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Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate...

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Surceptibility Constants for Co-ordinate Linkage in Addition Compounds, Part 1 (Received for publication, July 2, 1934.) The determination of t.he constitutire correction factor A in the additivity formula for magnetic susceptibility requires careful investigation. Pascal, in his classical research was able to affix certain definite vaIues of the correction constant for many of the valency linkages, like double bond, triple bond, etc, and showed that the constant retains its identity in a large number of organic compounds. But so far no measurements seem b have been made for the eonstant A, when 8 mrdinate linkage is established. Such a case is provided when two eub gtances react in simple atoicbiomettical ratios to give producis known a0 molecular or addition compounds. Different workers have put forward different viem to smccount for the formation of such ~arnpounds. Lowry and Bennett and Wills popostulate that it is very probable that one of the components acte as s donor and the other as an acceptor XI tbat co-ordination linkage is eetablished. On the elecmnic theory of vaIency, the donor molecula possessea a 1one pair which wj,
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Page 1: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and

Surceptibility Constants for Co-ordinate Linkage in Addition Compounds, Part 1

(Received for publication, July 2, 1934.)

The determination of t.he constitutire correction factor A in the additivity formula for magnetic susceptibility

requires careful investigation. Pascal, in his classical research was able to affix certain definite vaIues of the correction constant for many of the valency linkages, like double bond, triple bond, etc, and showed that the constant retains its identity in a large number of organic compounds. But so far no measurements seem b have been made for the eonstant A, when 8 mrdinate linkage is established. Such a case is provided when two e u b gtances react in simple atoicbiomettical ratios to give producis known a0 molecular or addition compounds.

Different workers have put forward different viem to smccount for the formation of such ~arnpounds. Lowry and Bennett and Wills popostulate that it is very probable that one of the components acte as s donor and the other as an acceptor XI tbat co-ordination linkage is eetablished. On the elecmnic theory of vaIency, the donor molecula possessea a 1one pair which wj,

Page 2: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and
Page 3: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and
Page 4: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and
Page 5: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and
Page 6: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and
Page 7: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and
Page 8: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and
Page 9: Surceptibility Constants for Co-ordinate Linkage Addition ... · PDF fileNaphthalene picrate was prepared in ether, 5 anthracene ... formed by the interaction of a nitro-compound and

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