Date post: | 26-Oct-2015 |
Category: |
Documents |
Upload: | sundarapandiyan-sundaramoorthy |
View: | 19 times |
Download: | 4 times |
UNIT OPERATIONS GENERATING TDSUNIT OPERATIONS GENERATING TDS
Beam house operations
Tanyard operations
Dyehouse oerations
Beam house operations
Tanyard operations
Dyehouse oerations
MEASURES ADOPTED TO REDUCE TDSMEASURES ADOPTED TO REDUCE TDS
• Effluent treatment system
• Present leather processing technology
• Process technology for tomorrow
• Effluent treatment system
• Present leather processing technology
• Process technology for tomorrow
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
Soaking Liming Deliming Pickling Cr Tanning Neutn. Dye&Fat
TDS (ppm)
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
Soaking Liming Deliming Pickling Cr Tanning Neutn. Dye&Fat
TDS (ppm)
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
Soaking Liming Deliming Pickling Cr Tanning Neutn. Dye&Fat
TDS (ppm)
T D S GENERATIONT D S GENERATION
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
SOAKING SOAKING
• Huge volume of wastewater
• High level of TDS
• High level of Chloride
•• Huge volume of wastewaterHuge volume of wastewater
•• High level of High level of TDSTDS
•• High level of ChlorideHigh level of Chloride
ProblemsProblems
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
SOAKING SOAKING
• Evaporation - viable solution• Solar Evaporation - not a complete solution• Mechanical evaporation - high operating cost• Accelerated Evaporation - Viable• Suspended Solids need to be removed• Wet air Oxidation - Viable and effective
•• Evaporation Evaporation -- viable solutionviable solution•• Solar Evaporation Solar Evaporation -- not a complete solutionnot a complete solution
•• MechanicalMechanical evaporation evaporation -- high operating costhigh operating cost•• Accelerated Evaporation Accelerated Evaporation -- ViableViable•• Suspended Solids need to be removedSuspended Solids need to be removed•• Wet air Oxidation Wet air Oxidation -- Viable and effectiveViable and effective
SolutionsSolutions
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
LIMING LIMING
• Use of Lime and Sulfide
• Pulping or Burning of Hair
•• Use of Lime and SulfideUse of Lime and Sulfide
•• Pulping or Burning of Hair Pulping or Burning of Hair
ProblemsProblems
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
LIMING LIMING
• Lime with low sludge
• Sulfide free / Less sulfide Enzyme Process
• Hair Saving Process
•• Lime with low sludge Lime with low sludge
•• Sulfide free / Less sulfide Enzyme ProcessSulfide free / Less sulfide Enzyme Process
•• Hair Saving Process Hair Saving Process
SolutionsSolutions
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
PICKLING PICKLING
• High Chloride
• High TDS
•• High ChlorideHigh Chloride
•• High TDS High TDS
ProblemsProblems
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
PICKLING PICKLING
• Pickle free Process
• Pickling liquor Recycling
•• Pickle free ProcessPickle free Process
•• Pickling liquor Recycling Pickling liquor Recycling
SolutionsSolutions
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
CHROME TANNING CHROME TANNING
• High TDS
• Significant level of Chromium
• High Sulfate
•• High TDSHigh TDS
•• Significant level of Chromium Significant level of Chromium
•• High SulfateHigh Sulfate
ProblemsProblems
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
CHROME TANNING CHROME TANNING
• Enhancing the uptake
• Direct Chrome Liquor recycling
• Recycling and Reuse
•• Enhancing the uptake Enhancing the uptake
•• Direct Chrome Liquor recyclingDirect Chrome Liquor recycling
•• Recycling and ReuseRecycling and Reuse
SolutionsSolutions
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
WETFINISHING WETFINISHING
• Poor Exhaustion
• Neutral salt content
•• Poor ExhaustionPoor Exhaustion
•• Neutral salt contentNeutral salt content
ProblemsProblems
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
WETFINISHING WETFINISHING
• Auxiliaries with better exhaustion levels
• Liquid auxiliaries
•• Auxiliaries with better exhaustion levelsAuxiliaries with better exhaustion levels
•• Liquid auxiliariesLiquid auxiliaries
SolutionsSolutions
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
GENERAL GENERAL
• High fluctuations in pH level - responsible for
salt formation -results high TDS
•• High fluctuations in pH level High fluctuations in pH level -- responsible forresponsible for
salt formation salt formation --results high TDSresults high TDS
ProblemProblem
• Close range pH profile process•• Close range pH profile processClose range pH profile processSolutionSolution
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
0
1
2
3
4
5
6
7
8
Soaking Liming Deliming Pickling Cr Tanning Neutn. Dye&Fat
Wastewater (L / Kg)
0
1
2
3
4
5
6
7
8
Soaking Liming Deliming Pickling Cr Tanning Neutn. Dye&Fat
Wastewater (L / Kg)
0
1
2
3
4
5
6
7
8
Soaking Liming Deliming Pickling Cr Tanning Neutn. Dye&Fat
Wastewater (L / Kg)
WASTEWATER GENERATIONWASTEWATER GENERATION
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
SOAKING SOAKING
• Counter Current Soaking•• Counter Current SoakingCounter Current Soaking
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
LIMING LIMING
• Paste or Paint Liming for unhairing
• Reuse of reliming liquor
•• Paste or Paint Liming for unhairingPaste or Paint Liming for unhairing
•• Reuse of reliming liquorReuse of reliming liquor
LERIG 2004 CLRI C KALYANAM & COLERIG 2004 CLRI C KALYANAM & CO
DELIMING DELIMING • Reuse of Deliming and Washing liquor•• Reuse of Deliming and Washing liquorReuse of Deliming and Washing liquor
PICKLING PICKLING • Reuse of Pickling liquor•• Reuse of Pickling liquorReuse of Pickling liquor
CHROME TANNING CHROME TANNING • Reuse of Chrome tan liquor•• Reuse of Chrome tan liquorReuse of Chrome tan liquor