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Thermodynamic Cycles
Objective•Classification of Thermodynamics Cycles•Analysis & Calculation of Thermodynamic Cycles Carnot Vapor Cycle, Rankie Cycle, Regeneration Ran
kie Cycle,Reheat Rankie Cycle
• Cogeneration• Gas Refrigeration Cycle• Vapor-Compression Refrigeration Cycle• Refrigerant• Other Refrigeration Cycles
Classification of Thermodynamics Cycles
Heat Energy Mechanical EnergyPower Cycle (+)
Heat Pump Cycle (- )
Refrigeration Cycle: keep low temperature of heat source with low temperature
Heat Pump Cycle: keep high temperature of heat source with high temperature
Working FluidGas Cycle: no phase-change of working fluid during cycle
Vapor Cycle: phase-change of working fluid during cycle
Combustion form Inner Combustion Outer Combustion
Combustion occurs in system Combustion occurs out of system
Gas is also the working fluid.The heat is transferred to working fluid through heat exchanger.
Carnot Vapor Cycle
Several impracticalities are associated with this cycle:
1. It is impractical to design a compressor that will handle two phases for
isentropic compression process(4-1).
2. The quality of steam decrease during isentropic expansion process(2-3)
which do harm to turbine blades.
3. The critical point limits the maximum temperature used in the cycle
which also limits the thermal efficiency.
4. The specific volume of steam is much higher than that of water which
means large amount of work and equipments input.
Carnot Vapor Cycle
Rankine Vapor Cycle
4-6 Constant pressure heat addition in a boiler
6-1 to Superheated Vapor
1-2 Isentropic expansion in a turbine
2-3 Constant pressure heat rejection in a condenser
3-4 Isentropic compression in a pump
S
4
6
1
2
3
Rankine Vapor Cycle
S
4
6
1
2
3
T
s
1
6
5
4
3 2
p
v
1654
32
p1
p2
Thermal Efficiency of Rankine Vapor Cycle
4-5-6-1 Constant pressure heat addition in a boiler
1 1 4q h h
1-2 Isentropic expansion in a turbine
tT 1 2w h h
2-3 Constant pressure heat rejection in a condenser
2 2 3q h h
3-4 Isentropic compression in a pump
tP 4 3w h h
Thermal Efficiency of Rankine Vapor Cycle
1.Hard compressibility of water
2. tP tTw w
( )tP 4 3
4 3
w v p p
h h
o tT tP 1 2 1 2 s
o 1 2t
1 1 3
w w w q q h h w
w h h
q h h
Ek,Ep=0
Thermal Efficiency of Rankine Vapor Cycle
1 21 2
1 2
2t
1
Q QT T
S S
T1
T
Definition:
o 1 2
3600 3600d
w h h
d( 汽耗率 ) — the heat rate required to generate work of
kW h1 td
Increase Efficiency of Rankine Vapor Cycle
o 1 2t
1 1 3
w h h
q h h
Entralpy of steam, turbine inlet
Entralpy of exhaust air , turbine outlet
Entralpy of condensed water
1
2
3
h
h
h
,1 1p t
2p
1. - Pressure of Steam, Turbine Inlet
Increase Efficiency of Rankine Vapor Cycle
1p
3
4
5
5’
1’ 1
22’
,1 2t p - Unchange
1p '1p
Two Cycles:
① 3-4-5-1-2-3
② 3-4-5’-1’-2’-3
3
4
5
5’
1’ 1
22’
'1 1
1 t
T T
p
Disadvantages:
1p 1. x
Increase Efficiency of Rankine Vapor Cycle
The presence of large quantities of moisture is highly desirable because itdecrease the turbine efficiency anderodes the turbine blades.
2. 1p Increase of requirements on pressurevessels and equipment investment.
Increase Efficiency of Rankine Vapor Cycle
2. - Temperature of Steam, Turbine Inlet1t
3
4
5
11’
2’2
6
,1 2t p - Unchange
1p '1p
Two Cycles:
① 3-4-5-6-1-2-3
② 3-4-5-6-1’-2’-3
Increase Efficiency of Rankine Vapor Cycle
3
4
51
1’
2’2
6
Advantages:
' ,1 1 1 2
1 t
T T p p
t
i
ii Superheating the steam to higher temperature is desirable becauseit decreases the moisture contentof the steam at the turbine exit.
Disadvantages:
Superheating temperature is limitedby metallurgical considerations.
1t 600 ℃
Increase Efficiency of Rankine Vapor Cycle
3. - Condenser Pressure, Turbine Exit2p
,1 1t p - Unchange
2p '2p
Two Cycles:
① 1-2-3-4-5-6-1
② 1-2’-3’-4’-5-6-13
4
5
1
3’ 2’
2
6
4’
Increase Efficiency of Rankine Vapor Cycle
3
4
5
1
3’ 2’
2
6
4’
,'2 2 1 2
2 t
p p t t
p
i
iiDisadvantages:
i Condense pressure is limited
by saturation pressure
corresponding to the
temperature.
ii It increases the moisture
content which is highly
undesirable.
Increase Efficiency of Rankine Vapor Cycle
Example
Consider a steam power plant operating on the ideal Rankine cycle.
The steam enters the turbine at 2.5MPa and 350 and is condensed℃in the condenser at pressure of 70kPa. Determine
(a)The thermal efficiency of this power plant
(b)The thermal efficiency if steam is condensed at pressure of 10kPa
(c) The thermal efficiency if steam is superheated to 600 ℃(d)The thermal efficiency if the boiler pressure is raised to 15MPa
while the turbine inlet temperature is maintain at 600 ℃
70kPa
2.5MPa
1
2
3
4
1
1
31
70 , Saturate Liquid
376.77kJ/kg
0.00104m /kg
p kPa
h
v
State 1:
2 2 1
, 1 2 1
2 1 ,
2.5 ,
( ) 2.53kJ/kg
376.77 2.53
=381.83kJ/kg
pump in
pump in
p MPa s s
w v p p
h h w
State 2:
1 2h h
State 3:
3 2
3
3
2.5MPa, 350
3128.2 kJ/kg
6.8442 kJ/kg K
p t
h
s
℃
Ideal Rankine Cycle
70kPa
2.5MPa
1
2
3
4
State 4:
3 4 3
4
70 Pa,
' ( '' ')
'
'' '6.8442 1.1921
0.89887.4804 1.1921
' ''
376.77 0.8988 2660.1 2767.7kJ/kg
x
x
p k s s
s s x s s
s sx
s s
h h xh
3 2
4 1
3128.2 381.83 2746.37
2767.7 376.77 2390.93
in
out
q h h
q h h
1 12.9% outt
in
q
q
1
1
31
10 , Saturate Liquid
191.83kJ/kg
0.00101m /kg
p kPa
h
v
State 1:
2 2 1
, 1 2 1
2 1 ,
2.5 ,
( ) 3.02kJ/kg
191.83 3.02
=194.85kJ/kg
pump in
pump in
p MPa s s
w v p p
h h w
State 2:
1 2h h
State 3:
3 2
3
3
2.5MPa, 350
3128.2 kJ/kg
6.8442 kJ/kg K
p t
h
s
℃
(b)
Lowing thepressure ofCondenser
State 4:
3 4 3
4
10 Pa,
' ( '' ')
'
'' '6.8442 0.6493
0.82588.1511 0.6493
' ''
191.83 0.8258 2584.8 2326.4kJ/kg
x
x
p k s s
s s x s s
s sx
s s
h h xh
2.5MPa
3 2
4 1
3128.2 194.35 2933.85
2326.4 191.83 2134.57in
out
q h h
q h h
1 27.2%outt
in
q
q
Actual Rankine Vapor Cycle
Irreversibility
• Fluid friction• Heat transfer under temperature
difference• Heat loss to the surroundings
Actual Rankine Vapor Cycle
2’
3(4
)
2
1
56
1 2' 'tTw h h Turbine Efficiency
1 2
1 2
' '0.92tT
itT
w h h
w h h
Ideal Cycle
1 20 3600
h hDN
d
Actual Cycle
1 20
'
3600i i
h hDN N
d
Actual Rankine Vapor Cycle
Mechanical Efficiency
em
i
N
N Effective
Power 0
ee
N
N
Relative Effective Efficiency
Boiler Efficiency
Heat Absorbed in Boiler
Heat Rejected by FeulB
Equipment Efficiency
Output Net work
Heat Rejected by Feul
Ideal Regenerative Cycle
3(4)e
2
7
1
d
56
T
s
预热锅炉给水,使其温度升高后再进入锅炉,可提高水在锅炉内的平均吸热温度,减小水与高温热源的温差,对提高循环效率有利。利用汽轮机中的蒸汽预热锅炉给水,称为回热。Transfer heat to the feedwater from the
expanding steam in a heat exchanger built
into the turbine ,called Regeneration.
Regenerative Cycle: 1-7-d-3-4-5-6-1
General Carnot Cycle:3-4-5-7-d-3
Ideal Carnot Cycle: 5-7-2-e-5Same
Efficiency
Regenerative Rankine
Ideal Regenerative Cycle
Boiler Turbine
Regenerator
Condenser
Mixing Chamber
Pump II Pump I
1
27
34
56
ExtractingRegeneration
Ideal Regenerative Cycle
3(4) 2
7
1
6
5
1kg
akg
(1-a)kg
T
s
( ) ( )( )
( ) ( )( )
7 5 5 4
5 4
7 5
0 1 7 7 2 tp
1 1 5
0t
1
a h h 1 a h h
h ha
h h
w h h 1 a h h w
q h h
w
q
( ) ( )
2 3t Rankine
1 3 1 7
h h1
ah h h h
1 a
>0
Ideal Regenerative Cycle
Boiler Turbine
Regenerator
Cond-enser
Mixing Chamber
Pump II Pump I
1
27
34
56
8
93 2
7
1
6
5
T
s
4
89
Ideal Reheat Cycle
蒸汽经汽轮机绝热膨胀至某一中间压力时全部引出,进入锅炉中特设的再加热器中再加热。温度升高后再全部引入汽轮机绝热膨胀做功。称为再热循环。
3 c 2
a1
5
4
6 b
Ideal Reheat Cycle
bp intermediate pressure
( ) ( )
( ) ( )1 b a 2
t1 3 a b
h h h h
h h h h
Cogeneration
Definition
Cogeneration is the production of more than one
useful form of energy from the same energy source.• electric power• heat in low quality
背压式热电联供抽气式热电联供
Gas Refrigeration Cycle
Ideal Reversed Carnot Cycle
2 2 2c
0 1 2 1 2
q q T
w q q T T
T1 — Temperature of heat source with high temperature,
surrounding temperature
T2 — Temperature of heat source with low temperature,
cold source
q1 — Heat rejected to the surroundings
q2 — Heat absorbed from cold source
w0 — Work input
if is constant1
2 c 0
T
T w
Gas Refrigeration Cycle
Turbine
Compressor
Condenser
ColdSource
1
23
4
1-2 Isotropic Compress
2-3 Isotonic Heat Rejection to Surrounding
3-4 Isotropic Expansion
4-1 Isotonic Heat Absorption
Gas Refrigeration Cyclep
v
1
23
4
1
T
s
2
3
4
T1
T3
Cp— Constant, Ideal Gas
• Heat Absorbed from Cold Source
( )2 1 4 p 1 4q h h c T T
• Heat Rejected to the condenser
( )1 2 3 p 2 3q h h c T T
• Work of Turbine
• Work of Compressor
( )c 2 1 p 2 1w h h c T T
( )e 3 4 p 3 4w h h c T T
Gas Refrigeration Cycle( ) ( )
=( ) ( )
, Isotropic Process
, Isotonic Process
( ) ( )
( )
0 c e 1 2 p 2 3 p 1 4
1 42
0 2 3 1 4
k 1 k 13 32 2 k k
1 1 4 4
4 1k 1
3 4 2 1 2 k
1
1c
3 1
w w w q q c T T c T T
T Tq
w T T T T
1 2 3 4
2 3 4 1
p TT p
T p p T
T T 1
T T T T p1
p
T
T T
Gas Refrigeration Cycle
Vapor-Compression Refrigeration Cycle
• Shortcomings of Gas-Compression Refrigeration Cycle
1.small Refrigeration-Coefficient because heat absorption
and rejection are not isothermal process;
2.Lower refrigeration capability of refrigerant (gas)
• So…refrigerant is change to Vapor
The highest efficiency is that of Vapor Carnot Reverse Cycle
Impracticalities:
1.Large moisture content is highly
undesirable for compressor and turbine.
2.Work output is limited by liquid expansion
in the turbine.
2 2c
0 1 2
2
1 2
q q
w q q
T
T T
Vapor-Compression Refrigeration Cycle
• So…practical vapor-compression refrigeration cycle is:
1
23
4
1
2
34
56
Vapor-Compression Refrigeration Cycle
1
2
34
56
1-2 Isotropic compress to superheated vapor
2-3-4 Isotonic condensed to saturated liquid
4-5 Isentropic expansion in a turbine
4-6 Isotropic expansion through throttle to humidity vapor
5-1 Constant pressure heat absorption in a cool source to dry saturate vapor
Vapor-Compression Refrigeration Cycle
1
2
34
56
2 1 5
1 2 4
c 2 1
q h h
q h h
w h h
Throttle:
4 5h h1 42
c0 2 1
h hq
w h h
Work difference between Turbine and throttle
① fluid with low quality is difficult to be compressed.
② work loss is relatively small ③ easily adjust pressure of fluid
and temperature of cold source
Vapor-Compression Refrigeration Cycle
Regeneration — more realistic cycle
T
s
11’
2
34
4’
5’ 5
Superheated Vapor
Super-cooled Liquid
Advantages:
1.
2.
3.Superheated vapor is desirable
c ' '2 1 5q h h
Vapor-Compression Refrigeration Cycle
Compressor
Condenser
ColdSource
1’
24
4’
Regenerator
Throttle Valve
5’
1
Conditions:
' '
'1 1 4 4
4 1
h h h h
t t
Vapor-Compression Refrigeration Cycle
1
2 2’4
5
3
ln p
h
''
2m
1 5
V m 1
m
h h
q q v
N q w
Irreversibility 1-2’Isotropic Compress Efficiency
'
' '
'
2 1ad
2 1
2 1ad
ad
h h
h h
ww h h
制冷机的制冷能力是随工作条件不同而变化的,因此,给出制冷能力时,必须指明相应的工作条件。