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  • Classification Level:

    Business Owner:

    Distribution List:

    Technology Licensing for the Petrochemical Industry

    Global E&C Solutions Communications

    Budapest, 13/10/2015 l Dirk Burghardt l Sales Director Licensing and Technology, Downstream & Petrochemicals

    CEE & Turkey Refining and Petrochemicals

    13th-15th October 2015 I Sofitel Budapest, Hungary

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 2 13/10/2015

    Synthesis Gas Production

    Air Separation Plants

    Methanol & MTP

    Natural gas conditioning

    Petrochemicals

    Oleochemicals, Biodiesel

    Fischer-Tropsch GTL

    The Air Liquide Group

    Large Industries Air gases and hydrogen 15-year contracts Pipeline networks Industrial basins

    Electronics Carrier gases Specialty gases Equipment and Installations

    Healthcare Hospitals Homecare Hygiene

    Industrial Merchant Bulk and cylinder gases 80 countries Wide variety of sectors and customer sizes

    Global E&C Solutions Design, Engineering & Construction

    of leading-edge processing facilities Plants for AL Group and 3rd Party Clients

    Other activities Welding & Cutting Diving Specialty chemicals

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 3 13/10/2015

    Agenda

    1. Petrochemistry General

    2. 1,3-Butadiene

    3. Benzene (Distapex)

    4. Acrylic Acid

    5. Melamine

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 4 13/10/2015

    Petrochemistry General Technology Map

    Products Intermediates

    Acrylic Acid

    Butadiene

    Benzene

    Urea

    Propylene

    C4-Cut

    Aromatics

    Melamine

    MTP MeOH

    Natural Gas

    Syngas

    (CO, H2)

    Refinery /

    Cracker

    ASU

    Acrylates

    SAP

    Synthetic

    Rubber

    Styrene,

    Phenol, CH

    Laminates

    Adhesives

    Poly-

    propylene

    Air Liquide E&C features special expertise in

    Oxidation

    Extraction

    Hydrogenation

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 5 13/10/2015

    Technology Portfolio Business Model

    Proprietary

    Technologies

    Own Research &

    Development

    Alliances

    Edgein

    Aquisition

    BP

    (Semi-) Exclusive

    Partnerships

    Technology

    Portfolio

    Distapex

    Acrylic Acid

    Butadiene

    Acrylates

    Melamine

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 6 13/10/2015

    1. Petrochemistry General

    2. 1,3-Butadiene

    3. Benzene (Distapex)

    4. Acrylic Acid

    5. Melamine

    Agenda

    //commons.wikimedia.org/wiki/File:Buta-1,3-diene_200.svg

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 7 13/10/2015

    Global Butadiene Demand - Outlook

    Global Consumption 2013: 10.5 mio tons

    Expected Average Annual Growth Rate 2013 2020: 3.2 % driven by growth in demand for ABS, SBR, and Butadiene Rubber

    Asia Pacific 55% North America

    17%

    Western Europe

    16%

    Eastern Europe

    5%

    South America

    3%

    Central Europe

    3%

    Middle East & Africa

    1%

    BD Consumption 2013

    -4%

    -2%

    0%

    2%

    4%

    6%

    8%

    10%

    12%

    14%

    16%

    BD Consumption Growth2000 - 2013

    BD Consumption Growth2013 - 2020

    Source: Nexant, Mai 2014

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 8 13/10/2015

    Butadiene Experience and Partnership

    NMP Process invented

    by BASF

    BASF

    Technology Owner

    First BASF Plant built by Lurgi

    Lurgi

    Sublisensor

    for BASF NMP Process

    Lurgis First Butadiene Reference

    Esso (CAA) Technology

    Lurgi projects based on

    Esso (CAA)

    Shell (ACN)

    Nippon Zeon (DMF)

    BASF (NMP)

    1958

    1968

    Since 1990

    Continuous Improvements

    Early

    1960s

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 9 13/10/2015

    BASF NMP Technology Features

    Worldwide recognized technology

    Safe

    Eco-Efficient

    Reliable

    Low environmental impact

    57 References in total

    30 since Y2000

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 10 13/10/2015

    Butadiene Extraction Technology - Challenges

    Separation of Butadiene from a complex Mix of C4

    C4 Mix is different in each individual project

    Operational Difficulties

    Popcorn Formation

    Foaming

    Fouling

    C4 Acetylenes

    Raffinate Propyne

    Butadiene C4 Feed

    C4 / C5

    Extractive Distillation

    Distillation

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 11 13/10/2015

    AL E&C - The Technology Partner of Choice

    AL E&C has long-term competence in Hydrocarbon Extraction

    Besides standard process concepts we offer tailor-made solutions to meet the specific requirements of its clients

    Active Contribution to continuous process improvements with regard to:

    Popcorn Formation

    Foaming

    Fouling

    Source: Popcorn Issue Group (European

    Ethylene Producers Committee)

    Proven highest On-stream Efficiency

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 12 13/10/2015

    ONGC, Gutjarat

    126,600 tpa (2009)

    Russian Federation

    105,000 tpa (2012)

    10 References since 2005, 4 in 2012, 36 in total

    EVONIK, Antwerp, Belgium

    100,000 tpa (2012)

    OMV, Schwechat, Austria

    + 12,000 tpa (2012)

    Petrobras, Rio

    + 165,000 tpa (2008)

    BASF, Ludwigshafen

    + 14,000 tpa (2008)

    HALDIA, India

    + 25,000 tpa (2007)

    Copesul, Triunfo

    + 103,500 tpa (2005)

    OXENO, Marl

    + 36,000 tpa (2006)

    MOL, Tiszaujvaros, Hungary

    130,000 tpa (2012)

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 13 13/10/2015

    1. Petrochemistry General

    2. 1,3-Butadiene

    3. Benzene (Distapex)

    4. Acrylic Acid

    5. Melamine

    Agenda

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 14 13/10/2015

    Global Benzene Demand - Outlook

    Global Production 2014: 45 mio tons

    Expected Average Annual Growth Rate 2015 2020: 3.5 % driven by growth in demand Styrene, Phenol & Cyclohexane

    0

    10

    20

    30

    40

    50

    60

    2014 2015 2016 2017 2018 2019 2020

    Millio

    ns

    Other Production Sorces

    On-Purpose Production

    Production from Petrochemicals

    Producton from Refineries

    Source: Platts

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 15 13/10/2015

    Distapex Proprietary Technology - Challenges

    Separation of Benzene from a complex Mix of Pyrolysis Gasoline

    C6 Mix is different in each individual project

    Pygas

    C5

    Benzene

    Selective

    Hydrogenation

    Full Hydrogenation

    and

    Desulphurisation

    Extractive

    Distillation

    C7+ to Gasoline Pool

    C5- to Gasoline Pool

    H2

    Off-gas H2 Off-gas

    C6

    Raffinate

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 16 13/10/2015

    AL E&C Frankfurt - The Technology Partner of Choice

    AL E&C has long-term competence in Hydrocarbon Extraction

    Lurgi technology developed in 1960s and continuously improved

    Reference capacities ranging from 20,000 tpa up to 400,000 tpa

    Use of same solvent as in Butadiene Extraction (NMP)

    Synergies for Cracker operators

    Advanced competences available with AL E&C Frankfurt

    Outstanding solution for Benzene production

    High purity and high Benzene yield

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 17 13/10/2015

    OPaL, India

    165,000 tpa (2009)

    6 Aromatics References since 2003, 25 in total

    Gexaro, France

    252,000 tpa (2005)

    OMV, Burghausen

    + 10,000 tpa (2003)

    HALDIA, India

    + 77,000 tpa (2005)

    Petrochimica Uniao, Brazil

    + 123,000 tpa (2007)

    SABIC, The Netherlands

    280,000 tpa (2005)

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 18 13/10/2015

    Agenda

    1. Petrochemistry General

    2. 1,3-Butadiene

    3. Benzene (Distapex)

    4. Acrylic Acid

    5. Melamine

  • Air Liquide, world leader in gases, technologies and services for Industry and Health 19 13/10/2015

    Global Consumption 2014: 5.2 mio tons

    Expected Average Annual Growth Rate 2014 2019: 3.8 % driven by growth in demand for SAP and Acrylic Esters

    Global Acrylic Acid Demand - Outlook

    0

    1000

    2000

    3000

    4000

    5000

    6000

    7000

    2011

of 30/30
Classification Level: Business Owner: Distribution List: Technology Licensing for the Petrochemical Industry Global E&C Solutions Communications Budapest, 13/10/2015 l Dirk Burghardt l Sales Director Licensing and Technology, Downstream & Petrochemicals CEE & Turkey Refining and Petrochemicals 13 th -15 th October 2015 I Sofitel Budapest, Hungary
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