© 2018 UOP LLC. A Honeywell Company All rights reserved.

UOP UNITY™ Hydrotreating ProductsSatyam Mishra

19 February 2018 Honeywell UOP ME-TECH SeminarDubai, UAE

UOP 8080A-0

Outline

1

UOP 8080A-1

Introducing ULTIMet™UOP Unity™ Hydroprocessing

Catalyst Portfolio

• Unity™ Case Story 1:

Hydrotreating catalyst

enabling ULSD production

• Unity™ Case Story 2:

Hydrotreating catalyst in

Hydrocracking pretreat

service

• Unity™ Case Story 3:

Successful commercialization

of HYT 4118 (Co-Mo

Catalyst) in ULSD service

UNITY

Unity

Honeywell UOP

Hydrotreating and Hydrocracking

Unified approach

Universal compatibility

Unity

UOP 8080A-2

2

Unity Means…Hydroprocessing Technology You Can Rely On

New Unit Design, Revamp, Process, Technology & Equipment Capabilities

3

0

40,000

80,000

120,000

160,000

200,000

1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 2020

Lic

en

se

d C

ap

ac

ity,

BP

SD

Award Year

UOP Hydroprocessing Experience

Unionfining Units

Unicracking Units

• Naphtha Hydrotreating

• Coker Naphtha Hydrotreating

• Gasoline Selective Desulfurization

• Kerosene Hydrotreating

• Distillate Hydrotreating

• VGO (Cat Feed) Hydrotreating

• Fixed-Bed Resid Hydrotreating

Unity Hydroprocessing Catalysts

4

Innovation Built on 50 Years in Hydroprocessing

UOP 8080A-4

UOP Unity Hydrotreating Catalysts Can Help Refiners Meet Market Demands

Catalysts Meeting Expectations At All Units

01 02

CASE STUDY CASE STUDY

HYT-6219 in ULSD Service HYT-6119 Hydrocracking Pretreat Service

03

CASE STUDY

HYT-4118 Commercialization in

ULSD Service

5

Unity Case Story 1: Enabling On-Spec ULSD Production

6

UOP 7200-6Objective: Deliver EURO V Only With a Change in Catalyst

Cycle Objectives

• Achieve cycle length• Successfully produce 10ppm• No revamp

Operating conditions:

• 70 bar(g) Reactor Inlet H2 PP

• 740 Nm3/m3 H2 to Oil,

UOP Catalyst solution:

Feed Composition

Unity

Hydroprocessing

Catalysts

UOP Unity

HYT-6219

Feed Details Blend

Source Imported

Blend

45% LCGO27% CN

15% SRD13% LCO

API 43

Specific Gravity 0.81

Sulfur, Wt-% 0.3

Nitrogen, wt-ppm 1100

Bromine Number 35

150°C+ (300°F+) Content, Wt-% 85*

* Est from Naphtha Yield

UOP Service and Sales Support Unit Troubleshooting

7

HYT-6219 Allowing 10% Increased Unit Throughput

ULSD Case Story #1

Base+20

Base+15

Base+10

Base+5

Base

Base-5

Base-10

Pro

du

ct

Su

lfu

r, w

pp

m

High activity of HYT-6219

Allowing Customer to Increase

Feed Rate 10% Above Design

& Still Make ULSD product

0 20 40 80 100 120 140 180

Operating Days Since Start of Run

60 160

Gasoline, Sulfur, wppm

Diesel Sulfur, wppm

Product Sulfur

Reactor BypassClosed

Target Operation

Unity Case Story 1:HYT-6219 Enables Meeting ULSD Specifications

Product Quality Before usage

Sulfur, wt-ppm 50 – 150

Cetane Index 46 – 51

After Reload with HYT-6219

3 - 8

48 – 53

Unity Catalyst and Service Key Enabler for EURO V Diesel

Achieved diesel quality is better than EURO V

Unity catalyst and UOP sales support/service key for this achievement

8

UOP Unity Hydrotreating Catalysts Can Help Refiners Meet Market Demands

Catalysts Meeting Expectations At All Units

01 02

CASE STUDY CASE STUDY

HYT-6219 in ULSD Service HYT-6119 Hydrocracking Pretreat Service

03

CASE STUDY

HYT-4118 Commercialization in

ULSD Service

9

Unity Case Story 2: Upgrading Petrochemical Feedstocks

UOP 7200-10Flexibility to Upgrade to Petrochemicals Feedstock

Cycle Objectives

• Achieve cycle length

• Improve naphtha quality and yield for downstream petrochemical production

Type of hydrocracking technology

• Non-UOP hydrocracking unit design

Feed Composition

• VGO/LCGO/HCGO

Conversion:

• 90% vol

UOP Catalyst solution:

Unity

Hydroprocessing

Catalysts

UOP Unity

HYT-6119

UOP Unity

Naphtha HC

10

Reactor Temperatures

Robust Hydrocracking Pretreat in Severe Conditions

11

HYT-6119 delivers

improved stability

Pretreat Reactor Temperatures

0 100 200 300 400 500 600 700

Operating Days Since Start of Run

R-6101 WABT

WABT Normalized to Average Conditions

Proposal Predicted WABT at Design Conditions

No

rmali

zed

Avera

ge B

ed

Tem

pera

ture

, °C

11

Nitrogen Slip from HC Pretreat Reactor

Excellent HDN Activity with HYT-6119 Catalyst

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Effluent Nitrogen

0 100 200 300 400 500 600

Calendar Days Since Start of Run

Nit

rog

en

, W

t-p

pm

Pretreat Outlet N (ppm)

Target Operation

12

No

rma

lize

d A

ve

rag

e B

ed

Te

mp

era

ture

, °C

Hydrocracking Catalyst Performance

Unity Delivers Improved Heavy Naphtha for Petrochemical Use

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Improved Stability

Normalized WABT

0 100 200 300 400 500 600 700

Operating Days Since Start of Run

R-6102 WABT

WABT Normalized to Average Conditions

Proposal Predicted WABT at Design Conditions

Unity Case Story 2 -Hydrocracker Products Feed The Aromatics Complex:

14

UOP 7200-14Understanding of the Big Picture Behind Refinery Operations

VGOLCGOHCGO Heavy

Naphtha

Hydrocracker

DesaltedCrude Oil

Cumene

p-XyleneNaphtha

BenzeneAromaticsComplex

BTX

CrudeFractionation

CCR

Results

• Unity portfolio delivers improved heavy naphtha product properties

• The achieved heavy naphtha properties enable extra $9 million per year of aromatics production

Unity

Hydroprocessing

Catalysts

UOP Unity

HYT-6119

UOP Unity

Naphtha HC

Cycle Objectives

• Achieve cycle length

• Increase naphtha quality and yield for downstream petrochemical production

UOP Unity Hydrotreating Catalysts Can Help Refiners Meet Market Demands

Catalysts Meeting Expectations at All Units

01 02

CASE STUDY CASE STUDY

HYT-6219 in ULSD Service HYT-6119 Hydrocracking Pretreat Service

03

CASE STUDY

HYT-4118 Commercialization in

ULSD Service

15

16

Cycle Objectives

• Meet or Exceed cycle length

• Diesel Sulphur of < 10 wt-ppm

Operating conditions:

• 29 barg Reactor Inlet (23 bara I/L H2 PP)

• 250 Nm3/m3 H2 to Oil,

• LHSV 1.8 – 2.3 h-1

Our Catalyst solution:

Feed Quality

Feed Details Blend

Source Indigenous

Blend 100% SRD

API 42

Specific Gravity 0.815

Sulfur, Wt-% 0.2

D-86 IBP, ºC 175-190

D-86 50%, ºC 220-240

D-86 FBP, ºC 340-370

Unity

Hydroprocessing

Catalysts

UOP Unity

HYT-4118

Unity Case Story 3Successful Commercialization of HYT-4118

UOP 8080A-16

0 10 20 30 40 50 60 70

Pro

du

ct

Su

lph

ur,

Wt-

pp

m

WA

BT,

°C

Calendar Days on Stream

Product Sulphur Target = 10 ppm

UOP Services

helped to optimize

unit operations

Base

+ 10 C

+ 20 C

+ 30 C

EOR WABT

Unity Integrates Catalyst and Service for Cycle Improvements

17

HYT-4118 Industrial Performance

HYT-4118 delivers

robust performance

HYT-4118 delivers

excellent sulfur

removal

Expected cycle to exceed target cycle length by 50%** Assuming operating conditions and feed

properties and targets remain, based on HYT activity & stability

Unity Case Story 3Successful Commercialization of HYT-4118

18

Cycle Objectives:

• Meet or Exceed Cycle Length

• Diesel Sulphur of < 10 wt-ppm

Unity

Hydroprocessing

Catalysts

UOP Unity

HYT-4118

UOP Unity Provides Flexibility:

Estimate 50% Cycle Increase

OR 30% Higher Capacity

Flexibility with More Difficult Feedstocks

Unity as Enabler for ULSD Production Improvement

Our Catalyst solution:

Unity Means…Access to a Global Network of Experts

Developing Strong Partnerships With You

19

Regional service team members collaborating with deep subject matter experts

Understanding of the big picture behind refinery operations

Knowledge of upstream & downstream units and

their interactions

Unmatched experience in servicing of hydroprocessing units worldwide

Seamless technology transfer from unit design, to unit start-up and catalyst reload

Unity Hydroprocessing Catalysts

20

Innovation Built on 50 Years in Hydroprocessing

UOP 8080A-20

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UOP 8080A-21

Created to Help Refiners Be More Profitable While Meeting Shifting Market Demands

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Refining customers tell us that they want a solution to:

• Get more profit from difficult feeds

• Go longer between catalyst change-outs

• Operate at higher feed rates to improve utilization

• Increase volume swell

A Customized Loading of ULTIMet and HYT-6219 Can Enable These Goals

23

Performance Testing With Heavy VGO

HYT

6219 + =

Improved

• HDS Activity

• HDN Activity

• Aromatics Saturation

UOP 8080A-23Tailored Catalyst Loading Specifically for Your Plant

ULTIMet

24

Premium Catalyst Solution that:

• Requires higher hydrogen availability

• Helps increase profits and margins from difficult feeds

• Provides additional catalyst loading flexibility

• Has the stability and durability for longer periods between change-outs

• Can be operated at higher feed rates

• Boosts volume sell

UOP 8080A-24Or to Put It Simply, Use ULTIMet and Achieve More

Commercial Success of UOP Unity Hydrotreating Catalysts

UOP Hydrotreating Catalysts Gaining World Wide Acceptance

UnityHoneywell UOP

Operating with difficult feeds in

high severity operations

Activity and stability are on

par or better than expectations

Product quality enabling

profitability

Robust catalysts to handle

operating upsets

25

26

UOP 8080A-26

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Q & A

UOP 8080A-27