Supporting InformationAtmospheric Pressure Plasma Synthesized Gold Nanoparticle/Carbon Nanotube Hybrids for Photo-thermal ConversionDaye Sun,† James McLaughlan,‡,§ Li Zhang,∥ Brian G. Falzon,† Davide Mariotti,⊥ Paul Maguire,⊥ Dan Sun,* †
†Advanced Composites Research Group (ACRG), School of Mechanical and Aerospace Engineering, Queen’s University, Belfast, UK‡School of Electronic and Electrical Engineering, University of Leeds, UK§Leeds Institute of Medical Research, University of Leeds, UK∥Research Center for Nano-Biomaterials, Analytical & Testing Center, Sichuan University, Chengdu, China⊥Nanotechnology and Integrated Bioengineering Centre, Ulster University, UK
*Corresponding author E-mail: [email protected]
This supporting information contains 4 pages with 7 figures.
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Figure S1. Photographs of (a) CNT-COOH-H, (b) 2.5 µM AuNP/CNT-COOH-H, (c) 0.1 mM AuNP/CNT-COOH-H, and (d) 0.2 mM AuNP/CNT-COOH-H.
Figure S2. TEM image of CNT-COOH-H. The TEM sample was prepared by depositing a 25 µL droplet of dispersed CNT-COOH-H solution (50 ± 3 µg/mL) onto a TEM sample grid.
Figure S3. Shape projections (left) and size distributions (right) of AuNPs within (a) 2.5 µM, (b) 0.1 mM, and (c) 0.2 mM AuNP/CNT-COOH-H hybrids.
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Figure S4. Typical TEM images (left) and shape projections (right) of (a) 2.5 μM AuNP, (b) 0.1 mM AuNP, and (c) 0.2 mM AuNP obtained under the same APP conditions (without the presence of CNTs). The size of spherical NPs is determined by diameter, while that of other shapes are determined by the longest length; the average size and distribution is fitted with a Gaussian function.
Figure S5. Size distribution (left) and shape projection (right) of AuNPs within 0.1 mM AuNP/CNT-COOH-L hybrid. The size of spherical NPs is determined by diameter, while that of other shapes are determined by the longest length; the average size and distribution is fitted with a Gaussian function.
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Figure S6. (a) - (c) Typical TEM images of 0.1 mM AuNP/CNT-COOH-H hybrid under different magnifications and (d) - (f) TEM images of 0.1 mM AuNP/CNT-COOH-L hybrid under the same magnifications.
Figure S7. Size distribution (left) and shape projection (right) of AuNPs within 0.1 mM AuNP/CNT-OH hybrid. The size of spherical NPs is determined by diameter, while that of other shapes are determined by the longest length; the average size and distribution is fitted with a Gaussian function.