Surf Act Ants for Industrial Applications

Surfactants

Applicationsfor Industrial

Nonionic and Anionic Emulsifiers, Copolymerizable Surfactants, Dispersing Agents and Defoamers

Division Functional Chemicals

Exactly your chemistry.

Surfactants

Applicationsfor Industrial


22

Contents

3

Alkyl polyethyleneglycol ether 13

phosphoric acid esters

Alkyl phosphonic acids 13

Alkyl polyethylene glycol 13

ether carboxylic acid

Fatty acid condensates 13

(fatty acid isethionates, methyl taurides,

sarkosin and sarkoside)

Alkyl benzene sulphonates, Ca-salts 13

Copolymerizable Surfactants

Vinyl ether alkoxylates

(PO-EO-block polymers) 14

Allyl ether alkoxylates

(PO-EO-block polymers) 14

Allyl polyoxyalkylene sulphates 14

Dispersing Agents 15

Defoamers

Fluorine containing defoamers 16

Silicone containing defoamers 16

Silicone and fluorine-free defoamers 16

Surfactants from Clariant

Emulsifiers for emulsion 17

polymerization

® = Registered trademark of Clariant

Surfactants from Clariant

What we offer for industrial customers 4

Product Range

Nonionic Surfactants

Alkyl ethoxylates 6

Nonylphenol ethoxylates 9

Tributylphenol ethoxylates 9

Tristyrylphenol ethoxylates 9

Alkyl alkoxylates 10

Ethylene oxide-propylene 10

oxide block polymers

Fatty acid polyethyleneglycol esters 11

Fatty acid polyglycerol esters 11

Fatty acid polyglycerol 11

ester ethoxylates

Castor oil ethoxylates 11

Sorbitan ester ethoxylates 11

Wax emulsifiers 11

Anionic Surfactants

Secondary alkyl sulphonates 12

Olefin sulphonates 12

Alkyl sulphates 12

Alkyl ether sulphates 12

Alkyl aryl ether sulphates 12

Polyglycol ether sulphates 12

Sulphosuccinic acid esters 12

Fatty alkyl amine sulphosuccinamates 12

Alkyl phosphoric acid esters 12

4

Surfactants from ClariantWhat we offer for industrial customers

Research and development

In addition to the product range we offer

our customers comprehensive advice

and technical service. Our application

laboratories assist you in developing

modern system solutions and help you to

select the products that are suitable

for your applications.

Our product range is constantly being

expanded by intensive research and

development work and is thus geared to

the requirements of our customers as

well as to optimization of the production

methods.

Quality and environment

Clariant’s Functional Chemicals Division

in Germany has established a quality

management system in accordance

with ISO 9001 in the production, rese-

arch & development and marketing

sectors. All products are subject to

strict quality control in our analytical

department to ensure our high quality

standard.

To safeguard environmentally friendly

operations the environment manage-

ment system in accordance with the eco

audit regulations (EEC 1836/93) was

introduced at Gendorf/Burgkirchen

(Germany), our largest production site.

Clariant’s Division Functional Chemi-

cals is one of the world's leading

manufacturers of surfactants and po-

lyglycols. The product range encom-

passes anionic, nonionic, cationic and

amphoteric surfactants. These include

raw materials for detergents and

cleaners, cosmetics and special pro-

ducts for chemical and industrial

applications.

This brochure presents a selection

of our products for chemical and indu-

strial applications.

The largest production

site of Division

Functional Chemicals:

Clariant Gendorf/

Burgkirchen.

Production and sales

Our surfactants are manufactured at our

production sites in Gendorf/Burgkirchen

and Wiesbaden (Germany), Tarragona

(Spain), Charlotte (USA), Clear Lake

(USA), Mexico City (Mexico), Coatza-

coalcos (Mexico), Maracay (Venezuela),

Sao Paulo (Brazil), Zarate (Argentina)

and elsewhere, and are available world-

wide through our sales organization.

5

Production site of

Division Functional

Chemicals in Tarragona

(Spain).

Industrial Applications of Surfactants

Surfactants are used as wetting agents,

emulsifiers and dispersing agents

for different chemical and industrial

applications. Clariant offers products for

the following fields:

■ Emulsifiers for emulsion polymerization

■ Dispersing agents for pigment pre-

parations, coatings, inks and paints

■ Wetting agents for hard surfaces,

ceramics, wood, plastics and metals

■ Emulsifiers for micro- and macro

emulsions of fats, hydrocarbons and

silicon oils

■ Emulsifiers for polyolefin wax

emulsions

■ Wetting agents for electroplating

processes

■ Surfactants for the building industry

■ Emulsifiers for bitumen emulsions

■ Auxiliaries for the sugar industry

■ Defoamers

Our service: new emulsifiers –

from the laboratory to production

In selecting suitable emulsifier systems

preliminary trials are necessary to

determine the stability of the monomer

emulsion and polymer dispersion and

the properties of the polymer films.

We will gladly supply product samples

from our commercial range for these

preliminary trials.

Besides the existing range Clariant

offers smaller sample amounts of

non-commercial products for labora-

tory investigations. These include

nonionic emulsifiers based on alcohol

ethoxylates, which are synthesized in

our development laboratory. If requi-

red, almost any alcohol can be reac-

ted with the desired amount of ethylene

oxide and a sample provided.

Our production know-how permits

rapid scale-up of new products from

the laboratory to the production stage.

Development products are thus

rapidly available commercially. We

will gladly advise you of what we

can do for you.

6

Nonionic SurfactantsProduct range

Trade name Chemical name Active content Appearance (20°C) Cloud point (°C) HLB value

Alkyl ethoxylates

Emulsogen EPN 118 Alkyl polyglycol ether with 11 EO ca. 80 % liquid 62 – 65 (3)* ca. 15

Emulsogen EPN 217 Alkyl polyglycol ether with 21 EO ca. 70 % liquid – ca. 17



Emulsogen LCN 050 Alkyl polyglycol ether with 5 EO ca. 100% liquid 67 – 70 (2) ca. 11

Emulsogen LCN 070 Alkyl polyglycol ether with 7 EO ca. 100% liquid 54 – 56 (1) ca. 13

Emulsogen LCN 088 Alkyl polyglycol ether with 8 EO ca. 80% liquid 62 – 65 (1)* ca. 13

Emulsogen LCN 118 Alkyl polyglycol ether with 11 EO ca. 80 % liquid 62 – 65 (3)* ca. 15

Emulsogen LCN 158 Alkyl polyglycol ether with 15 EO ca. 80 % liquid 69 – 71 (3)* ca. 16

Emulsogen LCN 217 Alkyl polyglycol ether with 21 EO ca. 70 % liquid – ca. 17



Emulsogen 3896 Fatty alcohol ethoxylate ca. 100 % waxy 73 – 75 (3) ca. 15

Genapol C 050 Coconut fatty alcohol ethoxylate with 5 EO ca. 100 % liquid 71 – 74 (2) ca. 10

Genapol C 100 Coconut fatty alcohol ethoxylate with 10 EO ca. 100 % paste 89 – 92 (1) ca. 14

Genapol C 200 Coconut fatty alcohol ethoxylate with 20 EO ca. 100 % waxy 76 – 78 (3) ca. 16

Genapol C 250 Coconut fatty alcohol ethoxylate with 25 EO ca. 100 % waxy 77 – 79 (3) ca. 17

Genapol LA 030 C12 / C14 fatty alcohol ethoxylate with 3 EO ca. 100 % liquid 53 – 55 (2) ca. 8




Genapol LA 079 C12 / C14 fatty alcohol ethoxylate with 7 EO ca. 90 % liquid 53 – 59 (1)* ca. 12

Genapol V 4463 C12 / C14 fatty alcohol ethoxylate with 10 EO ca. 100 % waxy – ca. 14

(1) 1 g in 100 cm3 distilled water • (2) 5 g in 25 cm3 25 % aqueous BDG • (3) 1 g in 100 cm3 10 % aqueous NaCl solution • * relative to the active substance

The following product range provides

a selection of our products and contains

nonionic and anionic surfactants used

as emulsifiers and wetting agents,

and further more dispersing agents and

defoamers.

New development products, which

will extend our product range, are not

yet included in this list.

7


Alkyl ethoxylates

Genapol O 020 Oleyl alcohol ethoxylate with 2 EO ca. 100 % liquid 35 – 38 (2) ca. 5

Genapol O 050 Oleyl alcohol ethoxylate with 5 EO ca. 100 % liquid 67 – 69 (2) ca. 9

Genapol O 080 Oleyl alcohol ethoxylate with 8 EO ca. 100 % liquid paste > 40 (1) ca. 11

79 – 81 (2)

Genapol O 100 Oleyl alcohol ethoxylate with 10 EO ca. 100 % paste > 75 (1) ca. 12

49 – 51 (3)

Genapol O 150 Oleyl alcohol ethoxylate with 15 EO ca. 100 % waxy 71 – 73 (3) ca. 13

Genapol O 200 Oleyl alcohol ethoxylate with 20 EO ca. 100 % waxy 74 – 76 (3) ca. 15

Genapol O 300 Oleyl alcohol ethoxylate with 30 EO ca. 100 % waxy – ca. 17

Genapol OA 040 C14 / C15 oxo alcohol ethoxylate with 4 EO ca. 100 % liquid 51 +/- 1,5 (2) ca. 9

Genapol OA 070 C14 / C15 oxo alcohol ethoxylate with 7 EO ca. 100 % paste 72 – 74 (2) ca. 12

Genapol OA 080 C14 / C15 oxo alcohol ethoxylate with 8 EO ca. 100 % paste 76 – 80 (2) ca. 12

Genapol OA 089 C14 / C15 oxo alcohol ethoxylate with 8 EO ca. 90 % liquid 76 – 80 (2)* ca. 12

Genapol OX 050 C12 / C15 oxo alcohol ethoxylate with 5 EO ca. 100 % liquid 63 – 64,5 (2) ca. 10

Genapol OX 060 C12 / C15 oxo alcohol ethoxylate with 6 EO ca. 100 % liquid paste 64 – 67 (2) ca. 11

Genapol OX 070 C12 / C15 oxo alcohol ethoxylate with 7 EO ca. 100 % liquid paste ca. 73 (2) ca. 12

Genapol OX 080 C12 / C15 oxo alcohol ethoxylate with 8 EO ca. 100 % paste 75 – 78 (2) ca. 13

Genapol OX 100 C12 / C15 oxo alcohol ethoxylate with 10 EO ca. 100 % paste 62 – 65 (1) ca. 14

Genapol OX 109 C12 / C15 oxo alcohol ethoxylate with 10 EO ca. 90 % liquid 62 – 65 (1)* ca. 14


„Alkyl ethoxylates“ to be continued on page 8

8



Alkyl ethoxylates continued from page 7

Genapol T 080 Tallow fatty alcohol ethoxylate with 8 EO ca. 100 % waxy 83 – 85 (2) ca. 11


60 – 63 (3)




Genapol T 250 p Tallow fatty alcohol ethoxylate with 25 EO ca. 100 % powder 77 – 79 (3) ca. 16

Genapol T 500 Tallow fatty alcohol ethoxylate with 50 EO ca. 100 % waxy – ca. 18

Genapol T 500 p Tallow fatty alcohol ethoxylate with 50 EO ca. 100 % powder – ca. 18

Genapol T 800 Tallow fatty alcohol ethoxylate with 80 EO ca. 100 % waxy – ca. 19

Genapol T 800 p Tallow fatty alcohol ethoxylate with 80 EO ca. 100 % powder – ca. 19

Genapol UD 030 C11 oxo alcohol ethoxylate with 3 EO ca. 100 % liquid 37 – 41 (2) ca. 9


Genapol UD 079 C11 oxo alcohol ethoxylate with 7 EO ca. 90 % liquid 52 – 55 (1)* ca. 13


Genapol UD 088 C11 oxo alcohol ethoxylate with 8 EO ca. 80 % liquid 62 – 65 (1)* ca. 13

Genapol UD 110 C11 oxo alcohol ethoxylate with 11 EO ca. 100 % liquid paste 62 – 65 (3) ca. 15

Genapol X 020 C13 oxo alcohol ethoxylate with 2 EO ca. 100 % liquid 25 – 30 (2) ca. 6



Genapol X 080 C13 oxo alcohol ethoxylate with 8 EO ca. 100 % liquid > 45 (1) ca. 13

74 – 76 (2)

Genapol X 089 C13 oxo alcohol ethoxylate with 8 EO ca. 90 % liquid > 45 (1)* ca. 13

74 – 76 (2)*


Genapol X 158 C13 oxo alcohol ethoxylate with 15 EO ca. 80 % liquid – ca. 15

Genapol X 250 C13 oxo alcohol ethoxylate with 25 EO ca. 100 % waxy – ca. 18



Genapol X 1000 C13 oxo alcohol ethoxylate with 100 EO ca. 100 % solid – ca. 19



Genapol 1879 C13 oxo alcohol ethoxylate ca. 40 % liquid – ca. 15

Genapol 3214 C13 oxo alcohol ethoxylate ca. 25 % liquid – ca. 18


9

(1)1 g in 100 cm3 distilled water • (2)5 g in 25 cm3 25 % aqueous BDG • (3)1 g in 100 cm3 10 % aqueous NaCl solution • *relative to the active substance


Nonylphenol ethoxylates ®Arkopal N 040 Nonylphenol ethoxylate with 4 EO ca. 100 % liquid 36 – 38 (2) ca. 9

Arkopal N 060 Nonylphenol ethoxylate with 6 EO ca. 100 % liquid 61 – 63 (2) ca. 11


76 – 78 (2)




Arkopal N 130 Nonylphenol ethoxylate with 13 EO ca. 100 % liquid paste 83 – 86 (1) ca. 14

Arkopal N 150 Nonylphenol ethoxylate with 15 EO ca. 100 % paste 92 – 95 (1) ca. 15

61 – 63 (3)

Arkopal N 200 Nonylphenol ethoxylate with 20 EO ca. 100 % paste 70 – 73 (3) ca. 16

Arkopal N 208 Nonylphenol ethoxylate with 20 EO ca. 80 % liquid 70 – 73 (3)* ca. 16

Arkopal N 230 Nonylphenol ethoxylate with 23 EO ca. 100 % waxy 73 – 75 (3) ca. 16


Arkopal N 300 Nonylphenol ethoxylate with 30 EO ca. 100 % waxy 76 – 78 (3) ca. 17



Arkopal N 1000 Nonylphenol ethoxylate with 100 EO ca. 100 % waxy – ca. 19

Tributylphenol ethoxylates®Sapogenat T 060 Tributylphenol ethoxylate with 6 EO ca. 100 % liquid 53 – 56 (2) ca. 10

Sapogenat T 080 Tributylphenol ethoxylate with 8 EO ca. 100 % liquid 60 – 68 (2) ca. 11



Sapogenat T 139 Tributylphenol ethoxylate with 13 EO ca. 90 % liquid 62 – 64 (1)* ca. 14

Sapogenat T 180 Tributylphenol ethoxylate with 18 EO ca. 100 % waxy 61 – 64 (3) ca. 15

Sapogenat T 300 Tributylphenol ethoxylate with 30 EO ca. 100 % waxy – ca. 17

Sapogenat T 500 Tributylphenol ethoxylate with 50 EO ca. 100 % waxy – ca. 18

Tristyrylphenol ethoxylates®Emulsogen TS 050 Tristyrylphenol ethoxylate with 5 EO ca. 100 % liquid 23 – 27 (2) ca. 7

Emulsogen TS 100 Tristyrylphenol ethoxylate with 10 EO ca. 100 % liquid 65 – 69 (2) ca. 10

Emulsogen TS 160 Tristyrylphenol ethoxylate with 16 EO ca. 100 % liquid 58 – 62 (1) ca. 13

Emulsogen TS 200 Tristyrylphenol ethoxylate with 20 EO ca. 100 % waxy 55 – 60 (3) ca. 14



Emulsogen TS 600 Tristyrylphenol ethoxylate with 60 EO ca. 100 % waxy – ca. 17

10




Alkyl alkoxylates

Genapol EP 0244 Alcohol EO-PO adduct ca. 100 % liquid ca. 20 (1)

(former name Genapol 2822) 33,5 – 36,5 (2)

Genapol EP 2424 Alcohol EO-PO adduct ca. 100 % liquid 25 – 27 (2)

(former name Genapol 3970)

Genapol EP 2464 Alcohol EO-PO adduct ca. 100 % liquid 42 – 44 (2)


Genapol EP 2544 Oxoalcohol EO-PO adduct ca. 100 % liquid 31 – 33 (2)




Genapol EP 2564 Oxoalcohol EO-PO adduct ca. 100 % liquid 27,5 – 31 (1)




Genapol PL 120 Alcohol EO-PO adduct ca. 100 % liquid > 25 (1)

31 – 34 (2)

Ethylene oxide-propylene oxide block polymers

Emulsogen 4084 EO-PO block polymer with 60 % EO ca. 100 % waxy 68 – 70 (3) ca. 12

Genapol PF 10 EO-PO block polymer with 10 % EO ca. 100 % liquid 34 – 37 (2) ca. 2



Genapol PF 80 p EO-PO block polymer with 80 % EO ca. 100 % powder 69 – 72 (3) ca. 16

Genapol ED 3030 Ethylenediamine EO-PO block polymer ca. 100 % liquid 52 – 55 (2) ca. 9

(former name Genapol B)

Genapol ED 3060 Ethylenediamine EO-PO block polymer ca. 100 % liquid 27 – 30 (2) ca. 6

(former name Genapol PN 30)

End capped Alkylethoxylates

Genapol BE 2410 Lauryl ethoxylate with 10 EO,

butyl-end capped ca. 100 % liquid 36 – 39 (2)

Genapol BE 2805 Coconut fatty alkyl ethoxylate

with 5 EO, butyl-end capped ca. 100 % liquid –

Genapol BE 2810 Coconut fatty alkyl ethoxylate

with 10 EO, butyl-end capped ca. 100 % liquid 39 – 42 (2)

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Trade name Chemical name Active content Appearance (20°C)

Fatty acid polyethyleneglycol esters®Genagen C 100 C12 / C14 fatty acid polyglycol ester with 10 EO ca. 100 % liquid

Genagen O 060 C16 / C18 fatty acid polyglycol ester with 6 EO ca. 100 % liquid



Genagen S 250 Stearic acid polyglycol ester with 25 EO ca. 100 % waxy

Fatty acid polyglycerol esters

Emulsogen OG Diglycerol oleate ca. 100 % liquid

Hostacerin DGI Diglycerol diisostearate ca. 100 % liquid

Hostacerin DGMS Diglycerol monostearate ca. 100 % pellets

Hostacerin TGI Polyglycerol diisostearate ca. 100 % liquid

Fatty acid polyglycerol ester ethoxylates

Hostacerin DGSB Diglycerol distearate ethoxylated with 4 EO ca. 100 % waxy

Hostacerin DGL Diglycerol laurate ethoxylated with 10 EO ca. 100 % liquid

Castor oil ethoxylates

Emulsogen EL 200 Castor oil ethoxylate with 20 EO ca. 100 % liquid




Emulsogen HCO 040 Hydrogenated castor oil ethoxylate with 40 EO ca. 100 % paste

Emulsogen HCO 060 Hydrogenated castor oil ethoxylate with 60 EO ca. 100 % paste

Emulsogen HCP 049 Hydrogenated castor oil ethoxylate with 40 EO ca. 090 % liquid

Sorbitane ester ethoxylate

Emulsogen 4156 Lauroyl sorbitane ethoxylate with 20 EO ca. 100 % liquid

Wax emulsifiers

Emulsogen P Alkylethoxylate ca. 100 % paste

Emulsogen PN extra Mixture of different alkyl ethoxylates ca. 100 % paste


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Anionic SurfactantsProduct range


Secondary alkyl sulphonates (Secondary alkane sulphonates)®Hostapur SAS 30 Secondary alkyl sulphonate, Na salt ca. 30 % liquid

Hostapur SAS 60 Secondary alkyl sulphonate, Na salt ca. 60 % paste

Hostapur SAS 93 Secondary alkyl sulphonate, Na salt ca. 93 % waxy pellets

Olefin sulphonates

Hostapur OS liquid C14 / C16 alpha-olefin sulphonate, Na salt ca. 42 % liquid

Hostapur OSB C14 / C16 alpha-olefin sulphonate, Na salt ca. 90 % powder

Alkyl sulphates

Emulsogen EPA 1954 C12 / C14 alkyl sulphate, Na salt ca. 30 % liquid

Emulsogen LS C12 alkyl sulphate, Na salt ca. 15 % liquid

Alkyl ether sulphates

Emulsogen EPA 073 Alkyl ether sulphate with 7 EO, Na salt ca. 28 % liquid

Emulsogen LCA 073 Alkyl ether sulphate with 7 EO, Na salt ca. 28 % liquid

Emulsogen LA 083 Alkyl ether sulphate with 8 EO, Ammonium salt ca. 30 % liquid®Genapol LRO liquid C12 / C 14 alkyl ether sulphate with 2 EO, Na salt ca. 27 % liquid

Genapol LRO paste C12 / C 14 alkyl ether sulphate with 2 EO, Na salt ca. 68 % paste

Emulsogen ZRO liquid C12 / C 14 alkyl ether sulphate with 3 EO, Na salt ca. 27 % liquid

Zeliquid LP 2 Lauryl ether sulphate with 3 EO, ammonium salt + organ. solvent ca. 50 % liquid

Alkyl aryl ether sulphates®Hostapal BV conc. Tributyl phenol ether sulphate with 7 EO, Na salt ca. 50 % paste

Hostapal BV liquid Tributyl phenol ether sulphate with 7 EO, Na salt ca. 17 % liquid

Polyglycol ether sulphates

Emulsogen PF 20 S Polyalkylene glycol ether sulphate, ammonium salt ca. 50 % liquid

Sulphosuccinic acid esters

Emulsogen SB 10 Diisodecyl sulphosuccinate, Na salt +IPA ca. 65 % liquid

Emulsogen SF 8 Diisooctyl sulphosuccinate, Na salt ca. 50 % liquid

Fatty alkyl amine sulphosuccinamates

Emulsogen OLS Octyl amine sulphosuccinamate, Na salt ca. 36 % liquid

Emulsogen TAS Tallow alkyl amine sulphosuccinamate, Na salt ca. 36 % liquid

Phosphoric acid mono esters

Hostaphat CC 100 Cetyl phosphoric acid ester, acid form ca. 100 % powder

Phosphoric acid di esters

Hostaphat L 327 Phosphoric acid ester of lauryl ethoxylate (2 EO) ca. 95 % liquid

and polyethylene glycol

Phosphoric acid mono/di esters

Hostaphat MDAH Mono-/di-2-ethylhexyl phosphoric acid ester, acid form ca. 98 % liquid

Hostaphat CG 120 Mono-/diisostearyl phosphoric acid ester, acid form ca. 90 % liquid

Hostaphat CS 120 Mono-/distearyl phosphoric acid ester, acid form ca. 92 % wax

Hostaphat 1306 Isotridecyl polyoxethyl (6 EO) phosphoric acid mono/diester, ca. 96 % liquid

acid form

13


Phosphoric acid mono/di/tri esters

Emulsogen DMR Stearoyl polyoxyethylene phosphate ca. 100 % flakers

Hostaphat B 310 Tributoxyethyl phosphate, acid form ca. 87 % liquid

Hostaphat KL 340 D Lauryl polyethoxy (4 EO) phosphoric acid ester, Na-salt ca. 90 % liquid

Hostaphat KL 340 N Lauryl polyethoxy (4 EO) phosphoric acid ester, Na-salt ca. 90 % liquid

Hostaphat KW 340 D Stearyl polyethoxy (4 EO) phosphoric acid ester, Na-salt ca. 90 % liquid

Hostaphat KW 340 N Stearyl polyethoxy (4 EO) phosphoric acid ester, Na-salt ca. 90 % liquid

Alkyl phosphonic acids

Hostaphat OPS 100 n-Octane phosphonic acid ca. 100 % waxy

Hostaphat OPS 75 n-Octane phosphonic acid + organ. solvent/water ca. 75 % liquid

Alkyl polyethylene glycol ether carboxylic acids

Emulsogen CLA 020 Fatty alcohol polyoxyethylene carboxylic acid with 2 EO ca. 90 % liquid





Emulsogen COA 070 Fatty alcohol polyoxyethylene carboxylic acid with 7 EO ca. 90 % liquid

Emulsogen COL 020 Fatty alcohol polyoxyethylene carboxylic acid with 2 EO ca. 90 % liquid




Fatty acid isethionates

Hostapon SCI-65 Coconut fatty acid isethionate, Na salt ca. 65 % flakes

Fatty acid methyl taurides

Arkopon T Teig 8015 Oleic acid methyl tauride, Na salt ca. 40 % paste

Hostapon CT Teig Coconut fatty acid methyl tauride, Na salt ca. 30 % paste

Hostapon TPHC Oleic acid methyl tauride, Na salt ca. 60 % powder

Fatty acid sarkosin and sarkoside

Arkomon SO Oleyl sarkosin ca. 95 % liquid

Medialan LD Lauroyl sarcoside, Na salt ca. 30 % liquid

Alkyl benzenesulphonates, Ca-salts

Calsogen 3546 Tetrapropylene benzenesulphonate, Ca-salt in 2-ethyl hexanol ca. 60 % liquid

Calsogen 4814 n-Dodecyl benzenesulphonate, Ca-salt in 2-ethyl hexanol ca. 60 % liquid

Phenylsulfonate CA Tetrapropylene benzenesulphonate, Ca-salt in isobutanol ca. 70 % pasty

Phenylsulfonate Tetrapropylene benzenesulphonate, Ca-salt in solvent naphtha ca. 40 % viscous liquid

CA 100 and a nonionic surfactant, flash point > 100°C

Phenylsulfonate CAL n-Dodecyl benzenesulphonate, Ca-salt in isobutanol ca. 70 % pasty

Phenylsulfonate CAN Tetrapropylene benzenesulphonate, Ca-salt in isobutanol ca. 62 % liquid

and a nonionic surfactant

14

Copolymerizable Emulsifiers &Speciality MonomersProduct range


Vinyl ether alkoxylates (PO-EO-block polymers)

Emulsogen R 109 Vinyl ether alkoxylate with 10 EO ca. 90 % liquid



Allyl ether alkoxylates (PO-EO-block polymers)

Emulsogen RAL 109 Allyl ether alkoxylate with 10 EO ca. 90 % liquid



Allyl polyoxyalkylene sulphates

Emulsogen APS 100 Allyl polyoxyalkylene sulphate with 10 EO, ammonium salt ca. 100 % liquid

Emulsogen APS 104 Allyl polyoxyalkylene sulphate with 10 EO, ammonium salt ca. 40 % liquid

Emulsogen APS 100 S Allyl polyoxyalkylene sulphate with 10 EO, Na salt ca. 100 % liquid

Allyl polyoxyarylene sulphates

Emulsogen APG 2019 Allyl phenylpolyol ether sulphate with 20 EO, ammonium salt ca. 90 % liquid

Methacrylic acid esters

Genagen M 750 MA Methacrylic acid ester of polyethyleneglycol ether ca. 100 % pasty

Genagen M 1100 MA Methacrylic acid ester of polyethyleneglycol ether ca. 100 % waxy

Genagen LA 070 MA Methacrylic acid ester of C12/C14 fatty alcohol ethoxylate with 7 EO ca. 100 % liquid

15

Dispersing AgentsProduct range


Naphthalene sulphonic acid - formaldehyde condensates

Dispersogen NN Condensation product of formaldehyde and ca. 80 % powder

naphthalene sulphonate, sodium salt, max. 20 % Na2SO4

Dispersogen R 5 Condensation product of formaldehyde and ca. 95 % powder


Dispersogen 5338 Condensation product of formaldehyde and ca. 92 % powder


Alkylphenol - formaldehyde - bisulphite condensates

Dispersogen 1494 Condensation product of formaldehyde, cresol, nonylphenol ca. 80 % powder

and sodium bisulphite; contains NaCl

Dispersogen 1494 liquid Condensation product of formaldehyde, cresol, nonylphenol ca. 35 % liquid

and sodium bisulphite; contains NaCl

Dispersogen P liquid Condensation product of formaldehyde, cresol and ca. 26 % liquid

sodium bisulphite; contains NaCl

Novolac derivatives

Dispersogen 1728 Nonylphenol novolac polyoxyethylene sulphosuccinate, ca. 35 % liquid

Na salt

Dispersogen 2774 Nonylphenol novolac ethoxylate ca. 100 % liquid

Dispersogen 2774-1 Nonylphenol novolac ethoxylate in ethylene glycol ca. 50 % liquid

Dispersogen 2774-2 Nonylphenol novolac ethoxylate in propylene glycol ca. 50 % liquid

Tristyrylphenol derivatives, anionic

Dispersogen LFH Tristyrylphenol polyoxyethylene phosphoric acid ester ca. 96 % liquid

Dispersogen LFS Tristyrylphenol polyoxyethylene phosphoric acid ester, ca. 92 % liquid

triethanolamine salt

Castor oil derivatives, anionic

Dispersogen 4387 Castor oil polyoxyethylene sulphosuccinic acid ester, Na salt ca. 80 % liquid

Quaternary dispersing agents

Dispersogen SPS Stabilizer and dispersing agent for sodium silicate n.n. liquid

in silicate paints

16

DefoamersProduct range

Trade name Ionicity Flash Point Appearance (20°C) Application example

Silicone containing defoamers

Antimussol 4752 nonionic > 100°C liquid FDA-approved defoamer for paper

treatment and other industrial

applications

Antimussol V 4847 nonionic > 100°C liquid EPA-approved defoamer for crop

protection

Antimussol V 5282 nonionic > 100°C liquid defoamer for water miscible

formulations

Polyalkylene glycol based defoamers

Antimussol TW nonionic > 100°C liquid emulsion polymers, water treatment

Antimussol V 5084 nonionic > 100°C liquid defoaming of surfactant formulations

Genapol PH 10 nonionic > 100°C liquid EO/PO block polymer for metal working

fluids and other industrial applications

Genapol PF 10 nonionic > 100°C liquid EO/PO block polymer for industrial

applications e.g. sugar refinement

Phosphate ester based defoamers

Antimussol TIP anionic ca. 27°C liquid Phosphorus containing defoamer for

emulsion polymerization and other

industrial applications, water treatment

Mineral oil based defoamers

Antimussol 4846 N anionic > 100°C liquid Phosphorus containing defoamer for

emulsion polymers and other industrial

applications

Antimussol V 5348 nonionic > 150°C liquid emulsion paints, coatings, pigment

preparations

17

Surfactants from ClariantEmulsifiers for emulsion polymerization

Emulsifiers are substances that become

active at interfaces. They perform a

number of tasks in the complex system

of emulsion polymerization. For example

they enable the water-insoluble mono-

mers to be distributed extremely finely

in the aqueous phase and stabilize the

polymer dispersion produced from it.

Clariant emulsifiers are used to manu-

facture a variety of polymer systems:

■ In the polymerization of vinyl acetate

to homopolymers or co- and ter-

polymers together with other vinyl

esters, acrylates, vinyl chloride

and ethylene

■ In the polymerization of pure acrylate

and styrene-acrylate dispersions

■ In the manufacture of butadiene-

styrene latices

■ In the manufacture of polyvinyl

chloride using the emulsion polymer-

ization process

■ In the manufacture of butadiene-

styrene rubber

■ In the manufacture of ABS plastic

The diagram beside shows a model of

the complex interactions involved in the

stabilization of the polymer particles.

Protective ColloidMolecules

OH Groups

Emulsifier Molecules

Explanation:

Polymer Particle

Diagram: emulsion polymerization

18


Apart from stabilizing the monomer

emulsion, emulsifiers have a great

influence on the properties of the poly-

mer dispersions. These include important

parameters such as particle size and

particle size distribution of the polymer

particles, viscosity, electrolyte stability,

frost resistance of the dispersion, film-

forming properties and many other

application properties of the polymer

dispersion.

The slightest changes to the polymer-

ization system can lead to consider-

able variations in the dispersion proper-

ties. To ensure consistent quality of

the polymer dispersion, our emulsifiers

are subject to strict quality control.

The influence of the nonionic emul-

sifier on the dispersion properties

was investigated by means of a model

formulation for a polyvinyl acetate

dispersion.

The ®Emulsogen EPN grades investigated are nonionic emulsifiers based on an

oxoalcohol with different degrees of ethoxylation.

The two graphs that follow on page 8

show the influence of the degree of

ethoxylation of the fatty alcohol ethoxy-

lates on the viscosity of the dispersion

and on the particle size. The emulsifier

concentrations were kept constant.

Monomer mixture®VeoVa 10, Shell1) 25 %

Initiator solution

Potassium peroxodisulphate 1.17 %

Vinyl acetate 75 %

Water 98.83 %

Degree of ethoxylation

11 mol ethylene oxide




Composition

Water®Tylose H 200 YG4

Borax®Emulsogen EPA 073®Emulsogen EPN grade

Acetic acid 98 %®Nipacide CI 15 (preservative)

Initiator solution (to liquor)

Monomer mixture (to liquor)

Initiator solution (stock batch)

Monomer mixture (stock batch)

Vinyl acetate dispersion, model formulation

Nonionic emulsifier

Emulsogen EPN 118

Emulsogen EPN 207

Emulsogen EPN 287

Emulsogen EPN 407

Concentration

32.02 %

1.06 %

0.26 %

0.91 %

1.51 %

0.11 %

0.15 %

4.50 %

5.30 %

6.48 %

47.70 %

1) VeoVa 10 is a registered trademark of Shell for 2,2-dimethyloctanoic acid vinyl ester

19

Influence of the emulsifier on the viscosity of a vinyl acetate/ VeoVa 10 dispersion

Influence of the emulsifier on the particle size2) of a vinyl acetate/ VeoVa 10 dispersion

Not only the constitution of the emul-

sifier but also its concentration has

an influence on the properties of the

dispersion. The next four graphs

illustrate this effect on the viscosity

of the dispersion by means of the model

formulation vinyl acetate/ VeoVa 10.

Viscosities of

Emulsogen-containing

polymer dispersions

(vinyl acetate/ VeoVa 10)

Tylose H 200 YG4 (1.06 %);

Emulsogen EPA 073

(0.91 %)

Particle size of polymer

dispersions (vinyl

acetate/ VeoVa 10) with:

Tylose H 200 YG4 (1.06 %);

Emulsogen EPA 073

(0.91 %); Emulsogen EPN

grades (1.51 %) 2) Determined by turbidity

measurements, these

values are not absolute

but indicate a tendency

20


Influence of the concentration of Emulsogen EPN 118 on the viscosity of the dispersion

Viscosities of Emulsogen

EPN 118-containing

polymer dispersions

(vinyl acetate/ VeoVa 10);

Tylose H 200 YG4

(1.06 %); Emulsogen

EPA 073 (0.91 %)


Viscosities of

Emulsogen EPN 207-

containing polymer

dispersions (vinyl

acetate/ VeoVa 10);

Tylose H 200 YG4

(1.06 %); Emulsogen

EPA 073 (0.91 %)

21




EPN 287-containing

polymer dispersions


Tylose H 200 YG4

(1.06%); Emulsogen

EPA 073 (0.91%)


EPN 407-containing

polymer dispersions


Tylose H 200 YG4

(1.06 %); Emulsogen

EPA 073 (0.91 %)

22


Influence of the emulsifier on the amount of coagulate in a vinyl acetate/ VeoVa 10 dispersion

The following graphs on this page show

the effect of the emulsifier system on the

amount of coagulate and the water ab-

sorption of the polymer film.

Amount of coagulate in


polymer dispersions


with: Tylose H 200 YG4

(1.06 %); Emulsogen

EPA 073 (0.91 %);

Emulsogen EPN grades

(1.51%)

Method: Filtration of the

dispersion through

a 100-µµm screen, then

filtration of the filtrate

through the finer

40-µµm screen.

Influence of the emulsifier on the water absorption of a dispersion film based on vinyl acetate/ VeoVa 10

Water absorption of


polymer dispersions


with: Tylose H 200 YG4

(1.06 %); Emulsogen

EPA 073 (0.91 %);

Emulsogen EPN grades

(1.51%)

23

This information is based on our present

knowledge and is intended to provide

general notes on our products and

their uses. It should not therefore be

construed as guaranteeing specific

properties of the products described

or their suitability for a particular appli-

cation. Any existing industrial property

rights must be observed. The quality

of our products is guaranteed under

our General Conditions of Sale.

February 2004

Our products are constantly upgraded

on the basis of the latest research re-

sults. Products may occasionally be

deleted in the course of updating the

sales range. Development products

that have reached the production stage

are not included in this list.

Clariant GmbH


Industrial Performance Chemicals

Research & Development

Worldwide

65926 Frankfurt, Tel.: +49-69-305-6308, Fax: +49-69-305-16504

Marketing

Europe

65840 Sulzbach, Tel.: +49-6196-757-7437, Fax: +49-6196-757-8945

USA & Canada

Mount Holly NC 28120, Tel.: +1-704-822-2514, Fax: +1-704-822-2193

Mexico

53500 Naucalpan, Tel.: +52-55-5329-1877, Fax: +52-55-5387-3248

Latin America

04795-900 São Paulo SP, Tel.: +55-11-5683-7413, Fax: +55-11-5683-7694

China

Tsuen Wan, Hong Kong, Tel.: +852-2406-4189, Fax: +852-2506-1636

Japan

Tokyo 113-8662, Tel.: +81-3-5977-7934, Fax: +81-3-5977-7893

South-East Asia

Tangerang, Jakarta, Tel.: +62-21-5579-3656, Fax: +62-21-5579-7139

Australia/New Zealand

Chadstone Vic 3148, Tel.: +61-3-9254-1092, Fax: +61-3-9254-1011

Internet: www.ipc.clariant.com

Exactly your chemistry.

DSB&

K

EBR

521

6 E

02/0

4

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