Test Report No. 5303972-30 Date: 20/MAR/2020 Page 1 of 13 mtm plastics GmbH Ms. Daniela Werner Bahnhofstr. 106 99759 Niedergebra GERMANY R:\M\mtm plastics GmbH_10070390\2020\5303972\5303972-30_SVHC.doc The following sample(s) was/were submitted and identified by/on behalf of the client as: SGS Job file : 5303972 Order date : 02/MAR/2020 Order number : - Sampling : by Client or by a third party acting at the Client’s direction Condition of the samples : appropriate for testing Sample receiving Date : 06/MAR/2020 Testing period : 06/MAR/2020 – 20/MAR/2020 Sample No Sample designation Sample material 200253653 Dipolen H -91 plastic granules Applied analytical technique Test Requested : As specified by client, the sample(s) was/were tested with reference to Regulation (EC) No 1907/2006 concerning the REACH for: 205 Substances of Very High Concern (SVHC) candidate list according to the press release (ECHA) on January 16, 2020 Test Result(s) : Please refer to following pages. Summary According to the ruling of the Court of Justice of the European Union on the definition of an article under REACH, and the specified scope as well as analytical technique, the test results of the selected component article are ≤ 0.1% (w/w) in the submitted sample(s). SGS INSTITUT FRESENIUS GmbH i.V. i.A. Wera Leonhard / tp Annkatrin Kuhl Projektleiterin / Project Manager Projektleiterin / Project Manager Consumer and Retail Consumer and Retail Tel. +49 (0)6128 / 744 - 186 Tel. +49 (0)6128 / 744 - 280
Transcript
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 1 of 13
The following sample(s) was/were submitted and identified by/on behalf of the client as:
SGS Job file : 5303972
Order date : 02/MAR/2020
Order number : -
Sampling : by Client or by a third party acting at the Client’s direction
Condition of the samples : appropriate for testing
Sample receiving Date : 06/MAR/2020
Testing period : 06/MAR/2020 – 20/MAR/2020
Sample No Sample designation Sample material
200253653 Dipolen H -91 plastic granules
Applied analytical technique
Test Requested : As specified by client, the sample(s) was/were tested with reference to Regulation (EC) No 1907/2006 concerning the REACH for: 205 Substances of Very High Concern (SVHC) candidate list according to the press release (ECHA) on January 16, 2020
Test Result(s) : Please refer to following pages.
Summary According to the ruling of the Court of Justice of the European Union on the
definition of an article under REACH, and the specified scope as well as analytical technique, the test results of the selected component article are ≤ 0.1% (w/w) in the submitted sample(s).
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 2 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
Test Method : SGS In-House method-RSTS-EE-SVHC-007. Analysis was performed by ICP-OES, UV-VIS, GC/MS, LC/MS, GC/FPD, LC/MS/DAD, UPLC-MSMS. (Cooperation with SGS Taiwan)
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 3 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 4 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
No. Substance Name RL (%)
Concentration (%)
56. Aluminosilicate, Refractory Ceramic Fibres【oxides of aluminium and
silicon are the main components present (in the fibres) within variable concentration ranges】
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 5 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
95. 4-Nonylphenol, branched and linear [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, covering also UVCB- and well-defined substances which include any of the individual isomers or a combination thereof]
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 6 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 7 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
No. Substance Name RL (%)
Concentration (%)
139. 4-Nonylphenol, branched and linear, ethoxylated [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB- and well-defined substances, polymers and homologues, which include any of the individual isomers and/or combinations thereof]
161. Reaction mass of 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate and 2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-octyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate (reaction mass of DOTE and MOTE)***
- n.d.
162. 1,2-benzenedicarboxylic acid, di-C6-10-alkyl esters; 1,2-benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters with ≧ 0.3% of dihexyl phthalate (CAS No.: 68515-51-5; 68648-93-1)
0,05 n.d.
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 8 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
No. Substance Name RL (%)
Concentration (%)
163. 5-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane [1], 5-sec-butyl-2-(4,6-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane [2] [covering any of the individual isomers of [1] and [2] or any combination thereof]
170. 4,4'- isopropylidenediphenol (Bisphenol A) (CAS No.: 80-05-7) 0,05 n.d.
171. 4-Heptylphenol, branched and linear (4-HPbl) [substances with a linear and/or branched alkyl chain with a carbon number of 7 covalently bound predominantly in position 4 to phenol, covering also UVCB- and well-defined substances which include any of the individual isomers or a combination thereof]
0,05 n.d.
172. Nonadecafluorodecanoic acid (PFDA) and its sodium and ammonium salts (CAS No.: 3108-42-7, 335-76-2, 3830-45-3)
174. Perfluorohexane-1-sulphonic acid and its salts (PFHxS) (CAS No.: 355-46-4)
0,05 n.d.
175. 1,6,7,8,9,14,15,16,17, 17,18,18- Dodecachloropentacyclo [12.2.1.16,9.02,13.05,10]octadeca-7,15-diene (“Dechlorane Plus”TM) [covering any of its individual anti- and syn-isomers or any combination thereof]
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 9 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
198. 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propionic acid, its salts and its acyl halides (covering any of their individual isomers and combinations thereof)
205. Perfluorobutane sulfonic acid (PFBS) and its salts 0,05 n.d.
Remark :
1. Candidate List of SVHC (2020/01/16) http://echa.europa.eu/web/guest/candidate-list-table
2. In accordance with Regulation (EC) No 1907/2006, any producer or importer of articles shall notify ECHA, in accordance with paragraph 2 of Article 7, if a substance meets the criteria in Article 57 and is identified in accordance with Article 59(1) of the Regulation, if (a) the substance is present in those articles in quantities totaling over one tonne per producer or importer per year; and (b) the substance is present in those articles above a concentration of 0.1% weight by weight (w/w).
3. Article 33 of Regulation (EC) No 1907/2006 requires supplier of an article containing a substance meeting the criteria in Article 57 and identified in accordance with Article 59(1) in a concentration above 0.1% weight by weight (w/w) shall provide the recipient of the article with sufficient information, available to the supplier, to allow safe use of the article including, as a minimum, the name of that substance.
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 10 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
4. If a SVHC is found over 0.1% (w/w) and/or the specific concentration limit which is set in Regulation (EC) No 1272/2008 and its amendments, client is suggested to prepare a Safety Data Sheet (SDS) against the SVHC to comply with the supply chain communication obligation under Regulation (EC) No 1907/2006, in which:
(I) a substance that is classified as hazardous under the CLP Regulation (EC) No 1272/2008. (II) mixture that is classified as hazardous under the CLP Regulation (EC) No 1272/2008, when it contains a substance with concentration equal to, or greater than the classification limit as set in Regulation (EC) No. 1272/2008; or (III) a mixture is not classified as hazardous under the CLP Regulation (EC) No 1272/2008, but contains either:
(a) a substance posing human health or environmental hazards in an individual concentration of ≥ 1 % by
weight for mixtures that are solid or liquids (i.e., non-gaseous mixtures) or ≥ 0.2 % by volume for gaseous
mixtures; or
(b) a substance that is PBT, or vPvB in an individual concentration of ≥ 0.1 % by weight for mixtures that
are solid or liquids (i.e., non-gaseous mixtures); or (c) a substance on the SVHC candidate list (for reasons other than those listed above), in an individual
concentration of ≥ 0.1 % by weight for non-gaseous mixtures; or
(d) a substance for which there are Europe-wide workplace exposure limits
5. If a SVHC is found over the reporting limit, client is suggested to identify the component which contains the SVHC and the exact concentration of the SVHC by requesting further quantitative analysis from the laboratory.
Note：：：：
1. mg/kg = ppm; 0.1wt% = 1000ppm
2. RL = Reporting Limit
3. n.d.= not detected = below Reporting Limit
4. F Parameter Conversion Table： http://twap.sgs.com/sgsrsts/chn/download-REACH_tw.asp
6. (*): conc. of Sodium dichromate dihydrate (CAS No.: 7789-12-0) = conc. of sodium dichromate x 1.1375
7. (**): The concentrations of above-mentioned mixtures are evaluated per the gained composition rate between the selected marks and the mixtures.
8. " - " = Not Regulated
9. (＊1): Oligomers of chromic acid and dichromic acid : since the oligomers are made of the unknown amount
of chromic acid or dichromic acid that results in no fixed molecular weight, therefore the monomer of chromic acid or dichromic acid is relevant and considered.
10. (＊2): Tetraboron disodium heptaoxide, hydrate: Only anhydrous form of disodium tetraborate is relevant and
considered according to ECHA explanation (Ref no.: INC 000000032519).
11. ***: The substance was calculated by the test results of MonooctylTin, Dioctyl Tin, Tributyl Tin, Dibutyl Tin, PFOA or element (Ex. Arsenic, Lead, Cr(VI), Boron, Cobalt, Barium, Cadmium respectively).
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 11 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
The test result is given as:
Substance Name RL (%)
Concentration (%)
Tributyl Tin (TBT) 0,05 n.d.
Arsenic (As) (※2) 0,005 n.d.
Lead (Pb) 0,005 n.d.
Hexavalent Chromium Cr(VI) 0,005 n.d.
Boron (B) (※2) 0,005 n.d.
Cobalt (Co) 0,005 n.d.
Dibutyl Tin (DBT) 0,05 n.d.
Barium (Ba) 0,005 0.0120
Dioctyl Tin (DOT) 0,0231 n.d.
MonooctylTin (MOT) 0.0140 n.d.
Cadmium (Cd) 0,005 n.d.
12. (※1): Regarding the compound containing arsenic and lead, lead and arsenic are tested and respectively
used for the calculation of the independent concentration of the compound containing arsenic and lead. The minimum value of the two independently calculated concentrations is used as the final concentration for the report.
13. (※2): The extracted soluble Boron / Arsenic are detected by ICP-OES.
14. (※3): TGIC is a mixture and also contains β-TGIC. According to the ECHA's technical dossier the ratio of β-
TGIC to TGIC is around 1 to 10. Therefore β-TGIC is issued based on the above-mentioned ratio.
15. (※4): Only if both qualitative results of lead and silicon are positive, the test result of the compound will be
calculated based on the concentration of barium.
16. (※5): Regarding the compound containing Cr(VI) and lead, lead and Cr(VI) are tested and respectively used
for the calculation of the independent concentration of the compound containing Cr(VI) and lead. The minimum value of the two independently calculated concentrations is used as the final concentration for the report.
17. (※7): RP-HP can't be identified directly and test result can't be calculated based on specific element(s) or
compound. RP-HP is identified as SVHC because of 4-HPbl, therefore 4-HPbl is analysed instead of RP-HP.
18. (●) : Since lead has a wide application, it is unlikely to determine if the detected lead comes from the lead ion, lead element or/ and lead compounds. Therefore the detected total lead is used on behalf of lead.
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 12 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
Analytical flow chart of SVHC
Sampling
Sample pretreated by acid digestion, solvent extraction
Analysis was performed by ICP-AES, UV-VIS, GC/MS, LC/MS, GC/FPD,
LC/MS/DAD, UPLC-MSMS
Data
Test Report No. 5303972-30 Date: 20/MAR/2020 Page 13 of 13 mtm plastics GmbH Bahnhofstr. 106 99759 Niedergebra GERMANY
SGS Institut Fresenius GmbH, Im Maisel 14, D-65232 Taunusstein
Member of the SGS Group (Societé Générale de Surveillance) The test results refer exclusively to the examined test items and the date of the test under the test specifications.
Sample photo:
***End of Report**
The test results refer exclusively to the examined test items and the date of the test under the test specifications. Written acknowledgement for publication and duplication of our analytical reports for promotional purpose, as well as fractional use for other purposes are mandatory. Numbers following „<“ represent limits of quantification. Determination of parameters marked with * was performed with a cooperation partner. This document is issued by the Company subject to its General Conditions of Service (www.sgsgroup.de/agb). Attention is drawn to the limitations of liability, indemnification and jurisdictional issues established therein. Any holder of this document is advised that information contained hereon reflects the Company's findings at the time of its intervention only and within the limits of client's instructions, if any. The Company's sole responsibility is to its client and this document does not exonerate parties to a transaction from exercising all their rights and under the transaction documents. Any unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law. Note: The sample(s) to which the findings recorded herein (the "findings ") relate was (were) probably drawn and / or provided by the client or by a third party acting at the client's direction. In this case the findings constitute no warranty of the sample's representativeness of any goods and strictly relate to the sample(s). The company accepts no liability with regard to the origin or source from which the sample(s) is/are said to be extracted. We would like to point out that measurement uncertainties are not taken into account for conclusions. On request, we can provide measurement uncertainties and take them into account for conclusions upon consultation.
