May 15, 2017May 17, 2017
Cairo, Egypt Alexandria, Egypt
A unified approach to enhance your refinery performanceUnityTM Hydroprocessing CatalystsAravindan Kandasamy
UOP Limited, Guildford, UK
2017 Honeywell Oil & Gas Technologies Symposium
UOP 7804F-1
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Outline
– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel
– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel
• Key Learnings
UOP 7804F-2
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Outline
– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel
– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel
• Key Learnings
Unity
Honeywell UOP
UOP 7804F-3
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Honeywell UOP Unity Portfolio4
UOP Unity Hydrotreating catalysts available to you
Unity portfolio includes:hydrotreating catalystshydrocracking catalysts
UnityHoneywell UOP
Honeywell UOP Unity Portfolio5
UOP 7804F-5
Honeywell UOP Unity Portfolio6
UOP 7804F-6
Honeywell UOP Unity Portfolio7
UOP 7804F-7
Flexibility Through Comprehensive Choice:8
Flexibility allows profitability
UnityHoneywell UOP
• Hydrotreating and Hydrocracking• Unified approach to drive profitability• Intended to meet your Needs
Fundamental R&D Knowledge - An Enabler:9
Fundamental R&D results in UOP Unity
3 ring aromatics
UOP’s Fundamental knowledge developed over time:• Alumina technology, particle morphology and surface chemistry• Forming techniques and precise control of pore size distribution• Catalyst physical properties impact on diffusion properties and reactivity• Feed characterization• Manufacturing techniques and methods for metals loading
UOP Unity | Hydrocracking Pretreat Catalysts10
Rigorous R&D and manufacturing – Robust performance
• Effective on a wide range of feeds– Atmospheric and Vacuum Gas Oil – Heavy Coker Gas Oil– Light Cycle Oil– Deasphalted Oil
• Designed to deliver the required HDN, HDA and HDS performance
• Prepare feeds for improved conversion to desired products
Commercially Proven
UOP 7804F-11
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Outline
– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel
– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel
• Key Learnings
HYT-6219 Commercial Experience: Improved Profitability Through increased Diesel
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Maximum Diesel with Stringent Specification
Cycle Objectives• Achieve cycle length of 2 years• Produce EURO V diesel quality product• Increase diesel yields
Type of hydrocracking technology• Non-UOP design of single stage recycle
with Recycle to R-1
Feed Composition• CGO, AGO, VGO • Opportunistic feedsConversion: • 95% volCut Point: • ASTM 370°C (698°F)
Unity
Hydroprocessing Catalysts
UOP Unity
HYT-6219
UOP Unity
Flexible HC
UOP Catalyst solution:
HYT-6219 in Hydrocracking Pretreat Service
Enhance performance of both catalyst systems
Hydrotreating Hydrocracking
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Unity
Hydroprocessing Catalysts
Products
Feed
TM
Generates high yields of either middle distillates or naphtha
HYT
8119
HYT
6219
HC
150
State-of-the-arthydrodemetallization catalyst with high capacity for nickel and vanadium uptake
Distillate selective flexible catalyst that produces higher distillate yields
Desulfurization and saturation catalyst for hydrocracking and ULSD applications
HC
140
0 50 100 150 200 250 300 350 400 450 500
Nitr
ogen
at o
utle
t, w
t-ppm
HT
WA
BT, °
C
Days on Stream
HYT-6219 Performance
Hydrotreating WABT
Expected Deactivation
Nitrogen at outlet
Nitrogen Target
Hydrocracking Pretreat Catalyst Performance14
Robust activity and stability to enable cycle
HYT-6219 delivers excellent HDN
activity and stability
HYT-6219 delivers excellent nitrogen
removal
0 50 100 150 200 250 300 350 400 450 500
HC
WA
BT, °
C
Days on Stream
HC Catalyst Performance
Hydrocracking WABT
Expected Deactivation
Hydrocracking Catalyst Performance15
The extra activity enables options for profitability
Hydrocracking catalyst activity and
stability enables CHOICE
• Longer cycle?• Drive operation to max diesel?• Customize loading for next cycleExpected cycle to exceed
target cycle length by 15%** Assuming increased operating window while
feed properties and targets remain same, based on HYT and HC activity & stability
Excellent Diesel Product Properties16
Enabling Profitability
• Diesel quality is better than EURO V, enabling more options for the diesel pool and overall refinery economics
Specification Target Achieved
Density @15C, kg/m3 Max 845 <<845
Sulphur, wppm Max 10 <<10
ASTM D86 T95%, °C Max 360 <360
Cetane Number Min 51 >51
0 50 100 150 200 250 300 350 400 450 500
Die
sel S
p G
ravi
ty
Cet
ane
Inde
x
Days on Stream
Cetane Index
Cetane Index Target
Diesel Sp Gravity
Diesel Sp Gravity Target
Unity Case Story: Improved Profitability Through increased Diesel
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UOP Unity helps refiners increase profitability
Cycle Objectives• Achieve cycle length• Produce EURO V diesel quality
product• Increase middle distillate yields
UOP Unity Results:Expected to exceed target
cycle length by 25%, based on catalyst activity and stability
Diesel product properties better than EURO V
Unity
HydroprocessingCatalysts
UOP Unity
HYT-6219
UOP Unity
Flexible HC
• Hydrotreating and Hydrocracking• Unified approach• Intended to meet your Needs
UOP 7804F-18
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Outline
– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel
– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel
• Key Learnings
Commercial ULSD Unit with HYT-621919
Feed Details BlendSource Imported
Blend 45% LCGO
27% CN15% SRD13% LCO
API 43Sp Gravity 0.81Sulfur, wt-% 0.3Nitrogen, wt-ppm 1100Bromine Number 35150 °C + content, Wt-% 85*
* Est from Naphtha Yield
Operating Conditions ValueReactor I/L H2 PP, MPag 7.0
SOR WABT (Main Catalyst), °C 350H2 to Oil, Nm3/m3 740
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Feed
MU H2
Separator
To Fractionation
Hydrotreater
HYT-6219 Improves Unit to Meet ULSD Specifications
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Product Quality Previous Cycle
Sulfur, wt-ppm 50 – 150
Cetane Index 46 – 51
Pour Point, °C -5 to – 18
CFPP, °C -3
Flash Point, °C 64 – 66
Producing Profitable Euro V Diesel
After Reload with HYT-6219
3 - 8
48 – 53
-13 to < -20
– 10
60 - 68
UOP 7804F-21
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Outline
– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel
– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel
• Key Learnings
Unity Hydrotreating Catalysts
• Manufactured in USA• State-of-the-art catalyst technology for high performance• Commercially proven in several challenging applications
– HC Pretreat– VGO Pretreat– ULSD– Mild hydrocracking
• Combine with HYT-8109 and HYT-8119 for demet of challenging feeds• Combine with Cat Trap for feeds with fouling tendencies
Unity
Hydroprocessing Catalysts
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Key Learnings What Can UOP Unity Catalysts Do For You?
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• Unity - Honeywell UOP hydrotreating and hydrocracking catalyst portfolio
Now UOP Unity is available to you!
• Benefit from Tailored Performance through UOP Unity portfolio
• Extra Profitability for your Hydroprocessing units within your refineries and petrochemical complexes
• Complete Solution from UOP: – Process technology – Catalyst Solutions – Equipment Solutions – and Operational Support
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UnityTM
Unified approach | Hydrotreating and Hydrocracking | Universal compatibility
Honeywell UOP
Hydroprocessing Catalysts
UOP 7804F-24
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UOP 7804F-25