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Toray's 3D Printing Solution, to Change your Production
Toray's 3D Printing Solution,to Change your Production
Toray Industries, Inc. Advanced Specialty Materials Sect. Chemicals Dept.TEL: 03-3245-5693
SEM image w/o Additives With Additives
”Toraymill®PPS”- World-first PPS powder for 3D Printer -
Features
Applications
Mechanical Strength
1.Uniform particle size distribution (D50=approx.50µm)
2.Superior flowability realized by blending appropriate additives
Toraymill® realizes complex structure with excellent mechanical strength,chemical resistance and heat resistance
<Functional parts for automotive> (Substitute metal parts)
Properties
Toraymill® PPS
Ref: Nylon
Tensile strength(MPa)
46
MP(˚C)
280
170
AerospaceAutomotive Industrial Medical
Neat
Glass reinforced
Carbon Fiber reinforced
55
64
92
Toraymill®PPS3D Printer
Complex structureFree from moldsFast completion
頻度（％）
粒径（um）
累積（％）
10
8
6
4
2
0
100
80
60
40
20
00.1 1 10 100 1000
Particle Size Distribution
※PPS (Polyphenylene Sulfide): Super engineering plastic resin with excellent heat resistance, flame retardance, chemical resistance and physical strength.
Toraymill® PPS powder has the optimum flowability and polymer propertyfor polymer SLS.
1. Enables one-path manufacturing of generally separate parts with heat-resistant materials2. Light-weighting by substituting resin for metal (weight reduction of 30~50%)
Please feel free to contact us about PPS parts by 3D printing.In addition, Please feel free to contact us about Toraymill®PBT and Toraymill®PA.
Toray Engineering Co.,Ltd. Electronics Div. Business Div.IITEL: 03-3241-8461
Features
Specifications
Zirconia Oxygen Analyzer
LC-450A
“LC-450A” offers the exact oxygen concentrationmonitoring during 3D printing.
• Measurement ranging from the ppm level to 100%.• Long-term stability and accuracy with proprietary zirconia micro sensor.• Compact and easy to set up.• LC-450A have the special sensor with high durable coating.• Various pretreatment filter enables the measurement of the abnormal sample gas
Model
Measurement system
Sampling system
Measurement range
Measurement units
Standards
LC-450A
Ion conductivity of zirconia ceramic cell
Continuous suction w/ built-in pump
0.001ppm~100vol%
0-1/10/100/1000ppm/1/10/100vol%
CE marking declaration of conformity EN61010-1:2002, N61326:+A3:2003
RoHS compliant
Toray Engineering Co.,Ltd. Computer Aided Engineering Business Div.TEL:03-3241-1543
Stre
ss[M
Pa]
Strain
40
35
30
25
20
15
10
5
00 0.01 0.02 0.03 0.04 0.05 0.06
Applicable 3D printing method
Warp estimation of objects by simulating the 3D printing process
Predicts Strength under various of printing direction
Cost reduction of injection molding by improving cycle time
Toray Engineering Co.,Ltd. offers a superior simulation Software to prevent warp and mechanically weak parts
Optimization of conformal cooling design applying 3D printed insert
Mold Conformal Cooling
3D printingprocess
Warp after 3D printing（ｘ50 amplification）
Indicates high temperature areas in redReduces warp by smooth flow of cooling water
SLS,FDM etc.
①
②
③
Specimens after tensile test
② ③①
3D printingprocess
Calculation shrinkage,layer by layer,from theprinting path and temperature distribution
Simulation taking residual stressinto consideration
Predicts warps under various ofprinting direction
Simulation Software for 3D Printing
Toray Precision Co., Ltd. Kanto BranchTEL:045-936-2990
Shaped samples
Air NozzleTurbine Nozzle
IlluminationLight-weight Gear
One-path 3D-P of 3-parts 3DP×Cutting×EDM*
3D-P×Surface polishing One-path 3D-P×Surface polishing
Air flow path (green)
50mm
30mm
Ø64mm
35mm
Lattice Structure
Realizes complex structures
• Metal 3D Printer offers various advantages compared to traditional manufacturing processes.• Toray Precision can improve surface roughness and dimensional accuracy of shaped objects by precision processing technology.
Toray Precision’s Metal 3D Printer Service
*electric discharge machining
Toray Research Center,Inc.E-Mail：[email protected] TEL：03-3245-5665
●Comparison of cure degree of the samples measured by photochemical reaction DSC
●Table Printing condition ●Printing method
Toray Research Center, Inc. supports you toimprove your 3D-printing with “Analyses”.
Sample preparation Cure degree of resin
The four kinds of samples were prepared on the different printing conditions.
• A cure degree of the samples rose so that UV irradiation time was long.• The difference of the cure degree made by 3D-printing method was not recognized.
Cure
deg
ree
/%※
100
90
80
70
60
50
A(①×1)
B(②×1)
C(①×4)
D(②×4)
Printing method ①
Printing method ②×1
×1
×4
×4
①②①②
Example：The resin curing condition optimization in the ink-jet method.
* Cf. right figure, Each Sample was used of the same materials.**Magnification for the standard application time.
Sample Printmethod*
UV irradiationtime**
The cure degree of the printed objects made by different printing method and irradiation time was measured by photochemical reaction DSC. By optimizing the irradiation time, the control of proparties of the printed objects becomes possible.
Experiment Analyses
Experiment Analyses
Overall Optimization
• Particle size distribution• Viscosity, Viscoelasticity• Stability of emulsion• Ink composition• Physical strength, density
• Cure degree• Form stability• Inner observation• Outgas Composition
A(①×1) B(②×1) C(①×4) D(②×4)
74 75
87 88
Analyses to fulfill your needs
• “To develop a new 3D printing material”• “To create a brand new product with 3D printing”• “To create a precise and tough product by optimizing 3D printing process”• “To explore a new function by 3D-printing a high performance object with a composite material”
What are your needs?
Printing Materials
Printed Objects
Printing Methods・Processes
• Speedup of the development Time• Reduction of the development cost• Epoch-making materials and process development
To be accomplished by utilizing “Analyses ”!!
Toray Research Center,Inc.E-Mail：[email protected] TEL：03-3245-5665
●Comparison of cure degree of the samples measured by photochemical reaction DSC
●Table Printing condition ●Printing method
Toray Research Center, Inc. supports you toimprove your 3D-printing with “Analyses”.
Sample preparation Cure degree of resin
The four kinds of samples were prepared on the different printing conditions.
• A cure degree of the samples rose so that UV irradiation time was long.• The difference of the cure degree made by 3D-printing method was not recognized.
Cure
deg
ree
/%※
100
90
80
70
60
50
A(①×1)
B(②×1)
C(①×4)
D(②×4)
Printing method ①
Printing method ②×1
×1
×4
×4
①②①②
Example：The resin curing condition optimization in the ink-jet method.
* Cf. right figure, Each Sample was used of the same materials.**Magnification for the standard application time.
Sample Printmethod*
UV irradiationtime**
The cure degree of the printed objects made by different printing method and irradiation time was measured by photochemical reaction DSC. By optimizing the irradiation time, the control of proparties of the printed objects becomes possible.
Experiment Analyses
Experiment Analyses
Overall Optimization
• Particle size distribution• Viscosity, Viscoelasticity• Stability of emulsion• Ink composition• Physical strength, density
• Cure degree• Form stability• Inner observation• Outgas Composition
A(①×1) B(②×1) C(①×4) D(②×4)
74 75
87 88
Analyses to fulfill your needs
• “To develop a new 3D printing material”• “To create a brand new product with 3D printing”• “To create a precise and tough product by optimizing 3D printing process”• “To explore a new function by 3D-printing a high performance object with a composite material”
What are your needs?
Printing Materials
Printed Objects
Printing Methods・Processes
• Speedup of the development Time• Reduction of the development cost• Epoch-making materials and process development
To be accomplished by utilizing “Analyses ”!!CORPORATE /
General
Toray Industries, Inc.
2-1-1 Nihonbashi-Muromachi, Chuo-ku, Tokyo 103-8666 http://www.toray.com/
Key contact: Shuichi Hariguchi E-mail: [email protected] Phone: +81-3-3245-5712
3D Printing Materials
Toray Industries, Inc.
2-1-1 Nihonbashi-Muromachi, Chuo-ku, Tokyo 103-8666 http://www.toray.jp/chemical/index.html
Key contact: Mikiya Nishida E-mail: [email protected] Phone: +81-3-3245-5693
Metal 3DPrinting
Toray Precision Co., Ltd.
322-17, Nakayama-cho, Midori-ku, Yokohama, Kanagawa 226-0011 http://www.tpc-jp.co.jp/
Key contact: Futoshi Yoshimura E-mail: [email protected] Phone: +81-45-936-2990
All-roundAnalyses
Toray Research Center, Inc.
1-1-1, Nihonbashi-Muromachi, Chuo-ku, Tokyo 103-0023 http://www.toray-research.co.jp/
Key contact: Yuko Yamazaki E-mail: [email protected] Phone: +81-3-3245-5665
Simulation Software
Toray Engineering Co., Ltd.
1-3-22, Yaesu, Chuo-ku, Tokyo 103-0028 http://www.toray-eng.co.jp/
Key contact: Tadashi Shirasu E-mail: [email protected] Phone: +81-3-3241-1543
Oxygen Analyzer
Toray Engineering Co., Ltd.
1-1-45, Oe, Otsu, Shiga 520-2141 http://www.toray-eng.co.jp/
Key contact: Takashi Matsumiya E-mail: [email protected] Phone: +81-77-544-6224
Key Contacts
