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Understanding Pesticides in California’s Delta · Fact Sheet 2012–3132. Printed on recycled...

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Sacramento Sacramento San Francisco San Francisco S a c r a m e n t o R i v e r S a c r a m e n t o R i v e r San Joaq u i n Riv e r San Joaq u i n Riv e r U.S. Department of the Interior U.S. Geological Survey Fact Sheet 2012–3132 November 2012 Printed on recycled paper Understanding Pesticides in California’s Delta Delta Watershed: • 6 million people (2009 estimate). • 4 million acres agricultural land. • 400 pesticides applied for total of 10 million pounds each year. Decades of USGS research have provided a good understanding of when, where, and how pesticides enter the Delta. However, pesticide use is continually changing. New field studies and methods are needed so that scientists can analyze which pesticides are present in the Delta, and at what concentrations, enabling them to estimate exposure and ultimate effects on organisms. Continuing research will provide resource managers and stakeholders with crucial information to manage the Delta wisely. Pesticide Sources • Pesticides are applied in agricultural and urban areas to control unwanted insects, plants, and fungi. • The amount and type of pesticides used changes as pesticides are withdrawn from the market, cropping patterns and pest pressures change, and new chemicals are developed. • Pesticide application, followed by runoff from rain or irrigation, creates well-defined seasonal patterns of pesticide concentrations in Delta water channels. • Waters carrying pesticides enter the Delta from the Sacramento and San Joaquin Rivers, Yolo Bypass, surrounding creeks, and within-Delta lands. • Changing water use and climate affect pesticide input and transport through the Delta. The Sacramento-San Joaquin River Delta (Delta) is the hub of California’s water system and also an important habitat for imperiled fish and wildlife. Aquatic organisms are exposed to mixtures of pesticides that flow through the maze of Delta water channels from sources including agricultural, landscape, and urban pest-control applications. While we do not know all of the effects pesticides have on the ecosystem, there is evidence that they cause some damage to organisms in the Delta.
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Page 1: Understanding Pesticides in California’s Delta · Fact Sheet 2012–3132. Printed on recycled paper November 2012. Understanding Pestici. des in California’s Delta. Delta Watershed:

SacramentoSacramento

San FranciscoSan Francisco

Sacramento River

Sacramento River

San Joaquin River

San Joaquin River

U.S. Department of the InteriorU.S. Geological Survey

Fact Sheet 2012–3132November 2012Printed on recycled paper

Understanding Pesticides in California’s Delta

Delta Watershed:

• 6millionpeople(2009estimate).

• 4millionacresagriculturalland.

• 400pesticidesappliedfortotalof10millionpoundseachyear.

DecadesofUSGSresearchhaveprovidedagoodunderstandingofwhen,where,andhowpesticidesentertheDelta.However,pesticideuseiscontinuallychanging.NewfieldstudiesandmethodsareneededsothatscientistscananalyzewhichpesticidesarepresentintheDelta,andatwhatconcentrations,enablingthemtoestimateexposureandultimateeffectsonorganisms.ContinuingresearchwillprovideresourcemanagersandstakeholderswithcrucialinformationtomanagetheDeltawisely.

Pesticide Sources

• Pesticidesareappliedinagriculturalandurbanareastocontrolunwantedinsects,plants,andfungi.

• Theamountandtypeofpesticidesusedchangesaspesticidesarewithdrawnfromthemarket,croppingpatternsandpestpressureschange,andnewchemicalsaredeveloped.

• Pesticideapplication,followedbyrunofffromrainorirrigation,createswell-definedseasonalpatternsofpesticideconcentrationsinDeltawaterchannels.

• WaterscarryingpesticidesentertheDeltafromtheSacramentoandSanJoaquinRivers,YoloBypass,surroundingcreeks,andwithin-Deltalands.

• ChangingwateruseandclimateaffectpesticideinputandtransportthroughtheDelta.

TheSacramento-SanJoaquinRiverDelta(Delta)isthehubofCalifornia’swatersystemandalsoanimportanthabitatforimperiledfishandwildlife.AquaticorganismsareexposedtomixturesofpesticidesthatflowthroughthemazeofDeltawaterchannelsfromsourcesincludingagricultural,landscape,andurbanpest-controlapplications.Whilewedonotknowalloftheeffectspesticideshaveontheecosystem,thereisevidencethattheycausesomedamagetoorganismsintheDelta.

Page 2: Understanding Pesticides in California’s Delta · Fact Sheet 2012–3132. Printed on recycled paper November 2012. Understanding Pestici. des in California’s Delta. Delta Watershed:

WINTEROrchardsRainfall

SPRINGAlfalfa

Rainfall & Irrigation

SPRING-SUMMERRice

Field Water ReleaseSUMMER

Row/Truck CropsIrrigation

How do Pesticides Move into the Water?

Res

ulting in Distinct Seasons of Pesticide Occurrence

PESTICIDES ARE APPLIED

THEN TRANSPORTED BY WATER AND SEDIMENTS

INTO WATERWAYS

ALL YEARUrban Use

Rainfall & Irrigation

Page 3: Understanding Pesticides in California’s Delta · Fact Sheet 2012–3132. Printed on recycled paper November 2012. Understanding Pestici. des in California’s Delta. Delta Watershed:

How Are Living Organisms Affected?Pe

stic

ide

Conc

entra

tion

Short time at high concentration

Long time at low concentration

Time

EXPOSURE = CONCENTRATION * TIME

CH2 Cl

S

O

N

CH3

H2C

H3C

H3C

CH2CH3

N

CH3

CHCH 2OCH 3

COCH 2CI

CH3

N

S

O

CH2

CH3

PESTICIDES Causes mortality or decreases growth

Changes quantity or quality of food

Direct Effects

Indirect Effects

ORGANISMS LIVING IN THE DELTA ARE EXPOSED TO

PESTICIDES

EFFECTS CAN BE DIRECT OR INDIRECT

Bothpesticideconcentrationandthelengthoftimethatanorganismisexposedtoapesticidedeterminetheeventualeffectithasontheorganism.SomepesticidesmovethroughtheDeltaquickly(hourstodays),butarepresentathighconcentrations.Otherpesticidesarepresentforlongerperiods(weekstomonths),butatmuchlowerconcentrations.Bothtypesofexposurecanaffectanorganism,soitisimportanttoknowspecificenvironmentalpesticideconcentrationsanddurations.

Themostobviouseffectofpesticideexposureonorganismsisdeath,usually,asaresultofdirectexposuretohighconcentrationsofpesticidesoverashorttime.But,exposuretolowerconcentrationsoveralongertimecanbejustasdeadly.Decreasedgrowth,impairedreproduction,andinhibitionofswimmingperformancecanalldiminishpopulationsize.Pesticidesintheenvironmentcanalsohaveindirecteffects,whichresultinproblemssuchasreductioninavailabilityorqualityoffood.

USGS Pesticide Fate Research Group

Waterisanalyzedbecausethisiswheremostanimalslive.Sedimentsareimportantfororganismsthatlivein,oratthebottomof,streams.Pesticidescanalso“moveupthefoodchain”asorganismseatanimalsorplantsthathavealreadyaccumulatedpesticides.Togainamorecompleteviewofenvironmentaleffectsofpesticidesonorganisms,weanalyzewater,sediments,andanimaltissue.

Effectivepesticideanalysisrequirespersistentmethoddevelopmentandresearch.TheUSGSPesticideFateResearchGroupisaleaderincurrent-usepesticidescience.ResearchersfrequentlyaddnewcompoundstoUSGSmethodstokeepupwithchangingpesticideuseandnewenvironmentalconcerns.Laboratorymethodsaresensitiveenoughtopreciselyandaccuratelymeasurepesticideconcentrationlevelsthatareverylowbutthatstillmayaffectlivingorganisms.

Page 4: Understanding Pesticides in California’s Delta · Fact Sheet 2012–3132. Printed on recycled paper November 2012. Understanding Pestici. des in California’s Delta. Delta Watershed:

Authors:KathrynM.Kuivila,[email protected],andJamesL.Orlando,[email protected]

Contact:CaliforniaWaterScienceCenter;6000JStreet,PlacerHall;Sacramento,CA95819http://ca.water.usgs.gov/

For More Information:http://ca.water.usgs.gov/projects/toxics/DesignedbyYvonneRoque

Reference: Kuivila,K.M.andHladik,M.L.,2008.Understandingtheoccur-renceandtransportofcurrent-usepesticideintheSanFranciscoEstuaryWater-shed,SanFranciscoEstuaryandWatershedScience,v.6(3),article2.

Science to Help Resource ManagersSummarizing Our Current Understanding of Pesticides in the DeltaFourmajorseasonalpatternsofriverineinputsofpesticidestotheestuarywereidentifiedonthebasisofapplicationtimingandtransportmechanism.Incontrast,urbaninputstookplacethroughoutmuchoftheyear.Identifieddatagapsincludedthelackofanalysisofmanypesticides(ordegradates),changingpesticideuse,limitedinformationonpesticidetransportwithintheDelta,andanincompleteunderstandingofthetransportandpersistenceofsediment-associatedpesticides(KuivilaandHladik,2008).

State-of-the-ArtAnalyticalLaboratory

Proven Field SamplingMethodsUnderstanding

of Delta Hydrology

Knowledge of Pesticide-Use

Practices

Knowledge of Chemical

Processes

Continuing to Conduct Focused Research on PesticidesADAPTING TO CHANGING USEAspesticideusechangesandnewchemicalscomeonthemarket,thetimingandconcentrationsofpesticidesenteringtheDeltawillchange.Routinemonitoringandadvancedmethodstoanalyzenewpesticidesprovidecurrentinformationonthecomplexmixtureofpesticidespresentintheecosystem.

EVALUATING PESTICIDE FATEPesticidesenteringtheDeltacanbedissolvedinthewaterorattachedtosediments,andcanalsodegradetonewcompoundsofpotentialconcern.Focusedfieldandlaboratorystudiesprovideinformationonthefactorscontrollingtheseprocesses,whichinturninfluencethetransportandpersistenceofpesticides.

ASSESSING FISH EXPOSUREInthecomplexDelta,itisdifficultandexpensivetoadequatelycharacterizefishexposurebymeasuringpesticideconcentrationsinwaterandsediments.Adifferentapproachisto“askthefish”bydirectlyanalyzinglevelsofpesticidesandtheirmetabolitesinfishtissuewithsensitiveanalyticalmethods.

Through ongoing collaborations with toxicologists, ecologists, and fisheries biologists, we can address questions of concern such as “how do pesticides affect native fish populations in the Delta and the ecosystem as a whole?”

Using Our Expertise to Address Data Gaps


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