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Supplemental Technical Analyses for Unified Command Taylor Energy Mississippi Canyon Block 20 A Dr. Richard Camilli Navistry Corp. 1 Dec 18, 2015
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Page 1: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Supplemental Technical Analyses for Unified Command

Taylor Energy Mississippi Canyon Block 20 A

Dr. Richard Camilli

Navistry Corp.

1 Dec 18, 2015

Page 2: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Eight years of sheen observations (2000+ daily aerial overflights) indicate that the surface sheen originating at MC20 is intermittent (with periods of no observable surface sheen) and variable in size (1 sigma >> mean).

2 Dec 18, 2015

Page 3: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Variability in sheen volume is strongly correlated with sediment disturbance Largest releases coincide with on-site intervention activity

A) Pipeline decommissioning and abandonment; B) Commencement of intervention well drilling and completion of IW21; C) Containment dome installation and shallow hazard survey; D) Completion of IW19; E) Drilling and completion of IW16; F) Drilling and completion of IW04; G) Drilling and completion of IW13; H) Drilling and completion of IW01; I) Drilling and completion of IW11; J) Drilling and completion of IW17; K) Drilling and completion of IW10; L) Deck removal, containment system repair, and debris collection; M) Containment system repair; N) Sediment drop coring, box coring, and sonar survey. Note, the Y-axis scale of daily sheen size is truncated to permit better visualization of the 30 day running average, causing extreme outlier data points to be off scale.

0

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1507/

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8/8/

089/

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/08

11/6

/08

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/08

1/5/

092/

4/09

3/6/

094/

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096/

4/09

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098/

3/09

9/2/

0910

/2/0

911

/1/0

912

/1/0

912

/31/

091/

30/1

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1/10

3/31

/10

4/30

/10

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/10

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/10

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/10

8/28

/10

9/27

/10

10/2

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1/25

/11

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/11

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/11

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/11

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/11

6/24

/11

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/11

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/11

9/22

/11

10/2

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1/20

/12

2/19

/12

3/20

/12

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/12

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/12

6/18

/12

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/12

8/17

/12

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/12

10/1

6/12

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1/14

/13

2/13

/13

daily

repo

rted

she

en s

ize

(gal

lons

)

0

1,000

2,000

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7,000

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cum

ulat

ive

obse

rved

she

en (g

allo

ns)

morning overflight dataupper standard deviation30 day averagelower standard deviationcumulative observed totalLinear (morning overflight data)

MA B C D E F G H I J K L N

3 Dec 18, 2015

Page 4: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Sheen size also exhibits correlation with lunar cycle and phase SHEEN SIZE VARIABILITY COORELATES WITH LUNAR FORTNIGHTLY PERIOD (13.65 DAYS)

4 Dec 18, 2015

Page 5: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

POST-INTERVENTION SHEEN SIZE MAXIMA CORRESPOND TO NEW MOON PHASES

0.01

0.1

1

10

100

1000

0 30 60 90 120 150 180 210 240 270 300 330 360

Full waning New waxing Full

5 Dec 18, 2015

Page 6: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Overflight data indicate that wind speed influences apparent sheen volume SHEEN SIZE EXHIBITS LOGRITHMIC CORRELATION WITH WIND SPEED

118.09

47.05

22.18

7.54

3.13

12.08

6.72

3.66

1.55

0.72

6.27

3.97

2.15

0.58

0.22

0.1

1.0

10.0

100.0

1000.0

0-5 kts 6-10 kts 11-15 kts 16-20 kts 21-25 kts

wind speed

shee

n si

ze (g

allo

ns)

max mean median

mean trendy = -5.7987Ln(x) + 18.541

R2 =0.9985

median trend y = -3.1326Ln(x) + 9.9836

R2 =0.9805

max trendy = -37.536Ln(x) + 119.84

R2 = 0.9852

WIND SPEED CORRELATION: 270% higher mean sheen size when wind speed below 10 kts than when wind speed equal to or higher than 10 kts.

6 Dec 18, 2015

Page 7: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

DAILY OVERFLIGHT ESTIMATES OF SHEEN LENGTH

0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

27.5

30.0

32.5

35.0

1/1/2008 1/1/2009 1/1/2010 1/1/2011 1/1/2012 1/1/2013 1/1/2014 1/1/2015

DATE

LEN

GTH

(MIL

ES)

length30 per. Mov. Avg. (length)

Sheen length strongly correlates with seasonality: maximum lengths recorded during summer months and minimum lengths recorded during winter months.

7 Dec 18, 2015

Page 8: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and
Page 9: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Supplemental Technical Analyses for Unified Command

Taylor Energy Mississippi Canyon Block 20 A January 20, 2016 presentation Version 1; December 20, 2015

9

Dr. Christopher Reddy

consultant

Woods Hole, MA

V1; 12/20/15

Page 10: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Sediment collection, analysis, and

interpretation at the MC20 site (2012/2013)

10 V1; 12/20/15

Page 11: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

11

1. Thorough and approved plans.

V1; 12/20/15

Page 12: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

12

2. Best practices: sample management and analysis (QA/QC).

V1; 12/20/15

Page 13: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Objectives for July 2012 and Feb 2013 sediment sampling

• Determine the vertical and horizontal extent of petroleum-hydrocarbon contamination.

• Generally characterize the petroleum hydrocarbons detected.

• Use sediment data to compare to surface sheens collected in 2012 and 2013 (discussed at 1:30pm today).

• Understand the current status of the site.

13 V1; 12/20/15

Page 14: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Analytical chemistry for sediments and sheens

• Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and the USCG Marine Safety Laboratory (New London, CT).

• Alpha Analytical measured over 100 distinct compounds that were used for gauging levels of contamination and calculating diagnostic ratios.

• The Marine Safety Laboratory performed an ASTM method for determining if sediments were a match or common source to sheens.

14 V1; 12/20/15

Page 15: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

15 V1; 12/20/15

Page 16: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Forensics • Forensics of oil spills is generally based on

comparing the “chemical-like genetic markers” or “signatures” present in oil.

• There are numerous approaches that can be particularly powerful, but it becomes increasingly harder to get “perfect matches” as spilled oil gets older (weathers).

• For the sediment data, one diagnostic ratio recommended by Professor Ed Overton (LSU) in the literature will be employed.

16 V1; 12/20/15

Page 17: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

17

Sour

reservoir

� Once released

OIL MIXTURE OF PETROLEUM HYDROCARBONS

V1; 12/20/15

Page 18: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Initial summary of results • Petroleum hydrocarbons were detected in

every discrete sediment sample. • Contamination varied horizontally and

vertically in the sampling area with moderately degraded crude oil.

• Using one diagnostic ratio recommended by LSU scientists in previous scientific studies, the sediment can be binned into two types (background and former wellbay and Dome C).

18 V1; 12/20/15

Page 19: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

2007 sampling TPHs values ‘grab’

S2=190 mg/kg

S5=47 mg/kg

S8=400 mg/kg

S3=210 mg/kg

S1= 98mg/kg

V1; 12/20/15

19

Page 20: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

20

10

7

4 3

2

1 5

6

11

8 9

12

former well bay

50 0 50 100 150 Feet

toppled jacket

containment system

Sediment coring Locations

(July 2012*

and Feb 2013*** )

*Sediment was collected at all 12 numbered sites with both box and piston corers. locations= **Divers collected four cores along each side of the containment system only in February 2013. locations=

dome C (four cores

collected by diver)

Note: The July 2012 piston cores were originally designated as “DC-x” for drop core. They are now “PC-x” so that the Feb 2013 diver cores’s can be “DC-x”.

V1; 12/20/15

Page 21: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

July 2012 sediment sampling -12 locations

-Each location included ~10 samples

V1; 12/20/15 21

Page 22: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Sediment samplers used in July 2012

22

Collected sediment down to ~5 meters but did not recover near surface sediment (also called drop cores)

Collected sediment in the surface layer, which in turn allows for a complete sediment record when married with the piston core. (Figure from USGS)

V1; 12/20/15

Page 23: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

February 2013 sediment sampling (diver)

-4 locations -Each location included ~4 samples

V1; 12/20/15

23

Page 24: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Blow-up of cores collected in February 2013 (DC-1 to 4)

24

Dome C

Collected by diver. Each core split into four horizons one-ft thick

DC-1

DC-4

DC-2

DC-3

diver core=DC

10.5’

V1; 12/20/15

Page 25: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Figures for total petroleum hydrocarbons (TPHs) from the piston cores (or drop cores)

collected in July 2013

Twelve cores collected to mud depths of ~5m, split at 0.5 m intervals and analyzed

V1; 12/20/15 25

Page 26: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

26

Page 27: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

27

Page 28: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

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Page 29: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

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Page 30: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

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Page 31: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

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Page 32: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

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Page 33: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

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Page 34: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

34

Page 35: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

35

Page 36: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

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Page 37: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15

37

Page 38: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15 38

Page 39: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15 39

Page 40: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

V1; 12/20/15 40

Page 41: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

41

Norhopane (NH)

Hopane (H)

Diagnostic Ratio= NH/H

V1; 12/20/15

Page 42: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Lower sections for all 12 cores; NH/H = 0.64r0.06

NH/H = 0.62r0.02 NH/H = 0.46r0.04

V1; 12/20/15 42

V1; 12/20/15

Page 43: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

43

10

7

4 3

2

1 5

6

11

8 9

12

former well bay

50 0 50 100 150 Feet

toppled jacket

containment system

Sediment coring Locations

(July 2012*

and Feb 2013*** )

*Sediment was collected at all 12 numbered sites with both box and piston corers. locations= **Divers collected four cores along each side of the containment system only in February 2013. locations=

dome C (four cores

collected by diver)

V1; 12/20/15

Note: The July 2012 piston cores were originally designated as “DC-x” for drop core. They are now “PC-x” so that the Feb 2013 diver cores’s can be “DC-x”.

V1; 12/20/15

Page 44: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Figures for TPHs from the diver core’s

collected in Feb 2013

Four cores collected to a mud depth of 4 feet, split at 1-ft intervals

V1; 12/20/15 44

Page 45: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

45

V1; 12/20/15

Page 46: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

46

V1; 12/20/15

Page 47: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

47

V1; 12/20/15

Page 48: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

48

V1; 12/20/15

Page 49: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

49 All sixteen sections; NH/H = 0.48r0.01 V1; 12/20/15

Page 50: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

50

1.00

10.00

100.00

1,000.00

10,000.00

100,000.00

1,000,000.00

0 0.2 0.4 0.6 0.8 1

1,7-12

2 to 6

Diver

Box

NH/H

Sedi

men

t TPH

(mg/

kg)

Former well bay and Dome C Background

v1; 12/20/15

Page 51: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

51

10

7

4 3

2

1 5

6

11

8 9

12

former well bay

50 0 50 100 150 Feet

toppled jacket

containment system

Sediment coring Locations

(July 2012*

and Feb 2013*** )

*Sediment was collected at all 12 numbered sites with both box and piston corers. locations= **Divers collected four cores along each side of the containment system only in February 2013. locations=

dome C (four cores

collected by diver)

Note: The July 2012 piston cores were originally designated as “DC-x” for drop core. They are now “PC-x” so that the Feb 2013 diver cores’s can be “DC-x”.

V1; 12/20/15

Page 52: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

52

Return to background; unlikely recharging at former well bay V1; 12/20/15

Page 53: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

53

V1; 12/20/15

Page 54: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

54

Cores ~25 meters from each other

V1; 12/20/15

Page 55: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Cores ~6 meters from each other

55

V1; 12/20/15

Page 56: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

Summary on sediment data 1. Petroleum hydrocarbons detected in every

sediment sample. 2. There is a “background” level of petroleum

hydrocarbons around the MC20. 3. Two locations at MC20 have well-constrained

and high levels of petroleum hydrocarbons, linked to “former well bay and Dome C”.

4. No evidence for active recharge (no significant horizontally and laterally).

5. Could be potential for “secondary” sources of petroleum hydrocarbons to the environment (sheens).

56

V1; 12/20/15

Page 57: Supplemental Technical Analyses for Unified CommandAnalytical chemistry for sediments and sheens • Samples were analyzed by Alpha Analytical (Mansfield, MA) for Taylor Energy and

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