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© 2019 Electric Power Research Institute, Inc. All rights reserved. www.epri.com Scott Hume Principal Technical Leader 30 th July 2019 ARPA-e Flexible Carbon Capture Technologies for a Renewable-Heavy Grid Thermal Energy Storage Cost-effective avoidance of plant cycling to enable economic carbon capture
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Page 1: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m

Scott HumePrincipal Technical Leader

30th July 2019

ARPA-e Flexible Carbon Capture Technologies for a Renewable-Heavy Grid

Thermal Energy Storage Cost-effective avoidance of plant cycling to

enable economic carbon capture

Page 2: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m2

Today’s Fossil Plants Are Being Run Flexibly

▪ Intermittent renewables are driving fossil plants to provide grid support– Damage from startup, shutdown, and cycling operations can occur

– Shorter lifetimes, higher emissions per kWh, and lower profitability

– More difficult for carbon capture operations

▪ If substantial energy can be stored:– Plants can operate during low/negative pricing periods without exporting power

– Electro-chemical battery technology can be used; however, the cost of storage can be prohibitive at $1300–2100/kW for a 4-hour system*

– Due to the high cost relative to incremental value, battery technology is more challenging for longer durations (e.g., 10+ hour storage)

Non-battery bulk energy storage may deliver lower-cost options

*Energy Storage Technology and Cost Assessment. EPRI, Palo Alto, CA: 2018. 3002013957

Page 3: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m3

UPS Grid Support Energy Management

Power Quality Load Shifting Bulk Power Mgmt.Bridging Power

Dis

ch

arg

e T

ime

at R

ate

d P

ow

er

Se

co

nd

sM

inu

tes

Ho

urs

System Power Ratings

1 kW 10 kW 100 kW 1 MW 10 MW 100 MW 1 GW

High Energy Super

Caps

Lithium Ion Battery

Lead Acid Battery

NiCd

NiMH

High Power Flywheels

High Power Super Caps SMES

NaS Battery .

NaNiCl2 Battery

Advanced Lead Acid BatteryCAES / LAES

Pumped Hydro

Flow Batteries

ZrBr VRB Novel Systems

Metal-Air Batteries

Lithium Ion Battery

Tesla’s South

Australia

Battery

($432/kWh)

Non-Battery

Battery

Energy Storage Options – Power vs. Discharge Duration

Page 4: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m4

UPS Grid Support Energy Management

Power Quality Load Shifting Bulk Power Mgmt.Bridging Power

Dis

ch

arg

e T

ime

at R

ate

d P

ow

er

Se

co

nd

sM

inu

tes

Ho

urs

System Power Ratings

1 kW 10 kW 100 kW 1 MW 10 MW 100 MW 1 GW

High Energy Super

Caps

Lithium Ion Battery

Lead Acid Battery

NiCd

NiMH

High Power Flywheels

High Power Super Caps SMES

NaS Battery .

NaNiCl2 Battery

Advanced Lead Acid BatteryCAES / LAES

Pumped Hydro

Flow Batteries

ZrBr VRB Novel Systems

Metal-Air Batteries

Lithium Ion Battery

Tesla’s South

Australia

Battery

($432/kWh)

Bad Creek

Pumped

Hydroelectric

StorageNon-Battery

Battery

320x larger

Can a different type of bulk energy storage be cheaper than a battery?

Energy Storage Options – Power vs. Discharge Duration

Page 5: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m5

UPS Grid Support Energy Management

Power Quality Load Shifting Bulk Power Mgmt.Bridging Power

Dis

ch

arg

e T

ime

at R

ate

d P

ow

er

Se

co

nd

sM

inu

tes

Ho

urs

System Power Ratings

1 kW 10 kW 100 kW 1 MW 10 MW 100 MW 1 GW

High Energy Super

Caps

Lithium Ion Battery

Lead Acid Battery

NiCd

NiMH

High Power Flywheels

High Power Super Caps SMES

NaS Battery .

NaNiCl2 Battery

Advanced Lead Acid BatteryCAES / LAES

Pumped Hydro

Flow Batteries

ZrBr VRB Novel Systems

Metal-Air Batteries

Lithium Ion Battery

Tesla’s South

Australia

Battery

($432/kWh)

Bad Creek

Pumped

Hydroelectric

StorageNon-Battery

Battery

320x larger

Thermal

Energy

Storage (TES)

Can a different type of bulk energy storage be cheaper than a battery?

Energy Storage Options – Power vs. Discharge Duration

Page 6: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m6

How Can TES Be Deployed?

▪ Consider a power facility with three units (of varying vintage) operating at low capacity factor and two of which are scheduled to be retired

▪ Renewable intermittency results in:

– Boilers incur frequent starts and stops

– Rapid ramping requirements

– Overall low capacity factors

– Higher O&M costs

– Increased emissions per MWh exported

CF=25%

CF=25%

CF=25%

Low or

negative price,

zero output

High price,

full output

Page 7: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m7

How Can TES Be Deployed?

▪ Consider a power facility with three units (of varying vintage) operating at low capacity factor and two of which are scheduled to be retired

▪ Renewable intermittency results in:

– Boilers incur frequent starts and stops

– Rapid ramping requirements

– Overall low capacity factors

– Higher O&M costs

– Increased emissions per MWh exported

▪By providing steam to TES during periods of low grid prices, the unit remains operational, avoiding shutdown and restart

CF=25%

CF=25%CF=75%

TES

Low or

negative price,

zero output

Page 8: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m8

How Can TES Be Deployed?

▪ Consider a power facility with three units (of varying vintage) operating at low capacity factor and two of which are scheduled to be retired

▪ Renewable intermittency results in:

– Boilers incur frequent starts and stops

– Rapid ramping requirements

– Overall low capacity factors

– Higher O&M costs

– Increased emissions per MWh exported

▪By providing steam to TES during periods of low grid prices, the unit remains operational, avoiding shutdown and restart

▪When energy prices increase, steam from the boiler can be diverted to the unit steam turbine AND the TES units can provide steam to the turbine-generators of the units with retired boilers

▪All three units generate power when needed

CF=25%

CF=25%CF=75%

TES

Low or

negative price,

zero output

High price,

full output

Page 9: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m9

Further Application of TES

Industrial heating loadGas unit with CCS

Solar PV, wind

Steam

Thermal Energy

Storage

constant

inte

rmitte

nt

Concentrated

solar

Coal unit with CCS

Ele

ctric

ityh

ea

t

Steam/ sCO2

cycle

Grid services

Nuclear unit

EOR or

Storage

constant

CO2

CO2

24/7

demand

Page 10: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m10

TES Materials

▪ Low-cost materials critical for long duration▪ Three categories:

▪ Applications:– Adiabatic compressed air, liquid air (compression heat, cold)– Direct thermal (store heat from power plant, dispatch when needed)– Pumped heat energy storage (AC-AC storage, better round trip efficiency)– Resistive heating (low-cost AC-AC storage, limited round-trip efficiency)

Sensible Heat Latent Heat Heat of Reaction

Ceramics, concrete, glycol, molten nitrate and fluoride salts, oil, rocks, sand, and water

Aluminum and magnesium alloys, elemental silicon, hydrocarbon waxes, steam accumulators, sulfur, and water/ice

Carbonate CaO, MgO, and CO2,

hydration/dehydration, metal oxides/hydroxide, and thermochemical endothermic and exothermic reactions

Page 11: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m11

Concrete TES

▪ Solid ‘thermocline’ structure used to store thermal energy

▪ Low-cost material $68/tonne

▪ Modular system (41 ft [12.5 m])

▪ Road/rail transportable

Images courtesy of Bright Energy Storage Technologies

▪ Steam tubes embedded into concrete monoliths as coils – conductive heat transfer only

▪ No moving parts

▪ Pilot planned under FOA-1989

3-block, flue gas-heated testing modules

Tube internal arrangement 10 MWh-e scale pilot plant

Page 12: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m12

Initial Conclusions from EPRI’s Analysis

▪ TES effective round-trip efficiency can be high as the thermal energy was never converted to power before discharge

▪ Capital cost is on the order of $100/kWh, i.e., 3 to 4 times less than Li-ion batteries today

▪ TES systems do not degrade with cycling – longer plant life

▪ TES can enable use of fossil plants with CO2 capture installed at 100% production with 24/7 operation regardless of grid price

Additional research needed to validate technology and costs

Page 13: Thermal Energy Storage · –Direct thermal (store heat from power plant, dispatch when needed) –Pumped heat energy storage (AC-AC storage, better round trip efficiency) –Resistive

© 2019 Electric Power Research Institute, Inc. All rights reserved.w w w . e p r i . c o m13

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