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TOMSThe Ultimate Biofuel

and much more than that

TOMS=Triglycerides of Modified Structure

FROM NATURAL OILS AND FATS wemanufacture:

1. NOVEL BIOFUEL PRODUCT TOMS RSPO CEN 590 RENEWABLE DIESEL.2. LIMITLESS NUMBER OF TAILOR MADE NEW MOLECULES FOR THE OLEOCHEMICAL INDUSTRIES (TOMS2)

TOTALLY NEW CONCEPT: “TOMS” i.e. Triglycerides Of Modified Structure

TOTALLY NEW CONCEPT AND APPROACH TO ELIMINATE AN ENVIRONMENTAL PROBLEM AND TO INCREASE BIOFUEL YIELDS OUT OF TG’s BY AT LEAST 15 – 20 % WITHOUT GLYCEROL.

TRIGLYCERIDE >>>>>>>>>>>>>>>> MODIFIED TRIGLYCERIDEC16 – C24 GLY esters PARTLY SHORT CHAINED

ADVANTAGES AND FAVOURABLE PROPERTIES OF THE NEW TOMS1BIOFUEL AND PROCESS:

• EVERY ATOM OF BIOMASS TRIGLYCERIDES IS UTILIZED FOR FUEL PURPOSES• UNIVERSAL PROCESS FOR ALL KINDS OF OILS/ANIMAL FATS • 15 - 20 % EXTRA YIELD OF BIOFUEL FROM THE FEEDSTOCK• BY RETAINING THE GLYCERYL BACKBONE NO NEED TO HANDLE A

BYPRODUCTNO GLYCEROL STREAMS 30% LESS PLANT COST• “TOMS” CAN BE PRODUCED IN OLD BIODIESEL PLANTS, TOO (SOME

REVAMPING)• LOWER MANUFACTURING COSTS• 30% MORE OXYGEN CONTENT, BETTER COMBUSTION ! CLEAN BURN !

MINIMUM PARTICULATE MATTER !• BETTER COLD FLOW PROPERTIES, CAN BE DESIGNED FOR SPECIFIC USE.• WASTELESS, ECO-FRIENDLY PROCESS, NO WATER USED, NO SEWAGE• MORE STABLE PRODUCT• 100% RENEWABLE (“GREEN”) AS NO METHANOL USED IN CASE OF

BIOETHYL ACETATE USAGE• CAN BE BLENDED TO PETRODIESEL WITHIN EN590 LIMIT!!! 80%

• ALSO UTILISED AS TOMS CEN 590 100% AS COMPLETE DIESEL REPLACER.

TOMS vs FAME EQUIPMENT REQUIREMENTS

YELLOW: NOT NEEDED IN TOMS PRODUCTION = LESS CAPEX

Visual Difference: FAME + Glycerol vs. TOMS from the same volume of feedstock oila. FAMEb. Glycerolc. TOMS, no glycerol, but + 15 - 20 % extra fuel mass

7.01 7.00 6.70 6.45 6.23 5.985.56

7.126.42 6.75

6.185.51

4.985.61

0.00

2.00

4.00

6.00

8.00

992.2 1196.4 1292.9 1392.5 1593.8 1789.7 1894.7

Sp

ecif

ic N

Ox e

mis

sio

n

[g/k

Wh

]

Engine speed [1/min]

Comparison of the specific NOx emissions while engine full load

SpecificNOxemission -Diesel fuel

SpecificNOxemission -TBKBiodiesel

0.680

0.380

0.2300.190

0.1180.078 0.106

0.1100.085 0.070

0.042 0.027 0.015 0.0150.000

0.200

0.400

0.600

0.800

992.2 1196.4 1292.9 1392.5 1593.8 1789.7 1894.7

Sm

ok

e [

1/m

]

Engine speed [1/min]

Comparison of the smoke values while engine full load

Smokevalues -Diesel fuel

0.5020.523

0.5010.468

0.5130.488 0.480

0.459 0.4420.485

0.090 0.092 0.086 0.097 0.099 0.093 0.089 0.091 0.085 0.0880

0.1

0.2

0.3

0.4

0.5

0.6

1. 2. 3. 4. 5. 6. 7. 8. 9. 10.

Sm

oke [

1/m

]

Measure ordinal number

Comparison of the free peak smoke values

Free peaksmoke - Dieselfuel

Free peaksmoke - TBKBiodiesel

Better Emission Values than Petrodiesel

c

a

b

EXAMPLE

RBD PO Stearin stocks usually create bottleneck, as

these are not so applicable for FAME manufacture,

owing to the high gelling point of the resulting

conventional BD (19 - 20°C).

However, using our TOMS methodology, we produce

+ 15 - 20% extra biofuel from this feedstock, with

greatly improved cold properties.

Similarly, from refined palm oil feedstock one gets

Fame with 15°C gelling point, whereas TOMS is still a

liquid below 4°C. (Potential for up to -12 GP from

Palm Oil Feedstock)

UNTIL NOW WE SPOKE ABOUT TOMS1:TWO PHASE PRODUCTION AND APPLICABILITY OF TRIGLYCERIDES OF MODIFIED STRUCTURE („TOMS“)

Triglycerides Modified Triglycerides F A E E+

TOMS 1 BIOFUEL

separation

COMPONENT 1 C O M P O N E N T 2:

F A E E„LIGHT PLANT OILS“ WITH LOWERED MOLECULAR MASSES, PARTIALLY CONTAINING C2 SIDE CHAINS BESIDES ORIGINAL C16-C24 ACYL GROUPS ---

APPLICABLE AS HIGH VALUE ADDED PRODUCTS

TAILORED/DESIGNED - LOWERED CALORIE FATS (DIETARY

SUPPLEMENTS)- NOVEL MONOMERS FOR NOVEL BIOPOLYMERS- NOVEL DEGRADABLE

BIOLUBRICANTS/HYDRAULIC FLUIDS

TOMS 2

=

2. TOMS FOR NON-FUEL PURPOSES:

SINCE WE CHANGE IN THE TOMS PROCESS THE CHEMICAL STRUCTURES OF TRIGLYCERIDES, WE ATTAIN NEW MATERIALS WITH HIGHLY FLEXIBLE MACRO PROPERTIES.

WE CAN MAKE HUNDREDS OF “NEW OILS” WHICH NOT AVAILABLE IN NATURE!

HUNDREDS OF “NOVEL BUILDING“ BLOCKS CREATED FOR VARIOUS USES TO REPLACE “PARENT OILS”

“TAILORED” (DESIGNED) TG’S WE CAN PRODUCE MEANT/FIT FOR A GIVEN PURPOSE

NEW AND NOVEL END PRODUCTS WITH NEW AND NOVEL MATERIAL PROPERTIES WILL BE GENERATED.

FURTHER R+D AND UPSCALING NEEDED:POTENTIAL AREAS OF UTILIZATION OF OUR mTG’s:

TG-based bioplastics Reduced calorie fats Biolubricants

Owing to the immense variabilityof our mTG’s as building blocksfor such polymerisations toreplace naturally occurring oils,hosts of new and novelbioplastics are bound to result,with new, novel and unexpectedproperties

(i.e. containing less numbers of Carbon and Hydrogen atoms to be burnt in the body) for dietary/medicament purposes, used aslower- calorie fat replacers

Under brand names such as Salatrim, Benefat, etc. such structures have been approved in the EU, USA, etc.

„Lubricating oils based on renewable sources such as vegetable and animal

oils and fats have a number of advantages. The vegetable and

animal oils or fats contain triglycerides having ester carbonyl groups. The polar nature of these

ester carbonyl groups leads to strong adsorption on metal faces as a very

thin film so that the film forming properties of triglyceride based

lubricants are particularly advantageous in hydraulic systems.

Vegetable oils and animal oils typically have high viscosity indices that facilitate their use over wide temperature ranges. In addition, vegetable and animal oil and fat based lubricants help reduce the

depletion of fossil-derived hydrocarbons. Moreover, vegetable

oil based lubricants are typically biodegradable, which would help reduce the introduction of waste lubricants into the environment. Currently, about 50% of mineral

lubricants used worldwide end up in landfills and the like.”

PATENT AND OTHER REGULATORY SITUATION:

1. CEN, the European Committee for Standardization:

“As your product ………..cannot be considered FAME or FAEE, it falls under ´no-harm´

clausal in EN 590 for other bio-components.…..these components are allowed in any proportions provided that the final blend complies with the requirements of EN 590”.

2. So fuel properties render this renewable fuel applicable in diesel

engines within broad limits

With the granting of our patents, our 1 and 3/4 years of priority over two Chevron patents “Low melting point triglycerides for use as fuels - US 8,324,413 and 8,361,172”, pertaining to the same fuels and manufacturing process, has been acknowledged

BEHIND TOMSName: Janos THESZ – THE INVENTOR OF „TOMS“

Born: 15. 09. 1949., Budapest, Hungary

Lives in Budapest, owner and managing director of TRANS-KEM Technical Consultancy, working out new routes in chemical technologies, coordinating implementation of the same (Hungary/Taiwan/India). Specialist in organic syntheses, organofluorides, biofuels.

Degrees:-B. Sc. (Chem.Eng.) 1979, Budapest Technical University-M. Sc. (Chemistry) 1983, Budapest Technical University

Professional experience:

1972-1977: Chemicals and Explosives Supervisory Board (working on oil well opening devices, shaped charges)1977-1979: Institute of Enzymology (working on exploring active centres of enzymes)1979-1987: laboratory manager at Chinoin Pharmaceutical Works (working on scaling up pyrethroid insecticides syntheses)1987-1991: deputy R&D manager at Chemicals and Explosives Supervisory Board (working on heat-resistant explosives for the oil industry)1991-1994: R&D manager at Budapest Chemical Works (conducting research on active ingredients and synthetic routes for pesticides)1994: forms own company, subcontractor of Chenco GmbH (Germany) for implementing fluoro-chemical technologies in India (Navin Fluorine, Tanfac Industries), Taiwan (Formosa Plastics), China (Maui Group)

Patents: HU 197 292 (GB 2 178 030, DE 3 619 294, FR 2 583 045)HU 209 385HU 226 873 & WO (international) family