480 Mallika, B. Ganesh
International Journal of Engineering Technology Science and Research
IJETSR
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October 2017
Study On Effect Of Chemical Stabilizing Agents On Strength
And Swelling Properties Of Soils
Mallika1, B. Ganesh2 1M.Tech student (14961D87 ), Lenora Engineering college, Rampachodavaram, A.P, India
2Assistant Professor, Department of Civil Engineering,
Lenora Engineering College, Rampachodavaram, A.P, India
ABSTRACT
In India, expansive soils popularly known as black cotton soils are highly problematic, as they swell on absorption of
water and shrink on evaporation thereof. Because of this alternate swell and shrinkage, distress is caused to the
foundations of structures laid on such soils. Understanding the behavior of expansive soil and adopting the appropriate
control measures have been great task for the geotechnical engineers. Proper characterization and selection of suitable
foundation is essential in case of problematic soils. Extensive research is going on to find the solutions to black cotton
soils. There have been many methods available to control the expansive nature of the soils. Treating the expansive soil
with electrolytes are one of the technique to improve the behavior of the expansive ground. Hence, in the present work,
experimentation is carried-out to investigate the influence of electrolytes like calcium chloride and ferric chloride on the
properties of expansive soil. A methodical process, involving experimentation in the laboratory under controlled
conditions is done. With addition of electrolytes to the expansive soil, improvement in its physical and engineering
properties is observed. It is observed that the maximum improvement in properties of expansive soil is obtained for
Ferric Chloride treatment compared to other electrolytes tried in this investigation
Key words: Calcium chloride and ferric chloride Electrolytes, black cotton soil, Ferric Chloride.
1. INTRODUCTION
Expansive soil is one among the problematic soils that has a high potential for shrinking or swelling due to
change of moisture content. Expansive soils can be found on almost all the continents on the Earth.
Destructive results caused by these soils have been reported in many countries. In India, large tracts are
covered by expansive soils known as black cotton soils. The major area of their occurrence is the south
Vindhyachal range covering almost the entire Deccan Plateau. These soils cover an area of about 200,000
square miles and thus form about 20% of the total area of India. To a large extent they are found in regions
having low to medium slope and poor drainage conditions. The primary bed rock is basalt or trap and in some
locations quartizites, schists and sedimentary rocks are found. It is expensive in nature due to the presence of
montmorillonite and illite clay minerals. Some of these black cotton soils are also found to contain high
amount of carbonates. The depth of black cotton soils can be as high as 20m.
The primary problem that arises with regard to expansive soils is that deformations are significantly greater
than the elastic deformations and they cannot be predicted by the classical elastic or plastic theory. Movement
is usually in an uneven pattern and of such a magnitude to cause extensive damage to the structures resting on
them.
Proper remedial measures are to be adopted to modify the soil or to reduce its detrimental effects if expansive
soils are indentified in a project. The remedial measures can be different for planning and designing stages
and post construction stages. Many stabilization techniques are in practice for improving the expansive soils
in which the characteristics of the soils are altered or the problematic soils are removed and replaced which
can be used alone or in conjunction with specific design alternatives. Additives such as lime, cement, calcium
chloride, rice husk, fly ahs etc. are also used to alter the characteristics of the expansive soils. The effect of the
additives and the optimum amount of additives to be used are dependent mainly on the mineralogical
481 Mallika, B. Ganesh
International Journal of Engineering Technology Science and Research
IJETSR
www.ijetsr.com
ISSN 2394 – 3386
Volume 4, Issue 10
October 2017
composition of the soils. The project focuses about the various stabilization techniques that are in practice for
improving the expansive soil for reducing its swelling potential and the limitations of the method of
stabilization there on. Modification of BC soil by chemical admixture is a common method for stabilizing the
swell-shrink tendency of expansive soil.
2. LITERATURE REVIEW
Expansive soils pose the greatest hazards that many geotechnical engineers face. Such soils may cause heavy
damages in light loaded structures such as water canals, reservoirs, highways, railways and airport runways
etc., unless appropriate measures are taken. Various stabilization techniques are in practice for improving
expansive soils by reducing its swelling potential and increasing its strength characteristics. Modification of
expansive soil by chemical admixture is a common practice for stabilizing the swell shrink tendency of
expansive soil, Advantages of chemical stabilization are that they reduce the swell-shrink tendency of
expansive soils and also render the soils less plastic.
In this section, the experiences of various investigators concerning chemical stabilization using
calcium chloride have been reviewed. Numerous investigators have studied the influence of lime, cement,
lime-cement, lime-fly ash, and cement–fly ash mixes on soil properties, mostly focusing on the strength and
swelling aspects. Among the chemical stabilization methods for expansive soils, lime stabilization is mostly
adopted for improving the swell-shrink characteristics of expansive soils. As lime and cement are binding
materials, the strength of soil-additive mixtures increases provided the soil is reactive with them. However, for
large-scale field use, the problems of soil pulverization and mixing of additives with soil have been reported
by several investigators.
Calcium chloride is an inorganic salt, which is a by-product of sodium carbonates. The use of
calcium chloride in place of lime, as calcium chloride is more easily made into calcium charged supernatant
than lime. Recent study indicated that CaCl2 could be an effective alternative to conventional lime used due to
its ready dissolvability in water and to supply adequate calcium ions for exchange reactions.
Petry and Armstrong (1989) stated that the calcium ions are the most effective and abundantly available in
calcareous fly ash, lime and calcium chloride, further the authors mentioned that the reasons why calcium
chloride has not been widely used are not clear. It is believed that the main one is economics, but perhaps it is
also because little definitive research has been done to define or support its use. Calcium chloride is known to
be more easily made into calcium charged supernatant than lime an helps in ready cation exchange reactions.
(Ramana Murthy, 1998). Mitchell and Radd (1973) also felt that CaCl2 might be effective in soils with
expanding lattice clays. Though, it is claimed that the magnitude of leaching in highly expansive clays
(KuulaVaisanen et al, 1995) over cycles of wetting and drying could be controlled by using Na2SiO3 along
with CaCl2. Though several works have been reported covering various aspects of chemical stabilization of
expansive soils, the understanding on cyclic swell-shrink behavior of stabilized and unstabilized soils was not
clear.
Chen and Ma (1987) felt that shrinkage cannot be treated as an image reflection of swelling and over a great
portion of the world shrinkage problems pose more of a threat to structural damage than swelling problems
especially in expansive clays of illite mineralogy.
Driscoll (1983) reported that in Britain, problems associated with swelling clays are largely related to the
shrinkage caused by extraction of moisture through tree roots. It is more useful if the complete cyclic swelling
and shrinkage behavior is understood.
Abouleid (1985) observed that there is nearly no volume change for remoulded clay specimens after three or
four wetting and drying cycles. From this discussion, it is evident that one group of researchers felt that the
swelling ability of clay decrease after few cycles of drying and wetting and yet another group recorded
increase in volume change after cyclic wetting and drying.
Reddy et al (1981) reported that, the test tracks with Murom sub-base and lime-pozzalana sub-base are rated
as the best among the ten test tracks constructed on expansive soil sub-grade with different sub-base courses.
482 Mallika, B. Ganesh
International Journal of Engineering Technology Science and Research
IJETSR
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ISSN 2394 – 3386
Volume 4, Issue 10
October 2017
Deshpande et al (1990) concluded that lime stabilized sub base has shown better performance compared to
untreated section in the test track laid on expansive soil subgrade. Many researchers attempted to stabilize the
expansive soils by using different electrolytes. Here we discuss some of the projects carried out on expansive
soils using different electrolytes all around the world.
P. Venkata Muthyalu, K. Ramu and G.V.R. Prasada Raju (JNTUK) studied the “The Performance of
Chemically Stabilized Expansive Soil.”In this project they stabilized the expansive soil using electrolytes like
Potassium Chloride (KCL), Calcium Chloride (CaCl2) and Ferric Chloride (FeCl3). Ahmed T. M. Farid and
Mohamed I. Wahdan (Saudi Arabia) studied the “Behavior of Expansive Soil Treated by using Different
Electrolyte Substances.” In this project they stabilized the expansive soil by using electrolytes like Potassium
Chloride (KCL), Calcium Chloride (CaCl2) Sodium Chloride (NaCl) and Ferric Chloride (FeCl3).
EI Sharif M. Abdulaziz, Yahya K. Taha, Mamdouh A. Kenawi and O. Kamel (Egypt) studied the “Treatment
of Expansive Soil with Chemical Additives.” In this project they stabilized the expansive soil by using
chemical additives like Addicrete P and Addicrete BV. In this project we are going to use the electrolytes like
Calcium Chloride (CaCl2) and Ferric Chloride (FeCl3) to stabilize the expansive soil.
3. EXPERIMENTAL INVESTIGATION
3.0. Scope of Work:
The experimental work consists of the following:
1. Specific Gravity of soil
2. Determination of soil index properties (Atterberg Limits)
Liquid limit by cassagrande’s apparatus
Plastic Limit
3. Determination of the maximum dry density (MDD) and the corresponding optimum moisture content
(OMC) of the soil by Proctor compaction test.
4. Determination of the shear strength by unconfined compressive strength test (UCS).
5. Determination of swelling pressure of the soil by consolidometer method.
3.1. Materials Used:
Soil sample location: Near Kakinada.
Chemicals: Calcium chloride, Ferric chloride.
3.2. Preparation of Soil Sample:
Following steps are carried out while mixing the chemicals viz., calcium chloride, ferric chloride to the soil.
All the soil samples are prepared by mixing Normal soil and the chemicals.
Percentage of chemicals in soil sample is given by the following equation.
Pb= Wb/ Ws
Wb = Weight of each chemical
Ws = Weight of soil sample
Pb= Percentage of each chemical
Different percentages of calcium chloride and ferric chloride for our study are 0.5%, 1.0%, 1.5%, 2.0%
respectively.
3.3. Experiments Performed
Specific Gravity of Soil, Differential Free Swell (DFS), Liquid Limit Test, Plastic Limit Test , Particle Size
Distribution , Proctor Compaction Test, Shear Strength a). Direct shear test b) Tri-axial Compression Test
c) Vane Shear Test d) Unconfined Compressive Strength (UCS) Test, Swell Test Using Consolidometer
TEST RESULTS
Laboratory Test Results on the samples
483 Mallika, B. Ganesh
International Journal of Engineering Technology Science and Research
IJETSR
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Volume 4, Issue 10
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Table 1 (Specific Gravity for Untreated soil sample)
Type of soil = Oven Dried Soil Passing Through IS SIEVE425µ
S.No OBSERVATIONS READINGS
1 Mass of Empty Pyconometer (M1) grams 618
2 Mass of Pyconometer + Dry soil (M2) grams 1020
3 Mass of Pyconometer + Soil + Water (M3) grams 1850
4 Mass of Pyconometer + Water (M4) grams 1597
5 Mass of Dry Soil (M2-M1) grams 402
6 Mass of Wet Soil (M3-M4) grams 253
7 Specific Gravity G=(M2-M1)/(M2- M1)-(M3-M4) 2.69
Table-2 Differential Free Swell (DFS)
Chemical Cacl2 Fecl3
0% 140 140
0.5% 80 60
1.0% 70 50
1.5% 60 50
2.0% 50 40
Effect of electrolytes on Index Properties of expansive soil
Table-3 Liquid Limit: For untreated soil sample
S.No Particulars Trail-1 Trail-2 Trail-3 Trail-4
1 Cup number 1 2 3 4
2 Number of blows 40 32 30 17
3 Weight of Cup (W1) 21.94 13.82 13.77 25.46
4 Cup+ Soil Weight (W2) 26.62 27.89 22.79 34.03
5 Cup + Oven Dry Soil (W3) 24.87 22.34 19.1 29.91
6 Weight of Water(Ww) =(W2-W3) 1.75 5.55 3.69 4.12
7 Weight of Oven Dry Soil(WS) =(W3-W1) 2.93 8.52 5.33 4.45
8 Water Content = (Ww/Ws)*100 59.73 65.14 69.23 92.58
Untreated Soil Sample Graph
(Graph-1)
Table-4 Soil sample treated with 0.5% Cacl2:
Sl.no Particulars Trail-1 Trail-2 Trail-3 Trail-4
1. Cup number 1 2 3 4
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2. Number of blows 38 29 20 12
3. Weight of Cup (W1) 8.50 13.91 13.78 8.39
4. Cup+ Soil Weight (W2) 23.32 29.85 32.40 15.06
5. Cup + Oven Dry Soil (W3) 17.19 23.17 24.43 12.04
6. Weight of Water (Ww) =(W2-W3) 6.13 6.68 7.97 3.02
7. Weight of Oven Dry Soil(WS) =(W3-W1) 8.69 9.26 10.65 3.65
8. Water Content = (Ww/Ws)*100 70.54 72.14 74.83 82.73
Treated Soil sample (Normal soil + 0.5% Cacl2)
(Graph-2)
Table-5 Treated Soil Sample (Normal Soil + 1.0% Cacl2)
S.No Particulars Trail-1 Trail-2 Trail-3 Trail-4
1. Cup number 1 2 3 4
2. Number of blows 40 24 19 15
3. Weight of Cup (W1) 8.40 13.78 8.54 14.10
4. Cup+ Soil Weight (W2) 19.57 22.10 18.85 31.50
5. Cup + Oven Dry Soil (W3) 15.34 18.83 14.51 24.52
6. Weight of Water(Ww) =(W2-W3) 4.23 3.27 4.34 6.98
7. Weight of Oven Dry Soil(WS) =(W3-W1) 6.94 5.05 5.97 10.42
8. Water Content = (Ww/Ws)*100 60.95 64.75 72.69 66.98
Treated Soil Sample (Normal Soil + 1.0% Cacl2)
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Volume 4, Issue 10
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(Graph-3)
Table-6 Soil sample treated with 1.5% Cacl2
Sl.no Particulars Trail-1 Trail-2 Trail-3 Trail-4
1. Cup number 1 2 3 4
2. Number of blows 35 25 16 10
3. Weight of Cup (W1) 8.42 13.80 9.82 8.51
4. Cup+ Soil Weight (W2) 19.41 22.97 19.92 16.18
5. Cup + Oven Dry Soil (W3) 15.04 19.15 15.140 12.78
6. Weight of Water(Ww) =(W2-W3) 4.37 3.82 4.78 3.40
7. Weight of Oven Dry Soil(WS) =(W3-W1) 6.62 5.35 5.32 4.27
8. Water Content = (Ww/Ws)*100 66.01 71.40 89.84 79.63
Treated Soil Sample (Normal Soil + 1.5% Cacl2)
(Graph-4)
Table-7 Soil sample treated with 2.0% Cacl2
486 Mallika, B. Ganesh
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Sl.no Particulars Trail-1 Trail-2 Trail-3 Trail-4
1. Cup number 1 2 3 4
2. Number of blows 42 30 21 12
3. Weight of Cup (W1) 8.57 8.41 8.74 8.34
4. Cup+ Soil Weight (W2) 14.82 13.84 15.61 15.47
5. Cup + Oven Dry Soil (W3) 12.51 11.79 12.98 12.64
6. Weight of Water(Ww) = (W2-W3) 2.31 2.05 2.63 2.83
7. Weight of Oven Dry Soil(WS) =(W3-W1) 3.94 3.38 4.24 4.3
8. Water Content = (Ww/Ws)*100 58.63 60.65 62.02 65.81
Treated Soil Sample (Normal soil + 2.0% Cacl2)
(Graph-5)
Table -8 Soil sample treated with 0.5% FeCl3:
Sl.no Particulars Trail-1 Trail-2 Trail-3 Trail-4
1. Cup number 1 2 3 4
2. Number of blows 40 28 24 15
3. Weight of Cup (W1) 26.26 24.04 21.95 8.65
4. Cup+ Soil Weight (W2) 33.26 29.45 28.98 15.33
5. Cup + Oven Dry Soil (W3) 30.57 27.22 26.03 12.40
6. Weight of Water(Ww) =(W2-W3) 2.69 2.23 2.95 2.93
7. Weight of Oven Dry Soil(WS) =(W3-W1) 4.31 3.18 4.08 3.75
8. Water Content = (Ww/Ws)*100 62.41 70.12 72.30 78.13
Treated Soil Sample (Normal Soil + 0.5% Fecl3)
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(Graph-6)
Table- 9 Soil sample treated with 1.0% Fecl3
Sl.no Particulars Trail-1 Trail-2 Trail-3 Trail-4
1. Cup number 1 2 3 4
2. Number of blows 39 36 26 21
3. Weight of Cup (W1) 13.78 13.74 13.82 13.94
4. Cup+ Soil Weight (W2) 19.17 19.26 19.65 19.83
5. Cup + Oven Dry Soil (W3) 17.11 17.12 17.29 17.34
6. Weight of Water(Ww) =(W2-W3) 2.06 2.14 2.36 2.49
7. Weight of Oven Dry Soil(WS) =(W3-W1) 3.33 3.38 3.47 3.4
8. Water Content = (Ww/Ws)*100 61.86 63.31 68.01 73.23
Treated Soil Sample ( Normal Soil + 1.0% Fecl3)
(Graph-7)
Table-10 Soil sample treated with 1.5% Fecl3
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Sl.no Particulars Trail-1 Trail-2 Trail-3 Trail-4
1. Cup number 1 2 3 4
2. Number of blows 38 34 23 16
3. Weight of Cup (W1) 13.40 13.78 13.73 13.96
4. Cup+ Soil Weight (W2) 18.37 25.38 17.54 20.74
5. Cup + Oven Dry Soil (W3) 16.55 20.83 16.10 18.07
6. Weight of Water(Ww) =(W2-W3) 1.82 4.55 1.44 2.67
7. Weight of Oven Dry Soil(W =(W3-W1) 3.15 7.05 2.37 4.17
8. Water Content = (Ww/Ws)*100 57.77 64.53 60.75 64.02
Treated Soil Sample ( Normal Soil + 1.5% Fecl3)
(Graph-8)
Table-11 Soil sample treated with 2.0% Fecl3
Sl.no Particulars Trail-1 Trail-2 Trail-3 Trail-4
1. Cup number 1 2 3 4
2. Number of blows 29 22 20 13
3. Weight of Cup (W1) 21.94 27.70 25.38 25.46
4. Cup+ Soil Weight (W2) 26.62 35.98 35.24 34.03
5. Cup + Oven Dry Soil (W3) 24.87 32.56 31.56 29.91
6. Weight of Water(Ww) =(W2-W3) 1.75 3.42 3.78 4.12
7. Weight of Oven Dry Soil(WS) =(W3-W1) 2.93 4.88 6.08 4.45
8. Water Content = (Ww/Ws)*100 59.73 70.08 62.17 92.58
Treated Soil Sample ( Normal Soil + 2.0% Fecl3)
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(Graph-9)
Plastic Limit Test
Table-12 Untreated Soil Sample
S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 25.33 21.56 20.12
3 Cup + Oven Dry Soil 27.71 25.29 23.50
4 Weight of Cup 27.13 24.31 22.64
5 Weight of Water(Ww) 0.58 0.98 0.86
6 Weight of Oven Dry Soil(WS) 1.8 2.75 2.52
7 Water Content= ( Ww/Ws)*100 32.22 35.64 34.13
Average Water Content= (32.22+35.64+34.13)/3= 34%
Table-13Soil Sample treated with 0.5% Cacl2
S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 21.56 20.13 25.41
3 Cup + Oven Dry Soil 23.50 24.11 27.82
4 Weight of Cup 23.02 23.13 27.26
5 Weight of Water(Ww) 0.48 0.98 0.56
6 Weight of Oven Dry Soil(WS) 1.46 3.00 1.85
7 Water Content= ( Ww/Ws)*100 32.87 32.67 30.27
Average water content = (32.87+32.67+30.27)/3= 33.5%
Table-14 Soil Sample treated with 1.0% Cacl2
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S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 13.62 13.40 21.56
3 Cup + Oven Dry Soil 18.26 16.26 25.29
4 Weight of Cup 17.03 15.52 24.31
5 Weight of Water(Ww) 1.23 0.74 0.98
6 Weight of Oven Dry Soil(WS) 3.41 2.12 2.75
7 Water Content= ( Ww/Ws)*100 36.07 34.9 35.0
Average Water Content= (36.07+34.9+35.0)/3= 35%
Table-15 Soil Sample treated with 1.5% Cacl2
S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 8.34 8.77 8.42
3 Cup + Oven Dry Soil 10.70 11.69 11.46
4 Weight of Cup 10.05 10.88 10.64
5 Weight of Water(Ww) 0.65 0.81 0.82
6 Weight of Oven Dry Soil(WS) 1.71 2.11 2.22
7 Water Content= ( Ww/Ws)*100 38.01 38.38 36.93
Average Water Content= (38.01+38.38+36.93)/3= 38%
Table-16 Soil Sample treated with 2.0% Cacl2
S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 8.42 8.52 8.43
3 Cup + Oven Dry Soil 11.37 11.4 11.46
4 Weight of Cup 10.51 10.57 10.64
5 Weight of Water(Ww) 0.86 0.83 0.82
6 Weight of Oven Dry Soil(WS) 2.09 2.05 2.21
7 Water Content= ( Ww/Ws)*100 41.14 40.48 37.10
Average Water Content= (41.14+40.48+37.10)/3= 39.57%
Table-17 Soil Sample treated with 0.5% Fecl3
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S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 13.62 13.40 13.77
3 Cup + Oven Dry Soil 18.26 16.26 16.90
4 Weight of Cup 17.03 15.52 16.07
5 Weight of Water(Ww) 1.23 0.74 0.83
6 Weight of Oven Dry Soil(WS) 3.41 2.12 2.3
7 Water Content= ( Ww/Ws)*100 36.07 34.90 36.09
Average Water Content= (36.07+34.90+36.09)/3= 35.69%
Table-18 Soil Sample treated with 1.0% Fecl3
S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 13.79 13.94 13.72
3 Cup + Oven Dry Soil 16.44 16.48 16.35
4 Weight of Cup 15.72 15.83 15.63
5 Weight of Water(Ww) 0.72 0.65 0.72
6 Weight of Oven Dry Soil(WS) 1.93 1.89 1.91
7 Water Content= ( Ww/Ws)*100 37.31 34.39 37.69
Average Water Content= (37.31+34.39+37.69)/3= 36.46%
Table-19 Soil Sample treated with 1.5% Fecl3
S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 26.52 26.84 25.48
3 Cup + Oven Dry Soil 29.17 28.83 28.08
4 Weight of Cup 28.51 28.30 27.25
5 Weight of Water(Ww) 0.66 0.53 0.83
6 Weight of Oven Dry Soil(WS) 1.99 1.46 1.77
7 Water Content= ( Ww/Ws)*100 33.16 36.30 46.89
Average Water Content= (33.16+36.30+46.89)/3= 39%
Table-20 Soil Sample treated with 2.0% Fecl3
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S.No Particulars Trail-1 Trail-2 Trail-3
1 Cup number 1 2 3
2 Cup + Soil Weight 13.82 13.62 13.41
3 Cup + Oven Dry Soil 16.51 17.46 16.36
4 Weight of Cup 15.72 16.26 15.52
5 Weight of Water(Ww) 0.79 1.20 0.84
6 Weight of Oven Dry Soil(WS) 1.90 2.64 2.11
7 Water Content= ( Ww/Ws)*100 41.57 45.45 39.81
Average Water Content= (41.57+45.45+39.81)/3= 42.27%
Plastic Index: Plasticity Index = Liquid Limit – Plastic Limit = WL - WP
Table-21
Chemical Cacl2 Fecl3
0% 42 42
0.50% 41.5 34.3
1.00% 37 32.5
1.50% 28 21
2.00% 21.7 15.7
Soil Classification
By using A-Line Chart
Taken form Highway Engineering By S.K. Khanna and C.E.G.Justo pg-273
In the plasticity chart following symbols are used:
CL= Clay of low compressibility
CH= Clay of high compressibility
ML= Silt of low compressibility
MH= Silt of high compressibility
OL= Organic soil of low compressibility
OH= Organic soil of high compressibility
Using Plasticity Chart for Unified Soil Classification System (U.S.C.S) the Sample Used for Stabilization is
classified i.e., The Liquid Limit for the Untreated Soil Sample is WL= 76%. The Plastic Limit for Untreated
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Soil Sample is WP = 37%. Corresponding Plastic Index Value is given by IP = WL - WP= 39%. From the A-
Liner chart our Sample is a Clay Sample and also our Sample comes under the zone of “CL” i.e., our sample
is clay of low compressibility.
(ii) By using Specific Gravity Table
Sand 2.63-2.67
Silt 2.65-2.7
Clay and Silty clay 2.67-2.9
Organic soil < 2.0
Specific Gravity of Untreated Soil Sample is = 2.68
Our Sample is Clay and Silty Clay that means is a combination of Clay and Silt.
Table-22Proctors Compaction Test:
S.No Observation 1 2 3 4 5 6
1 Water Content Added (%) 2% 4% 6% 8% 10% 12%
2
Mass Of Empty Mould+ Mass Of Empty Mould+Base
Plate (Gms) M1
3780 3780 3780 3780 3780 3780
3
Mass Of Empty Mould+Base Plate+ Compacted Soil
(Gms) M2
5430 5470 5520 5560 5570 5530
4 Mass Of Compacted Soil M=M1+M2 1650 1690 1740 1780 1790 1750
5 Volume Of Empty Mould (Cc) 982 982 982 982 982 982
6 Bulk Density Ρ=M/V (G/Cc) 1680 1720 1770 1810 1820 1780
7 Water Content (Ω) 0.19 0.18 0.18 0.19 0.18 0.18
8 DRY DENSITY Ρd= Ρ/(1+Ω) (G/Cc) 1.42 1.45 1.49 1.52 1.54 1.51
(Graph-10)
Swelling Pressure Test ByConsolidometer Method
Table-23 For Untreated Soil Sample
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Pressure Increment Swelling/Compressi
on
Change in Thickness of Expanded
Specimen In
kgf/cm2
In
KN/m2
0.05 4.905 23.54 3.54
Swelling
0.05 4.905 23.21 3.21mm
0.1 9.81 22.82 2.82mm
0.2 19.62 21.26 1.26mm
0.5 49.05 21.01 1.01mm
1 98.1 20.76 0.76mm
2 196.2 19.55 -0.45mm
(Graph-11)
Discussion and Test Results
The effect of adding different chemicals to the expansive soil on Atterberg limits, DFS and Strength
Properties are discussed in the following sections
Variation of Liquid limit with addition of percentage of chemical
(Graph-12)
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Variation of Plastic Limit with addition of percentage of chemical
(Graph-13)
Effect of Additives on Atterberg limits
The variation of liquid limit values with different percentages of chemicals added to the expansive soil is
presented in the Graph 21 & Table 33. It is observed that the decrease in the liquid limit is significant up to
1% of chemical added to the expansive clay for all the chemicals, beyond 1% there is a nominal decrease.
Maximum decrease in liquid limit for stabilized expansive clay is observed with the chemical FeCl3,
compared with other chemical, CaCl2. Nominal increase in plastic limit of stabilized expansive clay is
observed with increase the percentage of the chemical
Graph 23shows the variation of plasticity index with the addition of chemicals to expansive clay.
The increase in the plastic limit and the decrease in the liquid limit cause a net reduction in the plasticity
index. It is observed that, the reduction in plasticity index are 10% and 23% respectively for 1 % of CaCl2
and FeCl3 added to the expansive clay. The reduction in plasticity index with chemical treatment could be
attributed to the depressed double layer thickness due to cation exchange by calcium and ferric ions.
Effect of Additives on Atterberg limits
The variation of liquid limit values with different percentages of chemicals added to the expansive soil is
presented in the Graph 21 & Table 33. It is observed that the decrease in the liquid limit is significant up to
1% of chemical added to the expansive clay for all the chemicals, beyond 1% there is a nominal decrease.
Maximum decrease in liquid limit for stabilized expansive clay is observed with the chemical FeCl3,
compared with other chemical, CaCl2. Nominal increase in plastic limit of stabilized expansive clay is
observed with increase the percentage of the chemical
Graph 13shows the variation of plasticity index with the addition of chemicals to expansive clay.
The increase in the plastic limit and the decrease in the liquid limit cause a net reduction in the plasticity
index. It is observed that, the reduction in plasticity index are 10% and 23% respectively for 1 % of CaCl2
and FeCl3 added to the expansive clay. The reduction in plasticity index with chemical treatment could be
attributed to the depressed double layer thickness due to cation exchange by calcium and ferric ions.
Variation of DFS for different chemicals
(Graph-14)
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Effect of Additives on DFS
The variation of DFS of stabilized expansive clay with addition of different percentages of chemicals is shown
in the Graph 24 & Table 34. It is observed that the DFS is decreasing with increasing percentage of chemical
added to the expansive soil. Significant decrease in D.F.S. is recorded in stabilized expansive clay with
addition of 1% of chemical. The reductions in the DFS of stabilized expansive clay with addition of 1%
chemical are 50% and 64% for CaCl2 and FeCl3 respectively compared with the expansive clay. The reduction
in DFS values could be supported by the fact that the double layer thickness is suppressed by cation exchange
with calcium and ferric ions and with increased.
Variation of UCS for different chemicals
(Graph-15)
Effect of Chemicals on Swelling Pressure:
Variation of swelling pressure for different chemicals
(Graph-16)
Effect of Chemicals on Swelling
The Swelling pressure of the remoulded samples prepared at MDD and optimum moisture content with
addition of 0.5%, 1%, 1.5% and 2.0 % of chemicals CaCl2 & FeCl3, to the expansive soil are presented in the
Table 36. The prepared samples are tested. It is observed that the Swelling pressure of the stabilized expansive
soil is decresing with increase in percentage of chemical added to the soil.The Swelling pressure of stabilized
expansive clay is reduced by 26% and 35% when treated with 1 % chemical of CaCl2 and FeCl3
respectively. The decreasing in the swell with addition of chemicals may be attributed to the cation exchange
of CaCl2 & FeCl3 between mineral layers and due to the formation of silicate gel. The reduction in strength
beyond 1% each of CaCl2 & FeCl3 may be due to the absorption of more moisture at higher CaCl2 & FeCl3 .
CONCLUSIONS
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The following conclusions can be drawn from the laboratory study carried out in this investigation.
The liquid limit decreases as the chemical content increases and plastic limit slightly increases causing a
net decrease in plastic index. This reduction is effective up to 1% chemical content and is nominal
afterwards.
The DFS value of natural soil is very high and the addition of chemical contents decreased the value by
57% and 64% for 1% of CaCl2 and FeCl3 treatments respectively.
The swelling nature of the expansive soil is reduced considerably with the addition of the selected
chloride chemicals. For an optimum value of chemical contents the percentage decrease in the swelling
pressure are 26% and 35% for CaCl2 and FeCl3 treatments respectively.
The UCS values are increased by 177% and 203% for 1% of CaCl2 and FeCl3 treatments respectively.
From the above test results a conclusion could be made that the selected electrolytes are effective in
improving the properties of expansive soil and out of which FeCl3 is more effective.
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