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Ô_sƒVÏ WÁȬzø¬ Ì‚¶D 28.11.2013, sBVw¬˛wÁ\ MEETING OF THE STANDING COMMITTEE ON ACADEMIC AFFAIRS HELD ON THURSDAY THE 28 th NOVEMBER 2013 APPENDIX - BA1 - BA27 CBCS - Colleges UG / PG Courses UG / PG Courses UG / PG Courses UG / PG Courses UG / PG Courses \º™V[\ËBD ∑Õ>´™VÏ √_ÔÁȬÔwÔD ]ÚÿÂ_ºko -12 MANONMANIAM SUNDARANAR UNIVERSITY TIRUNELVELI -12
Transcript

Ô_sƒVÏ WÁȬzø¬ Ì‚¶D

28.11.2013, sBVw¬˛wÁ\

MEETING OF THESTANDING COMMITTEE ON ACADEMIC AFFAIRS

HELD ON THURSDAY THE 28th NOVEMBER 2013

APPENDIX - BA1 - BA27

CBCS - Colleges

UG / PG CoursesUG / PG CoursesUG / PG CoursesUG / PG CoursesUG / PG Courses

\º™V[\ËBD ∑Õ>´™VÏ √_ÔÁȬÔwÔD

]ÚÿÂ_ºko-12

MANONMANIAM SUNDARANAR UNIVERSITYTIRUNELVELI-12

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI – 12

INDEX

S.No SUBJECTS APPENDIX NUMBER

PAGE NUMBER

01. Tamil – Existing Syllabus for those who do not know Tamil and do not study Tamil as a paper – 2012 – 2013 BA1 1

02. Revised Scheme of Examinations for I & II Semester in B.A. History and Tourism, B.A. History (vocational) Tourism and B.A. Tourism and Hospitality Management (CBCS) – 2012 – 2013

BA2 2

03. B.Com with Computer Applications – Correction in unit V under III Semester for the paper in ‘Internet Applications’ – 2012 -2013

BA3 5

04. B.Sc.Mathematics – Included the paper ‘Basic Algebra’ in IV Semester – 2012 – 2013. BA4 6

05. Certificate Course in Medical Laboratory Technician – 2012-2013. BA5 7

06. Correction in passing minimum of marks - Certificate course in Medical Laboratory Technician and Certificate course in Economics & Statistics - 2012- 2013

BA6 12

07.

B.A Tamil (CBCS) V & VI Semesters – Syllabus – III Semester - modification in the paper “oh{<{qbl<” in Unit IV & V Scheme of Examinations for I & II Semester and change of Skill Based Subject from V to IV - 2012 - 2013

BA7 13

08. B.A. Tamil with Computer Applications- Syllabus IV to VI Semester – 2012 -2013 BA8 41

09 B.Com (Vocational) Computer Applications (CBCS) V & VI Semesters – Syllabus - 2012 – 2013 BA9 80

10. B.Com Professional Accounting (CBCS) V & VI Semesters – Syllabus - 2012 – 2013 BA10 95

11. B.Com Corporate Secretaryship (CBCS) V & VI Semesters – Syllabus - 2012 - 2013 BA11 109

12. B.C.A (CBCS) V & VI Semester – Syllabus - 2012 - 2013 BA12 125

13. B.Sc. Bio-Informatics (CBCS) V & VI Semesters- Syllabus - modification in Eligibility norms, Practicals and change of Skill Based Subject from V to IV - 2012-2013.

BA13 148

14. B.Sc.Microbiology – Revised Scheme of Examinations and change of Skilled based subject from V to IV – 2012 – 2013. BA14 167

 

S.No SUBJECTS APPENDIX NUMBER

PAGE NUMBER

15. M.A. History with Computer Application –CBCS –For Colleges – Second Year Syllabus – for those who joined the academic year 2012-2013

BA15 173

16. M.A.English & M.A.English with Computer Applicpations – CBCS- For Colleges – Corrections made in Third Semester – for those who joined the academic year 2012-2013

BA16 189

17. M.Phil. Zoology – for Colleges – Effective from the academic year 2013-2014 BA17 190

18. M.Sc. Nanoscience – Modified Syllabus – CBCS – for Colleges - 2013-2014 BA18 203

19. M,Sc. Conservation of Marine Environment - CBCS-for colleges - UGC Innovative Programme - for those who joined the course from the academic year 2013-2014

BA19 236

20 M.Sc., Chemistry (Specialization in Green Chemistry) - UGC Innovative Programme - CBCS- for colleges – effective from the academic year 2013-2014

BA20 271

21 M.A.Tamil – Revised Syllabus – CBCS – For Colleges – effective from the academic year 2013-2014 BA21 310

22 M.C.A.– CBCS –V & VI Semester syllabus for Colleges – effective from the academic year 2012-2013 BA22 315

23 M.Phil. Physics – Guidelines and format for Project work – Annexure II to VIII – for colleges – 2013 -2014 BA23 329

24. M.Sc.Software Engineering (5 years Integrated Course) – 3rd to 5th year Syllabus – CBCS - for Colleges – for those who joined the academic year 2012-2013

BA24 335

25.

B.A. Economics(CBCS) – Change of Skilled Based Subject from V to IV Semesters – 2012-2013 BA25 380

26. B.Sc Physical Education (CBCS) – Revised Scheme of Examinations and Change of Skilled Based Subject from V to IV Semester – 2012-2013

BA26 381

27. B.Sc Costume Design and Fashion(CBCS) – Change of Skilled Based Subject from V to IV Semester - 2012 - 2013 BA27 384

1  

APPENDIX - BA1

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI -12

Syllabus for those who do not know Tamil and who do not study Tamil as a Paper

For those who joined the course from the Academic Year 2012-2013

!klqp<!olipqjb!nxqbik!li{ui<g<Giqb!himk<kqm<ml<!;!

&e<xil<!hVul<! ;!nxqLgk<!klqp<!!kit<!2!!! Appendix – AS 82

fie<gil<!hVul<! ;!fx<xlqp<!gx<xz<!!kit<!3!! Page!61!–!79!

!

ohiKk<klqp<!hbqzik!li{ui<g<Giqb!sqxh<Hk<!klqp<!himk<kqm<ml<!

&e<xil<!hVul<! ;!sqxh<Hk<!klqp<!kit<!2!!.!jhf<klqp<!!!!!Appendix – AS 82

fie<gil<!hVul<! ;!sqxh<Hk!<klqp<!kit<!3!!.!uti<klqp<!!!!!Page!7:!–!319!

!

2  

APPENDIX - BA2

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI Choice Based Credit System (CBCS)

B.A. HISTORY & TOURISM REVISED SCHEME OF EXAMINATION

with effect from the academic year 2012-13 Sl. No Components

Teaching

HoursExam

DurationMax. Marks 100 Min.

Marks Credit Theory Internal

I. SEMESTER

1.1 Part : I Tamil / Other Languages 6 3 75 25 40 3

1.2 Part : II English 6 3 75 25 40 3

1.3 Part III-Core Subject (2 Courses) Major - I History of India upto 647A.D

5 3 75 25 40 5

1.4 Major - II Principles of Tourism 5 3 75 25 40 5

1.5 Allied - I (1 Course) Political Science / Economics / Sociology

6 3 75 25 40 5

1.6 Part :IV (1 Course) Environmental Studies 2 3 75 25 40 2

Total Course 6 30 23 II. SEMESTER

2.1 Part : I Tamil/Other Languages 6 3 75 25 40 3

2.2 Part : II English 6 3 75 25 40 3

2.3 Part : III (2 Courses) Major - I History of India from 647 A.D to 1526 A.D

5 3 75 25 40 5

2.4 Major - II Indian Heritage 5 3 75 25 40 5

2.5 Allied - I (1 course) Modern Constitution / Economics / Sociology

6 3 75 25 40 5

2.6 Part : IV (1 Course) Value based Education 2 3 75 25 40 2

Total (6 courses) 30 23

3  

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI Choice Based Credit System (CBCS)

B.A. History (Vocational) Tourism REVISED SCHEME OF EXAMINATION

with effect from the academic year 2012-13 Sl. No Components

Teaching

Hours

Exam Duratio

n

Max. Marks 100 Min. Marks Credit

Theory Internal

I. SEMESTER

1.1 Part : I Tamil / Other Languages 6 3 75 25 40 3

1.2 Part : II English 6 3 75 25 40 3

1.3 Part III-Core Subject Major - I History of India upto 647 A.D

5 3 75 25 40 5

1.4 Major - II Principles of Tourism 5 3 75 25 40 5

1.5 Allied - I (1 Course)Computer Application / Indian Archaeology / Economics

6 3 75 25 40 5

1.6 PART-IV (1 Course) Environmental Studies 2 3 75 25 30 2

Total Course 6 30 23

II. SEMESTER

2.1 Part : I Tamil/Other Languages 6 3 75 25 40 3

2.2 Part : II English 6 3 75 25 40 3

2.3

Part : III -Core Subjects (2 Courses) Major - I History of India from 647 A.D to 1526 A.D

5 3 75 25 40 5

2.4 Major - II Indian Heritage 5 3 75 25 40 5

2.5 Allied - I (1 Course) Computer Application / Indian Architecture / Economics

6 3 75 25 40 5

2.6 Part - IV (1 Course) Value based Education 2 3 75 25 40 2

Total (6 courses) 30 23

4  

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI Choice Based Credit System (CBCS)

B.A. Tourism & Hospitality Management REVISED SCHEME OF EXAMINATION

with effect from the academic year 2012-13 Sl. No Components

Teaching

HoursExam

DurationMax. Marks 100 Min.

Marks Credit Theory Internal

I. SEMESTER

1.1 Part : I Tamil / Other Languages 6 3 75 25 40 3

1.2 Part : II English 6 3 75 25 40 3

1.3

Part III-Core Subject (2 Courses) Major - I Tourism: Principles and Practices

5 3 75 25 40 5

1.4 Major - II Communication Skill 5 3 75 25 40 5

1.5 Allied - I (1 Course)General Management / Archaeology / Hotel Management

6 3 75 25 40 5

1.6 Part : IV (1 Course) Environmental Studies 2 3 75 25 35 2

Total Course 6 30 23

II. SEMESTER

2.1 Part : I Tamil/Other Languages 6 3 75 25 40 3

2.2 Part : II English 6 3 75 25 40 3

2.3

Part : III -Core Subjects (2 Courses) Major - I Tourism: Tourism Organisations

5 3 75 25 40 5

2.4 Major - II Business Communication 5 3 75 25 40 5

2.5 Allied - I (1 Course) General Management / Archaeology / Hotel Management

6 3 75 25 40 5

2.6 Part : IV (1 Course) Value based Education 2 3 75 25 40 2

Total (6 courses) 30 23

5  

5

 

APPENDIX - BA3

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI - 12

B.Com with Computer Applications

(III Semester) - Under CBCS

Non-Major Electives - MODIFIED SYLLABUS

With effect from the Academic Year 2012-2013

2. INTERNET APPLICATIONS

UNIT I

Data communication - Computer networking basics – LAN Teach Data communication - Computer networking basics - LAN Technology and networking Topology - WAN Technology and routing - protocols and layering - Networking Devices.

UNIT II

Meaning of internet, Intranet and Extranet – Evolution of internet – Important features of Internet – Brief description about Web Server, web Browser and (WWW), Search Engines.

UNIT III

Internet Addressing: Standard Internet Addresses – Top Level Domains – Pseudo – Internet Address – IP Addresses and DNS – Mail: SMTP – Signatures – Mail Addresses –Sending and Receiving mail – How mail is stored? Text and Binary data – Understanding the web : Links –URLs – web page – Home Page

UNIT IV

E-Mail-Description of E-Mail address and Message format – File Transfer Protocol World Wide Web- Usenet-Ip-telephony-Frequently Asked Questions (FAQ), Internet Relay Chat (IRC) and Instant Messaging

UNIT V

Internet Applications: E-Mail-Telnet-Chatting-video conferencing-Newsgroups(Usenet)

TEXT AND REFERENCE BOOKS:

1. Sanjay Saxsena, “A First Course in Computer”, Vikas Publishing House, 2000. 2. Fundamentals of the Internet and World Wide Web by Green law and Hepp,TMH Publication

6  

APPENDIX - BA4

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI -12

SEMESTER - IV UG Degree (CBCS) Non-Major Elective (30 hrs) With effect from the Academic Year 2012-2013

(1) Mathematical Models (OR) (Syllabus Already Given)

(2) Basic Algebra

Syllabus for ‘Basic Algebra’ Text Book : Algebra Volume II

By T.K. Manicavachagom Pillay, T.Natarajan and K.S. Ganapathy.

(S.Viswanathan Printers and Publishers Pvt. Ltd.,)

Unit I Rank of a Matrix-System of non-homogeneous linear equations in n unknowns.

(Chapter 2: Section 11, 12, 13 and 14)

Unit II System of non-homogeneous linear equations

(Chapter 2: Section 16 (only Problems))

Unit III Eigen Values and Eigen Vectors – Cayley Hamilton Theorem (Without Proof)

(Chapter 2: Section 17 (17.1 to 17.5))

Unit IV Theory of Numbers – Prime and Composite Numbers – Divisors of a given

number N – Problems.

(Chapter 5: Sections 1 to 7)

Unit V Euler’s function φ(N) – Integral part of a real number – The highest power of a

prime p contained in n! – Problems.

(Chapter 5: Sections 8 to 10)

7

APPENDIX - BA5 MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI – 12

CERTIFICATE COURSE IN MEDICAL LABORATORY TECHNICIAN

UNDER CAREER ORIENTED PROGRAMME

(For those who joined the course from the academic year 2012 - 2013) Medical Laboratory Technician Course also called clinical Lab science is an allied health profession which is concerned with diagnosis of diseases through the use of lab test. Medical Laboratory Technician Course will become an invaluable complementary resource to the students’ educational programme that teaches the skills that are necessary to work efficiently in a laboratory even when they are doing their regular graduate programme. Objective: To train the students to get employment in the diagnostic labs / hospitals / blood banks / research laboratories / pharmaceutical industries and to run their own clinical laboratories. Eligibility : Certificate course : Any first year B.Sc degree course (Students should have studied Biology and Chemistry at +2 level). Basic Qualification for those who handle classes : M.Sc. in Zoology / Chemistry / Biochemistry / Microbiology /Biotechnology / Lab Technology / Immunology Structure of the Programme and Scheme of Examination

Name of the Paper

No of Credits

Contact Hours

Minimum Marks

Maximum Marks

Paper I Haematology 6 90 40 100

Paper II Clinical Biochemistry, Clinical Microbiology and Clinical Pathology

6 90 40 100

Paper III Practical 8 120 40 100

Total 20 300 300

8

Question Paper pattern Part A 10 x 1 = 10 Marks (Objective Type)

Part B = 25 Marks

Part C = 40 Marks Explanation questions with internal choice.

PAPER I : HAEMATOLOGY

Unit I: Introduction to Medical Laboratory Technology

Basic Principles and Basic Medical Laboratory terminology

Organization of medical lab and medical lab management.

Identification and use of common laboratory glassware and instruments

Cleaning of glassware

Preparation of materials for experiments and sample collection - labeling and

processing of blood and body fluids used in diagnostic techniques

Safety regulations and first aid

Medical laboratory record preparation

Unit II: Haemotology

Human circulatory system - Heart, Blood vessels and constituents of blood

Functions of Plasma RBC, WBC and Platelets

Anticoagulants

Blood collection techniques through vein puncture and finger prick

Blood pressure reading

Haemolysis - Haemolytic agents and prevention of blood borne infections

Types of Anaemia and parasitic diseases

Unit III : Erythrocytes, Leukocytes and Platelets

Erythrocytes: Erythropoiesis, total RBC count, haemoglobin estimation, ESR

estimation, red cell indices, reticulosite count

Leukocyte: - Leukopoiesis, total WBC count, differential leukocyte count,

leukaemia - different types of leukaemia. absolute eosinophil count and abnormal

WBC

9

Thrombocytes (Platelets) : Thrombopoiesis, total platelet count, bleeding time,

clotting time, Prothrombin time,platelet related diseases

Study of blood smear

Unit IV: Blood grouping

Blood grouping and importance of blood grouping

Procedure for ABO blood grouping

Characteristics and reactions of Antigen and Antibodies

Importance and procedure for Rh typing

Unit V: Blood Banking

Mechanism of Blood coagulation

Anticoagulants used in blood banking

Donor selection, blood collection, transportation of blood, storage of blood and

screening of blood

Cross matching - Coomb' s test

Blood transfusion

Haemolytic diseases of new borne

PAPER II : Clinical Biochemistry, Clinical Microbiology and Clinical

Pathology

Unit I : Clinical Biochemistry Basic Principles of Chemistry ; Reagents - Solutions, types of solution,

Normal solutions, Molar solutions, percent solution, buffer solution, stock and

working solution. Preparation of normal saline pH indicators.

Unit II : Biochemical test profile Pancreas and liver function tests, direct, indirect-bilirubin, total protein,

albumin, globulin, alkaline phosphatase, acid phosphatase, SGOT, SGPT

and other functional tests

Estimation of Glucose, G.T.T

Amylase and gastric juice analysis

10

UNIT III: Instrumentation Principles and use of microscope, centrifuge, photoelectric colorimeter,

spectrophotometer, incubator, laminar airflow chamber, autoclave and

autoanalyser.

UNIT IV: Clinical Microbiology Management of Microbiology lab

Sterilization methods

Types of culture media

Stains - Simple stain, special stain, gram stain, fluorescent stain, flagella

stain, AFB stain, Infection and route of infections

Specimen collection and storage of urine, stool, throat swab, CSF, sputum,

pus and blood

Unit V: Clinical Pathology Physical and chemical examination of Urine - specific gravity of urine; test for

albumin, Benedict’s test, test for bile salts and pigments, Benzidine test,

common parasites found in urine and casts found in urine.

Physical examination of stool - Test for occult blood in stool

PAPER III - PRACTICALS

HAEMATOLOGY, CLINICAL BIOCHEMISTRY, CLINICAL MICROBIOLOGY AND CLINICAL PATHOLOGY

1. Laboratory management and planning, receiving and recording of

specimens, indexing and maintaining records and reporting

2. Blood grouping and Rh typing

3. Determination of Bleeding time and Clotting Time

4. Blood pressure reading

5. Estimation of Haemoglobin

6. Estimation of RBC count, WBC count

7. Estimation of ESR

11

8. Physical, Chemical and microscopic and microbiological examination of

urine

9. Physical, chemical and microscopic and microbiological examination of

stool

10. Physical, chemical and microscopic and microbiological examination of

sputum.

11. Estimation of Blood sugar, Blood urea, Uric acid, Serum creatinine,

Serum bilurbin, Total proteins, Albumin, Cholesterol, HDL, TGL, SGOT,

SGPT, PTT.

12. Preparation of glasswares for sterilization

13. Preparation of Nutrient media and culture methods

14. Staining techniques - Simple, Gram positive, Gram negative and acid

fast staining. References 1.Singh, S.P. Practical Manual to Biochemistry, CBS Publisher, New

Delhi.

2.Stryer, L.Biochemistry, WH, Freeman & Company, 5th Edition,

SanFrancisco. 3. Skoog, D.A and Leary, J.J. Principles of

Instrumental analysis, 4th Edition, Saunders College Publishing, New

York.

4. Praful B. Godkar - Medical Lab Technology

5. JoIn, D. Bener - Clinical Laboratory methods

6. Ramnik sood - Medical Lab Technology

7. Heinemann, W.H. Practical clinical Biochemistry - Verly

Publications

8. Deb, A.C. Medical Biochemistry

9. Kanai L. Mukherjee - Medical Lab Technology - Vol I - III

10. Jayaraman, J. Laboratory Manual in Biochemistry, Wiley Eastern

Limited.

12

APPENDIX - BA6

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI – 12

CERTIFICATE COURSE

Correction in passing minimum (For those who joined the course from the academic year 2012-2013)

The correction in passing minimum of marks has been made for the

Certificate courses viz.(i) Certificate course in Medical Laboratory

Technician (ii) Certificate course in Economics & Statistics as ‘40’ instead

of ‘35’, for those who joined the course from the academic year 2012-2013.

 

 

 

 

 

 

 

 

 

 

13

APPENDIX - BA7 !

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35

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36

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B.A. TAMIL.!

&e<xil<!hVul<!)Third Semester) CHANGE OF SYLLABUS IN UNIT IV & V

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37

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Lkz<!hVul<!(First Semester) !

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Major – 2 fe<E~z<!.!wPk<K! 5 3 75 5

Allied Subject Paper – I fim<Mh<Hxuqbz<! 6 3 75 5

Environmental Studies Sx<Xs<!S,pz<!gz<uq! 2 3 75 2

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week Exam Hours

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Major – 3 sqx<xqzg<gqbl<!! 5 3 75 5

Major – 4 fe<E~z<!.!osiz<! 5 3 75 5

Allied Subject Paper – II fim<Mh<Hxuqbz<! 6 3 75 5

Value Based Education s&g!lkqh<hQm<Mg<!gz<uq! 2 3 75 2

!

38

IV SEMESTER

Skilled Based Subject

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39

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! ! ! ! ! ! ! APPENDIX - BA8! !lOeie<l{qbl<!Sf<kveiI!hz<gjzg<gpgl<?!kqVofz<Ouzq!

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42

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43

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74

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75

hGkq!.!-!)5 x 8 = 40!lkqh<oh{<gt<*!

711!osix<gtqz<!uqjm!kVg/!

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!!!ui{qguijg!Kjxgjt!uqtg<Gg/!!

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likqiq!uqeik<kit<!

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hGkq!–!n!)10x1=10!lkqh<oh{<gt<*!!!I/!siqbie!uqjmjbk<!OkIU!osb<g! ! ! ! !!!!!! (10x1=10) !2/!! Lkz<!Oux<xvS!gizh<hGkqbqz<!Okie<xqb!F~z<!wK@!! ! n*!okiz<gih<hqbl<! ! N/!Lk<okit<tibqvl<!! ! -/!ff<kqg<gzl<hgl<! ! =/!hv{q!!3/!! gQp<uVueux<Xt<!wf<k!osiz<!klqp<!-z<jz!we<X!nxqRIgt<!%XuI@!! ! n*!%mz<!! ! N/!H{Ih<H! ! -/!sr<gl<! =/!njubl<!!4/!! sQug!sqf<kil{qbqe<!olik<k!-zl<hgr<gt<@!! ! n*!29!! N/!26!-/!24!!! =/!23!

76

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-/!kqu<bhqvhf<kl<!! ! =/!ohiqbHvi{l<!!8/!! 6!ubK!Lkz<!8!ubK!!ujvBt<t!oh{<gtqe<!hVul<!biK@!! ! n*!Ohjk! ! N/!ohKl<jh!! -/!lr<jg! =/!lmf<jk!!9/!! fQOvim<mg!blg!nf<kikqjbh<!hicbuI!biI@!! ! n*!squh<hqvgisI! N/!GlvGVhvI!! ! -/!ut<tziI!! =/!hm<pek<kcgt<!!:/!! fimgg<!gih<hqbl<!we<X!njpg<gh<hMuK!wK@!! ! n*!sqzh<hkqgivl<! N/!l{qOlgjz!! ! -*!sQugsqf<kil{q! =/!G{<mzOgsq!!21/!! HKg<guqjk!-bg<gk<jkk<!Okix<Xuqk<kuI!! ! n*!HKjlh<hqk<ke<! ! N/!f/!hqs<s&Ik<kq!! ! -*!Svki! ! ! =/!fi/!gilvise<!! ! ! ! ! hGkq!–!N!)5x5=25)!lkqh<oh{<gt<*!!II. 361!osix<gTg<G!lqgilz<!uqjm!kVg!! ! ! 22/! n/!-zg<gqb!uvzix<xqz<!gizh<hGkqgt<!hx<xqb!osb<kqgjtk<!!!!!!!!!!okiGk<K!wPKg@!! ! ! )nz<zK*!!!!! N/!sr<g!-zg<gqbr<gt<!hx<xqb!ohiKuie!ujvbjx!kVg@!!23/! n/!-vm<jmg<!gih<hqbr<gt<!hx<xqb!osb<kqgjtk<!kVg@!! ! ! )nz<zK*!! N/!gqxq <̂ku!gih<hqbr<gtqe<!osz<uig<jg!uquiq@!!24/!! n/!jsug<!Gvui<gjt!uiqjshMk<kq!uquiq@!! ! ! )nz<zK*!! N/!ju{u!slbl<!klqHg<gix<xqb!hr<jg!uquiq@!!25/! n/!hqt<jtk<!klqpqe<!-zg<g{l<!%xq!!uquiq@!! ! ! )nz<zK*!

N/!sqk<kI!hx<xqb!osb<kqgjtk<!kVg@!!!26/! n/!djv!ujggjt!uqtg<gqBjvg<g@!! ! ! )nz<zK*!

N/!sqXgjkbqe<!Okix<xl<!utIs<sq!hx<xqb!osb<kqgjtk<!kVg@!

77

hGkq!-!)5 x 8 = 40!lkqh<oh{<gt<*!!III.!711!osix<gTg<G!lqgilz<!uqjm!kVg@!! ! ! ! !!27! n/!-zg<gqbk<jk!Hkqb!Ofig<gqz<!NsqiqbI!n[Gl<!Ljxjb!uquiq@!! ! ! )nz<zK*!! N/!fQkq!-zg<gqbr<gt<!Gxqk<K!gm<Mjv!ujvg@!!28/! n/!JR<sqX!gih<hqbr<gt<!Gxqk<K!gm<Mjv!ujvg/!! ! ! )nz<zK*!! N/!Hvi{!-zg<gqbr<gjt!uqtg<gqBjvg<g@!!29/! n/!Np<uiIgt<!klqPg<gix<xqb!oki{<jm!nuIgtqe<!hjmh<Hgt<!upq!!!!!!!!!!!!!uqtg<Gg@!! ! ! )nz<zK*!! N/!hqx!slbr<gt<!klqp<!olipqg<Gs<!osb<k!oki{<jm!uquiq@!!2:/! n/!klqp<!-zg<gqbk<kqz<!sqx<xqzg<gqbr<gt<!ohXl<!-mk<jk!Nb<g@!! ! ! )nz<zK*!

N/!klqpqz<!sqx<xqzg<gqbr<gt<!hjmk<k!HzuIgjth<!hx<xqb!!!!!osb<kqgjtk<!kVg@!

!31/!! n/!-js!fimg!utIs<sqjbg<!Gxqk<K!gm<Mjv!ujvg@!! ! ! )nz<zK*!

N/!KjxOkiXl<!klqp<!utIf<Kt<t!fqjzjb!Nb<g@!!!

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78

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79

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we<hK!hx<xq!uquiq@!!

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80  

APPENDIX - BA9

MANOMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI -12

CHOICE BASED CREDIT SYSTEM

COURSE STRUCTURE FOR

B.COM (Vocational) Computer Applications

(With effect from the academic year 2012 -13)

V Semester

COMPONENTS

HOURS

CREDITS

Part III – Core Subjects (3 Courses) Corporate Accounting I Cost Accounting Business Law

7 7 6

5 5 6

Major Elective (1 Course) (Any One) 1. Application of Accounting Software – tally

(theory 4 hrs, practical 2 hrs) 2. Income Tax, Law & practice I 3. Logistics Management

6

5

Common Skilled Based Subject (1 Course) 1. Effective Communication 2. Personality Development

4

4

Total (5 Courses) 30 25 VI Semester

COMPONENTS

HOURS

CREDITS

Part III – Core Subjects (4 Courses) Corporate Accounting II Management Accounting Industrial Law Auditing

6 6 6 6

5 5 5 5

Major Elective (1 Course) (Any One) 1. Multimedia with Application

(Theory 4 hours, practical – 2 hours) 2. Retail Management 3. Income Tax, Law & Practice II

6

5

Total (5 Courses) 30 25

81  

Total number of courses :34 Total number of hours :180 Total number of credits :140 Distribution of marks in Theory between External and internal Assessment is75:25 pass

minimum of 40% for external and overall components.

B.Com (Vocational) Computer Applications – SYLLABUS UNDER CBCS

With effect from the Academic Year 2012-2013 V Semester

Part III Core Subjects (3 Courses) 1. Corporate Accounting I

Unit -1 Issue of shares-issue at par, premium and discount- calls in arrears- calls in advance-

Forfeiture and reissue of shares-Prorata allotment- redemption of preference shares-

issue of Bonus shares.

Unit II Issue of debentures - redemption of debentures- sinking fund method-Underwriting of

shares.

Unit III Profit prior to incorporation – alteration of share capital and internal reconstruction-

Accounting entries.

Unit IV Valuation of goodwill and shares- various methods of valuation of goodwill and shares.

Unit V Amalgamation, absorption, and external reconstruction- calculation of purchase

consideration – In the books of Vendor and purchaser.

Theory 40 Marks: Problem 60 Marks Text and Reference Books:

1. advanced Accountancy Volume II-S.P. Jain & K.L.Naranag-Kalyani Publishers, New Delhi

2. Advanced Accountancy Volume II – R.L.Gupta and M.Radhaswamy – Sultan Chand & sons, New Delhi.

3. Advanced Accountancy Volume II – M..Shukla and T.S.Grewal – S.Chand &co,New Delhi.

82  

V Semester Part III Core Subject 2. Cost Accounting

Unit I Cost accounting-Nature- Meaning – Features and importance limitation of financial

accounting-advantages and limitation of cost accounting – costing system-cost centre-

cost unit- elements of cost- cost classification – cost sheet.

Unit II Materials –objectives- purchase control- centralized and decentralized purchase – stock

levels and EOQ-ABC Analysis-Bin card- stores ledger- Material issue – FIFO, LIFO,

Average and weighted average methods

Unit –III Labour- Direct and indirect labour – methods of wage payments- remuneration and

incentives – premium and bonus plans- Idle time- over time- labour turnover.

Unit IV Overhead- Meaning- classification- allocation and apportionment of overheads- re

apportionment of overheads-absorption of over head- methods- machine hour rate.

Unit V Job costing (simple problems only) – process costing –features- process losses and

gains.

Theory 40 Marks: Problem 60 Marks Text Books:

1. Cost Accounting-S.P.Jain&K.L.Narang, Kalyani Publishers, New Delhi.

2. Cost Accounting – S.P.Iyengar, Sultan Chand & Sons, New Delhi.

3. Cost Accounting – S.N.Maheswari, Sultan Chand & Sons, New Delhi

Books for Reference: 1. Cost Accounting – Jawaharlal, Tata McGraw Hill Editions

2. Cost Accounting – M.L.Agarwal, Sahitya Bhavan Publishers

3. Cost Accounting – R.S.N.Pillai, Sultan Chand & Sons

4. Cost Accounting Principles & Practice – Thukkaram Rao, New Age Publishers.

83  

V Semester Part III Core Subject 3. Business Law

Unit I Indian contract Act 1872-Fundamental essential of a valid contract- classification of

contract- offer acceptance- consideration- capacity-free consent – legality of object –

contingent contracts.

Unit II Performance of contract- discharge of contract- breach of contract- remedies-Quasi

contracts.

Unit III Special contracts- Indemnity – Guarantee

Unit IV Bailment – pledge- contract of agency.

Unit V Sale of Goods Act- Difference between sale and agreement to sell- sale and hire

purchase agreement- classification of goods-documents of title to goods- Rights and

duties of buyers and sellers – Rights of unpaid seller.

Text books 1. Business law- N.D.Kapoor

2. Element of Mercantile Law- N.D.Kapoor,sultanchand& sons

3. Business Law-P.C.Tulsian, Tata McGraw- Hill station.

4. Business Law-R.S.N.Pillai, Bagavathy- S.Chand&Co,New Delhi.

Reference Books: 1. Business and Corporate Law- P.C.Tulsian, Tata McGraw- Hill station. 2. Business Law including Company Law- S.S.Gulshan, G.K.Kapoor- New age

International Pvt Ltd, New Delhi.

84  

Major Elective (1Course)(Any One) 1. APPLICATION OF ACCOUNTING SOFTWARE-TALLY

UNIT I Feature of Tally Accounting concepts-Company creation. UNIT II Classification of Accounts-Accounts Master. UNIT III Accounts vouchers-Final accounts. UNIT IV Stock item-inventory vouchers-invoice UNIT V Order processing-Stock summary-MIS Reports-Budget Scenario Management. TEXT AND REFERENCE BOOKS:

1) “Implementing Tally 6.3”,A.k. Nadhani, K.K. Nadhani, BPB Publications Chapters: 1,2,3,5,6,7,9,15,16,17,19,20,17,28. LIST OF PRACTICALS ACCOUNTING PACKAGE (TALLY)

1. Create the following company:

Wincom Computers deal in both Software and hardware. It has its corporate

office at 55, Indra Nagar, Chennai-12 PAN: B45678K.Lacal S.T.Regn

:St/Che/4323. They are not registered under Central Sales Tax.

There are operating within the country.

2. Create Groups and ledgers for sales as under

Sales

Computer sales

Service charges

Installation charges

Annual maintenance charges

Maintenance charges

Software development

85  

3. A. Develop a purchase day book with your own data

B. Create a sales Day Book with imaginary data

C. Create a format of petty cash book with your own figure

4. With the following particulars prepare a Trial Balance

Capital Accounts 50,000

Sales 6, 50,000

Purchases 7, 60,000

Salaries 2, 2000

Carriage inwards 400

Carriage outwards 500

Lighting 300

Rates and Insurance 400

Discount earned 500

Buildings 30,000

Furniture 6000

Sundry Debtors 8000

Sundry creditors 20,000

Cash and Bank 1850

5. Prepare a proper subsidiary book and do the transactions with your own data.

6. Prepare a petty cash book with your own data.

7. Prepare a Balance Sheet with your imaginary data.

8. Prepare a sales invoice of a Super market with your data.

86  

Major Elective (1Course)(Any One) 2. Income tax law and practice –I

Unit I Basic concepts – Person, assessee, previous and assessment year, total income, gross

total income – concept of income – Agricultural Income- Income exempted from tax –

Residential Status- problems.

Unit II Income from salary –different forms of salary and allowance – perquisites – problems in

computation of salary income.

Unit- III Income from House property – Annual value – Standard deduction– Unrealized rent –

problems in computation of house property income.

Unit –IV Income from under the Head – Business or profession – deduction allowable –

Expressly disallowed expenses – computations – problems in computation of business

or professional income.

Unit – V Income from capital gain - Types - Exemption- Computation- problems in computation

of capital gain.

Theory 40 and problem 60

Text Book for reference 1. Income tax law and accounts- Dr.H.C.Mehrotra and Dr.P.Mehrotra

2. Income tax law and practice - V.P Gaur, D.B Narang, PoojaGhai and Rajeev

Puri.

87  

Major Elective (1Course)(Any One) 3.Logistics Management

Unit I Logistics- meanings- importance-logistics competency- logistical mission – service-

total-cost- logistical renaissance- technological advancement- regulatory change- IT

Revolution- TQM Initiatives.

Unit II Work of logistics- -network design- information- transportation and Inventory-

warehousing – material handling- packaging- integrated logistics- Inventory flow –

Information flow.

Unit III Operating objectives- rapid response- minimum variance –minimum inventory –

movement consideration- quality- life cycle support- barriers to internal integration in

organizational structure – measurement system- inventory ownership – information

technology- knowledge transfer capacity.

Unit IV Information functionality- and inventory functionality- principles of logistics information-

information architecture-planning –operations- logistics information flow – application of

new information technologies – electronic data interchange standards- inventory

functionality- inventory types- characteristics- cost of carrying inventory- determining

order point-lot size- accommodation uncertainty- replenishing ordering and ware

housing management.

Unit V Transportation infrastructure- transport functionality- principles- modal classification-

transportation formats- suppliers of transportation services- storage functionality-

principles –concept of stratigice storage – developing warehouse resource- warehouse

4 strategies

Text books Logistical management (Integrated supply chain process-by DonaldJbowersox,

davidJcloss- Tata Mcgraw –Hill edition

88  

Common skill based subjects(1Course)(Any One) 1. Effective Communication 2. Personality Development

B.Com (vocational) Computer Application Course – SYLLABUS UNDER CBCS

with effect from the Academic Year 2012-2013 VI Semester

Part III Core Subjects – 4 Courses 1. Corporate Accounting-II

Unit –I Liquidators’ final statement- contributory.

Unit –II Holding companies- minority interest- capital profits- cost of control or goodwill-

preparation of consolidated balance sheet.

Unit –III Banking companies-Format of balance sheet and profit and loss account as per sec 29

of Banking Regulation Act.

Unit – IV Double account system- meaning-difference between double account and single

account system- difference between double account- and double entry system-

preparation of final accounts- capital base disposal of surplus- calculation of reasonable

return- replacement of assets.

Unit V Accounting ratios- responsibility accounts- human resource accounting.

Theory 40 Marks: Problem 60 Marks Text books Advanced Accountancy Dr. M.A Arulanandam Dr. K.S.Raman Advanced accountancy S.P.Jain K.L.Narang Advanced Accountancy M.C.Shuckla

89  

VI Semester Part III Core Subject 2. Management Accounting

Unit I Management accounting- Definition- Objectives- Nature, scope, function-management

accounting Vs financial accounting-Management Accounting vs cost accounting-

advantages-limitations of management accounting.

Unit II Fund flow and cash flow analysis- meaning –Difference between fund flow statement

and cash flow statement- funds- preparation of fund flow statement and cash flow

statement.

Unit III Marginal costing –meaning- features-assumption- contribution P\V Ratio-CVPanalysis-

Break even analysis-Assumption- Advantages – limitations- margin of safety.

Unit IV

Standard costing- meaning of standard cost and standard costing standard costing and

budgetary control- Advantages and limitations- analysis of variance- Direct material,

direct labour and overhead.

Unit V Budget and budgetary control- meaning of budget, budgeting and budgetary control-

objectives- features- advantages –limitations- flexible budget- cash budget- production

budget – purchase budget – sales budget.

Theory 40 Marks: Problem 60 Marks Text books: 1. Management accounting S.M. Maheswari sultan chand and sons.

2. Management accounting.R.S.N.Pillai&Bhawathi ,S.Chand&co

90  

VI Semester Part III Core Subject 3. Industrial Law

Unit I The factories Act 1948 – Definitions– approval, licensing and Registration of Factories

– duties of occupier – Inspection staff- certifying surgeons- provisions for health- safety-

welfare- working hours and holidays- employment of young persons and women-

Annual leave with wages- penalties and procedure.

Unit II Workmen’s compensation Act 1923 – scope and coverage- definitions- rules- personal

injury by accident- occupational disease- arising out of and in the course of employment

– theory of notional extension- amount of compensation- distribution of the

compensation- notice and claim.

Unit III Industrial disputes Act 1947 –object- definitions- conciliation machinery –adjudication

machinery- powers and duties of authorities- procedures-voluntary reference to

arbitration – award- strikes and lock outs-lay off- retrenchment- transfer and closing

down of the undertaking – penalties.

Unit IV The Trade Unions Act 1926- The payment of bonus Act 1965.

Unit V The Employees state insurance act 1948,- The Payment of Gratuity Act 1972

Text books

Elements of Mercantile Law-N.D.KAPOOR, Sultan chand&sons

Business and corporate law – p.c. tylsian , Tata McGraw- Hill edition

91  

VI Semester Part III Core Subject 4. Auditing

Unit I Introduction- meaning- objectives – difference between Accountancy and auditing –

advantages- limitations- Audit programme- Auditing working papers- preliminaries

before audit – test checking and routine checking.

Unit II Internal check – meaning- objectives- difference between internal control and internal

Audit- Advantages and disadvantages of internal check-internal check regarding cash,

purchases, purchase returns, sales and sales returns.

Unit III Vouching – meaning- objects- importance of vouchers- precautions to be taken by the

auditors while examining vouchers – vouching of various transactions.

Unit IV Verification of assets and liabilities – meaning- classification of assets- verification of

different types of assets- verification of liabilities.

Unit V Company auditor- appointment- qualification and disqualification removal of arditor-

status- rights – duties- and liabilities- auditors report content- kinds of auditor’s report-

general considerations for drafting report.

Text book 1. Auditing B.N.TandonS.Chand&co, new delhi.

2. Auditing Dr.T.R.Sharma, Sahitya publication, Agra

Reference Books: 1. Principles and Practice of Auditing- DinkarPagare, Sultan Chand& Sons, New

Delhi.

2. Text book of Auditing- Saxana, Reddy and Appannaiah, Himalaya Publishing

House

92  

Major Elective (1Coure) (any one) 1. Multimedia with Application

UNIT I Multimedia Fundamentals : Bsic Concepts – Multimedia applications design

consideration – multimedia application Goals and Objectives. Opportunities in multimedia productions – important in multimedia development – application designs and productions. UNIT – II

Multimedia applications, structure and organization, considering interface design – planning the production of your applications – creating multimedia building blocks. UNIT – III

Multimedia presentations building blocks: text – graphics. UNIT – IV

Video capturing – sound capturing – MIDI. UNIT – V

Structure and functions of authoring software – authoring software selection of authoring program – fundamentals of macro media directs 5.0 Text and Reference book:

1. Multimedia an introduction, John Villamil – Casa Nova, Louis Molina Prentice Hall/Macmillian Computer publishing reprint.

2. Multimedia: Making it works: sixth edition, Tay Vaughan, TMH.

LIST OF PRACTICAL’S:

1. To design a car with movement and sound effect in flash.

2. To create a simple presentation in flash.

3. To active new window/page using buttons in flash

4. To create a Text motion tweening in flash

5. To create a scrolling gallery in a page in flash

6. To Bouncing a ball with sound effect in flash

7. To create a scenery of rain in the frame in flash

8. To display the news Headlines letter by letter in flash

9. To Start a graphic animation at a specific frame in flash

10. To End Movie clip using script in flash

93  

Major Elective (1Course) (Any One)

2. RETAIL MANAGEMENT

Unit I: Introduction to retailing-nature and importance of retailing-contemporary retailing in

India and marketing challenges facing retailers-Strategic planning in retailing-owning or

managing Business-Wheels of retailing-retailing life cycle.

Unit II: Types of retailing institutions-retailing institutions by ownership-retailing institutions by

store based and non-store based-vertical marketing system-Traditional retailing.

Unit III: Strategic planning in retailing-understanding retailing environment-identifying and

understanding customers, information gathering, designing retail information system-

processing of information system and research.

Unit IV: Location and organizational decisions-Trading area analysis site selection -

organizational pattern in retailing- operational management-financial decisions- use of

technology.

Unit V: Merchandise Management-Buying and handling- product assortment decision-

Inventory Management- Merchandise pricing- Merchandise Labeling and packing-

Retail promotion- Retail promotion strategy- Building retail store image- Role of

atmosphere- retail promotion mix strategy- retail store sales promotion schemes.

Text Book: 1. Retailmanagement, Michael Levy and Barton A Weot, McGraw Hill Irwin,

Reference Books: 1. Retail management A Strategic Approach, Berman, Barry and Jeol R Evans,

Prentice Hall, New Jersey.

2. Retail management, Cox, Roger and Paul Brittain, Prentice Hall, Harlow.

3. Retailing Management-By Michael Levy, Barton A Weitz, Ajay Pandit-McGraw-

Hill.Com Company.

94  

Major Elective(1Course)(Any One) 3. Income tax law and practice-II

Unit I Income under the head-other sources-Computation –Problems.

Unit II Set off and carry forward of losses. Deductions from Gross total Income Problems.

Unit III Procedures for Assessment – Returns – Types of returns-Types of Assessment- Tax

Deducted at source.

Unit IV Assessment of Individual- Problems including computation of tax

Unit V Assessment of firm-Problems including Section 40 (b) applications.

Theory 40 problem 60

Text Book for reference 1. Income tax law and accounts- Dr.H.C.Mehrotra and Dr.P.Mehrotra

2. Income tax law and practice - V.P Gaur, D.B Narang, PoojaGhai and Rajeev

Puri.

95

APPENDIX - BA10

MANOMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI -12 CHOICE BASED CREDIT SYSTEM

COURSE STRUCTURE FOR B.COM Professional Accounting

(With effect from the academic year 2012-2013 ) III.B.Com (PA) – V Semester

Components Hours Credits Part – III – Core Subjects ( 3 courses)

1. Corporate Accounting II 2. Cost Accounting 3. Business law

7 7 6

5 5 6

Major Electives (1 course) (Any one) 1. Direct Tax – 1 2. Human Resource Management 3. Strategic Management

6

5

Common Skill Based Subject (1Course) (Any one)

1. Effective Communication 2. Personality Development

4

4

Total (5 Courses) 30 25 VI Semester

COMPONENTS HOURS CREDITS Part III – Core Subject (4 Courses)

1. Higher Financial Accountancy 2. Management Accounting 3. Accounting Standards 4. Industrial Law

6 6 6 6

5 5 5 5

Major Electives (1 Course) (Any one) 1. Direct Tax –II 2. Introduction to RDBMS (theory – 4

hrs, Practical- 2 Hrs) 3. Logistics Management

6

5

Total 30 25 Total number of courses :34 Total number of hours :180 Total number of credits :140 Distribution of marks in Theory between External and internal Assessment is75:25. pass

minimum of 40% for external and overall components.

96

B.Com (Professional Accounting) SYLLABUS UNDER CBCS With effect from the Academic Year 2012-2013

V Semester

Part III Core Subjects (3 Courses)

Core I: CORPORATE ACCOUNTING II

Unit – I: Final Accounts Company Final Accounts – Profit Prior to Incorporation

Unit – II: Holding Company Meaning and types of control – Rules for preparation of Consolidated Balance

Sheet – Calculation of Minority interest – Calculation of Cost of Control – Intercompany

transactions and intercompany Owings (Simple Problems Only)

Unit – III: Amalgamation and Absorption of Companies Amalgamation in the nature of merger and purchase – Absorption of company –

Calculation of purchase consideration – Treatment in the books of transferor and

transferee (as per Accounting Standard 14, excluding inter – company holdings)

Unit – IV: External and Internal Reconstruction Calculation of purchase Consideration under Net Payment and Net Asset

methods – Passing Journal Entries – Ledger preparation in the books of Vendor and

preparation of Balance Sheet after reconstruction incorporating all the concepts

mentioned in absorption – Internal Reconstruction or Capital Reduction: Meaning –

meaning – Objective – Procedure – form of reduction – accounting arrangements –

passing of Journal Entries – Preparation of Balance Sheet after Reconstruction.

Unit – V: Liquidation Voluntary Liquidation – Preparation of Liquidator’s Statement of affairs – order of

payment – calculation of commission on Assets Realized – payment to unsecured

creditors – payment to unsecured creditors other than preferential creditors – calculation

of pro rata – treatment of uncalled capital – liability of contributors.

Theory 40 % : Problem 60 % Reference Books:

1. T.S. Reddy, and A. Murthy, Corporate Accounting, Margham Publication, Chennai – 600017.

97

2. J.R. Monga, Fundamentals of Corporate Accounting, Mayoor Paperbacks c/o K.L. Malik and Sons Pvt. Ltd., 23- Darya Ganj, New Delhi.

3. R. L. Gupta, and M. Radhaswamy, Corporate Accounting, Sultan Chand and Sons, New Delhi.

4. M.C. Shukla, T.S.Grewal and S.C. Gupta, Corporate Accounting, S.Chand and Co., New Delhi.

5. S. N. Maheshwari, and S.K. Maheshwari, Corporate Accounting, Vikas Publication, New Delhi.

6. S. P. Jain and K.L. Narang, Advanced Accountancy, Vol. – II, Sultan Chand & Sons, and New Delhi.

7. Mukherjee and Hanif, Corporate Accounting, Tata McGraw Hill, New Delhi.

Core-2 COST ACCOUNTING Unit-I Cost Accounting-Nature-Meaning-Features and Importance Limitations of financial

Accounting-Advantages and limitation of Cost Accounting-CostingSystem-CodeCenter-

CostUnit-ElementsofcostCostClassifications-Cost Sheet.

Unit-II Material-Objectives-Purchase Control-Centralized and Decentralized Purchase-Stock

Levels and EOQ-ABC Analysis-Bin Card- Stores Ledger-Material Issue-FIFO, LIFO,

Average and Weighted Average methods.

Unit-III Labour-Direct and Indirect Labour-Method of Wage Payments-Remuneration and

Incentives-Premium and Bonus Plans-Idle Time-Over time-Labour Turnover.

Unit-IV Overhead-Meaning-Classification-Allocation and Apportionment of Overheads-Re-

apportionment-absorption of Overhead-Methods-Machine Hour rate (Simple Problems

only).

Unit-V Job Costing-Contract Costing (Simple Problems Only)-Process Costing-Features-

Process losses and gains.

Theory 40 % : Problem 60 % Text Books: Cost Accounting-S.P.Jain & K.L.Narang, Kalyani Publishers, New Delhi.

Cost Accounting-S.P.Iyengar, Sultan Chand & Sons, New Delhi.

Cost Accounting-S.N.Maheswari, Sultan Chand & Sons, New Delhi.

98

Books for Reference: Cost Accounting-Jawaharlal, Tata McGraw Hill Editions.

Cost Accounting-M.L.Agarwal, Sahitya Bhavan Publishers.

Cost Accounting-R.S.N.Pillai, Sultan Chand & Sons.

Cost Accounting Principles & Practice-Thukkaram Rao, New Age Publishers.

Core-3 BUSINESS LAW

Unit-I: Indian Contract Act, 1872-Fundamental essentials of a valid contract-classification of

contracts-offer-acceptance-consideration-capacity-free consent-legality of object-

contingent contracts.

Unit-II: Performance of contract-discharge of contract-breach of contract-remedies-Quasi

contracts.

Unit-III Special contracts-Indemnity-Guarantee.

Unit-IV Bailment-Pledge-contract of Agency.

Unit-V: Sale of Goods Act-Difference between sale and agreement to sell-sale and hire-

purchase agreement-classification of goods-documents of title to goods-Rights and

duties of buyers and sellers-Rights of unpaid seller.

Text Books 1. Business Law-N.D.Kapoor

2. Elements of Mercantile Law-N.D.Kapoor, Sultan chand & sons

3. Business Law-P.C.Tulsian, Tata Mc Graw-Hill edition

4. Business Law-R.S.N.Pillai, Bagavathi-S.Chand & Co, New Delhi.

Reference Book

1. Business and Corporate Law-P.C.Tulsian, Tata Mc Graw-Hill edition.

2. Business Law Including Company Law-S.S.Gulshan, G.K.Kapoor-New Age

International Pvt Ltd, New Delhi.

99

Major Electives: (One Course) (any one) 1. Direct Tax-I

Unit-I Important definitions in the Income Tax Act-concept of income, basis of charge,

previous year, assessment year, Gross total income, total income, residential status-

Distinction between capital and revenue receipts and expenditure-Basic of charge and

scope of total income: Incomes deemed to accrue or arise in India and deemed to be

received in India- Incomes which do not form part of total income.

Unit-II Computation of Total Income under the head Salaries and Computation of Total Income

under the head House Property.

Unit-III Computation Total Income under the head Income from Business or Profession

Unit-IV Computation Total Income from capital gains-Computation Total Income under the head

Income from other sources.

Unit-V Income of other persons included in assessee’s total income; aggregation of income

and set off or carry forward of losses; various deductions to be made in computing total

income, rebates and reliefs;

Books for Reference 1. Income Tax and practice-Mehrothra-Sultan Chand & Sons,

2. Direct Tax Law and practice-Dr.Vinod and K.Singhania-Tax Mann Publication

3. Income Tax and Practice-V.P.Gaur and D.B.Naran-Kalyani publishers.

2. HUMAN RESOURCE MANAGEMENT

Unit-I: Definition-concepts-objectives-charcteristics-funcions-principles of personal policies-

Organisational structure.

Unit-II: Manpower planning-definition-need-process job analysis-Job description-Job

specification-Job evaluation-recruitment and selection process.

100

Unit-III Employee training-need-Importance principles-Training methods-promotions-types-

procedures-promotion policy-demotion-transfer-dismissal-absenteeism-Labour

Turnover-Performance appraisal Methods.

Unit-IV Industrial relations-significance-causes of poor industrial relations-suggestions-labour

disputes and settlements-Industrial relations in India.

Unit-V: Workers participation in management-collective bargaining and industrial relations -

Employees grievance-procedures-industrial disciplinary system.

Books for Reference 1. Human Resource Management-Dr.C.B.Gupta, Sultan chand & sons.

2. Personal Management-C.B.Memoria Himalaya Publishing house.

3. Human Resource Development-Rand L.Decimore, Thomson Learning Third

Edition.

3. STRATEGIC MANAGEMENT

Unit-I Business Environment-General Environment-Demographic, Socio-Cultural. Macro

economic, Legal/political, Technological and Glopal competitive environment, Business

policy and Strategic Management-Meaning and nature; Strategic management

imperative vision, Mission and objectives; strategic levels in organizations.

Unit-II Strategic Analysis-Situational Analysis-SWOT Analysis, TOWS Matrix, potfolio Analysis-

BCG matrix Strategic planning-meaning, stages, alternatives, strategy formulation.

Unit-III Formulation of functional strategy-Marketing strategy, Financial Strategy, Production

strategy, Logistics strategy, Human Resource Strategy

Unit-IV Strategy Implementation and control-organizational structures; Establishing Strategic

business units; Establishing profit centers by business, product or service, market

segment or customer; Leadership and behavioural challenges

101

Unit-V Reaching strategic edge: Business process Re-engineering Bench marking, Total

Quality management, Six Sigma Contemporary Strategic Issues

Books for Reference 1. Business Policy and Strategic Management-P.Subba Rao-Himalaya Publishing

house

2. Strategic Management-Text and Cases-V.S.P Rao & V.Harikrishna-Excel Books

3. Quality Management-Howard S.Gitlow, Alan J.Oppenheim Rosa Oppenheim

Devid M.Levine-Tata Mc-Graw Hill.

4. Quality Management-K.Shridara Batt-Himalay Publishing house

5. Business Policy and Strategic Management-Azhar Kazhimi-Tat Mc-Graw Hill.

Common skill based subjects (1 Course) (Any one)

1. Effective Communication 2. Personality Development

VI Semester Part III Core Subjects – 4 Courses

Core – 1 – HIGHER FINANCIAL ACCOUNTANCY Unit 1: Accounts of Banking Companies Meaning of Banking Company – Accounting treatment of Rebate on bills

discounted – Ascertainment of Non – Performing Assets – Classifications of Assets

(advances) – Preparation of Final Accounts as per the existing Banking Regulation Act

(Simple Problems Only)

Unit 2: Accounts of Life Insurance Companies Meaning – Insurance terms – Premium – Consideration for annuities granted –

Policies becoming claims – reinsurance – surrender value and paid-up value – bonus –

cash bonus – bonus in reduction of premium – reversionary bonus – valuation –

preparation of Revenue Account applicable for life insurance business – balance sheet

of a life insurance company – Preparation of valuation Balance Sheet ( Simple

Problems Only)

102

Unit 3: Accounts of General Insurance Companies (Fire and Marine) Meaning – General Insurance Revenue Account for Fire and Marine – Treatment

of reserve or provision to be carried forward – Preparation of Profit and Loss Account in

Form B – Preparation of Profit and Loss Appropriation Account in Form C – Preparation

of Balance Sheet. (Simple Problems Only)

Unit 4: Special Accounts Educational Institutions, Hotels, Hospitals, Solicitors.

Unit 5: Inflation Accounting Meaning –Different methods of Inflation Accounting - Current Purchasing Power

Method (CPP) – Current Cost Accounting Method (CCA) – Accounting for Human

Resource.

Theory 40 % : Problem 60 % Reference Books:

1. T.S. Reddy, and A. Murthy, Corporate Accounting, Margham Publication, Chennai – 600017.

2. J.R. Monga, Fundamentals of Corporate Accounting, Mayoor Paperbacks c/o K.L. Malik and Sons Pvt. Ltd., 23- Darya Ganj, New Delhi.

3. R. L. Gupta, and M. Radhaswamy, Corporate Accounting, Sultan Chand and Sons, New Delhi.

4. M.C. Shukla, T.S.Grewal and S.C. Gupta, Corporate Accounting, S.Chand and Co., New Delhi.

5. S. N. Maheshwari, and S.K. Maheshwari, Corporate Accounting, Vikas Publication, New Delhi.

6. S. P. Jain and K.L. Narang, Advanced Accountancy, Vol. – II, Sultan Chand & Sons, and New Delhi.

7. Mukherjee and Hanif, Corporate Accounting, Tata McGraw Hill, New Delhi.

103

2. MANAGEMENT ACCOUNTING

Unit-1 Management accounting-definition-objectives-nature, scope, function-management

accountingVS financial accounting-management accounting VS cost accounting-

Advantages-Limitations of management accounting.

Unit- 2 Accountingratio-meaning-significance-types-various ratios like profitability, Slovence

and liquidity. Fund flow and cash flow analysis-meaning-differences between fund flow

statement and cash flow statement-funds preparation of fund flow statement and cash

flow statement.

Unit-3 Marginal costing-meaning-features-assumption contributions-p/v ratio-CVP analysis-

break-even analysis-assumption-advantages-limitations-margin of safety.

Unit-4 Standard costing-meaning of standard cost and standard costing-standard costing and

budgetary control-advantages and limitations-analysis of variance-direct material, direct

labour and overhead.

Unit-5 Budget and budgetary control-meaning of budget, budgeting and budgetarycontrol-

objectives-features-advances-limitations-flexible budget-cash budget-production

budget-purchase budget-sales budget.

Theory: 40 Marks : Problem : 60 Marks Text Books:

1. Management accounting S.M.Maheswari, Sultan Chand & sons 2. Management accounting R.S.N.Pillai & Bhagawathi, S.Chanf & co 3. Management accounting principles and practice-R.K.Sharma and K.Gupta,

Kalyani publishers. Reference Books:

1. Management accounting-M.Y.Khan and P.K.Jain tata McGraw hill edition. 2. Management accounting S.P.Gupta, Sultan Chand and co 3. Principles of management accounting-Man Mohan and Goyal, Sahitya Bhawan

Publication. 4. Management accounting-M.Wilson, Himalaya Publishing house.

104

Core 3: Accounting Standards Unit I Indian Accounting Standard: Meaning-Rationale of Accounting Standards-Objectives of

Acccounting Standards-Who issues Accounting Standards in India? Accounting

Standard-setting in India-Composition of the Accounting Standards Board-Accounting

Standards-setting Process-Compliance with Accounting Standards-Duty of Statutory

Auditor for Compliance with Accounting Standards-Number of Accounting Standards

prescribed-Applicability of accounting standard-Level I, II and III companies

Unit II Basic Knowledge Working Knowledge of: AS 1: Disclosure of Accounting Policies, AS 2:

Valuation of Inventories, AS 3: Cash Flow Statements, AS 4: Contingencies and Events

occurring after the Balance Sheet Date, AS 5: Net Profit or Loss for the Period, Prior

Period Items and changes in Accounting Policies and

Unit III Basic knowledge Working knowledge of: AS 6: Depreciation Accounting, AS 7:

Construction Contracts AS 9: Revenue Recognition, AS 10: Accounting for Fixed

Assets, AS 11: Effect of Changes in Foreign Exchange Rates AS 12: Accounting for

Government Grants, AS 13: Accounting for Investments

Unit IV Basic knowledge Working knowledge of: AS 14: Accounting for Amalgamations, AS 16:

Borrowing Costs AS17: Segment Reporting AS18: Related Party Disclosures AS 19:

Leases

Unit V Basic knowledge Working knowledge of: AS20: Earning per Share, AS 26: Intangible

Assets, AS28 Impairment of Assets, AS 29: Provisions, Contingent Liabilities and

Contingency Assets-

Books for Reference 1. S.P.Jain and K.L.Narang Advanced Accounting, Kalyani Publishers, New Delhi. 2. R.L.Gupta, and M.Radhaswamy, Advanced Accountancy, Vol-II, Sultan Chand &

Sons, New Delhi.

3. SP lyengar, Advanced Accountancy

4. Tulsian, Advanced Accounting

105

Core-4 INDUSTRIAL LAW

Unit-I Factories act 1948

Unit-II the Workman compensation Act 1923

Unit-III Consumer protection and Regulation Act 1986

Unit-IV The Employee’s State Insurance Act 1948

Unit-V The payment of gratuity Act, 1972. The Industrial Disputes Act 1947

Books for Reference: 1. Business Law-N.D.Kapoor-Sultan chand

2. Mercantice Law for CA. Common proficiency-P.C.Tulsian-Tata McGraw Hill

Publishing Co., Ltd.,

3. Business Law-R.S.N.Pillai & Bhagawathi-S.Chand

MAJOR ELECTIVES Core 1: Direct Tax II

Unit I Assessment of Individual - Firm and association of persons (excluding companies) –

Applicable rates of taxes and tax liability – Provisions concerning procedure for filing

returns, signatures, e-filing, assessment and reassessment, advance payment of Tax,

deducted at source, collection, recovery and refund of tax.

Unit II Banking Cash Transaction Tax Charge of banking cash transaction tax, taxable banking

transaction, value of taxable banking transaction, collection, recovery, return,

assessment, and rectification, interest on delayed payments, penalty, appeal and power

to make rules.

Unit III Fringe Benefit Tax: Charge of fringe benefit tax, fringe benefits and deemed fringe

benefits, valuation, payment and return of fringe benefits, assessment, issue of notice,

advance tax in respect of fringe benefits.

106

Unit IV Securities Transaction Tax (STT): Introduction – Definition of Securities – Meaning of

Security as per SCRA – Transaction Tax – Items fall under the category of securities –

Basis of charge – Rate of Securities Transaction Tax on Capital Gains – Securities

Transaction Tax on Sale and Purchase of securities – STT Computation – Tax

exemptions in regards to short term and long term capital gains – procedure is adopted

by the Exchange in respect of the calculation and collection of STT

Unit V Wealth Tax: Charge of wealth tax; assets; deemed assets and assets exempt from tax;

valuation of assets; computation of net wealth, return of wealth, return of wealth and

provisions concerning assessment.

Books for reference 1. Income Tax and Practice – Mehrothra – Sultan Chand & Sons

2. Direct Tax Law and Practice – Dr.Vinod and K. Singhania – Tax Mann

Publication

3. Income Tax and Practice – V.P Gaur and D.B. Naran – Kalyani publishers.

2. INTRODUCTION TO RDBMS

Unit-I: Introduction to Data Base Management Systems

Definition and Quality of Information-Information Processing-File Based Data

Management and its Disadvantages-Meaning and advantages of Database System-

Organisation of Database and Characteristics of Database-Meaning and Functions of a

Database Management System- Components of a DBMS

Unit-II: Data Models Basic understanding of Hierarchical model, network model, Relational Model-Entity

Relationship model, Object-Oriented Model-Advantages and Disadvantages of Various

Data Model-components of E-R. Model, Entities Attributes and Relationships-Relational

Database Management System RDBMS Terminology-Codd’s Rule-Relational Data

Integrity and Database Constraints

107

Unit-III: Structured Query Language (SQL) Introduction to Oracle9ii-Features of Oracle-Overview of SQI-SQI*Plus Environment-

Types of SQI Statements-DDL, DML, DQL, DCI and TCS Statements-SQI Operators-

Tables, Views and Indexes-Creating, Modifying and deleting Table-Creating Views,

Data Query and Manipulation Operations with views and Check options-Why uses and

Index, creating and Dropping index-Unique key-Primary Key-Foreign key-check

constraints INSERT, UPDATE and DELETE Operations

Unit-IV: Queries and Sub queries Retrieving data from database tables-Using the SELECT statement-using the WHERE

clause, GROUP BY clause, HAVING clause and ORDER BY clause Qualified Retrieval-

Using DISTINCT, IN, BETWEEN, LIKE, ESCAPE clause Grouping while selecting-

Ordering while selecting-Sub query and Its execution-Nested Subquery-Parallel

subquaries-Correlated sub queries Aggregate functions provided by SQI-Joins and

Unions operations

Unit-V: Database Security Data Security Risks-Dimensions of Database security-Data Security Requirements-

Protecting the data within the Database: Database Privileges, Roles and its properties-

Granting and Revoking privileges and Roles-GRANT and REVOKE Command-

Database Users: Database users-Database Administrators, Database Designers, End

users-Casual End users, Naïve or Parametric End users, Sophisticated End users and

Standalone end-users

References: 1. David Maier: The Theory of Relational Database, Computer Science Press,

Rockville, MD.

2. Database system concepts, A.Silberschatz, H.F.Korth, S.Suaarshan, McGraw-

Hill

3. T.Hawryszkiewycz, Database Analysis and Design, Science Research

Associates, Chicago, Illinois

4. Essentials of Database Management Systems, Alexis Leon and Mathews Leon,

Vijay Nicole Imprints (P) Ltd., Chennai.

108

3. LOGISTICS MANAGEMENT Unit-I: Logistics - Meaning-Importance - Logistical Competency - Logistical Mission - Service -

Total Cost - Logistical Renaissance - Technological Advancement - Regulatory Change

- IT Revolution-TQM initiatives

Unit-II: Work of Logistics - Network design - information - Transportation and Inventory –

Warehousing - material handling - packaging - integrated Logistics-Inventory flow-

Information flow

Unit-III: Operating objectives-Rapid response-minimum variance-minimum inventory-movement

consideration-quality-Life cycle support-barriers to internal integration in organizational

structure-measurement system-inventory ownership-information technology-knowledge

transfer capacity

Unit-IV: Information functionality-and inventory functionality-principles of logistics information-

Information Architecture-planning-operations-Logistics Information flow-application of

new information technologies-electronic data interchange standards-inventory-

determining order point-lot size-accommodating uncertainty-replenishing ordering and

warehousing management

Unit-V Transportation infrastructure-transport functionality-principles-modal classification-

transportation formats-suppliers of transportation service-storage functionality-

principles-concept of strategy

Reference Books: 1. Logistical Management (Integrated supply chain Process) – By Donald J

Bowersox, David J.Closs-Tata McGraw-Hill edition

2. Supply chain Logistics Management-By Donald J.Bowersox, David J.Closs, and

M.Bixby Cooper-Tata.

109

 

APPENDIX - BA11 MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI -12

CHOICE BASED CREDIT SYSTEM COURSE STRUCTURE FOR

B.COM Corporate Secretaryship (With effect from the academic year 2012-2013 onwards)

III.B.Com (CS) V Semester

Components Hours Credits Part-III- Core Subjects (3 Courses) 1.Corporate Accounting I 2.Cost Accounting 3.Business Law

7 7 6

5 5 6

Major Elective (1 Course) (Any One) 1. Income Tax ,Law & Practice I 2.Applications of Tally in Accounting (Theory 4 hours, Practical 2 hours) 3.Logistics Management

6

5

Common Skilled Based Subject (1 Course) (Any One) 1. Effective Communication 2.Personality Development

4

4

Total (5 Courses) 30 25 III B.Com (CS) VI Semester

Components Hours Credits Part-III - Core Subjects (4 Courses) 1.Corporate Accounting II 2 Management Accounting 3.Industrial Law 4.Auditing

6 6 6 6

5 5 5 5

Major Elective ( 1Course) INSTITUTIONAL TRANING 6 5

Total ( 5 courses) 30 25 Total number of courses :34 Total number of hours :180 Total number of credits :140 Distribution of marks in Theory between External and Internal Assessment is75:25 pass minimum of 40% for external and overall components.

110

 

B.Com (C.S) Course – SYLLABUS UNDER CBCS With effect from the Academic Year 2012-2013

V Semester Part III Core Subjects

(3 Courses) 1. Corporate Accounting I

Unit -1 Issue of shares-issue at par, premium and discount- calls in arrears- calls in advance-

Forfeiture and reissue of shares-Prorata allotment- redemption of preference shares-

issue of Bonus shares.

Unit II Issue of debentures - redemption of debentures- sinking fund method-Underwriting of

shares.

Unit III Profit prior to incorporation – alteration of share capital and internal reconstruction-

Accounting entries.

Unit IV Valuation of goodwill and shares- various methods of valuation of goodwill and shares.

Unit V Amalgamation, absorption, and external reconstruction- calculation of purchase

consideration – In the books of Vendor and purchaser.

Theory 40 Marks: Problem 60 Marks Text and Reference Books:

1. advanced Accountancy Volume II-S.P. Jain & K.L.Naranag-Kalyani Publishers,

New Delhi

2. Advanced Accountancy Volume II – R.L.Gupta and M.Radhaswamy – Sultan

Chand & sons, New Delhi.

3. Advanced Accountancy Volume II – M..Shukla and T.S.Grewal – S.Chand

&co,New Delhi.

111

 

2. Cost Accounting Unit I Cost accounting-Nature- Meaning – Features and importance limitation of financial

accounting-advantages and limitation of cost accounting – costing system-cost centre-

cost unit- elements of cost- cost classification – cost sheet.

Unit II Materials –objectives- purchase control- centralized and decentralized purchase – stock

levels and EOQ-ABC Analysis-Bin card- stores ledger- Material issue – FIFO, LIFO,

Average and weighted average methods

Unit –III Labour- Direct and indirect labour – methods of wage payments- remuneration and

incentives – premium and bonus plans- Idle time- over time- labour turnover.

Unit IV Overhead- Meaning- classification- allocation and apportionment of overheads- re

apportionment of over heads-absorption of over head- methods- machine hour rate.

Unit V Job costing (simple problems only) – process costing –features- process losses and

gains.

Theory 40 Marks: Problem 60 Marks Text Books:

1. Cost Accounting-S.P.Jain&K.L.Narang, Kalyani Publishers, New Delhi.

2. Cost Accounting – S.P.Iyengar, Sultan Chand & Sons, New Delhi.

3. Cost Accounting – S.N.Maheswari, Sultan Chand & Sons, New Delhi

Books for Reference: 1. Cost Accounting – Jawaharlal, Tata McGraw Hill Editions

2. Cost Accounting – M.L.Agarwal, Sahitya Bhavan Publishers

3. Cost Accounting – R.S.N.Pillai, Sultan Chand & Sons

4. Cost Accounting Principles & Practice – Thukkaram Rao, New Age Publishers.

112

 

3. Business Law Unit I Indian contract Act 1872-Fundamental essential of a valid contract- classification of

contract- offer acceptance- consideration- capacity-free consent – legality of object –

contingent contracts.

Unit II Performance of contract- discharge of contract- breach of contract- remedies-Quasi

contracts.

Unit III Special contracts- Indemnity – Guarantee

Unit IV Bailment – pledge- contract of agency.

Unit V Sale of Goods Act- Difference between sale and agreement to sell- sale and hire

purchase agreement- classification of goods-documents of title to goods- Rights and

duties of buyers and sellers – Rights of unpaid seller.

Text books 1. Business law- N.D.Kapoor

2. Element of Mercantile Law- N.D.Kapoor,sultanchand& sons

3. Business Law-P.C.Tulsian, Tata McGraw- Hill station.

4. Business Law-R.S.N.Pillai, Bagavathy- S.Chand&Co,New Delhi.

Reference Books: 1. Business and Corporate Law- P.C.Tulsian, Tata McGraw- Hill station. 2. Business Law including Company Law- S.S.Gulshan, G.K.Kapoor- New age

International Pvt Ltd, New Delhi.

113

 

Major Elective (1Course) (Any One) 1. Income tax law and practice –I

Unit I Basic concepts – Person, assessee, previous and assessment year, total income, gross

total income – concept of income – Agricultural Income- Income exempted from tax –

Residential Status- problems.

Unit II Income from salary –different forms of salary and allowance – perquisites – problems in

computation of salary income.

Unit- III Income from House property – Annual value – Standard deduction– Unrealized rent –

problems in computation of house property income.

Unit –IV Income from under the Head – Business or profession – deduction allowable –

Expressly disallowed expenses – computations – problems in computation of business

or professional income.

Unit – V Income from capital gain - Types - Exemption- Computation- problems in computation

of capital gain.

Theory 40% : Problem 60 % Text Book for reference 1. Income tax law and accounts- Dr.H.C.Mehrotra and Dr.P.Mehrotra

2. Income tax law and practice - V.P Gaur, D.B Narang, PoojaGhai and Rajeev

Puri.

114

 

2. Application of TALLY in Accounting

UNIT 1: Introduction to Tally, company and Accounting Information Menu Tally features

– Technological advantages of tally accounting software – tally screen components –

Gateway of Tally – company information menu – creating a company – Accounting

information menu – concept of groups in Tally-Managing and operating groups –

Managing and operating Ledgers UNIT II: Managing and Operating vouchers

Meaning of voucher – predefined voucher in tally, Accounting vouchers, Inventory

vouchers and unconventional vouchers – Entering transaction in vouchers

UNIT III: Managing and Operating Inventory Information Menu F11 Features-F12

Configuration –Stock items, Units of measure, Stock groups, stock categories, Godown,

price list, inventory vouchers

UNIT IV: Tally Reports

Reports which can be accessed from gateway of Tally under “Reports, Reports which

can be accessed through the menu “Display” under report – Export and import of data –

printing reports- Tally ODBC

UNIT V: Tally Advanced Financial Management and Control

Preparation of Bank Reconciliation Statement, Fund Flow Statement, Brach Accounting,

Flexible period accounting, Budgeting and Control, Variance Analysis and Ratio

Analysis

Reference Books 1. Tally User Manual, Tally Solutions (p) Limited

2. Tally- Nadani

3. Tally – NamrataAgrawal

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Application of TALLY in Accounting List of Practical

Answer any ONE question 1. Create an ‘Accounts With Inventory Company’ by Activating the necessary F11

company features-Change the address of the company – Convent it into

‘Account only Company’-Delete the Created Company

2. Operating of necessary ledger account from the given Trial balance and prepare

Final accounts

3. Accounting voucher posting from the given transaction and Display of Day Book

and alteration in Day Book

4. Accounting voucher posting for the given transaction and preparation of final

accounts with adjustments

5. Create necessary Stock Group, Stock Item and Units of Measure, Godown and

making inventory voucher posting and Display the Stock Summary and Individual

Stock Item Report

3. Logistics management Unit I Logistics- meanings- importance-logistics competency- logistical mission – service-

total-cost- logistical renaissance- technological advancement- regulatory change- IT

Revolution- TQM Initiatives.

Unit II Work of logistics- -network design- information- transportation and Inventory-

warehousing – material handling- packaging- integrated logistics- Inventory flow –

Information flow.

Unit III Operating objectives- rapid response- minimum variance –minimum inventory –

movement consideration- quality- life cycle support- barriers to internal integration in

organizational structure – measurement system- inventory ownership – information

technology- knowledge transfer capacity.

116

 

Unit IV Information functionality- and inventory functionality- principles of logistics information-

information architecture-planning –operations- logistics information flow – application of

new information technologies – electronic data interchange standards- inventory

functionality- inventory types- characteristics- cost of carrying inventory- determining

order point-lot size- accommodation uncertainty- replenishing ordering and ware

housing management.

Unit V Transportation infrastructure- transport functionality- principles- modal classification-

transportation formats- suppliers of transportation services- storage functionality-

principles –concept of stratigice storage – developing warehouse resource- warehouse

4 strategy

Text books Logistical management (Integrated supply chain process-by DonaldJbowersox,

davidJcloss- Tata Mcgraw –Hill edition

117

 

Common skilled based subjects(1Course)(Any One) 1. Effective Communication 2. Personality Development

B.Com (C.S) Course – SYLLABUS UNDER CBCS With effect from the Academic Year 2012-2013

VI Semester Part III Core Subjects – 4 Courses

1. Corporate Accounting-II Unit –I Liquidators’ final statement- contributory.

Unit –II Holding companies- minority interest- capital profits- cost of control or goodwill-

preparation of consolidated balance sheet.

Unit –III Banking companies-Format of balance sheet and profit and loss account as per sec 29

of Banking Regulation Act.

Unit – IV Double account system- meaning-difference between double account and single

account system- difference between double account- and double entry system-

preparation of final accounts- capital base disposal of surplus- calculation of reasonable

return- replacement of assets.

Unit V Accounting ratios- responsibility accounts- human resource accounting.

Theory 40 Marks % : Problem 60 Marks% Text books Advanced Accountancy Dr. M.A Arulanandam Dr. K.S.Raman Advanced accountancy S.P.Jain K.L.Narang Advanced Accountancy M.C.Shuckla

118

 

2. Management Accounting

Unit I Management accounting- Definition- Objectives- Nature, scope, function-management

accounting Vs financial accounting-Management Accounting vs cost accounting-

advantages-limitations of management accounting.

Unit II Fund flow and cash flow analysis- meaning –Difference between fund flow statement

and cash flow statement- funds- preparation of fund flow statement and cash flow

statement.

Unit III Marginal costing –meaning- features-assumption- contribution P\V Ratio-CVPanalysis-

Break even analysis-Assumption- Advantages – limitations- margin of safety.

Unit IV Standard costing- meaning of standard cost and standard costing standard costing and

budgetary control- Advantages and limitations- analysis of variance- Direct material,

direct labour and overhead.

Unit V Budget and budgetary control- meaning of budget , budgeting and budgetary control-

objectives- features- advantages –limitations- flexible budget- cash budget- production

budget – purchase budget – sales budget.

Theory 40 Marks : Problem 60 Marks Text books: 1. Management accounting S.M. Maheswari sultan chand and sons.

2. Management accounting.R.S.N.Pillai&Bhawathi ,S.Chand&co

3. Industrial Law

Unit I The factories Act 1948 – Definitions– approval, licensing and Registration of Factories

– duties of occupier – Inspection staff- certifying surgeons- provisions for health- safety-

welfare- working hours and holidays- employment of young persons and women-

Annual leave with wages- penalties and procedure.

119

 

Unit II Workmen’s compensation Act 1923 – scope and coverage- definitions- rules- personal

injury by accident- occupational disease- arising out of and in the course of employment

– theory of notional extension- amount of compensation- distribution of the

compensation- notice and claim.

Unit III Industrial disputes Act 1947 –object- definitions- conciliation machinery –adjudication

machinery- powers and duties of authorities- procedures-voluntary reference to

arbitration – award- strikes and lock outs-lay off- retrenchment- transfer and closing

down of the undertaking – penalties.

Unit IV The Trade Unions Act 1926- The payment of bonus Act 1965.

Unit V The Employees state insurance act 1948,- The Payment of Gratuity Act 1972

Text books

Elements of Mercantile Law-N.D.KAPOOR, Sultan chand&sons

Business and corporate law – p.c. tylsian , Tata McGraw- Hill edition

4. Auditing

Unit I Introduction- meaning- objectives – difference between Accountancy and auditing –

advantages- limitations- Audit programme- Auditing working papers- preliminaries

before audit – test checking and routine checking.

Unit II Internal check – meaning- objectives- difference between internal control and internal

Audit- Advantages and disadvantages of internal check-internal check regarding cash,

purchases, purchase returns, sales and sales returns.

Unit III Vouching – meaning- objects- importance of vouchers- precautions to be taken by the

auditors while examining vouchers – vouching of various transactions.

120

 

Unit IV Verification of assets and liabilities – meaning- classification of assets- verification of

different types of assets- verification of liabilities.

Unit V Company auditor- appointment- qualification and disqualification removal of arditor-

status- rights – duties- and liabilities- auditors report content- kinds of auditor’s report-

general considerations for drafting report.

Text book 1. Auditing B.N.TandonS.Chand&co, new delhi.

2. Auditing Dr.T.R.Sharma, Sahitya publication, Agra

Reference Books: 1. Principles and Practice of Auditing- DinkarPagare, Sultan Chand& Sons, New

Delhi.

2. Text book of Auditing- Saxana, Reddy and Appannaiah, Himalaya Publishing

House

Major Elective(1Course) Institutional Training

Objective: To give practical exposure regarding the secretarial functions relating to a

corporate organization. Supervised Institutional Training shall be an integral part of the Course. It is to be

a sort of job testing programme to bridge the gap between theory and practice. It is designed to create a natural interest in the practical aspects of the Company Secretary ship.

The training should be given under the joint supervision and guidance of the Training Officer of the Institution and Faculty member of Corporate Secretary ship of the College. The details of the training given and the assessment of each student in that regard should be fully documented.

The duration of the training shall be for a period of 30 days during the third year. The training shall broadly relate to

a) Office Management b) Secretarial Practice

121

 

The training relating to Office Management may be designed to acquaint the trainees

with.

1. Company’s activities, organization structure, department and authority

relationship

2. Study of layout, working conditions, office maintenance, safety and sanitary

conditions.

3. Study of the Secretarial service, communication, equipments, postal and mailing

services and equipments.

4. Acquaintance with office machines and equipments and accounting, machines.

5. Acquaintance with filing department, sales, purchases, Sales accounts, salary,

administration and personnel departments.

The training pertaining to Secretarial Practice shall be on all aspects of the functions

of a corporate secretary.

The training pertaining to Secretarial Practice shall be on all aspects of the functions

of a corporate secretary.

The following types of organizations may be selected for the training.

1. Public limited Companies (Both Industrial and Commercial)

2. Statutory bodies, Public Enterprises and Public Utilities like L.I.C, Electricity Board,

Housing Board and Chambers of Commerce, Cooperative Societies and banks.

3. Office Equipment Marketing Organizations.

Note: The paper on Institutional Training shall carry 100 marks. Internal and External

Viva-Voce shall be based on the report submitted by the candidate, under the guidance

of the faculty member of the department.

The report shall be around 50 typed pages, excluding tables, figures,

bibliographies and appendices. The department of the respective college shall value the

report. A candidate failing to secure the minimum for a pass (40%) shall be required to

resubmit this report to the department.

The external examiner and the internal examiner should jointly conduct viva-

Voce and evaluate the report. The maximum marks for the project report will be 75 and

25 for the viva-voce.

122

 

Model Question

SECRETARIAL PRACTICE (Total Marks 75)

SECTION - A

Choose the Correct answer (10X1=10 Marks)

1. The term secretary is originated from the word _-----------

(a) Secret (b) Secretarian

(c) Secrecy (d) Secretarius

2. The secretary of a company is, its ----------------

(a) Office Manager (b) Managing Director

(c) Chief Administrative Officer (d) General Manager

3. The Proper authority for convering a general meeting of the shareholders of a company is ---------------------

(a) Board of Directors (b) Shareholders

© Managing Directors (d) Company Secretary

4. A meeting of board of directors must be held at least once in every ------------

(a) Two months (b) Three months

© Five months (d) Six months

5. Ordinary resolution is passed with ----------------------

(a) Simple majority (b) 2/3 rd majority

© 1/3 rd majority (d) 3/4 rd majority

6. ------------- companies must convene the statutory meeting compulsorily

(a) Private (b) Holding

© Public (d) All

123

 

7. The right of a company to have lien on shares is conferred by

(a) Companies Act, 1956 (b) Memorandum of Association

© Contract with shareholders (d) Articles of Association

8. Call on shares can be expressed as -----------

(a) demand for money (b) obligatory

© debit due (d) all the above

9. In order to make the transfer of share a valid one it must be registered with the

(a) Government (b) company

© Court (d) Registrar

10. The rate of divided is fixed by the

(a) Board of Directors (b) Company Secretary

© Share holders (d) Managing Director

SECTION B (5x5 = 25 Marks)

11. (a) What are the rights of a company secretary

Or

(b) Define the term Secretary. Why a secretary is needed for a company ?

12. (a) Draft the specimen of the notice of the Annual General meeting of a company

Or

What are the different objects of convening statutory meeting?

13 a) What are the different kinds of resolution? Explain them with examples. Or

(b) What is Voting by poll ? Who can demand a poll?

14. (a) Enumerate the procedure for manking a call on a share. Or

(b) Describe the duties of company secretary relating to surrender of shares.

124

 

15. (a) On what grounds can transfer of share be rejected? Or

(b) What are the secretarial duties regarding payment of divided?

SECTION-C (5x8 = 40 Marks)

16. (a) Describe the legal provisions to be followed in the appointment of a company secretary.

Or

(b) Critically analyse the legal positions of the Secretary in a company.

17. What are the duties of the secretary regarding the extra-ordinary general meeting?

Or

(b) List down and explain the statutory provisions releating to conventing Annual General Meeting.

18. Explain the rules relating to drafting of minutes.

Or

What are the rights and powers of the Chairman of a meeting?

19. As a company secretary, explain the arrangement that you may have to make in connection with the allotment of shares.

Or

(b) What are the duties of the secretary relating to the formatting of a computer?

20. What is divided? Explain the legal rules to be follwed in relation to divided. Or

(b) Explain the duties of a Secretary in maintaining the Register of Members.

125

APPENDIX - BA12

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI -12

B.C.A Degree Course under CBCS 3 years - 6 Semesters - Course

Syllabus for V & VI Semester for those who joined the course from the academic year 2012-2013

Scheme of Examinations for V & VI Semesters

V SEMESTER

S.I.NO Components Subjects Hours Credits

1 Part-III

Core – Theory Software Engineering 4 4

2

Part-III Core – Theory

Web Technologies

4

4

3 Part-III

Core - Theory RDBMS 4 4

4 Part-III

Core - Practical RDBMS—Lab 8 -----

5 Major Elective Elective-I 6 5 6 Part-IV Skilled Based Subject 4 4

Total (5 Theory +1 practical = 6 Courses) 30 21 Note: Practical Credits are added in the even semester due to Year-wise Practical Exam

LIST OF ELECTIVE PAPERS:

OPTIONAL-II (Choose any one) 1. Artificial Intelligence. 2. Software Project Management. 3 . Mobile Communication.

126

VI SEMESTER

S.I.NO Components Subjects Hours Credits

1 Part-III

Core – Theory Operating System 4 4

2 Part-III

Core – Theory Data Mining

4

4

3 Part-III

Core – Theory Software Testing. 4 4

4 Part-III

Core – Theory Graphics & Multimedia 4 4

5 Part-III

Core – Practical Graphics & Multimedia-

LAB 8 4

6 Major Elective Elective-III 6 5

Total (5Theory +1 practical = 6 Courses) 30 25

Total Credits = 25 + V Semester Lab (Part-III Core – Practical- 4Credits) = 25 + 4 =29 Credits

LIST OF ELECTIVE PAPERS:

OPTIONAL-I (Choose any one)

1. Web services. 2. Cyber Security 3. Mobile OS.

127

V SEMESTER CORE SUBJECT – 1

SOFTWARE ENGINEERING

Unit I Software and Software Engineering: The Nature of software - What is software engineering? - Software engineering as a branch of the engineering profession - Stake holders in software engineering - Software quality - Software engineering projects - Activities common to software projects - Difficulties and risks in software engineering as a whole. Review of Object Orientation: What is object orientation/ - Classes and objects - Instance variables - Methods, Operations and polymorphism - Concepts best define object orientation - Difficulties and risks in programming language choice and object - oriented programming. Unit II Developing Requirements: Domain analysis - The starting point for software projects - Defining the problem and the scope - What is a requirement? - Types of requirements - Some techniques for gathering and analyzing requirements - Managing changing requirements - Difficulties and risks in domain and requirements analysis. Unit III Modeling with Classes: What is UML? - Essentials of UML class diagrams - Associations and Multiplicity - Generalization - Instance diagrams - More advanced features of class diagrams. Modeling Interactions and Behaviour: Interaction diagrams - State diagrams - Activity diagrams.

128

Unit IV Architecting and Designing Software: The process of design - Principles leading to good design - Techniques for making good design decisions - Software architecture - Architectural patterns - Writing a good designing document. Unit V Testing and Inspecting to Ensure High Quality: Basic definitions - Effective and efficient testing - Defects in ordinary Algorithms - Defects in numerical algorithms - Defects in timing and co-ordination: Deadlocks, livelocks and critical races - Defects in handling stress and unusual Situations. Managing the Software Process: What is project management? - Software process models - Cost estimation - building software engineering teams - Project scheduling and tracking. Text Book Object Oriented Software Engineering, Timothy C.Lethbridge and Robert Laganiere, TMH 2004 Reference Books

1. Object Oriented and Classical Software Engineering, Fifth Efition, Stephen, R.Schach, TMH

2. Fundamentals of Software Engineering, Second Edition, Cario Ghezzi, Medhi Jazayeri, Dino Mandrioli, PHI

CORE SUBJECT – 2

WEB TECHNOLOGIES

Unit I Introduction to the Web:Understanding the Internet and World Wide Web – History of the Web – Protocols Governing the Web – Creating Websites for Individuals and the Corporate World – Web Applications – Writing Web Projects – Identification of Objects – Target Users – Web Team – Planning and Process Development – Web Architecture – Major Issues in Web Solution Development – Web Servers (Apache Web

129

Server) – Web Browsers (Microsoft Internet Explorer and Netscape Navigator) – Internet Standards – TCP/IP Protocol Suite – IP Address – MIME – Cyber Laws. Hyper Text Transfer Protocol (HTTP):Introduction - Web Servers and Clients – Resources – URL and its Anatomy – Message Format – Example – Persistent and Non – persistent – Web Caching – Proxy. Unit II Hyper Text Markup Language (HTML):History of HTML and W3C – HTML and its Flavors – HTML Basics – Elements, Attributes, and Tags - Basic Tags – Advanced Tags-Frames. Cascading Style Sheet (CCS):Introduction – Advantages – Adding CSS – Browser Compatibility – CSS and Page Layout – Selectors. Unit III JAVA Script:Introduction – Variables – Literals – Operators – Control Structure – Conditional Statements – Arrays – Functions – Objects. JavaScript Regular Expression:Introduction. Unit IV Extensible Markup Language (XML):Common Usage – Role of XML – Prolog – Body – Elements – Attributes – Validation – Displaying XML – Namespace. XML DTD:XML Schema Languages – Validation – Introduction to DTD – Purpose of DTD – Using a DTD in an XML Document – Element Type Declaration – Attribute Declaration. Unit V Common Gateway Interface (CGI):Internet Programming Paradigm – Server – side Programming – Languages for CGI – Applications – Server Environment – Environment Variables – CGI Building Blocks – CGI Scripting Using C, Shell Script – Writing CGI Programs – CGI Security – Alternatives and Enhancements to CGI.Servlet:Server – Side Java – Advantages Over Applets – Servlet Alternatives – Servlet Strengths – servlet Architecture – Servlet Life Cycle – GenericServlet and HttpServlet – First Servlet – Passing Parameters to Servlets – Retrieving Parameters – Limitations of Cookies – Deploying Filter – Problems with Servlet.

130

Text book: Web Technologiies–Uttam K.Roy–Oxford University Press 2010. Reference Books

1. Web Technology and Design, C.Xavier, New Age International Publishers 2. Web Technologies TCP/IP Architecture and Java Programming Second Edition,

Achyut S. Godbole & Atul Kahate, Tata McGraw Hill 3. Web Technology A Developer's Perspective, N.P.Gopalan, J. Akilandeswari, PHI

CORE SUBJECT – 3 RDBMS

Unit I An overview: Personal databases - Client server databases - Oracle 9i An introduction - The SQL*PLUS Environment - SQL - SQL*PLUS commands - Sample Databases. Oracle Tables; Naming rules and conventions - Data types - Constrains - Creating an Oracle table - Displaying table informations - Altering and existing table - Dropping a table - Renaming a table - Truncating a table. Unit II Working with tables: DML statements - Arithmetic operations - Where clause - sorting - Define command - Built in functions - Grouping data Unit III Multiple tables; Joints - Set operators - Subquery - Top - N Analysis Advanced features: Views - Subsequences - Synonyms - Index - Transactions - Locking - Controlling access

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Unit IV PL/SQL: Fundamentals - Block structure - Comments - Data types - Variable declaration - Anchored declaration - Assignment operation - Bind variables - Substitution Variables - Arithmetic operators. Structures in PL/SQL: Control structures - Nested blocks - SQL in PL/SQL DML in PL/SQL - Transaction Control Statements. Unit V PL/SQL Cursors & Exceptions - PL?SQL Composite data types: Records, Tables and VARRAYS. Text Book Database Systems Using Oracle - Second edition - Nilesh Shan - PHI 2007 Reference Oracle 9i Complete reference - Loney Koch - Tata Mc Graw Hill 2005

CORE SUBJECT – 4 RDBMS – Practical

ORACLE PROGRAMMING LIST

1. Create an employee database with tables department, employee details,

address, pay details and project details. After the tables and add constrains relevant to the fields in the tables. Insert records into all the tables.

2. Create queries to retrieve relevant information from a table 3. Create a table from the existing tables. Create views from the tables. 4. Develop queries to retrieve information from more than one table. Develop

summary queries to retrieve relevant information from the table. 5. Create a partition table and query the records. 6. Create a table with abstract data type and query the records 7. Create PL/SQL program to print multiplication table 8. Create a PL/SQL program to check whether a given string is palindrome or not 9. Create a PL/SQL program to print student details using report 10. Create a Procedure to calculate Electricity Bill (use cursor) 11. Create a PL/SQL program to perform updation using various triggers 12. Create PL/SQL program to find factorial of numbers using function and

procedure

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MAJOR ELECTIVE PAPER SYLLABUS CATEGORY- B

(CHOOSE ANY ONE)

ELECTIVE-I ARTIFICIAL INTELLIGENCE

Unit I Problem, Problem Spaces and Search: What is AI? - AI Problems - What is an AI technique - Defining the problem as a state space search - Production system - Production System Characteristics - Problem Characteristics. Unit II Heuristic Search Techniques: Generate and test - Hill Climbing - Best first Search - Problem Reduction - Constraints satisfaction - Means end analysis. Unit III Knowledge Representation: Representations and Mappings - Approaches to Knowledge Representation. Using Predicate Logic: Representing simple facts in logic - Computable functions and prediction - Resolution - The basis of resolution - Resolution in Propositional Logic - The Unification algorithm - Resolution in Predicate Logic. Unit IV Representing Knowledg Using Rules: Procedural versus - Declarative knowledge-logic Programming-Forward versus Backward Resoning-Matching Unit V Game Playing: The Minimax search procedure - Adding Alpha Beta cut offs - Addition Refinements - Waiting for Quiescence - Secondary Searches - Using Book moves. Expert System: Introduction to Expert system - Definitions - Basic characteristic of an expert system - Development of Expert system - Knowledge Engineering Stages of Knowledge Acquisition - Expert system application - Eliza - Dendral Mycin Prospector.

133

Text Book 1. Elain Rich and Kevin knight "Artificial Intelligence" - Tata McGraw Hill 2. Artificial Intelligence and Intelligent Systems- N.P. PADHY Reference Book

1. Introduction to Artificial Intelligence Rajenda Akeskar PHI 2. Artificial Intelligence by PH, Winston - Addison Wesley 3. Introduction to Artificial Intelligence and Expert system by Patterson, PHI

ELECTIVE-II

SOFTWARE PROJECT MANAGEMENT

Unit I Conventional Software Management – Waterfall Model – Conventional Software Management Performance – Evolution of software economics – Software economics – Pragmatic software cost estimation – Improving software economics – Reducing software product size – Improving software process – Team effectiveness – Automation through software environments. Unit II Lift cycle phases – Engineering and production stages – Inception, Elaboration, Construction and Transition Phase – Artifacts of the process – The artifact sets – Management, Engineering and Pragmatic artifacts – Model based software Architectures. Unit III Workflows of the process – Software process workflows – Iteration workflows – Iterative process planning – work breakdown structures – Planning guidelines – cost & schedule estimation process – iteration planning process – pragmatic planning – Project Organizations & responsibilities.

134

Unit IV Process automation – Tools – The project environment – Project control and Process Instrumentation – The seven core metrics – Management indicators – Quality indicators – Life cycle expectations – Pragmatic software metrics – Metrics automation – Tailoring the Process – Process discriminates. Unit V Modern Project Profile – Continuous Integration – Early risk resolution – Evolutionary requirements – software management principles Next generation software economics – Modern Process transitions. Text

1. Software Project Management – Walker Royce – Pearson Education 2012. 2. Software Project Management, Bob Hughes and Mike Cotterell: Tata McGraw-

Hill Edition, 2011. 3. Software Project Management in practice, Pankaj Jalote, Pearson

Education.2012.

ELECTIVE-III MOBILE COMMUNICATION

Unit I Mobile Communication: Need for Mobile communication - Requirements of Mobile Communication - History of Mobile Communication - Properties of Wireless Medium - Radio Propagation - Propagation Coverage Calculation. Introduction to Cellular Mobile Communication: Cellular Structure - Frequency Reuse - System Architecture - Authentication Centre (AUC) - Home Location Register (HLR) - Visiting Location Register (VLR) - Equipment Identify Register (EIR) - Base Station System - Cellular Mobile Communication Switching. Unit II Mobile Communication Standards: First Generation Wireless Networks - Second Generation Wireless System - Third Generation and Beyond Wireless Systems - Implementation Organization - Regional Organizations - Global Organizations - Global

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System for Mobile Communication (GSM) - GSM Architecture - Advanced Mobile Phone Service (AMPS) - Digital Advanced Mobile Phone Service. Cordless Telephony Standards: - Personnel Access Communication Standards (PACS) - EIA/TIA IS-136-EIA TIA IS - 95 Standards - Digital European Cordless Telephone (DECT) - Personnel Handy Phone System (PHS) - IEEE 802.11 - Other Standards - Handoff Techniques - Handoff Detection and Assignment - Types of Handoff - Mobile Controlled Handoff - Network Controlled Handoff - Mobile Assisted handoff - Radio Link Transfer - Roaming Management - Connection to Public Telephone Network - Connection from Mobile Unit to a Fixer User, Cellular. System Spectrum: - Adaptive channel Allocation - Frequency Division - Spectrum Utilization - Channel Reservation for Handoff Calls - Control Channels - Channel Assignment Methods - Channel Borrowing and Sharing - Non - Fixed Assignment Methods - Permanent Cell Splitting - Temporary Cell Splitting. Unit III Cordless Mobile Communication Systems: Cordless Telephone Home - Multichannel Cordless Telephone System - Wireless Private Box Exchange History of Data networks - Classification of Mobile Data Networks - Independent Data networks - Shared Mobile Data - Overlay Mobile Data - Cellular Digital Part Data (CDPD) System - Architecture of CDPD - Satellite Classification - Earth Orbit Satellites - Medium Earth Orbit Satellites - Low Earth Orbit Global Satellite Communication - Changeover from One Satellite to Requirements of Global Mobile Communication - Global User Number - Configuration - Third Generation Global Mobile System - Satellite Systems for Mobility. Unit IV Interferences in Cellular Mobile Communication: Nature of Co-channel Interference - Measurement of Co-channel Interference - Measurement of Co-channel Interference with Mobile Unit - Frequency Reuse - Co-channel Interference Omni directional Radiation - Directional Antennas for Co-channel Interference Reduction - Other Methods of Co-channel Reduction - Non-Co-channel interference - Measurement of Signal to Noise and Distortion Ratio (SINAD) - Design Objective - Basic Specification - Co-Channel Interference Reduction Factor - Adjacent Channel Interference - Propagation Attenuation - Fading - Factors to be Considered at the Base Station - Working of Mobile IP - Wireless Threats - Authentication and Access control - Secrecy to Communication - Anonymity - Security Arrangement in CDMA - Security of Wireless Data Networks.

136

Unit V Wireless Local Loop Architecture: Components in Will - Problems in WLL - Modern Wireless Local Loop - Local Multipoint Distribution Service (LMDS) - Properties of WAP - Beater Services - Wireless Datagram Protocol (WDP) - Wireless Transport Layer Security (WTLS) - WAP Transaction Protocol (WTP) Wireless Session Protocol (WSP) Wireless Application Environment (WAE) - Components Integration - Bearer Adaptation - WAP Client Supporting Networks - System Description - Advantages of Microcellular - Layout of the Optical Fibre Microcellular Communication System - Need for Ad hoc Networks - MANET and Technical Factors Affecting Ad hoc Network - Ad hoc Nodes System Description - Routing in Ad hoc Network - Bluetooth Technology - Limitation on the Bluetooth Physical Layer - Types of Intelligent Cells - Power Delivery Intelligent Cells - Processing Gain Intelligent Cells - User Controlled Services - Reconfigurable Technology - Vision of 4G - 4G Mobile System Convergence. Text Book Wireless and Mobile Communication, T.G. Palanivelu & R Nakkeeran, PHI Learning Private Limited, 2009 Reference Books

1. Wireless and Cellular Telecommunications, Third Edition William C.Y. Lee, McGraw Hill.

2. Mobile Computing Technology, Applications and Service Creation, Asoke K. Telukder & Roopa R. Yavagal, TMH Publication

3. Wireless Communications and Networking made simple Prof. Satish Jain. Vineeta Pillai, BPB Publications.

137

CORE SUBJECT-1 OPERATING SYSTEM

Unit I Introduction: What is an Operating System: Mainframe Systems - Desktop Systems - Multiprocessor Systems - Distributed Systems - Clustered Systems - Real - time Systems - Handheld Systems. Unit II Process: Process concept - Process Scheduling - Operations on processes - Co-operating processes - Inter Process communication. CPU Scheduling: Basic Concepts - Scheduling Criteria - Scheduling algorithms - Multi processor scheduling - Real time scheduling - Algorithms evaluation. Unit III Process Synchronization: Background - the Critical section Problem - Synchronization hardware - Semaphores - Classical problems of synchronization - Critical regions - Monitors - Atomic transactions. Deadlocks: System model - Dead lock characterization - methods for handling deadlocks - Deadlock prevention - Deadlock Avoidance - deadlock detection - recovery from deadlock. Unit IV Memory management: Background - Swapping - Contiguous memory allocation - paging - segmentation - segmentation with paging. Virtual Memory: Background - Demand paging - Page replacement - Allocation of frames. Unit V File System Interface: File concept - Access methods - File system structure - File system implementation - Directories structure - Directory implementation - Allocation methods - Free space management - Effiency and performance - Recovery. mass Storage Structure: Disk Structure - Disk scheduling - Disk management - Swap space management - RAID structure - Disk attachment - Stable Storage.

138

Text Book Operating System Concepts - Abraham Silverschatz and Peter Baer Galvin. Addison Wesley publishing company - Sixth Edition Reference books 1. Operating Systems: Internal and Design Principles - Fifth Edition, William Stallings,

PHI 2. Understanding Operating Systems, Ida M.Flynn, Ann Mclver McHoes 3. Operating Systems - Second Edition, Achyut S. Godbole, TMH

CORE SUBJECT-2 CYBER SECURITY

Unit I Introduction to Information Security Introduction – The History of Information Security – What Is Security – Critical Characteristics of Information – NSTISSC Security Model – Components of an Information System – Securing Components – Balancing Information Security and Access – Approaches to Information Security Implementation – The Systems Development Life Cycle – The security systems development life cycle – Security Professionals and the Organization – Communities of Interest – Information Security – Is it an Art or a Science. The Need for Security Introduction – Business Needs First – Threats – Attacks – Secure Software Development. Legal, Ethical and Professional Issues in Information Security Introduction – Law and Ethics in Information Security – Relevant U.S. Laws – International Laws and Legal Bodies – Ethics and Information Security – Codes of Ethics and Professional Organizations.

139

Unit II Risk Management Introduction – An overview of Risk Management – Risk Identification – Risk Assessment – Risk control Strategies – Selecting a Risk Control Strategy – Quantitative versus qualitative risk control practices – Risk Management Discussion Points – Recommended Risk Control Practices. Planning for Security Introduction – Information Security Policy, Standards and Practices – The Information Security Blueprint – Security Education, Training and Awareness Program – Continuity Strategies. Security Technology : Firewalls and VPNs Introduction – Physical Design – Firewalls – Protecting Remote Connections. Unit III Security Technology: Intrusion Detection, Access Control and Other Security Tools Introduction – Intrusion Detection and Prevention Systems (IDS and IPSs) – Honey Pots, Honey Nets and Padded Cell Systems – Scanning and Analysis Tools – Access Control Devices. Cryptography Introduction – Foundations of Cryptology – Cipher Methods – Cryptographic Algorithms – Cryptographic Tools – Protocols for Secure Communications – Attacks on Cryptosystems. Unit IV Physical Security Introduction – Physical Access Controls – Fire Security and Safety – Failure of Supporting Utilities and Structural Collapse – Interception of Data – Mobile and Portable Systems – Special Considerations for Physical Security Threats.

140

Implementing Information Security Introduction – Information Security Project Management – Technical Topics of Implementation – Non technical Aspects of Implementation – Information Systems Security Certification and Accreditation. Unit V Security and Personnel Introduction – Positioning & Staffing the Security Function – Credentials of Information Security Professionals – Employment Policies and Practices – Security Considerations for Nonemployees – Internal Control Strategies – Privacy and the Security of Personal Data. Information Security Maintenance Introduction – Security Management Models – The Maintenance Model – Digital Forensics. Text Book: Principles and Practices of Information security --- Dr Michael E. Whitman, CISM, CISSP Herbert .J Mattord , CISM , CISSP — Cengage Learning India Private Limited Indian fourth edition Reprint 2010.

CORE SUBJECT-3

SOFTWARE TESTING Unit I Principles of Testing – Software life cycle development models – Phases of Software Project – Quality, QA, QC – Testing, Verification, Validation – Process Model - Life cycle Models Unit II White box testing: Static and Structural testing – Challenges – Black box testing – Integration testing

141

Unit III System and acceptance testing – Performance testing – Regression testing Unit IV Internationalization testing – Ad hoc testing-Testing of object oriented systems Unit V Test planning, Management, Execution and reporting – Software test automation – test metrics and measurements Books for reference: 1. Software Testing Principles and practices – Srinivasan Desikan, Gopalaswamy

Ramesh – Pearson -2012 2. Software Testing Principles and practices – Naresh Chauhan – Oxford University

Press 2010 3. Introduction to Software testing – Paul Ammann – Cambridge University Press –

2009 4. Foundations of Software Testing – Aditya P Mathur – Pearson - 2011

CORE SUBJECT-4 COMPUTER GRAPHICS AND MULTIMEDIA

Unit I Introduction: Application and Operations of Computer Graphics - Graphics Packages - Requirements of a Graphical System - GUI. Input Output Devices: Common Input Devices - Graphical Output Devices - Raster Scan Video Principle - Raster Scan CRT Monitors - Color Raster Scan System - Plasma Display - LCD - Hard Copy Raster Devices - Raster Scan System - Memory Tube Displays - Plotters - Graphics Accelerators - Coprocessors.

142

Unit II Scan Conversion - Methods - Polynomial Method - DDA algorithms for line drawing Alogrithm, Circle, Ellipse, Parabola - Bresenham's Line Drawing Algorithm - Bresenham's Circle Drawing Algorithm - Problem of Scan Conversion - Solid Areas - Odd Even Methods - Winding Number Method - Solid Area Filling - Algorithms - Boundary, Flood Fill Algorithm. Unit III Two Dimension Transformation - Translation - Scaling - Rotation - Transformation of Points and Objects - Homogenous Coordnate System and Transformations - Reflection - Shearing - Three Dimension Transformations - Translation - Scaling - Rotation - Reflection - Shearing. Unit IV 2D Viewing and Clipping - Windows and View Ports - Viewing Transformations - Clipping of lines in 2D - Cohen Sutherland Clipping Algorithms - Visibility - Midpoint subdivision method - parametric Clipping - Polygon Clipping - Sutherland Hodgeman Algorithm - Clipping against Concave windows - Hidden Surface Elimination - Black Face Removal Algorithm Z buffer Algorithm. Unit V Concept of Multimedia - types, Data Steams - Applications - Authoring digital Audio - MIDI - Image Compression - Video Compression - Graphic File Formals - BMP - GIF - JPEG - TIFF - PNG. Text Book Computer Graphics Multimedia and Animation - Malay K.Pakira - PHI Learning 2008 References 1. Computer Graphics - Apurva Desai - PHI - 2008 2. Prabhat Andleigh, Kiran Thakrar - Multimedia System and Design – Prentice Hall

2000.

143

CORE SUBJECT-4 GRAPHICS AND MULTIMEDIA LAB

1. Write a program to display an image as Tiled or cascaded according to the user's

option.

2. Write a program so that it should first display the image as the size of applet, then it should be reduced and again it should be reduced and so on and finally the image should disappear.

3. Write a program to scale as image

4. Write a program to rotate an image

5. Write a program to drop word by word o a sentence from the top

6. Write a program to draw a line using Bresenham's algorithm

7. Write a program to draw a line using DDA algorithm

8. Write a program to move a car with effect

9. Write a program to display the news Headlines letter by letter

10. Write a program to display as many balls in the frame in random position

11. Write a program for bouncing a ball and moving with sound effect

12. Write a program to create a scenery of rain in the frame with sound of rain

MAJOR ELECTIVE PAPER SYLLABUS CATEGORY- C

(CHOOSE ANY ONE) ELECTIVE-I

MOBILE OPERATING SYSTEM Unit I Role of Android OS – Android Execution Environment – Components – Activity Lifecycle – Service Lifecycle – Creating and Android Development Environment – Starting a New Android Application – Writing – Running – Android Development Environment for Real Time Applications – Android and Social Networking – Downloading the MJ Android Code – A Brief Tour of the MJ Android Code – The Project Root folder – Source Folder – Resource Folder – Building and Running the Micro jobs Application – Android SDK/Eclipse IDE – Loading and Starting the application – Running an application on the T – Mobile Phone.

144

Unit II Debugging Android Applications – Tools – Eclipse Java Editor – Java Errors – Debugger – Logcat – Android Debug Bidge )adb) – Dalvis Debug Motor Service (DDMS) – Trace view – Signing and Publishing Your Application – Testing Application – Create and Attach and Icon and Label – Cleanup for Release – Version the Application – Obtaining and Signing the certificate and API key – Getting and Signing Certificate for an application – Getting an Signing Certificate while Debugging – Signing the Application – Retesting the Application – Publishing on Android Market – Signing Up as an Android Developer. Unit III Persistent Data Storage : SQ Lite Data Base and Content Providers – Databases – Basic Structure of the Micro Jobs Databases Class – Reading Data from the Database – Modifying the Database – Content Providers – Introducing Notepad – Content Providers – Consuming a Content Provider – Location and Mapping – Location Based Services – Mapping – Google Maps activity – Map View and Map Activity – Working with Map Views – Pausing and Resuming a Map Activity – Controlling the Map with Menu Buttons – Controlling the Map with the Keypad – Location without Maps – Manifest and Layout Files – Connecting to a Location Provider and Getting Location Updates – Updating the Emulated Location. Unit IV Building a View – Android GUI Architecture – Model – View – Controller – Putting It Together – Assembling a Graphical Interface – Writing up the Controller – Listening to the Model – Listening for Touch Events – Listening for Key Events – Alternative Ways to Handle Events – Advanced Wiring : Focus and Threading – Android Views – Text View and Edit Text – Button and Image Button – Adapters and Adapter Views – Checkboxes, Radio buttons and Spinners Unit V View Groups – Gallery and Grid View – List View and List Activity – Scroll View – Tab Host – Layouts – Frame Layout – Linear Layout – Table Layout – Absolute Layout – Relative Layout.Rolling your own Widgets – Layout – Canvas Drawing – Drawables – Bitmaps – Bling – Shadows, Gradients and Filters – Animation – Open GL Graphics – Simple Phone Calls – Quick and Easy Phone Calls – Creating and Example Application to Run the call method

145

Text Book roid Application Development – Rick Rogers, John Lombardo, Zigard Mednieks & Black Meiek O' Reilly 2009 Edition (Unit I – V).

ELECTIVE - II DATA MINING

Unit I Introduction What is Data Mining – Why Data Mining Now – The Data Mining Process – Data Mining Applications – Data Mining Techniques – Some Data Mining Case Studies – The Feature of Data Mining – Guidelines for successful Data Mining – Data Mining Software. Unit II Association Rule Mining Introduction – Basics – The Task and Naive Algorithm – The Apriori Algorithm – Improving the efficiency of the Apriori Algorithm – Mining Frequent Patterns without Candidate Generation – Performance Evaluation of Algorithms – Software for Association Rule Mining. Unit III Classification Introduction – Decision Tree – Building a decision Tree The Tree Introduction Algorithm – Split Algorithm Based on the Information Theory – Decision Tree Rules – Decision Tree Summary – Naive Bayes Method – Other Evaluation Criteria for Classification Methods – Classification Software.

146

Unit IV Cluster Analysis What is Cluster Analysis – Desires Features of Cluster Analysis – Types of Data – Computing Distance – Types of Cluster Analysis Methods - Partitional Methods - Hierarchical Methods – Dealing with Large Databases – Cluster Analysis Software. Unit V Web Data Mining Introduction – Web Technology and Characteristics – Locality and Hierarchy in the Web – Web Content Mining – Web Usage Mining – Web Structure Mining – Web Mining Software. Text Book Introduction to Data Mining with Case Studies, G.K. Gupta, PHI Second Edition 2012. Reference Book

1. Data Mining Concepts & Technologies, Jiawei Han, Micheline Kamber, Morgan Kaufmann, Second Edition, 2005.

2. Data Mining, Vikram Pudi, P. Radha Krishna, Oxford University Press, First Edition, 2009.

3. Data Warehousing, Reema Thareja Oxford University Press. 2009. 4. Insight into Data Mining Theory and Practice, K.P. Soman, Shyam Diwakar, V.

Ajay, Prentice Hall of India, 2008.

ELECTIVE - III WEB SERVICES

Unit I Introduction to web services – Industry standards, Technologies and Concepts underlying Web Services – their support to Web Services, Applications that consume Web Services.

147

Unit II XML – its choice for web services – Network protocols to backend databases – Technologies – SOAP, WSDL – exchange of information between applications in distributed environment – Locating remote web services – its access and usage, UDDI specification – and introduction. Unit III A brief outline of web services – conversation – static and interactive aspects of system interface and its implementation, work flow – Orchestration and refinement, Transactions, Security issues – the common attacks – security attacks facilitated within web services quality of services – Architecting of systems to meet users requirement with respect to latency, performance, reliability, QOS metrics, Mobile and wireless services – energy consumption, network band with utilization, portals and services management. Unit IV Building real world enterprise applications using web services – sample source codes to develop web services – steps necessary to build and deploy web services and client applications to meet customer's requirement – Easier development, customization, maintenance, transactional requirements, seamless porting to multiple devices and platforms. Unit V Development of web services and applications onto tomcat application server and Axis SOAP server (both are freewares) – Web services platform as a set of enabling technologies for XML based distributed computing. Reference Books

1. Sandeep Chatterjee, James Webber, "Developing Enterprise Web Services : An Architects Guide", Prentic Hall, Nov. 2003.

2. Keith Ballinger, "NET web services "Architecture and Implementation with .Net", Pearson Education, First Education Feb. 2003.

3. Ramesh Nagappan, Developing Java Web Services: Architecting and developing secure web services using Java", John Wiley and Sons, first edition Feb. 2003.

4. Eric A marks and Mark J Werrell, "Executive Guide to Web Services", John Wiley and sons, March 2003.

5. Anne Thomas Manes, "Web Services : A managers Guide" Addison Wesley, June 2003.

148

APPENDIX - BA13

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI – 627 012

B.Sc. BIOINFORMATICS (CBCS)

(Effective from the Academic Year 2012 – 2013 onwards)

Course Structure

Eligibility for admission A pass in higher secondary (10+2) or any equivalent examination with subjects in biological sciences / computer science.

I Semester

Part Components Hours Credits I Tamil / Other Language 6 3 II English 6 3

III

Core Subjects Theory 1. Cell Biology and Genetics 2. Basics of Computer Practical 1. Lab in Cell Biology, Genetics and Molecular Biology

4 4 2

4 4

--

III

Allied Subject I Theory : 1. Programming in C Practical : 1. Lab in Programming in C and Visual Basic

4 2

4 --

IV Environmental Studies 2 2 Total (6 Theory) 30 20

149

II Semester

Part Components Hours Credits I Tamil / Other Language 6 3 II English 6 3

III

Core Subjects Theory 1. Molecular Biology 2. Biomolecular Structure Practical 1. Lab in Cell Biology, Genetics and Molecular Biology

4 4 2

4 4

2

III

Allied Subject I Theory : 2. Programming in Visual Basic Practical : 1. Lab in Programming in C and Visual Basic

4 2

4 2

IV Valued Based Education 2 2 Total (6 Theory + 2 Practical) 30 24

III Semester

Part Components Hours Credits I Tamil / Other Language 6 3 II English 6 3

III

Core Subject Theory 5. Introduction to Bioinformatics Practical 2. Lab in Bioinformatics, Genomics and Proteomics

4 2

4

--

III

Allied Subject II Theory : 3. Basic Mathematics Practical: 2. Lab in Mathematics using SciLab and Biostatistics using SPSS/STATA/Excel

4 2

4 --

IV Skill Based Subject 1 1(a) Programming in PERL (OR) 1(b) Programming in PHP

4

4

IV Non-Major Elective 1(a) Fundamentals of Computer and Networks (OR) 1(b) Basics of Bioinformatics

2

2

Total (6 Theory) 30 20

150

IV Semester

Part Components Hours Credits I Tamil / Other Language 6 3 II English 6 3

III

Core Subject Theory 6. Basics of Genomics and Proteomics Practical 2. Lab in Bioinformatics, Genomics and Proteomics

4 2

4

2

III

Allied Subject II Theory : 4. Biostatistics Practical: 2. Lab in Mathematics using SciLab and Biostatistics using SPSS/STATA/Excel

4 2

4 2

IV Skill Based Subject 2 2(a) Database Management Systems (OR) 2(b) Introduction to Algorithms

4

4

IV Non-Major Elective 2(a) Biological Database and Sequence Analysis (OR) 2(b) Introduction to Algorithms

2

2

V Extension Activity (NCC, NSS, YRC, and YWF) -- 1 Total (6 Theory + 2 Practical) 30 25

V Semester

Part Components Hours Credits

III

Core Subjects Theory 7. Biological Databases 8. Computational Biology Practical 3. Lab in Biological Databases 4. Lab in Computational Biology 5. Lab in Molecular Modeling and Computer Aided Drug Design

4 4 3 3 2

4 4

-- -- --

III Major Elective 1 9(a) Structural Bioinformatics (OR) 9(b) Biophysics

5

5

III Major Elective 2 10(a) Systems Biology (OR) 10(b) Introduction to Biomolecular Instrumentation

5

5

IV Skill Based Subject (Common) 3(a) Effective Communication (OR) 3(b) Personality Development

4

4

Total (5 Theory) 30 22

151

VI Semester

Part Components Hours Credits

III

Core Subjects Theory 11. Molecular Modeling 12. Computer Aided Drug Design 13. Free and Open Source Bioinformatics Tools Practical 3. Lab in Biological Databases 4. Lab in Computational Biology 5. Lab in Molecular Modeling and Computer Aided Drug Design

6 6 5 3 3 2

4 4 4

4 4 4

III Major Elective 3 14(a) Applications in Bioinformatics (OR) 14(b) Introduction to Intellectual Property Rights

5

5

Total (4 Theory + 3 Practical) 30 29 Total number of courses : 40 (33 Theory + 7 Practical) Total number of hours : 180 Total number of credits : 140 Distribution of marks in theory between external and internal assessment is 75:25; for practical 60:40; pass minimum of 40% for external and overall components.

152

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI – 627 012

B.Sc. BIOINFORMATICS (CBCS)

(Effective from the Academic Year 2012 – 2013 onwards)

Semester – V

Core 7: Biological Databases Unit I: Introduction to Bioinformatics data and Databases Introduction to database – Database models – Database languages – Types of databases: Flat file, Relational databases and Object oriented databases – Types of biological databases – Pitfalls of biological databases – Types of Biological data: Genomic DNA, Complementary DNA (cDNA), Recombinant DNA (rDNA), Expressed sequence tags (ESTs), Genomic survey sequences (GSSs) – Primary Databases: GenBank, EMBL, DDBJ – Composite Databases: NRDB, UniProt – Literature Databases: Open access and open sources, PubMed, PLoS, Biomed Central. Unit II: Genome Databases Viral genome database: ICTVdb – Bacterial Genomes database: Genomes OnLine Database (GOLD), Microbial Genome Database (MBGD) – Organism specific Genome database: OMIM / OMIA, SGD, WormBase, PlasmoDB, FlyBase, TAIR – Genome Browsers: Ensembl, VEGA genome browser, NCBI map viewer, KEGG, MIPS, UCSC Genome Browser. Unit III: Sequence Databases Nucleotide sequence Databases: GenBank, EMBL, DDBJ – Protein sequences Databases: SwissProt, TrEMBL, UniProt, UniProt Knowledgebase (UniProtKB), UniProt Archive (UniParc), UniProt Reference Clusters (UniRef), UniProt Metagenomic and Environmental Sequences (UniMES) – Sequence motifs Databases: Prosite, ProDom, Pfam, InterPro – Sequence file formats: GenBank, FASTA, PIR, ALN/ClustalW2, GCG/MSF. Unit IV: Structure and Derived Databases The primary structure databases: Protein Data Bank (PDB), Cambridge Structural Database (CSD), Molecular Modeling Database (MMDB) – The secondary structure databases: Structural Classification of Proteins (SCOP), Class Architecture Topology Homology (CATH), Families of Structurally Similar Proteins (FSSP), Catalytic Site Atlas (CSA) – Molecular functions/Enzymatic catalysis databases: KEGG, BRENDA. Unit V: Bioinformatics Database Search Engines Text-based search engines: Entrez, SRS, DBGET / LinkDB – Sequence similarity based search engines: BLAST and FASTA – Motif-based search engines: ScanProsite and eMOTIF – Structure similarity based search engines: VAST and DALI.

153

REFERENCES: 1. Bioinformatics: Sequence and Genome Analysis by Mount D., Cold Spring Harbor

Laboratory Press, New York. 2004 2. Bioinformatics- a Practical Guide to the Analysis of Genes and Proteins by

Baxevanis, A.D. and Francis Ouellellette, B.F., Wiley India Pvt Ltd. 2009 3. Introduction to bioinformatics by Teresa K. Attwood, David J. Parry-Smith. Pearson

Education. 1999

Core 8: Computational Biology Unit I: Strings and Graphs Strings and Sequences – Graphs and Trees – Algorithm basics – Comparing two sequence: Global, Local and Semi-global comparison – Linear and affine gap penalty functions – Comparing multiple sequences – PAM – BLOSUM – BLAST – FAST – Similarity and distance. Unit II: Fragment Assembly of DNA Fragment assembly of DNA – Alternative methods for DNA sequencing – Shortest common superstring – Reconstruction – Multicontig – Algorithms for fragment assembly of DNA: Shortest superstrings as paths, Acyclic subgraphs and Greedy – Heuristics: Fragment assembly in practice. Unit III: Phylogeny Phylogenetic trees – Character states and Perfect phylogeny problem – Binary character states – Parsimony and compatibility in phylogenies – Algorithm for distance matrices: Additive trees and Ultrametric trees. Unit IV: Genome Rearrangements Genome rearrangements: Introduction – Oriented blocks: Diagram of reality and desire, Interleaving graphs and Bad components – Unoriented blocks – Applications of genome rearrangements. Unit V: Sequence to Structure Prediction RNA secondary structure prediction – Protein folding problem – Protein threading – Computing with DNA: Hamiltonian path problem, Satisfiability, Problems and promises. REFERENCES: 1. Waterman, M. Introduction to Computational Biology: Maps, Sequences and

Genomes. 1995. CRC Press, ISBN: 0412993910 2. Setubal, J. and Meidanis, J. 1997. Introduction to Computational Molecular Biology.

Brooks Cole Publishing, ISBN: 0534952623 3. Durbin, R., Eddy, S., Krogh, A., and Mitchison, G. 1998. Biological Sequence

Analysis: Probabilistic Models of Proteins and Nucleic Acids, Cambridge University Press, ISBN 0521629713

4. Venter et al. 2001. The Sequence of the Human Genome. Science 291: 1304-1351 5. Eisen MB, Spellman, PT, Brown, PO, and Botstein, D. 1999. Cluster analysis and

display of genome-wide expression patterns. PNAS 95(25): 14863

154

6. Schena M, Shalon D, Davis RW, and Brown PO. 1995. Quantitative monitoring of gene expression patterns with a complementary DNA microarray. Science 270: 467-70.

7. Gusfield, D. 1997. Algorithms on strings, trees, and sequences: computer science and computational biology. Cambridge University Press, ISBN: 0521585198

8. Mount, D. Bioinformatics: Sequence and Genome Analysis. 2001. Cold Spring Harbor Laboratory Press, ISBN 0879696087

Major Elective 1: 9(a). Structural Bioinformatics Unit I: Basics and Structure Visualization Introduction to structural bioinformatics: Structural basis of biological phenomena, Challenges in computing with structural data. Fundamental principles of protein/DNA/RNA structure: Chemical structure of proteins, Protein secondary and tertiary structure, Protein domains and folds, Sequence-to-structure-to-function paradigm, Chemical structure of nucleic acids, Structure of nucleic acids. Molecular visualization: Visualization styles and software. Unit II: Structure Determination and Databases Experimental methods for structure determination: Basic principles of X-ray crystallography, Basic principles of NMR spectroscopy, Other methods for direct and indirect determination of structure of biopolymers, Structural/functional genomics initiative and high-throughput techniques, Structural quality assurance. Structure-based databases: Protein Data Bank, SCOP and CATH classifications, RNABase, Other sources. Unit III: Structure Comparison and Prediction Structure comparison and alignment: Automated assignment of secondary structure, Structural similarity measures, Structural alignment algorithms. Prediction of structure of biopolymers: Prediction of protein structure (prediction of secondary structure, homology modeling, fold recognition and ab initio methods), Membrane proteins, Prediction and Energy minimization of RNA structure, Prediction of DNA curvature. Unit IV: Function Prediction and Docking Prediction of protein function from structure and other types of data: Definition of protein function and gene ontology, Enzyme classification and functional site identification, Relationship between structure and function, Prediction of protein-ligand interactions. Principles of molecular recognition and docking: Protein-small molecule interactions, Macromolecular docking and protein-protein interactions, Structural bioinformatics in drug discovery. Unit V: Applications of Structural Bioinformatics Intrinsically disordered (unstructured) proteins: Sequence-to-disordered ensemble-to-function paradigm, Functional characterization of disordered proteins, Prediction of disordered proteins. Types of tools for Homology modeling, Threading/fold recognition, Ab initio structure prediction, Secondary structure prediction, Transmembrane helix prediction and Signal peptide prediction.

155

REFERENCES: 1. P.E. Bourne and H. Weissig (Eds.) Structural Bioinformatics, John-Wiley and Sons,

2003 2. C. Branden and J. Tooze, Introduction to Protein Structure, Garland Publishing Inc.,

New York, 1999. 3. Chris Calladine, Horace Drew, Ben Luisi, and Andrew Travers, Understanding DNA,

3rd Edition, Elsevier Academic Press, USA, 2004.

Major Elective 1: 9(b). Biophysics Unit I: Atomic & Molecular structure Structure of atom, Schrödinger’s theory, Quantum numbers, Pauli’s exclusion principle, Hund’s rule, Concept of bonding, Atomic and molecular orbitals, Hybridization of orbitals, σ and π bonds, Polar and non-polar molecules, Inductive effect, Resonance, Structural isomerism; Geometrical isomerism; Optical isomerism & Optical activity. Unit II: Acid & Bases Mole concept, Molarity & Normality, Weak acids, Ampholyte, pH, Calculations of pH from H & OH concentrations, Measurements of pH, Henderson – Hasselbalch equation, Buffers, Redox potential, Nernst equation, Oxidation-Reduction reactions. Unit III: Thermodynamics and Bioenergetics Laws of thermodynamics, Concept of free energy, Unavailable energy and Entropy, Enthalpy, Negative entropy change in living system, Heat content of food, Endergonic and exergonic, Molecularity of reactions, Energy of activation, Metabolism pathways, High energy compounds, Metabolism of glucose, Formation of ATP, Glycolysis, Kreb’s cycle, Electron transport chain. Unit IV: Biomembranes and Kinetics Membrane structure – Composition; Function; Membrane transport, Simple diffusion, Passive transport, Active transport, Reactions - 0th, 1st, 2nd and 3rd order reactions, Diffusion, Osmosis, Osmotic pressure, Osmoregulation, Surface tension, Dialysis, Adsorption, Viscosity, Thermal conduction, Collides, Sedimentation. Unit V: Macromolecular Interactions Receptor-ligand kinetics, Scatchard plot, Interaction between binding sites, MWC model, KNF model, Oxygen-hemoglobin binding, Binding of two different ligands, Cooperative binding, Anti-cooperative binding, Excluded site binding, Energetics and dynamics of binding, Structures of protein ligand complexes, free radicals in biology and medicine.

156

REFERENCES: 1. Ackerman E.A. Ellis, L.E.E. & Williams L.E. (1979), Biophysical Science, Prentice-

Hall Inc. 2. Barrow. C. (1974), Physical Chemistry for Life Sciences, McGraw-Hill. 3. Bloomfield V.A. and Harrington R.E. (1975), Biophysical chemistry, W.A.Freeman

and CO. 4. Bulter l.A.V. And Noble D.Eds. (1976), Progress in Biophysics and Molecular Biology

(all volumes) pergamon, Oxford. 5. Cantor C.R. and Schimmel P.R. (1980), Biophysical chemistry, W.A.Fremman and

Co. 6. Casey E.J. (1967), Biophysics, concepts and mechanisms. Affiliated East west

press. 7. Chang R. (1971), Basic principles of spectroscopy, McGraw-Hill. 8. De Robertis E.D.P. and De Robertis E.M.P. (1981), Essentials of cell and molecular

Biology, Holt sounders International Editions. 9. Dickerson R.E. & Geis I. (1972), Proteins: structure, function and evaluation,

Benjamin. 10. Dugas H. and Penney C. (1981), Bioorganic chemistry, Springer-Verlag. 11. Fleischer S. Hatefi Y. McLennan D.H. and Tzagoloff A. (1977), The molecular

biology of Membranes, Plenum press. 12. Haschemyer R.N. and Haschemyer A.E.B.V. (1973), Proteins, John willey and sons. 13. Hughes W. (1979), Aspects of Biophysics, John willey and sons. 14. Jain M.K. and Wanger R.C. (1980), Introduction to Biological Membranes, John

willey and sons. 15. Lehninger A. (1981), Biochemistry, Butter Worth Publication.

Major Elective 2: 10(a). Systems Biology

Unit 1: Introduction to Systems Biology Introduction to Systems Biology. Need for System Analysis in Biology. Basic Concepts in System Biology: Component vs System, Links and Functional States, Links to Networks, Hierarchical Organization in Biology. Unit 2: Metabolic Networks and Models in System Biology Basic Features of Metabolic Networks. Reconstruction Methods of Metabolic Networks. Models as Dynamical Systems. Parameter Problem. Meanings of Robustness. Unit 3: Systems Biology Databases KEGG (Kyoto Encyclopedia of Genes and Genomes). BRENDA (BRaunschweig ENzyme DAtabase). BioSilico. EMP (Embden-Meyerhof-Parnas). MetaCyc and AraCyc. SABIO-RK (System for the Analysis of Biochemical Pathways - Reaction Kinetics). BioModels.

157

Unit 4: Tools for System Biology CellDesigner. Ali Baba. CellProfiler. JDesigner. Bio-SPICE (Biological Simulation Program for Intra and Inter Cellular Evaluation). SBML (Systems Biology Markup Language). SBGN (Systems Biology Graphical Notation). SBML-SAT (SBML based Sensitivity Analysis Tool). Unit 5: Premises & Promises of Systems Biology Premise of Systems Biology. Promise of Systems Biology. Challenges of Systems Biology. Applications of Systems Biology. REFERENCES: 1. Bernhard O. Palsson (2006). Systems Biology: Properties of Reconstructed

Networks. Cambridge University Press, New York. 2. Björn H. Junker, Falk Schreiber (2008). Analysis of Biological Networks. John Wiley

& Sons, Inc., Hoboken, New Jersey. 3. Huma M. Lodhi, Stephen H. Muggleton. Elements of Computational Systems

Biology. John Wiley & Sons, Inc., Hoboken, New Jersey. 4. M. Cánovas, J.L. Iborra and A. Manjón (2006). Understanding and Exploiting

Systems Biology in Biomedicine and Bioprocesses. CajaMurcia Foundation, Spain. 5. http://www.systemsbiology.org 6. http://www.systems-biology.org

Major Elective 2: 10(b). Introduction to Biomolecular Instrumentation

Unit I: Spectroscopy Basic principles of spectroscopy; Nature of electromagnetic radiation; Interaction of light with matter; Absorption and emission of radiation; Electronic, vibrational and rotational spectroscopy of molecules; Principle, Instrument design, Methods and applications of UV - visible spectroscopy, IR spectroscopy, Raman spectroscopy, Fluorescence spectroscopy, Atomic absorption spectroscopy, Inductively coupled plasma atomic emission spectrophotometry, NMR spectroscopy, Nuclear quadrupole resonance spectroscopy, ESR spectroscopy, Mass spectroscopy, Photoacoustic spectroscopy. Unit II: Electrophoresis and Chromatography Electrophoresis: Principle; Electrophoretic mobility (EPM) estimation; Factors affecting EPM; Principle, Instrument design, Methods and applications of 2D electrophoresis and zone electrophoresis techniques (Paper, Cellulose acetate, Agarose, Starch gel, Pulsed-field, PAGE, SDS-PAGE, Capillary). Chromatography: Basic concepts of adsorption and partition chromatography; Principle, Instrument design, Methods and applications of all types of adsorption and partition chromatography methods – Paper, Thin layer, Gas, HPLC and Ion chromatography.

158

Unit III: Microscopy and Hydrodynamic Techniques Microscope: Principle, Instrumentation and Application of microscopy; Image formation; Magnification; Resolving power; Different types of Microscopy – Dark field, Phase contrast, Polarization, Fluorescence and Electron microscopy. Hydrodynamics: Fundamental, principles and applications of Centrifugation, Ultracentrifugation, Viscometry, Haemocytometer, Osmosis and Diffusion. Unit IV: X-ray Crystallography X-ray: Principle and applications, Unit cell, Crystal symmetry, Bravais lattices, Symmetry elements and operations, Point groups and space groups, Bragg’s law, Diffraction, Atomic scattering factors, Structure factors, Fourier transformation, Amplitude and Phase, Protein crystallization, Electron density map. Structure Determination: Different techniques of crystallization, Diffractometer, Imaging plates, Phase determination, Patterson method, Direct methods, Molecular replacement methods, Isomorphous replacement method, Anomalous dispersion, Structure refinement, Software for visualization and refinement, R- factor, Validation of the structures. Unit V: Microarray Principle, Instrumentation and Application of DNA microarray and protein array; Sequence databases for microarrays; Image processing; Normalisation; Analysis of relationships between genes, tissues or treatments; Validation tools: GoMiner, qPCR, and TM4-MeV; Emerging applications of microarray and next generation sequencing. REFERENCES: 1. Wilson K. and Walker J., Principles and Techniques of Biochemistry and Molecular

Biology (6th Edition, Cambridge University Press, 2008). 2. Freifielder D., Physical Biochemistry, (2nd Edition, W.H. Freeman and Co., New

York 1982). 3. Ghosal S. and Srivastav A.K., Fundamentals of Bioanalytical Techniques and

Instrumentation, (PHI Learning Private Limited, New Delhi, 2009). 4. Wang, Junbai; Tan, Aik Choon; Tian, Tianhai (Eds.). Next Generation Microarray

Bioinformatics (Methods and Protocols). Humana Press. 2012. 5. Dov Stekel, Microarray Bioinformatics. Cambridge University Press. 2003.

SEMESTER - VI

Core 11: Molecular Modeling Unit I: Molecular Modeling Introduction to molecular modeling, Quantum chemistry, Schrödinger equation, Potential energy functions, Energy minimization, Local and global minima, Saddle point, Grid search, Various approximations; LCAO, HF, Semi-empirical calculations; Single point calculations, Full-geometry optimization methods, ZDO, MNDO, CNDO, NDDO, AM1, PM3, RM1, Conformational search, Z-matrix, Docking, Molecular modeling packages, Molecular Graphics.

159

Unit II: Molecular Mechanics Introduction to molecular mechanics, Balls and springs, Force fields, Bond-stretching, Bond-bending, Dihedral motions, Out of plane angle potential, Non-bonded interaction, Coulomb interactions, Conformational search, United atoms and cut-offs, Derivative methods; First-order methods; Steepest descent, Conjugate gradient, Second order methods; Newton-Raphson method. Unit III: Molecular Dynamics Introduction to molecular dynamics, Newton’s equation of motion, Equilibrium point, Radial distribution function, Pair correlation functions, MD methodology, Periodic box, Algorithm for time dependence; Leapfrog algorithm, Verlet algorithm, Boltzman velocity, Time steps, Duration of the MD run. Starting structure, Analysis of MD job, Uses in drug designing, Ligand protein interactions. Unit IV: Quantum Mechanics Introduction to quantum mechanics; Postulates of quantum mechanics; Electronic structure calculations; Semi-empirical and density functional theory calculations; Molecular size versus accuracy; Approximate molecular orbital theories; Monte Carlo Simulations: Calculating properties by integration, Metropolis methods. Unit V: Protein Structure Prediction Protein Structure Prediction; Homology modeling; Threading and ab initio modeling; Prediction of protein structure from sequences; Functional sites; Protein folding problem; Protein folding classes; Protein identification and characterization: AACompIdent, TagIdent, PepIdent and MultiIdent, PROSEARCH, PepSea, PepMAPPER, FindPept; Predicting transmembrane helices; Primary structure analysis and prediction; Secondary structure analysis and prediction: motifs, profiles, patterns and fingerprints search; Levinthal's paradox and the kinetics of protein folding. REFERENCES: 1. C. Stan Tsai, An Introduction to Computational Biochemistry, Wiley-Liss Inc., New

York, 2002. 2. Cynthia Gibas and Per Jambeck, Developing Bioinformatics Computer Skills,

O’Reilly, 2001 3. Andrew Leach, Molecular Modelling: Principles and Applications, 2nd Edn, Pearson

Education, UK, 2010. 4. Höltje, Hans-Dieter Sippl, Wolfgang Rognan, Didier Folkers and Gerd, Molecular

Modeling: Basic Principles and Applications, Wiley-VCH, Weinheim. 2008. 5. Alan Hinchliffe, Molecular Modelling for Beginners, John Wiley, UK, 2003

Core 12: Computer Aided Drug Design

Unit I: Introduction to cheminformatics Introduction to cheminformatics, History of cheminformatics, Applications of cheminformatics, Evolution of cheminformatics, Future scope of cheminformatics, Data and data source in chemistry, Searching chemical structures, Chemical structure file formats.

160

Unit II: Representation of chemical compounds Representation of chemical compounds, Manipulations in 2D and 3D structures of chemical compounds, Representation of chemical reactions, Molecular descriptors, Calculations of physical and chemical data, Calculations of structural deciphers. Unit III: Drug Development Drugs, Development of drug, Source of drugs, Structural effects on drug action, Drug life cycle, Drug development time lines, Stages of drug discovery, Strategic issues in drug discovery, Emerging approaches to drug design and discovery, Drug metabolism, Drug design physicochemical properties: Hansch π; Hammett σ; Es, MR, Pharmacokinetic action of drug on human body, Prodrug design and applications. Unit IV: Computer Aided Drug Design Computer Aided Drug Design, Methods of computer aided drug design, Ligand design methods, Docking algorithms and programs, Drug design approaches, Strategy for target identification and validation, Lead compound identification and optimization, High throughput screening for lead discovery, Receptor theory, Receptor models and nomenclature. Unit V: Virtual Screening and ADMET properties Combinatorial Chemistry and Library Design, Virtual screening, Drug likeliness and Compound filters. ADMET (Absorption, Distribution, Metabolism, Excretion and toxicity) property prediction, Computer based tools for drug design. REFERENCES: 1. Andrew R. Leach, Valerie J. Gillet, Introduction to Chemoinformatics, Springer,

Netherlands, 2007. 2. Frank Jensen, Introduction to Computational Chemistry, Wiley, 1999. 3. S.P.Vyas and R.K.Khar, Targeted and Controlled Drug Discovery, CBS Publishers,

2012. 4. Johann Gasteiger and Thomas Engel, Cheminformatics, Wiley-VCH, 2003. 5. Thomas Lengauer (Ed.), Bioinformatics from Genome to Drug, Wiley-VCH, 2002. 6. Kerns, E.H.; Di, L. Drug-Like Properties: Concepts, Structure Design and Methods:

from ADME to Toxicity Optimization, Academic Press, Oxford, 2008 7. Burger’s Medicinal Chemistry and Drug Discovery, 5th Edition, Vol. 1. Principles and

Practice, edited by M. E. Wolff, John Wiley & Sons: New York, 1995. 8. Principles of Medicinal Chemistry, 4th Edition, edited by W.O. Foye, T.L. Lemke, and

D. A. Williams, Williams and Wilkins: Philadelphia, 1995. 9. Medicinal Chemistry: Principles and Practice, edited by F.D. King, Royal Society of

Chemistry: Cambridge, 1994. 10. A Practical Guide to Combinatorial Chemistry, edited by A. W. Czarnik and S. H.

DeWitt, American Chemical Society: Washington DC, 1997.

161

Core 13: Free and Open Source Bioinformatics Tools

Unit I: Introduction to Free and open-source software Introduction to Free and open-source software (FOSS), Open Bioinformatics Foundation (O|B|F), Software license, Types of software, Types of software licenses, Software categories, Benefits and challenges, Bioinformatics Linux distributions (BioBrew, Bio-Linux, BioLand, Vlinux, Vigyaan, Bioknoppix, Dnalinux, and Quantian). Unit II: Free and open-source software Tools I .NET Bio, AMPHORA, Anduril, Armadillo workflow platform, AutoDock, Biochemical Algorithms Library (BALL), caCORE, caArray, LabKey Server, OpenClinica, PromKappa, MeV: Multi-Experiment Viewer, PathVisio, REDCRAFT Unit III: Free and open-source software Tools II EMBOSS, Gaggle, Galaxy, GenePattern, GeWorkbench, GMOD, GeneTalk, GenGIS, GenomeSpace, GENtle, Integrated Genome Browser, Argo Genome Browser, Integrative Genomics Viewer (IGV), IntAct, InterMine, Java Treeview. Unit IV: Free and open-source software Tools III SAM Tools, Staden Package, STAMP, Taverna workbench, TGAC Browser, T-REX WebServer, Unipro UGENE, Visomics, Genome Analysis Toolkit 1.0 (GATK 1.0). Unit V: Bio Tools Projects Bio4j, Bioclipse, Bioconductor, BioHaskell, BioJava, BioMOBY, BioPerl, BioPHP, Biopython, BioRails, BioRuby, BioSmalltalk, BioUno. REFERENCES: 1. Edwards, David; Stajich, Jason; Hansen, David (Eds.), Bioinformatics: Tools and

Applications, Springer, 2009. 2. World Wide Web

Major Elective 3: 14(a). Applications in Bioinformatics Unit I: Eukaryotic Genome applications Sequencing of Complete Genomes – Characterization of Genomes using STS and EST Sequences – Sequence Tagged Sites are Landmarks in the Human Genome – Expressed Sequence Tags – Implementation of an EST Project – Identification of Unknown Genes – Discovery of Splice Variants – Genetic Causes for Individual Differences – Pharmacogenetics and Individual Medicine. Unit II: Functional analysis of genomes Identification of the Cellular Functions of Gene Products – Basic concepts of Transcriptomics, Proteomics, Metabolomics, Phenomics, Systems Biology. Unit III: Medical and forensic applications of gene manipulation Diagnosis and characterization of medical conditions – Treatment using rDNA technology – gene therapy – DNA profiling.

162

Unit IV: Transgenic plants and animals Transgenic plants – Why transgenic plants? – Ti plasmids as vectors for plant cells – Making transgenic plants – Putting the technology to work – Transgenic animals – Why transgenic animals? – Producing transgenic animals – Applications of transgenic animal technology. Unit V: Patenting of Biological Materials Product patents and its Importance to investors – Conditions for patenting – Patenting of Liveforms – Significance of Patents in India – Some example cases of patenting. REFERENCES: 1. P.M. Selzer, R.J. Marhöfe and A. Rohwer, Applied Bioinformatics, Springer-Verlag,

Heidelberg, 2008. 2. Desmond S. T. Nicholl, Introduction to Genetic Engineering, Cambridge Univ. Press,

UK, 2002. 3. R.C. Dubey, A Textbook of Biotechnology, Rev. Edn., S.Chand & Company, New

Delhi, 2006.

Major Elective 3: 14(b). Introduction to Intellectual Property Rights Unit I : Bioethics Bioethics – Definition – Goals – History – Principles – Approaches – Need – Problem and Solution – Environmental Ethics Unit II : Ethical Issues in Biotechnology Ethical Issues in Health and Biomedical Innovation – Organ Transplant – Stem Cells – Ethical Implication in Human Genome Project – Gene Therapy – Ethical Concern on Cloning –Biodiversity – Genetic Engineering Unit III : Introduction to Intellectual Property Rights Introduction to Intellectual Property Rights (IPR) – Patent and Confidential Information – Patent System – Need of Granting Patent – International Patent System – Patentability – Novelty – Publication – Application – Future of Patent Unit IV : IPR components Trademarks – Registration – Protection – Passing off – Ownership – Copyright and Moral Rights – Duration – Dealing – Design – Registered – Unregistered – Community Unit V : BioSafety and Regulatory Agencies Bio-Safety – International Agreement – Regulation – IPR – GATT– WTO – TRIPS – WIPO – Patent Status – International scenario – UPOV – PCT – EPC – Budapest Treaty – OECD – Biological Material – Significance REFERENCES 1. Tina Hart and Linda Fazzani, “Intellectual Property Rights”, 3rd edition, Palgrave

Macmillan, UK, 2004 2. S. Ignacimuthu, S. J., “Bioethics”, Narosa Publishing House, New Delhi, 2009 3. R. C. Dubey “A Textbook of Biotechnology”, S. Chand & Company Ltd, New Delhi,

2006

163

Core Practical 3: Lab in Biological Databases

1. Search a nucleotide sequence of your interest in GenBank database, and download

the sequence in GenBank file format.

2. Search a protein sequence of your interest in SwissProt database, and download the

sequence in FASTA file format.

3. Search a nucleotide sequence of your interest in EMBL database, and download the

sequence in EMBL file format.

4. Gather information about a disease/protein from Biomed Central.

5. Collect disease/disorder genome sequence data from OMIM database, and explore

its genome assembly using UCSC genome browser.

6. Search a drug compound and pathway of a disease protein from KEGG database.

7. Find the protein families, domains and functional sites, amino acid patterns and

profiles of a protein sequence using PROSITE.

8. Align protein sequences using ClustalX/W and construct amino acid patterns from

the aligned protein sequences using PRATT.

9. Download a protein structure from PDB and visualize it using RasMol.

10. Search similar structures using VAST, and download the result and visualize it using

Cn3D.

Core Practical 4: Lab in Computational Biology

1. Global and local alignment using EMBOSS.

2. Dotplot using EMBOSS.

3. Protein properties prediction using ProtScale.

4. Multiple sequence alignment using Clustal Omega/ T-Coffee/ MUSCLE/

KalignClustalX/W.

5. Phylogenetic tree construction using MEGA/Phylip/MrBayes.

6. DNA sequence assembly using Phrap/Staden/DNA Baser Sequence Assembler.

7. RNA secondary structure prediction using mfold/RNA123/RNAComposer.

8. Protein secondary structure prediction using CFSSP/GOR/NNPREDICT/SOPMA.

9. Protein sequence to structure/function prediction using ProFunc.

10. Protein threading server LOMETS/THREADER/PSIPRED.

164

Core Practical 5: Lab in Molecular Modeling and Computer Aided Drug Design 1. Homology modeling using Swiss-Model/MODELLER.

2. Protein structure and function predictions using I-TASSER/Phyre2.

3. Automatic fold recognition server for predicting the structure and/or function of your

protein sequence.

4. ab initio protein folding and protein structure prediction using QUARK.

5. Protein side chain modeling using YASARA.

6. Protein ligand binding site prediction using COACH.

7. Search and download drug compounds using ZINC/ChEMBL/DrugBank.

8. Ligand binding site prediction using 3DLigandSite.

9. Docking using AutoDock/ZDOCK/PatchDock.

10. Protein-Ligand interaction plotting using LigPlot.

165

SEMESTER - IV

Skill Based Subject 2: 2(a) Database Management Systems

Unit I: Introduction Purpose of Database System – Views of data – Data Models – Database Languages –Database System Architecture – Database users and Administrator – Entity-Relationship model (E-R model ) – E-R Diagrams – Introduction to relational databases Unit II: Relational Model The relational Model – The catalog- Types – Keys - Relational Algebra – Domain Relational Calculus – Tuple Relational Calculus - Fundamental operations – Additional Operations Unit III : SQL Concepts SQL fundamentals - Integrity – Triggers - Security – Advanced SQL features – Embedded SQL– Dynamic SQL- Missing Information – Views – Introduction to Distributed Databases and Client/Server Databases Unit IV: Transactions Transaction Concepts - Transaction Recovery – ACID Properties – System Recovery – Media Recovery – Two Phase Commit - Save Points – SQL Facilities for recovery –Concurrency – Need for Concurrency – Locking Protocols – Two Phase Locking – Intent Locking – Deadlock- Serializability – Recovery Isolation Levels – SQL Facilities for Concurrency Unit V: Database Design Functional Dependencies – Non-loss Decomposition – Functional Dependencies – First, Second, Third Normal Forms, Dependency Preservation – Boyce/Codd Normal Form - Multi-valued Dependencies and Fourth Normal Form – Join Dependencies and Fifth Normal Form TEXT BOOKS: 1. Abraham Silberschatz, Henry F. Korth, S. Sudharshan, “Database System

Concepts”, Fifth Edition, Tata McGraw Hill, 2006. (Unit I) 2. C. J. Date, A. Kannan, S. Swamynathan, “An Introduction to Database Systems”,

Eighth Edition, Pearson Education, 2006. (Unit II, III, IV and V) REFERENCES: 1. Ramez Elmasri, Shamkant B. Navathe, “Fundamentals of Database Systems”,

Fourth Edition, Pearson / Addision Wesley, 2007. 2. Raghu Ramakrishnan, “Database Management Systems”, Third Edition, McGraw

Hill, 2003. 3. S. K. Singh, “Database Systems Concepts, Design and Applications”, First Edition,

Pearson Education, 2006.

166

Skill Based Subject

2: 2(b) Introduction to Algorithms Unit I: Algorithmic problems Sorting and searching; Graph algorithms: Graph traversal (DFS, BFS) and applications – Connectivity, strong connectivity, bi-connectivity – Minimum spanning tree – Shortest path – Matchings - Network flow Unit II: Hard Algorthmic problems Hard problems: Traveling salesman problem – Longest path, Hamilton cycle – Boolean circuit satisfiability – Clique – Vertex cover Unit III: Algorithm design Divide-and-conquer; Graph traversal; Greedy; Dynamic Programming; Reductions; Use of advanced data structures Unit IV: Algorithm correctness Proofs and proof techniques (assumptions, basic logic inference and induction); Tree and graph properties that make graph algorithms work; When does the greedy algorithm work? Unit V: Algorithm analysis Time and space complexity; Asymptotic analysis: Big Oh – Little oh – Theta; Worst case and average case analysis; Lower bounds TEXT BOOKS: 1. Thomas H. Cormen, Charles E. Leiserson, Ronald L. Rivest, Clifford Stein.

Introduction to Algorithms. 3rd Edition. The MIT Press Cambridge, Massachusetts. 2009.

167

APPENDIX - BA14

MANONMANIAM SUNDARANAR UNIVERSITY - TIRUNELVELI-12 B.Sc., Microbiology (CBCS)

REVISED STRUCTURE OF THE UG COURSE (For Disciplinary Subjects)

(For those who joined the course from the academic year 2012 onwards)

Eligibility for admission to the B.Sc., Course in Microbiology Candidates shall be admitted to the course provided he / she has passed plus two examinations of the State or Central Board with Biology / Microbiology as one of the subjects.

Semester Part Paper Instruction

Hours / Week

Exam Hours

Max Marks

Passing Minimum Credits

I

I Tamil / Other languages - Paper I

6 3 100 40 3

II English - Paper I 6 3 100 40 3 III Core Subject

Major I Fundamentals of Microbiology

4 3 100 40 4

Major II Microbial Biochemistry

4 100 40 4

Practical for Major I & II 2

Allied Subject I Paper I Bio instrumentation

4 3 100 40 4

Practical for Paper I 2 - - - -

IV Environmental studies 2 3 100 40 2

Total (6 Courses) 30 20

168

Semester Part Paper Instruction

Hours / Week

Exam Hours

Max Marks

Passing Minimum Credits

II

I Tamil / Other languages - Paper II

6 3 100 40 3

II English - Paper II 6 3 100 40 3

III Core Subject Major III Microbial Physiology and Metabolism

4 3 100 40 4

Major IV Concepts in Molecular Biology

4 3 100 40 4

Allied Subject I Environmental Monitoring and Assessment

4 3 100 40 4

Major Practical -I 2 3 100 40 2

Allied Practical -I 2 3 100 40 2

IV Value based Education 2 3 100 40 2

Total (8 Courses) 30 24

169

Semester Part Paper Instruction

Hours / Week

Exam Hours

Max Marks

Passing Minimum

Credits

III

I Tamil / Other

languages 6 3 100 40 3

II English 6 3 100 40 3

III Core Subject

III Major -V

Microbial Genetics 4 3 100 40 4

Allied Subject 4 3 100 40 4

Paper II Biofertilizer &

Biopesticides

Practical for paper V

2 - - - -

Allied Practical II 2 - - - -

IV Skill Base Subject A. Medical Lab

Technology

OR

B. Enzymology

4

3

50

20

4

IV Non Major Elective

Paper I

A. General

Microbiology

OR

B. Food

Microbiology

2 3 50 20 2

Total (6 Courses) 30 20

170

Semester Part Paper Instruction

Hours / Week

Exam Hours

Max Marks

Passing Minimum Credits

IV

I Tamil 6 3 100 40 3 II English 6 3 100 40 3 III Core Subject

Major VI Fundamentals of Immunology

4 3 100 40 4

Allied Subject 4 3 100 40 4 Paper II

Genetic Engineering

Major Practical -II 2 3 100 40 2 Allied Practical - II 2 3 100 40 2

IV Skill Based Subject Paper - III Fermentation Technology OR Aquatic Microbiology

4 3 50 20 4

IV Non Major Elective

Paper II A. Clinical

Microbiology OR

B. Basics of Biotechnology

2 3 50 20 2

V Extension activity : NSS / NCC / YRC / YWF

- - - - 1

Total (10 Courses) 30 25

171

Semester Part Paper Instruction

Hours / Week

Exam Hours

Max Marks

Passing Minimum Credits

V

III Core Subject Major VII Agricultural Microbiology

4 3 100 40 4

Major VIII Industrial Microbiology

4 3 100 40 4

III Practical for Major VII & VIII 8 - - - -

Elective Paper I - Bio informatics

5 3 100 40 5

Paper II Dairy Microbiology 5 3 100 40 5

IV Skill Based Subject

Paper II Effective Communication OR Personality Development

4 3 100 40 4

Total (6 Courses) 30 22

172

Semester Part Paper Instruction

Hours / Week

Exam Hours

Max Marks

Passing Minimum

Credits

III Core Subject Major IX

Food Microbiology

6 3 100 40 4

III Major X

Clinical

Microbiology

6 3 100 40 4

III Major XI

Microbial

Biotechnology

5 3 100 40 4

Major Practical -III 3 3 100 40 4

Major Practical -IV 3 3 100 40 4

Major Practical - V 2 3 100 40 4

III Elective Paper III Marine

Microbiology

5 3 100 40 5

Total (8 Courses) 30 29

Total Number of courses : 40 (33T + 7P)

Total number of hours : 180

Total number of Credits : 140

Distribution of marks in Theory between External and Internal Assessment is 75 : 25;

For Practicals 60 : 40 ; Pass minimum of 40% for external and overall components.

173

 

APPENDIX - BA15

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI-627 012

M.A. History with Computer Applications

CBCS- For Colleges

Second Year Syllabus

(Effective from the Academic year 2012-2013)

Total Courses: 18 Total Hours: 120

Total Credits: 90 THIRD SEMESTER

Components Hours Credits

Core Subject - 3

Elective - 1

Project - 1

3x6=18

1x6=6

1x6=6

3x5=15

1x5=5

1x5=5

Total 5 courses 30 25

FOURTH SEMESTER

Components Hours Credits

Core Subject - 3

Elective - 1

3x8=24

1x6=6

3x5=15

1x5=5

Total 4 courses 30 20

174

 

SEMESTER III - Core Paper - 1

DESK TOP PUBLISHING (PAGE MAKER AND PHOTOSHOP)

UNIT I

Introduction to DTP – Exploring common features in PageMaker, Working with files and folders, Saving, Moving and Copying, Renaming, Deleting- Editing in PageMaker: PageMaker window, creating- closing publications, Editing text-Formatting text.

UNIT II

Master Pages- placing elements on Master Page-placing Guidelines, placing header and page number, creating Master Page –removing Master Page –editing Master Page – creating columns

UNIT III

Working with Graphics and objects: Tool Bar, Placing graphic on the page, importing graphic, resizing a graphic, moving a graphics, cropping a graphic, grouping and ungrouping-Managing and printing- page-orientation-numbering-page size- dimensions-margins- table of content-Managing books.

UNIT IV

Starting with Photoshop – program window, working with images-rotating, cropping, revealing the hidden image, freehand; Making Selection-selection tool, lasso tool, copying, filling, transforming- painting tools- Drawing tools - retouching tools

UNIT V

Creating Layers- Filters- printing and customization- import, export, printing.

TEXT BOOK

COMDEX DTP Course Kit, Vikas Gupta, Dream Tech Press, 2006 Edition.

175

 

LIST OF PRACTICALS: DESK TOP PUBLISHING (PAGE MAKER and PHOTOSHOP) PAGEMAKER:

1. Design of ID Card (3”×2”) / Visiting Card (3.5”×2”)

2. Design of an attractive Invitation Card (5.5”×8”) / Letter Pad (7.5”×9”)

3. Preparation of a small Booklet with six pages (3.5”×4.5”)

4. Design of a Handbill (5.5”×8.5”) / Advertisement

5. Design of a College Progress Card / a Receipt Bill with counter foil.

PHOTOSHOP:

1. Design of a brochure for an Institution

2. Seasonal Greeting Card

3. Transporting an image from one background to another

4. Design a Web Page Poster (1004×750) / Text Book cover page

5. Crop an image / rotate an image.

THIRD SEMESTER Core Paper - 2

ECONOMIC HISTORY OF INDIA: 1757-1947 A.D.

UNIT I

A. Issues in Indian Economic History: Different Approaches and Limitations –

Sources: Archival Records – Personal Diaries- Memoranda & Appeals.

B. Indian Economy in the Mid – Eighteenth Century: Nature and Structure –

Rural And urban – Agrarian and Non – Agrarian- Industry & Technology –

Methods production Indegenous banking – Trade and Commerce – Pre –

Colonial Cottage Industries & Crafts – Towards Capital Formation & Beginnings

of Commercialization.

176

 

C. Early Phase of Colonial Economy: Mercantilism & Laissez faire – East India Company: Factories in Madras – Jute Industry in Bengal- “Drain of Wealth”, Mechanism & Impact- Indian Manufacturer for External Markets – Abolition of Zamindari.

UNIT II

Agraian Settlement and Production: Agrarian Conditions – Regional variations – Permanent Revenue Settlement of Bengal- Bank of Bengal- Ryotwari Settlement – Mirasi & Mahalwari Systems – periodic settlements – Export of Crops- Commercialization of Crops- The Great Rural – Urban Divide.

UNIT III

A. Railways and Indian Economy: Indigenous Demand for Industrial Growth- Impact of commercialization of Agriculture- Famines – national Question of Relief Measures – laying of Railway Lines – Transport of Indigenous Goods – Shipping of Finished Products into India-High Cost of Production & Exploitation: Official & Individual.

B. Decay of Traditional Arts & Crafts: Death blow to indigenous Small Scale Industries – Demand of the Congress of Industrial Industry: Cotton, Jute, Iron & Steel and Indigo- Impact of World War I on Indian Economy: Indian Wealth for British War fronts- The Great Depression & its Impact on India- Industrial Unrest – Rise of Industrial Labour Force & Labour Movements.

UNIT IV

The fiscal System : Shift from Direct to Indirect Taxation – Tariff and Excise – Monetary Policies and Credit System- price Fluctuations: Main Trends and Impact on people.

UNIT V

De-Industrialization Policy of the British: Decay of Traditional Handicraft Industries – Artisans and Handicraft Products – Industrial Capitalism and Import of English Cloth and Yarn- Debate Over De- Industrialization – Regional Variations – Handicraft Industry in Transition under Colonialism – Capital and Labour in Handicraft Industry.

177

 

BOOK FOR REFERENCE:

1. C.J. Baker, Tamilnadu: The Countryside Economy

2. Dietmar Ruthermund, An Economic History of India

3. Dharmakumar (ed.), The Cambridge Economic History of India, Vol.IIc. 1757-c.

1970.

4. David Ludden, Peasant History in South India

5. India 1000 to 2000, The Express Publication, Madurai

6. Manorama year Book

7. RC Dutt, Economic History of India, 3 vols

8. Ravinder Kumar, Essays in the Social History of Modern India

9. R. Sarada Raju, Economic Conditions in the Madras Presidency

10. Sumit Sarakar, History of Modern India, New Delhi, 2004.

Core Paper-3

HISTORY OF SOUTH-EAST ASIA, 1900-1967

UNIT I

Forming of South East Asia: Land and people of Burma - Indonesia, Indo-

China and Malaysia.

UNIT II

Establishment of Colonialism: Imperialism in the early 20th Century -

Portguese in Malay Peninsula-Dutch in Indonesia-French in Indo-China and British in

Burma.

UNIT III

European Imperialism in South East Asia: Burma, Malaya-Indonesia and

Indo-China in the Inter-War Period-Japan in South-East Asia during Second World War

- Philippines.

178

 

UNIT IV

Decolonization in South East Asia: Burmese Independence Establishment of

Indonesian Republic-Achievement of Independence in Indo-China.

UNIT V

Post-Colonial Phase: Burma-Indonesia-Vietnam-Laos-Combodia-Malaysia-

Singapore.

BOOKS FOR REFERENCE

1. Berry, Society and Culture in Southeast Asia

2. Claude A. Bears, Asia in the Modern World

3. Chatterji, B.R., History of Indonesia

4. Duncanson, Government and Revaluation in Vietnam

5. Harvey, G.E, History of Burma

6. Hall, D.G.E, A History of Southeast Asia

7. Roff William, R., The Orgins of Malaya Nationalism

8. Thompson, V., French Indo-China.

Elective Paper - 1

CONSTITUTIONAL HISTORY OF ENGLAND FROM 1603 TO 1958A.D.

UNIT I

The Stuart Period - James 1 and his four Parliaments - Charles I and his first

three Parliaments - Petition of Rights - Personal Rule Long Parliament - Execution of

Charles I- the Common Wealth - the Constitutional Experiments of Cromwell.

UNIT II

Restoration - Charles II - Convention Parliament - Cavalier Parliament -

Clarendon Code - Glorious Revolution of 1688 - Bill of Rights and Act of Settlement,

1701.

179

 

UNIT III

Parliamentary growth under George I and George II - Growth of Cabinet System

- Evolution of the position of Prime Minister - George III and his Personal Rule -

Evolution of Party System.

UNIT IV

The Age of Reforms - Act of 1832, 1867, 1882, 1884, 1885. Parliamentary Act of

1911, Act of 1918, Act of 1928, Balfour Report and the Statute of Westminster.

UNIT V

Reorganization of Judiciary during 19th & 20th Centuries - Party System – House

of Commons - House of Lords - Commonwealth of Nations.

BOOKS FOR REFERENCE:

1. Keir, D.L., - Constitutional History of Modern Britain

2. Adams, G., - Constitutional History of England

3. Hall, - A Brief Survey of English Constitutional History

4. Jennings, I., - The British Cabinet System

5. -do- - Law and Constitution

6. -do- - The British Constitution

7. -do- - Rule of Law

8. Maitland, T, - English Constitutional History with Documents

9. Stubbs - Constitutional History of England

10. Mariot - Constitutional History of England

180

 

Group Project:

PROJECT

A group project study is introduced in order to develop research skill among

the students. Each group should have minimum 4 candidates. The students are

required to choose a fresh topic and to refer original primary sources as well as

secondary data for the completion of the dissertation / project work. The work should

include “Bibliography” citing the original and other sources that are consulted in the

preparation of the project.

EVALUATION

Project 70 Marks

Viva 30 Marks

Total 100 Marks

181

 

FOURTH SEMESTER Core Paper - 1

INTERNET AND HTML WITH LAB INTERNET AND HTML

UNIT I Introduction to Internet: Computers in business –Network- Internet- Electronic

mail- Resource sharing –Gopher-WWW-Usenet-Telnet-Bulletin services-Wide Area

information service. Internet browsers: Internet Explorer –Netscape Navigator

UNIT II Introduction to HTML: Designing a Home page – History of HTML – HTML

generations- HTML Documents-Anchor tag –Hyper links –Sample HTML documents.

Head and Body section: Header Section –Title-Prologue-Links-Colorful web page –

Comments lines. Designing the body: Heading printing –Aligning the headings-

Horizontal rule-paragraph-Tab settings-Image and pictures-Embedding PNG format

Images

UNIT III Ordered and unordered lists: List-Unordered lists- headings in a list –ordered

lists- Nested lists. Table handling: Tables- table creation in HTML- Width of the Tables

and cells-Cells spanning multiple rows/Columns- Coloring cells –Column specification UNIT IV

DHTML and Style sheets: Defining styles –Elements of styles-Linking a style

sheet to an HTML document –Inline styles –Internal & External style sheets –Multiple

styles

Frames: Frame set -Definition – Frame definition –Nested Framesets

UNIT V Forms: Action attributes –Method attributes – Enctype attribute –Drop down list

TEXTBOOK:

1. World wide web design with HTML, C. Xavier, TMH, 2001

2. Fundamentals of information technology, Mathews Leon and Alexis Leon, Vijay

Nicole private limited, Chennai.

182

 

REFERENCE BOOK:

1. Internet & World Wide Web, H.M.Deital, P.J.Deital & A.B.Goldberg, Pearson

Education.

2. Introduction to Information Systems, Alexis Leon and Mathews Leon, Vijay Nicole

private limited, Chennai.

PRACTICAL –INTERNET AND HTML

1. Write a HTML code to display information about your college.

2. Create a table to display the marks obtained in the exam.

3. Develop a complete web page to describe your skills in various areas.

4. Develop a website to publish your family and the details of each member.

5. Develop a complete web page using frames and framesets, which give the

information about a hospital.

6. Write a few HTML documents each explaining about a district of your state. The

list of districts must appear in a frame. When we click on a district, the details

must appear in another frame.

7. Write a set of frames to show your biodata in a colorful form with suitable links.

8. Write a HTML code to display list of 5 cars in a frame. Link each one to the brief

description in second frame.

183

 

Core Paper - 2 MODERN INDIA WITH REFERENCE TO FREEDOM STRUGGLE

(1757 A.D - 1947 A.D.)

UNIT I

Stages of Colonialism, Imperialism, Capitalism -. Nascent Nationalism -

Resistance of Indian rulers and chieftains - Various peasant and Tribal uprisings and

military Revolts.

UNIT II

Introduction of Western Education - Socio - Religious Reform Movements - Role

of the Press and Indian Awakening - Pre-Congress Associations - Formation of the

Indian National Congress, 1885.

UNIT III:

Constitutional Methods of Agitation: Aspiration and Demands of the Congress

Struggle and Strategy – Moderation and Extremism – Drain of wealth- Appeals,

Resolutions and Petitions - Role of Congress Leaders - Popular Methods of Agitation -

Partition of Bengal 1905, - Swadeshi and Boycott Movernents- Split in the Congress –

Rise of militant nationalism.

UNIT IV

Rise and Growth of Home Rule movement – Revolutionary Movement:

Maharastra, Bengal and Madras - Press and Literature in Bengal - Role of Shyamji

Krishna Verma, V.D. Savarkar, Madam Cama, MN Roy, MPT Acharya - Alipur

Conspiracy - Maniyatchi Incident - The Gaddar Party - Udham Singh and Bhagat Singh.

184

 

UNIT V

Gandhian Era: Gandhi’s Entry into Politics .- Non-Cooperation Movement, Chauri

- Chaura Incident - Swarajist Party -Motilal Nehru - Simon Commission, Nehru Report -

Jinnah’s 14 Points (1929) - Civil Disoobedience Movement (193034) - Gandhi-Irwin

Pact (1931) - Communal Award - Poona Pact - Cripps Proposals - Quit India Movement

(1942) - Muslim League and Demand for Pakistan - CR Formula - Rash Behari Bose -

Subash Chandra Bose & Indian National Army – Towards Freedom.

BOOKS FOR REFERENCE:

1. Agarwal, R.C., National Movement and Constitutional Development in India.

2. Ahluvalia, H.M., Freedom Struggle in India 1857-1909.

3. Bipin Charidra, India’s Struggle for Independence 18574947.

4. Bipin Chandra, Communalism in India.

5. Ghose, K.K., The Indian National Army.

6. Gopal, S., The British Policy in India 1858-1905.

7. Gupta, D.C., Indian National Movement.

8. Majumdar, R.C., History of Freedom Movement/n Bengal, Vols. I to II.

9. Pattabhi Sitaramayya, History of Indian National Congress; Vol.1 & II.

10. Rajayyan, K., South Indian Rebellion 18004801.

11. __________, Freedom Struggle in India.

185

 

Core Paper - 3

CONTEMPORARY INDIA SINCE 1947 A.D

UNIT I

Partition of British India: Demand for Pakistan – Post Independent India –

Resettlement & Repatriation Problem-Integration of Princely States: Kashmir,

Hyderabad & Junagarh - Role of Vallabhai Patel – Framing of adoption of the

Constitution - Features of the Constitution-Republic of India-General Elections-

Congress in Power-Cabinet Government & Party System-Bureaucracy-Judiciary

UNIT II

India’ Foreign Policy: It’s Basic Concepts - Panchaseela & Non-Alignment -

India and its Neighbours – Indo - Pak Relations – Indo - Sri Lankan Relations – Indo -

Bangladesh Relations & lndo - China Relations-India & The UN- Commonwealth,

SAARC, NAM-Indo-US & Indo-Russian Relations-India and Disarmament, NBT and

CTBT

UNIT III

Economic Development: Planning in lnaia Five Year Plans & Annual Plans -

National Development Council and its Role-Welfare Programmes of the Government-

IRDP, Jawahar Rozgar Yojana, etc, Growth of Education Radhakrishnan Commission-

AL Mudaliar Commission Kothari Commission, etc., - National Literacy Mission-Acharya

Commission- New Educational Policy (1986) - Navodaya Schools

UNIT IV

Development of Science and Technology Atomic Energy Commission (AEC) and

its Programmes-Indian Space Research Organization (ISRO) and its Programmes-

Defence Research and Development Organisation (DRDO) and its Programmes-Missile

Technology and its Development-Bio Technology-Green, White and Blue Revolutions-

Development of Communication - Railways, Roadways, Airways.

186

 

UNIT V

Makers of Contemporary India: Nehru, Patel, Indra Gandhi, CV Raman,

Radhakrishnan, Visveswarayya, HJ Bhaba, Vikram Sarabhai, HN SethnaShanti Swarup

Bhatnagar, BC Roy, M.S Swarninathan, Vargheese Kurian and APJ AbdulKaIam.

BOOKS FOR REFERENCE

1. Basu, D.D., Introduction to Indian Constitution, Culcutta, 2002.

2. Bipan Chandra, India After Independencel947- 2000, New Delhi,

3. John. Gilbert; G., Contemporary History of India, New Delhi, 2006.

4. Pylee, M.V., Indian Constitution, 2000.

5. Paul R. Brass, The Politics of India Since Independence, New York,2001.

6: RajaniKothari, Politics in India, New Delhi, 2003.

7. Sumit Sarkar, Modem India, New Delhi, 2004.

8. Dr. Sobitha Bai, Contemporary History of India 1947 – 2009 A.D., Marthandam.

187

 

Elective paper - 1

TWENTIETH CENTURY WORLD

UNIT I

Legacy of the Nineteenth Century – Modern State and its evolution - Growth of

Capitalism and Imperialism – Liberalism - Socialism - Nationalism.

UNIT II

World order upto 1919, First World War - its Nature, Peace Settlements and

Consequences – Reparation and war debts; Daws plan – young Plan, Disarmament

and concern for security – Washington Naval conference, Locarno pact – Kellogg

Briand Pact - Russian Revolution — Establishment of Socialist State Economic and

Political Policies - Lenin

UNIT III

League of Nations : Collective Security - Great Depression –Rise of Totalitarian

powers - Stalinism - Nazism and Fascism – Japan - Second World War – Surrender of

Japan and Germany – New Political Order - Sunyatson and Chinese Revolution –

Communist Revolution in China.

UNIT IV

Cold War Era: Ideological and Political Basis - Pacts and Treaties - UNO and

World Peace - Regional issues: Cuba, Korea, Palestine; Berlin wall demolition –end of

cold war.

UNIT V

Civil Rights Movement in USA - Ending the, Ea of Apartheid - Nelson Mandela,

Rise - Disintegration of Socialist Bloc - Change in the Political Order- Bi -Polar to Uni –

Polar world – BRICS, G8, G20, WTO

188

 

BOOKS FOR REFERENCE:

1. Palmer and Perkins - International Relations

2. William Schuman - International Politics

3. Margantha, Hans J., - Politics Among Nations

4. E.H. Carr - The World between Two World Wars

5. - do- - The Twenty Years Crisis, 1919-1939.

6. Charles P. Schleicher - Introduction to International Relations.

7. M.S. Rajan - United Nations and Domestic Jurisdiction

8. Hartman - World in Crisis

9. Eric Hobsbawm - Twentieth Century World

10. William R. Keyler - The Twentienth Century world.

********************

189  

APPENDIX- BA16

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI-12

M.A., ENGLISH

AND

M.A.ENGLISH WITH COMPUTER APPLICATIONS

CBCS- For affiliated colleges

(Effective from the Academic year 2012-2013 onwards)

The following corrections have been made in the syllabus for M.A.English & M.A.English with Computer Application courses for those who have joined the

courses from the academic year 2012-2013.

Name of the Course

Semester Title of the Paper & Unit

Corrections made

M.A.English

III Critical Theory II-

Unit III

Edward said: “Introduction” in Culture and Imperialism” instead of

Edward said : Culture and Imperialism

(Page No.158 of Appendix AZ90)

III Literature in Translation – Unit V

Fiction II instead of ‘Drama’

(Page No.161 of Appendix AZ90)

M.A.,English with Computer Application

III Critical Theory II-

Unit III

Edward said: “Introduction” in Culture and Imperialism” instead of

Edward said : Culture and Imperialism

(Page No.88 of Appendix AZ86)

III Literature in Translation – Unit V

Fiction II instead of ‘Drama’

(Page No.94 of Appendix AZ86)

.*********

 190

 

APPENDIX-BA17

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI-12

M. PHIL., ZOOLOGY

FOR AFFILIATED COLLEGES

(For those who joined the course from the academic year 2013-2014 onwards)

Scheme of Examination:

NO Internal passing minimum for Theory, Dissertation and Viva-Voce

External pass 50% Theory

Total Passing minimum -50%

Subject Exam Hours

Teaching Hours/weak

Credits TotalMarks Passing Minimum 25 75

SEMESTER I Paper I: Research Methodology Paper II: Advances in Animal Biotechnology and Nanotechnology SEMESTER II PAPER III Optional

3 3 3

6 6 6

8 8 8

100

100

100

50

50

50

Dissertation related to the optional paper (chose any one of from 6)

24 credits Total Marks 300 Project Viva

150 50 200 ( credits 16)

Total 500

 191

 

SEMESTER I

Paper I: Research Methodology

Paper II: Advances in Animal Biotechnology and Nanotechnology

SEMESTER II

Paper III (Optional)

1. Climate change and insect biodiversity

2. Aquatic Ecology

3. Recent advances in aquaculture technologies

4. Sericulture

5. Systematics, evolution, phylogeography, phylogenetics and conservation of freshwater fishes.

6. Remote sensing and Geographic Information system. (GIS)

Eligibility for Admission:

M.Sc. in Zoology/ Life Sciences/ Marine Biology/ Environmental Sciences/ Biotechnology/ Fishery Science/ Wild life Biology/ Aquaculture/ Bioinformatics/ Entomology/ Sericulture.

Internal 50, External 150

Dissertation shall be evaluated by the external examiner for 150 marks. This will be treated as external mark (150). The viva-voce examination shall carry a maximum of 50 marks (Guide 25 another examiner 25). This will be treated as Internal marks (50).

Qualification norms for the appointment of teachers to handle the classes:

Ph.D or M.Phil with 5 years Research Experience.

 192

 

SEMESTER – I

Paper 1- Research Methodology

Unit I:

Sources of research data- methods of collection, analysis and interpretation. organization of research paper, web based literature survey, citation index, impact factor, copy right, plagiarism.

Unit II:

High Performance Liquid Chromatography (HPLC) and its applications; SDS PAGE and Gradient Gel Electrophoresis, separation of nucleic acids; Gel Documentation, Isoelectric focussing, Southern,Northern and Western blotting techniques; Polymerase Chain Reaction (PCR), Microscopy- SEM, TEM, Flourescence.

Unit III:

Immunology: Radio Immuno Assay (RIA), ELISA&Hybridoma technology and their applications; Rapid Immunodiagnostic procedures – Microbiology; Colony Forming Unit (CFU); Evaluation of antimicrobial activity – Kirby- Bauer procedure; Minimal Inhibitory Concentration (MIC); Qualitative analysis of water; Most Probable Number (MPN) index and Membrane filter technique; Cultivation of anaerobic microorganisms: GasPak system and Minimal Inhibitory Concentration (MIC).

Unit IV:

Diversity indices, using of softwares for calculating Biodiversity methods.

Unit V: Bioinformatics-definition: Biological databases; Sequence comparison; Multiple

sequence alignment; Profiles, motifs and feature identification; Phylogenetic data analysis, Bioinformatics in genomes; Bioinformatics software. REFERENCE BOOKS: 1. Rana, S.V.S. 2005. Biotechniques – Theory and Practice, Rastogi Publishers,

Meerut, India, 259 pp. 2. Veerakumari, L. 2006. Bioinstrumentation, M.J.P. Publishers, Chennai, 556 pp. 3. Das, H.K. 2005. Text Book of Biotechnology (2nd Edition), Wiley Dreamtech India Pvt. Ltd., 1495pp. 4. Odum, E.P. 1983. Basic Ecology, Holt Saunders Publishing, Japan, 613pp. 5. Dash, M.C. 2001. Fundamentals of Ecology, Tata McGraw-Hill publishing Co. Ltd.,

NewDelhi, 525 pp. 6. Altmann, J. 1974. Observational study of behaviour: sampling methods,

Behaviour,49: 227-267.

 193

 

SEMESTER – I

Paper II – Advances in Animal Biotechnology and Nanotechnology Unit I: Cell dynamics, recombinant DNA technology, Introducing DNA into animal cells:

Injection, electrophoration, viral vectors Allitic exchange, vector less mode of gene

transfer Tissue culture in biomedical and biochemical research; regulatory proteins,

blood products vaccines and hormones.

Unit II: Transgenic animals, fertilization and embryo transfer, foreign gene expressions –

IPM – Mapping and sequencing the Human genome, The human genome project

&ethical, legal and social issues. Ethical issues in animal biotechnology – Genetically

modified organisms, phylogenetics using mitogenomes.

Unit III: Utility of Biotechnology and genetic engineering. Genomics and proteomics DNA

fingerprinting – diagnostic and forensics – Gene therapy, probes – monoclonal

antibodies – detection to genetic diseases, DNA bar-coding of animals.

Unit IV: Nanotechnology basics – Introduction to nanoworld, classification of nano materials,

application of nano crystals, nano factories, mechano chemistry, nano biosensors –

optical biosensors – DNA sensors Quantum dots – application in biotechnology – Is

nanotechnology bad or good?

Unit V: Nanotechnology in biomedical applications nanomedicines and drug delivery

systems, health and environmental impacts of nanotechnology.

Reference Books: 1. Balasubramanian, D., C.F.A. Bryce, K.Dharmalingam, J.Green and Kunthala

Jayaraman 2005, University press (India) private limited 502 pp.

2. Gupta, P.K.K..K Roy and M. Prasad DNA chips micro arrays and Genomics current

Science Vo.77, p875-884.

 194

 

3. Kumar, H.D., 1998 Modern concepts of Biotechnology, vikas publishing house pvt.

Ltd., New Delhi.

4. Niemeyer, C.M., C.A. Mirkin (2004). Nano biotechnology: concepts applications and

Perspectives, Wiley – VCH, ISBN: 3527306587.

5. Ratledge, C. and B. Kristiansen, basic biotechnology, Cambridge University Press.

6. Singh, B.D., 2003. Biotechnology, Kalyani Publications, Chennai.

7. Sree Krishna, V. Bioethics and Biosafety in Biotechnology, New Age International

Publishers., New Delhi.

8. Subbiah Balaji 2010. Nanobiotechnology. MJP Publishers, Chennai.

9. Willner, E. Katz (eds) (2005). Bioelectronics: from Therapy to Applications, Wiley –

VCH Verlag GmbH & Co. KGaA, ISBN: 352730690.

SEMESTER – II

Paper - III OPTIONAL: 1

CLIMATE CHANGE AND INSECT BIODIVERSITY

Unit I: Insect evolution and importance of insects in ecosystems, evolutionary

processes, molecular basis for ecological genetics.

Unit II: Insects and temperature, climate change and insect ecology, phenology,

diapauses, seasonality, nutritional ecology.

Unit III: Plant-herbivore interactions, plant defense theory, fundamentals of population

dynamics, evolutionary interactions between prey and predator.

Unit IV: Mutualism, pollination ecology, ecosystem function and services, north

expansion and south contractions of insect distribution altitudinal and latitudinal shifts.

 195

 

Unit V: Micro and macro evolutionary processes of insects by climate change, species

interactions, species extinctors, community changes, Rising carbondioxide levels on

pathogens and diseases.

Reference Books:

1. Rainers,s &C.Petzoldt (eds.) 2005. Integrated crop and pest Management

guidelines for commercial vegetable production. http://www.ny.sees.cornell.edu

2. Kareiva, P.M., J.C. Kingslover and R.B. Huey 1993(eds.)

3. Biotic interactions and global change, Sinauer Associates.

4. Speight, M.R., M.D. Hunter and A.D. Walt 1999 Ecology of Insects and applications.

Blackwell Scientific Ltd.

5. Samways, M.J. 2005 Insect diversity conservation Cambridge University press.

6. Huggaker, C.B. and A.P. Gutiercz 1998. Ecological Entomology, Wiley publishing

house pvt. Ltd.

OPTIONAL: 2

AQUATIC ECOLOGY

Unit I:

Structure of aquatic system, lotic and lentic, estuarine and coastal marine, climate change on aquatic ecosystems, Running waters – river continuem, flood pulse concept.

Unit II:

Auatic animals – Phytoplankton, Zooplankton, Periphyton in streams and lakes, macrophytes, aquatic invertebrates and fishes, community structure of animals.

Unit III:

Biogeography community assembly disturbance introuduced species in lakes and reservoirs.

 196

 

Unit IV:

Patterns of diversity inn aquatic ecosystems, threats to aquatic ecosystems, conservation of aquatic systems, Restoration of lakes, rivers and freshwater wetlands, Management of swamps, seagrass beds in estuarine and coastal marine systems.

Unit V:

Policies and Acts related to Aquatic ecosystems, Indian water policy, transboundary river disputes, River water sharing, Interlinking of rivers in India.

References:

1. Wetzel, R.G. 2001. Limnology, Academic Press. 2. Dodds, W.K. 2007. Freshwater Ecology Concepts and Environmental Applications,

Academic Press. 3. Allan, J.D. 1995. Stream Ecology, structure and function of running waters, Kluwer

Academic publishers. 4. Hauer, F. R and G.A. Lamberti, 1996. Methods in stream Ecology, Academic Press. 5. Pielox, E.C. 1998. Freshwater Univeristy of Chicago Press, Illinois. 6. Castro, P. and M.E. Huber, 1997. Marine Biology, Mc Graw Hill company IUCN

wetlands. OPTIONAL: 3

RECENT ADVANCES IN AQUACULTURE TECHNOLOGIES

Unit I: Culture ecosystems of fin fishes and shellfishes – Freshwater, brackish and

sew-water systems – Characteristics and features

Unit II : Aquaculture engineering – Site selection, layout, plan, design and construction of

fresh and brackish water farms and its components. Aerators and pumps in aqua farms,

Open sea farming – Design fabrication and construction of raft and retaining structures -

seaweed farming

Unit III: Species selection and seed production of fin fishes and shellfishes. Genetic and

socio-economic considerations for species selection. Seed resources – natural,

hatchery production. Hatchery technology – problems encountered in large-scale

production

 197

 

Unit IV:

Maintenance and management of aqua farms of fin fishes and shellfishes – pre-

stocking and post-stocking management - determination of stocking density. Nutritional

requirements – Natural foods – Formulation of diets – Storage and feeding techniques –

Live food organisms – mass culture. Harvesting – size, methods, production estimation.

Major diseases in aquaculture. Best management practices (BMP)

Unit V:

Advances in aquaculture grow-out technology – Integrated aquaculture –

Utilization of sewage. Friendly ecosystem through aquaculture. Environmental issues

connected with aquaculture.

REFERENCE BOOKS: 1. Badrach, J E et al. (1972). AQUACULTURE – Wiley Intersciences.

2. Boyd, C.D. (1979). Water Quality in warm water fish ponds.

3. Jhingran, A.G. 1983 Fish and Fisheries of India. Hindustan Publishing Corporation,

India.

4. Pilliai, T.V.R and M.N. Kutti., 2005. Aquaculture Principles and practices, Blackwell

Publishing Ltd, 640 pp.

5. Pillai, T.V.R Aquaculture and the environment, 2004, Blackwell Publishing Ltd,

208 pp.

6. John liu, 2007. Aquaculture genome technologies Blackwell Publishing Ltd, 528 pp.

7. David Scarfe, A Cheng-Sheng Lee and Patricia O’ Bryen Aquaculture biosecurity

2006, Blackwell Publishing Ltd, 188 pp.

8. Odd- Ivar Lekang, 2007, Aquaculture Engineering, Blackwell Publishing Ltd, 352 pp.

 198

 

OPTIONAL: 4 SERICULTURE

Unit I Introduction – Definition – Scope – state of the art of silk industries in China, Japan

and India; Mulberry and Non Mulberry Silk Industry in India.

Mulberry Silkworm races – Classification on the basis of the origin and voltinism –

characteristic features. Seed organization – seed Cocoon production – silkworm egg

production – Pure, hybrid.

Non mulberry silkworms – different species – habit and habitats; Food plants (a)

Tasar food plants – Terminalia species – Shorea Robusta (b) Muga food plants –

Listsea Polyantha – Guercus sp. (c) Eri food plants – Castor, Tapioca.

Unit II Mulberry growth and nutrition: Importance of oil in Mulberry cultivation – Sources

of nutrients in soil – Role of essential elements in plant growth of Mulberry. Propagation

(a) Seedlings – Methods of raising seedlings. (b) saplings – selection of plants for

cutting (c) grafting: Selection of stock and scion – physiological features – grafting

types- stem, root, and bud techniques (d) layering: types – techniques. Nursery raising:

layout: bed size – oil composition.

Mulberry Forms: bush, middlings and low trees, monocrop and mixed crop pattern.

Suitable variety for cultivation – manuring. Planting system: Row and pit system –

advantages and disadvantages - Intercultivation – Time and type of initial harvests.

Unit III: Silk worm – Systematic position – Order Lepidoptera – Family Bombycidae, life

history of Bombyx mori – morphology of egg, larva, pupa and adult. Morphology and

anatomy of the organ systems in silkworm Digestive System including mouth parts –

excretory, respiratory, circulatory, muscular, nervous and reproductive Systems – Silk

gland structure silk proteins, moulting and hormonal control of metamorphosis.

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Rearing: Selection of site model house, Rearing appliances, Disinfection: Types of

disinfection – concentration of disinfectants – Selection of races for rearing Biovoltine

and multivoltine their advantages and disadvantages. Incubation – influence of

environmental conditions on egg development – black boxing. Chawki rearing:

Brushing different types – loose eggs and sheet eggs. Cellular and mass brushing –

Selection of leaf for brushing – Time of transportation and storage of leaf for Chawki

worms- environmental conditions – leaf requirement – different Chawki rearing methods

– box rearing – Cellular rearing – bed cleaning with new – feeding schedule spacing –

Symptoms and care during moulting periods. Late age rearing: Spacing- leaf

requirement- environmental conditions – feeding and bed cleaning schedules –

methods of rearing: Shelf, shoot and floor rearing- advantage and disadvantages – Bed

cleaning schedules. Mounting: Types of mountages – bamboo – plastic, evolving –

rotary- bottle brush- advantages and disadvantages – Spinning- environmental

conditions for spinning. Harvesting of cocoons; Time of harvest – Sorting of cocoons –

preservation, transportation of cocoons – leaf cocoon ratio – cost of cocoon production.

Unit IV: Diseases of Silkworm – Introduction and Classification of different types of

Silkworm diseases, Protozoan diseases – pebrine – symptom – and mode of infection –

prevention and control. Bacterial disease – Flacherie- Symptoms – Causative agents –

factors influencing Flacherie – Sources and mode of infection – prevention and control,

viral diseases – grasserie – Symptoms mode of infection- defection, prevention and

control Fungal diseases – Muscardine – Symptoms of different types of fungal diseases

– Causative agents mode of infection – Prevention and control. Aspergillus diseases

symptoms – Causative agents – mode of infection – prevention and control, General

account of disinfection and relative efficiencies of different disinfections.

Disease of mulberry: Classification of diseases of mulberry. Fungal diseases of

Mulberry and their occurrence – Symptoms and control, a) leaf spot, b) leaf rust, c)

powdery mildew, d) Leaf blight, e) Root rot bacterial – viral and mycoplasmal diseases

of mulberry – control measures.

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Root knot nematode diseases of mulberry – its occurrence – Symptoms and

control. Mineral deficiency Symptoms mulberry and reclamation, Fungicide

formulations and method of applications.

Unit V: Cocoon marketing – Cocoon markets – Transport of Cocoons – Compositin of

cocoon – Physical characters of Cocoon considered for commercial purposes –

Defective Cocoons.

\ Silk reeling: Stifling – Storage of Cocoons – Sorting of Cocoon – Deflossing –

Cocoon riddling – Coccon mixing or blending – Cocoon boiling and brushing - Brushing

– Reeling operations – Reeling Appliances – Re-reeling – finishing – Raw silk Testing –

Silk wastes.

REFERENCE BOOKS: 1. Danding, S B Jayant Jayaswal K Giridhar 2000. Handbook of Sericulture

technologies. Central silk Board. Banglore, India.

2. Gang, G and J Sulochana Chetty 1991. An introduction to sericulture, Oxford & IBH

publishing Co. Pvt,Ltd. New Delhi, India.

OPTIONAL: 5

SYSTEMATICS, EVOLUTION, PHYLOGEOGRAPHY, PHYLOGENETICS AND CONSERVATION OF FRESHWATER FISHES

Unit I:

Taxonomic methods, genetic variability, speciation, hybridization, nomenclature.

Unit II: Evolution of chondrichthys, osteichthys, Actinopterygii, structural changes in

Actinoppterygians, evolutionary trends in teleosts.

Unit III: Zoogeography of freshwater fishes – Africa, Neotropical, Oriental, Palaeartic,

Nearctic, Australian regions, plate tectonics and distribution of fishes phylogeography,

phylogenetics using mitogenomes, phenology and osteology.

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Unit IV: Tropical freshwater lakes and streams – physico-chemical features, fish

communities speciation in African cichlids, lessons from tropical fishes.

Unit V: Threats to fish biodiversity, habitat degradation, conservation of fish genomes,

Danio rerio – model verterbrate for genomic and biomedical studies, mitogenomes in

fish conservation.

References: 1. Moyle, and J.J.Cech, Jr. 2006. Fishes on introduction to ichthyology, Prentice Hall.

2. Rehm, H. 2006. Protein biochemistry and proteomics Academic Press.

3. Ray, W.L. Grossmen, Moldave K. (eds) 2008. Recombinant DNA technology,

Academic Press.

4. Arratia, G. 1997. Basel teleosts and teleostean phylogeny Paleo Itchthyologica,

7:1-168.

5. Ricardo Betancur, R et al. 2013. The Tree of Life and a new classification of bony

fishes, PLOS currents Tree of Life, 1-44.

OPTIONAL: 6

REMOTE SENSING AND GEOGRAPHIC INFORMATION SYSTEM.(GIS)

Unit I: Basic principles Electromagnetic spectrum, spectral reflectance, Multi and hyper

spectral imaging systems remote sensing platforms, data products, aerial data and

satellite data, types of remote sensing, advantages of remote sensing.

Unit II: Types of sensors, Earth resource and environmental satellites, image, restoration,

extraction, Hardwares and softwaes in image processing and their uses. Satellite Data

products, Interpretation, Image processing structure of digital image, image restoration,

image enhancement, information extraction, Hardware and software image processing.

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Unit III: Remote sensing in natural resources monitoring, Geological overview, mineral and

oil exploration Drainage network, Landforms and geomorphology land use, land cover

mapping, Soil mapping and wetland mapping. Hazardous mapping.

Unit IV: Land use and land cover with Geographic Information system, Digital Terrain

Models, elevation models, vegetation mapping, GIS.

Unit V: Future trends in Remote sensing – Remote Sensing, Geographic Information

System – common applications, advantages of GIS, Essential elements of GIS, expert

system in GIS and ecosystem management. Hazardous Management landslides,

earthquakes, volcanoes, floods and , tsunami using Remote sensing and GIS.

REFERENCES: 1. Remote sensing in Geosciences 1998, Tripathi N.K and Vishwanath Bajpai, Anmol

publishing Pvt..Ltd, New Delhi, 299 pp.

2. Text Book of Remote Sensing 2005, Agarwal C.S and Garg. P.K Wheeler publishing ,

NewDelhi, Allahabad, 196 pp.

3. Remote Sensing 2007. Floyd F. Sabins, W.H. Freeman and company, 494 pp.

4. Chandra, A.M.2006. Remote sensing and Geograybical Information system. Narosa

Publishing House, New Delhi 308 pp.

*******

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APPENDIX - BA18

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI-12 M. Sc. NANOSCIENCE

Modified Syllabus For those who have joined the course from the

Academic year 2013-2014 and afterwards CBCS- For Colleges

COURSE STRUCTURE AND SCHEME OF EXAMINATION UNDER CBCS SYSTEM

Sl. No

Title Hrs Credits Internal Marks

External Marks

First semester

1 INTRODUCTION TO NANOSCIENCE 5 4 25 75

2 ORGANIC CHEMISTRY - I 5 4 25 75

3 INORGANIC CHEMISTRY – I 5 4 25 75

4 PHYSICAL CHEMISTRY – I 5 4 25 75

Second semester

5 SYNTHESIS OF NANOMATERIALS 5 4 25 75

6 NANOCOMPOSITES 5 4 25 75

7 INORGANIC CHEMISTRY -II 5 4 25 75

8 ORGANIC CHEMISTRY - II 5 4 25 75

9 ORGANIC CHEMISTRY PRACTICAL 6 4 40 60

10 INORGANIC CHEMISTRY PRACTICAL 6 4 40 60

11 PHYSICAL CHEMISTRY PRACTICAL 6 4 40 60

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Third Semester 40 60

12 CHARACTERIZATION OF NANO

MATERIALS 5 4 25 75

13 NANOBIOTECHNOLOGY 5 4 25 75

14 PHYSICAL CHEMISTRY – II 5 4 25 75

15 ORGANIC CHEMISTRY - III 5 4 25 75

Fourth Semester

16 CARBON NANOMATERIALS 5 4 25 75

17 PROPERTIES OF NANOMATERIALS 5 4 25 75

18 INORGANIC CHEMISTRY - III 5 4 25 75

19 PHYSICAL CHEMISTRY III 5 4 25 75

20 NANOSCIENCE PRACTICAL -I 6 4 40 60

21 NANOSCIENCE PRACTICAL -II 6 4 40 60

22 PROJECT AND VIVA VOCE 10 6 - 100

Total number of papers = 22 Total number of hours = 120 Total number of credits = 90

Eligibility qualification for admission to M. Sc. Nanoscience

B.Sc Chemistry; B.Sc Applied Chemistry; B.Sc Industrial Chemistry: B.Sc Nanoscience & Nanochemistry; B.Sc Biochemistry, other degrees equivalent to B.Sc Chemistry Degree.

Evaluation: The evaluation for each course consists of two components that is internal and external Theory; External: internal = 75:25 Practical; External: internal = 60:40

External Theory The external evaluation will be based on the examinations to be conducted at the end of each semester Practical Practical examinations will be conducted at the end of second and fourth semesters. Viva-voce examination will also be conducted during the practical examination

Internal

The internal component consists of the following:

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Theory: The 25 marks for the internal component has been divided as follows; 3 compulsory test, out of which average of the best two tests = 15 Marks Assignment = 04 Marks Seminar = 06 Marks ---------------- Total = 25 Marks ---------------- Practical: External: internal = 60:40 And the internal components of 40 marks is divided as follows: For the periodical class assessment = 25 Marks Record = 05 Marks One test = 10 Marks ------------------ Total = 40 Marks --------------------

There is no internal passing minimum. There is a passing minimum of 50% for external and overall components. Project and viva- voce The project report evaluation and the viva voce will be conducted by both the External examiner and the guide at the end of the IV semester The break up for the project work Dissertation evaluation = 60 Marks Viva voce = 40 Marks ----------------- Total = 100 Marks

------------------

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M. Sc. Nanoscience

Model question paper format for all theory papers

Time: 3Hrs Max Marks: 75 Answer ALL Questions

Part - A

Ten Questions 10x1=10 Two questions from each unit (multiple choice)

Part - B

Five Questions : 5X5 = 25 Two questions from each unit (either /or type)

Part – C

Five Questions : 5x8 = 40 Two questions from each unit (either /or type)

First Semester

1. INTRODUCTION TO NANOSCIENCE

UNIT I Background to nanotechnology -scientific revolutions -types of nanotechnology and nano machines -atomic structure -molecules & phases -energy -molecular and atomic size -surfaces and dimensional space -top down and bottom up. Misnomers and misconception of Nanotechnology. UNIT II Basic problems and limitations -opportunities at the nanoscale -time and length scale in structures -energy landscapes -basic intermolecular forces -interdynamic aspects of intermolecular forces -Evolution of Band structures and Fermi surface. UNIT III Definition of a nano system -dimensionality and size dependent phenomena; Quantum dots, Nanowires and Nanotubes, 2D films; Nano & mesopores –size dependent variation in Magnetic, electronic transport, reactivity etc. UNIT IV Forces between atoms and molecules, particles and grain boundaries, surfaces -strong intermolecular forces -van der Waals and electrostatic forces between surfaces -similarities and differences between intermolecular and interparticle forces -covalent and coulomb interactions -interactions involving polar molecules and polarization -weak intermolecular forces and total intermolecular pair potentials

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UNIT V Forces between solvation, hydration; polymers at surfaces; adhesion - thermodynamics of self assembly; micelles, bilayers, vesicles -bionanomachines - biological membranes. REFERENCE: 1. Nanotechnology: basic science and emerging technologies -Mick Wilson, Kamali

Kannangara, Geoff Smith, Michelle Simmons, Burkhard Raguse, Overseas Press (2005).

2. Amorphous and Nanocrystalline Materials: Preparation, Properties, and Applications, A.lnoue, K.Hashimoto (Eds.,) (2000)

3. Understanding Nanotechnology, Scientific American, editors at Scientific American, Warner Books (2002)

4. Introduction to Nanotechnology by Charles P. Poole, Frank J. Owens, Wiley-Interscience (2003).

5. www. nanonet.rice.edu/intronanosci/ 6. www.acclab.helsinki.fi/-knordlun/nanotiede/ 7. Nanotechnology: A Gentle Introduction to the Next Big Idea, Mark A. Ratner, Daniel

Ratner, Mark Ratne, Prentice Hall PTR; 1st edition (2002) 8. Nano : The Essentials' by T.Pradeep

2. ORGANIC CHEMISTRY – I Unit – I: AROMATICITY AND NOVEL RING SYSTEM Aromaticity: Benzenoid and non – benzenoid compounds – generations and reactions – sextet theory – MO theory – Huckel’s rule – Annulenes and hetero annulenes – Anti and homo aromaticity Nomenclature of bicyclic and tricyclic systems – structure and synthesis of Adamantane – Congressane – Alternant and non – alternant – Azulene – and sydnones. Unit – II: STUDY OF ORGANIC REACTION MECHANISM Reaction mechanism – Energy diagram of simple Organic reactions – Transition state and Intermediate. Kinetic and Thermodynamic requirements of reactions – Hammond Postulate and microscopic reversibility. Kinetic and Thermodynamic control of product formation. Kinetic and Non – kinetic methods of determination – Primary and secondary isotope effect–Testing and Trapping of intermediates, Isotopic labeling, Cross–over experiments and stereo chemical evidence. LFER : Hammett equation – Physical significance of �and � – Applications and Limitations – Taft equation. Unit – III: STEREOCHEMISTRY AND CONFORMATIONS ANALYSIS Concept of chirality: chirality – Enantiotopic, diastereotopic hydrogens and prochiral centres – axial and planar chirality – stereochemistry of compounds containing two dissimilar asymmetric carbons and ansa compounds. R/S notations of allenes and Biphenyl derivatives – E/Z notation of compounds containing one and two double

208

bonds. Stereospecific and stereoselective synthesis – Methods of Asymmetric synthesis including enzymatic and catalytic process – Cram’s rule and Prelog’s rule – Cram chelation model and Felkin – Aln model. Conformations of mono and disubstituted cyclohexanes-effect of hydrogen bonding, dipole and steric effects on the disubstituted cyclohexanes-conformation and reactivity of acyclic and cyclic compounds (6members)- conformation of decalin and perhydrophenanthrene-curtin-Hammett principle. Unit – IV: MOLECULAR REARRANGEMENTS Types of rearrangements : Nucleophilic , electrophilic and Free radical reactions – Nature of migration – migrating aptitude and memory effects, ring enlargement and ring contraction. Reaction and mechanism of the following : Carbon to carbon migration – Wagner – Meerwein, Pinacol – Pinacolone, Benzil – Benzilic acid, Arndt – Eistert synthesis, Demjanov and dienone-phenol rearrangements. Carbon to oxygen migration – Baeyer Villiger and Darkin rearrangements. Carbon to Nitrogen migration – Lossen, Neber and curtius rearrangements. Miscellaneous : Von – Richter rearrangement and Fischer - Indole synthesis. Unit – V: REAGENTS IN ORGANIC SYNTHESIS Gilman’s reagent – LDA – DCC – 1,3 – dithane (umpolung synthesis ) – Tri n–butyl tin hydride – Aluminium isopropoxide – chloro trimethyl silane. Fetizon’s reagent – Lemieux – Von Rudloff reagent – Lemieux–Johnson reagent – Woodward and prevost hydroxylation. Phase transfer catalysts – Merrifield resin – Vaskas catalyst – wilkinson’s catalyst –Ziegler – Natta catalyst. 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), DMSO, Super hydrides- K and L selectrides -Dess-martin-periodinane- Baker’s yeast –Quaternary ammonium salt and crown ethers REFERENCES 1. P. Sykes, ‘A Guide book to mechanism in organic chemistry’, Orient Longman, 1989. 2. S.M. Mukherji and S.P. singh, ‘ Reaction mechanism in Organic Chemistry ‘, Macmillan India Ltd, 1978. 3. M. Mukerji, S.P. Singh, and R.P. Kapoor, “Organic chemistry”, Vol . I and II, Wiley Eastern Ltd., 1985. 4. J.March, ‘ Advanced organic chemistry’, Fourth Edition, John Wiley and Sons, Newyork, 2006. 5. I.L. Finar, ‘Organic Chemistry’, Vol I and II, ELBS, fifth Editon, 2001. 6. F.A. Carey and R.A Sundberg, ‘ Advanced Organic Chemistry’ (part A and B) plenum publishers, 2000. 7. E.S. Gould, ‘ Mechanism and structure in organic chemistry’ Holt, Rinehart and Winston Inc., 1959 8. S.H. Pine, ‘Organic Chemistry’ , 5th Edition, Mc Craw Hill International Edition, 1987. 9. E.L. Eliel, ‘Stereochemistry of Carbon compounds, Mc Craw Hill 1999. 10. E.L. Eliel and S.H. Wilen, ‘Stereochemistry of organic compounds’, John Wiley and sons, Inc., 2003.

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11. P.S. Kalsi, ‘ Stereo chemistry – Conformation and mechanism – New Age international (p) Ltd., 2000. 12. P.Ramesh, ‘Basic Principles of organic stereochemistry’, Meenu Publications, Madurai, First Edition, 2005. 13. D. Nasipuri, ‘Stereochemistry of organic compounds – Principles and applications’,Wiley Eastern Ltd., 1991. 14. J.M. Harris and C. Wamser – John, ‘ Fundamentals of organic reaction mechanism –Wiley and sons 15. F.A Carey,’Organic Chemistry, Tata Mc Graw Hill, fifth reprint, 2005. 16. T.H. Lowry and K.S Richardson,’ Mechanism and Theory in Organic Chemistry’,Houper and Row Publishers – Newyork, 1987 17. V.M. Potapov, ‘Stereochemistry’ – Mir Publishers ,1979 18. R.O.C.Norman, ‘Principles of Organic Synthesis, Chapman Hall, London, 1993. 19. Raj K. Bansal, ‘Reaction mechanism in Organic chemistry, Tata Mc Graw Hill, Third Editon, 10th reprint, 2005. 20. Gurdeep R. Chatwal, ‘Reaction mechanism and Reagents in organic chemistry’,Himalaya publishing House, Bombay 1992. 21. J.N. Gurtu and R. Kapoor, ‘Organic Reactions and Reagents’, S.Chand and company Pvt. Ltd., 22. Gurdeep Chatwal,’Organic Chemistry of Natural Products,’ Vol.I and II, Himalaya Publishing House, Bombay 1992. 23. O.P. Agarwal, ‘Chemistry of Natural Products,’Vol I and II, Goel publishing House, Meerut, 1984. 24. V.K. Ahluwalia and R.K. Parshar, ‘Organic Reaction mechanism,’second Edition ,Narosa publishing House,2005. 25. H.O. House, ‘Modern synthetic Reaction,’Second Edition , W.A. Benjamin, Inc.,London, 1972. 26. R.K. Mackie, M.M. Smith and R.A. Aitken,’Guide Book to Organic Synthesis’ Second Edition, Longman Seientific and Technical, Singapore, 1990. 27. K. Nakanishi, ‘Natural Product Chemistry,’Blackie Publications, Vols, I, II, III. 28. R.H. Thomson, ‘Chemistry of Natural Products – Wiley, Newyork, 1996. 29. R.T. Morrison and R.N. Boyd,’Organic Chemistry’ sixth Edition, Prentice Hall, 1994. 30. Michael B. Smith, ‘Organic Synthesis,’ Mc Graw Hill international Edition , 1994. 31. Bhupinder Mehta, Manju Mehta, Organic Chemistry, PHI Learning, New Delhi, 2011

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3. INORGANIC CHEMISTRY – I Unit – I: CHEMICAL BONDING AND STEREOCHEMISTRY VSEPR theory – Concept of hybridization and structure of molecules- Walsh diagrams – Bent’s rule – apicophilicity – M.O. theory – symmetry and overlap – M.O. diagrams of homo and hetero diatomic molecules and BeH2 . Geometrical isomerism in complexes of coordination numbers 4 to 7 with examples – Fluxionality – Fluxional molecules and their characterization – Planar – tetrahedral, Trigonal bipyramidal – square Pyramidal interconversions. Unit – II: SOLID STATE CHEMISTRY – I Efficiency of packing in crystals — Limiting radius ratio – Description of crystal structures - calcite, zinc blende, wurtzite, rutile, fluorite, antifluorite, CsCl, CdI2, K2NiF4 – spinels and perovskite. Principles and measurements of X-ray diffraction studies. Electron diffractions by gases – principle and measurements - determination of structures – comparison between electron, neutron and X-ray diffraction. Unit – III: SOLID STATE CHEMISTRY – II Electronic structure of solids - Free electron and band theory - Types of solids — conductors and insulators- intrinsic and extrinsic semiconductors - Band structure and applications. Crystal defects in solids — line and plane defects - Point defects — Schottky and Frenkel defects — Non-stoichiometric defects - Preparation and properties of nonstoichiometric compounds - Colour centres - Solid electrolytes and their applications. Optical and electrical properties of semiconductors - Photovoltaic effect - Hall effect - p-n and n-p-n junctions and their applications as rectifier and transistor - Super conductivity high temperature super conductors, properties and applications - BCS theory - Cooper electrons - Meissener effect and levitation. UNIT – IV : APPLICATION OF SPECTROSCOPY TO THE STUDY OF INORGANIC COMPOUNDS -I VB theory and CFT – Splitting of d-orbitals under different geometries – CFSE – evidence for CFSE – structure of spinels – factors affecting CFSE – spectrochemical series – Jahn-Teller distortion – M.O. theory of bonding – sigma and _-bonding in coordination compounds Electronic spectroscopy : L-S coupling and j-j coupling schemes , micro states , Hund’s rule and term symbols . Selection rules for electronic transition and hole formalism – splitting of terms – Orgel and Tanabe Sugano diagrams – Evaluation of 10 Dq and B for octahedral d 2 and d8 systems. Charge transfer spectra. Electronic spectra of lanthanide and actinide complexes .

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Unit – V: APPLICATION OF SPECTROSCOPY TO THE STUDY OF INORGANIC COMPOUNDS -II Application of IR and Raman spectra in the study of coordination compounds : Application to metal carbonyls and nitrosyls – geometrical and linkage isomerism – detection of inter and intramolecular hydrogen bonding – stretching mode analysis of metal carbonyls. Mossbauer spectroscopy: Principle – application of isomer shift , quadrupole interactions and magnetic hyperfine splitting in the study of iron and tin compounds . REFERENCES INORGANIC CHEMISTRY – I 1. James E. Huheey, Ellen A. Keiter and Richard L. Keiter, Inorganic chemistry: principles Structure and Reactivity, 4th Ed., Harper College Publishers, 1993. 2. F. Albert Cotton, Geoffrey Wilkinson, Carlos A. Marilo and Manfred Bochman, Advanced Inorganic Chemistry, Wiley Interscience Publication, 6th Ed., 1999. 3. G.S. Manku, Theoretical Principles of Inorganic chemistry, Tata McGraw Hill, 12th reprint, 2004. 4. K.F. Purcell and J.C. Kotz, Advanced Inorganic Chemistry, Saunders Golden Publishers. 5. B.E. Douglas, D.H. McDaniel and J.J. Alexander, Concepts and Models of Inorganic Chemistry, John Wiley and Sons Ltd. 2nd Ed., 1983. 6. M.c. Day Jr and J. Selbin., Theoretical Inorganic Chemistry, 2nd Ed., East West Press, 2000. 7. J.D. Lee, Concise Inorganic Chemistry, ELBS, 2006. 8. A. R. West, Solid State Chemistry and its Application, John Wiley & Sons, (Asia), 1998. 9. T. Kutty, J. Tareen, Fundamentals of Crystal Chemistry, University Press, 1st Ed., 2001. 10. L.V. Azaroff, Introduction to Solids, Tata McGraw Hill Publishing Ltd., India, 1989. 11. C. Kittel, Introduction to Solid State Physics, Wiley Eastern Ltd., 5th Ed., 1993. 12. H.V. Keer, Principles of the Solid State, Wiley Eastern Ltd., 1993. 13. D.K. Chakrabarthy, Solid State Chemistry, New Age International. 14. A.F. Wells, Structural Inorganic Chemistry, Oxford Science Publication, London, 1979. 15. M.T. Weller, Inorganic Materials Chemistry, Oxford University Press, Reprint 1996. 16. B. Sahoo, N. C. Nayak, A. Samantaray, P.K. Pujapanda, Inorganic Chemistry, PHI Learning, New Delhi, 2012. R.S.Drago , Physical Methods in Inorganic Chemistry ,W.B.Saunders ,1977. E.A.V.Ebsworth David ,W.H.Rankin Stephen Credock ,Structural Methods in Inorganic Chemistry ,ELBS , IV 1988.

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4. PHYSICAL CHEMISTRY – I UNIT – I: Classical Thermodynamics Thermodynamics systems of variable composition: Partial molar quantities – Chemical Potential, partial molar volume and partial molar heat content. Gibbs-Duhem equation. Determination of these partial molar quantities. Variation of chemical potential with temperature and pressure. Thermodynamics of real gases and real solutions; Fugacity: Methods of determination. Dependence on temperature, pressure and composition. Activity and activity coefficient: Standard states, determination of activity and activity coefficient of non-electrolytes and electrolytes. UNIT – II: Statistical Thermodynamics Thermodynamic probability and entropy – Maxwell-Boltzman, Bose-Einstein and Fermi-Dirac statistics and applications – Partition functions and entropies for translational, rotational, vibrational and electronic motions of monoatomic and diatomic molecules – Calculations of thermodynamic functions and equilibrium constants – Specific heat of solids – Einstein and Debye theories. Unit – III: CHEMICAL KINETICS Collision theory of reaction rate – steric factor – Theory of absolute reaction rates – Thermodynamic treatment – Unimolecular reactions – Lindemann, Hinshelwood, RRK, RRKM and Slater theories – Chain reactions – Study of kinetics of chain reactions like H2-Br2 reaction, Decomposition of acetaldehyde and N2O4 – Explosive reactions – Study of H2-O2 reaction – Ionic reactions in solution – Factors influencing the reaction rate – Salt effect – Influence of pressure – Kinetic isotope effect. Unit – IV: CHEMICAL DYNAMICS Study of fast reactions – General features – Reactions in flow system, continuous and stopped flow – Chemical relaxation methods, temperature and pressure jump methods – Shock tube techniques – Flash photolysis – Pulse radiolysis. Concept of Linear Free Energy Relationship – derivation of Hammett equation- significance of substituent and reaction constants – Taft equation – Thermodynamic implications of LFER.

Unit - V: Adsorption and surface phenomenon Physisorption and chemisorption, adsorption and desorption, adsorption isotherms-Langmuir and B. E. T. equation and significance in surface area determination, surface films, adsorption from solution, Gibb's adsorption equation: derivation, significance. Kinetics of unimolecular and bimolecular surface reactions. Application of photoelectron spectroscopy, ESCA and Auger spectroscopy to the study of surfaces,

Surface activity, surface active agents and their classification, micellisation, critical micelle concentration ( cmc), thermodynamics of micellisation , factors affecting cmc, methods of determination of cmc , use of surfactants in oil recovery.

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References 1. S. Glasstone, Thermodynamics for chemists, Van Nostrand Co, New York, 1969.

2. K.G. Denbigh, Thermodynamic of Steady State, Methien and Co. Ltd., London, 1951.

3. L.K. Nash, Elements of Chemical Thermodynamics, Addison Wesly, 1962.

4. G.M.Barrow, Physical Chemistry, McGraw Hill, 1988.

5. J.C. Kuriacose and J. Rajaram, Thermodynamics, Shohan lal and Co. Delhi, 1986.

6. J. Rajaram and J.C. Kuriacose, Thermodynamics, 2nd Ed., S.N. Chand & Co., New Delhi, 1993.

7. D.N. Bajpai, Advanced Physical Chemistry, S. Chand & Co., New Delhi, 1998.

8. S.H. Maron and J.B. Lando, Fundamentals of Physical Chemistry, MacMillan International Education, New York, 1974.

9. M.C. Gupta, Statistical Thermodynamics, New Age International (P) Ltd., New Delhi, 2nd Edition, 1998.

10. K.J. Laidler, Chemical Kinetics, Tata McGraw Hill, New Delhi, 2nd Edition, 18th reprint 1994.

11. K.J. Laidler, Theories of Chemical Reaction Rates, McGraw Hill, 1988.

12. F. Wilkinson, Chemical Kinetics and Reacton Mechanism, Van Nostrand Reinhold Co., New York, 1980.

13. G.L. Agarwal, Basic Chemical Kinetics, Tata McGraw Hill, New Delhi, 1996.

14. R.G. Forest and Pearson, Kinetics and Mechanism, Wiley, New York, 1961.

15. Moore and R.G. Pearson, Kinetics and Mechanism, 1981.

16. C. Capellos and B.H.J. Bielski, Kinetics Systems, Wiley Interscience, New York, 1972.

17. I. Amdur and G.G. Hammes, Chemical Kinetics, Principles and Selected Topics, McGraw Hill, New York, 1968.

18. G.M. Harrus, Chemical Kinetics, D.C. Health and Co., 1966.

19. P.W. Atkins, Physical Chemistry, ELBS Ed., 1998.

20. P.L. Houston, Chemical Kinetics and reaction Dynamics, McGraw Hill, International Edition 2001.

21. J. Rajaram and J.C. Kuriacose, Kinetics and Mechanisms or Chemical transformations, Macmillan India Ltd., 1st reprint 1998.

22. Ira Levine, Physical Chemistry, Tata McGraw Hill, New Delhi, 5th Edition 2004.

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23. Symmetry, Orbitals and spectra by M. Orchin & H. Jaffe, Willey.

24. Chemical applications of group theory by F. A. Cotton Willey .

25. Symmetry in chemistry by H. Jaffe and M . Orchin , Jhon willey.

26. Group theory and its applications to chemistry by K. V. Raman.

27. Group theory and spectroscopy by K. Veera Reddy.

28. Group Theory and Its Chemical Applications. Author, P. K. Bhattacharya.

Group theory by Gobinathan and Ramakrishnan

Second semester

1. SYNTHESIS OF NANOMATERIALS UNIT I Nano outline -introduction -various preparation techniques -basic concepts of nanostructured materials -nucleation: surface nucleation growth -grain size distribution -nano particle transport in low density media -vapour nano phase thermodynamics -coagulation of nano particles, determination of grain size –aggregate formation -mass fractal morphologies. Hydro thermal methods UNIT II Film deposition methods -introduction -fundamentals of film deposition - thermal evaporation -Spray Pyrolysis, Flame Pyrolysis -molecular beam epitaxy - pulsed laser deposition -sputter deposition -chemical vapour deposition -layer by layer growth and ultra thin films -chemical solution deposition -Langmuir Blodgelt films. UNIT III Sol-gel processing -fundamentals of sol-gel process -sol-gel synthesis methods for oxides -other inorganic and nano composites -the Pecheni method –silica gel -Zirconia and Yttrium gel -aluminosilicate gel -polymer nano composites. UNIT IV Types of nanotubes -formation of nanotubes -methods and reactants - arcing in the presence of cobalt -laser methods -ball milling -chemical vapour deposition methods -Catalytic route -properties of nano tubes -plasma arcing - electro deposition -pyrolytic synthesis -zeolites and templated powders layered silicates, soft chemical & combustion methods, Graphene. UNIT V Synthesis of special nanomaterials: Introduction -Micro and mesoporous materials- Core-shell structures -Organic-inorganic hybrids -Intercalation compounds -Nanocomposites and nanograined materials. Microbial synthesis of Nanomaterials.

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REFERENCE: 1. www.eng.uc.edu/-gbeaucag/Classes/NanoPowder.html 2. Nanoelectronics and information technology: Advanced electronic materials and

novel devices (2nd edition), Rainer Waser (Ed.), Wiley-VCH Verlag, Weiheim (2005). 3. Recent Advances in the Liquid-phase syntheses if inorganic nanoparticles, Brain

L.Cushing, Vladimir L.Kolesnichenko, Charles J. O'Connor, Chem Rev.104 (2004) 3893-3946.

4. Nanocomposite science and technology, Pulickel M.Ajayan, Linda S.Schadler, Paul V.Braun, Wiley-VCH Verlag, Weiheim (2003).

5. Amorphous and Nanocrystalline Materials: Preparation, Properties, and, Applications, A.lnoue, K.Hashimoto (Eds.,) (2000). '.

6. Nanostructures and Nanomaterials -Synthesis, Properties and Applications by Guozhong Cao.

2. NANOCOMPOSITES

UNIT I Introduction of Nanocomposites: Nanocomposites- Definition - Nanocomposites past and present- Nomenclature -Solids -Atomic and molecular solids -Role of statistics in materials -Primary , secondary and tertiary structure - Transitions UNIT II Properties and features of nanocomposites: Physics of modulus - Continuum measurements -Yield -Fracture -Rubbery elasticity and viscoelasticity - Composites and nanocomposites -Surface mechanical properties -Diffusion and permeability -Features of nanocomposites -basics of polymer nano compos1tes UNIT III Processing of nanocomposites: Viscosity -Types of flow -Viscosity - Experimental viscosity -Non-newtonian Flow -Low-viscosity processing –Solvent processing -Particle behavior -In situ polymerization -Post-Forming -Hazards of solvent Processing -Melt, high -shear, and direct processing UNIT IV Characterization of nanocomposites: Introduction to characterization - Experiment design -Sample preparation -Imaging -Structural characterization - Scales in nanocomposites -Texture -Electromagnetic energy -Visualization - Physicochemical analysis -Characterization of physical properties -Identification -Mechanical -Surface mechanical properties. UNIT V Applications of nanocomposites: Nanocomposites -Optical, structural applications -Nanoparticulate systems with organic matrices -Applications - Biodegradable protein nanocomposites -Applications Polypropylene nanocomposites - Application as exterior automatic components -Hybrid nanocomposite materials - Application for corrosion protection

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Reference: 1. Thomas E. Twardow ski, Introduction to Nanocomposite Materials -Properties,

Processing, Characterization, DesTech Publications, April 2007 2. Boston New york Washing ton, DC. and Woodhead publishing Itd, England, 2006. 3. Parag Diwan and Ashish Bharadwaj. Nanocomposites Pentagon Press 4. Nanocomposite Science and Technology Pulickel M. Ajayan , Linda S. Schadler,

Paul V. Braun, 2006, Wiley-VCH

3. INORGANIC CHEMISTRY –II

Unit – I: COORDINATION CHEMISTRY Stability of complexes - stabilisation of unusual oxidation states- determination of stability constants by potentiometric and spectrophotometric methods- factors affecting stability- chelate and template effects. Ligand substitution reactions of square planar complexes- Trans effect and its theories of trans effect in synthesis of complexes- Substitution reactions in octahedral complexes acid hydrolysis, base hydrolysis and anation reactions- Electron transfer reactions – Inner sphere and outer sphere processes- outer sphere process in photochemical reactions. Unit – II: ORGANOMETALLIC CHEMISTRY - I Introduction - History-EAN and its correlation to stability- Synthesis and structures of metal carbonyls- carbonylate anions, carbonyl hydride complexes and metal nitrosyls-Isolobal analogy- IR study of metal carbonyls- Synthesis, properties and structural features of metal complexes with carbene, alkene, alkyne and arene. Hapticity-Metallocenes- synthesis, properties and bonding in ferrocene - covalent versus ionic bonding in beryllocene, clusters and catalysis, hydride and dihydrogen complexes, fluxionality. Unit – III: ORGANOMETALLIC CHEMISTRY - II Oxidative addition and reductive elimination- insertion and elimination reactions, nucleophilic and electrophilic attack of coordinating ligands- Catalysis by organometallic compounds - Homogeneous catalysis- alkene hydrogenation- synthesis gas and water-gas shift reaction- hydroformylation- carbonylation of alcohols and oxygenation of olefins- Heterogeneous catalysis- Fischer-Tropsch process and Ziegler—Natta polymerization - Immobilized homogeneous catalysts. UNIT – IV : THERMOANALYTICAL AND SPECTROANALYTICAL METHODS Theory and principles of thermogravimetric analysis , differential thermal analysis and differential scanning colorimetry–characteristic features of TGA and DTA curves-factors affecting TGA and DTA curves- complementary nature of TGA and DTA – applications of thermal methods in analytical chemistry- thermometric titrations- the study of minerals and polymers. Principle and applications of colorimetry,spectrophotometry, nephelometry, turbidimetry , fluorimetry and atomic absorption spectroscopy.

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Unit – V: ELECTROANALYTICAL METHODS Voltametry : Polarographic analysis - applications, quantitative determination, determination of equilibrium constant for complex formation - organic polarography - advanced voltametric techniques - rapid - scan techniques - pulse techniques – AC techniques - stripping techniques - coulometry - classification - controlled current coulometrycontrolled potential coulometry - advantage of coulometric methods - amperometry - amperometric sensors - amperometric tritrations - chronomethods - Chronopotentiometry - Chrono coulometry - cyclic voltametry. REFERENCES 1. James E. Huheey, Ellen A. Keiter and Richard L. Keiter, Inorganic chemistry: Principles, Structure and Reactivity, 4th Ed., Harper Collins College Publishers, 1993. 2. F. Albert Cotton, Geoffrey Wilkinson, Carlos A. ManIc and Manfred Bochman,Advanced Inorganic Chemistry, Wiley lntersceince Publication, 6th Ed., 1999. 3. D. Bannerje, Coordination Chemistry, Tata McGraw Hill, 1993. 4. G.S. Manku, Theoretical Principles of Inorganic Chemistry Tata McGraw Hill,12th reprint 2004. 5. K.F. Purcell and J.C. Kotz, Advanced Inorganic Chemistry, Saunders GolderPublishers. 6. B.E. Douglas, D.H. McDaniel and J.J. Alexander, Concepts and Models of InorganicChemistry, John Wiley and Sons Ltd., 2nd Ed., 1983. 7. M.C. Day Jr and J. Selbin, Theoretical Inorganic Chemistry, 2nd Ed., East West Press,2000. 8. J.D. Lee, Concise Inorganic Chemistry, ELBS, 2006. 9. D.F. Shriver, P.W. Atkins and C.H. Langford, Inorganic Chemistry, ELBS, OxfordUniversity Press, 1994. 10. W.L. Jolly, Modern Inorganic Chemistry, McGraw Hill Company, 2nd Ed., 1991. 11. R.S. Drago, Physical Methods in Inorganic Chemistry, Saunders College Publishers. 12. E.A.V. Ebsworth, D.W.H. Rankin and S. Cradock, Structural Methods in Inorganic Chemistry, ELBS, 1988. 13. D.A. Skoog, F. James Holler and J.A. Nieman, Principles of Instrumental Analysis,Saunders, 1992. 14. H.H. Willard, L.L. Merritt and J.A. Dean, Instrumental Methods of Analysis, CBS Publishers, 6th edition, 1986. 15. G.H. Jeffery et.aL, Vogel’s Textbook of. Quantitative Chemical Analysis, Revised 5th edition, ELBS, 1989. 16. R.A. Day and A.L. Underwood, QuantitativeAnalysis, Prentice Hall, 1999

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4. ORGANIC CHEMISTRY – II

Unit – I: ULTRAVIOLET, INFRA – RED SPECTROSCOPY, ORD AND CD UV: The absorption laws – Types of electronic transitions – effects of solvent and Hydrogen bonding on �max values. – Woodward – Fieser rules to calculate �max values of conjugated dienes and �,� - unsaturated ketones. IR: Characteristic of IR absorptions of different functional groups – factors influencing absorption of carbonyl and hydroxyl groups – electronic effect, hydrogen bonding and Fermi resonance. Optical rotatory dispersion (ORD): Octant rule - �- halo ketone rule and their applications-Circular Dichroism. Unit – II: NMR SPECTROSCOPY H1NMR spectroscopy: Basic Principle – number of signals – chemical shift – Factors influencing chemical shift - spin–spin coupling – classification of spin systems – analysis of AX, AMX and ABX systems – Geminal, Vicinal and long range couplings–NOE in stereochemistry – FTNMR. C13 spectroscopy: Principle of proton decoupled C13 spectroscopy - comparison with H1NMR – chemical shifts (aliphatic, olefinic, alkynic, aromatic and carbonyl compounds) 2D NMR spectroscopy: H1–H1COSY, H1–C13 COSY, NOESY, DEPT and INADEQUATE spectra. Unit – III: MASS SPECTROSCOPY Basic Principles – Techniques of Ion Production – E I, C I, FD, FAB, ESI – MS, MALDI – M S – Base peak – molecular ion – nitrogen rule – metastable ion – isotope ion daughter ions – Mc–Lafferty rearrangement – RDA – General rules for fragmentation pattern – Fragmentation pattern of simple compounds of hydrocarbons, alcohols, amines, aldehyde, ketone, ether, ester, acids and phenols – Detection of structure through mass spectral fragmentation. One conjunction problem based on the above spectroscopic techniques is compulsory under section – c. Problems shall be based on the reference books. Unit – IV: ALKALOIDS AND STEROIDS Alkaloids: Degradation studies – HEM , Emde and Von – Braun – The structural determination and synthesis of Quinine, Morphine, Cocaine, Strychnine and Reserpine –Biosynthesis of alkaloids. Classification- structural elucidation of cholesterol and ergosterol-irradiated products of ergosterol- structural elucidation of androsterone, testosterone, progesterone, Oestrone.Conversion of cholesterol into androsterone, progesterone, testosterone, 5α- and 5 β-cholanic acid. Conversion of Oestrone to Oestriol, Oestradiol and vice-versa. structural elucidation of equilenin (synthesis not expected)- Bile acids (general study) Conformational structure of cholestane and Coprostane Unit – V: VITAMINS AND TERPENOIDS Vitamins: structural determination of vitamins – A1, B1, B2, B6, C, D and E. Terpenoids : General methods to elucidate the structure of terpenes – structural determination of � pinene, Camphor, Zingiberene, Cadinene, � - Santonin, abietic acid and sqalene. Bio synthesis of mono and di terpenoids.

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REFERENCES 1. J. March, ‘Advanced organic chemistry,’ Fourth Edition, John Wiley and sons, New York, 2006. 2. R.T. Morrison and R.N. Boyd, ‘Organic Chemistry’, sixth Edition, Prentice Hall, 1994. 3. I.L. Finar, ‘Organic Chemistry’, volume 2, sixth Edition, Pearson Education Inc., Singapore, 2006. 4. Y.R. Sharma,’Fundamentals of Organic spectroscopy’. 5. P.S. Kalsi, ‘Spectroscopy of organic spectroscopy’, second Edition , New Age International publishers Limited, 1995. 6. Jag Mohan, ‘Organic Analytical Chemistry Theory and Practice, ‘ Narosa Publishing House, 2003. 7. W.Kemp, ‘Organic spectroscopy’, Third Edition, Macmillan, 1994. 8. S.M. Silverstein, G.V.Bassler and T.C. Morril, ‘Spectrometric Identification of organic compounds, sixth Edition, Wiley 2004. 9. D.H.Williams and Ian Fleming, ‘Spectroscopic methods in organic chemistry,’fifth Editon, Tata Mc Graw Hill, 1988. 10. F.W. Wherli and T. Wirthilin, ‘Interpretation of carbon – 13 spectra’, Heyson and sons, London. 11. V.R. Dani, ‘Organic spectroscopy’, Tata Mc Graw Hill, 1995. 12. J.R. Dyer, ‘Application of Absorption spectroscopy, prentice Hall, 1987. 13. Pavia, Lampmann, Kriz and Vyuyan, spectroscopy, cengage learning India Private Ltd., First Indian Reprint,2008. 14. D.H. William and R.D. Bower, ‘Mass spectrometry – principles and Applications,’ I. Howe, Mc Graw Hill. 15. R.M. Silverstein and F.X.Webster, ‘Spectrophotometric Identification of Organic Compounds’ John Wiley and Sons, Ine., Sixth Edition, 1997. 16. F.A. Carey and J.Sundberg,’Advanced Organic chemistry ‘ part A and B, Plenum Press, 2005. 17. Gurdeep Chatwal,’Organic Chemistry of Natural products, Vol I and II, Himalaya Publishing House, Bombay,1992. 18. O.P. Agarwal, ‘Chemistry of Natural Products,’Vol I and II, Goel Publishing House, Meerut, 1984. 19. M. Mukerji, S.P. Singh, and R.P. Kapoor, ‘Organic Chemistry, Vol I and II, Wiley Eastern Ltd., 1985. 20. I.L. Finar, Organic Chemistry , Vol. I. ELBS fifth Edition,2001. 21. R.O.C. Normon, principles of organic synthesis – Chapman and Hall 1994. 22. W. Carruthers, some modern methods & Organic synthesis – Cambridge University Press. 23. E.L. Eliel, stereochemistry of carbon compounds – Mc Craw Hill, 1999. 24. ORD and CD in chemistry and Bio chemistry – Academic press. 25. F.A. Carey, Organic chemistry – Tata Mc Graw Hill, Delhi, 5th edition 2005.

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ORGANIC CHEMISTRY PRACTICAL

A. Separation of Organic mixture of Analysis:

Separation and analysis of atleast 6 two component mixtures. Determination

of two physical constants of components and derivatives is expected.

B. Single stage preparation:

1. Preparation of 1,2,3,4- tetrahydrocarbazone from cyclohexanone.

2. Preparation of Resacoteophenone from resorcinol.

3. Preparation of dinitrodiphenylamine from aniline.

4. Preparation of benzoquinone from hydroquinone.

5. Preparation of benzpinacol from benzophenone.

6. Preparation of di-β-naphthol from β-naphthol.

C. For class work only:

1. Estimation of Ethylmethylketone.

2. Estimation of Glucose- Bertrands method.

References:

1. F.C.Mann and B.C. Saunders, Practical Organic Chemistry, Fourth edition,ELBS

1970.

2. A.I. Vogel, A textbook of Practical organic chemistry.

3. A.N. Vishnoi, Advanced practical organic chemistry.

INORGANIC CHEMISTRY PRACTICAL

1. Qualititative analysis of inorganic mixture two less familiar cations W, Tl,Te, Se,

Mo,Ce, Th, Zr,V, U, Ti and Li.

2. Volumetric analysis

a. Estimation of Cu by iodimetric titration; Zn by redox titration

b. Estimaton of Cu, Zn and Mg by EDTA titration in the presence of either Pb or

Ba.

3. Preparation of single stage inorganic complexes ( a minimum of 5 complexes).

Cousre Work only: Characterisation of any one metal complex by UV and IR

spectral techniques.

221

PHYSICAL CHEMISTRY PRACTICAL

A. CONDUCTIVITY

1. Determination of solubility product of a sparingly soluble salt 2. Determination of Ka by using Ostwald distribution method. 3. Titrations

(i) HCl + CH3COOH vs NaOH (ii) NH4Cl + HCl vs NaOH (iii) CH3COOH + CH3COONa vs NaOH (iv) CH3COOH + CH3COONa vs HCl

B. THERMOMETRY 4. Determination of solution enthalpy

(i) Oxalic acid – water (ii) Naphthalene - toluene

C. ABSORPTION :

5. Adsorption of acetic acid/oxalic acid on activated charcoal – verification of Freundlich isotherm – determination of unknown concentration.

D. POTENTIOMETRY :

6. Determination of formation constant of [Ag(NH3)2]+ complex. 7. Determination of pH of buffer solutions using quinhydrone electrode. 8. Determination of dissociation constant of a weak acid. 9. Determination of solubility product of springly soluble salts by concentration cell

method and chemical cell method.

POTENTIOMETRIC TITRATION : i) Redox 9. FAS – Ce4+ 10. Fe2+ - KMnO4 11. KI - KMnO4

ii) Precipitation 12. Kcl – AgNO3 13. Kcl + KI - AgNO3

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Third Semester

1. NANOBIOTECHNOLOGY UNIT I Self-Assembly of nanostructured materials – Nonascience – Nanobiology- Nanotechnology and nonobiotechnology – cellular nanostructures – Cell surface layers- Molecular motors – Action fibers UNIT II Cancer detection/diagnosis via nanotechnologies and nanosensors - Biomimetic amplification of nanoparticle homing to tumors -Polymer genomics: An insight into pharmacology and toxicology of nanomedicines. UNIT III Introduction to challenges to macromolecular drug delivery -Nanocontaniner - Liposome nanocontainers -Biopolymer nanocontainers -nanocapsules –Applications in drug and gene target delivery -Lipid-based nanoparticles for nucleic acid delivery - Nanotechnology approaches for drug and small molecule delivery across the blood brain barrier- Fluorocarbon nanoparticles as multifunctional drug delivery vehicles. UNIT IV Introduction to controlled fabrication of hierarchically branched nanopores, nanotubes and nanowires -Integration of cell membranes and nanotube transistors - Manufacturing of nanochannels with controlled dimensions using protease nanolithography- Controlled synthesis of nonspherical microparticles using microfluidics -Introduction to bioelectronics and biosensing devices -Nano circuitry -Applications in tissue engineering -Nanoprobes -Protein polymer nanomachines. UNIT V Imaging -Animal models: Live and in color- Sentinel lymph node mapping of the pleural space -A biomagnetic system for in vivo cancer imaging -Quantum dots for live cells -In vivo imaging and diagnostics -Luminescent nanoparticle probes for bioimaging. Reference: 1. Nanobiotechnology- Concepts, Applications and Perspectives by C. M. Niemeyer and

C. A. Mirkin , 2. Biotechnology: Lessons from Nature by David S.Goodsell 3. Handbook of Nanostructured Biomaterials and Their Applications in

Nanobiotechnology by H.S.Nalwa

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2. CHARACTERIZATION OF NANO MATERIALS UNIT I Electron microscopes -Scanning Electron Microscopes –Transmission Electron Microscopes -Scanning Probe Microscopy -Atomic Force Microscopy - Scanning Tunneling Microscope -Scanning Non-linear Dielectric microscopy - Nanomanipulator -nanotweezers –EDOX--XPS -ICP . UNIT II Mechanical characterization -modulus and load carrying capability of nano region/compression -micro hardness -fatigue -failure stress and strain toughness - glass transition and relaxation behaviour -abrasion and wear resistance, super plasticity- Nano indentation. UNIT III Neutron and X-ray diffraction -Debye-Scherer formula -dislocation density - micro strain -comparison of X-ray and neutron powder pattern -the Rietveld for powder pattern -macro molecular crystallography using synchrotron radiation -role for neutron scattering in nanoscience. UNIT IV Optics -photonics of nanotechnology -properties of light and nano technology-interaction of light with nano systems -absorbance, Surface plasma excitation, Size dependent PL -nano holes and photons -imaging -solar energy absorbents using nano particles -nano technology and day light -photonic crystals -wave guides and control of light paths. UNIT V UV-Vis-NIR spectrometer, band gap measurement -FTIR spectrometer, principle and application -Photoluminescence spectrometer, principle and application- force spectroscopy – biofunctionalized nanoparticles for SERS and SPR. Reference: 1. Nanotechnology: basic science and emerging technologies -Mick Wilson, Kamali

Kannangara, Geoff Smith, Michelle Simmons, Burkhard Raguse, Overseas Press (2005).

2. Nanocomposite science and technology, Pulickel M.Ajayan, Linda S.Schadler, Paul V.Braun, Wiley-VCH Verlag, Weiheim (2003).

3. www .eng .uc. edu/-gbeaucag/Classes/XRD/Neutron DiffractionatLN L. pdf 4. Scanning Probe Microscopy: Analytical Methods (Nanoscience and Nanotechnology)'

by R. Wiesendanger 5. Advanced X-ray Techniques in Research and Industries by A.K.Singh(ed.) 6. Transmission Electron Micrscopy of Materials by G. Thomas 7. Physical Principles of Microscopy: An introduction to TEM, SEM and AFM by R.F.Egerton 8. Instrumental Methods of Analysis (7th edn.) by Willard, Merritt, dean and Settle 9. Scanning Electron Microscopy and X-ray Microanalysis by J.Goldstein

10. Principles of Instrumental Analysis (5th edn.) by D.A.Stook, E.J.Holler and T.A.Nieman

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3. PHYSICAL CHEMISTRY – II

Unit – I: QUANTUM MECHANICS – I

Inadequacy of classical mechanics – Plank’s quantum theory - Compton effect - wave particle duality - uncertainty principle . Operators and their algebra , Eigen value and Eigen functions. Quantum mechanical postulates, Schrodinger equations(Time dependent and Time independent). Particle in a box (1D and 3D), Quantum mechanical tunneling and transmission coefficient – rigid rotor and harmonic oscillator.

Unit – II: QUANTUM MECHANICS – II

The hydrogen atom – radial distribution and spherical harmonics functions – shapes of atomic orbitals. Approximation methods: variation theorem, application of variation method to hydrogen and helium atoms. Perturbation theory (First order): application to helium atom. Pauli exclusion principle - Slater determinant and HF-SCF methods to He atom. Born-Oppenheimer approximations: LCAO-MO and VB treatments of H2 molecule. Huckel theory: application to ethylene, butadiene and benzene. Calculation of electron density and bond order. Unit – III: GROUP THEORY I Symmetry elements, symmetry operations and point groups, properties of group, symmetry and dipole moment, symmetry and optical activity, symmetry operations as a group, multiplication table. Classes of symmetry operations and matrix representations of operations. Reducible and irreducible representations, orthogonality theorem. Properties of irreducible representations. Constructions of character table for point groups (C2v, C3v, C2h, C4v and D2). Explanations for the complete character table for a point group. Unit – IV: GROUP THEORY II : Applications of group theory

Symmetry selection rules for infrared, Raman and electronic Spectra. Standard reduction formula. Determination of representations of vibrational modes in non-linear molecules (H20, NH3 and Trans N2F2). Infrared and Raman activities of normal modes of vibrations. Rule of mutual exclusion.

Electronic Spectra of Ethylene and formaldehyde molecules. Hybrid orbital in non-linear molecules (CH4, XeF4, BF3,and PF5). Projection operators and symmetry adapted linear combinations(SALC). Simplification of HMO calculations using group theory. Calculation of delocalization of energy in 1,3-butadiene and cyclopropenyl systems.

225

Unit – V: Electrochemistry Electrode-electrolyte interface, adsorption at electrified interface, electrical

double layer, electrocapillary phenomenon-Lipmann equation.Polarization and over potential, Butler-Volmer equation for one step and multistep electron transfer reactions, Tafel equation, significance of I0 and transfer coefficient, polarizable and non polarizable electrodes, mechanism of hydrogen and oxygen evolution reactions. Corrosion and polarization of metals - Pourbaix diagrams, Evan’s diagram, Fuel cells, electrode deposition-principle and applications. References

1. D. A. McQuairrie: Quantum Chemistry, Oxford University press, Oxford,1982. 2. P. W Atkins:. Molecular Quantum Mechanics, Clarendon Press, Oxford, 1983. 3. R. K. Prasad: Quantum Chemistry through Problems and Solutions, New Age

International, 1997. 4. A.K. Chandra: Introduction to Quantum Chemistry, Tata McGraw Hill, 1994. 5. H. K. Moudgil: Text Book of Physical Chemistry, Eastern Economy Publ.Co.Ltd.,

New Delhi,2010. 6. W. Levine: Quantum Chemistry, Prentice Hall, 1994. 7. Sen: Quantum Chemistry, Tata McGraw-Hall, 1992. 8. G. Aruldhas, Quantum Mechanics, 2nd Ed., PHI Learning, New Delhi, 2011. 9. Symmetry, Orbitals and spectra by M. Orchin & H. Jaffe, Willey. 10. Chemical applications of group theory by F. A. Cotton Willey . 11. Symmetry in chemistry by H. Jaffe and M . Orchin , Jhon willey. 12. Group theory and its applications to chemistry by K. V. Raman. 13. Group theory and spectroscopy by K. Veera Reddy.

14. Group Theory and Its Chemical Applications. Author, P. K. Bhattacharya.

15. Group theory by Gobinathan and Ramakrishnan.

16. Vibrational spectroscopy by D.N.Satyanarayana.

17. Physical chemistry. by F. Daniels and A. Alberty.

18. An Introduction to Electrochemistry by S. Glasstone.

19. Modern Electrochemistry Vol. I & II by J. O. M. Bockris and A.K.N. Reddy .

20. Physical Chemistry by P. W. Atkins. ELBS.

21. Physical chemistry of surfaces: A. W. Adamson.

22. Theories of chemical reaction rates by A. J. K. laidler.

23. Text book of physical Chemistry by H.K. Moudgil.

226

4. ORGANIC CHEMISTRY - III

Unit-I Aliphatic nucleophilic substitution and Elimination Reactions: Aliphatic nucleophilic substitution : Mechanism of SN1, SN2, SNi, SN1’, SN2’ and SNi reactions- Effect of substrate, nucleophile, leaving group and solvent on the rate of substitution- Ambient nucleophile- NGP- Mechanism of esterifications and ester hydrolysis (BAC2 and AAC2 mechanisms only) Elimination reaction: E1, E2 and E1CB mechanisms- Factors influencing elimination reactions- Hofmann and Satyzeff rules- Pyrolytic elimination- Chugaev and cope reactions. Unit-II Aromatic nucleophilic substitution Reaction and Addition to carbon-carbon multiple bonds Aromatic nucleophilic substitution reaction: Unimolecular, Bimolecular and Benzyne mechanisms. Catalytic hydrogenation- Birch reduction-Dieckmann condensation-Mannich reaction- Wittig reaction- Sharpless asymmetric epoxidation-addition of hydrogen and hydrogen halides to carbon-carbon double bonds-Michael addition (1,2 and 1,4). Unit-III Reactive intermediates and rearrangements Carbenes: Generation, stability, structure, reactions and stereochemistry of carbenes-Wolff rearrangement of acyl carbenes and its synthetic applications. Nitrenes: Generation, stability, reaction of nitrenes- Mechanism of rearranegements through Nitrene intermediate: Schmidt, Hoffmann, Beckmann rearrangements. Carbanion: Mechanism of rearrangements involving carbanion as intermediate: Steven, Sommelet Hauser and Favorski rearrangements. Arynes : Generation, Structure, Stability, reactions and trapping of arynes- cine substitution. Unit-IV Organic photochemistry and pericyclic reactions Photosensitization- cis-trans isomerisation- photo oxidation and reductions- Norris type-I and II reactions- Paterno-Buchi reaction- Barton reaction- Di-π methane rearrangement. Atomic and molecular orbitals-Woodward-Hoffmann rules, FMO and correlation diagram approaches: Electrocyclic reaction- con and dis rotatory motions for 4n and 4n+2system (butadiene and 1,3,5-hexatriene)- Stereochemical course of electro cyclic reaction in terms of conservation of orbital symmetry. Cycloaddiation- suprafacial and antarafacial additions, [2+2] and [4+2] reactions (ethylene and butadiene)- Sigmatropic rearrangements - [i,j] shift of C-H and C-C bonds (1+3 and 1+5system)

227

Unit-V Heterocyclic and biomolecules Synthesis and reactions of oxazole, imidazole, thiazole, coumarins benzopyrones and anthocyanins-synthesis of flavones, flavonol and quercetin-Biosynthesis of flavonoids. Pyranose and furanose forms of aldohexose and ketohexose-methods used for the determination of ring size-A Detailed study on the structure of maltose, sucrose and lactose- A brief study on starch and cellulose. Nucleoproteins and nucleic acid-chemistry and Heredity- genetic code.

REFERENCES

1.J.March, ‘ Advanced organic chemistry’, Fourth Edition, John Wiley and Sons, Newyork, 2006. 2. Depuy, E.C.H. and Chapman, O.S., “Molecular reactions and photochemistry” , Prentice Hall, New York, 1988. 3.I.L. Finar, ‘Organic Chemistry’, volume 2, sixth Edition, Pearson Education Inc., Singapore, 2006. 4.Raj K. Bansal, ‘Organic Reaction mechanisms”, Tata Mc Graw Hill, Third Editon, 2007 5.Singh, J., and Singh, J., “Photochemistry and Pericyclic reaction”, New Age International, New Delhi, 2004 6.H.O. House, ‘Modern synthetic Reaction,’Second Edition , W.A. Benjamin, Inc., London, 1972 7.R.K. Mackie, M.M. Smith and R.A. Aitken,’Guide Book to Organic Synthesis’ Second Edition, Longman Seientific and Technical, Singapore, 1990. 8.Carrutherus , W., “ Some Modern Methods in Organic Syntheis”, Third edition, Cambridge University Press, New York, 1997. 9.F.A. Carey and J.Sundberg,’Advanced Organic chemistry ‘ part A and B, Plenum Press, 2005. 10.Michael B. Smith, ‘Organic Synthesis,’ Mc Graw Hill international Edition , 1994 11.P. Sykes, ‘A Guide book to mechanism in organic chemistry’, Orient Longman, 1989. 12.Gurdeep R. Chatwal, ‘Reaction mechanism and Reagents in organic chemistry’Himalaya publishing House, Bombay 1992. 13. R.T. Morrison and R.N. Boyd,’Organic Chemistry’ sixth Edition, Prentice Hall,1994 14.R.O.C .Norman, Principles of organic synthesis- Chapman and hall, London. 15.De Mayo, Molecular rearrangements 16. E.S. Gould, ‘Mechanism and structure in organic chemistry’ Holt, Rinehart and Winston Inc., 1959 17. F.A. Carey, Organic chemistry – Tata Mc Graw Hill, Delhi, 5th edition 2005. 18. Stryer, L., “Biochemistry”, Fifth edition, W.H.Freeman and company, San Francisco, 2002. 19. Jain, J.L., “Fundamentals of Biochemistry”,Fourth edition, S.Chand & Company Limited, New Delhi.2007 20. Bansal, K., “Heterocyclic Chemistry”, Fourth edition, New Age International, New Delhi, 2005

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Fourth Semester 1. CARBON NANOMATERIALS

UNIT I Well known allotropes of carbon – Diamond and graphite – Their crystal structures – Distinguishing features – Discovery of fullerenes (0 D Carbon nanomaterials) – Laser ablation and arc-discharge methods - Structures of C60 & C70 – UV, IR, Raman and 13C NMR spectra of C60 & C70 – Cyclic voltammetric studies of C60 & C70 – Higher fullerenes – Some chemical reactions of C60 - like reduction, halogenation, Friedel-Crafts reaction, [2+2], [3+2] and [4+2] cycloaddition reactions. UNIT II 1D Carbon nanomaterials - Carbon nanotubes (CNTs) – Iijima’s observation – MWCNT and SWCNTs- Characterization by TEM - Methods of preparation of MWCNTs – Laser ablation & arc-discharge methods, decomposition of hydrocarbons by catalysts, organometallics as sources, microwave method –Separation and purification of MWCNTs – Synthesis of SWCNTs – Laser ablation, arc-discharge, HiPco methods – Metallic and semiconductor SWCNTs – Properties – Electrical, mechanical and vibrational (Raman spetra). UNIT III Chemistry of CNTs – Functionalization of CNTs – Covalent chemistry at the open ends of SWCNTs – Fluorination of CNTs and fluorine substitution reactions – Cycloadditions – 1,3-dipolar, nitrenes cycloadditons, nucleophilic and radical additons – Non-covalent bonding – surfactant molecules adsorbed on nanotube surfaces – Filling the inner cavity of CNTs by C60. UNIT IV Novel nano-forms of carbon – Carbon nanohorns, cup-stacked CNTs, carbon nanotori, carbon nano-onions, carbon nanobuds – Graphene (2 D Carbon nanomaterial) – Preparation – Exfoliation, from the tip of graphite, reduction of graphite oxide and by the opening of CNTs – Characterization by Raman spectrum – Mechanical properties, conductivity, Quantum Hall effect. Inorganic fullerene like molecules – MoS2 & WS2 – Boron nitride nanotubes. UNIT V Applications of carbon nanomaterials – Fullerides as superconductors – Fullerene nanocar – CNTs in field emission, shielding, FETs & logic gates – Hydrogen storage in CNTs and Fuel cells – Mechanical reinforcement by CNTs – Nanocomposites of CNTs – CNTs in chemical sensors, catalysis – Analytical applications of CNTs – Adsorption of dioxin, adsorption of substituted phenols from industrial wastes and determination of their concentration – some commercial products – CNTs in cancer therapy – Hyperthermia and carrier for direct drug delivery

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References 1. C. N. R. Rao (ed.), Special Issue of Fullerenes, Indian J. Chem., A & B, 1992, May. 2. W. Edward Billiups and M.A. Ciufolini (eds.), Buckminsterfullerenes, VCH

Publishers, New York, 1999. 3. Y. Gogatsi (ed.), Carbon Nanomaterials, C R C., Taylor & Francis, New York, 2006. 4. K. Tanaka, T. Yamabe and K. Fukui (eds.), The Science and Technology of Carbon

Nanotubes, Elsevier, Amsterdam, 1999. 5. T.W. Ebbesen (ed.), Carbon Nanotubes: Preparation and Properties, CRC Press,

Boca Raton, FL., 1997. 6. C. P. Poole, Jr., and F. I. Owens, Introduction to Nanotechnology, JohnWiley &

Sons, Inc., New Jersey, 2003. 7. T. Pradeep, NANO: The Essentials: Understanding Nanoscience and

Nanotechnology, Tata McGraw-Hill Publishing Co., Ltd., New Delhi, 2007. 8. L. Dai (ed.), Carbon Nanotechnology, Elsevier, 2006; 9. A. K. Geim and K. S. Novoselov, Nature Mat., 2007, 6, 183. 10. C. N. R. Rao et al., J. Mater. Chem., 2009, 19, 2457; A. K. Geim, Science, 2009,

324, 1530. 11. G. Park and R. S. Ruoff, Nat. Nanotechnol., 2009, 6, 183. 12. Y. Gogotsi (ed.), Nanotubes and Nanofibres, CRC, Taylor & Francis, New York,

2006. J. L. Delgado, M. A. Herranz and N. Martin, J. Mater. Chem., 2008, 18, 1417.

2. PROPERTIES OF NANOMATERIALS UNIT-I: ELECTRICAL AND MECHANICAL PROPERTIES Introduction - Energy Storage Basics - General Information: Electrical Energy Storage Devices and Impact of Nanomaterials – Batteries – Capacitors - Gold Standards (State of the Art) for Both Batteries and Capacitors - Electrochemical Properties of Nanoscale Materials - Aerogels and Structure-Directed Mesoporous and Macroporous Solids - Nanoparticles - Nanotubes, Nanowires, and Nanorolls. Nanoscale Mechanics - Introduction – Mechanical properties – Density Considered as an Example Property – The Elasticity of Nanomaterials – Elasticity of Bulk Nanomaterials – Plastic Deformation of Nanomaterials - The Physical Basis of Yield Strength – Crystals and Crystal Plasticity – From Crystal Plasticity to Polycrystal Plasticity. UNIT-II: NANOOPTICS Absorption: direct and indirect bandgap transitions - Emission: photoluminescence and Raman Scattering - Emission: chemiluminescence and Electroluminescence - Shape dependent optical properties - Optical absorption - Optical emission - Surface plasmon resonance (SPR) - Surface enhanced Raman scattering (SERS) UNIT-III: NANOCATALYSIS Introduction – nanomaterials in catalysis – metals – recent progress – nanostructured adsorbant – metals – controlled pore size materials – pelletized nanocrystal – nanoparticles as new chemical reagents – metals – metal oxide reactions – nanocomposite polymers – fluids, inks and dyes – block co polymers and dendrimers – nanocrystal superlattices.

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UNIT-IV: NANOMAGNETISM Introduction – fundamental concepts – magnetic materials – dia, para and ferromagnetism - magnetic phenomena in ferromagnetic materials – magnetic anisotropy – magnetic domains – hysteresis small particle magnetism – single domain particles – coercivity of single domain particles – superparamagnetism – the coercivity of small particles - review of some issue in nanoscale magnetism. UNIT-V: NANOELECTRONICS Basics of nanoelectronics - Single electron transistor – Principle – Coulomb Blockade effect – performance of the single electron transistor – Bioelectronics – molecular processor – DNA analyzer as biochip – DNA computer – Quantum computer. Reference 1. Nanomaterials : Mechanics and Mechanisms, K. T. Ramesh, Springer 2009. 2. Nanoscale materials in chemistry, Edited by Kenneth J. Klabunde, John Wiley & Sons, 2009. 3. Nanoscale materials in chemistry, Edited by Kenneth J. Klabunde, John Wiley & Sons, 2001. 4. Nanoscopic materials; Size dependent phenomena, Emil Roduner, RSC publishing, 2006. 5. Optical properties and spectroscopy of nanomaterials, Jin Zhong Zhang, World Scientific, 2009. 6. Nanoelectronics and nanosystems – K. Goser, P. Glösekötter and J. Dienstuhl, Springer 2008.

3. INORGANIC CHEMISTRY - III UNIT – I : NUCLEAR CHEMISTRY- I Atomic nuclei : classification , composition and stability – nuclear shell structure – nuclear reactions : types , Q-value , threshold energy , cross sections and excitation functions – nuclear reaction models : optical and compound nucleus models . Direct nuclear reactions – transfer reactions : stripping and pick-up –high energy reactions : neutron evaporation and spallation – heavy ion reactions – photonuclear reactions. Nuclear fusion and stellar energy – nuclear fission : mass and charge distribution of fission products – fission energy – fission neutrons – theory of nuclear fission – spontaneous fission . UNIT – II : NUCLEAR CHEMISTRY - II Nuclear reactors : classification , components , reproduction factor and design parameter – fuel materials and their production. Breeder reactor : fast breeder test reactor – reprocessing of spent fuels : aqueous and non-aqueous processes – disposal of gaseous , liquids and solid radioactive wastes –radiation hazards and protection – India’s nuclear reactors . Radio isotopes : preparation, application of radio isotopes in

231

elucidating reaction mechanisms and structural determinations . Analytical applications : radio chromatography , neutron activation analysis , neutron absorptiometry and radiometric titrations – hot atom chemistry – synthesis of transuraniens . UNIT – III : INORGANIC CHAINS , RINGS , CAGES AND CLUSTERS Hetero catenation - silicates - classification and structure-property correlation . Polyacids – structures of isopoly and heteropoly anions - polymeric sulphur nitride - borazines – phosphazenes - phosphazene polymers - boranes and carboranes – structure and bonding in boranes. Metal-metal bonds and metal atom clusters - carbonyl type - anionic and hydrido clusters- non- carbonyl type – octahedral clusters and triangular clusters . UNIT-IV : APPLICATION OF SPECTROSCOPY TO THE STUDY OF INORGANIC COMPOUNDS-III NMR SPECTROSCOPY: 31P, 19F and 15N - NMR - introduction - applications in structural problems — evaluation of rate constants — monitoring the course of reaction — NMR of fluxional molecules — NMR of paramagnetic molecules — contact shifts and shift reagents. ESR spectroscopy: Principles — presentation of the spectrum — hyperfine splittingfactors affecting the magnitude of g-values — zero- field splitting and Kramers’ degeneracy — anisotropy in the hyperfine coupling constant. Application of ESR in the study of transition metal complexes. J-T distortion: studies of Cu(II) complexes. UNIT-V : BIOINORGANIC CHEMISTRY Essential and trace elements in biological system – biological importance and toxicity of elements such as Fe , Cu , Zn , Co , Mo , W , V , Mn , and Cr in biological system. Metallo porphyrins – chlorophyll – photosynthetic electron transport sequence – biological electron carriers : iron-sulphur proteins , cytochromes and blue copper proteins – oxygen carriers: haemoglobin and myoglobin - Haemoglobin modelling : synthetic oxygen carriers . Corrin ring system - vitamin B12 , Fixation of nitrogen – in vitro and in vivo. REFERENCES Samuel Glasstone , Source Book of Atomic Energy , East West Pvt.Ltd., 1969. H.J.Arnikar , Essentials of Nuclear Chemistry , Wiley Eastern Ltd., 4th Edition ,2000 . G.Friedlander , J.W.Kennedy , E.S.Macies and Julian Malcolm , Nuclear and Radiation Chemistry , A . Wiley Interscience publication ,1981. James .E.Huheey , Ellen .A. Keiter and Richard .L. Keiter , Inorganic Chemistry : Principles of Structure and Reactivity , 4th Edition , Harper Collins College Publishers , 1993 . F.Albert Cotton , Geoffrey Wilkinson , Carlos .A.Manic and Manfred Bochman , Advanced Inorganic Chemistry ,Wiley Interscience Publication , 6th edition , 1999 . G.S.Manku , Theoretical Principles of Inorganic Chemistry , Tata McGraw Hill, 12 reprint 2004.

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K.F.Purcell and J.C.Kotz ,Advanced Inorganic Chemistry , Saunders Golden Publishers . B.E.Douglas , D.H.McDaniel and J.J.Alexander , Concepts and Models of Inorganic Chemistry , John Wiley and Sons Ltd . 2nd Edition , 1983. J.D.Lee , Concise Inorganic Chemistry , Blackwell Science Ltd., 5th Edition, Reprint 2003. M.C.Day Jr. And J.Selbin.,Theoretical Inorganic Chemistry , 2nd Edition , East West Press , 2000. R.S.Drago , Physical Methods in Inorganic Chemistry ,W.B.Saunders ,1977. E.A.V.Ebsworth David ,W.H.Rankin Stephen Credock ,Structural Methods in Inorganic Chemistry ,ELBS , IV 1988. D.E.Fenton ,BioCoordination Chemistry , Oxford Science Publications ,1995. I.Bertini, H.B.Gray ,S.J.Lippard and J.S.Valantine , Bioinorganic Chemistry , Viva Books Pvt. Ltd., 1998. .

4. PHYSICAL CHEMISTRY - III

Unit-I: Introduction of spectroscopy and Rotational Spectra Characterization of electromagnetic radiation. Regions of Spectrum, transition probability, the width and intensity of spectral transitions. Classification of molecules according to their moment of inertia. Rotational spectra of rigid and nonrigid diatomic molecules. The intensities of spectral lines. The effect of isotopic substitution. Polyatomic and symmetric top molecules. The stark effect. Unit- II: Infrared spectroscopy and Raman Spectroscopy Diatomic molecules : Molecules as harmonic oscillator, Force constant, zero point energy, isotope effect. The Anharmonic oscillator, the diatomic vibrating rotator. Polyatomic molecules-Fundamental vibrations and their symmetry, overtone and combination frequencies, concept of group frequencies, Fermi resonance and FTIR. Raman Spectroscopy Rayleigh scattering . Raman Scattering, classical and quantum theories of Raman effect. Rotational Raman Spectra for linear and symmetric top molecules. Vibrational Raman Spectra , rotational fine structure. Polarization of light and the Raman effect. Technique and instrumentation- Laser Raman spectrometer. Structure determination from Raman and Infra-red spectroscopy. Unit –III: Electronic Spectroscopy Electronic spectroscopy of diatomic molecules. Born – oppenheimer approximation. Sequences and progressions, the vibrational course structure and rotational fine structure of electronic band. The Franck-Condon principle, dissociation energy and dissociation products. Birje-Sponer extrapolation. The fortrat diagram. Predissociation, Photoelectron spectroscopy: principle, instrumentation,X-ray and UV-PES. ESCA applications, Auger electron spectroscopy

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Unit -IV: Nuclear Magnetic Resonance Spectroscopy The theory of PMR spectra, Chemical shift, factors affecting chemical shift, relaxation times and spin- spin interactions. NMR of simple AX and AMX type molecules. Calculation of coupling constants, Techniques and instrumentation of continuous wave and FT-NMR spectroscopy. 13C, 19F and 31P NMR spectra-principle and applications. Electron Spin Resonance Spectroscopy Basic principles , factors affecting “g” value, hyperfine splitting . Deuterium, Methyl, benzene, naphthalene, anthrazene, xylene(o, m, p-), p-benzosemiquinone radicals, calculation of electron density- McConnel equation, Fine structure in ESR- Zero field shifting and Kramer’s degeneracy. Double resonance-ELDOR and ENDOR, study of unstable paramagnetic species, spin labeling studies of bio-molecules. Unit – V: Quadrupole resonance and Mössbauer Spectroscopy (a)Nuclear quadrupole resonance: Basic principle, comparison with NMR, splitting of quadrupole energy levels, asymmetry parameter, Applications- hydrogen bonding, phase transition, substituent effect and Pi- bond character. (b) Mössbauer parameters:– Isomer shifts, quadrupole splitting, Magnetic hyperfine interaction, Doppler effect/shift. Application of Mössbauer Spectroscopy:- (i) covalently bonded compounds, (ii) oxidation states of metal ion in compounds,(iii) Structural detetrmination, (iv) magnetically ordered compounds (i.e Ferromagnetic & antiferromagnetic compounds). REFFERENCES

1. Fundamental of molecular spectroscopy by C. N. Banwell Tata McGrew Hill. 2. Molecular structure and spectroscopy, IInd edition – 2011 by G. Aruldhas. 3. Molecular spectroscopy by K.V.Raman, R.Gopalan and P.S.Raghavan. 4. Spectroscopy, Vol. 1,2 and 3 by B.P. Straughan and S.Walker. 5. Molecular spectroscopy by Sindhu. 6. Basic principles of spectroscopy by R.Chang. 7. Molecular Spectroscopy by I. N. Levine , Willey interscience. 8. Molecular Spectroscopy by G. M. Barrow. 9. Physical Methods for Chemists,. 2nd ed.”, by R.S.Drago. 10. Vibrational spectroscopy by D.N.Satyanarayana. 11. Graebeal, Molecular Spectroscopy Prientice Hall, 1968. 12. A. Carrington and Machlachlon, Magnetic Resonance, Harper & Row. 1967. 13. A. Rahman, Nuclear Magnetic Resonance- Basic Principles, Springer-Verlag,

Newyork, 1986. 14. J.A. Weil, J.R. Bolton and J.E. Wertz, Electron Paramagnetic Resonance; Wiley

Interscience: 1994.

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NANOSCIENCE PRACTICALS- I

1. Synthesis of ZnS nanoparticles by chemical route and determination of band

gap through UV-Vis spectroscopy

2. Synthesis of CdS nanoparticles by chemical route and X-ray powder

diffraction pattern analysis

3. Synthesis of oxide nanostructures/ nanocomposites and determination of

resistance by impedance spectroscopy technique

4. Synthesis of BaTiO3 nanostructure by mechanical ball milling

5. Synthesis of Cu/Ag nanopartcle through Micellar route and film thickness

measurement using weigh method

6. Hydrolysis method of sample preparation

7. Sol-Gel method of sample preparation and characterization by FTIR

8. Preparation of nanoparticles by co-precipitation method

9. ZnO nanopowder preparation by using NaOH as capping agent and

characterization by AFM

10. Synthesis of TiO2 nano particles by sonochemical method

11. X-ray diffraction pattern of nano-ZnO powder and thin films; determination of

particle size

NANOSCIENCE PRACTICALS- II

NANOTHIN FILMS

1. Electroless of deposition of Cu/Ni on glass substrate

2. Preparation of Cu/Ni thin film by using electrodeposion

3. Nanostructured thin film preparation by using the spray pyrolysis method

4. Nanostructured thin film preparation by using the sol-gel process

5. Nanostructured thin film preparation by using the chemical bath technique

6. Nanostructured thin film preparation by using the spin-coating process

7. Nanostructured thin film preparation by using the dip-coating method

235

NANOBIOLOGY

8. Quantitation of proteins and sugars

9. Analysis of oils : iodine number, saponification value, acid number

10. Agarose gel electrophoresis

11. SDS-Poly Acrylamide Gel Electrophoresis (SDS-PAGE)

12. Titration of amino acids

13. Colorimetric determination of pKa

14. Model building using space filling/ ball and stuck models

15. Reaction of amino acids, sugars and lipids

16. Nanomicrobial degradation of various xenobiotics (e.g. pesticides, organochlorines, pyretheroids, PAH)

PROJECT

The research project should be completed and the Dissertation (Report) should

be submitted for evaluation. The project report is expected to provide clear answers for

following questions:

(i) Why this particular investigation was selected?

(ii) How was the investigation carried out?(Describing the methodology used);

(iii) What are the results obtained? (Reporting the results obtained);

(iv) How are the results interpreted? (Discussing the results);

(v) What are the conclusions derived?

Note:

Project for PG students shall be group projects Each group contain 3 or 4 students

The students are asked to submit their project report on or before the last working day of the fourth semester end

236

APPENDIX-BA19

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI – 12

M.Sc. Conservation of Marine Environment CBCS-For Colleges – UGC Innovative Programme

(For those who joined the course in June 2013 – 2014 and afterwards) Eligibility for Admission: Candidates with B.Sc., Degree in Zoology, Botany, Geology, Microbiology, Biochemistry, and Biotechnology with 50% marks and above obtained from Manonmaniam Sundaranar University or equivalent to B.Sc., Zoology / Botany, Geology, Microbiology, Biochemistry, and Biotechnology as recognized by Manonmaniam Sundaranar University with 50% marks and above are eligible to be admitted in to this course. However, the relaxation to 50% for SC, ST and MBC candidates is allowed as per the State Government norms.

M.Sc. Conservation of Marine Environment COURSE CONTENT

I Semester Course code Subject CME1 Marine Invertebrates and Prochordates CME2 Marine Vertebrates CME3 Physical Oceanography CME4 Chemical Oceanography CME5 Elective: Marine Biotechnology CMEP1 Practical I

II Semester CME6 Biological Oceanography CME7 Marine Ecology and Microbiology CME8 Marine Biodiversity – importance and threats CME9 Fisheries and Quantitative Biology CME10 Elective: Marine Pollution CMEP2 Practical II

III Semester CME11 SCUBA Diving CME12 GIS and Remote Sensing CME13 Marine Environment Conservation Strategies CME14 Marine Policy and Socio-economics CME15 Elective: Integrated Coastal Zone Management CME16 Elective: Environmental Impact Assessment and Disaster

Management CMEP3 Practical III IV Semester CMPER Project work

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Course Structure and Examination under CBCS System

Course code Subject Title Hrs Credits Internal

Marks External Marks

Total marks

First Year - I Semester Subject

CME1 Marine Invertebrates and Prochordates 6 4 25 75 100

CME2 Marine Vertebrates 5 4 25 75 100 CME3 Physical Oceanography 5 4 25 75 100 CME4 Chemical Oceanography 5 4 25 75 100

CME5 Elective : Marine Biotechnology 5 5 25 75 100

CMEP1 Practical I 4 4 40 60 100 II Semester

CME6 Biological Oceanography 5 4 25 75 100

CME7 Marine Ecology and Microbiology 5 4 25 75 100

CME8 Marine Biodiversity – importance and threats 6 4 25 75 100

CME9 Fisheries and Quantitative Biology 5 4 25 75 100

CME10 Elective: Marine Pollution 5 5 25 75 100

CMEP2 Practical II 4 4 40 60 100 Second Year - III Semester

CME11 Scuba Diving 4 4 25 75 100 CME12 GIS and remote sensing 4 4 25 75 100

CME13 Marine Environment Conservation Strategies 4 4 25 75 100

CME14 Marine Policy and Socio-economics 4 4 25 75 100

CME15 Elective: Integrated Coastal Zone Management

5 5 25 75 100

CME16

Elective: Environmental Impact Assessment and Disaster Management

5 5 25 75 100

CMEP3 Practical III 4 4 40 60 100 IV Semester

CMEPR Project work 10 40 60 100

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SEMESTER I

PAPER-CME1-MARINE INVERTEBRATES AND PROCHORDATES Unit 1 Classification of animation kingdom upto phylum – Life history and phylogenetic relationship of Protozoa, and Porifera (Sponges). Coelenterata – Polymorphism – Life history of Jelly Fish – Theories on Coral reefs – Distribution & economic importance of coral reefs. Unit 2 Functional morphology – Development and evolution of following. a. Nemertinea b. Entoprocta, c. Ectoprocta, d. Phoronida and e. Pogonophora. Unit 3 Chaetognatha – Classification – Distribution – Morphology and anatomy – Embryology and evolution – Brachiopoda – Classification – Morphology – Paleontology and evolution. Polychaeta – Classification – Morphology, reproduction and adaptive radiation. Unit 4 Crustacea – Classification – Comparative morphology – Crustacean appendages – Larval forms and evolution – Paleontology. Echinodermata – water vascular system – Life History of Sea Urchin. Unit 5 Mollusca – Classification – General characters – Torsion – adaptive radiation. Prochordates – Classification and Comparative morphology, reproduction and early development including larvae. References:

1. Highnam, K.C. And Hill, L. (1979), The Comparative Endocrinology of Invertebrates, ELBS & Edward Arnold (Publishers) Ltd., London.

2. Hyman, G.H., The Invertebrates, Vol. I to VII, McGraw Hill Book Co., Inc., N.Y. 3. Vasantika Kashyap (1997), Life of Invertebrates, Vikas Publishing House Pvt.

Ltd., New Delhi. 4. Barnes, R.D., 1974. Invertebrate Zoology, Toppan Company Limited, Tokyo,

Japan. 5. Kotpal, R.L., Minor Phyla, Rastogi Publication, Meerut.

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PAPER-CME2-MARINE VERTEBRATES Unit 1 Chordate features and theories on the origin of chordates. Classification and evolution of jawless and primitive jawed vertebrates. Evolution and adaptive radiation of elasmobranches and bony fishes. Origin of Amphibia, distribution, anatomical peculiarities and affinities of urodele and apoda. Unit 2 Origin of reptiles – Adaptive radiation of contemporary reptiles – Sea Turtles – Mammal like reptiles – Origin, rise and fall of Mesozoic marine reptiles. Unit 3 General characters of mammals – Aquatic mammals – classification, adaptations and evolution of Cetacea and Sirenia. Unit 4 Aquatic adaptations – Structural, functional and behavioural adaptation of aquatic animals – Comparative anatomy of skin derivatives. Unit 5 Gametogenesis, fertilization, types of eggs, cleavage, gastrulation in fishes with special reference to marine fishes. References:

1. Colbert, H. Edwin, 1989. Evolution of the Vertebrates, II Ed., Wiley Eastern Limited, New Delhi.

2. Harrey Pough, John B. Heisher, William N. Mcfarland, 1990. Vertebrate Life, Macmillan Publishing Co., N.Y.

3. Jollie, M., 1962. Chordate Morphology, Reinholt Publishing Corporation, N.Y. 4. Kent, G.C., 1976. Comparitive anatomy of the Vertebrates, McGraw Hill Book

Co., Inc., New York. 5. Romer, A.S., 1974. The Vertebrate Body, W.B. Saunders, London.

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PAPER-CME3 – PHYSICAL OCEANOGRAPHY Unit 1 Oceanography – Introduction, history. Origin of Oceans. Bottom topography – Abyssal hills and plains – Submarine canyons – Oceanic trenches. Unit 2 Physical properties of sea water – density, viscosity, surface tension, conductivity and their interrelationship, UV radiation, Acoustics. Light in the sea. Temperature distribution – heat budget. Unit 3 Ocean circulation – General surface circulation – forces causing currents – monsoon and trade winds – wind driven and thermohaline circulation – boundary currents – Langmuir circulation – geostrophic currents – turbidity currents – upwelling. Unit 4 Waves – formation of swell – Internal and standing waves – tidal waves – storm surges – Tides – tide generating forces – tidal currents – tidal effects in coastal areas. Unit 5 Sedimentation – origin and physical properties of sediments. Classification of marine sediments (lithogenous biogenous and cosmogenous). Distribution and transport of sediments. Determination of age of sediments.

References: 1. Sverdrup,H.U., M.W.Johnson and R.H. Flemming 1958. The Oceans - their Physics, Chemistry and General Biology. Prentice-Hall Inc. New Jersey. 2. Duxbury, A. C., A. B. Duxbury and K.A. Sverdrup, 2000. An introduction to the

World's oceans. Wm. C. Brown Publishers. 3. Stowe, K., 1996. Exploring Ocean Science. John Wiley Sons Inc. 4. McCormick,J.M. and J.V. Thiruvathakal, 1976. Elements of Oceanography.

W.B.Saunders, Philadelphia. 5. Flickard, G.L. and W.J. Emery, 1995. Descriptive Physical Oceanography - an

Introduction (fifth edition). Pergamon Press, London.

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PAPER-CME4 – CHEMICAL OCEANOGRAPHY Unit 1 Marine chemistry – Introduction. Physical and chemical properties of water. Difference between fresh water, sea water and brackish water. Chemical composition of seawater. Ionic composition of seawater – Major and minor constituents - Major and minor elements – trace elements their importance and distribution - Concept of chlorinity and salinity of seawater – methods of measurement. Unit 2 Dissolved gases – carbon-di-oxide-origin, importance and distribution. CO2 – CO3 system. Dissolved oxygen – origin and factors governing the distribution, BOD and COD. N2, H2S, methane – noble gases – their origin, distribution and importance. Unit 3 Organic matter – dissolved and particulate – sources, classification, composition, distribution, seasonal variation and estimation - Humic substances and their role in the chemistry, fertility and biogeochemistry of the sea – interaction with heavy metals and significance in detoxification. Unit 4 Nutrients – Inorganic plant nutrients – origin, role in the fertility of the sea. Kinds of nitrogen, phosphorus and silicon in the sea – analytical methods, distribution and cycling–“New” and “regenerated” reproduction, N: P ratio and significance. Mineral wealth of the sea – salts, glauconite, petroleum, phosphorite, manganese nodules etc. – potential and economics of extraction. Unit 5 Desalination–techniques. Marine corrosion–causes, prevention and protection from corrosion. Radio nuclides in the sea – origin, distribution and use as tracers of water mass. References: 1. Riley, J.P. and R. Chester, 1971. Introduction to Marine Chemistry. Academic Press,

London. 2. Riley, J.P. and G. Skirrow, 1975-1984. Chemical Oceanography, Vols. 1- 8. Academic Press, London. 3. Strickland, J.D.H. and T.R. Parsons, 1972. A Practical Handbook of 4. Seawater Analysis. Fisheries Board of Canada, Ottawa, Bulletin, 167. 5. Broecker W.S., 1974. 2nd edition, Chemical Oceanography. Harcout Brace,

Jovanovich.

242

PAPER-CME5– MARINE BIOTECHNOLOGY

Unit-1 Definition of gene, prokaryotic and eukaryotic gene and its expression -Vectors- types of vectors-Restriction Enzymes: Type I, II, III-commonly used restriction enzymes resulting blunt ends and cohesive ends. Ligases- DNA replication - DNA polymerases, RNA primer, Primosome complex, helicase, ssb proteins; discontinuous synthesis. Transcription- DNA-RNA hybrid, enzymes involved in RNA synthesis; Reverse transcription; Protein Synthesis - translation factors - mRNA, tRNA and rRNA. Structure and function; genetic code. Genetic Recombination - homogenous & heterogenous genetic recombinations, DNA repair. Unit-2 Genetic Engineering – Recombinant DNA- Construction of Genomic DNA libraries. Construction of cDNA libraries- Nick translation, probes using oligos, RNA, DNA and auto radiogram. DNA sequencing - Sanger’s Dideoxy sequencing and Maxam & Gilbert sequencing. Automated DNA sequencing using fluorescence. PCR basic principles. Gene cloning and analysis of cloned genes. Transgenic animals – Transgenic fish, GMO and their risks. DNA Bar coding – methods and its applications.

Unit-3 Bioactivities of Marine Natural Products. An introduction to the marine natural products - Antibiotic-tumor, repellent, anti-parasitic, Microbial, antifouling. Commercial potential and development of marine natural products - actinomycetes, bacteria, algae, sponges. Chitosan as a biomaterial. Algal products - carrageenan, algin, Beta-carotene, agar and vitamins. Dinoflagellates as a source of bioactive compounds: A brief introduction of isolation, chemistry and pharmacology of saxitoxin, brevitoxin and ciguatoxin Tunicromes. Phytochemical – classes of phytochemical– mechanism of action of phytochemical- extraction of phytochemical from micro and macroalgae –Techniques - Applications. Microalgal biotechnology - Single Cell Protein(SCP) – Biomass Production of Spirulina maxima.

Unit-4 Marine toxins - Chemistry, Toxicity, occurrence and detection. Marine organisms and Biotoxins - Jellyfish, anemone, horseshoe crab, sting ray and lionfish. Biotoxins- Mycotoxins, Zootoxins, Phytotoxins, cone snail. Hydrophilic and lipophilic toxins.Syndrome – PSP, NSP, DSP,CFP. Isolation techniques: Liquid – Liquid extraction, membrane separation methods and Chromatography (TLC, HPLC) and conventional techniques. Characterization techniques: IR, UV, NMR, and mass spectra.

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Unit-5 Biotechnology applications in Aquaculture. Tissue Culture: Culture techniques of plant (marine algae and mangroves) and animal (crustaceans, molluscs & fishes) tissues, preservation of germplasms, cryopreservation of tissue cultures, in vitro fertilization technique. Gene manipulations to improve strains: Industrial applications of tissue culture Techniques – protoplast fusion. Diseases in marine organisms: Application of biotechnology in disease diagnosis, prevention and control – gene probes and their industrial applications. Role of biotechnology in environmental pollution control: Indicator organisms, Test organisms, Monitoring organisms, Enzymes.

References: 1. David H.Attway & Oskar R.Zabosky: Marine Biotechnology: Volume 1,2,3,

Plenum Press, 1993.

2. W.Old & Primrose: Principles of gene manipulation SB Univ. Press.Cambridge.

3. Lewin.B: GENES V, John Wiley.

4. Watson et al : Molecular Biology of Gene. Benj. Cumm.

5. G. Reed et al : Industrial Microbiology. C.B.S. Publishers.

6. H H Rehm & G. Reed : Biotechnology Vol. IV.

7. R.R.Colwell (ed), Biotechnology of Marine Science, 1982.

8. R.R.Colwell et. al (eds) Biotechnology of Marine polysaccharides, 1985.

9. A. M. Chakravarthy: Biodegradation and detoxification of Environmental

pollutants, CRC Press, 1928.

10. Rita Colwell (Ed): Biotechnology in Marine Sciences, Academic Press, 1981.

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PAPER - CMEP1 - PRACTICAL I

1. Water sampling devices – Mayers water sampler; Light measuring devices – Secchi disc

2. Analysis of seawater - Salinity, Alkalinity, Dissolved oxygen, Nitrite, Nitrate. 3. Bottom sampling devices –Van Veen grab – corer 4. Analysis of sediment – organic carbon, sediment texture 5. Determination of primary production using light and dark bottle techniques. 6. Chromatography – TLC, GLC, HPLC – principles. 7. Identification of coastal invertebrate fauna 8. Mounting of gastropod radulae. 9. Mouth Parts of Squilla and Balanus. 10. Anatomy of shrimp. 11. Nervous system of gastropods. 12. Alimentary Canal of gastropods.

SEMESTER II

PAPER – CME6 – BIOLOGICAL OCEANOGRAPHY Unit 1 Plankton–Phytoplankton-classification, diatoms and dinoflagellates-identification features. Methods of collection of phytoplankton and zooplankton – Estimation of standing crop – Wet and dry weight estimations – Plankton volume – settling and displacement methods – Determination of plankton biomass. Unit 2 Adaptations of plankton-structural and Physiological mechanisms. Marine fungi and Actinomycetes – Occurrence and distribution – adaptations – Ecological role – Economic significance. Unit 3 Plankton production-primary and secondary production. Methods of estimation of primary and secondary production. Influencing factors on primary production. Regional difference in (primary and secondary) production. Phytoplankton and zooplankton interrelations. Red tide phenomenon – Its causes and effects – Bioactive Substances, their potential and uses. Unit 4 Seaweeds – taxonomy, identification features, occurrence and distribution in India, economic importance, production-agar, algin, carragenan, culture. Sea grass – classification, identification, morphological and anatomical adaptations, occurrence and distribution in India, ecological role. Chemical ecology-ecological role of metabolites, host-bacteria interactions.

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Unit 5 Mangroves and salt marshes – classification, identification, distribution, adaptations, ecological role, uses, need for conservation. Remote sensing technique for biological resources assessment. References: 1. Lalli, C.M. & T.R. Parsons, Biological Oceanography: An introduction (2nd Ed). 2. Raymont, J.E.G., 1973. Plankton and Productivity in the Oceans. Pergamon Press,

London. 3. Yale Dawson, E., 1966. Marine Botany: an Introduction. Hole Reinhart and Winston

Inc., New York. 4. Sverdrup, H.U., M.W. Johnson and R.H. Fleming, 1959. The Oceans – their 5. Physics, Chemistry and General Biology. Prentice- H" Inc., New Jersey. 6. Clinton J. Dawes, 1988. Marine Botany. John'Wiley & Sons Inc. 7. Nair, N.B. & D.M. Thampy, 1980. A text book of Marine Biology, Macmillan.

PAPER – CME7 - MARINE ECOLOGY AND MICROBIOLOGY Unit 1 Marine environment – divisions and classification. Pelagic Division – Neritic and Oceanic environments, planktonic and nektonic adaptations. Benthic Division – Intertidal ecology – rocky shores – sandy shores – muddy shores – environmental factors – zonation – fauna and their adaptations. Deep-Sea Ecology – characteristics features of the deep sea – adaptations. Unit 2 Marine Ecosystems - Concept – Principal components. Marine ecosystem analysis and modeling. Marine food chains – Trophic structure – Food web – Ecological pyramids – Energy flow – Evolution and management of Ecosystem – Systems ecology and modeling. Animal association in the marine environment – endoecism – Inquilinism – Phoresis – Epizoism – Mutualism – Commensalism – Symbiosis – Parasitism. Prey-predator relationship – Density dependent and density independent factors. Unit 3 Community Ecology - Community concept – Structure and composition – Diversity and stability – Concept of niche – Succession. Zoogeography with reference to the Indian Ocean, Arctic and Antarctic fauna. Marine borers and foulers, their biology and adaptations. Biofouling – primary film. Influence of environmental factors – Succession among fouling organisms – Economic importance – Antifouling measures – imposex. Relationship between fouling and corrosion. Unit 4 History and scope of microbiology – composition of microbes – Prokaryotes and Eukaryotes-distinguishing features. Cyanobacteria. Significance in Oceanographic studies – Influence of physical, chemical and biological factors on marine microorganisms. Microorganisms and marine animals – relationship, commensals, symbionts and parasites. Role in the cycling of minerals – carbon, nitrogen and

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phosphorus cycle-decomposition of organic matter. Methods of studying the marine microorganisms – isolation of bacteria from water and sediment samples – culture and enumeration – Total and viable counts – Identification. Unit 5 Seafood Microbiology - Microbial spoilage of fish. Microbial hazards in fish and fishery products. Food poisoning – Bacterial toxins – botulism, Staphylococcal food poisoning, Salmonellosis. Mycotoxins – Aflatoxins – production and occurrence – mode of action. HACCP. Halotolerant and halophobic bacteria. Microorganisms and water pollution – pathogens-distribution-indicators of pollution (Faecal coliforms) – Prevention and control. Biodegradation – microbial degradation – biodegradation of xenobiotics. Bioremediation – case histories – constraints and priorities. References:

1. Sverdrup, H.U., M.W. Johnson and R.H. Fleming, 1959. The Oceans - their Physics, Chemistry and General Biology. Prentice- H" Inc., New Jersey.

2. Rheinhemer, G., 1980. Aquatic Microbiology, John Wiley & Sons, pp. 235. 3. Processcott, L. M., J. D. Chan and N. R. Kerig, 1993. Microbiology, WEB MCc

Graw Hill, pp. 962. 4. Pelczar, M. J. J., E. C. S. Chan and N. r. Kreig, 1993. Microbiology – concepts

and applications. 5. Dube, H. C., 1994. A text book of fungi, bacteria and viruses, Vikas Publishing

House, pp. 240. 6. Davis, D., Dulbecco, R., Eisen, H. N. and Ginsberg, H. S., 1990. Microbiology.

Third Ed., Harper and Row Publishers, Hagerstown. 7. A.D. Bonnell, Quality assurance in seafood processing – a practical guide,

Chapen and Hall, London 8. Charles L. Cutting. Fish processing and preservation. Agro-botanical Publishers,

India 9. Connel, J.J., 1975. Control of Fish Quality, Fishing News Books Ltd. 10. Aitikin, A., 1982. Fish handling & processing 2nd edition, Min. Agr. Fish and Food,

U.K.

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PAPER – CME8 - MARINE BIODIVERSITY– IMPORTANCE AND THREATS

Unit 1 Definition – Types of Biodiversity – Species, ecosystem and Genetic biodiversity. Importance of Marine Biological Diversity – Products from marine life: Food, Medicine and Raw materials – seaweeds, seagrass, significance of three dimensional structure of mangrove plantation – Ecosystem services from sea. Unit 2 Threats to Marine biological diversity : Proximate threats – over exploitation of marine invertebrates (crustaceans and molluscs), pisces (fish), reptile (sea turtle), marine mammals (whale, dolphin), Physical alterations – mining, dredging, navigation, simplification, fragmentation, marinas, jetties, pollution – oil spilage, chemicals, radionucleocides – transfer through ballast water– global warming and its impact on marine biodiversity. Unit 3 Impediments to Marine conservation: Insufficient scientific information – available with traditional users of sea, scientists but not complete, inadequate transfer of information – improve vertical transfer to horizontal transfer, decision makers, cultural and biological diversity – fundamental ecological shift, tragedy of the commons, economic valuation – value of species and ecosystem that do not enter markets, internalization of externalities. Unit 4 Conservation of biodiversity: areas of diversity, areas to be protected, larval and nursery grounds. Risk factors for populations: demography – sex ratio, anthropogenic uncertainty, low recruitment, mortality - Tools for conservation of marine biodiversity: political advocacy – Expanding knowledge base – science, research, planning, regulating threats, economic tools, protecting areas, active manipulation. Unit 5 Hurdles in enforcement of existing laws / regulation –insitu conservation – exsitu conservation – alternate livelihood programmes

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References:

1. Chapman, V. J., 1976. Mangrove vegetation. J. Gramer, Berlin. 2. Peter Mc Roy, C. and G. Helferich, 1977. Seagrass Ecosystems. A Scientific

respective. Marcel Dekker Inc., Ney York. 3. Yale Eawson, E., 1966. Marine Botany: An introduction. Hole Reinhart and

Winston Inc., New York. 4. Kaestner, A., 1967. Invertebrate Zoology. Vol. I to III. Wiley Interscience

Publishers. 5. Carl E. Bond, 1979. Biology of Fisheries. W. B. Saunders Company, Philadelphia. 6. King, M., 1995. Fisheries Biology, Assessment and management, Fishing News

Books. 7. Nikolshi, G. V., 1969. Theory of fish population dynamics as the biological

background for rational exploitation and management of fishery resources. Otto Koeltz Science Publishers, Berlin.

8. Naskar K. and R. Mandal, 1999. Ecology and Biodiversity of Indian mangroves. Daya Publishers, 361.

9. Agarwal et al., 1996. Biodiversity and Environment, APH pp. 351. 10. Heywood, V. H,m 1995. Global Biodiversity Assessment, UNEP, pp. 1140. 11. Miller, R. I., 1994. Mapping the Diversity of Nature, Chapman & Hall, 218. 12. Zar,J.H. 1974, Biostatistical analysis, Prentice Hall, New Jercy, 620 p.

PAPER – CME9 – FISHERIES AND QUANTITATIVE BIOLOGY Unit 1 Fishes – General morphology and outline classification – Marine fisheries of India. Anatomy – digestive, circulatory, respiratory, nervous and reproductive system of marine teleost fish. Unit 2 Maturation and spawning habits of marine fishes – process of maturation – methods to determine spawning – Biotic and abiotic factors affecting spawning in fishes. Population dynamics – fishing method, Unit stock, Recruitment, Mortality. Migration – Fish tagging and marking. Unit 3 Survey of fishery resources – Methods-acoustic method, aerial method. Survey of fish eggs and larvae, analyzing population features. Sampling techniques – Biometry of fish. Age and growth – Otolith. Fish diseases. Principal methods of exploitation of sea fishes – Indigenous and modern gears and crafts.

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Unit 4 Biostatistics-Collection and representation of data. Probability distributions and their properties – hypothesis testing – analysis of frequencies. Experimental design and sampling theory – analysis of variance – correlation – regression – non-parametric tests – probability theory. Test of significance – The chi-square rest. Computer application for fish stock assessment - Estimation of age & growth, mortality and biomass - ELEFAN, FISAT, BIOMASS, CEDA, YIELD Unit 5 Biodiversity indices – univariate method – Shannon-Weiner index, Simpson index, similarity and dissimilarity index – Graphical/distributional techniques. Multivariate method-cluster analysis, non-metric multi dimensional scaling. Mathematical modeling – types – building a model-planning, implementation, evaluation, sensitivity analysis. Computer applications in biostatistics. References: 1. Fikret Berkes, Robin Mahon, Patrick McConney, Richard Pollnac, Robert Pomeroy,

2001. Managing Small-scale Fisheries: Alternative Directions and Methods. IDRC, 250 pages.

2. T. R. McClanahan, , Charles R. C. Sheppard, David O. Obura, Coral Reefs of the Indian Ocean: Their Ecology and Conservation, Published 2000, Oxford University Press, 525 pages

3. Cushing D.H., 1975. Marine ecology and fisheries, Cambridge University press 4. Jhingran V.G., 1991. Fish and fisheries of India, Hindustan Publ. Corpn. 5. Robert S. Pomeroy, Rebecca Rivera-Guieb, Fishery Co-management: A Practical

Handbook, Published 2006, IDRC, 264 pages 6. Rögnvaldur Hannesson , Manuel Barange , Samuel F. Herrick, Global Ocean

Ecosystems Dynamics (Program), Climate change and the economics of the world's fisheries: examples of small pelagic stocks. Published 2006, Edward Elgar Publishinh, 310 pages

7. Tim McClanahan, Juan Carlos Castilla, Fisheries Management: Progress towards sustainability, Published 2007, Blackwell Publishing, 352 pages

8. Gupta S.C., Fundamentals or Statistics, Himalaya publishing House Delhi.

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PAPER – CME10 – MARINE POLLUTION Unit 1 Marine pollution – definition. Major pollutants – sources, transport path, dynamics. Toxicology – lethal and sublethal effects of pollutants to marine organisms, bioconcentration, bioaccumulation and biomagnification – methods of toxicity testing – factors influencing toxicity – synergistic and antagonistic effects – role of microcosms and mesocosms. Unit 2 Sewage – industrial, agricultural and domestic discharge – compositions of sewage – disposal system (river drainage, piped disposal and sludge dumping) – impact of sewage disposal on marine environment – treatment methods (primary, secondary and tertiary). Detergents – composition – eutrophication and ecological significance – interference in the sewage treatment systems. Unit 3 Heavy metal pollution – essential and nonessential – sources, distribution, fate- analytical approaches, toxicity and diseases. Pesticide pollution – classification and composition – organochlorines, organophosphates, carbamates etc. – sources – transport, distribution and fate in the marine environment. Analytical approaches, biological concern and ecological impacts with special reference to fishes, marine birds and marine mammals. Unit 4 Oil pollution – composition, sources – role of weathering forces on the fate of spilled oil – biological impacts of oil on fishes, birds, mammals and marine plants – treatment techniques (chemical, biological and mechanical). Thermal pollution sources – waste heat disposal – uses of waste heat – role of biocides (chlorine) – ecological impacts. Unit 5 Radioactive pollution – sources (natural and artificial) – distribution, biological effects of radiation. Plastics and litter impact of mining and dredging operations in the marine environment. Environmental monitoring methods for critical pollutants – objective, status, limitations – biological indicators – natural bioaccumulations (mussel watch) – water quality assessment.

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References: 1. Sharma PD (recent ed.). Environmental Biology and Toxicology, Rastogi Publication,

Meerut. 2. Gormack, D. 1983. Responses to Oil and Chemical Marine Pollution, Science

Publishers. 3. Johnston R. (Ed.), 1976. Marine Pollution, Academic Press, 4. Olson, TA, F.J. Burgess (recent ed.) Pollution and Marine Ecology, Interscience

Pub., New York. 5. Park, PK., Kester, DR, JW. Deudall and BH. Ketchum, 1983 Wastes in the Ocean

Vol- I, II, and III, Wiley Interscience Publishers. 6. Johnston,R. (recent ed.) Marine Pollution, Holt Rinchart and Winston, New York. 7. Yven Breton, David Brown, Brain Davy, Milton Hougton, and Luis Overes (eds):

Coastal Resource Management in the Wider Caribbean Resilience, Adaptation and Community Diversity, Published 2006, Ian Randle Publishers, 265 pages

8. Carl J. Sindermann: Coastal pollution: effects on living resources and humans, Published 2006, CRC Press, 280 pages

9. Don Hinrichsenand Stephen Olsen: Coastal Waters of the World: Trends, Threats, and Strategies, Published 1997, Island Press, 275 pages

PAPER - CMEP2 - Practical II

1. Interstitial fauna and meiofauna – methods of collection and sorting. 2. Pelagic and benthic fauna of marine environment – Collection and identification. 3. Field trips to study: Animal communities in different biotopes – Mud flat – Sandy

and rocky shore – Mangrove – Oyster bed. Burrowing fauna (c) Epifauna (d) Boring animals (e) Fouling animals (f) Symbionts (g) Parasites (h) Epizoites (i) Commensals (j) tubiculous organisms (k) Phytal fauna.

4. Identification of locally available marine macro algae, sea grasses and mangrove. 5. Collection, Identification of phytoplankton and zooplankton (Diatom,

Dinoflagellates, Hydromedusae, Copepods) 6. Bacteria culture Media – constituents, defined media – preparation and

sterilization. 7. Sterilization – Principles and methods. 8. Enumeration of microorganisms – Bacteria, Actinomycetes and Fungi. 9. Staining – simple, gram, spore and capsule staining – staining fungi. 10. Growth of microorganisms – colony count, MPN – calculation of generation time. 11. Characterization and differentiation of bacteria - Hydrolysis of starch, Casein,

Gelatin and fat. Catalase and oxidase test. Antibiotic assay

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SEMESTER III

PAPER - CME11 - SCUBA DIVING Unit 1 Skin-diving - scientific diving-regulations and history. Underwater Diving – Principle;

physics of diving; physiology of diving-indirect effects of pressure; underwater

environment, decompression theory and its application; Snorkeling-basics; Recreational

diving; Usefulness - marine research, maritime operations. PADI. Government

Unit 2 SCUBA equipment – standards - mask, fins, Buoyancy control device, cylinder,

regulator, submersible pressure gauge, exposure suit, compass, dive watch, dive

computer, dive light, dive knife, floatation devices, compressor systems - concept,

design, handling and safety issues. Diving types-tropical, temperate, cold water and

tech diving. Snorkeling kit.

Safety first-concept; Code of conduct - pre-dive procedure, dive planning, pre-dive

safety check-diver’s responsibility, equipment evaluation, post-dive safety checks.

Unit 3 Dive emergencies-procedure, rescue techniques. Buddy system. Safety stop in deep

dives. Equipment maintenance – mask cleaning, regulator clearing/recovery. Air quality

standards. Medical requirements – diver evaluation and monitoring, conditions for

disqualification. Record maintenance.

Unit 4 Underwater data gathering techniques - Quadrats and Transects; Mapping; Tagging;

behavior and ecology; site selection, location and relocation; specialized equipment for

data gathering – Archaeology.

Unit 5 Underwater resource assessment techniques – Coral reef and seagrass – assessment,

monitoring. Visual senses. Marine Protected Areas. Photography- digital underwater

photo system-still and video-uses in monitoring and documentation. Commercial diving.

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Reference 1. Michael Ange, 2005. Diver Down: Real-World SCUBA Accidents and How to Avoid

edition. International Marine/Ragged Mountain Press; pp.192.

2. Dan Orr and Eric Douglas, 2007. Scuba Diving Safety. Human Kinetics. Pp.196.

3. Jack Drafahl and Sue Drafahl, 2005. Master Guide for Underwater Digital

Photography. Amherst Media, Inc. pp. 128.

4. B. R. Wienke, 2001. Technical diving in depth. Best Publishing Company. Pp. 460.

5. Dennis Graver, 2009. Scuba Diving. Human Kinetics. Pp.233.

6. Martin Edge, 2006. The Underwater Photographer: Digital and Traditional

Techniques. Focal Press. Pp.408.

7. Dive Manual - http://www.sfos.uaf.edu/dive/manual/contents.html

8. Wilkinson, C., A. Green, J. Almany and S. Dionne, 2003 Monitoring coral reef marine

protected areas: version 1. A practical guide on how monitoring can supporteffective

management of MPAs. Australian Institute of Marine Science, Townsville,Australia

and IUCN Global Marine Program, Gland 1196, Switzerland.

9. John N. Heine, 1999. Scientific Diving Techniques, A Practical Guide for the

Research Diver. Best Publishing Company. Pp. 225

10. Mumby, P. and E. Green, 2000. Mapping of coral reefs and macro algae,p. 155-174.

In: A.J. Edwards (ed.) Coastal Management Source Book 3, UNESCO,

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PAPER - CME12 - GIS AND REMOTE SENSING

Unit 1 Overview and Definition. Fundamentals of Maps and Map Interpretation, Remote Sensing application to Ground Water Environment, mining of mineral resources, Landslides, Land subsidence and earthquake, Waste land mapping, Ecology, environmental Impact Assessment. Unit 2 Acquisitions of multi spectral images from space-borne platforms – visual range. IR bands. Types of sensors. Data from ERS and other satellites. Data resolution, band width requirement for various themes. Data formats. Unit 3 Processing of data: rectification and classification, edge extraction, spatial and wave number domain filtering, estimation of band ratio, principal component analysis. Normalized Difference Vegetation Index, histogram equalization, density slicing , linear feature extraction. Unit 4 Thematic application: application of remote sensing in the field of ground water exploration, identification of surface feature, drainage pattern and catchment delineation, identification of structural patterns and thermal spots from IR bands. Unit 5 Delineation of coastal features, study of ocean waves from ERS data. A brief outline of Digital Image processing, EOS and NASA's Mission to Planet Earth, The Basic and application of Geological Information System (GIS), Global Positioning Systems, Integration of Information Technology for Resource Assessment. References: 1. Alexey Bunkin and Konstantin Voliak 2001 Laser Remote Sensing of the Ocean:

Mthods and Applications, Wiley & Sons, NY. 2. Peter M. Atkinson and Nicholas J. Tate, 1996 Advances in Remote Sensing and GIS

Analysis, ISBN Powell’s Edn. 3. Robert A. Schowengerdt, 1998, Remote Sensing BookHq. 4. Robert A. Schowengerdt, Basic Principles of Remote Sensing, (recent ed.) Wiley &

Sons, NY. 5. Thomas M. Lillies and Ralph W. Kiefer, (recent ed.) Remote Sensing and Image

Interpretation, Book News Inc. 6. Gert A. Schultz, Ewin T.Engman, E.T. Engman, 2000, Remote Sensing in Hydrology

and Water Management, Spinger-Verlag, berlin, Germany. 7. C.A. Brebbia and P. Pascolo, 2002, Management Information Systems 2002: GIS

and Remote Sensing Volume IV, Wit Press

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PAPER - CME13 - MARINE ENVIRONNENT CONSERVATION STRATEGIES

Unit 1 Threats to ecosystem and resources – anthropogenic and natural – pollution – industrial & domestic, destructive & over fishing practices, coral mining, mangrove deforestation, denudation of seagrass beds and trawling. Marine mammals and sea turtle – threats and effects. Unit 2 Marine bio-resources – Methods of exploitation. Endangered and vulnerable species. Climate change - loss of habitat and fishery, sea level rise and resources, migration of fishes, adaptation and management; Diseases – causes, monitoring and management Unit 3 Beach sand mineral deposits with special reference to India– Marine metalliferous muds and placer deposits – classification of placer deposits - Important placer minerals in India – composition and resource status - Garnet, Zircon, Monzite, Limenite and Magnetite. Effect of mining on environment and biological resources – mining impact on ecologically sensitive ecosystems. Eco-friendly mining practices. Processing and potential environmental impact – management mechanism and strategies in mineral mining for sustainability. Remote sensing in mineral utilization and management. Unit 4 Conservation and management of marine resources – concepts, mechanisms and action plan; coastal ecosystem restoration - Artificial reefs, coral restoration, seagrass restoration and mangrove restoration; Bio-resources culture & sea ranching. Unit 5 Government initiatives in marine environment conservation and management – laws, regulation, outreach and enforcement; Role of NGOs, research institutions; Local community participation.

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References: 1. Victor Rajamanickam, G. 2001. Handbook of Placer Mineral Deposits, New

Academic Publishers, 327 pages 2. India's mineral resources - Krishnaswamy, S. 3. Metallic and Industrial minerals - Lamey Carl, A. 4. A treatise on industrial minerals of India-Sinha, R.L. 5. Introduction to India's economic minerals - Sharma, N.L. & Ram . K.S. 6. Bell, F. G. ; Donnelly, Laurance J., 2006, Mining and Its Impact on the Environment,

Taylor & Francis Group, 547 p. 7. Duxbury, A.C., A.B. Duxbury and K.A. Sverdrup. 2000. An introduction to the

World’s Oceans. 6th Edition. McGraw Hill Companies Inc. 8. Stowe, K., 1996. Exploring Ocean Science, John Wiley & Sons Inc. 9. Iversen, E.S., 1996. Living Marine Resources. Chapman & Hall, New York. 10. Firth, F.E., 1971. The Encyclopaedia of Marine Resources, Von Nostrand Reinholt,

New York. 11. Sverdrup, H.U., M.W. Johnson and R.H. Fleming, 1959. The Oceans - their Physics,

Chemistry and General Biology. Prentice- H" Inc., New Jersey.

PAPER - CME14 - MARINE POLICY AND SOCIO-ECONOMICS Unit 1 Scientific expeditions for ascertaining the wealth of the sea. The three major oceans – their relative importance – Historical evolution of ideas: Oceans as a common heritage of mankind. Evolving law of the sea – The Geneva Conventions – UNCLOS Series. United Nation’s Convention on the Law of the Sea 1982 (UNCLOS), the Atlantic treaty and its salient features, including CCAMLR, CEP, SOAR; the Seabed treaty, scientific; earth summit UNCED; Geneva Conventions. Role of Intergovernmental Oceanographic Commission (IOC) and Man and the Biosphere Programme of the United Nations Educational, Scientific, and Cultural Organization (UNESCO) – Concepts of ecosystem-based management and marine spatial planning. Unit 2 The ‘Regional Seas’ programmes of the UN – their global significance. The Antarctic Treaty and its importance. CITES convention. Navigation and communication. Exclusive Economic Zone. Marine International Relations. Scientific, economic and geo-political aspects of seabed exploration and mining – The seabed treaty. Mining act, law, regulations in India. National and International Biodiversity Conventions - Endangered marine animals, CITES Convention, Marine biosphere reserves, National marine parks, Marine Protected areas and Sanctuaries. Unit 3 Coastal population - Socio-demographic and economic conditions, traditions and culture, caste and religion, women and children, leadership, issues and problems: Basic facilities – communication, drinking water, sanitation and housing. Education and health issues - education (formal and informal). Environmental issues - exploitation and developmental activities - socio-religious and cultural factors influencing environment degradation.

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Unit 4 Fisheries investment projects, finance and project planning. Fisheries extension service for development Importance of training in fisheries development - training methods - trainers-training - follow-up programmes - entrepreneurship development – Role of GOMBRT. Unit 5 Economics of fish marketing, role of middle man, market trend, domestic and export - economic utilization of fishery resources - role of women. Empowerment of fisher women - development of new social paradigm that focuses on sustainability and justice. Impact of resources depletion – alternative and additional livelihood – food security - maintenance of bio-potential areas - Socio-economic monitoring and assessment. References: 1. Christie, Donna R., and Richard G. Hildreth. 1999. Coastal and Ocean Management

Law in a Nutshell. 2nd ed. , West Publishing Company 2. Maraist, Frank L. 1996. Admiralty in a Nutshell. 3rd ed., West Publishing Company 3. Sohn, Louis, and Kristen Gustafson. 1984. The Law of the Sea in a Nutshell, West

Publishing Company 4. Burke, William T. 1995. International Law of the Sea: Documents and Notes, West

Publishing Company 5. Kalo, Joseph, et al. 1999. Coastal and Ocean Law: Cases and Materials. 3rd ed. ,

West Publishing Company 6. Schoenbaum, Thomas J. 1994. Admiralty and Maritime Law. 2nd ed., West

Publishing Company 7. Third United Nations Conference on the Law of the Sea: Documents 1973-1982 (18

vols.); and The Law of the Sea: Documents 1983-1992 (15 vols.). 8. Moore, John Norton, ed. International and United States Documents on Oceans Law

and Policy. Buffalo, NY: William S. Hein & Co., 1986. 5 vols. 9. The Law of the Sea: A Bibliography on the Law of the Sea, 1968-1988

Compiled by the UN Office (now Division) for Ocean Affairs and the Law of the Sea. Books and articles are listed for all the major law of the sea topics.

10. Butler, LMD., Elliott et al, 2001 Strategies to overcome oppression and discrimination for marginalized groups, Lewiston, NY. Edwin Mellen Press.

11. Hoon, V., G. Sriskanthan, P. Townsley, B. Cattermoul, L. Bunce And B. Pomeroy, 2008. Socioeconomic Monitoring Guidelines for Coastal Managers in South Asia: SocMon South Asia. IUCN/CORDIO.

12. Loper, C., R. Pomeroy, V. Hoon, P. McConney, M. Pena, A. Sanders, G. Sriskanthan, S. Vergara, M. Pido, R. Vave, C. Vieux and I. Wanyonyi, 2008. Socioeconomic conditions along the world’s tropical coasts: 2008. SocMon Global Report, 56 pp.

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PAPER - CME15 - INTEGRATED COASTAL ZONE MANAGEMENT

Unit 1 Coastal Zone - definition, importance, coastal resources, developmental activities and their impacts on the coastal ecosystems. Ports and Harbours – Dredging – navigational routes – shore-front construction and their impacts, global and national coastal problems such as loss of habitats, sea level change, degradation of water quality and fisheries resource depletion. Shore-line changes. Unit 2 Coastal management issues - boundaries of coastal zone - major ecological, social and economic trends and their importance; environmental economics of integrated coastal zone management (ICZM); comparison between developed and developing countries, temperate and tropical countries and their ICZM. Unit 3 Marine Biosphere Reserves – Marine Parks– Sanctuaries – Concept, implementation and management. Management action plan – ecosystem and species. MAB – UNESCO’s role in the establishment and functioning of Marine biospheres - Great Barrier Reef Marine Park Authority – concept and functional mechanism. Marine Biospheres, National Marine Parks and Sanctuaries in India – role and function. Unit 4 Role of National and International agencies and organizations in ocean management – FAO, UNEP, MPEDA, WOCE, DOD, OOETb of UN, WHOI, IOI (Malta), International Maritime Institute (Sweden), Law of the Sea Institute (Rhode Island), International Maritime Satellite Organization (INMARSAT), IUCN (Switzerland), SCAR, SCOR, Marine Pollution Commission on Sustainable Development. Unit 5 Integrated Ocean Management - Change of resource utilization pattern – Capacity building – trans boundary issues – Climate change issues - International treaties – community based ocean management – livelihood associated conservation and management mechanism. Coastal Zone Regulation in India, Coastal Management Plan in India, marine biodiversity act.

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References: 1. Biliana Cicin-Sain, Robert W. Knecht, , Dosoo Jang, Gregory, W. Fisk, 1998.

University of Delaware Center for the Study of Marine Policy, Intergovermental, Oceanographic Commission, Unesco, University of Delaware College of Marine Studies Integrated Coastal and Ocean Management: Concepts and Practices, Island Press, 543 pages.

2. Yvan Breton, 2006. Integrated Coastal Zone Management of Coral Reefs: Decision Support , IDRC, 300 pages.

3. Robert Kay, Jacqueline Alder, 2005. Coastal Planning and Management, Taylor & Francis, 380 pages.

4. Bhaskar Nath, 2003. Environmental Management in Practice: Managing the Ecosystem, Published 1999, Routledge, 297 pages Peter Jacques, Zachary A. Smith, Ocean politics and policy: a reference handbook, ABC-CLIO, 267 pages.

5. Lawrence Juda, 1996. International Law and Ocean Use Management, Routledge, 345 pages.

PAPER - CME16 - ENVIRONMENTAL IMPACT ASSESSMENT AND DISASTER MANAGEMENT

Unit 1 Environmental Impact Assessment (EIA) - Overview and history – Origin - development and legislative background - principles – types and purpose – importance – necessity – global, national and local priorities and usefulness – environmental law. EIA process and stages - screening and scoping criteria - impact identification and evaluation techniques: checklist, matrix, networks, systems modeling techniques for identifying impacts. Unit 2 Environmental impact prediction - prediction methods, criteria for selecting methods - prediction techniques - use of primary and secondary data. Planning process and decision making: decision paths, the scope for public involvement, relationship with economic and social impact assessment. Mitigation and compensation measures - monitoring and evaluation: environmental and socio-economics. Other related issues: Strategic Environmental Assessment. Contribution of Environmental Impact Assessment and Strategic Environmental Assessment (SEA) to sustainable development. Unit 3 Hazard - introduction and overview – natural disasters – Effects and developmental problems. Types – Earthquake, cyclones, floods, land slides, drought, coastal erosion, tsunami – Histories of earlier hazards. Coastal hazards- magnitudes and frequencies – global scenario of coastal hazards and impacts. Disaster management system – Concepts & Procedures - institutional mechanism – policy – preparedness and response – Capacity building and resource development – financial mechanism.

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Unit 4 Disaster management initiatives - State, national and international levels – Early Warning Systems - Policies and Laws – socio-political issues. Community based disaster management - socio-economic vulnerability – community response capabilities, preparedness and mitigation, risk management - issues that impact communities such as shelter, livelihood, food security, etc. - community empowerment through access to resources, participation, equity, education and awareness. Unit 5 Disaster mitigation mechanism in the coastal areas – mapping the Zones of Risk – identifying the Elements at Risk (societal, infrastructural, and analyses and damage assessment) – mitigation of physical vulnerabilities – hard and soft measures, infrastructure development – awareness creation,– capacity building of stakeholders - addressing livelihood issues, environmental degradation – climate change and loss of fishery – sustainability issues. References: 1. Carroll B & Turpin T, 2002, Environmental Impact Assessment Handbook; A

practical guide for planners, developers and communities, Thomas Telford Publishing, ISBN 0727727818.

2. Glasson J, Therivel R & Chadwick A, 1999. Introduction to Environmental Impact Assessment: principals & procedures, process, practice & prospects, ISBN 1857289455, UCL Press Ltd, University College London, Gower Street, London, WC1E 6BT

3. Hyde, P & Reeve, P 2002, Essentials of Environmental Management, ISBN 0901357286, The Institution of Occupational Safety & Health.

4. Petts J, 1999, Handbook of Environmental Impact Assessment, Vol. 1 & 2, ISBN 0632047720 & 0632047712, Blackwell Science Ltd, Osney Mead, Oxford, 0X2 0EL,

5. Therivel R & Partidario MR, 1996, The Practice of Strategic Environmental Assessment, ISBN 1853833738.

6. Environmental Impact Assessment, Canter, L.W., 1977, McGraw Hills New York. 7. Handbook of variables of environmental impact assessment Ann Arbor Science

1979. 8. Kees Bastmeijer and Timo Koivurova, 2007. Theory and Practice of Transboundary

Environmental Impact Assessment. Publisher: Martinus Nijhoff Publishers / Brill Academic. 400 pp.

9. Damon P. Coppola, 2006. Introduction to International Disaster Management, Butterworth-Heinemann, 547 pages.

10. Mark Pelling, 2003. The Vulnerability of Cities: Natural Disasters and Social Resilience, Earthscan, 256 pages.

11. Alcira Kreimer, Margaret Arnold, Managing Disaster Risk in Emerging Economies, Published 2000, World Bank Publications, 193 pages

12. Greg Bankoff, Georg Frerks, Dorothea, Hilhorst, 2004. Mapping Vulnerability: Disasters, Development, and People, Earthscan, 236 pages.

13. U.S. National Committee for the Decade for Natural Disaster Reduction, Committee on Geosciences, Richard E . Hallgren A Safer Future: Reducing the Impacts of Natural Disasters, Published 1991, National Academies Press, 67 pages.

261

PAPER - CMEP3 - Practical III

1. Study of the external morphology of fishes 2. Dissection of 9th and 10th cranial nerves of shark, ray and teleost fishes. 3. Study of food and feeding habits of fishes. 4. Fecundity estimation and ova-diameter studies 5. Life history stages of fishes 6. Mini project on Environmental Impact assessment 7. Mini project on assessment of disaster vulnerability and preparedness of a

coastal village 8. Practical exposure to GIS and Remote sensing techniques 9. Demonstration-Analysis and estimation of critical pollutants in seawater,

sediments and organisms - Estimation of BOD and COD, Pesticide residues, Petroleum hydrocarbons, Heavy metals (Cu, Cd, Pb, Hg), LC50 values – sublethal effects of critical pollutants to fish and shellfishes.

SEMESTER IV

PAPER – CMEPR – PROJECT WORK Group project work not more than two students in each group in the related

subjects.

262

Exam Scheme

For Theory Paper : External Marks : 75

Internal Marks : 25

Theory Paper- External Exam

Part A : 10 x 1 = 10 (No Choice) Multiple Internal Choice - 10 Questions

Part B : 5 x 5 = 25 (either OR) - 5 Questions

Part C ; 5 x 8 = 40 (either OR) - 5 Questions

Total = 75 Marks

Internal Assessment for Theory Paper

Average of' the best two from three compulsory test - 15 Marks

Assignment = 4 Marks

Seminar = 6 Marks

Total - 25 Marks

263

M.Sc. (CBCS) DEGREE EXAMINATION

I SEMESTER

CONSERVATION OF MARINE ENVIRONMENT- MAIN

CME4 - Physical Oceanography

Time: Three hours Maximum: 75 Marks

Part-A (10 x I = 10 Marks)

Answer ALL questions

1. The first oceanographic expedition Challenger Expedition hapr>ened during

a) 1820-24

b)1872-76

c) 1873-77

d)1870-74

2. The title with two high and two low tides a day is called

a) Diurnal tide

b) Mixed tide

c) Semi-diurnal tide

d) Ebb tide

3. The area between high water line and low water line is called

a) Intertidal

b) Subtidal

c) Littoral

d) Iinterstitial

4. The inshore ocean zone is called

a) Oceanic

B Hadal

c) Neritic

d) Abyssal

264

5. The water layer in which temperature changes rapidly with increasing depth is

known as

a) Thermocline

b) Stenohaline

c) Euryhaline

d) Rathyal zone

6. The sediment formed due to weathering process is known as

a) Lilhogcnous

b) Cosmogenous

c) Biogenous

d) Hydrogenous

7. The zone of light penetration in the sea is called

a) Pelagic

b) Euphotic

c) Aphoiic

d) Epipelagic

8. Fkman transport theory explains the wind driven movement of

a) Bottom Ocean water

b) Deep ocean water

c) Surface Ocean water

d) Lagoon water

9. The area where waves are breaking as the water gets shallower closer to shore.

a) Intertidal

b) Hadal

c) Surge

d) Surf zone

265

10. Sail wedge estuary is the classification based on

a) Habitat

b) Geological feature

c) Biological component

d) Water circulation

Part-B(5X5 = 25Marks) Answer ALL questions choosing either a or b

11. a) Write an account on the origin of ocean basin

(OR)

b) Write a short note on submarine canyons

12. a) Write in brief about light in the sea and its significance

(OR)

b) Give an account on temperature distribution in the sea

13. a) Explain the forces causing surface and deep currents

(OR)

b) Write a note on EI Nino

14. a) Give an account on estuarine circulation

(OR) b) Write an account on internal and standing waves

15. a) Explain the origin and physical properties of marine sediments

(OR)

b) Give an account on tidal current

Part - C (5 X 8=40 Marks) Answer ALL questions choosing, either a or b

16. a) Explain the classification of marine environment

(OR)

b) Write an account on bottom topography of the ocean

266

17. a) Give a detailed account on the history of oceanography

(OR)

b) Describe the physical properties of sea water and their interrelationship

18. a) Explain wave formation and their properties

(OR)

b) Write in detail the circulation pattern in the ocean

19. a) What are currents? Explain the types of currents and the significance of

upwelling

(OR)

b) Write an account on the origin, classification and zonation of estuaries

20. a) Explain types of tides and give an account on its effect on coastal areas

(OR)

b) Classify marine sediments and write an account on their distribution and transport

267

M.Sc. (CBCS) DEGREE EXAMINATION

I SEMESTER

CONSERVATION OF MARINE ENVIRONMENT-MAIN

CME5 - Chemical Oceanography

Time: Three hours Maximum: 75 Marks

Part-A (10 x 1 = 10 Marks) Answer ALL questions

1. The process by which (he water moves from the sea to the atmosphere

a) Precipitation

b) Transportation

c) Evaporation

d) Conduction

2. The most abundant element in seawater

a) Sodium

b) Chloride

c) Magnesium

d) Calcium

3.'The carbon dioxide dissolves in seawater to form

a) Carbonic acid

b) Calcium carbonate

c) Oxygen

d) Carbon monoxide

4. The organism that can converts ammonia into nitrite in the nitrogen cycle

a) Phytoplanktom

b) Zooplankton

c) Nitrosomonas

d) Virus

268

5. Hypoxia refers to

a) Low level of oxygen

b) High level of oxygen

c) Low level of Carbon dioxide

d) Low level of ammonia

6. The process by which elements are cycled between biotic and abiotic compartments

of earth is called

a) Photosynthesis

b) Biogeochemical cycle

c) Nitrogen cycle

d) Carbon cycle

7) The following does not have a gaseous state as part of its cycle

a) Nitrogen

b) Oxygen

c) Carbon

d) Phosphorus

8) The process of movement of water molecules from seawaier side to freshwater side

by pressure is called

a) Osmosis

b) Reverse osmosis

c) Ion exchange

d) Electro dialysis

9) Humic substances are renowned for their ability to

a) Chelate soil nutrients

b) Decrease soil fertility

c) Pollute seawater

d) Affect nutrient uptake

269

10) The process of electrochemical degradation of metals due to reaction with their

environment is known as

a) Desalination

b) Decomposition

c) Disintegration

d) Corrosion

Part -B (5X5 = 25 Marks) Answer ALL questions choosing cither a or b

11. a) Give an account on the concept of chlorinity

(OR)

b) Explain the differences between freshwater and seawater

12. a) Write an account on the major and minor constituents of seawater

(OR)

b) Constancy of composition of seawater - Explain

13. a) Explain the origin of dissolved oxygen in the sea and give an account on it*.

importance

(OR)

b) Give an account on the origin and importance of noble gases

14. a) Write a short note on interaction between humic substances and heavy metals

(OR)

b) Describe the ecological significance of dissolved organic matter

15. a) Write an account on nitrogen cycle in the marine environment

(OR)

b) Explain the role of inorganic nutrients in the fertility of the sea

Part-C (5X8=40 Marks) Answer ALL questions choosing cither a or b

16. a) Explain hydrological cycle and its significance

(OR)

b) What are humic substances'.' Explain their role in the fertility and

Bio geochemistry of the sea.

270

17. a) Write an account on trace elements and their importance in the marine

environment

(OR)

b) Explain carbonate system in the marine environment

18. a) Write in detail the origin, distribution and importance of CO2 in marine

environment

(OR)

b) Give an account on the minerals of the sea

19. a) Give an account on the origin, distribution and ecological significance of

particulate organic matter

(OR)

b) Explain the origin and distribution radio nuclides

20. a) Write an account on phosphorus cycle in the sea

(OR)

b) Define desalination and explain the methods

271  

APPENDIX- BA20

MANONMANIAM SUNDARANAR UNIVESITY, TIRUNELVELI-12 M.Sc CHEMISTRY - SPECIALISATION IN GREEN CHEMISTRY

CBCS-For Colleges

Effective from the Academic year 2013-2014

SYLLABUS AND SCHEME OF EXAMINATION

Scheme of Examination and Question pattern for M.Sc Chemistry (Specilisation in Green Chemistry) Course is the same followed currently for M.Sc. Chemistry

course offered in affiliated colleges. The pattern is follows:

Course No. & Title Hours per week

Credits Marks for CA

Marks for ESA

Total Marks

L P SEMESTER I

Organic Chemistry-I 5 5 25 75 100 Inorganic Chemistry-I 5 5 25 75 100 Physical Chemistry-I 5 5 25 75 100 Elective -Research Methodology

3 3 25 75 100

Organic Chemistry Practical-I

4 (To be continued in Semester II)

Inorganic Chemistry Practical-I

4 (To be continued in Semester II)

Physical Chemistry Practical-I

4 (To be continued in Semester II)

Total Marks for Semester I 400

SEMESTER II Organic Chemistry-II 6 5 25 75 100 Inorganic Chemistry-II 6 5 25 75 100 Physical Chemistry-II 6 5 25 75 100 Organic Chemistry Practical-I

4 4 40 60 100

Inorganic Chemistry Practical-I

4 4 40 60 100

Physical Chemistry Practical-I

4 4 40 60 100

Total Marks for Semester II 600

272  

SEMESTER III Organic Chemistry-III 5 5 25 75 100 Inorganic Chemistry-III 5 5 25 75 100 Physical Chemistry-III 5 5 25 75 100 Project (Group) 3 3 25 75 100 Organic Chemistry Practical-II

4 (To be continued in Semester IV)

Inorganic Chemistry Practical-II

4 (To be continued in Semester IV)

Physical Chemistry Practical-II

4 (To be continued in Semester IV)

Total Marks for SemesterIII 400

SEMESTER IV Inorganic Chemistry-IV 6 5 25 75 100 Green Chemistry-I 6 5 25 75 100 Green Chemistry-II 6 5 25 75 100 Organic Chemistry Practical-II

4 4 40 60 100

Inorganic Chemistry Practical-II

4 4 40 60 100

Physical Chemistry Practical-II

4 4 40 60 100

Total Marks for SemesterIV 600

Total Number of Courses : 20

Total Number of Hours : 120

Total Number of Credits : 90

273  

Question Pattern

Time : 3 Hours Max. Marks : 75

Part A : 10 Questions fully objective type

Two questions from each unit of a paper, Each question carries one mark

10 X 1 = 10 marks

Part B : 5 Descriptive questions of either a or b type (internal Choice) One question is

from one unit. Each question carries 5 mark. 5 X 5 = 25 Marks

Part C : 5 Descriptive type questions of either a or b type (internal type) One question

is from one unit. Each question carries 8 mark. 5 X 8 = 40 Marks

PROJECT

Project for this course shall be a group project. Each group consists of 3 – 4 students.

Students shall submit the project report (Dissertation) on or before the last working day

of III semester. Project evaluation will be done by guide and one External Examiner

appointed by the university.

Project evaluation : 75 Marks

Viva voce : 25 Marks

Total : 100 Marks

Eligibility criteria :

The eligibility norms for this course is the qualification in B.Sc. Chemistry course

or any degree considered equivalent to this.

274  

SYLLABUS

FIRST SEMESTER

ORGANIC CHEMISTRY - I UNIT – I: AROMATICITY AND NOVEL RING SYSTEM Aromaticity: Benzenoid and non – benzenoid compounds – generations and reactions –

sextet theory – MO theory – Huckel’s rule – Annulenes and hetero annulenes – Anti and

homo aromaticity – Fullerenes. Nomenclature of bicyclic and tricyclic systems –

structure and synthesis of Adamantane – Congressane – Alternant and non – alternant

– Azulene – and sydnones.

UNIT – II: STUDY OF ORGANIC REACTION MECHANISM Reaction mechanism – Energy diagram of simple Organic reactions – Transition state

and Intermediate.Kinetic and Thermodynamic requirements of reactions – Hammond

Postulate and microscopic reversibility. Kinetic and Thermodynamic control of product

formation. Kinetic and Non – kinetic methods of determination – Primary and secondary

isotope effect–Testing and Trapping of intermediates, Isotopic labeling, Cross–over

experiments and stereo chemical evidence. LFER : Hammett equation – Physical

significance of σ and ρ – Applications and Limitations – Taft equation.

UNIT – III: STEREOCHEMISTRY Concept of chirality: chirality – Enantiotopic, diastereotopic hydrogens and prochiral

centres – axial and planar chirality – stereochemistry of compounds containing two

dissimilar asymmetric carbons and ansa compounds. R/S notations of allenes and

Biphenyl derivatives – E/z notation of compounds containing one and two double bonds.

Stereospecific and stereoselective synthesis – Methods of Asymmetric synthesis

including enzymatic and catalytic process – Cram’s rule and Prelog’s rule – Cram

chelation model and Felkin – Aln model.

UNIT – IV: MOLECULAR REARRANGEMENTS Types of rearrangements : Nucleophilic , electrophilic and Free radical reactions –

Nature of migration – migrating aptitude and memory effects, ring enlargement and ring

contraction.

Reaction and mechanism of the following : Carbon to carbon migration – Wagner –

Meerwein, Pinacol – Pinacolone, Benzil – Benzilic acid, Arndt – Eistert synthesis,

275  

Demjanov and dienone-phenol rearrangements. Carbon to oxygen migration – Baeyer

Villiger and Darkin rearrangements.Carbon to Nitrogen migration – Lossen, Neber and

curtius rearrangements.Miscellaneous : Von – Richter rearrangement and Fischer -

Indole synthesis.

UNIT – V: REAGENTS IN ORGANIC SYNTHESIS Gilman’s reagent – LDA – DCC – 1,3 – dithane (umpolung synthesis ) – Tri n–butyl tin

hydride – Aluminium isopropoxide – chloro trimethyl silane. Fetizon’s reagent – Lemieux

– Von Rudloff reagent – Lemieux–Johnson reagent – Woodward and prevost

hydroxylation. Phase transfer catalysts – Merrifield resin – Vaskas catalyst – wilkinson’s

catalyst – Ziegler – Natta catalyst.

REFERENCES 1. P. Sykes, ‘A Guide book to mechanism in organic chemistry’, Orient Longman, 1989.

2. S.M. Mukherji and S.P. singh, ‘ Reaction mechanism in Organic Chemistry ‘,

Macmillan India Ltd, 1978.

3. M. Mukerji, S.P. Singh, and R.P. Kapoor, “Organic chemistry”, Vol .I and II, Wiley

Eastern Ltd., 1985.

4. J.March, ‘ Advanced organic chemistry’, Fourth Edition, John Wiley and Sons,

Newyork, 2006.

5. I.L. Finar, ‘Organic Chemistry’, Vol I and II, ELBS, fifth Editon, 2001.

6. F.A. Carey and R.A Sundberg, ‘ Advanced Organic Chemistry’ (part A and B)

plenumpublishers, 2000.

7. E.S. Gould, ‘ Mechanism and structure in organic chemistry’ Holt, Rinehart

andWinston Inc., 1959

8. S.H. Pine, ‘Organic Chemistry’ , 5th Edition, Mc Craw Hill International Edition, 1987.

9. E.L. Eliel, ‘Stereochemistry of Carbon compounds, Mc Craw Hill 1999.

10. E.L. Eliel and S.H. Wilen, ‘Stereochemistry of organic compounds’, John Wiley

andsons, Inc., 2003.

11. P.S. Kalsi, ‘ Stereo chemistry – Conformation and mechanism – New Age

international(p) Ltd., 2000.

12. P.Ramesh, ‘Basic Principles of organic stereochemistry’, Meenu Publications,

Madurai,First Edition, 2005.

276  

13. D. Nasipuri, ‘Stereochemistry of organic compounds – Principles and

applications’,Wiley Eastern Ltd., 1991.

14. J.M. Harris and C. Wamser – John, ‘ Fundamentals of organic reaction mechanism

–Wiley and sons

15. F.A Carey,’Organic Chemistry, Tata Mc Graw Hill, fifth reprint, 2005.

16. T.H. Lowry and K.S Richardson,’ Mechanism and Theory in Organic

Chemistry’,Houper and Row Publishers – Newyork, 1987

17. V.M. Potapov, ‘Stereochemistry’ – Mir Publishers ,1979

18. R.O.C.Norman, ‘Principles of Organic Synthesis, Chapman Hall, London, 1993.

19. Raj K. Bansal, ‘Reaction mechanism in Organic chemistry, Tata Mc Graw Hill,

ThirdEditon, 10th reprint, 2005.

20. Gurdeep R. Chatwal, ‘Reaction mechanism and Reagents in organic

chemistry’,Himalaya publishing House, Bombay 1992.

21. J.N. Gurtu and R. Kapoor, ‘Organic Reactions and Reagents’, S.Chand and

companyPvt. Ltd.,

22. Gurdeep Chatwal,’Organic Chemistry of Natural Products,’ Vol.I and II,

HimalayaPublishing House, Bombay 1992.

23. O.P. Agarwal, ‘Chemistry of Natural Products,’Vol I and II, Goel publishing

House,Meerut, 1984.

24. V.K. Ahluwalia and R.K. Parshar, ‘Organic Reaction mechanism,’second Edition

,Narosa publishing House,2005.

25. H.O. House, ‘Modern synthetic Reaction,’Second Edition , W.A. Benjamin,

Inc.,London, 1972.

26. R.K. Mackie, M.M. Smith and R.A. Aitken,’Guide Book to Organic Synthesis’

SecondEdition, Longman Seientific and Technical, Singapore, 1990.

27. K. Nakanishi, ‘Natural Product Chemistry,’Blackie Publications, Vols, I, II, III.

28. R.H. Thomson, ‘Chemistry of Natural Products – Wiley, Newyork, 1996.

29. R.T. Morrison and R.N. Boyd,’Organic Chemistry’ sixth Edition, Prentice Hall, 1994.

30. Michael B. Smith, ‘Organic Synthesis,’ Mc Graw Hill international Edition , 1994.

31. Bhupinder Mehta, Manju Mehta, Organic Chemistry, PHI Learning, New Delhi,

2011.

277  

INORGANIC CHEMISTRY – I UNIT – I: CHEMICAL BONDING AND STEREOCHEMISTRY VSEPR theory – Concept of hybridization and structure of molecules- Walsh diagrams –

Bent’s rule – apicophilicity – M.O. theory – symmetry and overlap – M.O. diagrams of

homo and hetero diatomic molecules and BeH2 . Geometrical isomerism in complexes

of coordination numbers 4 to 7 with examples – Fluxionality – Fluxional molecules and

their characterization – Planar – tetrahedral, Trigonal bipyramidal – square Pyramidal

interconversions.

UNIT – II: CHEMICAL BONDING AND NON-AQUEOUS SOLVENTS Bond order – bond energy – bond length – bond polarity – Fajan’s rule – partial ionic

character – electronegativity and different scales of pauling, Mulliken, Aldrich and

Rochow and sanderson scale – conversion to pauling scale – periodicity of

electronegativity, electron affinity and ionic radius – lattice energy – Born Haber cycle

and numerical problems involving it for the calculation of electron affinity or lattice

energy-Covalent character in ionic compounds – different types of electrostatic

interaction, hydrogen bonding. General properties and classification of solvents.Self

ionization and leveling effect.Reactions in non aqueous solvents – solute-solvent

interaction.Liquid NH3 and Liquid SO2.

UNIT – III: SOLID STATE CHEMISTRY – I Electronic structure of solids - Free electron and band theory - Types of solids —

conductors and insulators- intrinsic and extrinsic semiconductors - Band structure and

applications. Crystal defects in solids — line and plane defects - Point defects —

Schottky and Frenkel defects — Non-stoichiometric defects - Preparation and properties

of nonstoichiometric compounds - Colour centres - Solid electrolytes and their

applications. Optical and electrical properties of semiconductors - Photovoltaic effect -

Hall effect - p-n and n-p-n junctions and their applications as rectifier and transistor -

Super conductivity — high temperature super conductors, properties and applications -

BCS theory - Cooper electrons - Meissener effect and levitation.

UNIT – IV: SOLID STATE CHEMISTRY – II Efficiency of packing in crystals — Limiting radius ratio – Description of crystal

structures - calcite, zinc blende, wurtzite, rutile, fluorite, antifluorite, CsCl, CdI2, K2NiF4

– spinels and perovskite. Principles of TGA, DTA and DSC-applicdation to simple salts,

278  

oxy salts, carbonates and complex salts – thermometric titrations. Principles and

measurements of X-ray diffraction studies. Electron diffractions by

gases – principle and measurements - determination of structures – comparison

between electron, neutron and X-ray diffraction.

UNIT – V: LANTHANIDES AND ACTINIDES Correlation of electronic structures, occurrence and properties of the elements -

Chemistry of separation of Np, Pu and Am from U & fission products - Common and

uncommon oxidation states - Comparison with transition elements - Lanthanide and

actinide contractions - Spectral and magnetic characteristics of lanthanides and

actinides - Similarities between actinides and lanthanides - Coordination compounds of

lanthanides - Use of lanthanide complexes as shift reagents.

REFERENCES 1. James E. Huheey, Ellen A. Keiter and Richard L. Keiter, Inorganic chemistry:

principles Structure and Reactivity, 4th Ed., Harper College Publishers, 1993.

2. F. Albert Cotton, Geoffrey Wilkinson, Carlos A. Marilo and Manfred Bochman,

Advanced Inorganic Chemistry, Wiley Interscience Publication, 6th Ed., 1999.

3. G.S. Manku, Theoretical Principles of Inorganic chemistry, Tata McGraw Hill, 12th

reprint, 2004.

4. K.F. Purcell and J.C. Kotz, Advanced Inorganic Chemistry, Saunders Golden

Publishers.

5. B.E. Douglas, D.H. McDaniel and J.J. Alexander, Concepts and Models of Inorganic

Chemistry, John Wiley and Sons Ltd. 2nd Ed., 1983.

6. M.c. Day Jr and J. Selbin., Theoretical Inorganic Chemistry, 2nd Ed., East West

Press, 2000.

7. J.D. Lee, Concise Inorganic Chemistry, ELBS, 2006.

8. A. R. West, Solid State Chemistry and its Application, John Wiley & Sons, (Asia),

1998.

9. T. Kutty, J. Tareen, Fundamentals of Crystal Chemistry, University Press, 1st

Ed.,2001.

10. L.V. Azaroff, Introduction to Solids, Tata McGraw Hill Publishing Ltd., India, 1989.

11. C. Kittel, Introduction to Solid State Physics, Wiley Eastern Ltd., 5th Ed., 1993.

12. H.V. Keer, Principles of the Solid State, Wiley Eastern Ltd., 1993.

279  

13. D.K. Chakrabarthy, Solid State Chemistry, New Age International.

14. A.F. Wells, Structural Inorganic Chemistry, Oxford Science Publication, London,

1979.

15. M.T. Weller, Inorganic Materials Chemistry, Oxford University Press, Reprint 1996.

16. B. Sahoo, N. C. Nayak, A. Samantaray, P.K. Pujapanda, Inorganic Chemistry,

PHILearning, New Delhi, 2012.

PHYSICAL CHEMISTRY – I UNIT – 1: CLASSICAL THERMODYNAMICS Thermodynamics systems of variable composition: Partial molar quantities – Chemical

Potential, partial molar volume and partial molar heat content. Gibbs-Duhem

equation.Determination of these partial molar quantities.Variation of chemical potential

with temperature and pressure. Thermodynamics of real gases and real solutions;

Fugacity: Methods of determination. Dependence on temperature, pressure and

composition. Activity and activity coefficient: Standard states, determination of activity

and activity coefficient of non-electrolytes and electrolytes.

UNIT – 2: IRREVERSIBLE THERMODYNAMICS Non equilibrium process: General theory – Conservat ion of mass and energy – Entropy

production in open system by (i) heat (ii) matter and (iii) current flow. Onsager theory:

Validity and verification. Thermoelectricity–Electrokinetic and thermo mechanical

effects.Application of irreversible thermodynamics to biological and non–linear systems.

UNIT – 3: CHEMICAL AND PHASE EQUILIBRIA Reaction free energy/ Reaction Potential – Reaction isotherm and direction of

spontaneity – Standard reaction free energy – its calculation from thermochemical,

electrochemical and equilibrium data – Temperature coefficient of reaction free energy

and equilibrium constant. Gibbs phase rule – its thermodynamic derivation – Application

of phase rule to three component systems – Formation of one pair, two pairs and three

pairs fo partially miscible liquids – systems composed of two solids and a liquid.

280  

UNIT – 4: STATISTICAL THERMODYNAMICS Thermodynamic probability and entropy – Maxwell-Boltzman, Bose-Einstein and Fermi-

Dirac statistics and applications – Partition functions and entropies for translational,

rotational, vibrational and electronic motions of monoatomic and diatomic molecules –

Calculations of thermodynamic functions and equilibrium constants – Specific heat of

solids – Einstein and Debye theories.

UNIT – 5: MACROMOLECULES Polymerization in homogeneous and heterogeneous phases – Kinetics and mechanism

of polymerization (Addition and Condensation) – Kinetics of copolymerization –

Properties of polymers: Glass transition temperature, crystallinity of polymers. Molecular

weights: Distribution, methods of determination – Light Scattering, Ultracentrifuge,

Viscosity and Osmometry – Gel Permeation Chromatography. Conducting polymers –

Factors affecting the conductivity of conducting polymer – Doping of conducting

polymers – Nature of charge carriers in conducting polymers – solitons, polarons and

bipolarons.

REFERENCE 1. S. Glasstone, Thermodynamics for chemists, Van Nostrand Co, New York, 1969.

2. K.G. Denbigh, Thermodynamic of Steady State, Methien and Co. Ltd., London, 1951.

3. L.K. Nash, Elements of Chemical Thermodynamics, Addison Wesly, 1962.

4. G.M.Barrow, Physical Chemistry, McGraw Hill, 1988.

5. J.C. Kuriacose and J. Rajaram, Thermodynamics, Shohan lal and Co. Delhi, 1986.

6. J. Rajaram and J.C. Kuriacose, Thermodynamics, 2nd Ed., S.N. Chand & Co.,

NewDelhi, 1993.

7. D.N. Bajpai, Advanced Physical Chemistry, S. Chand & Co., New Delhi, 1998.

8. S.H. Maron and J.B. Lando, Fundamentals of Physical Chemistry,

MacMillanInternational Education, New York, 1974.

9. M.C. Gupta, Statistical Thermodynamics, New Age International (P) Ltd., New

Delhi,2nd Edition, 1998.

10. G.K. Narula and V.K. Gupta, Material Science, Tata McGraw Hill, New Delhi, 1988.

281  

11. F. Rodriguez, Principles of Polymer Science, Tata McGraw Hill, New Delhi, 2nd

Ed.,1987.

12. F.W. Billmeyer Jr., Text book of Polymer Science, John Wiley and Sons, New

York,1984.

13. Premamoy Ghosh, Polymer Science and Technology, Tata McGraw Hill, New

Delhi,2nd Ed., 4th Reprint, 2005.

14. V.R. Gowarikar, N.V. Viswanathan and J. Sreedhar, Polymer Science, Wiley

Eastern,New Delhi, 1988.

15. C.E.H. Bawn, The chemisty of High Polymers, Butterworth and Co., London, 1948

16. E.A. Collins, J. Bares and E.W. Billmeyer, Experiments in Polymer Science,

WileyInterscience, New York, 1973.

17. G.S. Krishenbaum, Polymer Science Study Guide, Gordon Breach Science

Publishing,New York, 1973.

18. G. Odian, Principles of Polymerization, Mc Graw Hill Book Company, New York,

1973.

19. P.J. Flory, Principles of Polymer Chemistry, Cornell Press, Ithaca, 1971.

20. Degennes, P.G. Scaling, Concepts in Polymer Physics, Cornell University Press,

1979.

21. Young, R.J. and Lovell, P.A. Introduction to polymers. 2nd Ed. Chapman & Hall,

1991.

22. H.K. Moudgil, Text Book of Physical Chemistry, PHI Learning, New Delhi – 2010.

ELECTIVE - RESEARCH METHODOLOGY

UNIT – I: LITERATURE SURVEY AND CHOOSING A RESEARCH PROBLEM Survey of literature including patents – primary source – secondary source – including

reviews, treatise and monographs – literature survey – abstraction of research papers –

possible ways of getting oneself familiar with current literature. Identification of research

problem – assessing the status of the problem guidance from the supervisor – actual

investigation and analysis of experimental results – conclusions –presenting scientific

seminar – reporting the results in the form of communication, paper etc. – writing thesis.

282  

Unit – II: SPECTROSCOPIC TECHNIQUES Types of atomic spectroscopy – emission methods – absorption methods –fluorescence

methods – atomizers for atomic spectroscopy – flame atomizers –Electrothermal

atomizers – inductively coupled plasma sources of radiation – Applications of atomic

emission spectroscopy.Principle, instrumentation and data interpretation of TEM, SEM,

EDAX and XRD analysis.Calculation of particle size of nanoparticles from XRD spectra

– Debye- Scherrer formula – lattice constant findings.

UNIT – III: CHROMATOGRAPHY Gas Chromatography: Theory of chromatography – column efficiency and column

equation – sample injection – sampling system for capillary columns and packed

columns – detectors – gas flow control system – high resolution gas

chromatography/mass spectroscopy. HPLC: Principles of high performance liquid

chromatography – the liquid chromatography – the requirements of solvent pumping

and different pumping systems – gradient elution, isocratic elution, sampling – detectors

for liquid chromatography – the mobile phase in HPLC – solvent degassing – column

technology – column selection – quantitative analysis by HPLC.

UNIT – IV: RADIOCHEMICAL METHODS General theoretical considerations – special precautions for radiochemical studies –

equipment for measuring radio activity – G.M. Counter – tracers and traces –

determination of characteristics of GM counter – determination of dead time of GM tube

– determination of the absorption curve for 234Th – 234Pa sample. Isotope dilution

analysis – verification of the principle of isotope dilution analysis – determination of

equilibrium constant of a reaction by ion-exchange method using tracers.

UNIT – V: DATA ANALYSIS AND ARTICLE & PROPOSAL WRITINGS Errors in chemical analysis – classification of errors – determination of accuracy of

methods – improving accuracy of analysis – significant figures – mean, standard

deviation –comparison of results : “t” test, “f” test and “chi” square test – rejection of

results –presentation of data.Idea of writing research articles - project proposals to the

funding agency.

283  

REFERENCES 1. C. Mahadevan, Research Methodology, Sakuntala Publications, Nagercoil, 1st

Ed.,2000.

2. R.T. Bottle, The use of Chemical literature, Butterworths, 1969.

3. A.J. Durston, Thesis and assignment writing.

4. R.M.Silverstein, G.C. Bassler and Morril, Spectrometric identification of organic

compounds.

5. J.Dyer, Applications of absorption spectroscopy of organic compounds.

6. D.L.Pavia, G.M.Lampman and G.S.Kniz Jr., Introduction to spectroscopy – A guide

forstudents of organic chemistry.

7. H.Willard, L.Merrit Jr.and A.Dean, Instrumental methods of analysis.

8. D.A.Skoog and M.West, Principles of instrumental analysis.

9. B.K.Sharma, Instrumental methods of chemical analysis.

10. D.A. Skoog and M.West, Fundamentals of analytical chemistry.

11. J.D.Dick, Analytical chemistry.

12. S.M.Khopkar, Basic concepts of analytical chemistry.

13. C.N.Banwell, Fundamentals of molecular spectroscopy.

14. R.Chang, Basic principles of spectroscopy.

15. R.O.Bullet, Preparing thesis and other manuscripts.

16. http://www.dst.gov.in/whats_new/whats_new07/tsd-format.pdf

17. http://www.ugc.ac.in/financialsupport/xiplan/mrpxiplan.pdf

SECOND SEMESTER

ORGANIC CHEMISTRY - II UNIT – I: ULTRAVIOLET, INFRA – RED SPECTROSCOPY, ORD AND CD UV: The absorption laws – Types of electronic transitions – effects of solvent and

Hydrogen bonding on λ max values. – Woodward – Fieser rules to calculate λ max values

of conjugated dienes and α, β- unsaturated ketones. IR: Characteristic of IR absorptions

of different functional groups – factors influencing absorption of carbonyl and hydroxyl

groups – electronic effect, hydrogen bonding and Fermi resonance. Optical rotatory

dispersion (ORD): Octant rule - α - halo ketone rule and their applications-Circular

Dichroism.

284  

UNIT – II: NMR SPECTROSCOPY H1NMR spectroscopy: Basic Principle – number of signals – chemical shift – Factors

influencing chemical shift - spin–spin coupling – classification of spin systems – analysis

of AX, AMX and ABX systems – Geminal, Vicinal and long range couplings–NOE in

stereochemistry – FTNMR.C13 spectroscopy: Principle of proton decoupled C13

spectroscopy - comparison with H1NMR – chemical shifts (aliphatic, olefinic, alkynic,

aromatic and carbonyl compounds) 2D NMR spectroscopy: H1–H1COSY, H1–C13

COSY, NOESY, DEPT and INADEQUATE spectra.

UNIT – III: MASS SPECTROSCOPY Basic Principles – Techniques of Ion Production – E I, C I, FD, FAB, ESI – MS, MALDI –

M S – Base peak – molecular ion – nitrogen rule – metastable ion – isotope ion

daughter ions – Mc–Lafferty rearrangement – RDA – General rules for fragmentation

pattern –Fragmentation pattern of simple compounds of hydrocarbons, alcohols,

amines, aldehyde,ketone, ether, ester, acids and phenols – Detection of structure

through mass spectral fragmentation. One conjunction problem based on the above

spectroscopic techniques is compulsory under section – c. Problems shall be based on

the reference books.

UNIT – IV: ALKALOIDS AND ANTIBIOTICS Alkaloids: Degradation studies – HEM , Emde and Von – Braun – The structural

determination and synthesis of Quinine, Morphine, Cocaine, Strychnine and Reserpine

–Biosynthesis of alkaloids.Antibioties: Structural elucidation of penicillin,

chloramphenicol and cephalosporin – C

UNIT – V: VITAMINS AND TERPENOIDS Vitamins: structural determination of vitamins – A1, B1, B2, B6, C, D and E. Terpenoids :

General methods to elucidate the structure of terpenes – structural determination of

α - pinene, Camphor, Zingiberene, Cadinene, a - Santonin, abietic acid and sqalene.

Bio synthesis of mono and di terpenoids.

285  

REFERENCES 1. J. March, ‘Advanced organic chemistry,’ Fourth Edition, John Wiley and sons, New

York, 2006.

2. R.T. Morrison and R.N. Boyd, ‘Organic Chemistry’, sixth Edition, Prentice Hall, 1994.

3. I.L. Finar, ‘Organic Chemistry’, volume 2, sixth Edition, Pearson Education Inc.,

Singapore, 2006.

4. Y.R. Sharma,’Fundamentals of Organic spectroscopy’.

5. P.S. Kalsi, ‘Spectroscopy of organic spectroscopy’, second Edition , New Age

International publishers Limited, 1995.

6. Jag Mohan, ‘Organic Analytical Chemistry Theory and Practice, ‘ Narosa

PublishingHouse, 2003.

7. W.Kemp, ‘Organic spectroscopy’, Third Edition, Macmillan, 1994.

8. S.M. Silverstein, G.V.Bassler and T.C. Morril, ‘Spectrometric Identification of

organiccompounds, sixth Edition, Wiley 2004.

9. D.H.Williams and Ian Fleming, ‘Spectroscopic methods in organic

chemistry,’fifthEdition, Tata Mc Graw Hill, 1988.

10. F.W. Wherli and T. Wirthilin, ‘Interpretation of carbon – 13 spectra’, Heyson and

sons,London.

11. V.R. Dani, ‘Organic spectroscopy’, Tata Mc Graw Hill, 1995.

12. J.R. Dyer, ‘Application of Absorption spectroscopy, prentice Hall, 1987.

13. Pavia, Lampmann, Kriz and Vyuyan, spectroscopy, cengage learning India

PrivateLtd., First Indian Reprint,2008.

14. D.H. William and R.D. Bower, ‘Mass spectrometry – principles and Applications,’

I.Howe, Mc Graw Hill.

15. R.M. Silverstein and F.X.Webster, ‘Spectrophotometric Identification of

OrganicCompounds’ John Wiley and Sons, Ine., Sixth Edition, 1997.

16. F.A. Carey and J.Sundberg,’Advanced Organic chemistry ‘ part A and B,

PlenumPress, 2005.

17. Gurdeep Chatwal,’Organic Chemistry of Natural products, Vol I and II,

HimalayaPublishing House, Bombay,1992.

18. O.P. Agarwal, ‘Chemistry of Natural Products,’Vol I and II, Goel Publishing

House,Meerut, 1984.

286  

19. M. Mukerji, S.P. Singh, and R.P. Kapoor, ‘Organic Chemistry, Vol I and II,

WileyEastern Ltd., 1985.

20. I.L. Finar, Organic Chemistry , Vol. I. ELBS fifth Edition,2001.

21. R.O.C. Normon, principles of organic synthesis – Chapman and Hall 1994.

22. W. Carruthers, some modern methods & Organic synthesis – Cambridge

UniversityPress.

23. E.L. Eliel, stereochemistry of carbon compounds – Mc Craw Hill, 1999.

24. ORD and CD in chemistry and Bio chemistry – Academic press.

INORGANIC CHEMISTRY -II

UNIT – I: COORDINATION CHEMISTRY Stability of complexes - stabilisation of unusual oxidation states- determination of

stability constants by potentiometric and spectrophotometric methods- factors affecting

stability- chelate and template effects. VB theory and CFT – Splitting of d-orbitals under

different geometries – CFSE – evidence for CFSE – structure of spinels – factors

affecting CFSE – spectrochemical series – Jahn-Teller distortion – M.O. theory of

bonding – sigma and _-bonding in coordination compounds. Ligand substitution

reactions of square planar complexes- Trans effect and its theoriesuse of trans effect in

synthesis of complexes- Substitution reactions in octahedral complexesacid hydrolysis,

base hydrolysis and anation reactions- Electron transfer reactions - Inner sphere and

outer sphere processes- outer sphere process in photochemical reactions.

UNIT – II: ORGANOMETALLIC CHEMISTRY - I Introduction - History-EAN and its correlation to stability- Synthesis and structures of

metal carbonyls- carbonylate anions, carbonyl hydride complexes and metal nitrosyls-

Isolobal analogy- IR study of metal carbonyls- Synthesis, properties and structural

features of metal complexes with carbene, alkene, alkyne and arene. Hapticity-

Metallocenes- synthesis,properties and bonding in ferrocene - covalent versus ionic

bonding in beryllocene, clusters and catalysis, hydride and dihydrogen complexes,

fluxionality.

287  

UNIT – III: ORGANOMETALLIC CHEMISTRY - II Oxidative addition and reductive elimination- insertion and elimination

reactionsnucleophilic and electrophilic attack of coordinating ligands- Catalysis by

organometallic compounds - Homogeneous catalysis- alkene hydrogenation- synthesis

gas and water-gas shift reaction- hydroformylation- carbonylation of alcohols and

oxygenation of olefins-Heterogeneous catalysis- Fischer-Tropsch process and Ziegler—

Natta polymerization - Immobilized homogeneous catalysts.

UNIT – IV: APPLICATION OF SPECTROSCOPY TO THE STUDY OF INORGANICCOMPOUNDS - II NMR SPECTROSCOPY: 31P, 19F and 15N - NMR - introduction - applications in

structural problems — evaluation of rate constants — monitoring the course of reaction

—NMR of fluxional molecules — NMR of paramagnetic molecules — contact shifts and

shift reagents.ESR spectroscopy: Principles — presentation of the spectrum —

hyperfine splittingfactors affecting the magnitude of g-values — zero- field splitting and

Kramers’ degeneracy —anisotropy in the hyperfine coupling constant. Application of

ESR in the study of transition metal complexes. J-T distortion: studies of Cu(II)

complexes.

UNIT – V: ELECTROANALYTICAL METHODS Voltametry : Polarographic analysis - applications, quantitative determination,

determination of equilibrium constant for complex formation - organic polarography -

advanced voltametric techniques - rapid - scan techniques - pulse techniques - AC

techniques - stripping techniques - coulometry - classification - controlled current

coulometrycontrolled potential coulometry - advantage of coulometric methods -

amperometry -amperometric sensors - amperometric tritrations - chronomethods -

Chronopotentiometry -Chrono coulometry - cyclic voltametry.

REFERENCES 1. James E. Huheey, Ellen A. Keiter and Richard L. Keiter, Inorganic chemistry:

Principles, Structure and Reactivity, 4th Ed., Harper Collins College Publishers, 1993.

288  

2. F. Albert Cotton, Geoffrey Wilkinson, Carlos A. ManIc and Manfred Bochman,

Advanced Inorganic Chemistry, Wiley lntersceince Publication, 6th Ed., 1999.

3. D. Bannerje, Coordination Chemistry, Tata McGraw Hill, 1993.

4. G.S. Manku, Theoretical Principles of Inorganic Chemistry Tata McGraw Hill, 12th

reprint 2004.

5. K.F. Purcell and J.C. Kotz, Advanced Inorganic Chemistry, Saunders Golder

Publishers.

6. B.E. Douglas, D.H. McDaniel and J.J. Alexander, Concepts and Models of

InorganicChemistry, John Wiley and Sons Ltd., 2nd Ed., 1983.

7. M.C. Day Jr and J. Selbin, Theoretical Inorganic Chemistry, 2nd Ed., East West

Press,2000.

8. J.D. Lee, Concise Inorganic Chemistry, ELBS, 2006.

9. D.F. Shriver, P.W. Atkins and C.H. Langford, Inorganic Chemistry, ELBS,

OxfordUniversity Press, 1994.

10. W.L. Jolly, Modern Inorganic Chemistry, McGraw Hill Company, 2nd Ed., 1991.

11. R.S. Drago, Physical Methods in Inorganic Chemistry, Saunders College Publishers.

12. E.A.V. Ebsworth, D.W.H. Rankin and S. Cradock, Structural Methods in

InorganicChemistry, ELBS, 1988.

13. D.A. Skoog, F. James Holler and J.A. Nieman, Principles of Instrumental

Analysis,Saunders, 1992.

14. H.H. Willard, L.L. Merritt and J.A. Dean, Instrumental Methods of Analysis,

CBSPublishers, 6th edition, 1986.

15. G.H. Jeffery et.aL, Vogel’s Textbook of. Quantitative Chemical Analysis, Revised5th

edition, ELBS, 1989.

16. R.A. Day and A.L. Underwood, QuantitativeAnalysis, Prentice Hall, 1999.

289  

PHYSICAL CHEMISTRY – II UNIT – I: QUANTUM MECHANICS – I Inadequacy of classical mechanics – Plank’s quantum theory - Compton effect - wave

particle duality - uncertainty principle . Operators and their algebra , Eigen value and

Eigen functions. Quantum mechanical postulates, Schrodinger equations(Time

dependent and Time independent). Particle in a box (1D and 3D), Quantum mechanical

tunneling and transmission coefficient – rigid rotor and harmonic oscillator.

UNIT – II: QUANTUM MECHANICS – II The hydrogen atom – radial distribution and spherical harmonics functions – shapes of

atomic orbitals. Approximation methods: variation theorem, application of variation

method to hydrogen and helium atoms. Perturbation theory (First order): application to

helium atom. Pauli exclusion principle - Slater determinant and HF-SCF methods to He

atom. Born- Oppenheimer approximations: LCAO-MO and VB treatments of H2

molecule. Huckel theory: application to ethylene, butadiene and benzene. Calculation of

electron density and bond order.

UNIT – III: CHEMICAL KINETICS Collision theory of reaction rate – steric factor – Theory of absolute reaction rates –

Thermodynamic treatment – Unimolecular reactions – Lindemann, Hinshelwood, RRK,

RRKM and Slater theories – Chain reactions – Study of kinetics of chain reactions like

H2-Br2 reaction, Decomposition of acetaldehyde and N2O4 – Explosive reactions –

Study of H2-O2 reaction – Ionic reactions in solution – Factors influencing the reaction

rate – Salt effect –

Influence of pressure – Kinetic isotope effect.

UNIT- IV: CHEMICAL DYNAMICS Study of fast reactions – General features – Reactions in flow system, continuous and

stopped flow – Chemical relaxation methods, temperature and pressure jump methods

–Shock tube techniques – Flash photolysis – Pulse radiolysis. Concept of Linear Free

Energy Relationship – derivation of Hammett equationsignificance of substituent and

reaction constants – Taft equation – Thermodynamic implications of LFER.

290  

UNIT- V: PHOTOCHEMISTRY AND RADIATION CHEMISTRY Absorption of light by molecules – Reaction paths of electronically excited molecules –

Fluorescence and phosphorescence – Jablonski diagram – Physical properties of the

electronically excited molecules: Excited state dipole moments, Excited state pKa and

redox potentials – Stern-Volmer equation and its application – Eximers and Exiplus –

Photosensitization – Chemiluminescence. Radiation chemistry – Sources of high energy

– Radiolysis of water – Dosimetry and G value – Primary and secondary processes –

Linear energy transfer – The hydrated electron and its reaction

REFERENCES 1. D. A. McQuairrie: Quantum Chemistry, Oxford University press, Oxford,1982.

2. P. W Atkins:. Molecular Quantum Mechanics, Clarendon Press, Oxford, 1983.

3. R. K. Prasad: Quantum Chemistry through Problems and Solutions, New Age

International, 1997.

4. A.K. Chandra: Introduction to Quantum Chemistry, Tata McGraw Hill, 1994.

5. H. K. Moudgil: Text Book of Physical Chemistry, Eastern Economy Publ.Co.Ltd., New

Delhi,2010.

6. W. Levine: Quantum Chemistry, Prentice Hall, 1994.

7. Sen: Quantum Chemistry, Tata McGraw-Hall, 1992.

8. G. Aruldhas, Quantum Mechanics, 2nd Ed., PHI Learning, New Delhi, 2011.

9. K.J. Laidler, Chemical Kinetics, Tata McGraw Hill, New Delhi, 2nd Edition, 18th

reprint1994.

10. K.J. Laidler, Theories of Chemical Reaction Rates, McGraw Hill, 1988.

11. F. Wilkinson, Chemical Kinetics and Reacton Mechanism, Van Nostrand Reinhold

Co.,New York, 1980.

12. G.L. Agarwal, Basic Chemical Kinetics, Tata McGraw Hill, New Delhi, 1996.

13. R.G. Forest and Pearson, Kinetics and Mechanism, Wiley, New York, 1961.

14. Moore and R.G. Pearson, Kinetics and Mechanism, 1981.

15. C. Capellos and B.H.J. Bielski, Kinetics Systems, Wiley Interscience, New York,

1972.

16. I. Amdur and G.G. Hammes, Chemical Kinetics, Principles and Selected

Topics,McGraw Hill, New York, 1968.

291  

17. G.M. Harrus, Chemical Kinetics, D.C. Health and Co., 1966.

18. P.W. Atkins, Physical Chemistry, ELBS Ed., 1998.

19. P.L. Houston, Chemical Kinetics and reaction Dynamics, McGraw Hill,

InternationalEdition 2001.

20. J. Rajaram and J.C. Kuriacose, Kinetics and Mechanisms or Chemical

transformations,Macmillan India Ltd., 1st reprint 1998.

21. Ira Levine, Physical Chemistry, Tata McGraw Hill, New Delhi, 5th Edition 2004.

22. K.K. Rohatgi Mukherjee, Fundamentals of Photochemistry, New Age International

(P)Ltd., 1997.

23. Gordon Hughes, Radiation Chemistry, Clarendon Press, Oxford, 1973.

24. N.J. Turro, Molecular Photochemistry, Benjamin, 1965.

25. J.G. Calvertz and J.N. Pitts, Photochemistry, Wiley, New York, 1966.

LABORATORY COURSE First year (Semester I & II)

ORGANIC CHEMISTRY PRACTICAL – I A. SEPARATION OF ORGANIC MIXTURE: (i) Separation of two component mixture and determination of their physical constants.

(ii) Separation and analysis of at leasteight two component mixture. The students are

expected to determine the physical constants for both the components as well as their

derivatives.

(iii) Analysis may be performed in micro scale for both economic and eco-friendliness

B. LIST OF SINGLE STAGE PREPARATIONS : (i) Preparation of Benzal acetophenone from Benzaldehyde.

(ii) Preparation of 1,2,3,4 –Tetrahydro carbazole from cyclohexanone.

(iii) Preparation of Resacetophenone from Resorcinol.

(iv) Preparation of dinitro-diphenyl amine from Aniline.

(v) Preparation of benzoquinone from hydroquinone.

Note : Each student is expected to submit recrystallised samples of the derivatives and

recrystallised sample of the preparation during their regular practical for evaluation

during the practical examinations.

292  

C. FOR CLASS WORK ONLY : (i) Interpretation of IR and UV-VIS spectra of any three simple Organic Compounds.

(ii) Organic preparations using Alternative Green Procedure

(Any 4 preparations)

1. Acetylation of primary amine - Acetanilide from aniline

2. Base catalyzed aldol condensation (Synthesis of Dibenzalpropanone)

3. Halogen addition to C=C bond (bromination of trans-stilbene)

4. [4+2] Cycloaddition reaction (diels-alder reaction between furan and maleic acid)

5. Preparation of benzilic acid in solid state under solvent-free condition rearrangement

reaction (benzilbenzilic acid rearrangement)

6. Coenzyme catalyzed benzoin condensation (thiamine hydrochloride catalyzed

synthesis of benzoin)

7. Pechmann condensation for coumarin synthesis (clay catalyzed solid state synthesis

of 7-hydroxy-4-methylcoumarin)

8. Electrophilic aromatic substitution reaction (nitration of phenol)

N.B:- 1.Section C is course work only

2.It is the purpose of internal assessment only

REFERENCES

1.F.C.Mann and B.C.Saunders, Practical organic chemistry, Fourth edition, ELBS,1970

2.A.I. Vogel, A Text book of Practical organic chemistry.

3. A.I. Vogel, A Text book of Quantitative Organic Analysis,1989.

4. Raj K. Bansal,Laboratory Manual of Organic Chemistry,Second Edition,Wiley Eastern

Ltd., 1990

5.Moore, Dalrympk and Rodig, Experimental methods in organic chemistry, 3rd edition,

Saunders College publishing, The Oxford Press,1982

293  

INORGANIC CHEMISTRY PRACTICAL - I 1. Qualitative analysis of inorganic mixture containing two familiar and two less familiar

cations Pb, Cu, Bi, Cd, Sb, Zn, Co, Ni, Mn, Ca, Ba, Sr, W, Tl, Te, Se, Mo, Ce, Th, Zr, V,

U, Ti and Li.

2. Complexometric titrations – Estimation of Cu, Zn and Mg by EDTA titration in

presence of either Pb or Ba .

3. Photocolorimetric Estimation of Fe, Ni, Cr, Mn, Cu and NH4 +.

4. Separation and identification of a binary mixture of inorganic cations by

chromatography.

FOR CLASS WORK ONLY : EDTA Titrations - estimation using alternate green principle (Any two only)

i. Estimation of Ca2+ from the mixture of Ca& Ba

ii. Estimation of Cu2+ from the mixture of Cu & Pb

iii. Estimation of Mg2+ from the mixture of Mg & Ba

iv. Estimation of Zn2+ from the mixture of Zn & Pb

N.B:-The ClassWork is for the purpose of internal assessment only

PHYSICAL CHEMISTRY PRACTICAL - I A. DISTRIBUTION 1. Distribution of benzoic acid between benzene/toluene and water

B. CONDUCTIVITY 2. Determination of solubility product of a sparingly soluble salt

3. Determination of Ka by using Ostwald distribution method.

4. Titrations

(i) HCl + CH3COOH vs NaOH

(ii) NH4Cl + HCl vs NaOH

(iii) CH3COOH + CH3COONa vs NaOH

(iv) CH3COOH + CH3COONa vs HCl

C. KINETICS 5. Study of primary salt effect on K2S2O8

6. Kinetics of K2S2O8 and KI reaction

294  

D. THERMOMETRY 7. Determination of solution enthalpy

(i) Oxalic acid – water

(ii) Ammonium oxalate – water

(iii) Naphthalene - toluene

SECOND YEAR

THIRD SEMESTER

ORGANIC CHEMISTRY - III

UNIT -I :ALIPHATIC NUCLEOPHILIC SUBSTITUTION AND ELIMINATION REACTIONS: Aliphatic nucleophilic substitution : Mechanism of SN1, SN2, SNi, SN1’, SN2’ and SNi

reactions- Effect of substrate, nucleophile, leaving group and solvent on the rate of

substitution- Ambient nucleophile- NGP- Mechanism of esterifications and ester

hydrolysis (BAC2 and AAC2 mechanisms only)Elimination reaction: E1, E2 and E1CB

mechanisms- Factors influencing elimination reactions- Hofmann and Satyzeff rules-

Pyrolytic elimination- Chugaev and cope reactions.

UNIT -II:AROMATIC NUCLEOPHILIC SUBSTITUTION REACTION AND ADDITION TO CARBON-CARBON MULTIPLE BONDS Aromatic nucleophilic substitution reaction: Unimolecular, Bimolecular and Benzyne

mechanisms.Catalytic hydrogenation- Birch reduction-Dieckmann condensation-

Mannich reaction- Wittig reaction- Sharpless asymmetric epoxidation-addition of

hydrogen and hydrogen halides to carbon-carbon double bonds-Michael addition (1,2

and 1,4).

UNIT -III:REACTIVE INTERMEDIATES AND REARRANGEMENTS Carbenes: Generation, stability, structure, reactions and stereochemistry of carbenes-

Wolff rearrangement of acyl carbenes and its synthetic applications.

295  

Nitrenes: Generation, stability, reaction of nitrenes- Mechanism of rearranegements

through Nitrene intermediate: Schmidt, Hoffmann, Beckmann rearrangements.

Carbanion: Mechanism of rearrangements involving carbanion as intermediate:

Steven, Sommelet Hauser and Favorski rearrangements.

Arynes : Generation, Structure, Stability, reactions and trapping of arynes- cine

substitution.

UNIT -IV: ORGANIC PHOTOCHEMISTRY AND PERICYCLIC REACTIONS Photosensitization- cis-trans isomerisation- photo oxidation and reductions- Norris type-I

and II reactions- Paterno-Buchi reaction- Barton reaction- Di-π methane

rearrangement.Atomic and molecular orbitals-Woodward-Hoffmann rules, FMO and

correlation diagram approaches: Electrocyclic reaction- con and dis rotatory motions for

4n and 4n+2system (butadiene and 1,3,5-hexatriene)- Stereochemical course of electro

cyclic reaction in terms of conservation of orbital symmetry.

Cycloaddiation- suprafacial and antarafacial additions, [2+2] and [4+2] reactions

(ethylene and butadiene)- Sigmatropic rearrangements - [i,j] shift of C-H and C-C bonds

(1+3 and 1+5system)

UNIT -V: HETEROCYCLIC AND BIOMOLECULES Synthesis and reactions of oxazole, imidazole, thiazole, coumarins benzopyrones and

anthocyanins-synthesis of flavones, flavonol and quercetin-Biosynthesis of flavonoids.

Pyranose and furanose forms of aldohexose and ketohexose-methods used for the

determination of ring size-A Detailed study on the structure of maltose, sucrose and

lactose- A brief study on starch and cellulose.Nucleoproteins and nucleic acid-chemistry

and Heredity- genetic code.

REFERENCES 1.J.March, ‘ Advanced organic chemistry’, Fourth Edition, John Wiley and Sons,

Newyork, 2006.

2. Depuy, E.C.H. and Chapman, O.S., “Molecular reactions and photochemistry” ,

Prentice Hall, New York, 1988.

3.I.L. Finar, ‘Organic Chemistry’, volume 2, sixth Edition, Pearson Inc., Singapore, 2006.

296  

4.Raj K. Bansal, ‘Organic Reaction mechanisms”, Tata Mc Graw Hill, Third Editon,

2007

5.Singh, J., and Singh, J., “Photochemistry and Pericyclic reaction”, New Age

International, New Delhi, 2004.

6.H.O. House, ‘Modern synthetic Reaction,’Second Edition , W.A. Benjamin, Inc.,

London, 1972

7.R.K. Mackie, M.M. Smith and R.A. Aitken,’Guide Book to Organic Synthesis’ Second

Edition, Longman Seientific and Technical, Singapore, 1990.

8.Carrutherus , W., “ Some Modern Methods in Organic Syntheis”, Third edition,

Cambridge University Press, New York, 1997.

9.F.A. Carey and J.Sundberg,’Advanced Organic chemistry ‘ part A and B, Plenum

Press, 2005.

10.Michael B. Smith, ‘Organic Synthesis,’ Mc Graw Hill international Edition , 1994.

11.P. Sykes, ‘A Guide book to mechanism in organic chemistry’, Orient Longman, 1989.

12.Gurdeep R. Chatwal, ‘Reaction mechanism and Reagents in organic chemistry’,

Himalaya publishing House, Bombay 1992.

13. R.T. Morrison and R.N. Boyd,’Organic Chemistry’ sixth Edition, Prentice Hall,1994

14.R.O.C .Norman, Principles of organic synthesis- Chapman and hall, London.

15.De Mayo, Molecular rearrangements

16. E.S. Gould, ‘Mechanism and structure in organic chemistry’ Holt, Rinehart and

Winston Inc., 1959.

17. F.A. Carey, Organic chemistry – Tata Mc Graw Hill, Delhi, 5th edition 2005.

18.Stryer, L., “Biochemistry”, Fifth edition, W.H.Freeman and company, San Francisco,

2002.

19.Jain, J.L., “Fundamentals of Biochemistry”,Fourth edition, S.Chand & Company

Limited, New Delhi.2007

297  

INORGANIC CHEMISTRY - III UNIT – I : NUCLEAR CHEMISTRY- I Atomic nuclei : classification , composition and stability – nuclear shell structure –

nuclear reactions : types , Q-value , threshold energy , cross sections and excitation

functions – nuclear reaction models : optical and compound nucleus models . Direct

nuclear reactions – transfer reactions : stripping and pick-up –high energy reactions :

neutron evaporation and spallation – heavy ion reactions – photonuclear reactions.

Nuclear fusion and stellar energy – nuclear fission : mass and charge distribution of

fission products – fission energy – fission neutrons – theory of nuclear fission –

spontaneous fission .

UNIT – II : NUCLEAR CHEMISTRY - II Nuclear reactors : classification , components , reproduction factor and design

parameter – fuel materials and their production. Breeder reactor : fast breeder test

reactor – reprocessing of spent fuels : aqueous and non-aqueous processes – disposal

of gaseous , liquids and solid radioactive wastes –radiation hazards and protection –

India’s nuclear reactors . Radio isotopes : preparation, application of radio isotopes in

elucidating reaction mechanisms and structural determinations . Analytical applications :

radio chromatography , neutron activation analysis , neutron absorptiometry and

radiometric titrations – hot atom chemistry – synthesis of transuraniens .

UNIT – III : INORGANIC CHAINS , RINGS , CAGES AND CLUSTERS Hetero catenation - silicates - classification and structure-property correlation .

Polyacids – structures of isopoly and heteropoly anions - polymeric sulphur nitride -

borazines – phosphazenes - phosphazene polymers - boranes and carboranes –

structure and bonding in boranes. Metal-metal bonds and metal atom clusters -

carbonyl type - anionic and hydrido clusters- non- carbonyl type – octahedral clusters

and triangular clusters .

298  

UNIT-IV: APPLICATION OF SPECTROSCOPY TO THE STUDY OF INORGANIC COMPOUNDS – II Application of IR and Raman spectra in the study of coordination compounds :

Application to metal carbonyls and nitrosyls – geometrical and linkage isomerism –

detection of inter and intramolecular hydrogen bonding – stretching mode analysis of

metal carbonyls.

Mossbauer spectroscopy : Principle – application of isomer shift , quadrupole

interactions and magnetic hyperfine splitting in the study of iron and tin compounds .

UNIT-V : BIOINORGANIC CHEMISTRY –I Essential and trace elements in biological system – biological importance and toxicity

of elements such as Fe , Cu , Zn , Co , Mo , W , V , Mn , and Cr in biological system.

Metallo porphyrins – chlorophyll – photosynthetic electron transport sequence –

biological electron carriers : iron-sulphur proteins , cytochromes and blue copper

proteins – oxygen carriers: haemoglobin and myoglobin - Haemoglobin modelling :

synthetic oxygen carriers . Corrin ring system - vitamin B12 , Fixation of nitrogen – in

vitro and in vivo.

REFERENCES

1. Samuel Glasstone ,Source Book of Atomic Energy , East West Pvt.Ltd., 1969.

2. H.J.Arnikar ,Essentials of Nuclear Chemistry , Wiley Eastern Ltd., 4th Edition ,2000 .

3.G.Friedlander , J.W.Kennedy , E.S.Macies and Julian Malcolm , Nuclear and

Radiation Chemistry , A . Wiley Interscience publication ,1981.

4.James .E.Huheey , Ellen .A. Keiter and Richard .L. Keiter , Inorganic Chemistry :

Principles of Structure and Reactivity , 4th Edition , Harper Collins College Publishers ,

1993

5.F.Albert Cotton , Geoffrey Wilkinson , Carlos .A.Manic and Manfred Bochman ,

Advanced Inorganic Chemistry ,Wiley Interscience Publication , 6th edition , 1999 .

6.G.S.Manku , Theoretical Principles of Inorganic Chemistry , Tata McGraw Hill , 12

reprint 2004.

299  

7.K.F.Purcell and J.C.Kotz ,Advanced Inorganic Chemistry , Saunders Golden

Publishers .

8.B.E.Douglas , D.H.McDaniel and J.J.Alexander , Concepts and Models of Inorganic

Chemistry , John Wiley and Sons Ltd . 2ndEdition , 1983.

9.J.D.Lee , Concise Inorganic Chemistry , Blackwell Science Ltd., 5th Edition, Reprint

2003.

10.M.C.Day Jr. And J.Selbin.,Theoretical Inorganic Chemistry , 2nd Edition , East West

Press , 2000.

11.R.S.Drago, Physical Methods in Inorganic Chemistry ,W.B.Saunders ,1977.

12.E.A.V.Ebsworth David ,W.H.Rankin Stephen Credock ,Structural Methods in

Inorganic Chemistry ,ELBS , IV 1988.

13.D.E.Fenton ,BioCoordination Chemistry , Oxford Science Publications ,1995.

14.I.Bertini, H.B.Gray ,S.J.Lippard and J.S.Valantine , Bioinorganic Chemistry , Viva

Books Pvt. Ltd., 1998.

PHYSICAL CHEMISTRY-III

UNIT-I:GROUP THEORY I :SYMMETRY PROPERTIES OF MOLECULES AND GROUP THEORY: Symmetry elements, symmetry operations and point groups, properties of group,

symmetry and dipole moment, symmetry and optical activity, symmetry operations as a

group, multiplication table.Classes of symmetry operations and matrix representations

of operations.Reducible and irreducible representations, orthogonality

theorem.Properties of irreducible representations. Constructions of character table for

point groups (C2v, C3v, C2h, C4vand D2). Explanations for the complete character table for

a point group.

UNIT- II: GROUP THEORY II :APPLICATION OF GROUP THEORY: Symmetry selection rules for infrared, Raman and electronic Spectra.

Standard reduction formula.Determination of representations of vibrational modes in

non-linear molecules (H20, NH3 and Trans N2F2).Infrared and Raman activities of

normal modes of vibrations. Rule of mutual exclusion.

300  

Electronic Spectra of Ethylene and formaldehyde molecules. Hybrid orbital in non-linear

molecules (CH4, XeF4, BF3,and PF5). Projection operators and symmetry adapted linear

combinations(SALC). Simplification of HMO calculations using group theory. Calculation

of delocalization of energy in 1,3-butadiene and cyclopropenyl systems.

UNIT - III :ELECTROCHEMISTRY Electrolytic conductance-Debye - Huckel theory of inter-ionic attraction , Debye-Huckel-

Onsagar equation and its validity. Debye-Falkenhagen and Wein effects. Debye-Huckel

limiting law, its applications to concentrated solutions. Debye-Huckel Bronsted

equation.Quantitative and qualitative verification of DebyeHuckel limiting law.

Electrode-electrolyte interface, adsorption at electrified interface, electrical double layer,

electrocapillary phenomenon-Lipmann equation

UNIT - IV:- Polarization and over potential, Butler-Volmer equation for one step and

multistep electron transfer reactions, Tafel equation, significance of I0 and transfer

coefficient, polarizable and non polarizable electrodes, mechanism of hydrogen and

oxygen evolution reactions. Corrosion and polarization of metals - Pourbaix diagrams,

Evan’s diagram, Fuel cells, electrode deposition-principle and applications

UNIT - V:-ADSORPTION AND SURFACE PHENOMENON: Physisorption and chemisorption, adsorption and desorption, adsorption isotherms-

Langmuir and B. E. T. equation and significance in surface area determination, surface

films, adsorption from solution, Gibb's adsorption equation: derivation, significance.

Kinetics of unimolecular and bimolecular surface reactions. Application of photoelectron

spectroscopy, ESCA and Auger spectroscopy to the study of surfaces, Surface activity,

surface active agents and their classification, micellisation, critical micelle concentration

( cmc), thermodynamics of micellisation , factors affecting cmc, methods of

determination of cmc , use of surfactants in oil recovery.

REFFERENCE 1. Symmetry, Orbitals and spectra by M. Orchin & H. Jaffe, Willey.

2. Chemical applications of group theory by F. A. Cotton Willey .

3. Symmetry in chemistry by H. Jaffe and M .Orchin , Jhon willey.

4. Group theory and its applications to chemistry by K. V. Raman.

301  

5. Group theory and spectroscopy by K. Veera Reddy.

6. Group Theory and Its Chemical Applications. Author, P. K. Bhattacharya.

7. Group theory by Gobinathan and Ramakrishnan.

8. Vibrational spectroscopy by D.N.Satyanarayana.

9. Physical chemistry. by F. Daniels and A. Alberty.

10. An Introduction to Electrochemistry by S. Glasstone.

11. Modern Electrochemistry Vol. I & II by J. O. M. Bockris and A.K.N. Reddy .

12. Physical Chemistry by P. W. Atkins. ELBS.

13. Physical chemistry of surfaces: A. W. Adamson.

14. Theories of chemical reaction rates by A. J. K. laidler.

15. Text book of physical Chemistry by H.K. Moudgil.

FOURTH SEMESTER

INORGANIC CHEMISTRY- IV

UNIT – I: APPLICATION OF SPECTROSCOPY TO THE STUDY OF INORGANIC COMPOUNDS –III Electronic spectroscopy : L-S coupling and j-j coupling schemes , micro states ,

Hund’s rule and term symbols . Selection rules for electronic transition and hole

formalism – splitting of terms – Orgel and Tanabe Sugano diagrams – Evaluation of 10

Dq and B for octahedral d 2 and d8 systems. Charge transfer spectra. Electronic spectra

of lanthanide and actinide complexes .

Photo electron spectroscopy : Koopman’s theorem , PES – XPES(ESCA) – chemical

shifts in XPES – application of ESCA to inorganic systems – Auger electron

spectroscopy.

UNIT – II : THERMOANALYTICAL AND SPECTROANALYTICAL METHODS Theory and principles of thermogravimetric analysis , differential thermal analysis and

differential scanning colorimetry–characteristic features of TGA and DTA curves-factors

affecting TGA and DTA curves- complementary nature of TGA and DTA –

302  

applications of thermal methods in analytical chemistry- thermometric titrations- the

study of minerals and polymers.

Principle and applications of colorimetry,spectrophotometry, nephelometry, turbidimetry

, fluorimetry and atomic absorption spectroscopy.

UNIT – III : CHEMISTRY OF INORGANIC MATERIALS Synthesis of inorganic materials – high temperature reactions and experimental

methods – precipitation, gel, solution and hydrothermal methods , synthesis in sealed

tubes and special atmospheres . Low temperature methods . Insertion compounds of

metal oxides – Intercalation compounds of graphite and transition metal disulphides

.Zeolites : structures and properties – pillared clays – fullerenes and fullerides.

UNIT -IV : INORGANIC PHOTOCHEMISTRY Properties of excited states of metal complexes – charge transfer excitation –

bimolecular deactivation(quenching) and energy transfer – photochemical path ways :

oxidation-reduction, isomerisation and substitutional processes – photochemistry of

Cr(III), Co(III), Rh(III) and Pt(II) complexes – photophysical and photochemical

properties of ruthenium polypyridyls – applications of inorganic photochemistry :

photochemical conversion and storage of solar energy – inorganic photochemistry at

semi-conductor electrodes.

UNIT – V : BIOINORGANIC CHEMISTRY – II Metalloenzymes – enzymes in dioxygen management – superoxide dismutase ,

peroxidases, catalases, oxidases and monooxygeneases – zinc enzymes: carbonic

anhydrase , carboxypeptidase and alcohol dehydrogenase – the structural role of zinc –

trinuclear zinc constellations .

Chelate therapy - therapeutic chelating agents and their uses – anti -cancer platinum

complexes and their interaction with nucleic acids , gold compounds and anti-arthritic

agents – metal complexes as probes of nucleic acids.

303  

REFERENCES 1.R.S. Drago , Physical Methods in Inorganic Chemistry , Saunders College

Publishers .

2.E.A.V.Ebsworth , D.W.H.Rankin and S.Cradock , Structural Methods in Inorganic

Chemistry ,ELBS ,1988 .

3.D.A.Skoog , F.J. Holler & T.A.Nieman , Principles of Instrumental Analysis , Saunders

1992

4.D.A.Skoog , D. M.West , F.J.Holler , S.R.Grouch , Fundamentals of Analytical

Chemistry, Thomson Asia Pvt.Ltd.,Eighth Edition , Third Reprint , 2005 .

5.H.H.Willard , L.L.Merritt and J.A.Dean , Instrumental Methods of Analysis , CBS

Publishers , 6th edition , 1986 .

6.Mark.T.Weller, Inorganic Materials Chemistry , Oxford Chemistry Primers , Oxford

Science Publications , Reprint 1996.

7.A.R.West ,Solid State Chemistry and its Application .John Wiley & Sons ,(Asia ) ,

1998.

8.D.M.Adam ,Inorganic Solids , John Wiley & Sons Ltd. London 1974.

9.A.F.Wells ,Oxford University Press , Structural Inorganic Chemistry , 1984.

10.G.H.Jeffery et.al ,Vogel’s Textbook of Quantitative Chemical Analysis , Revised 5th

edition ,ELBS , 1989 .

11.James.E.Huheey , Ellen .A.Keiter and Richard .L.Keiter, Inorganic Chemistry :

Priciples of Structure and Reactivity , 4th Edition., Harper Collins College Publishers

,1993 .

12.F.Albert Cotton , Geoffrey Wilkinson , Carlos A.marilo and Manfred Bochman ,

Advanced Inorganic Chemistry , Wiley Interscience Publication ,6th Edition ., 1999 .

13.K.F.Purcell and J.C.Kotz , Advanced Inorganic Chemistry , Saunders Golden

Publishers .

Journal Chemical Education, Vol. 60, October 1983 issue.

14.A.W.Adamson and P.D. Fleischauer, Concepts of inorganic photochemistry, John

wiley and sons, New York, 1975.

15.D.E.Fenton , Bio-coordination Chemistry , Oxford Science Publications , 1995 .

16.I.Bertini ,H.B.Gray , S.J.Lippard and J.S.Valantine , Bioinorganic Chemistry ,Viva

Books Pvt.Ltd., 1998 .

304  

GREEN CHEMISTRY-I UNIT -I: PRINCIPLES AND CONCEPTS OF GREEN CHEMISTRY Introduction - Sustainable Development and Green Chemistry- Atom Economy- Atom

Economic Reactions-Rearrangement Reactions-Addition Reactions-Atom Un-economic

Reactions-Substitution Reactions-Elimination Reactions- Wittig Reactions - Reducing

Toxicity-Measuring Toxicity

UNIT -II:WASTE: PRODUCTION, PROBLEMS AND PREVENTION Introduction-Some Problems Caused by Waste-Sources of Waste from the Chemical

Industry-The Cost of Waste- Process Design for Waste Minimization-Minimizing Waste

from Existing Processes-On-site Waste Treatment-Physical Treatment-Chemical

Treatment-Biotreatment Plants- Design for Degradation -Degradation and Surfactants-

DDT-Polymers- Rules for Degradation-Polymer Recycling- Separation and Sorting-

Incineration-Mechanical Recycling-Chemical Recycling to Monomers

UNIT III:CATALYSIS AND GREEN CHEMISTRY Introduction to Catalysis- Comparison of Catalyst Types -Heterogeneous Catalysts -

Basics of Heterogeneous Catalysis -Zeolites and the Bulk Chemical Industry -

Heterogeneous Catalysis in the Fine Chemical and Pharmaceutical Industries -Catalytic

Converters-- Homogeneous Catalysis -Transition Metal Catalysts with Phosphine

Ligands -Greener Lewis Acids -Asymmetric Catalysis-Phase Transfer Catalysis -Hazard

Reduction -C-C Bond Formation- Oxidation Using Hydrogen Peroxide-Biocatalysis –

Photocatalysis

UNIT -IV:ORGANIC SOLVENTS: ENVIRONMENTALLY BENIGN SOLUTIONS Organic Solvents and Volatile Organic Compounds-Solvent-free Systems- Supercritical

Fluids -Supercritical Carbon Dioxide- Supercritical Water-Water as a Reaction Solvent -

Water-based Coatings- Ionic Liquids- Ionic Liquids as Catalysts-Ionic Liquids as

Solvents- Fluorous Biphase Solvents

305  

UNIT -V:SOLVENT EFFECTS ON THE POSITION OF HOMOGENEOUS-CHEMICAL EQUILIBRIA: Solvent Effects on Acid/Base Equilibria- on Tautomeric Equilibria - on

Keto/Enol Equilibria - on Bronsted Acid/Base Equilibria- on Lewis Acid/Base Equilibria -

on Electron-Transfer Equilibria - on Host/Guest Complexation Equilibria

REACTIONS- Qualitative Theory of Solvent Effects on Reaction Rates-The Hughes–

Ingold Rules-Solvent Effects on Dipolar Transition State Reactions - on Isopolar

Transition State Reactions- on Free-Radical Transition State Reactions - Limitations of

the Hughes–Ingold Rules .

REFERENCE 1.Green chemistry- An Introductory Text – Mike Lancaster-The Royal Society of Chemistry, Thomas Graham House, Science Park, Milton Road,Cambridge CB4 OWF, UK 2. Organic Reactions In Water – U.Marcus Lind Strom- 2007 by Black Well Publishing 3. Solvent Free Organic Synthesis 2009- WILEY- VCH VERLAG GmbH & Co. KGaA, Weinhein. 4. Green Chemistry Thoery & Practice – F.T.Anastas & J.C.Warner, Oxford University Press 1998

GREEN CHEMISTRY - II

UNIT- I: RENEWABLE RESOURCES Biomass as a Renewable Resource -Energy-Fossil Fuels-Energy from Biomass- Solar

Power- Other Forms of Renewable Energy -Fuel Cells -Chemicals from Renewable

Feedstock's- Chemicals from Fatty Acids- Polymers from Renewable Resources -Some

Other Chemicals from Natural Resources -Alternative Economies -The Syngas

Economy -The Biorefinery

UNIT -II: EMERGING GREENER TECHNOLOGIES AND ALTERNATIVE ENERGY SOURCES Design for Energy Efficiency-Photochemical Reactions -Advantages of and Challenges

Faced by Photochemical process -Examples of Photochemical Reactions -Metal-

catalyzed Reactions in Water under MW Irradiation Addition Reaction-Isomerization

Reactions-Sonochemistry- Sonochemistry and Green Chemistry -Electrochemical

Synthesis- Examples of Electrochemical Synthesis

306  

UNIT -III: MEASURING AND CONTROLLING ENVIRONMENTAL PERFORMANCE The Importance of Measurement-Lactic Acid Production-Safer Gasoline-Introduction to

Life Cycle Assessment-Green Process Metrics-Environmental Management Systems-

environmental policy IS0 14001-The European Eco-management and Audit Scheme-

Eco-labels-Legislation-Integrated Pollution Prevention and Control

UNIT - IV: DESIGNING GREENER PROCESSES Conventional Reactors- Batch Reactors- Continuous Reactors -Inherently Safer

Design- Minimization -Simplification -Substitution -Moderation -Limitation -Process

Intensification -Some PI Equipment -Examples of Intensified Processes-In-process

Monitoring - Near-infrared Spectroscopy

UNIT - V: INDUSTRIAL CASE STUDIES A Brighter Shade of Green-Greening of Acetic Acid Manufacture-EPDM Rubbers-

Vitamin C-Leather Manufacture- Tanning-Fatliquoring-Dyeing to be Green -Some

Manufacturing and Products Improvements -Dye Application-Polyethene -Radical

Process-Ziegler-Natta Catalysis- Metallocene Catalysis -Eco-friendly Pesticides –

Insecticides

REFERENCE 1.Green chemistry- An Introductory Text – Mike Lancaster-The Royal Society of

Chemistry,

Thomas Graham House, Science Park, Milton Road, Cambridge CB4 OWF, UK

2. Green Chemistry Thoery & Practice – F.T.Anastas & J.C.Warner, Oxford University

Press 1998.

3. Solvents and Solvent Effects in Organic Chemistry, Fourth Edition. Edited by

Christian Reichardt and Thomas Welton

307  

LABORATORY COURSE Second year (Semester III & IV)

ORGANIC CHEMISTRY PRACTICAL – II Estimations, two stage preparations and chromatographic techniques have been

included as the practical components.

Microscale preparations are recommended for the simple reason, they are both

economic-friendly and eco-friendly

A.List of Estimations 1.Ethylmethylketone

2.Glucose-Lane Eynon and method

3.Glucose-Bertrand’s method

4.Saponification value of an oil

5.Iodine value of an oil

6.Number of hydroxyl groups in a given compound

7. Purity of Glucose

B. List of preparations 1.Asprin from Methylsalicylate

2.p-Bromoaniline from Acetanilide

3.m-Nitrobenzene from Acetanilide

4.p- Nitroaniline from Acetanilide

5.Benzpinacolone from Benzophenone

6.Benzanilide from Benzophenone

7.s-Benzylisothiuroniumbenzoate from Thiourea

8.9,10-Dihydroanthracene-9,10-α,β-succinic anhydride from Succinic anhydride

9.Phthalimide from Phthalic acid

10.s-Tribromobenzene from Aniline

Students are expected to submit at the time of practical examination at least eight

recrystallised samples of the final products, for evaluation by the examiners

C.FOR CLASS WORK ONLY Organic preparations using Alternative Green Procedure(Any 4 preparations)

1. Electrophilic aromatic substitution reaction (bromination of acetanilide)

2. Green photochemical reaction (photoreduction of benzophenone to benzopinacol)

308  

3. Pinacol-pinacolone rearrangement reaction (preparation of benzopinacolone)

4.Rearrangement reaction (rearrangement of diazoaminobenzene to p-

aminoazobenzene)

5. Radical coupling reaction (preparation of 1, 1-bis-2-naphthol)

6. Green oxidation reaction (synthesis of adipic acid)

7. Trans-esterification reaction (synthesis of biodiesel)

8. Solvent-free reaction (Microwave-assisted ammonium formate-mediated

Knoevenagel reaction)

N.B:- 1.Section C is course work only

2.It is the purpose of internal assessment only

REFERENCES 1.F.C.Mann and B.C.Saunders, Practical organic chemistry, Fourth edition, ELBS,1970 2.A.I. Vogel, A Text book of Practical organic chemistry. 3. A.I. Vogel, A Text book of Quantitative Organic Analysis,1989. 4. Raj K. Bansal,Laboratory Manual of Organic Chemistry,Second Edition,Wiley Eastern Ltd., 1990 5.Moore, Dalrympk and Rodig, Experimental methods in organic chemistry, 3rd edition, Saunders College publishing, The Oxford Press,1982

INORGANIC CHEMISTRY PRACTICAL – II

I . Quantitative estimation of a mixture containing two metal ions (Volumetric and Gravimetric Estimations ). 1.Estimation of Cu2+ and Ni2+ ions. 2 . Estimation of Cu2+and Zn2+ ions. 3 . Estimation of Fe2+ and Cu2+ ions . 4 . Estimation of Fe2+and Ni2+ ions . 5. Estimation of Ca2+ and Mg2+ ions. 6. Estimation of Ca2+ and Ba2+ ions . 7. Analysis of ores and alloys (course work only ) Note: For examination , a mixture may be given from which one cation is to be estimated volumetrically and the other gravimetrically . II . Preparation of single stage inorganic complexes (a minimum of 10 complexes). Note : Characterisation of any one metal complex by UV or IR spectral techniques (course work only)

309  

FOR CLASS WORK ONLY Estimation of simple mixture of metal ions in solution (involving quantitative separation) by volumetric and Gravimetric methods- using Alternative Green Procedure (Any Two)

I. Cu & Ca II. Cu & Ni III. Cu & Fe IV. Cu & Zn N.B:-The ClassWork is for the purpose of internal assessment only

PHYSICAL CHEMISTRY PRACTICAL – II

I. ABSORPTION :

1. Adsorption of acetic acid/oxalic acid on activated charcoal – verification of

Freundlich isotherm – determination of unknown concentration.

II. POTENTIOMETRY : 2. Determination of formation constant of [Ag(NH3)2]+ complex.

3. Determination of pH of buffer solutions using quinhydrone electrode.

4. Determination of dissociation constant of a weak acid.

5. Determination of solubility product of springly soluble salts by concentration

cell method and chemical cell method.

POTENTIOMETRIC TITRATION : i) Redox

6. FAS – Ce4+

7. Fe2+ - KMnO4

8. KI - KMnO4

ii) Precipitation

9. Kcl – AgNO3

10. Kcl + KI - AgNO3

III. CHEMICAL KINETICS : 11. Kinetics of reaction between potassium perdisulphate and potassium iodide.

12. Kinetics of saponification of ethylacetate using NaOH by conductivity method.

N.B: All the class works are only for internal assessment purpose

310  

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APPENDIX-BA22 MANONMANIAM SUNDARANAR UNIVERSITY , TIRUNELVELI-12

M.C.A Degree Course under CBCS

3years-Six Semesters-Course For affiliated Colleges

Syllabus for V and VI Semester

V SEMESTER

S.I.NO Components Subjects Hours Credits

1 Core .NET Programming 4 4

2 Core Data Warehousing & Mining 4 4

3 Core Computer Networks and Network Management

4 4

4 Elective Elective-III 4 4

5 Elective Elective-IV 4 4

6 Lab .NET Programming – Lab 5 3

7 Lab Mini Project 5 6

Total (5 Theory+2 practical = 7 Courses) 30 29

LIST OF ELECTIVE PAPERS

CATEGORY – B (CHOOSE ANY TWO)

1. Software Agent.

2. Digital Image Processing.

3. Cloud Computing.

4. Web Services.

5. Soft Computing.

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VI SEMESTER

SEMESTER V CORE SUBJECT-1

.NET PROGRAMMING Unit I ASP.NET applications, ASP.NET file types – Three ways to code web forms – ASP.Net configuration web form fundamentals : A simple page applet – Improving the currency converter – A deeper Look at HTML control classes – The page Class.

Unit II Web controls : Stepping up to web controls – Web control classes – Auto post back and Web control events – A simple web page applet – Assessing web controls. Unit III Validation and rich controls : The calendar control – Formatting the calendar – Restricting Dates – The AdRotator – The advertisement file – The AdRotator class validation – The validation controls – The validation process – The validator class – A simple validation example. Unit IV The data list : Data grid & repeater : Introducing Templates – Using Templates with the Data List – Data Binding with Multiple Templates – Comparing the Template Controls – Preparing your list for selection & Editing – Selecting Items – Editing Items – Paging & Sorting with the Data Grid.

S.I.NO Components Subjects Hours Credits

1 Lab Project Work

Viva-Vice 12

317

Unit V Overview of ADO.NET – Introducing ADO.NET and Data Management – Characteristics of ADO.NET – The ADO.NET object model. ADO.NET Data Access : SQL Basics – The SQL select statement – The SQL update Statement – The SQL Insert statement – The SQL delete statement – Accessing, creating a connection – Defining a select command – updating data – Accessing Disconnected Data – Selecting Multiple Tables – Modifying Disconnected Data – Updating Disconnected Data. Text & Reference Books

1. ASP.NET – The complete reference – Matthew Mac Donald – Tata McGraw Hill 2005.

2. Rescued by Active server pages & ASP.NET – Rob Francis – Thomson Delmar Learning Edition 2005.

CORE SUBJECT-2

DATA WAREHOUSING & MINING

Unit – I Operational Data Stores – Data Warehouses – ODS and DW Architecture – DW Implementation – Meta Data –Data Cube: Introduction - Implementation – Operations - Data Mining: Introduction – Process – Applications – Techniques Unit - II Association Rules Mining – Introduction – The Apriori Algorithm –– Direct Hashing and Pruning – Mining Frequent Patterns without Candidate Generation – Classification: Introduction - Decision tree : The Induction Algorithm – Split Algorithms

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Unit - III Classification: Naïve Bayes Method – Accuracy Measures – Other Evaluation Criteria Clustering – Introduction – Feature set – Types of Data - distance measures - Partitional methods - Hierarchial methods Unit - IV Web Mining: Web Terminology and Characteristics – Locality and Hierarchy – Web content Mining – Web structure Mining – Web usage Mining – Search Engines: Introduction – Functionality – Architecture – Ranking of Web Pages Unit - V Spatial Mining – Introduction – spatial data overview – spatial data Mining primitives - Generalization and specialization – Spatial Rules – Spatial classification algorithm – spatial clustering Algorithms Books:

1. G. K. Gupta, “Introduction to Data Mining with Case studies”, PHI , 2011

2. Margaret H. Dunham, “Data Mining Introductory and Advanced Topies”,

Pearson Education, 2003.

3. George M. Marakas, “ Modern Data Warehousing, Mining and Visualization”, Pearson Education , 2003.

4. Alex Berson and Stephen J.Smith, “Data warehousing, Data Mining and OLAP”, McGraw Hill Book Company, 2001.

319

CORE SUBJECT-3 COMPUTER NETWORKS AND NETWORK MANAGEMENT

Unit I Data Communications – Networks – Internet – Protocols and standards, Network models – The Internet model. The physical Layer –Transmission media: Guided and Unguided Media.

Unit II Circuit switching – Time division and Space division switches and their combinations – Telephone network –High speed digital access: DSL, Cable Modems and SONET. Data Link Layer: Error Detection and Correction. Data Link Layer Protocols: Stop and wait ARQ, Go back N ARQ and Selective repeat ARQ, HDLC protocols.

Unit III LAN Medium Access Techniques: Multiple Access: ALOHA, CSMA and CSMA/CD technique, Controlled Access methods – Canalization. Ethernet LAN standard: Traditional Ethernet – Fast Ethernet and Gigabit Ethernet. Virtual Circuit Switching: Frame Relay Architecture – ATM: Design goals – Architecture of ATM – Layers and functions.

Unit IV Network Layer functions: Internetworking – Packet switched internet, Addressing – Classes of addresses – sub netting and super netting. Routing – types – classful and classless addressing. Network Layer Protocols: ARP, IPv4, ICMP, IPv6 and ICMPv6.

Unit V IP Network Management – choosing to manage network – choosing a configuration method – Management information base – SNMP – XML –CORBA –Choosing a configuration protocol – policy control Network management Architecture – Defining network management – Network management mechanisms – Architecture considerations

320

Text Book

1. Data Communication & Networking written by Behrouz A. Forouzan, Third Edition, Tata McGraw Hill Edition 2004

2. Network Management know it all – Farrel et al Morgan Kaufmann Publishers – 2009

3. Data Mining – Vikram Pudi, P.Radha Krishna– Oxford.

Reference Books 1. Computer Networks, Tananbaum, Fifth Edition –Pearson /PHI. 2004. 2. Data & Computer Communications, William Stalling PHI/ Pearson Edition

Asia, Sixth Edition, 2004 3. Computer Networking – Janes F. Kurose, Kerth W. Ross Second Edition.

2003

ELECTIVE SUBJECT-1 SOFTWARE AGENT

Unit I Introduction- Agents and the user experience – How might people interact with Agents – Agents: From direct manipulation to delegates – Interface agents: Metaphors with character Unit II Designing agents as if people mattered – Agents for information sharing and coordination: A history and some reflections Unit III Agents that reduce work and information overload- Software agents for cooperative learning –M: An architecture of integrated agents Unit IV An overview of agent oriented programming – An agent based Framework for interoperability

321

Unit V Agents for information gathering –Communicative actions for artificial agents – mobile agents Text: Software agents – Jeffrey M. Bradshaw – PHI – 2010 Reference Books

1. Bigus & Bigus, " Constructing Intelligent agents with Java ", Wiley, 1997.

2. Bradshaw, " Software Agents ", MIT Press, 2000.

3. Russel, Norvig, "Artificial Intelligence: A Modern Approach", Second Edition, Pearson Education, 2003.

4. Richard Murch, Tony Johnson, "Intelligent Software Agents", Prentice Hall, 2000.

5. Gerhard Weiss, “Multi Agent Systems – A Modern Approach to Distributed Artificial Intelligence”, MIT Press, 2000.

ELECTIVE SUBJECT-2

DIGITAL IMAGE PROCESSING Unit I Introduction: What is Digital Image Processing? – Fundamentals Steps in Digital Image Processing – Components of an Image Processing System. Digital Image Fundamentals: Light and the Electromagnetic Spectrum – Image Sensing and Acquisition – Image Sampling and Quantization(Basic Concepts in Sampling and Quantization - Representing Digital Images - Spatial and Gray-level Resolution - Zooming and Shrinking Digital Images) – Some Basic Relationships between Pixels (Neighbors of a Pixel - Adjacency, Connectivity, Regions and Boundaries – Distance Measures).

322

Unit II Image Enhancement in the Spatial Domain: Some Basic Gray level Transformations (Image Negative – Log Transformations – Power-law Transformations – Piecewise-Linear Transformation Functions)- Histogram Processing(Histogram Equalization- Histogram Matching)- Enhancement using Arithmetic/ Logic operations (Image subtraction – Image averaging) - Basics of Spatial Filtering – Smoothing Spatial Filters . Unit III Image enhancement in the frequency domain: Two Dimensional DFT and its inverse – Basics of filtering in the frequency domain - Lowpass filters(Ideal, Butterworth) – Sharpening frequency domain filters (Ideal, Butterworth ). Image Restoration: A model of the Image degradation / Restoration process – Spatial filtering (Mean filters – Order statistics filters – Adaptive filters). Unit IV Image Compression : Fundamentals (Coding Redundancy – Interpixel redundancy – Psychovisual redundancy – Fidelity criteria ) - Image Compression Models (Source encoder and Decoder) – Error free compression (Variable length coding – LZW coding) –– Lossy Compression(Transform coding) - Image Compression Standards (Continuous tone still image , Video Compression Standards) . Unit V Image Segmentation: Detection of discontinuities (Point, line, Edge detections) – Thresholding(Basic Global and Adaptive) - Region based segmentation (Basic formulations – Region growing – Region splitting and merging)

323

Reference Books

1. Digital Image Processing - Rafael C. Gonzalez and Richard E.Woods, Pearson Education Limited 2004

2. Digital Image Processing and Analysis – B. Chanda and D.Dutta Majunder PHI Limited, 2004

3. Image Processing Analysis and Machine Vision - Milan Sonka , Vaclav Hlavac and Roger Boyle, Vikas Publications 2005.

4. Digital Image Processing - Pratt – Wiley Publications , 2004.

ELECTIVE SUBJECT-3 CLOUD COMPUTING

Unit I Mainframe architecture – Client – Server architecture – 3 tier architectures with TP monitors – Evolution of Cloud computing – Cloud computing basics – Cloud computing – SPI framework for Cloud computing – Traditional Software model – Cloud services deliver model – Cloud deployment models – Key Drivers to Adopting the cloud – Impact of Cloud computing on users – Governance in the Cloud – Barriers to Cloud computing Adoption in the enterprise – Dev 2.0 platforms – Dev 2.0 in the cloud for enterprises. Unit II Cloud platforms – Infrastructure as a service: Amazon EC2 – Platform as a service Google App Engine – Microsoft Azure – Cloud computing economics – Is cloud infrastructure cheaper – Economics of Private clouds – Software productivity in the cloud Public vs. Private clouds – Cloud Technologies – Web services : Soap and Rest – Soap versus Rest – AJAX : asynchronous rich interfaces – Mashups: user interface services – Virtualization Technology – Virtual machine technology – Virtualization application in enterprises – Pitfalls of virtualization.

324

Unit III Cloud development – Relational databases – Clod file systems: GFS and HDFS – Big Table, HBase and Dynamo, cloud data stores : Data store and simple DB – Map Reduce and Extensions – Parallel computing – Map Reduce model – Parallel Efficiency of Map Reduce – Enterprise batch processing using MapReduce. Unit IV Dev2.0 platforms – slaesforce.coms Force.com platform – TCS Instant Apps on Amazon cloud – More Dev 2.0 platforms and related efforts – Advantages, applicability and limits of Dev2.0 – anatomy of a large enterprise – Partners: People and Organizations – Products – Orders : Sales and Purchase – Execution : Tracking work – Billing – Accounting – Enterprises processes, build vs. buy and SaaS. Unit V Enterprise cloud computing – Enterprise cloud computing ecosystem – Public cloud providers – Cloud management platforms and tools – Tools for building private clouds – Quick wins using public clouds – Future of enterprise cloud computing. Text Book

1. Enterprise Cloud Computing – Gautam Shroff, Cambridge University press Edition 2010 (Unit I – V).

2. Cloud Security and Privacy – Tim Mather, Subra Kumaraswamy, Shahed Latif, O' Reilly Edition 2009 (Unit I).

325

ELECTIVE SUBJECT-4 WEB SERVICES

Unit I Introduction to web services – Industry standards, Technologies and Concepts underlying Web Services – their support to Web Services, Applications that consume Web Services. Unit II XML – its choice for web services – Network protocols to backend databases – Technologies – SOAP, WSDL – exchange of information between applications in distributed environment – Locating remote web services – its access and usage, UDDI specification – and introduction. Unit III A brief outline of web services – conversation – static and interactive aspects of system interface and its implementation, work flow – Orchestration and refinement, Transactions, Security issues – the common attacks – security attacks facilitated within web services quality of services – Architecting of systems to meet users requirement with respect to latency, performance, reliability, QOS metrics, Mobile and wireless services – energy consumption, network band with utilization, portals and services management. Unit IV Building real world enterprise applications using web services – sample source codes to develop web services – steps necessary to build and deploy web services and client applications to meet customer's requirement – Easier development, customization, maintenance, transactional requirements, seamless porting to multiple devices and platforms.

326

Unit V Development of web services and applications onto tomcat application server and Axis SOAP server (both are freewares) – Web services platform as a set of enabling technologies for XML based distributed computing. Reference Books

1. Sandeep Chatterjee, James Webber, "Developing Enterprise Web Services : An Architects Guide", Prentic Hall, Nov. 2003.

2. Keith Ballinger, "NET web services "Architecture and Implementation with .Net", Pearson Education, First Education Feb. 2003.

3. Ramesh Nagappan, Developing Java Web Services: Architecting and developing secure web services using Java", John Wiley and Sons, first edition Feb. 2003.

4. Eric A marks and Mark J Werrell, "Executive Guide to Web Services", John Wiley and sons, March 2003.

5. Anne Thomas Manes, "Web Services : A managers Guide" Addison Wesley, June 2003.

ELECTIVE SUBJECT-5

SOFT COMPUTING Unit I Neural Network and Supervised Learning Network Basic concepts of Neural networks – Evolution of Neural Networks – Basic Models of Artificial neural network – Terminologies of ANN – Mc Culloch – Pitts Neuron – Linear seperability – Hebb Network – Applications of Neural Networks. Supervised learning network – Introduction – Perception Networks – Adaptive Linear Neuron – Multiple Adaptive Linear Neurons – Back propagation Network – Radial Basis function Network.

327

Unit II Associative Memory Networks and Unsupervised Learning Networks Associate memory networks – Introduction – Training algorithms for pattern association – Autoassociative Memory Network – Bidirectional Associative Memory – Hopfield Networks. Unsupervised Learning networks – Introduction – Fixed Weight Competitive Nets – Kohonen Self – Organized Maps – Learning Vector Quantization – Adaptive Resonance Theory Network. Unit III Fuzzy Logic Introduction to classical sets and Fuzzy sets – Introduction – Classical sets – Fuzzy sets. Classical Relation and Fuzzy Relations – Introduction – Cartesian product of a relation – Classical Relation – Fuzzy Relations. Membership Functions – Introduction – Features of Membership functions – Fuzzification – Methods of Membership Value Assignments. Defuzzification – Introduction – Lambada – Cuts for Fuzzy Sets – Lambada – Cuts for Fuzzy Relations – Defuzzification Methods. Unit IV Genetic Algorithm Fundamentals of Genetic Algorithms – History – Basic concepts – Creation of offspring's – Working principle – Encoding – Fitness function – Reproduction. Genetic Modeling – Inheritance Operators – Cross Over – Inversion and Deletion – Mutation Operator – Bit – wise Operators – Bit-wise Operators used in GA – Generational Cycle – Convergence of Genetic Algorithm – Differences and similarities between GA and Other Traditional Methods – Advances in Genetic Algorithm. Unit V Hybrid Systems and Applications of Soft Computing Integration of Neural Networks, Fuzzy Logic and Genetic Algorithms – Hybrid Systems – Neural Networks, Fuzzy logic and Genetic Algorithms Hybrids – Preview of the Hybrid systems to be discussed. Genetic Algorithm

328

based Back propagation networks – GA based with determination. ANFIS – Adaptive Neuro – Fuzzy Inference systems – Introduction – ANFIS Architecture – Hybrid learning algorithm. Coactive Neuro – Fuzzy Modeling – Introduction – Framework. Applications of Soft Computing – Introduction – A Fusion approach of Multispectural Images with SAR Image for flood area analysis Optimization of TSP using genetic algorithm approach – Genetic Algorithm based Internet Search Technique. References

1. S.N. Sivanandam, S.N Deepa "Principles of Soft Computing", Wiley – India, 2007.

2. S. Rajesekaran and G.A.V. Pai, "Neural Networks, Fuzzy Logic and Genetic Algorithms", PHI, 2004.

3. J.S.R. Jang, C.T. Sun and E. Mizutani, "Neuro – Fuzzy and Soft Computing", PHI, Pearson Education 2004.

4. S.N. Sivanandam, S.N. Deepa, "Introduction to Genetic Algorithms", Springer, 2007.

5. Timothy J. Ross, "Fuzzy Logic with Engineering Application", McGraw Hill, 2000.

6. Davis E. Goldberg, "Genetic Algorithms : Search, Optimization and Machine Learning" Addison Wesley, N.Y., 2003.

329  

APPENDIX – BA23 MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI – 12

M.PHIL. PHYSICS AFFILIATED COLLEGES

Choice Based Credit System ( CBCS ) ( From the academic year 2013-2014 onwards )

6.2 Guidelines for Project / Dissertation Work : The duration of the project / dissertation work commences from the beginning of

the second semester. The project work shall be based on preliminary research oriented

topics in the fields of theoretical or experimental Physics and the type of work may be of

analytical or design or a combination of all the above. The work has to be carried out

under the guidance of a faculty member of the Department as a project supervisor.

In case, if a student needs to use the facilities from other Universities /

Laboratories / Institutions / Industries outside the campus, he / she may seek for a due

permission from the Project supervisor and acknowledge the source of facilities utilized

by them. If a student needs to stay away from the campus for the purpose of the project

work for a period of more than one month, a special approval from the Principal of the

College through the Project Supervisor should be obtained and on return a certificate to

the above effect should be submitted to the Project Supervisor and to Principal of the

College. A copy of this certificate should be attached in a page after the certificate of the

Project Supervisor in the student’s thesis.

The students should prepare four copies of Project Thesis / Dissertation out of

which one may be held by the student and one should be handed over to the Project

Supervisor. Two copies of the same shall be submitted to the University, one being for

the Departmental / College Library and the other for evaluation by a duly appointed

external examiner from other University or Institution after which the same will be

retained in the University Library.

330  

6.3 Format for Project Thesis or Dissertation : The format of the Project Thesis or Dissertation to be submitted by the students

should have the following in the formats :

a) Format of the Title Page ( Annexure - III ) b) Format of Declaration by the Candidate ( Annexure - IV ) c) Format of the Certificate ( Annexure - V ) d) Acknowledgement

e) Format for Table of Contents ( Annexure - VI ) f) Format for Chapters I – V ( Annexure - VII ) g) Format for References ( Annexure - VIII )

7.0 Scheme of Evaluation for the Project Work : After completion of the project work, by the end of semester IV, each student should

prepare a draft thesis and make a pre - M. Phil. presentation in the Department that

may be open to all the Faculty members and research scholars for getting feedback and

comments, which may be suitably incorporated into the draft thesis under the advice of

the supervisor. Each student submit four copies of the Project Thesis or Dissertation as

mentioned earlier, on or before the date notified by the Department. The thesis will be

evaluated by the concerned Project Supervisor ( PS ) and by the duly appointed two

External Examiners ( E -1 & E - 2 ). A list of examines for for the project viva-voce

examination is given in Annexure – I. The marks for the Project work are awarded on the basis of three components,

viz., (1) Format of the Project Thesis or Dissertation as specified, (2) Evaluation based

on the contents of the Thesis or dissertation and (3) Performance of the student in the

Project the viva-voce examination. The components (1), (2) and (3) carry marks of

maximum as 10, 60 and 30 respectively. These marks for the components (1) and (2)

are awarded separately by the concerned PS and the duly appointed External

Examiner - 1 and the average of the same separately for both the above components

are considered. The evaluation report of the thesis from Examiner E - 1 along with the

marks both from the PS and Examiner -1 for components (1) and (2) for the project

work of each candidate is obtained. The students may be informed the date on which

they will undergo a viva-voce examination which shall be openly defended in the

presence of the concerned Project Supervisor, duly appointed Examiner E-2 and the

331  

Head of the Department concerned. After the viva-voce examination, the marks for

component (3) from the concerned PS and Examiner - 2 for all the students are

obtained. The structure of the marks awarded for the project work is given in the table

below :

-------------------------------------------------------------------------------------------------------------------- Evaluation of Project Work ( Max. : 100 marks )

Thesis Format Thesis Contents Viva-voce Total ( Max.: 10 ) ( Max.: 60 ) ( Max.: 30 ) ( Max.: 100 ) --------------------------------------------------------------------------------------------------------------------- PS E – 1 Mean PS E – 1 Mean PS E – 2* Mean Mean --------------------------------------------------------------------------------------------------------------------- 10 10 10 60 60 60 30 30 30 100 --------------------------------------------------------------------------------------------------------------------

The passing minimum for the project work is 50 % in each of the above three

components. Candidates who do not obtain the required minimum marks for a pass

shall be required to appear in one of the following years along with the other batch of

the students, with a revised version of the Thesis or Dissertation, if required. The

guidelines regarding the minimum attendance, grading, distinction, ranking etc. are as

stipulated by the University.

Annexure – II 6.1 Guidelines for approval to perform as a Project Supervisor : ( for Project or Dissertation work of the candidates of the M.Phil. ( Physics ) Degree Course in the Affiliated Colleges of the M.S. University, Tirunelveli -12 )

The Faculty member seeking recognition as a Project supervisor for the

candidates of M. Phil. Physics should be a Faculty member with Ph.D. Degree in

Physics. The number of M. Phil. project students per Project Supervisor may be

limited to a maximum of 2 students.

332  

Annexure - III 6.3 (a) Format of Title Page : Title of the Dissertation Project Thesis / Dissertation submitted in partial fulfilment of the requirement for the

Degree of Master of Philosophy in PHYSICS

to the

Manonmaniam Sundaranar University

Tirunelveli – 627 012

by

Student Name Register Number

University Emblem

Department of Physics College Name

Address

Month and Year

Annexure - IV 6.3 (b) Format of Declaration by the Candidate : Name of the student : Register No. :

DECLARATION I hereby declare that the Dissertation entitled

_______________________________ has been submitted to the Manonmaniam

Sundaranar University for the award of the Degree of MASTER OF PHILOSOPHY is my

original work and that it has not formed the basis for the award of any Degree, Diploma /

Associateship or any other similar title so far, of any other University or Institution.

Signature of the Student Signature of the Project Supervisor : Signature of the Head of the Department :

333  

Annexure - V

6.3 (c) Format of Certificate : CERTIFICATE

This is to certify that the dissertation entitled

______________________________________________________________________

________ submitted in partial fulfilment of the requirement of the Degree of Master of

Philosophy in Physics to the <College Name> is a record of the bonafide research work

carried out by ____________________________________ under my supervision and

guidance and that no part of the project has been submitted for the award of any

Degree, Diploma, Fellowship or other similar titles or prizes and that the work has not

been published in part or full in any scientific or popular journals or magazines.

Date: Signature of Project Supervisor

Place:

Annexure - VI 6.3 (e) Format for Table of Contents :

The table should contain the subtitles in the format according to the nature of the

project topic studied as below :

Title of the Dissertation Contents

Chapter No. Title Page No.

The thesis may contain chapters with titles such as Introduction, Review of

Literature, Specimen Preparation, Experimental Methods, Theoretical Models,

Computations / Simulations, Results, Data Analysis, Discussion, Conclusion, Summary,

References, Annexures, Appendices etc.

334  

Annexure - VII

6.3 (f) Format for Chapters : The text of the Thesis or Dissertation should be typed with the font type Times

New Roman with size 12 and with 1.5 line spacing. Tables and figures should be

presented within the text wherever necessary for results or discussion and their page

numbers may also be counted. The pager number may be typed at the right bottom of

each page. Default margins on the left, right, top and bottom of the page may be

provided as per the Microsoft Word.

Annexure - VIII

6.3 (g) Format for References : All the references should be typed in a uniform format containing all the details in

the order such as :

All the Authors’ names , “ Title of the article ”, Journal name, Volume number ( Issue

number ) Page numbers from – to ( Year )

335

APPENDIX - BA24

MANONMANIAM SUNDARANAR UNIVERSITY,TIRUNELVELI-12 M.Sc. Software Engineering

(Integrated course) 5 Year-Ten Semesters

(CBCS-For Colleges)

Syllabus (With Effect from 2012-13) SCHEME OF EXAMINATIONS

I Semester

Components Hours Credits

Part I

Tamil/Other Languages

6 3

Part II

English

6 3

Part III Core Subjects

Theory: PROGRAMMING METHODOLOGY AND C PROGRAMMING

Practical:C Programming Lab

6

4

4

4

Part III Allied Subject-I

Mathematics-I

6

5

Part IV

Environmental Studies

2

2

Total ( 6 Courses) 30 21

336

II Semester

Components Hours Credits

Part I

Tamil/Other Languages

6 3

Part II

English

6 3

Part III Core Subjects

Theory:Object Oriented Programming Using C++

Practical:C++ Programming Lab

6

4

4

4

Part III Allied Subject-I

Mathematics-II

6

5

Part IV

Value Based Education

2

2

Total ( 6 Courses) 30 21

III Semester

Components Hours Credits

Core Subjects

Computer Organization and Architecture

Data Structures and Algorithms

Data Structures and Algorithms Lab

6

6

6

5

5

4

Allied II

Applied Physics

6 4

Non Major Elective I

Skill based subject I

2

4(1 T+ 3 P)

2

2

Total ( 6 Courses) 30 22

337

IV Semester

Components Hours Credits

Core Subjects

System Analysis and Design

Java Programming

Java Programming Lab

6

6

6

5

5

4

Allied II

Digital Electronics

6 4

Non Major Elective II

Skill based subject II

2

4(1 T+ 3 P)

2

2

Total ( 6 Courses) 30 22

V Semester

Components Hours Credits

Core Subjects

Software Engineering

Operating System

Visual Basic

Resource Management Techniques

Part-IV

Skill-based Subject Common

Lab

Visual Basic Lab

5

5

5

5

4

6

5

5

5

5

4

4

Total ( 6 Courses) 30 28

338

VI Semester

Components Hours Credits

Core Subjects

Computer Graphics and Multimedia

Computer Networks and Data Communications

Relational Database Management System

Software Project Management

Lab

RDBMS Lab

Computer Graphics and Multimedia Lab

5

5

5

5

5

5

4

5

4

5

4

4

Total ( 6 Courses) 30 26

VII Semester

Components Hours Credits

Core Subjects

Compiler Design

Design and Analysis of Algorithms

Advanced Java Programming

Elective-2(Choose any ONE)

Probability and Statistics / Managerial

Accounting / E-Commerce

Lab

Algorithm Lab Using C Language

Advanced Java Lab

5

5

5

5

5

5

4

4

4

5

4

4

Total ( 6 Courses) 30 25

339

VIII Semester

Components Hours Credits

Core Subjects

Internet Programming

Object Oriented Systems Development using UML

Embedded System

Elective-2(Choose any ONE)

Multimedia Systems / Data Mining /

Web Technology

Lab

Internet Programming Lab

UML Lab

5

5

5

5

5

5

4

4

4

5

4

4

Total ( 6 Courses) 30 25

IX Semester

Components Hours Credits

Core Subjects

Digital Image Processing

Network Security and Cryptography

Software Quality Assurance and Testing

Elective-2(Choose any ONE)

Mobile Computing / Cloud Computing /

Artificial Neural Networks

Lab

Image Processing Lab

Mini Project

5

5

5

5

5

5

4

4

4

5

4

4

Total ( 6 Courses) 30 25

340

X Semester

Components Hours Credits

Major Project 15

Total ( 1 Course) 15

Each theory course shall carry an internal assessment component (External:Internal=75:25) Each practical course shall carry an internal assessment component (External:Internal=60:40) Internal Assessment

For Theory Course

The Average of the best two tests from three compulsory Tests-15 Marks

Assignment - 4 Marks

Seminar - 6 Marks

Total - 25 Marks

For Practical Course

Completion of Program List within the stipulated time - 20 Marks

Record - 10 Marks

Model Test - 10 Marks

Total - 40 Marks

V SEMESTER (Core Subject) SOFTWARE ENGINEERING

UNIT I

Introduction – Software Engineering Discipline – Evolution and Impact – Programs Vs Software Products – Emergence of Software Engineering – Changes in Software Development Practices – Computer Systems Engineering. Software Life Cycle Models: Use of a Life Cycle Models – Classical Waterfall Model –Iterative Waterfall Model – Prototyping Model – Evolutionary Model – Spiral Model. Software Project Management: Responsibilities of a Software Project Manager – Project Planning – Metrics for Project Size Estimation – Project Estimation Techniques –Risk Management – Software Configuration Management.

341

UNIT II

Requirements Analysis and Specification: Requirements Gathering and Analysis –Software Requirements Specification (SRS) – Formal System Development Techniques; Software Design: Characteristics of a Good Software Design – Cohesion and Coupling –Neat Arrangement – Software Design Approaches.

UNIT III

Function-Oriented Software Design: Overview of SA/SD Methodology – Structured Analysis – Data Flow Diagrams (DFDs) – Structured Design - Detailed Design – Design Review. Object Modeling Using UML: Overview of Object-Oriented Concepts – UML – UML Diagrams – Use Case Model – Class Diagrams – Interaction Diagrams – Activity Diagrams – State Chart Diagram.

UNIT IV

User Interface Design: Characteristics of a Good User Interface – Basic Concepts – Types of User Interfaces – Component-Based GUI Development; Coding and Testing: Coding – Testing – UNIT Testing – Black-Box Testing – White-Box Testing – Debugging –Integration Testing – System Testing.

UNIT V

Statistical Testing –Software Quality – Software Quality Management System – ISO 9000. Computer Aided Software Engineering: CASE Environment – CASE support in Software Life Cycle – Characteristics of CASE Tools –Architecture of a CASE Environment. Software Maintenance: Characteristics of Software Maintenance – Software Reverse Engineering – Software Maintenance Process Models – Estimation of Maintenance Cost; Software Reuse: Issues in any Reuse Program – Reuse Approach.

TEXT BOOK:

Fundamentals of Software Engineering - RAJIB MALL, Prentice Hall of India Learning Private Limited, 2008.

REFERENCE BOOK:

1. SOFTWARE ENGINEERING CONCEPTS, Richard Fairley, TMH. 2. OBJECT ORIENTED SOFTWARE ENGINEERING, Yogesh Singh,Ruchika

Makhotra, PHI Learning Private Limited 3. Software Engineering, Principles and Practices, Depak Jain, OXFORD University

Press

342

V SEMESTER (Core Subject) OPERATING SYSTEM

Unit I

Introduction: Operating System – Mainframe Systems – Desktop Systems – Multiprocessor Systems – Distributed Systems – Clustered Systems – Real-time Systems.

Operating System Structures: System Components – Operating-System Services – System Calls – System Programs – Virtual Machines.

Unit II

Processes: Process Concept – Process Scheduling – Operations on Processes – Cooperating Processes – Inter Process Communication.

CPU Scheduling: Basic Concepts – Scheduling Criteria – Scheduling Algorithms – Multiple Processor Scheduling – Real time Scheduling – Algorithm Evaluation.

Unit III

Process Synchronization: Background – Critical Section Problem – Semaphores – Classical Problems of Synchronization - Critical Regions – Atomic Transactions.

Deadlocks: System Model – Deadlock Characterization - Methods for Handling Deadlocks – Deadlock Prevention – Deadlock Avoidance – Deadlock Detection - Recovery from Deadlock.

Unit IV

Memory Management: Background – Swapping – Contiguous Memory Allocation – Paging – Segmentation – Segmentation with Paging.

Virtual Memory: Background – Demand Paging – Page Replacement – Allocation of Frames.

Unit V

File-System Interface: File Concept – Access Methods – Directory Structure

File System Implementation: File System Structure – Directory Implementation – Allocation Methods.

Mass Storage Structure: Disk Structure - Disk Scheduling.

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TEXT BOOK:

Operating System Concepts – Abraham Silberschartz , Peter Baer Galvin , and Greg Gange.

Addison Wesley Publishing Company – Sixth Edition.

REFERENCE BOOK:

1. Operating Systems: Internal and Design Principles – Fifth Edition, William Stalling ,PHI Learning Private Limited.

2. Understanding Operating Systems: Ida M. Flynn, Ann MclverMcHoes.

V SEMESTER (Core Subject)

RESOURCE MANAGEMENT TECHNIQUES

Unit I

Linear Programming Problem (LPP) - Mathematical Formulation of L.P.P- Simplex Method - Maximization.

Unit II

Game Theory- Mixed stragies- saddle point- Dominance Property- Graphical method- Method of solving 2xn game-Method of solving nx2 game- Application of L.P.P in Game theory.

Replacement Problem- Individual replacement- Groups replacement- model I Replacement of an item whose maintenance cost increases with time and money value is not changed.

Unit III

Queuing Theory- Poisson Process - Model I (M|M|1): ( ∞|FIFO) - Generalisation Model.

Unit IV

Inventory Control- Various Costs- Deterministic Model- Probabilistic or stochastic- Model I-Model II- No shortage- Model III with shortage- Newspaper boy problem.

Unit V

Network Analysis- CPM- Determination of Critical path and Project Duration- PERT- Time estimates- Variance for activities.

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TEXT BOOK:

Operations Research, P. R. Vital and V. Malini, Margham Publications.

REFERENCE BOOK:

1. Operations Research Principles and Practice, Pradeep Prabhakar Pai, OXFORD University Press. 2. Operations Research, R.Panneerselvam, PHI.

V SEMESTER (Core Subject)

VISUAL BASIC

Unit I

Getting started with Visual Basic 6.0: Introduction to Visual Basic - Visual Basic 6.0 Programming Environment – Working with Forms – Developing an Application – Variables, Data types and Modules – Procedures and Control Structures – Arrays in Visual Basic – Additional Examples.

Working with Controls: Introduction – Creating and using Controls – Working with Control Arrays – Additional Examples.

Unit II

Menus, Mouse Events and Dialog Boxes: Introduction – Mouse Events – Dialog Boxes - additional Examples.

Graphics, MDI, and Flex Grid: Introduction – Graphics for Applications – Multiple Document Interface (MDI) – Using the Flex Grid Control - Additional Examples.

Unit III

ODBC and Data Access Objects: Evolution of Computer Architectures – Data Access Options - Additional Examples.

ODBC using Data Access Objects and Remote Data Objects: Open Database Connectivity (ODBC) – Remote Data Objects – Additional Examples.

Unit IV

Data Environment and Data Report: Introduction – Data Environment Designer – Data Report - Additional Examples.

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Object Linking and Embedding: Introduction - OLE Fundamentals – Using OLE Container Controls – Using OLE Automation Objects - OLE Drag and Drop - Additional Examples.

Objects and Classes: Introduction to Objects – Working with Objects – Classes and Class Modules - Additional Examples.

Unit V

Built-In ActiveX Controls: Working with Built-In ActiveX Controls - Additional Examples.

Working with ActiveX Data Objects: An Overview of ADO and OLE DB – ADO Object Model - Additional Examples.

Files and File System Controls: Introduction – File System Controls – Accessing Files – Interface with Windows - Additional Examples.

Text Books:

Visual Basic 6.0 Programming – Content Development Group – Tata McGraw-Hill Publishing Company Limited, New Delhi.

Reference Books:

1. VISUAL BASIC 6 in Record Time by Steve Brown, BPB Publications. 2. VISUAL BASIC 6 from the Ground UP – GARY CORNELL – Tata McGraw Hill.

VISUAL BASIC - PRACTICAL LIST

Programs should include but not limited to: 1. Design an Analog Clock. 2. Design a Desktop Calculator. 3. Design Mixing of Colors using basic Colors. 4. Create an application to format the text inside the text box. 5. Create an application using File controls and use two option buttons to show and

hide a picture in the Picture box. 6. Create an application to do Matrix Addition using Flex Grid control. 7. Create an Editor with File and Edit Menus using Menu Editor Tool. 8. Create a MDI Application with tile and cascade child forms. 9. Create an application to implement OLE Drag and Drop. 10. Create a mailing address database in access `and view the records using Data

Control. 11. Create a student database application using ADO. 12. Create a student database in Access and prepare a Report using Data Report

Control.

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PART IV

Skill-based Subject Common

VI SEMESTER (Core Subject)

SOFTWARE PROJECT MANAGEMENT

UNIT I

Introduction – Importance of Software Project Management – Project – Software Project Vs Other types of Project – Contract Management and Technical Project Management – Activities covered by Software Project Management – Plans, Methods and Methodologies – Categorizing Software Projects –Setting Objectives – Stake holders – Business Case – Requirement specification – Management control. Step wise: An overview of Project Planning: Introduction – Ten steps. Programme management and project evaluation: Introduction – Programme management – Managing the allocation of resources within programmes – Strategic Programme management – Creating a Programme – Aids to Programme management – Benefits Management – Evaluation of Individual Projects – Technical Assessment – Cost Benefit Analysis – Cash Flow forecasting – Cost Benefit Evaluation Techniques – Risk Evaluation.

UNIT II

Selection of an appropriate project approach: Introduction – Choosing Technologies – Technical plan contents list – Choice of process models – Structure Vs Speed of delivery – The Waterfall model – The V-Process Model – The Spiral Model – Software Prototyping – Other ways of categorizing prototypes – Incremental Delivery – Dynamic Systems Development method – Extreme Programming – Managing iterative processes – Selecting the most appropriate process model.

Software Cost Estimation: Introduction – Where are estimates done? – Problems with over and under estimates – Basis for software estimating – Software effort estimation techniques – Expert Judgement – Estimating by analogy – Albrecht function point analysis – Function points Mark II – COSMIC Full function points – A Procedure code oriented approach – COCOMO: a Parametric model

UNIT III

Activity Planning: An Introduction – Objectives of Activity Planning – When to plan – Project Schedules – Projects & Activities – Sequencing and scheduling activities – Network planning models – Formulating a network model – Adding the time dimension

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– The forward pass – The backward pass – Identifying the critical path – Activity float – Shortening the project duration – Identifying critical activities – Activity on arrow networks.

Risk Management: Introduction – Risk – Categories of Risk – A framework for dealing with this – Risk Identification – Risk Assessment – Risk Planning – Risk Management – Evaluating risks to the schedule – Applying the PERT Technique – Mote Carlo simulation – Critical Chain concepts.

Resource Allocation: Introduction – The Nature of Resources – Identifying resource requirements – Scheduling resources – Creating Critical paths – Counting the cost – Being specific – Publishing the resource schedule – Cost Schedule – The Scheduling Sequence.

UNIT IV

Monitoring and Control: Introduction – Creating the framework – Collecting the data – Visualizing Progress – Cost Monitoring – Earned Value Analysis – Prioritizing monitoring – Getting the project back to target – Change control.

Managing Contracts: Introduction – ISO 12207 approach to the acquisition and supply of software – The supply process – Type of contract – Stages in Contract placement – Typical terms of a contract – Contract Management – Acceptance.

UNIT V

Managing people and Organizing terms: Introduction – Understanding Behavior – Organizational Behavior: a background – Selecting the right person for the job – Instruction in the best methods – Motivation – The Oldham-Hackman job characteristics model – Working in groups – Working in groups – Becoming a team – Decision making – Leadership – Organizational Structures – Dispersed and Virtual team – The influence of culture – Stress – Health & Safety.

Software Quality: Introduction – The place of Software quality in project planning – The importance of software quality – Defining Software quality – ISO 9126 – Practical Software Quality Measures – Product Vs Process Software quality management – External Standards – Techniques to help enhance software quality – Quality Plans.

TEXT BOOK: Software Project Management, Bob Hughes and mike Cotterell, Tata Mc Grawhill , Fourth edition, 2006. REFERENCE BOOK: Software Project Management, A Concise Study, S.A.Kelkar, PHI, 2007

348

VI SEMESTER (Core Subject) COMPUTER GRAPHICS AND MULTIMEDIA

Unit I

Overview of Graphics System: Video Display Devices – Input Devices - Hard Copy Devices – Graphics Software.

Output Primitives: Points and Lines –Line drawing algorithms – DDA algorithm- Bresenham’s line algorithm- Circle drawing algorithms: properties of circles – Midpoint circle algorithm – Filled Area primitives.

Unit II

Attributes of Output Primitives: Line attributes – Curve attributes – Character attributes.

Two-Dimensional Geometric Transformation: Basic Transformations – Matrix Representations and homogenous co-ordinates – Composite and other Transformations.

Unit III

Two-Dimensional Viewing: The viewing pipeline, Viewing co-ordinate reference frame – Window to view port co-ordinate transformation – Two-dimensional viewing function.

Clipping Operations: Point clipping – Line clipping (only Cohen-Sutherland line clipping) – Polygon Clipping (only Sutherland-Hodgeman polygon clipping).

Unit IV

Interactive Input Methods: Input of graphical data – Input functions – Three dimensional display methods.

Three Dimensional Viewing: Projections. Visible surface deduction methods: Back- face deduction – Depth buffer method.

Unit V

Multimedia Introduction: What is Multimedia? – Hardware components of a Multimedia system.

Multimedia Elements: Text and Graphics – Sound – Animation – Video – Issues and trends in Multimedia.

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TEXT BOOK:

1. Computer Graphics, Second Edition, Donald Hearn, M.Pauline Baker, Pearson Publications

2. Multimedia in Action, James E. Shumman, Vikas Publishing House, Chapters 1 to 4 and 12.

REFERENCE BOOK:

1. Computer Graphics, Apurva Desai, Prentice Hall of India, 2012 2. Principles of Interactive Graphics, William M. Newman, Robert F.Sproull 1979,

McGraw Hill. 3. Desk top Multimedia Bible, Burger 1993, Addison Wesley. 4. Prabhat Andleigh, Kiran Thakrar, Multimedia System and Design, Prentice Hall of

India, 2000.

VI SEMESTER (Core Subject) RELATIONAL DATA BASE MANAGEMENT SYSTEM

UNIT I

Introduction: Database - System applications-Purpose of Database Systems - View of

Data-Database languages -Relational Databases - Database Design - Data Storage

and Querying - Transaction Management - Database Architecture - Data Mining and

Information Retrieval-Specialty Databases - Database Users and Administrators

UNIT II

Introduction to the Relational Model and Introduction to SQL- Structure of Relational

Databases -Database Schema-Keys-Schema Diagrams-Relational Query Languages-

Relational Operations- Overview of the SQL Query Language -SQL Data Definition-

Basic Structure of SQL Queries

UNIT III

SQL operations and Intermediate SQL Additional Basic Operations-Set Operations-Null

values-Aggregate functions-Nested Subqueries-Join Expressions – Views -

Transactions-Integrity Constraints - SQL Data Types and Schemas-Authorization

350

UNIT IV

E-R Model and Relational Database Design:E-R Model-Overview of the Design

Process-The Entity-Relationship model - Constraints - Removing Redundant Attributes

in Entity Sets-Entity – Relationship Diagrams-Reduction to Relational Schemas-Entity-

Relationship Design Issues-Extended E-R Features

Features of Good Relational Designs-Atomic Domains and First Normal Form-

Decomposition Using Functional Dependencies-Functional –-Decomposition using

Multivalued Dependencies-More Normal Forms

UNIT V

Implementation using Oracle:Creating Table-Modifying Table-Creating SEQUENCE-

creating Views-PL/SQL-triggers Stored procedures and Functions-packages-cursors

TEXT BOOK: 1. Database System Concepts – Abraham Silberschalz, Henry F.Horth and S.Sudarashan, McGraw-Hill International Sixth Edition. 2. Oracle8i Jose A.Ramalho BPB Publications

REFERENCE BOOK: 1. Database Management Systems, R.Panneerselvam, PHI Learning Private Limited 2.Database Management Systems, Ramakrishnan and Gehrke, Mc Graw Hill Publications

VI SEMESTER (Core Subject) COMPUTER NETWORKS AND DATA COMMUNICATIONS

Unit I

Basic model of Data Communication system – Data Representation – data Transmission – Modes of Data Transmission – Digital Signal Encoding – Unipolar and Polar Line Codes – Bipolar Line Codes – Block Codes – Frequency spectrum - Transmission Channel –Data Compression – Data Communication.

Transmission Line Characteristics – Linear Distortions – Metallic Media – Optical Fibre – Radio Media – Baseband Transmission of Data Signals.

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Unit II

Transmission Errors – Coding for Detection and Correction of content Errors – Error Detection Methods – Forward Error Correction Methods – Reverse Error Correction.

Topology of a Computer Network – Elements of Meaningful Communication - Transport-Oriented Functions – Components of a Computer Network – Architecture of a Computer Network – Layered Architecture of a Computer Network – Open System Interconnection – Layered Architecture of the OSI Reference Model – Functionality of the Layered Architecture – OSI Terminology – Service Interface – Data Transfer Modes – Supplementary Functions – Other Layered Architectures.

Unit III

The Physical Layer – Functions within the Physical Layer – Relaying Function in the Physical Layer – Physical Interface – Physical Layer Standards.

Need for Data Link Control –Data Link Layer – Frame Design Considerations – Flow Control Mechanism – Data Link Error Control.

Binary Synchronous Communication Data Link Protocol -Transmission Frame – Protocol Operation.

Unit IV

Need for Local Area Networks –Lan Topologies - Media Access Control – Layered Architecture of LAN – IEEE Standards – LLC Sublayer – MAC Sublayer – Transmission Media for LANs.

Contention Access - Carrier Sense Multiple Access – CSMA/CD – Physical Topology of Ethernet LAN – Ethernet Repeater - Types of Ethernets – 10 Mbps Ethernets – Fast Ethernet – Flow Control –Auto Negotiation – Gigabit Ethernet

Unit V

Security Requirements – Cryptography Algorithms – Algorithms for Confidentiality - Algorithms for Integrity –Basic Authentication Mechanisms – Mechanisms for Ensuring Message Integrity – Digital Signature – Management of Public Keys Through Third Parties – Transport Layer Security –IP Security – Firewalls.

TEXT BOOK:

“DATA COMMUNICATIONS AND COMPUTER NETWORKS “–PRAKASH C. GUPTA – PHI - 2011.

352

Reference Books: 1. Data Communications and Networking, Behrouz A Forouzan, 4th Edition,

McGraw Hill. 2. Computers Networks, Andrew S. Tanenbaum, 4th Edition, PHI. 3. Computer Networks, Brijendra Singh, Third Edition, PHI 4. Computer Networks, Bhushan Trivedi, OXFORD University Press

COMPUTER GRAPHICS AND MULTIMEDIA –PRACTICAL LIST

Programs should include but not limited to: 1 Write a program to translate an image 2 Write a program to rotate an image 3 Write a program to scale an image 4 Write a program to draw a line using DDA Algorithm 5 Write a program to draw a line using Bresenham’s Algorithm 6 Write a program to draw a circle using Bresenham’s Algorithm 7 Write a program to titled or cascade a image according user option 8 Write a program to display an image as size of screen ,then reduces its size until

disappears 9 Write a program to drop a word by word of a sentence from top 10 Write a program to display a news headlines letter by letter 11 Write a program to display as many as balls at random positions 12 Write a program to display a bouncing ball and moving with sound effect

RDBMS – PRACTICAL LIST Programs should include but not limited to:

1. Create an employee database with tables department, employee details, address, pay details and project details. Alter the tables and add constraints relevant to the fields in the tables. Insert records into all the tables.

2. Create queries to retrieve relevant information from a table. 3. Create a table from the existing tables. Create views from the tables. 4. Develop queries to retrieve information from more than one table. Develop

summary queries to retrieve relevant information from the tables. 5. Create a partition table and query the records. 6. Create the table with abstract data type and query the records. 7. Write a PL/SQL program to print multiplication table 8. Write a PL/SQL program to check whether given string is palindrome or not 9. Write a PL/SQL program to print student details using Report 10. Create a procedure to calculate Electricity bill ( use cursor ) 11. Write a PL/SQL program to perform updation using various triggers 12. Write a PL/SQL program to find factorial of numbers using function and

procedure.

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VII SEMESTER (Core Subject) COMPILER DESIGN

UNIT-I Compiler - Phases of Compiler – Compiler writing tools – Lexical Analysis – Role of

Lexical analyzer – specification and reorganization of tokens -Finite Automata – Regular

Expression – From a Regular expression to an NFA , NFA to DFA – Design of Lexical

Analyzer.

UNIT - II

Syntax Analyzer – CFG – Role of the Parser – CFG – Top Down Parsing – Recursive

descent parsing, predictive Parsers – Bottom up Parsing – Shift reduce, operator

precedence parsers, LR Parsers.

UNIT -III

Syntax directed definition : Construction of Syntax trees – Intermediate code generation

: Intermediate Languages – Syntax trees, post fix form, Three address code – Boolean

expressions – Back Patching.

UNIT - IV

Symbol table – contents of Symbol table – Data Structures for Symbol table – Runtime

storage Administration – Implementation of Stack allocation scheme block structured

Languages – Storage allocation in Fortran.

UNIT -V Code Optimization and code generation – principles sources of optimization – loop

optimization – DAG Representation of Basic blocks. Code generation – problems in

code generation – a simple code generator – Register allocation and Assignment –

Peephole optimization.

TEXT BOOKS : 1. Alfred V.Aho, Ravi Sethi, Jeffrey D.Ullman Compilers Principles, Techniques and

Tools,., Pearson Eduction, 2nd Edition , 2008

2. Alfred V.Aho and Jeffrey D.Ullman ,Principles of Compiler Design ,.

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VII SEMESTER (Core Subject) DESIGN AND ANALYSIS OF ALGORITHMS

UNIT-I Introduction - Algorithm - Specification - Performance Analysis

Elementary Data Structures – Stacks and Queues - Trees – Dictionaries-Priority

Queues

UNIT-II Divide and Conquer – General Method – Binary Search – Finding the maximum and

minimum – Quick Sort – Strassen’s matrix multiplication.

The Greedy Method - General Method - Knapsack Problem – Job Sequencing with

deadlines – Minimum-cost spanning Trees- Single-Source Shortest Paths

UNIT-III Dynamic Programming – General Method – Multistage Graphs – All pairs shortest

paths- Binary Search Tree. 0/1/Knapsack –Reliability Design-Travelling Salesperson

Problem

Basic Traversal and Search Techniques –Techniques for Binary Trees - Graphs -

Connected Components and Spanning Trees - Biconnected Components.

UNIT-IV Backtracking - General Method - 8 Queens Problem - Graph Coloring-Hamiltonian

Cycles

Branch and Bound - Method - 0/1 Knapsack Problem

UNIT-V NP-Hard and NP-Complete Problem - Basic Concepts - Cooke’s Theorem - NP-Hard

Problems - Clique Decision Problem - Job Shop Scheduling - Code generation with

Common Sub expressions - Approximation Algorithms - Introduction - Absolute

Approximations – ε-Approximations

Text Book: Ellis Horowitz, Sartaj Sahni and Sanguthevar Rajasekaran, “Fundamentals of

Computer Algorithms”, 2nd Edition,Universities Press(India) Private Ltd., 2008

355

Reference Books:

1. Sara Baase and Allen Van Gelde, “Computer Algorithms, Introduction to Design and Analysis”, 3rd Edition, Pearson Education, Delhi, 2002. 2. Aho, Hoporoft and Ullman, “The Design and Analysis of Computer Algorithm”, Pearson Education, Delhi, 2001. 3. Basu S.K.,”Design Methods and Analysis of Algorithms”, PHI, 2006. 4. Brassad and Bratley,”Fundamentals of Algorithms”, PHI, 1995.

VII SEMESTER (Core Subject)

Advanced Java Programming

UNIT I Abstract Windows Toolkit (AWT)-I: Introduction-Events- Listeners-Event Handling

Methods- Interfaces, Controls such as Label, Button, Checkbox, Radiobutton, Choice,

List, Scrollbar-Layout Manager

Abstract Windows Toolkit (AWT)-II:Introduction-Windows and Frames-Menus-Dialogs-

MouseEvent and their listeners-Adapter classes-Inner classes-Anonymous Inner

classes

Swing:Introduction-JApplet-Icons-Jalbel-JButton-JTextField-JCheckbox-JRadioButton-

JMenu

UNIT II

RMI:Introduction-Remote Interface-java.rmi.Server package-Naming Class-

RMIException-Creating a simple RMI Client and Server application

JDBC: Java database connectivity, Types of JDBC drivers, Writing JDBC applications,

Types of statement objects( Statement, PreparedStatement and CallableStatement),

Types of resultset, Inserting and updating records,Using Transactions

UNIT III

Java Beans:

An Overview of JavaBeans:Background-Software Components-Properties,Events and

Methods-Introspection and Builder Tools-BDK-The Benefits of Java Components

356

Building Simple Beans:Your First Bean-Introspection and Naming convention-Difference

between a Bean and other class

UNIT IV

Java Servlets: Java Servlets and CGI Programming-A Simple Java Servlet-Anatomy of

a Java Servlet-Reading Data from a Client-Sending Data to a Client-Working with

Cookies-Tracking Sessions.

Java Server Pages:JSP-JSP tags-Tomcat-Request String-User Sessions-Cookies-

Session Objects

UNIT V

Server Side Component Architecture – Introduction to J2EE – Session Beans – Entity

Beans – Persistent Entity Beans – Transactions.

Reference Books:- 1 Ed Roman, “Mastering Enterprise Java Beans”, John Wiley & Sons Inc., 1999.

2. Patrick Naughton, “COMPLETE REFERENCE: JAVA2”, Tata McGraw-Hill, 2003.

3.. Herbert Schildt, “The Complete Reference”, Seventh Edition, [TMH]

4..Joseph O’Neil, “JavaBeans Programming”, TMH

5.Jim Keogh,”The Complete Reference J2EE”,TMH

6. C.Muthu,” Programming with Java”, Second Edition, VNI.

VII SEMESTER (Elective Subject)

MANAGERIAL ACCOUNTING

UNIT - I Accounting: Definition – Objectives - Branches of Accounting - Accounting Concepts

and Conventions - Groups Interested in Accounting Information - Accounting Rules –

Journal - Ledger - Trial Balance – Preparation Final Accounts of Sole Trading

Concerns.

357

UNIT -II Analysis and Interpretation of Financial Statements: Tools used - Comparative

Statement - Common Size Statement and Trend Percentage. Ratio Analysis: Meaning -

Advantages and Limitations - Classification of Ratios – Solvency – Profitability - Activity

and Capital Structure Ratios. UNIT - III Fund Flow Analysis: Concept of Funds - Fund Flow Statement - Uses and Limitation -

Preparation of Fund Flow Statement. Cash Flow Analysis: Computation of Cash from

operation and Preparation of Cash Flow Statement.

UNIT - IV Rate o Budget and Budgetary Control: Meaning – Advantages and limitations -

Classification of Budgets - Preparation of Production - Sales - Cash and Flexible

Budgets. Capital Budget: Meaning and Importance - Methods of Ranking Investment

Proposals - Pay-Back - Average f Return and Discounted Cash Flow Methods.

UNIT - V Marginal Costing: Meaning - Advantages and Uses - Cost Volume - Profit Analysis -

Break-even Concept - Uses and Assumptions - Decisions Involving Alternative Choices.

TEXT BOOKS: 1. Shukla M.C. & Grewal T.S., Advanced Accounts , 1991, S.Chand, (Unit I)

2. Dr.S.N.Maheswari, Principles of Management Accounting , Sultan Chand &

sons,2005.(Unit II to Unit V)

REFERENCE BOOKS: 1. S.P.Jain & K.L.Narang, Advanced Accountancy – Part-I , Kalyani, Publishers,1991.

2. Gupta R.L.& Radhasamy M., Advanced Accounts (Vol.II) , S.Chand, 1991.

3. R.K.Sharma & Shasi K.Gupta, Management Accounting – Principles And Pratices ,

Kalyani publishers, 1992.

4. Man mohan & S.N.Goyal, Principles Of Management Accounting , Agra, Sahithya

Bhawan, 1987.

5. Hingorani N.L. & Ramanathan A.R., Management Accounting , S. Chand, Edn.2,

1982.

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VII SEMESTER (Elective Subject)

Probability and Statistics

Unit-1 Basics of statistics - Measures of central tendency - Measures of dispersion - Moments

- skewness and kurtosis-Probability-Addition and Multiplication Theorems-Conditional

Probabilities-Bayes’ Theorem-Mathematical Expectation.

Unit-2 Theoretical Distributions: Distribution function-Binomial, Poisson, Normal, Uniform and

Gamma Distributions-Basic Properties and application problems on these distributions

Unit-3 Concept of Sampling - Nature of distribution and sample means-Testing of Hypothesis-

Null hypothesis-Types of Errors-Levels of Significance-Confidence intervals-Theory of

Estimation-Properties of good estimator-Method of estimation.

Unit-4 Correlation - Rank correlation - Fitting of curves - Regression coefficients - Regression

lines-Forecasting through regression lines.

Unit-5 Time Series: Meaning and Importance-Trend-Seasonal variation-Cyclical variation-

Analysis of time series-Method of semi-averages-Method of moving averages-

Measurement of seasonal variations.

Reference Books: 1. Trivedi.K.S., Probability and Statistics with Reliability,Queuing and Computer Science

Applications, Prentice Hall of India.

2. S.K. Gupta and P.K.kappor,Mathematical Statistics,Chand & Co.

359

VII SEMESTER (Elective Subject)

E-Commerce

UNIT-I INTRODUCTION Networks and Commercial Transactions - Internet and Other Novelties - Electronic

Transactions Today - Commercial Transactions - Establishing Trust - Internet

Environment - Internet Advantage - World Wide Web.

UNIT-II SECURITY TECHNOLOGIES Why Internet is Unsecure - Internet Security Holes - Cryptography : Objective - Codes

and Ciphers - Breaking Encryption Schemes - Data Encryption Standard - Trusted Key

Distribution and Verification - Cryptographic Applications - Encryption - Digital Signature

- Nonrepudiation and Message Integrity.

UNIT- III ELECTRONIC PAYMENT METHODS Traditional Transactions : Updating - Offline and Online Transactions - Secure Web

Servers - Required Facilities - Digital Currencies and Payment Systems - Protocols for

the Public Transport - Security Protocols - SET - Credit Card Business Basics.

UNIT- IV ELECTRONIC COMMERCE PROVIDERS Online Commerce Options - Functions and Features - Payment Systems : Electronic,

Digital and Virtual Internet Payment System - Account Setup and Costs - Virtual

Transaction Process - InfoHaus - Security Considerations – CyberCash: Model -

Security - Customer Protection - Client Application - Selling through CyberCash.

UNIT-V ONLINE COMMERCE ENVIRONMENTS Servers and Commercial Environments - Payment Methods - Server Market Orientation

- Netscape Commerce Server - Microsoft Internet Servers - Digital Currencies -

DigiCash - Using Ecash - Ecash Client Software and Implementation - Smart Cards -

The Chip - Electronic Data Interchange - Internet Strategies, Techniques and Tools.

TEXT BOOKS 1. Pete Loshin, “Electronic Commerce”, 4th Edition, Firewall media, An imprint of

Laxmi Publications Pvt. Ltd., New Delhi, 2004.

2. Ravi Kalakota , Andrew B.Winston, “E-Commerce” Pearson Education, 2004.

360

REFERENCES 1. Jeffrey F.Rayport and Bernard J. Jaworski, “Introduction to E-Commerce”, 2nd

Edition, Tata Mc-Graw Hill Pvt., Ltd., 2003.

2 P.T. Joseph, “E-Commerce – A Managerial Perspective”, PHI, 2003.

3. Greenstein, "Electronic Commerce", Tata Mc-Graw Hill Pvt., Ltd., 2000.

Algorithm Lab Using C Language–Practical List

Programs should include but not limited to: 1. Write a program that implements Stacks and Queues

2.Write a program that implements Priority Queue

3.Write a program that implements Binary Search

4.Write a program that implements Quick Sort

5.Write a program that implements Strassen’s matrix multiplication

6.Write a program that implements Prim’s Algorithm

7.Write a program that implements Kruskal’s Algorithm

8. Write a program that implements All pair shortest path problem

9. Write a program that implements N-Queen Problem

10. Write a program that implements BFS

11. Write a program that implements DFS

12. Write a program that implements Travelling Salesperson Problem

13. Write a program that implements knapsack using greedy

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Advanced Java – PRACTICAL LIST

Programs should include but not limited to: 1. Write a java applet program using AWT-I components(Using EventHandling)

2. Write a java applet program using AWT-II components(Using EventHandling)

3. Write a java applet program using swing components(Using EventHandling)

4.. Write a program in Java to implement a Client/Server application using RMI.

5. Write a program in Java to implement JDBC connection process.

6. Write a program in Java to insert, update, delete, display records

7. Write a program in java servlet to create a form and validate a password.

8. Write a program in Java Servlet to create and display cookies

9. Write a program in JSP to create a form and validate a password.

10.Write a program in JSP to implement session handling.

11. Develop a simple Java Bean.

12. Develop a simple EJB bean

VIII SEMESTER (Core Subject)

Internet Programming Unit-I Introduction Introduction to Internet, Web Client/Server Model, Components of .NET Framework,

Overview of IIS ,Web Forms, Common Language Runtime and Class Library, Managed

Components, Web Services, COM+ Component services.

Unit-II Crash Course in VB.NET Data Types, Arrays, Functions, Flow Control, Exception Handling, Constructors and

Destructors, Class Properties, Inheritance, Polymorphism, Interfaces, Implementing

polymorphism using Interfaces, Multithreaded Programming.

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Unit-III Essentials ASP.NET History of ASP.NET, Introduction to ASP.NET, Working with web forms, Directory

structure in ASP.NET, ASP.NET Compilation Model, Code Behind Model, Working with

Web form controls, HTML Server Controls, Validation Controls, Validation Groups,

Calendar and Ad Rotator control. Unit-IV ASP.NET Intrinsic Objects HTTPRequest Object, HTTPResponse Object, HTTPServerUtility Object,

HTTPApplicationState Object, HTTPSessionState Object, ObjectContext Object Unit-V

Data Access with ADO.NET What are Databases? Working with ADO.NET, Overview of ADO.NET Objects, Using

Basic SQL, Working with Connection Object, Command Object, DataAdapter Object,

DataSet Object, DataReader Object, DataTable Object, DataRow Object, DataColoumn

Object, DataRelation Object. Reference Books: 1 Crouch Matt J, “ASP.NET and VB.NET Web Programming”, Addison Wesley 2002.

2. Mathew Mac Donald,”ASP.NET Complete Reference “, TMH 2005.

3 Steven Holzner ,”Visual Basic Programming 2005 Black Book”, Dreamtech Press.

4. J.Liberty, D.Hurwitz, Programming ASP.NET, Third Edition, O’REILLY, 2006.

VIII SEMESTER (Core Subject)

Object Oriented Systems Development using UML

UNIT-I Structured approach to system construction: - An overview of object oriented systems

development & Life cycle –Object basics-OOD Life cycle

UNIT-II Various object oriented methodologies – Introduction to UML

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UNIT-III Object oriented analysis – Use cases- Object classification, Identifying object

relationships, attributes, methods

UNIT-IV Object oriented design – Design axioms – Designing classes – Access Layer-View

Layer

UNIT-V Software Quality Assurance-System Usability and Measuring User satisfaction.

TEXT BOOK: 1. Ali Bahrami, “Object Oriented Systems Development using UML”, Tata McGraw-Hill

Education Private Limited, 2008

Reference Book: 1. Simon Bennett, Steve Mcrobble and Ray Farmer,”Object-Oriented Systems Analysis

and Design using UML”,Third Edition-McGraw-Hill Education Private limited,2006 VIII SEMESTER (Core Subject)

Embedded System UNIT-I Introduction: Overview of dedicated and automated systems - their specific

requirements - robust design - environmental issues - temporal constraints -

technological constraints - software systems - product design cycle.

UNIT-II Development of a System Specification: Evaluation - justification of the available levels

of system integration (custom chip design through turnkey - systems) - technological

choice.

UNIT-III Software Issues: Development environment compilers - linkers - debuggers - emulators

- real time operating systems - kernels - Designing and implementing code for dedicated

systems.

UNIT-IV Hardware Issues: Choice of processor - I/O - memory - speed integration - development

facilities - economics - DSP devices.

364

UNIT-V Transducers: Sensors for measuring physical phenomena - output devices such as

power actuators - motors. Data transformation - signal conditioning - data conversion.

The impact of EMC regulations on design practice. Text Book: Heath S. “Embedded Systems Design”, Elsevier, 1997.

References: 1. Kirk Zurell - “C Programming for Embedded Systems” R & D Books - 2000

2. David. E, Simon, “An embedded software primer”, PHI/Pearson Education, 2001.

3. Michael Barr, “Programming Embedded Systems in C and C++”, Shroff Publishers &

Distributors Pvt.Ltd., Calcutta, 2001.

4. Raj Kamal, “Embedded systems architecture, programming and design”, TMG, 2007

VIII SEMESTER (Elective Subject)

DATA MINING Unit-I

Introduction:Basic Data Mining Tasks-Data Mining Versus Knowledge Discovery in

Databases-Data Mining Issues-Data Mining Metrics-Social Implication of Data Mining-

Data Mining from a Database Perspective

Data Mining Techniques:A Statistical Perspective on Data Mining-Similarity Measures-

Decision Trees-Neural Networks-Genetic Algorithms

Unit-II

Classification:Introduction-Statistical-Based Algorithms-Distance-Based Algorithms-

Decision Tree-Based Algorithms-Neural Network-Based Algorithms-Rule-Based

Algorithms-Combining Techniques

365

Unit-III

Clustering:Introduction-Similarity and Distance Measures-Outliers-Hierarchical

Algorithms-Partitional Algorithms-Clustering Large Databases-Clustering with

Categorical Attributes

Unit-IV

Association Rules:Introduction-Large Itemsets-Basic Algorithms-Parallel and Distributed

Algorithms-Comparing Approaches-Incremental rules-Advanced Association Rule

Techniques-Measuring the Quality of Rules

Unit -V

Web Mining:Introduction-Web content Mining-Web Structure Mining-Web Usage Mining

Spatial Mining:Introduction-Spatial Data Overview-Spatial Data Mining Primitives-

Generalization and Specialization-Spatial rules-Spatial Classification Algorithms-Spatial

Clustering Algorithms

Text Book:

1. Marget H.Dunham,”Data Mining Introductory and Advanced Concepts”,Pearson

Education 2003

Reference Book:

1. Data Mining Concepts & Technologies, Jiawei Han, Micheline Kamber, Morgan Kaufmann, Second Edition, 2005.

2. Data Mining, Vikram Pudi, P.Radha Krishna, OxfordUniversity Press, First Edition,

2009.

3. Data Warehousing – Reema Thareja Oxford University Press – 2009.

4. Insight into Data Mining Theory and Practice – K.P. Soman, Shyam Diwakar, V.Ajay, Prentice Hall of India – 2008.

366

VIII SEMESTER (Elective Subject)

WEB TECHNOLOGY

Unit I

Introduction: What is the Internet-History of Internet-Internet Services and Accessibility-

Uses of the Internet-Protocols-Web concepts-The client/server model at the web-

Retrieving data from the web. Internet Protocols: Introduction – Internet protocols-

transmission control protocols-User Datagram protocols - Host Names - Internet

applications and application protocols.

Unit II

HTML: Introduction-SGML-DTD-DTD Elements- attributes-outline of an HTML

document-Head section-Body section-HTML forms-Dynamic HTML: Introduction-

cascading style sheets-DHTML Document object model and collections-Event handling

- filters and transitions.

Unit III

Javascript: Introduction-language elements-objects of Javascript-other objects-Arrays.

VBScript: Introduction-embedding VBScript code in an HTML document-comments-

variables-operators-procedures-conditional statements-looping constructs-objects &

VBScripts-Cookies.

Unit IV

Introducing PHP & MYSQL: Features of PHP & MYSQL- Architecture- sample

application-using valuables, statements & operators: Embedding PHP in HTML-

statement & comments-storing values in variables-simple data types-various operators

to manipulate & compare variables-operator precedence.

367

Unit V

Conditional statement & loops: conditional statements-merging forms-Repeating actions

with loops: while(), do(), for() loop-break & continue.

Arrays & custom functions: Create Array-modify array element-processing array with

loops-Grouping form selections with arrays-using array functions.

TEXT BOOK:

1. Web Technology, N.P Gopalan, J.Akilandeswari, PHI,2009

2. How to do Everything with PHP & MYSQL, Vikram Vaswans, Tata MCGraw-Hill 2005.

REFERENCE BOOK:

Web Technology, S. Padma Priya, SCITECH Publications (India) Pvt. Ltd.

VIII SEMESTER (Elective Subject)

MULTIMEDIA SYSTEMS Unit-I Defining the scope of multimedia, Hypertext and Collaborative research, Multimedia and

personalised computing, Multimedia on the map, Emerging applications, The challenges

The convergence of computers, Communications, and entertainment products The

technology trends, Multimedia appliances, Hybrid Devices, Designers perspective,

industry perspective of the future, Key challenges ahead, Technical, regulatory, Social

Architectures and issues for Distributed Multimedia systems Distributed Multimedia

systems, Synchronization, and QOS Architecture, The role of Standards, A frame work

for Multimedia systems.

Unit-II Digital Audio Representation and processing: Uses of Audio in Computer Applications,

Psychoacoustics, Digital representation of sound, transmission of digital sound, Digital

Audio signal processing, Digital music making, Speech recognition and generation,

digital audio and the computers Video Technology:Raster Scanning Principles, Sensors

368

for TV Cameras, Colour Fundamentals, Colour Video,Video performance

Measurements, Analog video Artifacts, video equipments, World wide television

standards Digital Video and Image Compression Video compression techniques,

standardization of Algorithm, The JPEG Image Compression Standard, ITU-T

Recommendations, The EPEG Motion Video Compression Standard, DVI Technology

Unit-III Operating System Support for Continuous Media Applications: Limitation of Work

station Operating system, New OS support, Experiments Using Real Time Mach

Middleware System Services Architecture:Goals of Multimedia System services,

Multimedia system services Architecture, Media stream protocol Multimedia Devices,

Presentation Services, and the User Interface:Client control of continuous multimedia,

Device control, Temporal coordination and composition, toolkits, hyper applications

Multimedia File systems and Information Models:The case for multimedia information

systems, The file system support for continuous Media,Data models for multimedia and

Hypermedia information, Content- based Retrieval of Unstructured Data Multimedia

presentation and Authoring: Design paradigms and User interface, barriers to wide

spread use, research trends

Unit-IV

Multimedia Services over the Public Networks: Requirements, Architecture, and

protocols, Net work services, applications Multimedia Interchange Quick time Movie File

Format, QMFI, MHEG (Multimedia and Hypermedia Information Encoding Expert

Group), Format Function and representation, Track model and Object model, Real Time

Interchange Multimedia conferencing Teleconferencing Systems, Requirements of

Multimedia Communications, Shared Application Architecture and embedded

Distributed objects, Multimedia Conferencing Architecture Multimedia Groupware :

Computer and Video fusion approach to open shared workspace

Unit-V High Definition Television and desktop computing, Video versus Computing-Viewing

Conditions-Quality-HDTV,ATV,EDTV,IDTV-HDTV Standards – Standardization Issues

HDTV standards, Knowledge based Multimedia systems, Anatomy of an Intelligent

Multimedia system

369

Text Book: John F.Koegel Buford, Multimedia Systems, Pearson Education 2012

Reference Book: 1.Tay Vaughan,Multimedia – Making it work,Fifth Edition,TMH 2003

2.Ralf Steinmetz and Klara Nahrstedt,Multimedia:Computing , Communication and

Application Pearson Education 2009

Internet Programming –Practical List Programs should include but not limited to: 1. Write a program to change the background color using RGB ()

2. Write a program to implement Currency Converter

3. Write a program to demonstrate Event Tracker

4. Write a program using file uploading control

5. Write a program to create a registration page using validation controls

6. Write a program using Session State and Application State variables

7. Write a program using QueryString and Cookies

8. Write a program using DataGrid and DataList controls

9. Write a program to search and store student data in MSAccess

10. Write a program to save customer information and generate electricity bill using

SQL Server

11. Write a program to demonstrate the use of Session.TimeOut

370

UML –Practical List (Use UML Tools)

Programs should include but not limited to: 1) Draw the Use Cases and define all the classes for Automatic Teller Machine

1) Draw the Use Cases and define all the classes for Employee Management System.

3) Draw the Use Cases and define all the classes for Library Management System.

4) Draw the Use Cases and define all the classes for Bus Reservation System.

5) Draw the Sequence and Collaboration diagrams for Automatic Teller Machine.

6) Draw the Sequence and Collaboration diagrams for Employee Management System.

7) Draw the Sequence and Collaboration diagrams for Library Management System.

8) Draw the Sequence and Collaboration diagrams for Bus Reservation System.

9) Draw the state Transition Diagrams and Class Diagrams for Automatic Teller

Machine.

10) Draw the state Transition Diagrams and Class Diagrams for Employee Management

System.

11) Draw the state Transition Diagrams and Class Diagrams for Library Management

System.

12) Draw the state Transition Diagrams and Class Diagrams for Bus Reservation

System.

13) Draw the Component Deployment Model for Automatic Teller Machine.

14) Draw the Component Deployment Model for Employee Management System.

15) Draw the Component Deployment Model for Library Management System.

16) Draw the Component Deployment Model for Bus Reservation System.

371

IX SEMESTER (Core Subject)

Digital Image Processing

Unit-I

Introduction :-Fundamentals-The MATLAB Desktop-Using Mat lab Editor /Debugger-

getting help-saving and Retrieving work session data-Digital Image Representation-

Image I/O and Display –Classes and Image Types-M-Function Programming.

Intensity Transformation and Spatial Filtering: - Background-Intensity transformation-

histogram Processing and function Plotting-Spatial filtering-Image processing toolbox

standard spatial filters.

Unit-II

Filtering in Frequency Domain:-The 2-D Discrete Fourier transform-Computing and

Visualizing the 2-D DFT in MATLAB – Filtering in the Frequency domain- Obtaining

frequency domain filters from spatial filters- Generating filters directly in the frequency

domain-sharpening frequency domain filters.

Image Restoration and Reconstruction:- A model of the image degradation / restoration

process- noise models- Restoration in the presence of noise only-Spatial filtering-

periodic noise reduction by frequency domain filtering- Modelling in degradation

function-Direct inverse filtering –wiener filtering- Constrained least squares filtering –

Iterative non-linear restoration using the lucy - Richardson algorithm- Blind

deconvolution - Geometric transformation and image registration.

Unit-III

Color image processing:- Colour image representation in matlab-converting to other

color spaces-The basics of color image processing-Color transformation-spatial filtering

of colour images-Working directly in a RGB vector space

Wavelets:-Background- The fast wavelet transform-working with wavelet decomposition

structures-the inverse wavelet transform-wavelets in image processing.

372

UNIT -IV

Image compression:-Background-coding redundancy-spatial redundancy-irrelevant

information-jpeg compression

Morphological image processor:-preliminaries-dialation and erosion-combining dialation

and erosion-labelling connected components –morphological reconstruction-gray scale

morphology

UNIT-V

Image segmentation:- Image segmentation-point, line and edge detection-Line detection

using the hough transform-thresholding-region-based segmentation using the

watershed transform

Representation and description:-Background-Representation-Boundary descriptors-

regional descriptors using principal components for descriptors.

REFERENCE BOOKS :

1. Rafael C.Gonzalez, Richard E.Woods, Steven L.Eddins ,Image Processing Using

MATLAB,Second edition, Tata McGraw Hill Education Private Limited,New Delhi.

2.Anil.K.Jain, Fundamentals of Digital Image Processing, Prentice-Hall, 1989.

3.Chanda & Majumdar, Digital Image Processing and Analysis, Prentice Hall ,3rd Edition

4.S.Sridhar, Digital Image Processing,Oxford University Press 2011.

IX SEMESTER (Core Subject)

SOFTWARE QUALITY ASSURANCE AND TESTING Unit I Principles of Testing – Software Development Life Cycle Models

Unit II White Box Testing-Integration Testing-System and acceptance testing.

373

Unit III Testing Fundamentals -2 & Specialized Testing: Performance Testing-Regression

testing-Testing of Object Oriented Systems-Usability and Accessibility Testing.

Unit IV Test Planning, Management, Execution and Reporting.

Unit V Software Test Automation-Test Metrics and Measurements

Text Book(s) 1. Software Testing -Srinivasan Desikan, Gopalaswamy Ramesh, Pearson Education

2006.

References 1. Introducing Software testing-Louis Tamres, Addison Wesley Publications, First

Edition.

2. Software testing, Ron Patten, SAMS Techmedia, Indian Edition 2001.

3. Software Quality-Producing Practical, Consistent Software-Mordechai Ben-

Menachem, Gary S Marliss, Thomson Learning, 2003.

IX SEMESTER (Core Subject)

Network Security and Cryptography

Unit I: Introduction – Security Goals – Attacks – Services and Mechanism – Techniques

Traditional Symmetric-key Ciphers: Introduction – Substitution Ciphers – Transposition

Ciphers – Stream and Block Ciphers

Unit II: DES: Introduction – DES Structure – DES Analysis – Multiple DES. AES:

Introduction – Transformations – Key Expansion – Ciphers - Use of Modern Block

Ciphers – use of Stream Ciphers

374

Unit III: Asymmetric-key Cryptography: Introduction – RSA cryptosystem – RABIN

Cryptosystem

Message Integrity & Authentication: Message Integrity – Message Authentication

Unit IV: Digital Signature : Comparison – process – services – attacks on digital signature

– digital signature schemes - variations and applications

Entity authentication : Introduction – passwords – challenge – response – zero

knowledge – biometrics

Unit V: Key Management : Symmetric key distribution – Kerberos – Symmetric key

agreement – Public key distribution

Security at the Transport layer : SSL Architecture – four protocols – SSL message

formats – transport layer security

Reference Books: 1. Behrouz A Forouzan ,”Cryptography & Network Security”, TMH

2. William Stalings,”Cryptography & Network Security” ,PHI

3. Atul Kahate ,”Cryptography & Network Security”, TMH

IX SEMESTER (Elective Subject)

Artificial Neural Networks

UNIT - I Brain Style Computing:Origins and Issues-Lessons from Neuroscience-Artificial

Neurons,Neural Networks and Architectures-Geomentry of Binary Threshold Neurons

and their Networks-

UNIT - II Supervised Learning I:Perceptrons and LMS Supervised Learning II:Back propagation

and Beyond

375

UNIT - III Neural Networks:A Statistical Pattern Recognition Perspective Focusing on

Generalization:Support Vector Machines and Radial Basis Function Networks

UNIT - IV Dynamical Systems Review-Attractor Neural Networks

UNIT - V Adaptive Resonance Theory- Towards the Self Organizing Feature Map.

TEXT BOOK: Satish Kumar, Neural Networks-A Classical Approach, Tata McGraw Hill,2007

REFERENCE BOOK: 1.James A.Freeman and David M.Slapura, Neural Network Algorithms,Application

Programming Techniques,Addition Wesley Publishing Company 1991

2.S.N.Sivanandam,S,Sumathi and S.N.Deepa, Introduction to Neural Networks using

Mat Lab 2006.

IX SEMESTER (Elective Subject)

Mobile Computing UNIT - I Introduction: Advantages of Digital Information - Introduction to Telephone Systems –

Mobile communication: Need for Mobile Communication – Requirements of Mobile

Communication – History of Mobile Communication- Introduction to Cellular Mobile

Communication

UNIT - II Mobile Communication Standards – Mobility Management – Frequency Management –

Cordless Mobile Communication Systems- Mobile Computing: History of data networks

– Classification of Mobile data networks - CDPD System

UNIT - III Satellites in Mobile Communication: Satellite classification – Global Satellite

Communication – Changeover from one satellite to other – Global Mobile

Communication – Interferences in Cellular Mobile Communication- Important

Parameters of Mobile Communication System

376

UNIT - IV Mobile Internet: Working of Mobile IP – Wireless Network Security – Wireless Local

Loop Architecture: Components in WLL – Problems in WLL – Modern Wireless Local

Loop – Local Multipoint Distribution Service – Wireless Application Protocol-WCDMA

Technology and Fibre Optic Microcellular Mobile Communication – Ad hoc Network and

Bluetooth technology – Intelligent Mobile Communication system – Fourth Generation

Mobile Communication systems.

UNIT - V Mobile Application Languages-XML and JAVA:Mobile Application Development- XML -

JAVA-Java 2 Micro Editions-Java Card Mobile Application Development Platforms:OS-

Windows Mobile and CE-Windows Phone 7-Android-Symbian

TEXT BOOK: 1. T.G. Palanivelu, R. Nakkeeran, Wireless and Mobile Communication, PHI Learning

Private Limited.2009

2. Raj Kamal, Mobile Computing,Second Edition,Oxford University Press-2012

REFERENCE BOOK: 1. Jochen Schiller, Mobile Communications, Second Edition, Pearson Education. 2007

2. William Stallings, Wireless Communication and Networks -Pearson Education Asia-

2002

IX SEMESTER (Elective Subject)

CLOUD COMPUTING UNIT – I INTRODUCTION Cloud Computing Introduction, From, Collaboration to cloud, Working

of cloud computing, pros and cons, benefits, developing cloud computing services,

Cloud service development, discovering cloud services.

377

UNIT – II CLOUD COMPUTING FOR EVERYONE Centralizing email communications, cloud

computing for community, collaborating on schedules, collaborating on group projects

and events, cloud computing for corporation, mapping schedulesm managing projects,

presenting on road.

UNIT – III USING CLOUD SERVICES Collaborating on calendars, Schedules and task

management, exploring on line scheduling and planning, collaborating on event

management, collaborating on contact management, collaborating on project

management, collaborating on word processing,spreadsheets, and databases.

UNIT – IV OUTSIDE THE CLOUD Evaluating web mail services, Evaluating instant messaging,

Evaluating web conference tools, creating groups on social networks, Evaluating on line

groupware, collaborating via blogs and wikis

UNIT – V STORING AND SHARING Understanding cloud storage, evaluating on line file storage,

exploring on line book marking services, exploring on line photo editing applications,

exploring photo sharing communities, controlling it with web based desktops. REFERENCE BOOKS 1. Michael Miller, “Cloud Computing”, Pearson Education, New Delhi, 2009 2.Anthony T.Velte,Toby J.Velte,Pobert Elsenpeter,”Cloud Computing”,TMH,2010

Image Processing – Practical List (Tools: Java/Mat Lab/VC++)

Programs should include but not limited to: 1. Read and display digital Images.

2. Image Arithmetic Operations

3. Image Logical Operations

4. Geometric transformation of Image

378

5. Histogram Equalization.

6. Non-linear Filtering.

7. Edge detection using Operators.

8. 2-D DFT and DCT.

9. Filtering in frequency domain.

10. Conversion between color spaces.

11. DWT of images.

12. Segmentation using watershed transform.

Mini Project

Students are to take up sample project development activities with the guidelines given

below:

Preparing a project - brief proposal including

• Problem Identification

• Developing a model for solving the problem

• A statement of system / process specifications proposed to be developed (Data

Flow Diagram)

• List of possible solutions including alternatives and constraints

• Cost benefit analysis

• Time line activities

A report highlighting the design finalization [based on functional requirements &

standards (if any)]

A presentation including the following

• Implementation phase (Hardware / Software / both)

• Testing & Validation of the developed system

• Learning in the project

Consolidated report preparation

379

Semester - X Major Project

The objective of the project is to enable the students to work in a project of latest

topic / research area / industrial applications. Each project student shall have a guide

who is a faculty member.

During this semester the students are expected to do literature survey, formulate

the problem and form a methodology of arriving at the solution of the problem. Also

during this semester, the students are expected to complete the project and submit a

full-fledged report comprising of the complete system developed along with

implementation and test results. The departmental committee shall examine the

students for 50 marks and the evaluation is based on continuous internal assessment

comprising of two reviews.

After two reviews internal 50 marks (is based on seminar (20 marks), demo (20

marks) and internal viva-voce (10 marks)) will be given by the guide. At the end of the

semester, a viva-voce examination will be conducted for 150 marks.

380  

APPENDIX - BA25

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI -12

B.A. Economics (CBCS)

(With effect from the academic year 2012-2013 onwards)

The following changes have been incorporated in the syllabus for

B.A. Economics in Part-IV-Skilled Based Subject for IV & V semesters in

affiliated colleges for those who joined the course from the academic year

2012-2013.

1. Part IV- Skilled Based Subject Appendix – AZ 34

IV Semester – Tourism Management Page No. 386

2. Part IV –Skilled Based Subject (common)

V Semester – Personality Development

381  

APPENDIX - BA26 MANONMANIAM SUNDARANAR UNIVERSITY- TIRUNELVELI-12

B.Sc Physical Education (CBCS) (With effect from the academic year 2012-2013 onwards)

Revised Scheme of Examinations

I Semester

Components Core/Allied Title Hours Credits Part I Tamil 6 3 Part II English 6 3 Part III Core I Foundation of Physical

Education ( 1 Course) 4 4

Core II Theories of Yoga (1 Course )

4 4

Core P I Gymnastics ( Carry over Practical)

2 -

Allied I Anatomy and Physiology (1 Course)

4 4

Allied PI Yoga ( Carry over practical)

2 -

Part IV Environmental Studies ( 1 Course)

2 2

Total ( 6 Courses ) 30 20

II Semester

Components Core/Allied Title Hours Credits Part I Tamil 6 3 Part II English 6 3 Part III Core III Theories of Gymnastics

( 1 Course) 4 4

Core IV Statistics in Physical Education ( 1 Course )

4 4

Core P I Gymnastics ( Carry over Practical)

2 2

Allied II Health Education, Safety Education and First aid (1 Course)

4 4

Allied PI Yoga ( Carry over practical)

2 2

Part IV Value Based Education ( 1 Course)

2 2

Total ( 6 Courses ) 30 24

382  

III Semester

Components Core/Allied Title Hours Credits Part I Tamil ( 1 Course) 6 3 Part II English ( 1 Course) 6 3 Part III Core V Psychology and Sociology in

Physical Education ( 1 Course)

4 4

Core PII Intensive Teaching Practice Practical

2 -

Allied III Computer Applications in Physical Education ( Theory) (1 Course)

4 4

Allied PII Computer Applications in Physical Education ( Carry over practical)

2 -

Part IV Skill Based subject I Sports Medicine ( 1 Course)

4 4

Non Major Elective

Theories of Yoga ( For other than Physical Education ) ( 1 Course)

2 2

Total ( 6 Courses) 30 20

IV Semester

Components Core/Allied Title Hours Credits Part I Tamil ( 1 Course) 6 3 Part II English ( 1 Course) 6 3 Part III Core VI Organisation and

Administration in Physical Education ( 1 Course)

4 4

Core PII Intensive Teaching Practice Practical

2 2

Allied IV Applied Kinesiology (1 Course)

4 4

Allied PII Computer Applications in Physical Education ( Carry over practical)

2 2

PART IV *** Skill Based subject II Bio Mechanics

( 1 Course)

4 4

Non Major Elective

Principles and History of Physical Education( For other than Physical Education ) ( 1 Course)

2 2

Part V Extension Activities ( NCC,NSS,YRS,YWF)

- 1

Total ( 6 Courses) 30 25

383  

V Semester

Components Core/Allied Title Hours Credits Part III Core VII Theories of Games

( Basket Ball, Foot Ball, Hockey, Cricket, Volley Ball ) ( 1 Course)

4 4

Core VIII Theories of Track and Field ( 1 Course)

4 4

Major Elective Sports Nutrition 5 5 Major Elective Exercise Physiology 5 5 Core practical

III Major games ( Basket Ball, Foot Ball, Hockey, Cricket, Volley Ball ) Carry Over practical

3 -

Core practical IV

Track and Field (Carry Over practical )

3 -

Core practical V

Physiotherapy (Carry Over practical)

2 -

Part IV *** Skill Based subject III

Personality Development ( 1 Course)

4 4

Total ( 6 Courses) 30 22

VI Semester

Components Core/Allied Title Hours Credits Part III Core IX Test Measurement and

Evaluation ( 1 Course) 6 4

Core X Principles of Sports Training ( 1 Course)

6 4

Core XI Sports Physiotherapy ( 1 Course)

5 4

Major Elective Sports Journalism and Mass Communication

5 5

Core practical III

Major games ( Basket Ball. Foot Ball, Hockey, Cricket, Volley Ball ) ( 1 Course)

3 4

Core practical IV

Track and Field (Course1) 3 4

Core practical V

Physiotherapy (Course 1) 2 4

Total ( 7 Courses) 30 29 Total Number of Courses : 40 ( 33 T + 7 P ) Total Number of Hours : 180 Total Number of Credits : 140

384  

APPENDIX - BA27

MANONMANIAM SUNDARANAR UNIVERSITY, TIRUNELVELI -12

B.Sc. Costume Design and Fashion (CBCS)

(With effect from the academic year 2012-2013 on wards)

The following changes have been made in the skilled based subject

from V to IV semester in the syllabus for B.Sc. Costume Design and

Fashion (UG) in affiliated colleges for those who joined the course from the

academic year 2012-2013.

1) Part IV - Skilled Based Subject IV Semester

- Appendix –AZ61 a) Fashion photography Page No. 1238, 1239

b) Art portfolio

2) Part IV - Skilled Based Subject (Common) V Semester

a) Effective Communication b) Personality Development


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