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Biotechnology (Enterprise)
Dr Geoff Robson
Word count: 2616
The History and Development of Bioethanol as an
Alternative Fuel
Introduction
Bioethanol is ethanol that has been produced from or by a biological
source. The clearest way of demonstrating this production is in
fermentation of sugars in the brewing industry. In this process glucose,
along with water, is converted into ethanol, carbon dioxide and water.
It’s use as a fuel is realised by the exothermic reaction when burnt,
producing CO2 and water.
Bioethanol is used as a fuel because it is non-petroleum based, thereby
reducing our dependence on crude oil resources, and is thought to be
carbon neutral[1], thus reducing net carbon emissions that are thought to
contribute to climate change. The basis for the thought of a reduced
carbon footprint by using bioethanol as a fuel is that the biomass –
typically sugarcane or corn – used for conversion into ethanol has already
absorbed more CO2 whilst growing than is released from the production
and burning of ethanol [2]. The chemical reactions of sugar into ethanol
and burning of ethanol, respectively, are described below:
C6H12O6 + H2O 2C2H5OH + 2CO2 +H2O
C2H5OH + 3O2 2CO2 +3H2O
This usage and production of CO2 has been argued to be more beneficial
in prevention of climate change than regular petroleum fuels as the
carbon utilised and produced is part of the ‘free carbon cycle’ whereas
petroleum from crude oil is released from a ‘locked carbon cycle’ into the
free carbon cycle. The free carbon cycle involves conversion of carbon
into living organic matter by plants and animals, and it’s release back into
the atmosphere. The extra carbon released by burning fossil fuels that
have been ‘trapped’ for so long upsets this cycle. Developing fuels that
reduce the need for petroleum substances or burn with less CO2
production is seen as a major step in battling ongoing climate change.
The EU recently passed a bill whereby car manufacturers will have to
reduce the carbon emissions of their cars to 120g/km by 2012[3]. With
policy increasingly considering the effects that climate change may have,
alternative fuels are set to grow in importance and use, with more
research into increasing efficiency of production and running of these
fuels.
As well as bioethanol, industry is researching into other alternative fuels
such as biodiesel, hydrogen power, electricity, natural gas, propane,
methanol and p-series fuels[4]. These fuels all have potential as an
alternative fuel, with biodiesel and natural gas currently being used the
most, along with bioethanol. Hydrogen looks to be the fuel of the future,
eventually replacing biofuels as the main consumer fuel, but depends on
overcoming some serious technological limitations.
Current Use of Bioethanol
When examining the current use of biofuels, the obvious starting point is
to look at Brazil. Brazil has successfully been industrially producing
bioethanol since the 1970’s, when it heavily relied on foreign oil. The
Middle Eastern Oil Embargo forced Brazil to look at more sustainable
means of fuelling the nation[5]. Although it has not always been
problem-free, the Brazilian program is seen as a model success story for
sustainable development. Today all cars in Brazil run on at least 25%
ethanol mixed with petrol, with 60% of all automobiles being ‘fuel-
flexible’ (able to run on up to 100% ethanol).
Brazil produces its bioethanol almost exclusively from sugarcane. In this
model, 1 ton of sugarcane harvest yields only 72 litres of ethanol. This
ethanol may have to be refined further for blended use, or can be used as
is in a pure ethanol fuel. It is obvious from these figures that there is a lot
of waste in the conversion of biomass into ethanol. Most of this waste is
from lignin and cellulose – cellulose is the most abundant biological
compound on the planet – which are not easily converted into sugars and
then fermented.
The USA is following
the lead set by Brazil,
investing heavily in its
own biofuel
production. The USA
currently serves all
petrol as a blend with
10% ethanol, with
moves to increase this proportion. Also all new vehicles sold in the USA
must have the flexible fuel engine type. The EU has also moved to
support renewable fuels for the future by legislation stating minimum
usage for member states.
As figure 1 shows, the global use of biomass for fuel is about 10%, with a
global bioethanol production of 36.5billion litres per year[6]. Due to the
high production costs of ‘modern biomass’ it is not as widely used as
‘traditional biomass’. If the traditional biomass is replaced with modern
biomass then bioethanol as a fuel will be in good stead to take off as a
Figure 1: Current global fuel usage. New renewables refers to sustainable production, whereas tradtitional biomass refers to labour and cost intesive commercial production. Picture from: Ethanol For A
Sustainable Energy Future, Goldemburg et al.
genuine consumer fuel. This is already seen in Sweden, where Ford
produces a flex-fuel model that outsells its petrol and diesel
equivalents[7].
Advantages of Bioethanol
As an alternative fuel, bioethanol is very attractive. The need for
alternative fuels comes from the depletion of easy to access reserves of
coal, gas and crude oil within the next 150 years, with our oil reserves
being depleted before the end of the century[8]. Because of this,
industrialised nation’s governments are offering tax incentives and grants
in the commercial development and application of renewable energy in
the form of biomass. In Brazil, the government subsidises ethanol
production in order to keep the cost per gallon in line with currently
cheap petroleum. The USA is heavily funding ethanol production as a
means to reduce its future reliance on Middle Eastern oil[9].
As a fuel for automobile use, bioethanol was historically the fuel of
choice, with the first internal combustion engine designed to run on
ethanol. Ethanol has been touted as an extremely beneficial fuel due to
its higher octane rating of 113 to that of petrol’s of between 83 and 95.
The higher the octane rating, the less likely it is that ‘knocking’ will occur
– pre-ignition of the fuel – which damages engines [10].
The main advantage of bioethanol over petroleum based fuels however,
are its renewability and its supposed carbon neutrality. As will be
discussed later, there is debate over whether bioethanol is currently
carbon neutral and how it might become so. From the renewable
perspective, it is hard not to agree. Bioethanol is produced from crops,
grown and harvested every year, using the sun’s energy as the major
source of energy. The argument for it’s carbon neutrality stems from,
during photosynthesis plants absorb CO2, and the supposed amount of
CO2 produced from burning the ethanol is less than that absorbed during
growth [11]. The counter-argument states that more energy and fuel is
Figure 2: The net energy balance (NEB) of biofuels, showing a higher output than input. Source: Environmental, economic, and energetic costs and benefits of
biodiesel and ethanol biofuels,Hill et al.
used in production than is produced [12]. Hill et al find that bioethanol
has a net energy balance of 1.25 (25% higher output than input), whilst
biodiesel has an energy balance of 1.93 – see figure 2. However, they
also note that phosphorous and nitrogen used in production have negative
environmental impacts. To improve the overall benefits of they suggest
low inputs of agricultural energy, fertiliser and pesticides. These studies
focus only on corn grain and soybean however. Over a 10 year period
Hill et al [13] discovered that low-input grass (in the form of agricultural
techniques such as fertilising) can potentially reduce by 15% the global
carbon emissions if utilised as the main biofuel crop, whilst not
competing for land used for food crops.
Another advantage of bioethanol is the independence that it offers
nations. Nations that do not have access to crude oil reserves are entirely
dependent on importing their oil. If these same nations can produce crops
for energy uses then they will gain some economic independence. As
mentioned earlier, the USA is already investing in its own biofuel
programs as a means to reduce any future dependence on foreign oil.
There is an argument against the use of crops for fuel as their farming
will displace the land used for food farming[14], however many areas
currently unused for farming – either through infertility or geographically
unutilised for food farming – could be used for the production of
dedicated fuel crops. It may seem count-intuitive that infertile ground
could be used for harvesting, however switchgrass is a very robust crop
that can grow in unfertilised ground[13] and would not require intensive
farming techniques yet still producing high bioethanol yields.
Disadvantages of Bioethanol
As alluded to earlier, there is still a debate raging as to the extent of the
carbon footprint of bioethanol[12, 13]. Much of this is down to the extent
to which researchers account for labour, but also due to which source of
sugar the researchers are using. On studies focused on the USA, corn is
the major source or sugars, whereas in Brazil sugarcane is the major
source. Sugarcane has a higher energy ratio than corn. As such there is
an obvious need for further funding to both study the net energy balances
and also work towards more efficient conversion techniques. Along with
different crops having differing energy contents, not all crops can be
grown in all regions. The local geography and climate will dictate which
crops can be grown and so production may well rely on importing crops
or sugar.
As well as geography determining which crops could be grown and
harvested for fuel use, so too the land use for dedicated fuel farming. A
5% displacement of petrol with bioethanol would require a 5%
displacement of food crops in the EU[15]. In many developed nations
this does not amount to a crisis, as they are net food exporters in certain
products. However, the techniques could not then be transferred to
developing nations with large numbers of people living below the poverty
line. There is a large argument against the use of biofuels in China,
where irrigation of fields is paramount, because of this argument[14].
Bioethanol is a less efficient fuel than petroleum, having an energy
content of about 70% of that of petrol [16]. As such, when used as a fuel,
more is needed to achieve the same results as petrol. This is a problem
that cannot be changed. As consumers, the debate will be whether it is
worth switching to less efficient fuels, meaning that more fuel and
ultimately more money will be required to be spent on fuel. For public
forms of transport this might mean higher costs of travel, lowering
support for alternative fuel initiatives. Currently all new cars sold in the
USA are flexible fuel vehicles, meaning that they can run on an ethanol-
petrol blend of up to 85% ethanol. However, many older cars are not able
to run on high concentrations of ethanol and so a phasing in of ethanol
blends would be required and many classic cars would require
conversions. This would incur large costs in advertising the change of
petrol blend to ensure that everybody had sufficient time to change, with
no doubt many protesters.
These increased running costs are also seen in increased production costs
to those of petrol. This is seen in the labour-intensiveness of producing
bioethanol[8]. Again this is a factor that would increase the price of
ethanol fuel. Currently it is economically viable to produce bioethanol
due to tax breaks and government grants. However, this cannot continue
forever and will likely sway the other way with higher taxation once
bioethanol is used widely as a fuel. The most effective ways in reducing
this cost would be to utilise economies of scale, coupled with
technological innovation.
Future Developments
Bioethanol needs to become more efficient at converting biomass to fuel
if it is to become sustainable to replace petrol with. This will involve
reducing costs of conversion, increasing yields and potentially increasing
the diversity of crops used. The way in which research is currently going
for the improvements of bioethanol is by looking at ways to convert
cellulose and lignin to sugars for fermentation. An exciting prospect is
simultaneous saccharification and fermentation (SSF) as described by
Takagi et el. [17]. However this has some problems, notably with the
different optimum temperatures of saccharification and fermentation[18].
Current methods can obtain conversion of between 50 and 72% ethanol
per gram of glucose, limited by the tolerance of the yeast to the
ethanol[19]. This suggests that with engineering of yeast strains for high
tolerance even more efficiency can be achieved. In this respect
biotechnology and microbiology will be extremely useful in the genetic
engineering, not just of yeasts, but of other microbes that can hopefully
one day convert cellulose and lignin into sugars and then ferment them
into ethanol.
Increasing the efficiency will no doubt create a more sustainable fuel
technology. However, to replace petrol as a fuel major tracts of land
must be used solely for the purpose of fuel crops. As discussed earlier
this has lead to opposition of the technology in many countries. Another
possibility would be for the consumers to take control of their own fuel
supply. This would involve commercial production of small-scale
fermenters and distillers for home use. By recycling all of their
household waste and converting much of it to biofuels, the energy
demand would greatly diminish.
As our technology grows, so other alternative fuels will come to the fore.
There is a lot of research into photovoltaic (PV) energy and also
hydrogen energy is seen as a fuel for the long-term future. Figure 3
shows the predicted increase in the importance and use of hydrogen as the
prime alternative fuel. Although there is currently not a cheap way of
producing hydrogen, there is a lot of research being done in the area[20].
Of course there are many
other alternative energy
sources, such as nuclear, wind
and geothermal. It would
seem like an obvious move
for a nations geography to
play a large factor in which
alternative fuels they utilise[21]. For example Australia would be able to
take advantage of PVs more than the UK. Greenland and Iceland could
use geothermal power as an alternative source of energy. As a
replacement for petrol rather than a displacement of reliance on petrol, we
cannot rely on just one energy source for the near future.
Figure 3: Predicted use of alternative fuels until 2050. Percent of alternative fuel consumption on the ordinate axis against years. Source: Glycerol delignification of poplar wood chips in aqueous medium, Adeeb 2004 [24]
Conclusion
Bioethanol is very much a fuel of the future. It currently stands as the
leader of the pack in alternative fuels alongside bio-diesel. As a
substitute for petrol it is the obvious choice in it’s blending ability with
petrol, from which it can easily become the fuel of choice. There is a
largely positive public opinion about bioethanol[22], with California,
USA leading the way in adoption of it as an alternative fuel[23]. With
such public and government opinion, in the foreseeable future bioethanol
will be a globally used fuel with a wide user base.
There is much research ongoing into bioethanol, improving our
technology and understanding year on year. This can only enhance the
standing of bioethanol as a viable and cheap alternative fuel. With the
development now of lignocellulosic bioethanol, the efficiency of this fuel
looks set to continue to improve. Environmentally, regardless of the
current state of opinion, the carbon footprint of bioethanol will
undoubtedly decrease, helping reduce global carbon emissions. It would
not take too much to persuade the public to domesticate their own
bioethanol production, if such a project was economically and technically
feasible.
As figure 3 shows, it is projected that hydrogen will be the fuel of choice
for our long-term future. This gives bioethanol a short-term life as a
major fuel. However, it will be many years before hydrogen fuel is safe
and economic enough for its mass use. Until that time there will be a
high demand for bioethanol as an alternative fuel. Even then, hydrogen
may not be the fuel of choice for all applications, with bioethanol still
taking a role in powering our society.
References