspace (ml) V (V) I (A)

FR3 09/29/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas-in-gas_TM8-Background 29/9/10:07 3751 389.6 0.9 4.6 9.4 143.1 117650.6 0.0 116.7 11.9 24.6

Gas-in-gas_TM8 1 29/9/12:15 3753 380.5 10.3 48.7 9.1 3234.8 116967.1 28.3 528.8 12.2 25.4

Gas in Gas_TM8 2 29/9/13:15 3754 379.1 10.6 53.1 9.8 3289.1 115455.9 29.6 543.6 12.4 25.7

Gas in Gas_TM8 3 29/9/14:15 3755 377.7 11.3 56.1 9.5 3141.3 115121.8 29.1 511.9 12.5 25.9

Gas-in-total calculated 29/9/10:07 3751 483.5 1.2 9.4 16.1 9.4 16594.3 0.0 13.4

Gas-in-total calculated 29/9/12:15 3753 480.6 14.2 100.8 15.9 219.1 17032.0 8.8 62.5

Gas-in-total calculated 29/9/13:15 3754 485.3 14.8 111.3 17.4 226.9 17132.1 9.4 65.3

Gas-in-total calculated 29/9/14:15 3755 486.6 15.9 118.3 16.9 218.8 17250.2 9.3 62.0

Average GIT 484.2 15.0 110.1 16.7 221.6 17138.1 9.2 63.3

Generation GIT 0.7 13.8 100.7 0.6 212.2 543.8 6.7 49.9

AII.10 FR3 Sparking test 5- DGA data

Test 5 Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

139

FR3 10/03/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 03/10/12:40 3846 295.3 0.8 5.1 3.2 91 116021.7 0 82.3 11.3 27.1

Gas in Gas_TM8 1 03/10/13:40 3847 298.4 10.4 45.8 4.2 2892.9 114510.2 30.8 478.3 11.5 27.3

Gas in Gas_TM8 2 03/10/14:40 3848 296.8 11 50.2 3.9 2847.3 114280.1 25.5 484.2 11.7 27.5

Gas in Gas_TM8 3 03/10/15:40 3849 291.9 10.7 51.1 3.1 2640.6 113944.7 24.9 454.3 12.1 27.7

Gas-in-total calculated 03/10/12:40 3846 340.2 1.0 9.6 5.1 5.8 15880.0 0.0 9.0

Gas-in-total calculated 03/10/13:40 3847 349.2 13.3 87.4 6.8 187.2 15978.0 9.1 53.5

Gas-in-total calculated 03/10/14:40 3848 352.7 14.3 97.2 6.4 187.7 16251.2 7.6 55.1

Gas-in-total calculated 03/10/15:40 3849 358.1 14.4 102.1 5.3 180.3 16786.3 7.7 53.5

Average GIT 353.3 14.0 95.5 6.2 185.1 16338.5 8.1 54.0

Generation GIT 13.2 13.0 86.0 1.1 179.3 458.5 5.9 45.0

AII.11 FR3 Sparking test 6- DGA data

Test 6 Oil

Type Date

Oil Volume

(ml)

Headspace

(ml) V (V) I (A)

FR3 10/07/201

1 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH

4 CO P T

Gas in Gas_TM8-

Background

07/10/12:1

7 3930 384.4 9.5 48 2 282.7 133534 11.8

154.

9

13.

9

22.

4

Gas in Gas_TM8 1 05/10/14:1

7 3932

389.3

9 16.2 83.1 2.1

3222.

2

131768.

7 33.9

511.

1

13.

9

22.

9

Gas in Gas_TM8 2 05/10/15:1

7 3933 393 16.9 86.9 1.7

3158.

4

131315.

4 35.9

516.

3

13.

9

23.

1

140

Gas in Gas_TM8 3 05/10/16:1

7 3934 393.6 16.9 89.6 1.9

3098.

2

130596.

6 35.5

510.

7

13.

9

23.

2

Gas-in-total calculated 07/10/12:1

7 3930 568.6 15.3 117.3 4.1 21.4 21580.0 4.2 20.7

Gas-in-total calculated 07/10/14:1

7 3932 573.3 26.0 201.9 4.3 244.4 21388.6 12.1 68.4

Gas-in-total calculated 07/10/15:1

7 3933 577.6 27.0 210.6 3.5 239.9 21352.5 12.8 69.1

Gas-in-total calculated 07/10/16:1

7 3934 577.9 27.0 216.9 3.9 235.5 21254.3 12.7 68.4

Average GIT 576.3 26.7 209.8 3.9 239.9 21331.8 12.5 68.6

Generation GIT 7.7 11.4 92.5 0.0 218.6 (248.2) 6.1 47.9

AII.12 Gemini X PD test 1- DGA data

PD attitude Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

1500pC Mineral 04/12/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 01/12/14:58

4640 336.9 0 0 0 0 128541.3 0 18 15.5 21.6

Gas in Gas_TM8 1 04/12/06:50

4657 348 0 5.3 0.6 65.4 122568.1 0 43.3 15.3 19.1

Gas in Gas_TM8 2 04/12/10:50

4657 348 0 5.3 0.6 65.4 122568.1 0 43.3 15.4 18.8

Gas in Gas_TM8 3 04/12/15:50

4657 348 0 5.3 0.6 65.4 122568.1 0 43.3 15.2 18.7

141

Gas-in-total calculated 01/12/14:58 4640 421.2 0.0 0.0 0.0 0.0 21285.0 0.0 2.8

Gas-in-total calculated 04/12/06:50 4657 442.3 0.0 6.3 1.7 5.1 20205.4 0.0 6.7

Gas-in-total calculated 04/12/10:50 4657 446.8 0.0 6.4 1.7 5.1 20358.4 0.0 6.7

Gas-in-total calculated 04/12/15:50 4657 441.5 0.0 6.3 1.7 5.0 20100.8 0.0 6.7

Average GIT 443.6 0.0 6.3 1.7 5.1 20221.5 0.0 6.7

Generation GIT 22.4 0.0 6.3 1.7 5.1 (1063.5) 0.0 3.9

AII.13 Gemini X PD test 2- DGA data

PD attitude Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

2000pC Mineral 29/11/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 25/11/13:13 4624 0.0 0.0 0.0 0.0 0.0 119372.6 0.0 35.9 12.6 22

Gas in Gas_TM8 1 29/11/10:45 4625 403.5 0.0 8.8 0.0 217.0 140225.6 8.3 54.6 15.5 20.6

Gas in Gas_TM8 2 29/11/11:45 4625 403.5 0.0 8.8 0.0 217.0 140225.6 8.3 54.6 15.6 21.2

Gas in Gas_TM8 3 29/11/12:45 4625 403.5 0.0 8.8 0.0 217.0 140225.6 8.3 54.6 15.6 21.5

142

Gas-in-total calculated 25/11/13:13 4624 0.0 0.0 0.0 0.0 0.0 16046.7 0.0 4.5

Gas-in-total calculated 29/11/10:45 4625 510.4 0.0 10.4 0.0 17.1 23298.9 3.5 8.5

Gas-in-total calculated 29/11/11:45 4625 510.1 0.0 10.4 0.0 17.2 23401.4 3.5 8.6

Gas-in-total calculated 29/11/12:45 4625 508.3 0.0 10.4 0.0 17.2 23377.6 3.5 8.6

Average GIT 509.6 0.0 10.4 0.0 17.2 23359.3 3.5 8.6

Generation GIT 509.6 0.0 10.4 0.0 17.2 7312.5 2.6 4.0

AII.14 Gemini X PD test 3- DGA data

PD attitude Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

1500pC-2 Mineral 06/12/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 04/12/16:50

4658 350.6 0 6.6 0 60.4 123193 3 37.2 15.1 18.8

Gas in Gas_TM8 1 06/12/13:50

4661 368.2 1.6 17.9 1.3 393.6 121610 22.2 61.2 15 20.1

Gas in Gas_TM8 2 06/12/14:50

4661 368.2 1.6 17.9 1.3 393.6 121610 22.2 61.2 15 20.5

Gas in Gas_TM8 3 06/12/15:50

4661 368.2 1.6 17.9 1.3 393.6 121610 22.2 61.2 15.1 20.8

Gas-in-total calculated 04/12/16:50 4658 441.4 0.0 7.8 0.0 4.6 20063.5 1.3 5.7

143

Gas-in-total calculated 06/12/13:50 4661 453.4 2.5 20.7 3.5 29.9 19587.4 9.1 9.3

Gas-in-total calculated 06/12/14:50 4661 451.3 2.5 20.6 3.5 30.0 19560.7 9.1 9.2

Gas-in-total calculated 06/12/15:50 4661 452.7 2.5 20.6 3.5 30.2 19671.0 9.2 9.3

Average GIT 452.5 2.5 20.6 3.5 30.0 19606.3 9.1 9.3

Generation GIT 11.1 2.5 12.8 3.5 25.4 (457.2) 5.8 3.6

AII.15 Gemini X PD test 4- DGA data

PD attitude Oil

Type Date

Oil Volume

(ml)

Headspace

(ml) V (V) I (A)

4000pC Mineral 30/11/201

1 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-

Background

29/11/13:4

5 4628 403.3 1.6 10.5 1.1 183.1

137518.

3 9.9 49.8

15.

7

21.

7

Gas in Gas_TM8 1 30/11/11:3

5 4629 401.5 5.7 31.9 2.8

1041.

7 135301 48.9 73

15.

6

20.

6

Gas in Gas_TM8 2 30/11/12:3

5 4629 401.5 5.7 31.9 2.8

1041.

7 135301 48.9 73

15.

7

21.

3

Gas in Gas_TM8 3 30/11/13:3

5 4629 401.5 5.7 31.9 2.8

1041.

7 135301 48.9 73

15.

8

21.

6

Gas-in-total calculated 29/11/13:4

5 4628

510.1

1 2.55 12.46 3.00 14.61

23057.5

3 4.22 7.86

Gas-in-total calculated 30/11/11:3

5 4629

511.1

9 9.16 38.09 7.72 82.47

22625.6

6

20.8

6

11.4

7

144

Gas-in-total calculated 30/11/12:3

5 4629

510.2

3 9.14 38.03 7.69 83.07

22716.5

7

20.9

0

11.5

3

Gas-in-total calculated 30/11/13:3

5 4629

511.6

7 9.16 38.13 7.70 83.63

22838.0

0

20.9

9

11.6

0

Average GIT 511.0

3 9.15 38.08 7.70 83.06

22726.7

4

20.9

2

11.5

3

Generation GIT 0.92 6.60 25.63 4.70 68.45 (330.79) 12.1

8 3.67

AII.16 FR3 PD test 1- DGA data

PD attitude Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A) B

1000pC-1 FR3 21/11/2011 2570.00 0.00 0.03

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 1 21/11/07:25 4556 268.8 0 0 5.3 16.2 130932.7 0 41.2 14.2 22

Gas in Gas_TM8-Background 2 21/11/08:25 4556 268.8 0 0 5.3 16.2 130932.7 0 41.2 14.2 22

Gas in Gas_TM8-Background 3 21/11/09:25 4556 268.8 0 0 5.3 16.2 130932.7 0 41.2 14.2 22

Gas in Gas_TM8 1 22/11/05:45 4570 269.7 0 0 4.1 148.5 119709.3 0 87.1 14.9 22.5

Gas in Gas_TM8 2 22/11/06:45 4570 269.7 0 0 4.1 148.5 119709.3 0 87.1 14.9 22.5

Gas in Gas_TM8 3 22/11/07:45 4570 269.7 0 0 4.1 148.5 119709.3 0 87.1 14.9 22.5

Gas-in-total calculated 21/11/09:25 4556.0 407.7 0.0 0.0 11.1 1.2 21540.3 0.0 5.6

Gas-in-total calculated 22/11/05:45 4570.0 427.2 0.0 0.0 9.0 12.0 20755.9 0.0 12.5

Gas-in-total calculated 22/11/06:45 4570.0 427.2 0.0 0.0 9.0 12.0 20755.9 0.0 12.5

Gas-in-total calculated 22/11/07:45 4570.0 427.2 0.0 0.0 9.0 12.0 20755.9 0.0 12.5

Average GIT 427.2 0.0 0.0 9.0 12.0 20755.9 0.0 12.5

Generation GIT 19.5 0.0 0.0 (2.1) 10.8 (784.3) 0.0 6.9

AII.17 FR3 PD test 2- DGA data

145

PD attitude Oil

Type Date

Oil Volume

(ml)

Headspace

(ml)

V

(V) I (A) B

1000pC-2 FR3 23/11/201

1 2570.00 0.00 0.03

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH

4 CO P T

Gas in Gas_TM8-Background

1

22/11/07:4

5 4573 269.3 0.0 0.0 3.4 132.6

117429.

9 0.0 85.2 15

22.

7

Gas in Gas_TM8-Background

2

22/11/08:4

5 4573 269.3 0.0 0.0 3.4 132.6

117429.

9 0.0 85.2 15

22.

7

Gas in Gas_TM8-Background

3

22/11/09:4

5 4573 269.3 0.0 0.0 3.4 132.6

117429.

9 0.0 85.2 15

22.

7

Gas in Gas_TM8 1 23/11/01:1

3 4581 269.1 0.0 0.0 3.8 203.4

112475.

5 0.0 92.7

15.

3

22.

8

Gas in Gas_TM8 2 23/11/02:1

3 4581 269.1 0.0 0.0 3.8 203.4

112475.

5 0.0 92.7

15.

3

22.

8

Gas in Gas_TM8 3 23/11/03:1

3 4581 269.1 0.0 0.0 3.8 203.4

112475.

5 0.0 92.7

15.

3

22.

8

Gas-in-total calculated 22/11/09:4

5 4573

428.6

8 0.00 0.00 7.49 10.84

20533.4

6 0.00

12.3

0

Gas-in-total calculated 23/11/01:1

3 4581

436.5

3 0.00 0.00 8.53 16.97

20078.1

4 0.00

13.6

5

Gas-in-total calculated 23/11/02:1

3 4581

436.5

3 0.00 0.00 8.53 16.97

20078.1

4 0.00

13.6

5

Gas-in-total calculated 23/11/03:1

3 4581

436.5

3 0.00 0.00 8.53 16.97

20078.1

4 0.00

13.6

5

Average GIT 436.5

3 0.00 0.00 8.53 16.97

20078.1

4 0.00

13.6

5

Generation GIT 7.85 0.00 0.00 1.04 6.13 (455.32) 0.00 1.35

AII.18 FR3 PD test 3- DGA data

146

PD attitude Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

2000pC-1 FR3 14/11/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 14/11/11:00 4407 384.9 2.8 6.7 1.6 301.7 90419.7 8.0 154.9 15.1 22.7

Gas in Gas_TM8 1 14/11/21:40 4419 390.3 4.1 10.1 2.1 646.6 88132.9 14.4 189.3 15.3 23.5

Gas in Gas_TM8 2 14/11/21:40 4419 390.3 4.1 10.1 2.1 646.6 88132.9 14.4 189.3 15.3 23.5

Gas in Gas_TM8 3 14/11/21:40 4419 390.3 4.1 10.1 2.1 646.6 88132.9 14.4 189.3 15.3 23.5

Gas-in-total calculated 14/11/11:00 4407 616.79 4.88 17.72 3.55 24.83 15915.94 3.10 22.51

Gas in total calculated 14/11/21:40 4419 629.06 7.20 26.81 4.68 54.21 15829.67 5.65 27.93

Gas in total calculated 14/11/21:40 4419 629.06 7.20 26.81 4.68 54.21 15829.67 5.65 27.93

Gas in total calculated 14/11/21:40 4419 629.06 7.20 26.81 4.68 54.21 15829.67 5.65 27.93

Average GIT 629.06 7.20 26.81 4.68 54.21 15829.67 5.65 27.93

Generation GIT 12.28 2.32 9.09 1.14 29.39 (86.27) 1.86 5.41

AII.19 FR3 PD test 4- DGA data

147

PD attitude Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

2000pC-2 FR3 23/11/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 23/11/10:13 4589 261.0 0.2 0.0 3.5 169.1 109181.8 1.8 86.7 10.8 21.6

Gas in Gas_TM8 1 23/11/20:30 4596 268.8 1.7 10.7 4.1 615.9 105468.6 10.8 158.5 16.1 23.4

Gas in Gas_TM8 2 23/11/22:30 4596 268.8 1.7 10.7 4.1 615.9 105468.6 10.8 158.5 16.1 23.4

Gas in Gas_TM8 3 24/11/00:30 4596 268.8 1.7 10.7 4.1 615.9 105468.6 10.8 158.5 16.1 23.4

Gas in total calculated 23/11/10:13 4589 302.21 0.25 0.00 5.60 9.88 13613.02 0.50 8.99

Gas in total calculated 23/11/20:30 4596 456.31 3.14 29.93 9.63 54.30 19916.39 4.46 24.60

Gas in total calculated 23/11/22:30 4596 456.31 3.14 29.93 9.63 54.30 19916.39 4.46 24.60

Gas in total calculated 24/11/00:30 4596 456.31 3.14 29.93 9.63 54.30 19916.39 4.46 24.60

Average GIT 456.31 3.14 29.93 9.63 54.30 19916.39 4.46 24.60

Generation GIT 154.10 2.89 29.93 4.03 44.42 6303.37 2.89 15.61

AII.20 FR3 PD test 5- DGA data

PD attitude Oil Type Date Oil Volume (ml) Headspace (ml) V (V) I (A)

3000pC-1 FR3 15/11/2011 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 15/11/11:50 4424 387.5 4.6 10.2 1.5 620.6 89578.7 15.2 204.5 15 21.5

Gas in Gas_TM8 1 15/11/19:50 4431 405.2 11.0 21.4 2.9 2387.7 86963.4 43.4 376.4 15.2 24

148

Gas in Gas_TM8 2 15/11/19:50 4431 405.2 11.0 21.4 2.9 2387.7 86963.4 43.4 376.4 15.2 24

Gas in Gas_TM8 3 15/11/19:50 4431 405.2 11.0 21.4 2.9 2387.7 86963.4 43.4 376.4 15.2 24

Gas in total calculated 15/11/11:50 4424 623.75 8.04 27.19 3.34 50.31 15498.61 5.86 29.44

Gas in total calculated 15/11/19:50 4431 645.83 19.12 56.10 6.40 199.57 15585.59 16.92 55.23

Gas in total calculated 15/11/19:50 4431 645.83 19.12 56.10 6.40 199.57 15585.59 16.92 55.23

Gas in total calculated 15/11/19:50 4431 645.83 19.12 56.10 6.40 199.57 15585.59 16.92 55.23

Average GIT 645.83 19.12 56.10 6.40 199.57 15585.59 16.92 55.23

Generation GIT 22.09 11.08 28.91 3.06 149.26 86.98 8.07 25.79

AII.21 FR3 PD test 6- DGA data

PD attitude Oil

Type Date

Oil Volume

(ml)

Headspace

(ml) V (V) I (A)

3000pC-2 FR3 15/11/201

1 2570.00 0.00 57.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-

Background

15/11/20:5

0 4432 405.1 11.3 21.1 2.8

2336.

4 86675.5 43.2

376.

5

15.

2

23.

9

Gas in Gas_TM8 1 16/11/06:5

5 4439 401.9 18.2 33.0 3.6

4545.

8 84276.0 73.7

575.

2

15.

3

22.

7

Gas in Gas_TM8 2 16/11/06:5

5 4439 401.9 18.2 33.0 3.6

4545.

8 84276.0 73.7

575.

2

15.

3

22.

7

Gas in Gas_TM8 3 16/11/06:5

5 4439 401.9 18.2 33.0 3.6

4545.

8 84276.0 73.7

575.

2

15.

3

22.

7

149

Gas in total calculated 15/11/20:5

0 4432

646.2

7 19.65 55.38 6.18

195.1

4

15520.4

1

16.8

4

55.2

3

Gas in total calculated 16/11/06:5

5 4439

652.5

6 32.15 88.45 8.09

379.0

0

15030.9

9

28.9

4

84.7

0

Gas in total calculated 16/11/06:5

5 4439

652.5

6 32.15 88.45 8.09

379.0

0

15030.9

9

28.9

4

84.7

0

Gas in total calculated 16/11/06:5

5 4439

652.5

6 32.15 88.45 8.09

379.0

0

15030.9

9

28.9

4

84.7

0

Average GIT 652.5

6 32.15 88.45 8.09

379.0

0

15030.9

9

28.9

4

84.7

0

Generation GIT 6.29 12.50 33.07 1.90 183.8

6 (489.42) 8.83

29.4

7

AII.22 FR3 PD test 7- DGA data

PD attitude Oil

Type Date

Oil Volume

(ml)

Headspace

(ml) V (V) I (A)

3000pC-3 FR3 17/11/201

1 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-

Background

17/11/11:5

3 4464 676.5 0 0 5.3 43.3

118981.

3 0

161.

5 7.2 23

Gas in Gas_TM8 1 17/11/16:4

0 4470 591.4 7.2 28 6.6

2950.

1

109328.

5 58.4

439.

3 8.8

24.

4

Gas in Gas_TM8 2 17/11/18:4

0 4470 591.4 7.2 28 6.6

2950.

1

109328.

5 58.4

439.

3 8.8

24.

4

Gas in Gas_TM8 3 17/11/20:4

0 4470 591.4 7.2 28 6.6

2950.

1

109328.

5 58.4

439.

3 8.8

24.

4

Gas in total calculated 17/11/11:5

3 4464

515.4

7 0.00 0.00 5.59 1.70

10012.6

4 0.00

11.2

0

Gas in total calculated 17/11/16:4

0 4470

543.7

2 7.22 42.30 8.40

143.1

5

11383.5

2

13.1

7

37.3

5

Gas in total calculated 17/11/18:4

0 4470

543.7

2 7.22 42.30 8.40

143.1

5

11383.5

2

13.1

7

37.3

5

150

Gas in total calculated 17/11/20:4

0 4470

543.7

2 7.22 42.30 8.40

143.1

5

11383.5

2

13.1

7

37.3

5

Average GIT 543.7

2 7.22 42.30 8.40

143.1

5

11383.5

2

13.1

7

37.3

5

Generation GIT 28.25 7.22 42.30 2.81 141.4

5 1370.89 9.61

26.1

5

AII.23 FR3 PD test 8- DGA data

PD attitude Oil

Type Date

Oil Volume

(ml)

Headspace

(ml) V (V) I (A)

4000pC FR3 18/11/201

1 2570.00 0.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-

Background

18/11/14:4

0 4490 441.7 6 21.3 4.6

1771.

6 95293.9 38.9 330

12.

2 24

Gas in Gas_TM8 1 18/11/16:2

5 4496 443.3 15.7 38.7 8

4546.

6 90867.1 81.8

616.

4

12.

4

24.

2

Gas in Gas_TM8 2 18/11/18:2

5 4496 443.3 15.7 38.7 8

4546.

6 90867.1 81.8

616.

4

12.

4

24.

2

Gas in Gas_TM8 3 18/11/20:2

5 4496 443.3 15.7 38.7 8

4546.

6 90867.1 81.8

616.

4

12.

4

24.

2

Gas in total calculated 18/11/14:4

0 4490

565.0

6 8.37 44.82 8.14

118.8

5

13707.8

1

12.1

7

38.8

6

Gas in total calculated 18/11/16:2

5 4496

575.3

5 22.23 82.57 14.37

310.4

4

13308.5

4

26.0

1

73.8

1

Gas in total calculated 18/11/18:2

5 4496

575.3

5 22.23 82.57 14.37

310.4

4

13308.5

4

26.0

1

73.8

1

Gas in total calculated 18/11/20:2

5 4496

575.3

5 22.23 82.57 14.37

310.4

4

13308.5

4

26.0

1

73.8

1

Average GIT 575.3

5 22.23 82.57 14.37

310.4

4

13308.5

4

26.0

1

73.8

1

Generation GIT 10.29 13.86 37.75 6.23 191.5

9 (399.26)

10.1

0

34.9

5

AII.24 Gemini X 300°C thermal test -1 DGA data

151

Test Temperature Test 1 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml)

V

(V) I (A)

300.00 Mineral 20 mins 25/07/2011 2748.00 3.50 0.40 261.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 P T

Gas in Gas_TM8-

Background 7/25/11:44 3200 440.80 0.00 0.00 0.00 0.00 155118.00 0.00 11.80 23.80

Gas in Gas_TM8 1 7/25/12:44 3201 556.30 0.00 0.00 0.00 0.00 151366.10 33.50 12.00 31.90

Gas in Gas_TM8 2 7/25/13:44 3202 521.00 0.00 0.00 0.00 0.00 151752.00 36.50 12.10 26.40

Gas in Gas_TM8 3 7/25/14:44 3203 514.30 0.00 0.00 0.00 0.00 152405.00 33.30 12.20 24.80

Gas in total calculated 7/25/11:44 3200 408.20 0.00 0.00 0.00 0.00 19187.01 0.00

Gas in total calculated 7/25/12:44 3201 477.53 0.00 0.00 0.00 0.00 18669.02 10.23

Gas in total calculated 7/25/13:44 3202 484.40 0.00 0.00 0.00 0.00 19377.88 11.72

Gas in total calculated 7/25/14:44 3203 487.16 0.00 0.00 0.00 0.00 19565.75 10.80

Average GIT 483.03 0.00 0.00 0.00 0.00 19204.22 10.92

Average GIO 470.30 0.00 0.00 0.00 0.00 19204.22 10.92

AII.25 Gemini X 300°C thermal test -2 DGA data

Test 2 Test

Temperature

Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml)

V

(V) I (A)

300.00 Mineral 20 mins 25/07/2011 2778.00 3.50 0.40 261.00

Gas Type No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 P T

Gas in Gas_TM8-

Background 7/25/14:44 3203 514.30 0.00 0.00 0.00 0.00 152405.00 33.30 12.20 24.80

Gas in Gas_TM8 1 7/25/15:44 3204 679.60 0.00 0.00 0.00 0.00 148664.20 97.40 12.50 36.20

152

Gas in Gas_TM8 2 7/25/16:44 3205 619.40 0.00 0.50 0.00 0.00 147760.70 99.40 12.50 27.70

Gas in total calculated 486.68 0.00 0.00 0.00 0.00 19425.05 10.77

Gas in total calculated 578.61 0.00 0.00 0.00 0.00 18795.70 30.17

Gas in total calculated 581.06 0.00 0.44 0.00 0.00 19209.20 32.43

Average GIT 579.83 0.00 0.22 0.00 0.00 19002.45 31.30

Average GIO 562.44 0.00 0.22 0.00 0.00 19002.45 31.30

AII.26 Gemini X 300°C thermal test 2-2 DGA data

Test

2_2

Test

Temperature

Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml)

V

(V) I (A)

300.00 Mineral 20 mins 25/07/2011 2748.00 3.50 0.40 261.00

Gas Type No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 P T

Gas in Gas_TM8-

Background 7/25/14:44 3203 514.30 0.00 0.00 0.00 0.00 152405.00 33.30 12.20 24.80

Gas in Gas_TM8 1 7/25/18:44 3207 589.30 0.00 0.00 0.00 0.00 146967.30 89.80 12.90 24.80

Gas in Gas_TM8 2 7/25/19:44 3208 581.40 0.00 0.00 0.80 0.00 145649.00 87.90 13.00 24.30

Gas in Gas_TM8 3 7/25/20:44 3209 576.90 0.00 0.70 0.00 0.00 145468.80 84.90 13.10 24.20

Gas in total calculated 486.68 0.00 0.00 0.00 0.00 19425.05 10.77

Gas in total calculated 590.23 0.00 0.00 0.00 0.00 19950.23 30.80

Gas in total calculated 594.81 0.00 0.00 1.75 0.00 20111.56 30.72

Gas in total calculated 590.90 0.00 0.67 0.00 0.00 20093.43 29.69

AII.26 Gemini X 300°C thermal test -3 DGA data

153

Test Temperature Test 3 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml) V (V) I (A)

300.00 Mineral 40 mins 26/07/2011 2742.00 2.00 0.40 265.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 P T

Gas in Gas_TM8-

Background 7/26/12:44 3225 547.20 0.00 0.00 0.00 0.00 139369.50 68.20 13.80 24.30

Gas in Gas_TM8 1 7/26/15:42 3227 729.10 0.60 0.60 0.00 0.00 138672.70 173.20 13.90 28.00

Gas in Gas_TM8 2 7/26/16:42 3228 708.10 0.00 0.00 0.00 0.00 138120.10 169.40 13.90 26.10

Gas in Gas_TM8 3 7/26/17:42 3229 696.40 0.00 0.80 0.40 0.00 137220.30 160.40 14.00 25.30

Gas in total calculated 7/26/12:44 3225 589.16 0.00 0.00 0.00 0.00 20127.01 25.03

Gas in total calculated 7/26/15:42 3227 757.82 0.78 0.59 0.00 0.00 20005.21 62.69

Gas in total calculated 7/26/16:42 3228 757.80 0.00 0.00 0.00 0.00 20113.96 62.38

Gas in total calculated 7/26/17:42 3229 752.25 0.00 0.81 0.92 0.00 20036.48 59.36

AII.26 Gemini X 400°C thermal test -1 DGA data

Test Temperature Test 1 Oil

Type

Heatin

g Date

Oil Volume

(ml)

Headspace

(ml) V (V) I (A)

400.00 Mineral 5min 08/02/201

1 2732.00 10.00 1.30 600.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-

Background

2/8/14:1

4 3368 985.0 1.2 0.0 2.7 15.1 132161.8 271.8

1285.

9

14.

6

28.

3

Gas in Gas_TM8 1 2/8/15:1

4 3369 1534.5 480.3 2.0 64.6

4350.

7 127410.0

2471.

1

2093.

0

14.

7 43

154

Gas in total calculated 2/8/14:1

4 3368 1071.03 1.63 0.00 6.22 1.10 19924.66

102.9

7

184.3

2

Gas in total calculated 2/8/15:1

4 3369 1428.76 548.74 1.75 121.68

341.9

8 18881.38

871.1

5

302.2

0

Generation GIT 5min 357.73 547.11 1.75 115.46 340.8

8

(1043.28

)

560.5

6

117.8

7

AII.27 Gemini X 400°C thermal test -2 DGA data

Test Temperature Test 2 Oil Type Heating Date Oil Volume (ml) Headspace (ml) V (V) I (A)

400.00 Mineral 50s 08/02/2011 2732.00 30.00 1.30 600.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 2/8/15:14 3369 1534.5 480.3 2.0 64.6 4350.7 127410.0 2471.1 2093.0 14.7 43

Gas in Gas_TM8 1 2/8/17:04 3371 1332.1 5332.6 73.2 511.8 33835.6 123776.0 19656.0 2132.9 14.7 28.1

Gas in Gas_TM8 2 2/8/18:04 3372 1318.7 5329.5 72.5 520.9 32886.9 123722.6 19345.8 2082.3 14.7 27.8

Gas in Gas_TM8 3 2/8/19:04 3373 1292.5 5395.4 72.4 529.3 31917.5 123417.2 19177.1 2052.8 14.9 27.9

Gas in total calculated 2/8/15:14 3369 1423.5 547.1 1.7 121.5 326.9 18440.7 862.6 295.0

Gas in total calculated 2/8/17:04 3371 1476.2 7382.6 76.2 1196.1 2855.9 20148.4 7720.7 331.2

Gas in total calculated 2/8/18:04 3372 1466.4 7406.5 75.7 1222.7 2775.1 20159.8 7612.8 323.5

Gas in total calculated 2/8/19:04 3373 1455.2 7590.4 76.6 1257.5 2730.2 20376.9 7644.4 323.2

Average GIT 1466.0 7459.8 76.2 1225.4 2787.1 20228.4 7659.3 325.9

Average GIO 1414.7 7250.9 73.3 1205.1 1503.8 15402.4 6902.4 244.4

Generation GIT 50s 42.5 6912.7 74.4 1104.0 2460.1 1787.6 4959.7 31.0

AII.28 Gemini X 400°C thermal test -3 DGA data

Test Temperature Test 3 Oil

Type

Heatin

g Date

Oil Volume

(ml)

Headspace

(ml)

V

(V) I (A)

155

400.00 Mineral 16s 08/11/201

1 2732.00 0.00 - 470-510

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 11/8/9:00 3447 528.8 0.8 0.0 1.0 0.0 142989.

8 0.0 49.6 15.2 24.6

Gas in Gas_TM8 1 11/8/12:3

0 3449 550.0 33.7 3.5 3.9 162.2

143270.

0

128.

3 63.5 15.0 25.9

Gas in Gas_TM8 2 11/8/13:3

0 3450 549.7 34.5 3.8 3.8 182.7

142977.

5

120.

8 59.1 15.0 25.7

Gas in Gas_TM8 3 11/8/14:3

0 3451 551.8 33.9 3.2 4.1 177.7

142535.

5

120.

2 61.7 15.0 25.6

Gas in total calculated 11/8/9:00 3447 624.9 1.2 0.0 2.5 0.0 22721.8 0.0 7.4

Gas in total calculated 11/8/12:3

0 3449 631.8 48.6 3.8 9.6 12.1 22369.2 50.7 9.4

Gas in total calculated 11/8/13:3

0 3450 632.9 49.9 4.1 9.3 13.7 22338.4 47.8 8.7

Gas in total calculated 11/8/14:3

0 3451 636.0 49.1 3.5 10.1 13.3 22276.8 47.6 9.1

Average GIT 633.6 49.2 3.8 9.7 13.0 22328.1 48.7 9.1

Average GIO 617.7 48.2 3.7 9.6 8.0 18220.0 45.1 7.3

Generation GIT 16s 8.7 48.0 3.8 7.1 13.0 (393.7) 48.7 1.6

Generation GIO 16s 8.3 47.0 3.7 7.0 8.0 (321.3) 45.1 1.3

AII.29 FR3 300°C thermal test -1 DGA data

Test Temperature Test 1 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml)

V

(V) I (A)

300.00 FR3 90 mins 27/07/2011 2732.00 0.00 0.40 260

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 7/27/13:45 3245 634.5 0.6 0.0 35.0 67.8 101867.9 46.7 595.6 15 28.6

156

Gas in Gas_TM8 1 7/27/17:40 3247 930.5 1.8 0.5 78.4 212.2 101656.7 145.5 1647.5 14.7 30

Gas in Gas_TM8 2 7/27/18:40 3248 905.8 2.2 0.0 75.0 193.0 101852.0 138.3 1618.7 14.7 28.4

Gas in Gas_TM8 3 7/27/19:40 3249 892.7 2.3 0.0 74.4 201.3 102321.6 139.8 1595.3 14.7 27.8

Gas in total calculated 7/27/13:45 3245 956.10 0.99 0.00 73.13 5.65 18565.29 17.82 86.07

Gas in total calculated 7/27/17:40 3247 1357.03 2.89 1.18 158.62 17.51 18377.44 54.35 234.05

Gas in total calculated 7/27/18:40 3248 1340.01 3.58 0.00 153.84 15.75 18159.59 51.72 229.13

Gas in total calculated 7/27/19:40 3249 1327.77 3.75 0.00 153.41 16.35 18148.34 52.30 225.50

Average GIT 1341.60 3.41 0.39 155.29 16.54 18228.46 52.79 229.56

Average GIO 1316.24 3.35 0.39 153.17 10.90 15385.39 48.85 184.37

Generation GIT 90 mins 385.50 2.41 0.39 82.16 10.89 (336.84) 25.52 143.49

Generation GIO 90 mins 378.20 2.37 0.39 81.04 7.18 (279.73) 32.36 115.26

AII.30 FR3 300°C thermal test -2 DGA data

Test Temperature Test 2 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml)

V

(V) I (A)

300.00 FR3 3h 28/07/2011 2732.00 0.00 0.40 253.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 7/28/08:40 3262 810.8 1.4 0.0 65.6 97.4 106522.6 115.8 1281.1 15.1 26.6

Gas in Gas_TM8 1 7/28/16:00 3264 1274.3 3.5 0.4 118.3 347.7 93579.0 201.1 2653.0 14.7 36.1

Gas in Gas_TM8 2 7/28/17:00 3265 1181.9 3.5 0.4 109.6 304.8 93789.1 196.0 2631.3 14.6 30.9

Gas in Gas_TM8 3 7/28/18:00 3266 1134.8 3.1 0.3 106.7 318.4 93898.3 181.2 2559.1 14.7 29.1

Gas in total calculated 7/28/08:40 3262 1252.26 2.37 0.00 140.40 8.06 19205.16 44.54 185.51

157

Gas in total calculated 7/28/16:00 3264 1761.89 5.38 0.88 227.36 29.98 17816.48 74.77 381.98

Gas in total calculated 7/28/17:00 3265 1698.33 5.55 0.93 218.55 25.15 16970.65 72.67 372.02

Gas in total calculated 7/28/18:00 3266 1668.30 5.01 0.72 217.55 26.11 16843.42 67.73 362.82

Average GIT 1709.51 5.31 0.84 221.15 27.08 17210.19 71.72 372.27

Average GIO 1676.57 5.22 0.83 218.08 18.17 14629.39 66.42 300.31

Generation GIT 3h 457.25 2.95 0.84 80.75 19.02 (1994.98) 19.83 186.77

Generation GIO 3h 447.71 2.89 0.83 79.58 12.93 (1502.49) 25.22 151.77

AII.31 FR3 300°C thermal test -3 DGA data

Test Temperature Test 3 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml)

V

(V) I (A)

300.00 FR3 3h 29/07/2011 2732.00 0.00 0.40 250.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 7/29/09:00 3281 984.1 2.7 0.0 90.7 156.0 101624.1 144.3 1989.7 15 27.1

Gas in Gas_TM8 1 7/29/14:38 3282 1250.1 3.9 0.6 118.2 364.9 94373.1 196.9 3100.8 14.6 31

Gas in Gas_TM8 2 7/29/15:38 3283 1195.8 3.4 0.0 113.1 366.0 94607.8 190.1 3078.8 14.5 28.1

Gas in total calculated 7/27/13:45 3281 1503.04 4.52 0.00 191.99 12.87 18280.48 55.12 286.53

Gas in total calculated 7/27/17:40 3282 1794.75 6.18 1.39 235.50 30.13 17090.98 72.99 438.50

Gas in total calculated 7/27/18:40 3283 1749.67 5.46 0.00 229.43 29.39 16595.16 70.14 429.58

Average GIT 1772.21 5.82 0.70 232.46 29.76 16843.07 71.57 434.04

Average GIO 1738.54 5.72 0.69 229.28 19.70 14241.80 66.24 348.98

Generation GIT 3h 269.17 1.30 0.70 40.47 16.89 (1437.41) 12.00 147.50

Generation GIO 3h 263.66 1.28 0.69 39.88 11.30 (1130.99) 15.25 119.37

158

AII.32 FR3 400°C thermal test -1 DGA data

Test Temperature Test 1 Oil Type Heating Date Oil Volume

(ml)

Headspac

e (ml) V (V) I (A)

400.00 FR3 1.5h 29/07/201

1 2732.00 1.00 0.54 298.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-

Background

7/29/15:3

8 3283 1195.8 3.4 0.0 113.1 366.0 94607.8 190.1 3078.8 14.5 28.1

Gas in Gas_TM8 1 7/29/19:1

5 3285 1983.8 18.5 0.6 276.0 1898.7 72424.4 463.4 6298.5 14 38.8

Gas in Gas_TM8 2 7/29/20:0

0 3286 1863.0 17.4 0.3 264.2 1769.5 73437.4 446.1 6180.5 14.1 30.3

Gas in Gas_TM8 3 7/29/21:0

0 3287 1818.8 17.5 0.6 261.1 1640.1 74465.0 438.1 6039.3 14.2 27.3

Gas in total calculated 7/29/15:3

8 3283 1749.67 5.46 0.00 229.43 29.39 16595.16 70.14 429.58

Gas in total calculated 7/29/19:1

5 3285 2553.37 26.59 1.22 494.16 159.60 13454.25 163.91 870.73

Gas in total calculated 7/29/20:0

0 3286 2599.79 26.76 0.68 511.49 141.00 12792.42 159.95 844.89

Gas in total calculated 7/29/21:0

0 3287 2625.64 27.70 1.41 522.40 128.82 12728.96 158.54 825.83

Average GIT 2592.93 27.02 1.10 509.35 143.14 12991.88 160.80 847.15

Average GIO 2542.35 26.54 1.09 502.20 95.77 11022.81 148.77 681.75

Generation GIT 1.5h 843.26 21.55 1.10 279.92 113.75 (3603.28) 66.16 417.57

Generation GIO 1.5h 825.65 21.17 1.09 275.88 76.47 (2964.33) 83.87 337.04

AII.33 FR3 400°C thermal test -2 DGA data

Test Temperature Test 2 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml) V (V) I (A)

159

400.00 FR3 3h 08/01/2011 2732.00 1.00 0.60 310.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 01/08/9:00 3346 1161.2 10.7 0.0 170.6 130.5 114811.6 187.9 2469.7 14.9 27

Gas in Gas_TM8 1 01/08/17:36 3348 3005.8 47.8 0.0 596.6 3224.1 58617.9 799.6 9825.8 13.7 33.2

Gas in Gas_TM8 2 01/08/19:07 3350 2790.0 45.5 0.8 563.1 2999.3 61838.6 764.7 9543.2 13.9 30

Gas in Gas_TM8 3 01/08/20:07 3351 2726.9 44.5 0.9 554.1 2811.1 63327.8 742.5 9290.6 13.9 29.3

Gas in total calculated 01/08/9:00 3346 1763.3 17.8 0.0 359.0 10.7 20497.1 71.3 353.2

Gas in total calculated 01/08/17:36 3348 3972.8 69.9 0.0 1095.0 254.8 10169.5 278.0 1313.5

Gas in total calculated 01/08/19:07 3350 3848.4 69.1 1.8 1077.5 235.1 10591.8 270.4 1285.2

Gas in total calculated 01/08/20:07 3351 3784.9 67.9 2.0 1066.6 219.2 10781.7 262.6 1249.2

Average GIT 3848.4 69.5 0.9 1086.2 245.0 10380.7 274.2 1299.4

Average GIO Heating 3793.7 67.8 1.3 1064.6 156.9 8896.3 250.0 1030.5

Generation GIT 3h 2085.1 51.3 1.8 718.4 224.4 (9905.2) 145.3 932.0

Generation GIO 1.5h 2063.5 50.3 1.3 710.4 150.0 (8336.6) 184.1 747.5

AII.34 FR3 500°C thermal test -1 DGA data

Test Temperature Test 1 Oil

Type Heating Date

Oil Volume (ml)

Headspace (ml)

V (V) I (A)

500.00 FR3 20mins 08/04/201

1 2732.00 11.00 1.6 393

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background

4/8/09:40

3392 352.9 16.9 0.0 18.2 270.2 143295.7 27.2 133.7 10.7 28.6

Gas in Gas_TM8 1 4/8/14:20

3396 1292.2 115.0 0.0 434.3 1189.5 99915.7 588.3 5819.8 11 31.6

Gas in Gas_TM8 2 4/8/15:20

3397 1242.8 111.3 0.6 419.2 1118.0 100357.5 564.2 5661.5 11.2 30.2

160

Gas in Gas_TM8 3 4/8/16:20

3398 1214.0 109.9 0.0 412.5 1064.1 100984.0 556.6 5491.1 11.3 29.6

Gas in total calculated 4/8/09:40

3392 379.3 20.0 0.0 27.1 16.1 18629.0 7.4 13.8

Gas in total calculated 4/8/14:20

3396 1394.2 137.0 0.0 649.9 77.8 13998.3 166.0 638.1

Gas in total calculated 4/8/15:20

3397 1382.2 136.4 1.1 646.4 73.8 14149.9 162.3 630.2

Gas in total calculated 4/8/16:20

3398 1369.5 136.4 0.0 645.0 70.6 14293.4 161.6 615.9

Average GIT 1382.0 136.6 0.4 647.1 74.1 14147.2 163.3 628.0

Average GIO 1351.9

1 133.89 0.35 636.92 47.02 11729.59 149.56 491.89

Generation GIT 20mins 1002.7 116.6 0.4 620.0 58.0 (4481.8) 113.7 614.3

Generation GIO 20mins 979.75 114.27 0.35 610.17 36.44 (3989.31

) 142.71 480.83

AII.35 FR3 500°C thermal test -2 DGA data

Test Temperature Test 2 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml) V (V) I (A)

500.00 FR3 30mins 08/05/2011 2732.00 16.00 1.70 424.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 05/08/9:30 3401 1029.7 89.2 0.7 334.6 519.6 119299.5 411.3 4089.8 12 28.2

Gas in Gas_TM8 1 05/08/16:00 3403 2053.2 175.4 0.3 664.0 1229.5 84681.5 899.9 8398.9 13.6 31

Gas in Gas_TM8 2 05/08/17:00 3404 1894.2 162.8 0.7 621.1 1144.1 86843.8 846.4 7944.3 14.2 28.7

Gas in Gas_TM8 3 05/08/18:00 3405 1791.0 154.7 0.0 591.9 1019.0 89805.0 800.7 7491.9 14.7 28

161

Gas in total calculated 05/08/9:30 3401 1245.75 118.51 1.38 561.25 34.56 17333.41 125.58 472.36

Gas in total calculated 05/08/16:00 3403 2756.77 259.71 0.65 1235.84 101.10 14736.05 315.55 1151.07

Gas in total calculated 05/08/17:00 3404 2710.25 255.92 1.62 1230.98 96.77 15482.25 310.43 1131.48

Gas in total calculated 05/08/18:00 3405 2669.49 253.04 0.00 1221.77 88.82 16477.77 304.18 1103.03

Average GIT 2712.17 256.22 0.76 1229.53 95.56 15565.36 310.05 1128.53

Average GIO 2650.29 250.91 0.75 1209.28 59.01 12739.52 282.58 871.44

Generation GIT 30mins 1466.42 137.72 (0.62) 668.28 61.01 (1768.05) 134.61 656.16

Generation GIO 30mins 1428.03 134.43 (0.61) 655.67 36.30 (1873.13) 166.38 492.35

AII.36 FR3 600°C thermal test -1 DGA data

Test Temperature Test 1 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml) V (V) I (A)

600.00 FR3 1.5min 08/08/2011 2732.00 7.00 2.9 550

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 8/8/13:26 3407 770.1 3.8 0.0 27.4 0.0 114493.1 7.1 383.2 10.2 27.1

Gas in Gas_TM8 1 8/8/16:09 3411 1044.3 150.1 0.0 152.5 447.4 108238.4 492.3 2231.0 10.7 27

Gas in Gas_TM8 2 8/8/17:09 3412 1021.7 144.7 0.8 148.1 423.8 108680.6 463.7 2167.2 10.8 26.8

Gas in Gas_TM8 3 8/8/18:09 3413 1007.2 140.7 0.6 145.0 408.4 109239.2 459.3 2081.2 11 26.7

Gas in total calculated 8/8/13:26 3407 799.81 4.33 0.00 39.44 0.00 14004.87 1.84 37.53

Gas in total calculated 8/8/16:09 3411 1140.72 179.67 0.00 230.76 27.13 14077.56 135.06 233.27

Gas in total calculated 8/8/17:09 3412 1128.50 175.08 1.44 226.59 25.91 14242.72 128.42 228.62

Gas in total calculated 8/8/18:09 3413 1134.11 173.52 1.10 226.15 25.41 14568.53 129.57 223.56

Average GIT 1134.45 176.09 0.85 227.83 26.15 14296.27 131.01 228.48

Average GIO 1111.34 172.82 0.84 224.48 16.53 11843.12 120.37 179.77

Generation GIT 90s 334.64 171.77 0.85 188.39 26.15 291.40 94.26 190.96

162

Generation GIO 90s 326.51 168.57 0.84 185.57 16.53 65.86 118.67 149.70

AII.37 FR3 600°C thermal test -2 DGA data

Test Temperature Test 2 Oil

Type Heating Date

Oil

Volume

(ml)

Headspace

(ml)

V

(V) I (A)

600.00 FR3 1.5min 08/09/2011 2732.00 10.00 2.90 554.00

Gas Type Time No. CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO P T

Gas in Gas_TM8-Background 09/08/12:10 3415 636.1 31.9 0.7 38.8 15.0 138702.4 45.8 267.7 13.8 34.3

Gas in Gas_TM8 1 09/08/14:15 3417 880.9 137.5 1.0 137.2 294.1 132446.7 392.2 1700.3 13.8 34.7

Gas in Gas_TM8 2 09/08/15:15 3418 859.2 132.9 0.9 134.0 297.5 132014.7 378.4 1600.6 13.9 34.5

Gas in total calculated 05/08/9:30 3415 838.59 46.64 1.48 71.06 1.20 24418.68 16.01 36.04

Gas in total calculated 05/08/16:00 3417 1160.23 200.92 2.10 250.89 24.55 23837.73 138.36 234.80

Gas in total calculated 05/08/17:00 3418 1141.83 195.89 1.91 247.23 24.98 23892.89 134.48 222.54

Average GIT 1151.03 198.40 2.01 249.06 24.77 23865.31 136.42 228.67

Average GIO 1151.03 198.40 2.01 249.06 24.77 23865.31 136.42 228.67

Generation GIT 90s 312.44 151.76 0.53 178.00 23.57 (553.38) 87.86 192.63

Generation GIO 90s 328.79 152.58 0.55 179.00 23.95 3012.22 121.59 199.51

AII.38 Gemini X sparking tests energy

test 1

BD

number lf number Energy(J) hf number Energy(J)

BD 1 WASCO0144 1.68 Xiao0866 0.00

BD 2 WASCO0145 1.85

BD 3 WASCO0146 1.36

163

BD 4 WASCO0147 1.81

BD 5 WASCO0148 1.40

BD 6 WASCO0149 1.69

BD 7 WASCO0150 1.76

BD 8 WASCO0151 3.22 XIAO0869 1.10

BD 9 WASCO0152 3.04 XIAO0870 0.79

BD 10 WASCO0153 1.34 XIAO0871 0.25

BD 11 WASCO0154 1.24 XIAO0872 0.40

BD 12 WASCO0155 1.78 XIAO0873 1.60

BD 13 WASCO0156 3.55 XIAO0874 2.09

BD 14

BD 15

test 2

BD 16 WASCO0157 1.77 XIAO0875 2.02

BD 17 WASCO0158 1.37 XIAO0876 1.07

BD 18 WASCO0159 1.64 XIAO0877 1.42

BD 19 WASCO0160 1.63 XIAO0878 1.79

BD 20 WASCO0161 1.51 XIAO0879 1.42

BD 21 WASCO0162 4.01 XIAO0880 2.24

BD 22 WASCO0163 1.77 XIAO0881 1.64

BD 23 WASCO0164 1.92 XIAO0882 2.25

BD 24 WASCO0165 1.30 XIAO0883 1.04

BD 25 WASCO0166 4.93 XIAO0884 1.55

BD 26 WASCO0167 1.75 XIAO0885 1.73

BD 27 WASCO0168 1.81 XIAO0886 1.89

BD 28 WASCO0169 2.04 XIAO0887 2.30

BD 29 WASCO0170 1.92 XIAO0888 2.07

BD 30

test 3

BD 1 WASCO0171 1.17 XIAO0889 0.95

BD 2 WASCO0172 1.76 XIAO0890 1.82

BD 3 WASCO0173 1.75 XIAO0891 1.81

BD 4 WASCO0174 1.78 XIAO0892 1.89

BD 5 WASCO0175 1.47 XIAO0893 1.55

BD 6 WASCO0176 1.69 XIAO0894 1.90

164

BD 7 WASCO0177 1.76 XIAO0895 1.89

BD 8 WASCO0178 5.13 XIAO0896 1.94

BD 9 WASCO0179 1.71 XIAO0897 1.91

BD 10 WASCO0180 1.45 XIAO0898 1.45

BD 11 WASCO0181 1.54 XIAO0899 1.60

BD 12 WASCO0183 1.80 XIAO0900 1.87

BD 13 WASCO0184 1.72 XIAO0901 1.75

BD 14 WASCO0185 1.82 XIAO0902 2.11

BD 15

test 4

BD 1 WASCO0186 1.83 XIAO0903 1.96

BD 2 WASCO0187 1.71 XIAO0904 2.08

BD 3 WASCO0188 1.78 XIAO0905 1.97

BD 4 WASCO0189 1.69 XIAO0906 1.69

BD 5 WASCO0190 1.93 XIAO0907 2.04

BD 6 WASCO0191 1.80 XIAO0908 2.01

BD 7 WASCO0192 0.00 XIAO0909 2.29

BD 8 WASCO0193 0.00 XIAO0910 1.52

BD 9 WASCO0194 1.82 XIAO0911 2.00

BD 10 WASCO0195 1.62 XIAO0912 1.89

BD 11 WASCO0196 1.65 XIAO0913 1.74

BD 12 WASCO0197 1.86 XIAO0914 1.81

BD 13 WASCO0198 1.70 XIAO0915 1.73

BD 14 WASCO0199 1.80 XIAO0916 1.93

BD 15 WASCO0200 1.73 XIAO0917 1.66

test 5

BD 1 WASCO0201 1.77 XIAO0918 2.04

BD 2 WASCO0202 1.80 XIAO0919 2.21

BD 3 WASCO0203 1.84 XIAO0920 2.12

BD 4 WASCO0204 1.84 XIAO0921 2.12

BD 5 WASCO0205 1.84 XIAO0922 2.00

BD 6 WASCO0206 1.87 XIAO0923 1.32

BD 7 WASCO0207 1.47 XIAO0924 1.77

BD 8 WASCO0208 1.80 XIAO0925 1.32

BD 9 WASCO0209 1.38 XIAO0926 1.97

165

BD 10 WASCO0210 1.74 XIAO0927 1.85

BD 11 WASCO0211 1.70 XIAO0928 1.80

BD 12 WASCO0212 1.70 XIAO0929 2.03

BD 13 WASCO0213 1.81 XIAO0930 1.70

BD 14 WASCO0214 1.66 XIAO0931 1.94

BD 15 WASCO0215 1.74 XIAO0932 1.90

AII.39 FR3 sparking tests energy

Test

BD

number lf number Energy(J) hf number Energy(J)

1

BD 1 wasc0016 1.78

BD 2 XIAO0742 1.22

BD 3 XIAO0743 1.27

BD 4 XIAO0744 1.22

BD 5 wasc0017 1.63 XIAO0745 1.30

BD 6 wasc0018 1.47 XIAO0746 1.16

BD 7

BD 8 wasc0019 1.74 XIAO0747 1.34

BD 9 wasc0020 1.67 XIAO0748 1.29

BD 10 wasc0021 1.48 XIAO0749 1.13

BD 11

BD 12

BD 13

BD 14

BD 15 wasc0022 4.04 XIAO0750 1.14

2

BD 16 wasc0023 1.59 XIAO0751 1.26

BD 17 wasc0024 1.59 XIAO0752 1.29

BD 18 wasc0025 1.75 XIAO0753 1.28

BD 19 wasc0026 1.61 XIAO0754 1.22

BD 20 wasc0027 1.70 XIAO0755 1.34

BD 21 wasc0028 1.63 XIAO0756 1.26

BD 22 wasc0029 1.62 XIAO0757 1.34

166

BD 23 wasc0030 1.61 XIAO0758 1.26

BD 24 wasc0031 1.77 XIAO0759 1.37

BD 25 wasc0032 1.59 XIAO0760 1.29

BD 26 wasc0033 1.63 XIAO0761 1.08

BD 27 wasc0034 1.69 XIAO0762 1.32

BD 28 wasc0035 1.60 XIAO0763 1.22

BD 29 wasc0036 1.69 XIAO0764 1.17

BD 30 wasc0037 1.43 XIAO0765 1.11

3

BD 1 wasc0038 1.56 xaio0766

BD 2 wasc0039 1.57 xaio0767

BD 3 wasc0040 1.45 xaio0768

BD 4 wasc0041 1.67 xaio0769

BD 5 wasc0042 1.55 xaio0770

BD 6 wasc0043 1.50 xaio0771

BD 7 wasc0044 1.44 xaio0772

BD 8 wasc0045 1.60 xaio0773

BD 9 wasc0046 1.56 xaio0774

BD 10 wasc0047 1.36 xaio0775

BD 11 wasc0048 1.54 xaio0776

BD 12 wasc0049 1.59 xaio0777

BD 13 wasc0050 1.42 xaio0778

BD 14 wasc0051 1.65 xaio0779

BD 15 wasc0052 1.57 xaio0780

4

BD 1 wasc0054 1.62 XIAO0781 1.00

BD 2 wasc0055 1.46 XIAO0782 1.18

BD 3 wasc0057 1.54 XIAO0783

BD 4 wasc0058 1.62 XIAO0784

BD 5 wasc0059 1.49 XIAO0785

BD 6 wasc0061 1.46 XIAO0786

BD 7 wasc0062 1.76 XIAO0787

BD 8 wasc0063 1.58 XIAO0788 1.05

BD 9 wasc0064 1.66 XIAO0789 1.13

167

BD 10 wasc0065 1.75 XIAO0790 1.07

BD 11 wasc0066 1.69 XIAO0791 1.21

BD 12 wasc0067 1.63 XIAO0792 1.23

BD 13 wasc0068 1.70 XIAO0793 1.22

BD 14 wasc0069 1.72 XIAO0794 1.16

BD 15 wasc0070 1.72 XIAO0795 1.14

5

BD 1 wasc0101 1.47 XIAO0822 1.21

BD 2 wasc0102 1.57 XIAO0823 1.24

BD 3 wasc0103 1.64 XIAO0824 1.12

BD 4 wasc0104 1.79 XIAO0825 1.21

BD 5 wasc0105 1.68 XIAO0826 1.13

BD 6 wasc0106 1.70 XIAO0827 1.29

BD 7 wasc0107 1.51 XIAO0828 1.08

BD 8 wasc0108 1.58 XIAO0829 1.24

BD 9 wasc0109 XIAO0830 1.09

BD 10 wasc0110 1.60 XIAO0831 1.25

BD 11 wasc0111 1.57 XIAO0832 1.26

BD 12 wasc0112 1.60 XIAO0833 1.27

BD 13 wasc0113 1.72 XIAO0834 1.29

BD 14 wasc0114 1.83 XIAO0835 1.51

BD 15 wasc0115 1.82 XIAO0836 1.34

6

BD 1 wasc0129 1.40 XIAO0851 0.81

BD 2 wasc0130 1.38 XIAO0852 0.99

BD 3 wasc0131 1.45 XIAO0853 0.69

BD 4 wasc0132 1.41 XIAO0854 1.01

BD 5 wasc0133 1.38 XIAO0855 0.62

BD 6 wasc0134 1.34 XIAO0856 0.58

BD 7 wasc0135 1.35 XIAO0857 0.63

BD 8 wasc0136 1.22 XIAO0858 0.91

BD 9 wasc0137 1.40 XIAO0859 1.08

BD 10 wasc0138 1.51 XIAO0860 1.04

BD 11 wasc0139 1.46 XIAO0861 1.02

168

BD 12 wasc0140 1.22 XIAO0862 0.39

BD 13 wasc0141 1.51 XIAO0863 0.82

BD 14 wasc0142 1.42 XIAO0864 0.96

BD 15 wasc0143 1.29 XIAO0865 0.55

AII.40 Gemini X PD test -1 energy

1500pC 50kV

Time

9-

369min

369-

969min

1449-

1749min

1749-

2349min

2590-

2890min

2890-

3190min

PD Attitude 1407 1486.9 1466.1 1528.49 1438.37 1466.1

PD number 7970 14044 6113 9778 4477 4350

Power(mW) 0.032752 0.02018 0.017539 0.014433 0.013045 0.01302

PD current 0.000001 0 0 0 0 0

Energy 0.403727 0.727004 0.315035 0.511059 0.23461 0.234253

Energy below 1000 0.348365 0.564099 0.244025 0.384345 0.180944 0.178995

Energy from 1000 to 2000 0.055363 0.162905 0.071009 0.126714 0.053666 0.055258

Energy from 2000 to 3000

Energy from 3000 to 4000

Energy from 4000 to 5000

Energy from 5000 to 6000

AII.41 Gemini X PD test -2 energy

2000pc 58kV

Time 2-62min 63-123min

124-

184min

185-

305min

337-

1358min

PD Attitude 1860.4 2208.01 2149.26 2286.34 2139.47

PD number 1421 3978 5686 10976 48040

Power(mW) 0.02377 0.083638 0.123514 0.12023 0.059723

PD current 0 0.000001 0.000002 0.000002 0.000001

Energy 0.07564 0.300275 0.444146 0.86466 3.655812

169

Energy below 1000 0.043686 0.131333 0.169526 0.325465 0.957189

Energy from 1000 to 2000 0.031954 0.168418 0.274273 0.53815 2.695214

Energy from 2000 to 3000 0.001045 0.003409

Energy from 3000 to 4000

Energy from 4000 to 5000

Energy from 5000 to 6000

AII.42 Gemini X PD test -3 energy

3000pC 50kV

Time

3210-

3215min

3215-

3218min

3218-

3221min

3221-

3224min

3225-

3285min

3285-

3345min

3345-

4045min

4047-

4287min

4287-

4357min

4357-

5357min

5357-

5362min

PD Attitude 2531.13 2100.3 2256.96 2403.84 3074.56 2413.63 3099.04 2922.79 2462.59 3148 2007.28

PD number 206 80 149 164 2204 1919 17440 5816 1532 19800 89

Power(mW)

0.06484

2

0.04101

7

0.07387

2

0.08375

2

0.05598

1

0.04760

9

0.03725

4

0.03565

1

0.03197

4

0.02917

5

0.02555

1

PD current

0.00000

1

0.00000

1

0.00000

1

0.00000

1

0.00000

1

0.00000

1

0.00000

1

0.00000

1

0.00000

1 0 0

Energy

0.01926

7

0.00697

6

0.01315

1

0.01468

3

0.20142

4

0.17073

9

1.56448

9 0.51348

0.13419

6

1.74960

2

0.00751

9

Energy below

1000

0.00089

8 0.00076

0.00076

5

0.00080

9

0.00952

1 0.01995

0.14508

7

0.04569

6

0.01599

6

0.20944

1

0.00053

4

Energy from

1000 to 2000

0.01668

6

0.00564

6

0.01211

2

0.01313

2

0.18150

5

0.14588

5

1.36821

8

0.45193

1

0.11499

3

1.48906

3

0.00685

7

Energy from

2000 to 3000

0.00168

3 0.00057

0.00027

5

0.00074

2

0.01018

8

0.00490

4 0.05097

0.01585

3

0.00320

7

0.05061

6

0.00012

9

Energy from

3000 to 4000 0.00021

0.00021

4

0.00048

2

Energy from

4000 to 5000

Energy from

5000 to 6000

AII.43 Gemini X PD test -4 energy

170

4000pc 58kV

Time 1-31min 32-62min 63-93min

94-

124min

125-

155min

156-

186min

186-

1146min

PD Attitude 3545.68 3545.68 3545.68 3545.68 3545.68 3545.68 4440.49

PD number 2496 1935 2388 2910 2533 2758 61255

Power(mW) 0.166666 0.137344 0.165138 0.165928 0.145456 0.158171 0.130842

PD current 0.000002 0.000002 0.000002 0.000002 0.000002 0.000002 0.000002

Energy 0.300003 0.246909 0.297593 0.298259 0.261372 0.283743 7.528894

Energy below 1000 0.024767 0.007095 0.031721 0.06056 0.065623 0.087698 0.931736

Energy from 1000 to 2000 0.174608 0.129074 0.154227 0.146039 0.116079 0.113735 3.534853

Energy from 2000 to 3000 0.099446 0.108266 0.109014 0.090555 0.077525 0.08092 3.014477

Energy from 3000 to 4000 0.001181 0.002475 0.002631 0.001106 0.002145 0.00139 0.044091

Energy from 4000 to 5000 0.003736

Energy from 5000 to 6000

PD number below 1000 287 122 279 855 751 877 9678

PD number from 1000 to 2000 1413 1146 1241 1276 1075 1096 27831

PD number from 2000 to 3000 787 657 849 769 690 771 23387

PD number from 3000 to 4000 9 10 19 10 17 14 333

PD number from 4000 to 5000 26

PD number from 5000 to 6000

AII.44 FR3 PD test -1 energy

1000pc-1 34kV

Time 5min 12min 25min 50min 61min 95min 116min 125min 141min 156min 176min

PD Attitude 1071.79 1127.38 1235.08 1266.34 1339.3 1200.33 1231.6 1266.34 1224.65 1224.65 1318.46

PD number 1702 2177 1386 959 889 826 722 757 666 511 546

Power(mW) 0.457662 0.636786 0.534047

0.41160

7

0.39141

5

0.36325

6

0.33288

1 0.35101

0.32201

6

0.25007

5

0.27449

8

171

PD current 0.000011 0.000015 0.000012

0.00000

9

0.00000

9

0.00000

8

0.00000

7

0.00000

8

0.00000

7

0.00000

6

0.00000

6

Energy(J) 0.027267 0.038067 0.031893

0.02453

2

0.02339

1

0.02174

4

0.01986

6

0.02088

5

0.01931

4 0.01501

0.01639

3

Energy below 1000 0.027168 0.037525 0.030285 0.02163

0.02040

4

0.01911

6

0.01649

9 0.01813

0.01552

5

0.01261

6

0.01238

8

Energy from 1000 to

2000 0.0001 0.000543 0.001608

0.00290

1

0.00298

7

0.00262

8

0.00336

8

0.00275

6

0.00378

9

0.00239

4

0.00400

5

1000pc-1 34kV

Time 191min 210min 261min 281min 296min 310min 341min 357min 372min 390min

PD Attitude 1308.03 1228.13 1255.92 1255.92 1297.61 1269.82 1276.77 1314.98 1262.87 1321.93

PD number 500 570 438 498 441 488 448 476 485 474

Power(mW) 0.248928 0.285772 0.229005

0.24823

1

0.22833

4

0.25201

6

0.23712

4

0.23345

5

0.24800

6

0.26017

1

PD current 0.000006 0.000006 0.000005

0.00000

6

0.00000

5

0.00000

6

0.00000

5

0.00000

5

0.00000

6

0.00000

6

Energy(J) 0.014796 0.017003 0.01363

0.01480

4

0.01364

5

0.01507

6

0.01418

9

0.01373

6

0.01477

1

0.01450

2

Energy below 1000 0.011737 0.013617 0.010587

0.01212

1

0.01035

8

0.01186

8

0.01097

5 0.01139

0.01177

8

0.01071

6

Energy from 1000 to

2000 0.00306 0.003387 0.003043

0.00268

3

0.00328

7

0.00320

8

0.00321

4

0.00234

7

0.00299

3

0.00378

6

AII.45 FR3 PD test -2 energy

1000pc-2 34kV

Time 1min 16min 31min 46min 61min 76min 91min 106min 121min 136min

PD Attitude 1030.1 1210.76 1259.39 1224.65 1148.22 1134.32 1189.91 1176.01 1165.59 1217.7

PD number 332 354 357 416 343 390 359 384 314 353

Power(mW)

0.14161

6

0.16367

9 0.16394

0.19253

8

0.16419

8

0.18161

5

0.16478

3

0.17307

1

0.14610

7

0.16528

9

PD current

0.00000

3

0.00000

4

0.00000

4

0.00000

4

0.00000

4

0.00000

4

0.00000

4

0.00000

4

0.00000

3

0.00000

4

Energy(J)

0.00847

7

0.00968

3

0.00981

7

0.01151

4

0.00980

3

0.01078

8

0.00984

7

0.01032

9

0.00873

7

0.00978

5

172

Energy below 1000

0.00838

3

0.00869

4

0.00861

9

0.01018

3

0.00858

4

0.00979

3

0.00904

7

0.00955

7

0.00789

8 0.00887

Energy from 1000 to

2000

0.00009

4

0.00098

9

0.00119

8

0.00133

1

0.00121

8

0.00099

5 0.0008

0.00077

2

0.00083

9

0.00091

5

1000pc-2 34kV

Time 151min 166min 181min 226min 241min 301min 316min 331min 346min 361min

PD Attitude 1155.17 1266.34 1224.65 1221.18 1280.24 1214.23 1231.6 1221.18 1210.76 1207.28

PD number 336 311 292 335 342 406 358 370 320 331

Power(mW) 0.14575

0.14869

8

0.13575

9

0.16023

5

0.16284

3

0.19350

1

0.18053

5

0.18401

8

0.15551

6

0.16411

8

PD current

0.00000

3

0.00000

3

0.00000

3

0.00000

4

0.00000

4

0.00000

4

0.00000

4

0.00000

4

0.00000

4

0.00000

4

Energy(J)

0.00873

8

0.00884

8

0.00806

7

0.00959

2

0.00972

5

0.01157

1

0.01083

9 0.01096

0.00924

4

0.00978

5

Energy below 1000

0.00828

8

0.00804

6 0.00712

0.00818

7

0.00814

2

0.01015

8

0.00887

4

0.00953

6

0.00778

6

0.00810

6

Energy from 1000 to

2000 0.00045

0.00080

2

0.00094

6

0.00140

5

0.00158

3

0.00141

3

0.00196

5

0.00142

4

0.00145

8

0.00167

9

AII.46 FR3 PD test -3 energy

2000pc-1 44kV

Time 1min 16min 31min 46min 61min 76min 91min

106mi

n

121mi

n

136mi

n

151mi

n

166mi

n

181mi

n

PD Attitude 2193.9

5

2076.1

1

2089.9

8

2270.2

1

2089.9

8

2166.2

3

2076.1

1

2270.2

1

2103.8

4

1992.9

3

2058.7

8 2311.8

2166.2

3

PD number 846 760 674 680 698 562 694 776 638 651 791 802 912

Power(mW) 0.7896

97

0.7045

29

0.6288

6

0.6144

38

0.6392

45

0.5227

78

0.6175

14

0.6894

08

0.5721

35

0.5664

72

0.6830

62

0.6927

68

0.7589

6

PD current 0.0000

14

0.0000

13

0.0000

11

0.0000

11

0.0000

12

0.0000

1

0.0000

11

0.0000

12

0.0000

1

0.0000

1

0.0000

12

0.0000

12

0.0000

14

Energy(J)

0.0475

13

0.0417

34

0.0381

24

0.0362

26

0.0382

92

0.0308

86

0.0374

08

0.0415

14

0.0340

95

0.0338

03

0.0408

86

0.0415

3

0.0458

76

Energy below 1000

0.0207

33

0.0179

32

0.0163

89

0.0171

29

0.0163

31

0.0141

95

0.0167

79

0.0199

47

0.0155

79

0.0167

19

0.0208

5

0.0212

02

0.0246

59

173

Energy from 1000

to 2000

0.0264

1

0.0237

73

0.0215

28

0.0189

2

0.0218

33

0.0165

07

0.0205

4

0.0214

61

0.0183

14

0.0170

83

0.0198

6

0.0202

68

0.0209

8

Energy from 2000

to 3000

0.0003

7

0.0000

28

0.0002

06

0.0001

77

0.0001

27

0.0001

84

0.0000

9

0.0001

05

0.0002

02

0.0001

76

0.0000

6

0.0002

37

AII.47 FR3 PD test -4 energy

2000pc-2 44kV

Time 1min 16min 31min 46min 61min 76min 91min 106min 121min 151min 165min 181min 196min 235min

PD Attitude

2207.8

2

2242.4

8

2166.2

3 2291

2089.9

8

2079.5

8

2145.4

3

2270.2

1

2055.3

2

2187.0

2

2367.2

5

2270.2

1 2138.5

2155.8

3

PD number 949 949 889 884 825 983 969 911 856 1009 1027 1040 1019 994

Power(mW)

0.9262

83

0.8613

69

0.8235

89

0.8132

85 0.7627

0.8152

38

0.8332

14

0.8140

92

0.7778

19

0.8459

42

0.8646

91

0.8623

73

0.8361

48

0.8372

86

PD current

0.0000

17

0.0000

16

0.0000

15

0.0000

15

0.0000

14

0.0000

15

0.0000

15

0.0000

14

0.0000

14

0.0000

15

0.0000

15

0.0000

15

0.0000

15

0.0000

15

Energy(J) 0.0550

26

0.0516

15

0.0492

24

0.0484

4

0.0453

28

0.0497

04

0.0493

85

0.0482

39

0.0461

7

0.0514

5

0.0520

64

0.0508

91

0.0500

61

0.0507

09

Energy below 1000 0.0217

0.0254

78

0.0225

26

0.0229

89

0.0208

81

0.0272

13

0.0266

64

0.0237

37

0.0217

3

0.0274

05

0.0289

59

0.0286

05

0.0289

97

0.0276

31

Energy from 1000 to

2000

0.0329

63

0.0259

9

0.0263

32

0.0252

15

0.0244

19

0.0222

52

0.0224

22

0.0243

07

0.0243

37

0.0239

19

0.0227

33

0.0221

24

0.0208

56

0.0229

68

Energy from 2000 to

3000

0.0003

62

0.0001

47

0.0003

66

0.0002

36

0.0000

29

0.0002

4

0.0002

98

0.0001

95

0.0001

04

0.0001

26

0.0003

73

0.0001

61

0.0002

08

0.0001

1

AII.48 FR3 PD test -5 energy

3000pc-1 57kV

Time 1min 2min 17min 32min 47min

PD Attitude 3028.99 3194.96 3216.54 3524.98 3559.25

PD number 6388 6574 5913 5231 4839

Power(mW) 6.542552 6.85363 6.170048 5.637501 5.442414

PD current 0.000099 0.000104 0.000091 0.000082 0.000078

Energy(J) 0.390106 0.407393 0.369871 0.339017 0.326013

Energy below 1000 0.271986 0.286327 0.265127 0.239425 0.225482

Energy from 1000 to 2000 0.081202 0.078602 0.064186 0.062601 0.06157

174

Energy from 2000 to 3000 0.03686 0.041724 0.039785 0.03551 0.03552

Energy from 3000 to 4000 0.000058 0.00074 0.000773 0.001481 0.003442

AII.49 FR3 PD test -6 energy

3000pc-2 57kV

Time 1min 3min 16min 31min 46min 76min 91min 105min 120min

PD Attitude 3500.5 3451.54 3412.37 3387.89 3559.25 3441.75 3368.31 3451.54 3451.54

PD number 3284 2978 3495 3289 3320 3194 3009 3119 3135

Power(mW) 3.133418 2.944347 3.725295 3.377506 3.534698 3.492992 3.134563 3.344037 3.448978

PD current 0.000044 0.000042 0.000053 0.000048 0.00005 0.00005 0.000045 0.000047 0.000049

Energy(J) 0.186918 0.180206 0.223178 0.20066 0.212876 0.210771 0.190181 0.199089 0.206235

Energy below 1000 0.147386 0.138484 0.167518 0.153773 0.157311 0.151758 0.140483 0.148291 0.150484

Energy from 1000 to 2000 0.020772 0.020565 0.031543 0.026743 0.031572 0.034984 0.029602 0.03264 0.035384

Energy from 2000 to 3000 0.018033 0.020801 0.022418 0.018876 0.022068 0.021818 0.018991 0.016888 0.018123

Energy from 3000 to 4000 0.000727 0.000357 0.001698 0.001268 0.001924 0.002211 0.001106 0.00127 0.002244

AII.50 FR3 PD test -7 energy

3000pc-3 57kV

Time 1min 2min 16min 31min 46min 61min

PD Attitude 2584.98 2707.38 2922.79 3241.02 3304.67 3544.56

PD number 4137 4921 5588 6245 6134 5892

Power(mW) 4.87019 5.395667 5.960676 6.380814 6.25298 6.036548

PD current 0.000074 0.000081 0.00009 0.000094 0.00009 0.000087

Energy(J) 0.281478 0.326109 0.356629 0.381429 0.376218 0.360791

Energy below 1000 0.131544 0.194031 0.231971 0.271918 0.276471 0.268962

Energy from 1000 to 2000 0.14074 0.118595 0.09642 0.070709 0.057117 0.052708

Energy from 2000 to 3000 0.009194 0.013483 0.028237 0.038641 0.042239 0.0374

Energy from 3000 to 4000 0.00039 0.001721

175

AII.51 FR3 PD test -8 energy

4000pc-2 61kV

Time 1min 2min 17min 32min 47min 62min

PD Attitude 4315.27 3755.1 3962.58 6085.64 7067.64 5380.26

PD number 5270 5620 6186 6157 5444 5047

Power(mW) 6.702896 7.037141 7.564214 8.226669 7.524878 6.964843

PD current 0.000092 0.000098 0.000104 0.000112 0.000102 0.000094

Energy 0.40607 0.421873 0.450036 0.493855 0.450005 0.41623

Energy below 1000 0.263138 0.282599 0.304134 0.316951 0.277161 0.264822

Energy from 1000 to 2000 0.080348 0.077805 0.090108 0.110259 0.108734 0.09615

Energy from 2000 to 3000 0.049075 0.049464 0.037758 0.039962 0.037224 0.029606

Energy from 3000 to 4000 0.013252 0.012006 0.018036 0.026262 0.026375 0.024789

Energy from 4000 to 5000 0.000257 0.000421 0.000486 0.000696

Energy from 5000 to 6000 0.000025 0.000168

AII.52 Sparking test laboratory comparison

Oil type Gas-in-oil (ppm)

FR3 CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO

TM8 sample 513.4 24.0 197.3 3.0 80.4 14190.4 12.1 53.5

Laboratory sample 592 19 151 3 59 59060 8 34

Laboratory / TM8 115.31% 79.08% 76.52% 99.84% 73.43% 416.20% 65.91% 63.60%

AII.53 PD test laboratory comparison

Oil type Gas-in-oil(ppm)

Mineral CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO

176

TM8 sample 498 12 41 12 46 18118 23 9

Laboratory sample 1 1035 17 44 10 58 20819 24 10

Laboratory sample2 820 13 27 7 57 20206 19 9

Laboratory average 928 15 36 9 58 20513 22 10

Laboratory / TM8 186.31% 125.35% 86.98% 71.07% 124.14% 113.22% 91.55% 105.69%

AII.54 Thermal test laboratory comparison

Oil type Gas-in-oil(ppm)

Mineral CO2 C2H4 C2H2 C2H6 H2 O2 CH4 CO

TM8 sample 1163.82 6149.45 58.56 1060.74 945.86 14751.58 2956.23 186.84

Laboratory

sample 1 1058 6798 67 961 928 29506 4033 99

Laboratory

sample2 933 5889 55 836 924 20823 3614 77

Laboratory

average 995.5 6343.5 61 898.5 926 25164.5 3823.5 88

Laboratory /

TM8 85.54% 103.16% 104.17% 84.70% 97.90% 170.59% 129.34% 47.10%


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